TWI855430B - Deposition system and method - Google Patents
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- 238000000034 method Methods 0.000 title claims abstract description 173
- 230000008021 deposition Effects 0.000 title claims abstract description 52
- 238000005137 deposition process Methods 0.000 claims abstract description 152
- 239000007789 gas Substances 0.000 claims description 137
- 238000000151 deposition Methods 0.000 claims description 70
- 238000000231 atomic layer deposition Methods 0.000 claims description 23
- 238000010438 heat treatment Methods 0.000 claims description 21
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 claims description 14
- 239000011261 inert gas Substances 0.000 claims description 10
- 238000005229 chemical vapour deposition Methods 0.000 claims description 9
- 238000001505 atmospheric-pressure chemical vapour deposition Methods 0.000 claims description 5
- 235000012431 wafers Nutrition 0.000 description 68
- 239000010408 film Substances 0.000 description 24
- 239000002243 precursor Substances 0.000 description 16
- 239000012159 carrier gas Substances 0.000 description 11
- 238000010586 diagram Methods 0.000 description 6
- 239000010409 thin film Substances 0.000 description 6
- 238000000427 thin-film deposition Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 2
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 1
- 101100233916 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) KAR5 gene Proteins 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- OWKFQWAGPHVFRF-UHFFFAOYSA-N n-(diethylaminosilyl)-n-ethylethanamine Chemical compound CCN(CC)[SiH2]N(CC)CC OWKFQWAGPHVFRF-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45563—Gas nozzles
- C23C16/45565—Shower nozzles
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/50—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
- C23C16/505—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using radio frequency discharges
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/50—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
- C23C16/513—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using plasma jets
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- C—CHEMISTRY; METALLURGY
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/52—Controlling or regulating the coating process
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Abstract
本申請案係關於一種沈積系統及方法。在本申請案之一個實施例中,沈積系統包括:製程腔;噴淋頭,其位於上述製程腔內;以及氣箱,其通過氣體管道連接至上述噴淋頭且包括切換裝置;其中上述氣箱包含第一源氣體及第二源氣體,上述切換裝置可操作以在上述製程腔中執行第一沈積製程期間將上述第一源氣體提供至上述氣體管道,並在上述製程腔中執行第二沈積製程期間將上述第二源氣體提供至上述氣體管道,上述第二沈積製程與上述第一沈積製程不同。The present application relates to a deposition system and method. In one embodiment of the present application, the deposition system includes: a process chamber; a showerhead located in the process chamber; and a gas box connected to the showerhead via a gas pipeline and including a switching device; wherein the gas box contains a first source gas and a second source gas, and the switching device is operable to provide the first source gas to the gas pipeline during a first deposition process in the process chamber, and to provide the second source gas to the gas pipeline during a second deposition process in the process chamber, wherein the second deposition process is different from the first deposition process.
Description
本申請案大體上係關於半導體加工設備領域,且更具體而言,係關於沈積系統及方法。This application relates generally to the field of semiconductor processing equipment and, more particularly, to deposition systems and methods.
半導體製程可包含薄膜沈積製程,例如原子層沈積(ALD)及電漿增強化學氣相沈積(PECVD)等,用以在晶圓或基材上形成各種薄膜以製備半導體裝置。ALD製程製成之薄膜可具有較高的底部覆蓋率,但是要得到所需的膜厚需要較長的時間,因此ALD製程之單位時間出片量(WPH)較低。PECVD製程可實現高的WPH,但是製成之薄膜具有較低的底部覆蓋率。單一沈積製程可能不能同時滿足對於成膜品質(例如底部覆蓋率)及產能(例如WPH)之特定生產需求。Semiconductor processes may include thin film deposition processes, such as atomic layer deposition (ALD) and plasma enhanced chemical vapor deposition (PECVD), which are used to form various thin films on wafers or substrates to manufacture semiconductor devices. The thin films produced by the ALD process can have a higher bottom coverage, but it takes a longer time to obtain the required film thickness, so the ALD process has a lower wafer throughput (WPH). The PECVD process can achieve a high WPH, but the produced thin film has a lower bottom coverage. A single deposition process may not be able to meet specific production requirements for film quality (such as bottom coverage) and throughput (such as WPH) at the same time.
然而,當前沈積系統僅能完成單一沈積製程。因此,需要改良之沈積系統及方法來同時滿足對於成膜品質及產能之需求。However, current deposition systems can only complete a single deposition process. Therefore, an improved deposition system and method are needed to simultaneously meet the requirements for film quality and throughput.
本申請案提供一種沈積系統,其允許在同一製程腔內執行多種不同的沈積製程,從而可在保證成膜品質的同時簡化製程步驟並提高產能。This application provides a deposition system that allows a variety of deposition processes to be performed in the same process chamber, thereby simplifying the process steps and improving productivity while ensuring film quality.
根據本申請案之一些實施例,一種沈積系統可包括:製程腔;噴淋頭,其位於上述製程腔內;以及氣箱,其通過氣體管道連接至上述噴淋頭且包括切換裝置。上述氣箱包含第一源氣體及第二源氣體,上述切換裝置可操作以在上述製程腔中執行第一沈積製程期間將上述第一源氣體提供至上述氣體管道,並在上述製程腔中執行第二沈積製程期間將上述第二源氣體提供至上述氣體管道,上述第二沈積製程與上述第一沈積製程不同。According to some embodiments of the present application, a deposition system may include: a process chamber; a showerhead located in the process chamber; and a gas box connected to the showerhead via a gas pipeline and including a switching device. The gas box includes a first source gas and a second source gas, and the switching device is operable to provide the first source gas to the gas pipeline during a first deposition process in the process chamber, and to provide the second source gas to the gas pipeline during a second deposition process in the process chamber, wherein the second deposition process is different from the first deposition process.
根據本申請案之一些實施例,上述沈積系統亦包括加熱裝置,其可操作以對上述製程腔中之晶圓進行加熱,以使上述晶圓之表面在上述第一沈積製程期間具有第一溫度,且在上述第二沈積製程期間具有第二溫度。According to some embodiments of the present application, the deposition system also includes a heating device operable to heat the wafer in the process chamber so that the surface of the wafer has a first temperature during the first deposition process and has a second temperature during the second deposition process.
根據本申請案之一些實施例,上述第一溫度與上述第二溫度相同或相近。According to some embodiments of the present application, the first temperature is the same as or similar to the second temperature.
根據本申請案之一些實施例,上述沈積系統亦包括射頻裝置,其可操作以在上述第一沈積製程期間將第一射頻功率提供至上述噴淋頭,並在上述第二沈積製程期間將第二射頻功率提供至上述噴淋頭。According to some embodiments of the present application, the deposition system also includes an RF device operable to provide a first RF power to the showerhead during the first deposition process and to provide a second RF power to the showerhead during the second deposition process.
根據本申請案之一些實施例,上述第一射頻功率不同於上述第二射頻功率。According to some embodiments of the present application, the first RF power is different from the second RF power.
根據本申請案之一些實施例,上述第一射頻功率與上述第二射頻功率相同。According to some embodiments of the present application, the first RF power is the same as the second RF power.
根據本申請案之一些實施例,上述第一源氣體不同於上述第二源氣體。According to some embodiments of the present application, the first source gas is different from the second source gas.
