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TWI853724B - Method of forming aluminum alloy - Google Patents

Method of forming aluminum alloy Download PDF

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TWI853724B
TWI853724B TW112137861A TW112137861A TWI853724B TW I853724 B TWI853724 B TW I853724B TW 112137861 A TW112137861 A TW 112137861A TW 112137861 A TW112137861 A TW 112137861A TW I853724 B TWI853724 B TW I853724B
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aluminum alloy
aging
treatment
strength
forming
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TW112137861A
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TW202516033A (en
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庾忠義
邱黃正凱
顏鴻威
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中國鋼鐵股份有限公司
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Abstract

An age forming method for automotive parts of 6XXX and 7XXX aluminum alloys is provided. The automotive 6XXX and 7XXX aluminum alloys processed by this invention can reach excellent mechanical properties after forming and paint baking. This invention includes a pre-aging process and an age forming of 6XXX and 7XXX aluminum alloys. The aluminum alloys show following characteristics: Yield strength of the alloy after pre-aging is lower than 90% of yield strength at peak aging; yield strength of the alloy after age forming is not lower than yield strength after pre-aging. After the processes above, yield strength of the 6XXX and 7XXX aluminum alloys after natural aging and paint baking is not lower than yield strength after age forming.

Description

鋁合金的製造方法 Manufacturing method of aluminum alloy

本發明是關於一種鋁合金及其製造方法,特別是關於一種可做為車用部件的鋁合金及其製造方法。 The present invention relates to an aluminum alloy and a method for manufacturing the same, and in particular to an aluminum alloy that can be used as a vehicle component and a method for manufacturing the same.

近年來,由於節能減碳意識高漲,燃油車及電動車的主要開發策略之一為輕量化。因此,輕量化金屬材料在車體結構的應用逐年提升,其中根據非專利參考文獻[1],高強度鋁合金為現今最重要的車體輕量化材料。習知高強度鋁合金係藉由尖峰時效(T6)熱處理所製得,然而,尖峰時效熱處理會造成鋁合金的延展性隨強度的提升而下降,同時影響鋁合金的冷成形性,進而造成成形部件的裂損。此外,成形後的鋁合金車用部件還須經過塗漆烘烤處理,而塗漆烘烤處理會使前述鋁合金的強度下降,故不利於做為車用部件的應用。 In recent years, due to the rising awareness of energy conservation and carbon reduction, one of the main development strategies for fuel vehicles and electric vehicles is lightweighting. Therefore, the application of lightweight metal materials in vehicle body structures has increased year by year. According to non-patent reference [1], high-strength aluminum alloys are the most important lightweight materials for vehicle bodies today. It is known that high-strength aluminum alloys are produced by peak aging (T6) heat treatment. However, peak aging heat treatment will cause the ductility of aluminum alloys to decrease as the strength increases, and at the same time affect the cold formability of aluminum alloys, thereby causing cracks in formed parts. In addition, the formed aluminum alloy automotive parts must also undergo paint baking treatment, and the paint baking treatment will reduce the strength of the aforementioned aluminum alloy, which is not conducive to its application as automotive parts.

根據非專利參考文獻[2],溫成形(warm forming)將成形溫度提高以換取鋁合金成形性的製程,此外,溫成形時材料的強度較低,故其回彈量較低,因此,溫成形是一種新穎的車用高強度鋁合金成形技術。根據非 專利參考文獻[3],溫成形的溫度一般介於150℃至300℃之間,過低的成形溫度無法提高延展性,而過高的成形溫度會因為析出物過度固溶而造成強度顯著下降。 According to non-patent reference [2], warm forming is a process that increases the forming temperature in exchange for the formability of aluminum alloys. In addition, the strength of the material is lower during warm forming, so its rebound is lower. Therefore, warm forming is a new forming technology for high-strength aluminum alloys for automobiles. According to non-patent reference [3], the temperature of warm forming is generally between 150℃ and 300℃. Too low a forming temperature cannot improve ductility, while too high a forming temperature will cause a significant decrease in strength due to excessive solid solution of precipitates.

專利公開號為WO2017062403A1的習知技術揭露溫成形製程參數以使成形後之6XXX鋁合金可達到200MPa至275MPa的抗拉強度,然而此技術並無法兼顧塗漆烘烤所帶來的影響。目前主要的車用鋁合金溫成形製程必須在適當的溫度進行溫成形,成形時析出物僅會部份固溶,自然時效後再經後續漆烘烤時析出強化,以彌補強度損失。實際上,根據非專利參考文獻[4],這樣的過程就是以溫成形與塗漆烘烤來共同實現回歸與再時效成形(Retrogression and Re-Aging Forming,RRA Forming)。在近期文獻中(例如非專利參考文獻[3]),在預時效處理7075鋁合金中選擇適當的成形溫度參數,使其降伏強度可達到尖峰時效的95%,此為迄今所有報導中最成功的案例。然而在實際案例中,經RRA處理的6XXX系與7XXX系鋁合金多數無法達到如T6尖峰時效的高降伏強度,在競爭激烈的車用金屬材料市場中較趨劣勢,因此鋁合金溫成形技術要被大量應用仍有瓶頸。 The prior art with patent publication number WO2017062403A1 discloses warm forming process parameters so that the 6XXX aluminum alloy after forming can achieve a tensile strength of 200MPa to 275MPa. However, this technology cannot take into account the effects of paint baking. The current main warm forming process for automotive aluminum alloys must be performed at an appropriate temperature. During forming, the precipitates will only be partially dissolved. After natural aging, they will be precipitated and strengthened during subsequent paint baking to compensate for the strength loss. In fact, according to the non-patent reference [4], such a process is to achieve regression and re-aging forming (RRA Forming) by combining warm forming and paint baking. In recent literature (e.g., non-patent reference [3]), by selecting appropriate forming temperature parameters in the pre-aging treatment of 7075 aluminum alloy, its yield strength can reach 95% of that of peak aging, which is the most successful case reported so far. However, in actual cases, most 6XXX and 7XXX aluminum alloys treated with RRA cannot achieve the high yield strength of T6 peak aging, which is at a disadvantage in the highly competitive automotive metal material market. Therefore, there is still a bottleneck for the large-scale application of aluminum alloy warm forming technology.

此外,專利公開號為WO2010032002A1的另一習知技術以熱成形取代溫成形,並在熱成形後進行時效熱處理,使鋁合金達到目標強度。此方法可以避免塗漆烘烤造成的軟化問題,而熱成形對於鋁合金成形之延展性與回彈都較溫成形有優勢。不過,熱成形溫度需達到鋁合金析 出物的固溶溫度以上,高溫製程造成較高的能源損耗並提高成本,此外,熱成形後的部件需要進行較長時間之時效熱處理才能達到高強度,而溫成形或RRA成形一般不必再進行成形後熱處理。 In addition, another known technology with patent publication number WO2010032002A1 replaces warm forming with hot forming, and performs aging heat treatment after hot forming to make the aluminum alloy reach the target strength. This method can avoid the softening problem caused by paint baking, and hot forming has advantages over warm forming in terms of ductility and rebound of aluminum alloy forming. However, the hot forming temperature needs to reach above the solid solution temperature of aluminum alloy precipitates, and the high temperature process causes higher energy loss and increases costs. In addition, the parts after hot forming need to undergo a longer aging heat treatment to achieve high strength, while warm forming or RRA forming generally does not require post-forming heat treatment.

從上述關於先前技術之6XXX系與7XXX系的溫成形與熱成形研究,可以知道目前尚無以時效成形(Age Forming)為基礎之車用高強度鋁合金之溫成形技術。此外,無先前技術涉及預時效與時效成形的串聯應用,亦無先前技術在溫成形技術中整合塗漆烘烤之強化效果與可行性。 From the above research on warm forming and hot forming of the 6XXX series and 7XXX series of prior art, we can know that there is currently no warm forming technology for automotive high-strength aluminum alloys based on age forming. In addition, there is no prior art involving the serial application of pre-aging and age forming, nor is there any prior art integrating the strengthening effect and feasibility of paint baking in warm forming technology.

有鑑於此,亟須提供一種鋁合金及其製造方法,以節能能源及成本的情況下,製得兼具高強度及成形性的鋁合金。 In view of this, it is urgent to provide an aluminum alloy and a manufacturing method thereof, so as to produce an aluminum alloy with high strength and formability while saving energy and cost.

非專利參考文獻 Non-patent references

非專利參考文獻[1]:W. Miller, L. Zhuang, J. Bottema, A.J. Wittebrood, P. De Sment, A. Haszler, A. Vieregge, Recent development in aluminum alloys for the automotive industry, Materials Science and Engineering: A 280(1)(2000) p. 37-49。 Non-patent references [1]: W. Miller, L. Zhuang, J. Bottema, A.J. Wittebrood, P. De Sment, A. Haszler, A. Vieregge, Recent development in aluminum alloys for the automotive industry, Materials Science and Engineering: A 280(1)(2000) p. 37-49.