根據本申請案之一些實施例,上述第一源氣體與上述第二源氣體相同。According to some embodiments of the present application, the first source gas is the same as the second source gas.
根據本申請案之一些實施例,上述第一沈積製程或上述第二沈積製程為選自原子層沈積製程、化學氣相沈積製程、電漿增強原子層沈積製程、電漿增強化學氣相沈積製程、熱原子層沈積製程、次常壓化學氣相沈積製程中之一種製程。According to some embodiments of the present application, the first deposition process or the second deposition process is a process selected from an atomic layer deposition process, a chemical vapor deposition process, a plasma enhanced atomic layer deposition process, a plasma enhanced chemical vapor deposition process, a thermal atomic layer deposition process, and a sub-atmospheric pressure chemical vapor deposition process.
根據本申請案之一些實施例,一種用於根據本申請案之任一實施例之沈積系統之沈積方法可包括:將晶圓提供至上述沈積系統之製程腔內;在上述製程腔內對上述晶圓執行第一沈積製程;在上述第一沈積製程期間,控制氣箱中之切換裝置將上述氣箱中之第一源氣體提供至氣體管道,進而提供至上述製程腔內之噴淋頭;在上述製程腔內對上述晶圓執行不同於第一沈積製程之第二沈積製程;以及在上述第二沈積製程期間,控制上述切換裝置將上述氣箱中之第二源氣體提供至上述氣體管道,進而提供至上述製程腔內之上述噴淋頭。According to some embodiments of the present application, a deposition method for a deposition system according to any embodiment of the present application may include: providing a wafer into a process chamber of the deposition system; performing a first deposition process on the wafer in the process chamber; during the first deposition process, controlling a switching device in a gas box to provide a first source gas in the gas box to a gas pipeline and then to a shower head in the process chamber; performing a second deposition process different from the first deposition process on the wafer in the process chamber; and during the second deposition process, controlling the switching device to provide a second source gas in the gas box to the gas pipeline and then to the shower head in the process chamber.
根據本申請案之一些實施例,上述第一沈積製程或上述第二沈積製程為選自原子層沈積製程、化學氣相沈積製程、電漿增強原子層沈積製程、電漿增強化學氣相沈積製程、熱原子層沈積製程、次常壓化學氣相沈積製程中之一種製程。According to some embodiments of the present application, the first deposition process or the second deposition process is a process selected from an atomic layer deposition process, a chemical vapor deposition process, a plasma enhanced atomic layer deposition process, a plasma enhanced chemical vapor deposition process, a thermal atomic layer deposition process, and a sub-atmospheric pressure chemical vapor deposition process.
根據本申請案之一些實施例,上述方法進一步包括:在上述第一沈積製程期間,藉由加熱裝置將上述晶圓之表面加熱至第一溫度;及在上述第二沈積製程期間,藉由上述加熱裝置將上述晶圓之表面加熱至第二溫度。According to some embodiments of the present application, the method further comprises: during the first deposition process, heating the surface of the wafer to a first temperature by a heating device; and during the second deposition process, heating the surface of the wafer to a second temperature by the heating device.
根據本申請案之一些實施例,上述第一溫度與上述第二溫度相同或相近。According to some embodiments of the present application, the first temperature is the same as or similar to the second temperature.
根據本申請案之一些實施例,上述方法進一步包括:在上述第一沈積製程期間,藉由射頻裝置將第一射頻功率提供至上述噴淋頭;及在上述第二沈積製程期間,藉由上述射頻裝置將第二射頻功率提供至上述噴淋頭。According to some embodiments of the present application, the method further comprises: during the first deposition process, providing a first RF power to the showerhead by the RF device; and during the second deposition process, providing a second RF power to the showerhead by the RF device.
根據本申請案之一些實施例,上述第一射頻功率不同於上述第二射頻功率。According to some embodiments of the present application, the first RF power is different from the second RF power.
根據本申請案之一些實施例,上述第一射頻功率與上述第二射頻功率相同。According to some embodiments of the present application, the first RF power is the same as the second RF power.
根據本申請案之一些實施例,上述第一源氣體不同於上述第二源氣體。According to some embodiments of the present application, the first source gas is different from the second source gas.
根據本申請案之一些實施例,上述第一源氣體與上述第二源氣體相同。According to some embodiments of the present application, the first source gas is the same as the second source gas.
根據本申請案之一些實施例,在上述製程腔中對上述晶圓連續執行多次上述第一沈積製程或上述第二沈積製程中之至少一種製程。According to some embodiments of the present application, at least one of the first deposition process or the second deposition process is continuously performed multiple times on the wafer in the process chamber.
根據本申請案之一些實施例,上述沈積系統在上述製程腔中連續執行上述第一沈積製程及上述第二沈積製程。According to some embodiments of the present application, the deposition system continuously performs the first deposition process and the second deposition process in the process chamber.
根據本申請案之一些實施例,上述沈積系統在上述製程腔中交替執行上述第一沈積製程及上述第二沈積製程。According to some embodiments of the present application, the deposition system alternately performs the first deposition process and the second deposition process in the process chamber.
在以下附圖及描述中闡述本申請案之一或多個實例之細節。其他特徵、目標及優勢將根據上述描述及附圖以及申請專利範圍而顯而易見。The details of one or more embodiments of the present application are set forth in the following drawings and description. Other features, objects and advantages will be apparent from the above description and drawings and the scope of the application.
為更好地理解本發明之精神,以下結合本發明之部分實施例對其作進一步說明。In order to better understand the spirit of the present invention, some embodiments of the present invention are further described below.
本說明書內使用之詞彙「在一實施例」或「根據一實施例」並不必要參照相同的具體實施例,且本說明書內使用之「在其他(一些/某些)實施例」或「根據其他(一些/某些)實施例」並不必要參照不同的具體實施例。其目的在於例如主張之主題包括全部或部分範例具體實施例之組合。本文所指「上」及「下」之意義並不限於圖式所直接呈現之關係,其應包含具有明確對應關係之描述,例如「左」及「右」,或者係「上」及「下」之相反。本文所稱之「連接」應理解為涵蓋「直接連接」以及「經由一或多個中間部件連接」。本文中之詞彙「晶圓」應理解為可與術語「晶元」、「底板」、「基材」、「基板」等術語互換使用,可指代任何在其上進行沈積製程之元件,而非某一具有特定結構及組成之元件。本說明書中所使用之各種部件之名稱僅出於說明之目的,並不具備限定作用,不同廠商可使用不同的名稱來指代具備相同功能之部件。The terms "in one embodiment" or "according to an embodiment" used in this specification do not necessarily refer to the same specific embodiment, and the terms "in other (some/certain) embodiments" or "according to other (some/certain) embodiments" used in this specification do not necessarily refer to different specific embodiments. The purpose is, for example, that the claimed subject matter includes a combination of all or part of the exemplary specific embodiments. The meaning of "upper" and "lower" referred to herein is not limited to the relationship directly presented in the drawings, and should include descriptions with a clear corresponding relationship, such as "left" and "right", or the opposite of "upper" and "lower". The term "connected" as used herein should be understood to cover "directly connected" and "connected via one or more intermediate components". The term "wafer" in this article should be understood to be interchangeable with the terms "chip", "base plate", "substrate", "substrate", etc., and can refer to any component on which a deposition process is performed, rather than a component with a specific structure and composition. The names of various components used in this manual are for illustrative purposes only and are not limiting. Different manufacturers may use different names to refer to components with the same function.