非專利參考文獻[2]:K. Zheng, D. J. Politis, L. Wang, J. Lin, Areviewon forming techniques for manufacturing lightweight complex-shaped aluminum panel components, International Journal of Lightweight Materials and Manufacture 1(2)(2018) p.55-80。 Non-patent reference [2]: K. Zheng, D. J. Politis, L. Wang, J. Lin, Areviewon forming techniques for manufacturing lightweight complex-shaped aluminum panel components, International Journal of Lightweight Materials and Manufacture 1(2)(2018) p.55-80.

非專利參考文獻[3]:J. A. Österreicher, M.A. Tunes, F. Grabner, A. Arnoldt, T. Kremmer, S. Pogatscher, C.M. Schlögl, Warm-forming of pre-aged Al-Zn-Mg-Cu alloy sheet, Materials & Design 193(2020) 108837。 Non-patent references [3]: J. A. Österreicher, M.A. Tunes, F. Grabner, A. Arnoldt, T. Kremmer, S. Pogatscher, C.M. Schlögl, Warm-forming of pre-aged Al-Zn-Mg-Cu alloy sheet, Materials & Design 193(2020) 108837.

非專利參考文獻[4]:T.A. Ivanoff, Retrogression-reaging and hot forming of AA 7075, 2014。 Non-patent reference [4]: T.A. Ivanoff, Retrogression-reaging and hot forming of AA 7075, 2014.

本發明之一態樣是提供一種鋁合金的製造方法,其係對鋁合金材料進行預時效處理、時效成形處理及塗漆烘烤處理,以製得高強度鋁合金。 One aspect of the present invention is to provide a method for manufacturing an aluminum alloy, which is to perform pre-aging treatment, aging forming treatment and paint baking treatment on the aluminum alloy material to obtain a high-strength aluminum alloy.

本發明之另一態樣是提供一種鋁合金,其係利用上述態樣的方法所製得。 Another aspect of the present invention is to provide an aluminum alloy, which is prepared using the method of the above aspect.

本發明之再一態樣是提供一種車用部件,其係包含上述態樣的鋁合金。 Another aspect of the present invention is to provide a vehicle component, which comprises the aluminum alloy of the above aspect.

根據本發明之一態樣,提供一種鋁合金的製造方法。方法包含提供鋁合金材料,其中鋁合金材料為6XXX系鋁合金或7XXX系鋁合金;對鋁合金材料進行預時效處理,以獲得預時效鋁合金;對預時效鋁合金進行時效成形處理, 以獲得時效成形鋁合金;以及對時效成形鋁合金進行塗漆烘烤處理,以獲得鋁合金。預時效鋁合金之降伏強度為預時效強度;時效成形鋁合金之降伏強度為時效成形強度,且時效成形強度不小於預時效強度;鋁合金之降伏強度不小於時效成形強度。 According to one aspect of the present invention, a method for manufacturing an aluminum alloy is provided. The method comprises providing an aluminum alloy material, wherein the aluminum alloy material is a 6XXX series aluminum alloy or a 7XXX series aluminum alloy; performing a pre-aging treatment on the aluminum alloy material to obtain a pre-aged aluminum alloy; performing an aging forming treatment on the pre-aged aluminum alloy to obtain an aged formed aluminum alloy; and performing a paint baking treatment on the aged formed aluminum alloy to obtain an aluminum alloy. The yield strength of the pre-aged aluminum alloy is the pre-aging strength; the yield strength of the aged formed aluminum alloy is the aged forming strength, and the aged forming strength is not less than the pre-aging strength; the yield strength of the aluminum alloy is not less than the aged forming strength.

根據本發明之一實施例,上述方法更包含對鋁合金原料進行固溶熱處理,以獲得鋁合金材料。 According to one embodiment of the present invention, the above method further includes performing a solid solution heat treatment on the aluminum alloy raw material to obtain an aluminum alloy material.

根據本發明之一實施例,上述預時效強度低於尖峰時效強度的90%。 According to one embodiment of the present invention, the above-mentioned pre-aging strength is less than 90% of the peak aging strength.