以下詳細地論述本發明之各種實施方案。儘管論述了具體實施方案,但是應當理解,此等實施方案僅用於示出之目的。熟習相關技術者將認識到,在不偏離本發明之精神及保護範疇的情況下,可使用其他部件及組態。本發明之實施方案可不必包含說明書所描述之實施例中之所有部件或步驟,亦可根據實際應用而調整各步驟之執行順序。Various embodiments of the present invention are discussed in detail below. Although specific embodiments are discussed, it should be understood that these embodiments are for illustrative purposes only. Those skilled in the art will recognize that other components and configurations may be used without departing from the spirit and scope of protection of the present invention. The embodiments of the present invention may not necessarily include all components or steps in the embodiments described in the specification, and the execution order of each step may be adjusted according to actual applications.
如前所述,單一沈積製程可能不能同時滿足對於成膜品質(例如底部覆蓋率)及產能(例如WPH)之特定生產需求。為了保證薄膜品質並滿足生產需求,可使用多種沈積製程在晶圓上沈積多層不同的薄膜。然而,當前沈積系統在一個製程腔中僅能完成一種沈積製程,要進行不同的沈積製程,就需要將晶圓依次放入不同的製程腔中進行處理,操作步驟複雜且產能較低,而且在晶圓轉移程序中容易對晶圓造成污染。本申請案提供改良之沈積系統及方法來解決上述問題。As mentioned above, a single deposition process may not be able to simultaneously meet specific production requirements for film quality (e.g., bottom coverage) and throughput (e.g., WPH). In order to ensure film quality and meet production requirements, multiple deposition processes can be used to deposit multiple layers of different films on wafers. However, the current deposition system can only complete one deposition process in a process chamber. To perform different deposition processes, the wafers need to be placed in different process chambers for processing in turn. The operating steps are complicated and the throughput is low, and the wafers are easily contaminated during the wafer transfer process. This application provides an improved deposition system and method to solve the above problems.
圖1為根據本申請案之一些實施例之沈積系統10的結構示意圖。沈積系統10可包括製程腔1及氣箱3。製程腔1中可設置噴淋頭2,氣箱3通過氣體管道4連接至噴淋頭2。FIG1 is a schematic diagram of a deposition system 10 according to some embodiments of the present application. The deposition system 10 may include a process chamber 1 and a gas box 3. A shower head 2 may be disposed in the process chamber 1, and the gas box 3 is connected to the shower head 2 via a gas pipeline 4.
如圖1所示,製程腔1中可包含晶圓承載盤5。沈積系統10可對置放在晶圓承載盤5上之晶圓100連續執行多種沈積製程而無需將晶圓100移出製程腔1。此等沈積製程包括但不限於原子層沈積(ALD)製程、化學氣相沈積(CVD)製程、電漿增強原子層沈積(PEALD)製程、電漿增強化學氣相沈積(PECVD)製程、熱原子層沈積(Thermal ALD)製程、次常壓化學氣相沈積(SACVD)製程等。氣箱3可通過氣體管道4向噴淋頭2提供沈積製程所需的各種氣體,例如反應源氣體(反應體(reactant)或者前驅體(precursor))、前驅體載氣(carrier)、吹掃(purge)氣體等。在執行沈積製程期間,噴淋頭2向晶圓100提供各別氣體。在圖1之實例中,噴淋頭2位於晶圓100上方。在其他實施例中,噴淋頭2可位於晶圓100下方。在另一些實施例中,可在晶圓100上方及下方都設置噴淋頭。As shown in FIG. 1 , the process chamber 1 may include a wafer carrier 5. The deposition system 10 may continuously perform a variety of deposition processes on the wafer 100 placed on the wafer carrier 5 without moving the wafer 100 out of the process chamber 1. Such deposition processes include but are not limited to atomic layer deposition (ALD) processes, chemical vapor deposition (CVD) processes, plasma enhanced atomic layer deposition (PEALD) processes, plasma enhanced chemical vapor deposition (PECVD) processes, thermal atomic layer deposition (Thermal ALD) processes, sub-atmospheric pressure chemical vapor deposition (SACVD) processes, etc. The gas box 3 can provide various gases required for the deposition process to the shower head 2 through the gas pipeline 4, such as the reaction source gas (reactant or precursor), the precursor carrier gas, the purge gas, etc. During the deposition process, the shower head 2 provides the wafer 100 with respective gases. In the example of FIG. 1 , the shower head 2 is located above the wafer 100. In other embodiments, the shower head 2 may be located below the wafer 100. In other embodiments, the shower head may be disposed both above and below the wafer 100.
氣箱3中可包含多種氣體。出於簡化之目的,圖1中僅示出氣箱3中之用於第一沈積製程之第一源氣體32、惰性氣體33及用於第二沈積製程之第二源氣體34,其中第二沈積製程不同於第一沈積製程。此等氣體分別儲存於各自的容器內。熟習此項技術者應理解,氣箱3中亦可包含用於第一沈積製程或第二沈積製程之其他氣體,或者用於其他沈積製程之氣體。氣箱3包括切換裝置31。切換裝置31可操作以在沈積製程期間將各別氣體提供至氣體管道4,例如,在執行第一沈積製程期間將第一源氣體32提供至氣體管道4,而在執行第二沈積製程期間將第二源氣體34提供至氣體管道4。切換裝置31之操作可藉由系統控制器(圖中未示出)根據具體製程流程來控制。在一些實施例中,用於第一沈積製程之源氣體與用於第二沈積製程之源氣體不同。在另一些實施例中,用於第一沈積製程之源氣體與用於第二沈積製程之源氣體相同。The gas box 3 may contain a variety of gases. For the purpose of simplification, FIG. 1 only shows a first source gas 32 for a first deposition process, an inert gas 33, and a second source gas 34 for a second deposition process in the gas box 3, wherein the second deposition process is different from the first deposition process. These gases are stored in respective containers. Those skilled in the art should understand that the gas box 3 may also contain other gases for the first deposition process or the second deposition process, or gases for other deposition processes. The gas box 3 includes a switching device 31. The switching device 31 is operable to supply respective gases to the gas pipeline 4 during the deposition process, for example, to supply the first source gas 32 to the gas pipeline 4 during the first deposition process and to supply the second source gas 34 to the gas pipeline 4 during the second deposition process. The operation of the switching device 31 can be controlled by a system controller (not shown) according to a specific process flow. In some embodiments, the source gas used for the first deposition process is different from the source gas used for the second deposition process. In other embodiments, the source gas used for the first deposition process is the same as the source gas used for the second deposition process.