根據本發明之一實施例,上述預時效處理的溫度與尖峰時效(T6)處理的溫度相同,且預時效處理的時間為尖峰時效(T6)處理的時間的1/48倍至1/12倍。 According to one embodiment of the present invention, the temperature of the above-mentioned pre-aging treatment is the same as the temperature of the spike aging (T6) treatment, and the time of the pre-aging treatment is 1/48 to 1/12 times the time of the spike aging (T6) treatment.

根據本發明之一實施例,上述時效成形處理的溫度為180℃至280℃。 According to one embodiment of the present invention, the temperature of the aging forming treatment is 180°C to 280°C.

根據本發明之一實施例,上述方法更包含在進行塗漆烘烤處理之前,對時效成形鋁合金進行自然時效處理,其中自然時效處理包含在室溫下存放至少一週。 According to one embodiment of the present invention, the above method further includes performing a natural aging treatment on the aged formed aluminum alloy before performing the paint baking treatment, wherein the natural aging treatment includes storage at room temperature for at least one week.

根據本發明之一實施例,上述時效成形鋁合金不進行一時效熱處理。 According to one embodiment of the present invention, the above-mentioned aging formed aluminum alloy does not undergo an aging heat treatment.

根據本發明之另一態樣,提供一種鋁合金,其係利用上述態樣的方法所製得。 According to another aspect of the present invention, an aluminum alloy is provided, which is prepared using the method of the above aspect.

根據本發明之再一態樣,提供一種車用部件,其係包含上述態樣的鋁合金。 According to another aspect of the present invention, a vehicle component is provided, which comprises the aluminum alloy of the above aspect.

應用本發明之鋁合金的製造方法,結合預時效處理 及時效成形處理,以使鋁合金在成形過程中的強度逐步上升,且在塗漆烘烤處理後,獲得具有高強度而適用為車用部件的鋁合金。 The aluminum alloy manufacturing method of the present invention is applied to combine pre-aging treatment and aging forming treatment, so that the strength of the aluminum alloy is gradually increased during the forming process, and after the paint baking treatment, an aluminum alloy with high strength suitable for automotive parts is obtained.

100:方法 100:Methods

110,120,130,140:操作 110,120,130,140: Operation

根據以下詳細說明並配合附圖閱讀,使本揭露的態樣獲致較佳的理解。需注意的是,如同業界的標準作法,許多特徵並不是按照比例繪示的。事實上,為了進行清楚討論,許多特徵的尺寸可以經過任意縮放。 The following detailed description and accompanying drawings will provide a better understanding of the present disclosure. It should be noted that, as is standard practice in the industry, many features are not drawn to scale. In fact, for the sake of clarity of discussion, the dimensions of many features may be arbitrarily scaled.

[圖1]係繪示根據本發明一些實施例之鋁合金的製造方法的流程圖。 [Figure 1] is a flow chart showing a method for manufacturing an aluminum alloy according to some embodiments of the present invention.

如本發明所使用的「大約(around)」、「約(about)」、「近乎(approximately)」或「實質上(substantially)」一般係代表在所述之數值或範圍的百分之20以內、或百分之10以內、或百分之5以內。 As used in the present invention, "around", "about", "approximately" or "substantially" generally means within 20%, within 10%, or within 5% of the value or range described.

承上所述,本發明提供一種鋁合金的製造方法,結合預時效處理及時效成形處理,以使鋁合金在成形過程中的強度逐步上升,且在塗漆烘烤處理後,獲得具有高強度而適用為車用部件的鋁合金。利用此方法大幅縮短製程時間,且仍能獲得具有高強度的鋁合金,故可有效降低製程成本並達到節能減碳的效益。 As mentioned above, the present invention provides a method for manufacturing aluminum alloy, which combines pre-aging treatment and aging forming treatment to gradually increase the strength of the aluminum alloy during the forming process, and after the painting and baking treatment, obtain an aluminum alloy with high strength suitable for automotive parts. This method greatly shortens the process time, and still obtains an aluminum alloy with high strength, so it can effectively reduce the process cost and achieve the benefits of energy saving and carbon reduction.