在一些實施例中,切換裝置31包括但不限於一或多個閥35,可藉由敞開或閉合各別閥35實現氣路之切換。在一些實施例中,切換裝置31中之一或多個閥35具有較短的開關時間,例如小於或等於20 ms,從而可實現快速切換沈積製程。圖1之實例僅示出切換裝置31之一種例示性組態,熟習此項技術者應理解,切換裝置31可具有其他元件及結構。在一些實施例中,切換裝置31亦可位於氣箱3外部。In some embodiments, the switching device 31 includes but is not limited to one or more valves 35, and the gas circuit can be switched by opening or closing the respective valves 35. In some embodiments, one or more valves 35 in the switching device 31 have a short switching time, for example, less than or equal to 20 ms, so that a fast switching deposition process can be achieved. The example of FIG. 1 only shows an exemplary configuration of the switching device 31. Those skilled in the art should understand that the switching device 31 may have other components and structures. In some embodiments, the switching device 31 may also be located outside the gas box 3.
在一些實施例中,氣體管道4包括至少兩條氣體管道,例如,其中一條氣體管道用於輸送反應源氣體(例如第一源氣體32或第二源氣體34),另一條氣體管道用於輸送惰性氣體33 (例如前驅體載氣或吹掃氣體)。在一些實施例中,第一源氣體32為用於ALD製程之反應源氣體,例如SAM24 (雙(二乙胺基)矽烷)、O 2及N 2O中之一者或多者;第二源氣體34為用於CVD製程之反應源氣體,例如TEOS (正矽酸乙酯)及/或O 2。在一些實施例中,惰性氣體33包含用於載運反應源(例如SAM24)進入氣體管道4之載氣,例如,用於提供惰性氣體33之管路之部分支路可選擇性地與第一源氣體32連通,以使惰性氣體33載運第一源氣體32進入氣體管道4。氣體管道4之設定可根據實際製程需要進行調整。切換裝置31可操作以選擇性地將各種氣體提供至各別氣體管道。 In some embodiments, the gas pipeline 4 includes at least two gas pipelines, for example, one of the gas pipelines is used to transport a reactive source gas (e.g., the first source gas 32 or the second source gas 34), and the other gas pipeline is used to transport an inert gas 33 (e.g., a precursor carrier gas or a purge gas). In some embodiments, the first source gas 32 is a reactive source gas used in an ALD process, such as one or more of SAM24 (bis(diethylamino)silane), O 2 and N 2 O; the second source gas 34 is a reactive source gas used in a CVD process, such as TEOS (tetraethyl orthosilicate) and/or O 2 . In some embodiments, the inert gas 33 includes a carrier gas for carrying a reaction source (e.g., SAM 24) into the gas pipeline 4. For example, a portion of a branch of a pipeline for providing the inert gas 33 can be selectively connected to the first source gas 32 so that the inert gas 33 carries the first source gas 32 into the gas pipeline 4. The setting of the gas pipeline 4 can be adjusted according to actual process requirements. The switching device 31 can be operated to selectively provide various gases to respective gas pipelines.
在一些實施例中,晶圓承載盤5可包括加熱裝置。例如,晶圓承載盤5中可設置加熱元件(例如電阻絲等)以及溫度感測或控制裝置(例如熱電偶等)。加熱裝置可操作以對製程腔1中之晶圓100進行加熱,使晶圓100之表面溫度滿足沈積製程之要求。例如,在第一沈積製程期間,可藉由加熱裝置使晶圓100之表面具有第一溫度;在第二沈積製程期間,可藉由加熱裝置使晶圓100之表面具有第二溫度。第一溫度可與第二溫度相同或不同。當第一溫度與第二溫度相同或相近(例如,二者差值不超過100℃)時,晶圓100在連續執行之第一沈積製程及第二沈積製程期間具有相同或相近的製程溫度,則可節省用於升降溫程序之時間,提高產能。應瞭解,取決於具體製程條件及升降溫操作方式,用於判斷第一溫度與第二溫度是否相同或相近之差值臨限值亦可高於或低於100℃。In some embodiments, the wafer carrier 5 may include a heating device. For example, a heating element (such as a resistor, etc.) and a temperature sensing or control device (such as a thermocouple, etc.) may be provided in the wafer carrier 5. The heating device may be operated to heat the wafer 100 in the process chamber 1 so that the surface temperature of the wafer 100 meets the requirements of the deposition process. For example, during the first deposition process, the surface of the wafer 100 may have a first temperature by the heating device; during the second deposition process, the surface of the wafer 100 may have a second temperature by the heating device. The first temperature may be the same as or different from the second temperature. When the first temperature is the same as or similar to the second temperature (for example, the difference between the two does not exceed 100° C.), the wafer 100 has the same or similar process temperature during the first deposition process and the second deposition process that are performed continuously, which can save time for the temperature ramping process and improve productivity. It should be understood that, depending on the specific process conditions and the temperature ramping operation method, the difference threshold used to determine whether the first temperature and the second temperature are the same or similar may also be higher or lower than 100° C.
在一些實施例中,沈積系統10亦包括射頻裝置6 (例如射頻產生器及匹配電路等)。噴淋頭2可作為或包括射頻電極。射頻裝置6連接至噴淋頭2,且可操作以提供沈積製程所需的射頻功率,例如,在第一沈積製程期間將第一射頻功率提供至噴淋頭2,並在第二沈積製程期間將第二射頻功率提供至噴淋頭2。第一射頻功率可與第二射頻功率相同或不同。在一些實施例中,射頻裝置6可提供高頻功率或低頻功率中之一者或多者。在一些實施例中,射頻裝置6提供之射頻功率之範圍為0至5000 W。射頻裝置6之操作可藉由系統控制器(圖中未示出)根據具體製程流程來控制。射頻裝置6可具有較快的通信速度及較短的通信時間,例如小於或等於10 ms,從而可實現快速切換沈積製程。In some embodiments, the deposition system 10 also includes an RF device 6 (e.g., an RF generator and a matching circuit, etc.). The showerhead 2 may serve as or include an RF electrode. The RF device 6 is connected to the showerhead 2 and is operable to provide the RF power required for the deposition process, for example, providing the first RF power to the showerhead 2 during the first deposition process and providing the second RF power to the showerhead 2 during the second deposition process. The first RF power may be the same as or different from the second RF power. In some embodiments, the RF device 6 may provide one or more of a high frequency power or a low frequency power. In some embodiments, the RF power provided by the RF device 6 ranges from 0 to 5000 W. The operation of the RF device 6 can be controlled by a system controller (not shown) according to a specific process flow. The RF device 6 can have a faster communication speed and a shorter communication time, for example, less than or equal to 10 ms, so as to realize a fast switching deposition process.
在一些實施例中,沈積系統10亦可包括真空泵7。真空泵7連接至製程腔1,其可操作以抽取製程腔1內之氣體。在一些實施例中,真空泵7包括壓力控制裝置,其可用於控制製程腔1內之氣壓。In some embodiments, the deposition system 10 may also include a vacuum pump 7. The vacuum pump 7 is connected to the process chamber 1 and is operable to extract gas from the process chamber 1. In some embodiments, the vacuum pump 7 includes a pressure control device that can be used to control the gas pressure in the process chamber 1.
根據本申請案之一些實施例,沈積系統10可在同一製程腔內對晶圓連續執行多種不同的沈積製程,並且每種沈積製程可執行一次或多次,因此可在保證薄膜品質的同時簡化製程步驟並有效地提高產能。According to some embodiments of the present application, the deposition system 10 can continuously perform a variety of deposition processes on a wafer in the same process chamber, and each deposition process can be performed once or multiple times, thereby simplifying the process steps and effectively improving the throughput while ensuring the film quality.
圖2為根據本申請案之一些實施例之沈積方法20的例示性流程圖。下文結合圖1所示之沈積系統10來描述沈積方法20。熟習此項技術者應理解,方法20亦可應用於具有類似結構或組態之其他沈積系統。FIG2 is an exemplary flow chart of a deposition method 20 according to some embodiments of the present application. The deposition method 20 is described below in conjunction with the deposition system 10 shown in FIG1. Those skilled in the art should understand that the method 20 can also be applied to other deposition systems with similar structures or configurations.
如圖2所示,沈積方法20包括:步驟S1:將晶圓100提供至製程腔1內;步驟S2:在製程腔1內對晶圓100執行第一沈積製程;以及步驟S3:在製程腔1內對晶圓100執行第二沈積製程。第一沈積製程與第二沈積製程不同。沈積方法20亦包括:在第一沈積製程期間,控制切換裝置31將氣箱3中之第一源氣體32提供至氣體管道4;在第二沈積製程期間,控制切換裝置31將氣箱3中之第二源氣體34提供至氣體管道4。第一源氣體32可與第二源氣體34相同或不同。As shown in FIG. 2 , the deposition method 20 includes: step S1: providing a wafer 100 into a process chamber 1; step S2: performing a first deposition process on the wafer 100 in the process chamber 1; and step S3: performing a second deposition process on the wafer 100 in the process chamber 1. The first deposition process is different from the second deposition process. The deposition method 20 also includes: during the first deposition process, controlling the switching device 31 to provide a first source gas 32 in the gas box 3 to the gas pipeline 4; during the second deposition process, controlling the switching device 31 to provide a second source gas 34 in the gas box 3 to the gas pipeline 4. The first source gas 32 may be the same as or different from the second source gas 34.
在一些實施例中,沈積方法20亦包括:在第一沈積製程期間,藉由加熱裝置(例如晶圓承載盤5中之加熱裝置)將晶圓100之表面加熱至第一溫度;在第二沈積製程期間,藉由加熱裝置將晶圓100之表面加熱至第二溫度。第一溫度可與第二溫度相同或不同。當第一溫度與第二溫度相同或相近(例如,二者差值不超過100℃)時,可節省切換沈積製程時用於升降溫程序之時間,提高產能。應瞭解,取決於具體製程條件及升降溫操作方式,用於判斷第一溫度與第二溫度是否相同或相近之差值臨限值亦可高於或低於100℃。In some embodiments, the deposition method 20 also includes: during the first deposition process, heating the surface of the wafer 100 to a first temperature by a heating device (e.g., a heating device in the wafer carrier 5); during the second deposition process, heating the surface of the wafer 100 to a second temperature by a heating device. The first temperature may be the same as or different from the second temperature. When the first temperature is the same or similar to the second temperature (e.g., the difference between the two does not exceed 100°C), the time used for the temperature rise and fall procedures when switching the deposition process can be saved, thereby improving productivity. It should be understood that, depending on the specific process conditions and the temperature rise and fall operation method, the difference threshold used to determine whether the first temperature and the second temperature are the same or similar may also be higher or lower than 100°C.
在一些實施例中,沈積方法20亦包括:在第一沈積製程期間,藉由射頻裝置6將第一射頻功率提供至製程腔1內之噴淋頭2;在第二沈積製程期間,藉由射頻裝置6將第二射頻功率提供至製程腔1內之噴淋頭2。第一射頻功率可與第二射頻功率相同或不同。In some embodiments, the deposition method 20 also includes: during the first deposition process, the RF device 6 provides a first RF power to the showerhead 2 in the process chamber 1; during the second deposition process, the RF device 6 provides a second RF power to the showerhead 2 in the process chamber 1. The first RF power may be the same as or different from the second RF power.
在一些實施例中,可在製程腔1中對晶圓100連續執行多次第一沈積製程或第二沈積製程中之至少一種製程。例如,在連續執行多次第一沈積製程之後執行一次第二沈積製程;或者在執行一次第一沈積製程之後連續執行多次第二沈積製程;或者在連續執行多次第一沈積製程之後連續執行多次第二沈積製程。In some embodiments, at least one of the first deposition process or the second deposition process may be continuously performed multiple times on the wafer 100 in the process chamber 1. For example, the second deposition process may be performed once after the first deposition process is continuously performed multiple times; or the second deposition process may be continuously performed multiple times after the first deposition process is performed once; or the second deposition process may be continuously performed multiple times after the first deposition process is continuously performed multiple times.
在一些實施例中,可在製程腔1中對晶圓100連續執行第一沈積製程及第二沈積製程,即在執行一次或多次第一沈積製程之後緊接著執行第二沈積製程。在另一些實施例中,在執行一次或多次第一沈積製程之後,可接著執行其他製程,然後再執行第二沈積製程。In some embodiments, the first deposition process and the second deposition process may be continuously performed on the wafer 100 in the process chamber 1, that is, the second deposition process may be performed immediately after performing the first deposition process once or multiple times. In other embodiments, after performing the first deposition process once or multiple times, other processes may be performed, and then the second deposition process may be performed.
在一些實施例中,可在製程腔1中對晶圓100交替執行第一沈積製程及第二沈積製程。例如,在執行一次或多次第一沈積製程之後,執行一次或多次第二沈積製程,接著再執行一次或多次第一沈積製程,之後可能再執行一次或多次第二沈積製程。In some embodiments, the first deposition process and the second deposition process may be alternately performed on the wafer 100 in the process chamber 1. For example, after performing the first deposition process once or multiple times, the second deposition process may be performed once or multiple times, and then the first deposition process may be performed once or multiple times again, and then the second deposition process may be performed once or multiple times again.
在一些實施例中,亦可在製程腔1內對晶圓100執行與第一沈積製程及第二沈積製程不同的其他沈積製程,例如第三沈積製程。類似地,在第三沈積製程期間,可藉由加熱裝置將晶圓100之表面加熱至第三溫度,或者藉由射頻裝置6將第三射頻功率提供至製程腔1內之噴淋頭2。In some embodiments, other deposition processes different from the first deposition process and the second deposition process, such as a third deposition process, may be performed on the wafer 100 in the process chamber 1. Similarly, during the third deposition process, the surface of the wafer 100 may be heated to a third temperature by a heating device, or a third RF power may be provided to the shower head 2 in the process chamber 1 by an RF device 6.
圖3為根據本申請案之一些實施例之在一個製程腔(例如圖1所示之製程腔1)內執行兩種沈積製程的例示性流程圖。該製程流程可在圖1所示之沈積系統10中實施,亦可在具有類似結構或組態之其他沈積系統中實施。圖3之實例可用於沈積SiO膜,其中第一沈積製程為PEALD製程,第二沈積製程為PECVD製程。在其他實施例中,可利用不同的氣體及沈積製程形成不同的薄膜(例如SiN、TiO等)。FIG. 3 is an exemplary flow chart of performing two deposition processes in a process chamber (e.g., process chamber 1 shown in FIG. 1 ) according to some embodiments of the present application. The process flow can be implemented in the deposition system 10 shown in FIG. 1 , or in other deposition systems having similar structures or configurations. The example of FIG. 3 can be used to deposit SiO films, wherein the first deposition process is a PEALD process and the second deposition process is a PECVD process. In other embodiments, different gases and deposition processes can be used to form different thin films (e.g., SiN, TiO, etc.).
如圖3所示,首先,在步驟S11中,向製程腔內通入O 2、N 2O、遠端電漿源(Remote Plasma Source,RPS) Ar以及不載運反應前驅體之Ar載氣。例如,可控制切換裝置31將氣箱3中之O 2、N 2O、RPS Ar以及不載運反應前驅體之Ar載氣提供至各別氣體管道4,進而提供至製程腔1中之噴淋頭2。在一實施例中,O 2之流量可為1000至30000 sccm,N 2O之流量可為0至30000 sccm,RPS Ar之流量可為0至10000 sccm,Ar載氣之流量可為500至10000 sccm,製程腔內氣壓可為1至10托(torr),噴淋頭與晶圓之間的間隙(gap)可為5 mm至80 mm。在其他實施例中,可根據實際需求採用其他製程參數。 As shown in FIG3 , first, in step S11, O 2 , N 2 O, remote plasma source (RPS) Ar, and Ar carrier gas that does not carry reaction precursors are introduced into the process chamber. For example, the switching device 31 can be controlled to provide O 2 , N 2 O, RPS Ar, and Ar carrier gas that does not carry reaction precursors in the gas box 3 to the respective gas pipelines 4, and then to the showerhead 2 in the process chamber 1. In one embodiment, the flow rate of O2 may be 1000 to 30000 sccm, the flow rate of N2O may be 0 to 30000 sccm, the flow rate of RPS Ar may be 0 to 10000 sccm, the flow rate of Ar carrier gas may be 500 to 10000 sccm, the pressure in the process chamber may be 1 to 10 torr, and the gap between the showerhead and the wafer may be 5 mm to 80 mm. In other embodiments, other process parameters may be used according to actual needs.
接著,在步驟S12中,以脈衝形式向製程腔內通入O 2、N 2O、RPS Ar以及載運反應前驅體(例如SAM24)之Ar載氣。例如,可控制切換裝置31將氣箱3中之O 2、N 2O、RPS Ar以及載運反應前驅體之Ar載氣提供至各別氣體管道4,進而提供至製程腔1中之噴淋頭2。該反應前驅體可藉由吸附反應沈積至製程腔內之晶圓之表面。在一實施例中,步驟S12中通入之氣體種類及流量與步驟S11中通入之氣體種類及流量相同,區別僅在於步驟S12中通入之氣體包括載運反應前驅體之Ar載氣,製程腔內氣壓及噴淋頭與晶圓之間的間隙與步驟S11亦相同。在其他實施例中,步驟S12中通入之氣體種類、氣體流量、製程腔內氣壓及噴淋頭與晶圓之間的間隙與步驟S11亦可不同。 Next, in step S12, O 2 , N 2 O, RPS Ar, and Ar carrier gas carrying reaction precursors (e.g., SAM 24) are introduced into the process chamber in a pulsed form. For example, the switching device 31 can be controlled to provide O 2 , N 2 O, RPS Ar, and Ar carrier gas carrying reaction precursors in the gas box 3 to respective gas pipes 4, and then to the showerhead 2 in the process chamber 1. The reaction precursors can be deposited on the surface of the wafer in the process chamber by adsorption reaction. In one embodiment, the type and flow rate of the gas introduced in step S12 are the same as those in step S11, except that the gas introduced in step S12 includes an Ar carrier gas for carrying the reaction precursor, and the gas pressure in the process chamber and the gap between the shower head and the wafer are the same as those in step S11. In other embodiments, the type of gas introduced in step S12, the gas flow rate, the gas pressure in the process chamber, and the gap between the shower head and the wafer may be different from those in step S11.
然後,在步驟S13中執行吹掃步驟,例如,向製程腔內通入O 2、N 2O、RPS Ar以及不載運反應前驅體之Ar載氣,以自晶圓之表面去除過量的反應前驅體及副產物。在一實施例中,步驟S13中通入之氣體種類及流量與步驟S12中通入之氣體種類及流量相同,區別僅在於步驟S13中通入之氣體不載運反應前驅體,製程腔內氣壓及噴淋頭與晶圓之間的間隙與步驟S12亦相同。在其他實施例中,步驟S13中通入之氣體種類、氣體流量、製程腔內氣壓及噴淋頭與晶圓之間的間隙與步驟S12亦可不同。 Then, in step S13, a purge step is performed, for example, O 2 , N 2 O, RPS Ar, and Ar carrier gas that does not carry reaction precursors are introduced into the process chamber to remove excess reaction precursors and byproducts from the surface of the wafer. In one embodiment, the type and flow rate of the gas introduced in step S13 are the same as the type and flow rate of the gas introduced in step S12, the only difference being that the gas introduced in step S13 does not carry reaction precursors, and the gas pressure in the process chamber and the gap between the showerhead and the wafer are also the same as those in step S12. In other embodiments, the type of gas introduced, the gas flow rate, the gas pressure in the process chamber, and the gap between the showerhead and the wafer in step S13 may be different from those in step S12.
接著,在步驟S14中,在保持與步驟S13相同之氣體繼續通入的情況下,開啟射頻裝置(例如圖1所示之射頻裝置6)以提供第一射頻功率至製程腔(例如提供至製程腔1中之噴淋頭2)。第一射頻功率作用於製程腔中之氣體以產生電漿,進而促使製程腔中之晶圓表面形成共價鍵。在一實施例中,第一射頻功率包括高頻功率或低頻功率中之一者或多者。在一實施例中,第一射頻功率之範圍為0至5000 W。Next, in step S14, while the same gas as in step S13 is continuously introduced, the RF device (e.g., the RF device 6 shown in FIG. 1 ) is turned on to provide the first RF power to the process chamber (e.g., to the showerhead 2 in the process chamber 1). The first RF power acts on the gas in the process chamber to generate plasma, thereby causing the formation of covalent bonds on the surface of the wafer in the process chamber. In one embodiment, the first RF power includes one or more of high frequency power or low frequency power. In one embodiment, the first RF power ranges from 0 to 5000 W.
然後,在步驟S15中,在保持與步驟S13相同之氣體繼續通入的情況下,關斷射頻裝置,從而完成一次PEALD沈積製程。Then, in step S15, while the same gas as in step S13 is continuously introduced, the RF device is turned off, thereby completing a PEALD deposition process.
在一實施例中,可重複執行步驟S12至S15多次(例如N次),以執行多次PEALD沈積製程。In one embodiment, steps S12 to S15 may be repeatedly executed multiple times (eg, N times) to perform multiple PEALD deposition processes.
接著,在步驟S21中,向製程腔內通入O 2、N 2O、RPS Ar以及載運反應前驅體之Ar載氣。在一實施例中,步驟S21中之反應前驅體可與步驟S12中之反應前驅體相同,例如SAM24。在另一實施例中,步驟S21中之反應前驅體可為TEOS。步驟S21中通入之氣體種類、氣體流量、製程腔內氣壓及噴淋頭與晶圓之間的間隙可與之前的步驟S11至S15相同或不同。 Next, in step S21, O 2 , N 2 O, RPS Ar, and Ar carrier gas carrying a reaction precursor are introduced into the process chamber. In one embodiment, the reaction precursor in step S21 may be the same as the reaction precursor in step S12, such as SAM24. In another embodiment, the reaction precursor in step S21 may be TEOS. The type of gas introduced in step S21, the gas flow rate, the gas pressure in the process chamber, and the gap between the showerhead and the wafer may be the same or different from the previous steps S11 to S15.
然後,在步驟S22中,在保持與步驟S21相同之氣體繼續通入的情況下,開啟射頻裝置(例如圖1所示之射頻裝置6)以提供第二射頻功率至製程腔(例如提供至製程腔1中之噴淋頭2),產生用於沈積之電漿。在一實施例中,第二射頻功率包括高頻功率或低頻功率中之一者或多者。在一實施例中,第二射頻功率之範圍為0至5000 W。第二射頻功率可與步驟S14中之第一射頻功率相同或不同。Then, in step S22, while the same gas as in step S21 is continuously introduced, the RF device (e.g., the RF device 6 shown in FIG. 1 ) is turned on to provide a second RF power to the process chamber (e.g., to the showerhead 2 in the process chamber 1) to generate plasma for deposition. In one embodiment, the second RF power includes one or more of high frequency power or low frequency power. In one embodiment, the second RF power ranges from 0 to 5000 W. The second RF power may be the same as or different from the first RF power in step S14.
在一實施例中,可重複執行步驟S21至S22多次(例如M次,M可與N相同或不同),以執行多次PECVD沈積製程。In one embodiment, steps S21 to S22 may be repeatedly performed multiple times (eg, M times, where M may be the same as or different from N) to perform multiple PECVD deposition processes.
最後,在步驟S23中停止提供氣體並且關斷射頻裝置,從而完成所有沈積製程。在一些實施例中,在步驟S22與S23之間亦可執行其他沈積製程。Finally, in step S23, the gas supply is stopped and the RF device is turned off, thereby completing all deposition processes. In some embodiments, other deposition processes may also be performed between steps S22 and S23.
雖然圖3例示性地描述在一個製程腔內執行PEALD及PECVD製程之流程,但是本申請案不限於此。本申請案之沈積系統亦可用於執行多種不同製程,並根據不同的沈積製程具有不同的製程流程。Although FIG. 3 exemplarily describes the process of performing PEALD and PECVD processes in one process chamber, the present application is not limited thereto. The deposition system of the present application can also be used to perform a variety of different processes, and has different process flows according to different deposition processes.
圖4A至圖4C為根據本申請案之一些實施例之薄膜沈積程序的示意圖。在此程序中需要填充晶圓400表面上之凹槽401。此程序可在圖1所示之沈積系統10中實施,亦可在具有類似結構或組態之其他沈積系統中實施。可利用圖2或圖3所示之方法或類似方法實施此程序。4A to 4C are schematic diagrams of a thin film deposition process according to some embodiments of the present application. In this process, it is necessary to fill a groove 401 on the surface of a wafer 400. This process can be implemented in the deposition system 10 shown in FIG. 1, or in other deposition systems with similar structures or configurations. This process can be implemented using the method shown in FIG. 2 or FIG. 3 or a similar method.
如圖4A至圖4C所示,在將晶圓400提供至製程腔(例如圖1所示之製程腔1)內之後,可在晶圓400之表面上進行第一沈積製程,以形成第一薄膜402 (如圖4B所示)。第一薄膜402可形成在凹槽401之底部及側壁上,並且封閉凹槽401之頂部。凹槽401中可能留有氣孔403。接著,可在晶圓400之表面上進行第二沈積製程,以形成第二薄膜404 (如圖4C所示)。在一實施例中,第一沈積製程係PEALD製程,因此第一薄膜402可具有較好的覆蓋率。在一實施例中,第二沈積製程係PECVD製程,因此第二薄膜404可具有較快的沈積速度。As shown in FIGS. 4A to 4C , after the wafer 400 is provided into a process chamber (e.g., the process chamber 1 shown in FIG. 1 ), a first deposition process may be performed on the surface of the wafer 400 to form a first film 402 (as shown in FIG. 4B ). The first film 402 may be formed on the bottom and side walls of the groove 401 and close the top of the groove 401. Air holes 403 may be left in the groove 401. Then, a second deposition process may be performed on the surface of the wafer 400 to form a second film 404 (as shown in FIG. 4C ). In one embodiment, the first deposition process is a PEALD process, so the first film 402 may have a better coverage. In one embodiment, the second deposition process is a PECVD process, so the second film 404 may have a faster deposition rate.
圖5A至圖5C為根據本申請案之另一些實施例之薄膜沈積程序的示意圖。在此程序中需要填充晶圓500表面上之凹槽501。此程序可在圖1所示之沈積系統10中實施,亦可在具有類似結構或組態之其他沈積系統中實施。可利用圖2或圖3所示之方法或類似方法實施此程序。5A to 5C are schematic diagrams of thin film deposition processes according to other embodiments of the present application. In this process, it is necessary to fill the groove 501 on the surface of the wafer 500. This process can be implemented in the deposition system 10 shown in FIG. 1, and can also be implemented in other deposition systems with similar structures or configurations. This process can be implemented using the method shown in FIG. 2 or FIG. 3 or a similar method.
如圖5A至圖5C所示,在將晶圓500提供至製程腔(例如圖1所示之製程腔1)內之後,可在晶圓500之表面上進行第一沈積製程,以形成第一薄膜502 (如圖5B所示)。第一薄膜502可形成在凹槽501之底部及側壁上,並且完全填充凹槽501。接著,可在晶圓500之表面上進行第二沈積製程,以形成第二薄膜503 (如圖5C所示)。在一實施例中,第一沈積製程係PEALD製程,因此第一薄膜502可具有較好的覆蓋率。在一實施例中,第二沈積製程係PECVD製程,因此第二薄膜503可具有較快的沈積速度。As shown in FIGS. 5A to 5C , after the wafer 500 is provided into a process chamber (e.g., the process chamber 1 shown in FIG. 1 ), a first deposition process may be performed on the surface of the wafer 500 to form a first film 502 (as shown in FIG. 5B ). The first film 502 may be formed on the bottom and sidewalls of the groove 501 and completely fill the groove 501. Then, a second deposition process may be performed on the surface of the wafer 500 to form a second film 503 (as shown in FIG. 5C ). In one embodiment, the first deposition process is a PEALD process, so the first film 502 may have a better coverage. In one embodiment, the second deposition process is a PECVD process, so the second film 503 may have a faster deposition rate.
本申請案之沈積系統可在晶圓上沈積各種類型之薄膜,並且可根據具體製程需求改變沈積製程以及製程順序。在一實施例中,可在晶圓上順序地執行CVD、ALD及CVD製程,以製備滿足製程需求之薄膜。The deposition system of the present application can deposit various types of thin films on a wafer, and the deposition process and process sequence can be changed according to specific process requirements. In one embodiment, CVD, ALD and CVD processes can be sequentially performed on a wafer to prepare a thin film that meets the process requirements.
根據本申請案之實施例,本申請案之沈積系統及方法可在同一製程腔內對晶圓執行兩種或更多種不同的沈積製程,因此可在滿足薄膜品質需求的同時簡化製程步驟並有效地提高產能。According to the embodiments of the present application, the deposition system and method of the present application can perform two or more different deposition processes on a wafer in the same process chamber, thereby simplifying the process steps and effectively improving the throughput while meeting the film quality requirements.
本說明書中之描述經提供以使熟習此項技術者能夠進行或使用本發明。熟習此項技術者將易於顯而易見對本發明之各種修改,且本說明書中所定義之一般原理可應用於其他變化形式而不會脫離本發明之精神或範疇。因此,本發明不限於本說明書所述之實例及設計,而是被賦予與本說明書所揭示之原理及新穎特徵一致的最寬範疇。The description in this specification is provided to enable one skilled in the art to make or use the invention. Various modifications to the invention will be readily apparent to one skilled in the art, and the general principles defined in this specification may be applied to other variations without departing from the spirit or scope of the invention. Therefore, the invention is not limited to the examples and designs described in this specification, but is to be given the widest scope consistent with the principles and novel features disclosed in this specification.
1:製程腔 2:噴淋頭 3:氣箱 4:氣體管道 5:晶圓承載盤 6:射頻裝置 7:真空泵 10:沈積系統 20:沈積方法 31:切換裝置 32:第一源氣體 33:惰性氣體 34:第二源氣體 35:閥 100:晶圓 400:晶圓 401:凹槽 402:第一薄膜 403:氣孔 404:第二薄膜 500:晶圓 501:凹槽 502:第一薄膜 503:第二薄膜 S1:步驟 S2:步驟 S3:步驟 S11:步驟 S12:步驟 S13:步驟 S14:步驟 S15:步驟 S21:步驟 S22:步驟 S23:步驟 1: Process chamber 2: Shower head 3: Gas box 4: Gas pipeline 5: Wafer carrier 6: RF device 7: Vacuum pump 10: Deposition system 20: Deposition method 31: Switching device 32: First source gas 33: Inert gas 34: Second source gas 35: Valve 100: Wafer 400: Wafer 401: Groove 402: First film 403: Air hole 404: Second film 500: Wafer 501: Groove 502: First film 503: Second film S1: Step S2: Step S3: Step S11: Step S12: Step S13: Step S14: Step S15: Step S21: Step S22: Step S23: Step
本說明書中之揭示內容提及且包含以下各圖: 圖1為根據本申請案之一些實施例之沈積系統的結構示意圖; 圖2為根據本申請案之一些實施例之沈積方法的例示性流程圖; 圖3為根據本申請案之一些實施例之在一個製程腔內執行兩種沈積製程的例示性流程圖; 圖4A至圖4C為根據本申請案之一些實施例之薄膜沈積程序的示意圖;及 圖5A至圖5C為根據本申請案之另一些實施例之薄膜沈積程序的示意圖。 The disclosure in this specification refers to and includes the following figures: Figure 1 is a schematic diagram of the structure of a deposition system according to some embodiments of the present application; Figure 2 is an exemplary flow chart of a deposition method according to some embodiments of the present application; Figure 3 is an exemplary flow chart of performing two deposition processes in a process chamber according to some embodiments of the present application; Figures 4A to 4C are schematic diagrams of thin film deposition procedures according to some embodiments of the present application; and Figures 5A to 5C are schematic diagrams of thin film deposition procedures according to other embodiments of the present application.
根據慣例,圖示中所繪示之各種特徵可能並非按比例繪製。因此,為了清晰起見,可任意擴大或減小各種特徵之尺寸。圖示中所繪示之各部件之形狀僅為例示性形狀,並非限定部件之實際形狀。另外,為了清楚起見,可簡化圖示中所繪示之實施方案。因此,圖示可能並未繪示給定設備或裝置之全部組件。最後,可貫穿說明書及圖示使用相同參考標號來表示相同特徵。As a rule, the various features depicted in the drawings may not be drawn to scale. Therefore, the sizes of the various features may be arbitrarily enlarged or reduced for clarity. The shapes of the components depicted in the drawings are merely illustrative and do not limit the actual shapes of the components. In addition, the embodiments depicted in the drawings may be simplified for clarity. Therefore, the drawings may not depict all components of a given device or apparatus. Finally, the same reference numerals may be used throughout the specification and drawings to represent the same features.
1:製程腔 1: Process cavity
2:噴淋頭 2: Shower head
3:氣箱 3: Air box
4:氣體管道 4: Gas pipeline
5:晶圓承載盤 5: Wafer carrier
6:射頻裝置 6: RF device
7:真空泵 7: Vacuum pump
10:沈積系統 10:Deposition system
31:切換裝置 31: Switch device
32:第一源氣體 32: First source gas
33:惰性氣體 33: Inert gas
34:第二源氣體 34: Second source gas
35:閥 35: Valve
100:晶圓 100: Wafer
Claims (22)
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| CN202111511883.9 | 2021-12-07 | ||
| CN202111511883.9A CN116288261A (en) | 2021-12-07 | 2021-12-07 | Deposition systems and methods |
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| CN118563288B (en) * | 2023-12-26 | 2025-08-19 | 拓荆创益(沈阳)半导体设备有限公司 | Thin film deposition apparatus, thin film deposition method, and storage medium |
| CN118563289B (en) * | 2024-07-31 | 2024-11-29 | 上海陛通半导体能源科技股份有限公司 | Chemical vapor deposition method and apparatus capable of improving film formation uniformity |
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| CN104112639A (en) * | 2013-04-22 | 2014-10-22 | 中微半导体设备(上海)有限公司 | Plasma reaction chamber for realizing fast reaction gas switching and method thereof |
| CN105316651A (en) * | 2014-07-30 | 2016-02-10 | 朗姆研究公司 | Method and device for suppressing parasitic plasma on the back of shower head |
| CN109943826A (en) * | 2018-09-11 | 2019-06-28 | 东南大学 | A kind of multifunctional composite deposition equipment and its preparation process |
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| US20120097330A1 (en) * | 2010-10-20 | 2012-04-26 | Applied Materials, Inc. | Dual delivery chamber design |
| TWI480415B (en) * | 2013-11-27 | 2015-04-11 | 財團法人工業技術研究院 | Multimode thin film deposition apparatus and thin film deposition method |
| CN111524788B (en) * | 2019-02-01 | 2023-11-24 | Asm Ip私人控股有限公司 | Method for forming topologically selective films of silicon oxide |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104112639A (en) * | 2013-04-22 | 2014-10-22 | 中微半导体设备(上海)有限公司 | Plasma reaction chamber for realizing fast reaction gas switching and method thereof |
| CN105316651A (en) * | 2014-07-30 | 2016-02-10 | 朗姆研究公司 | Method and device for suppressing parasitic plasma on the back of shower head |
| CN109943826A (en) * | 2018-09-11 | 2019-06-28 | 东南大学 | A kind of multifunctional composite deposition equipment and its preparation process |
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| WO2023103607A1 (en) | 2023-06-15 |
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