請參閱圖1,其係繪示根據本發明一些實施例之鋁 合金的製造方法100的流程圖。首先,進行操作110,提供鋁合金材料。在一些實施例中,鋁合金材料係藉由對鋁合金原料進行固溶熱處理所製得。在一些實施例中,鋁合金材料(或鋁合金原料)可為6XXX系鋁合金或7XXX系鋁合金。在另一些實施例中,鋁合金材料可為鋁合金棒、鋁合金板、鋁合金捲或其他鋁合金製造商生產的鋁合金產品。 Please refer to FIG. 1, which is a flow chart of a method 100 for manufacturing an aluminum alloy according to some embodiments of the present invention. First, operation 110 is performed to provide an aluminum alloy material. In some embodiments, the aluminum alloy material is prepared by solution heat treating an aluminum alloy raw material. In some embodiments, the aluminum alloy material (or aluminum alloy raw material) may be a 6XXX series aluminum alloy or a 7XXX series aluminum alloy. In other embodiments, the aluminum alloy material may be an aluminum alloy rod, an aluminum alloy plate, an aluminum alloy coil, or an aluminum alloy product produced by other aluminum alloy manufacturers.

6XXX系鋁合金又稱為鋁-鎂-矽系列(Al-Mg-Si)鋁合金,例如6111鋁合金及6016鋁合金。舉例而言,6111鋁合金包含0.6wt%至1.1wt%的矽、小於0.4wt%的鐵、0.5wt%至0.9wt%的銅、0.1wt%至0.45wt%的錳、0.5wt%至1.0wt%的鎂、小於0.1wt%的鉻、小於0.1wt%的鈦及平衡量的鋁;而6016鋁合金包含1.0wt%至1.5wt%的矽、小於0.5wt%的鐵、小於0.2wt%的銅、小於0.2wt%的錳、0.25wt%至0.6wt%的鎂、小於0.1wt%的鉻、小於0.15wt%的鈦及平衡量的鋁。再者,7XXX系鋁合金又稱為鋁-鋅-鎂-銅系列(Al-Zn-Mg-Cu)鋁合金,例如7075鋁合金。舉例而言,7075鋁合金包含小於0.4wt%的矽、小於0.5wt%的鐵、1.2wt%至2.0wt%的銅、小於0.3wt%的錳、2.1wt%至2.9wt%的鎂、0.18wt%至0.28wt%的鉻、5.1wt%至6.1wt%的鋅、小於0.2wt%的鈦、小於0.05wt%的鋯及平衡量的鋁。 6XXX series aluminum alloys are also called aluminum-magnesium-silicon series (Al-Mg-Si) aluminum alloys, such as 6111 aluminum alloy and 6016 aluminum alloy. For example, 6111 aluminum alloy contains 0.6wt% to 1.1wt% silicon, less than 0.4wt% iron, 0.5wt% to 0.9wt% copper, 0.1wt% to 0.45wt% manganese, 0.5wt% to 1.0wt% magnesium, less than 0.1wt% chromium, less than 0.1wt% titanium, and the balance of aluminum; while 6016 aluminum alloy contains 1.0wt% to 1.5wt% silicon, less than 0.5wt% iron, less than 0.2wt% copper, less than 0.2wt% manganese, 0.25wt% to 0.6wt% magnesium, less than 0.1wt% chromium, less than 0.15wt% titanium, and the balance of aluminum. Furthermore, 7XXX series aluminum alloys are also called aluminum-zinc-magnesium-copper series (Al-Zn-Mg-Cu) aluminum alloys, such as 7075 aluminum alloy. For example, 7075 aluminum alloy contains less than 0.4wt% silicon, less than 0.5wt% iron, 1.2wt% to 2.0wt% copper, less than 0.3wt% manganese, 2.1wt% to 2.9wt% magnesium, 0.18wt% to 0.28wt% chromium, 5.1wt% to 6.1wt% zinc, less than 0.2wt% titanium, less than 0.05wt% zirconium and the balance of aluminum.

接著,進行操作120,對鋁合金材料進行預時效 處理,以獲得預時效鋁合金。在一些實施例中,預時效處理的溫度與尖峰時效(T6)處理的溫度大約相同,且預時效處理的時間為尖峰時效處理的時間的約1/48倍至約1/12倍。須理解的是,尖峰時效處理的溫度及時間係根據不同的材料組成而有所差異。舉例而言,6XXX系鋁合金的尖峰時效處理可例如為以約180℃的溫度進行約8小時至約10小時,或可例如為以約160℃的溫度進行約16小時至約20小時;而7XXX系鋁合金的尖峰時效處理可例如為以約120℃的溫度進行約24小時。 Next, operation 120 is performed to pre-age the aluminum alloy material to obtain a pre-aged aluminum alloy. In some embodiments, the temperature of the pre-aging treatment is approximately the same as the temperature of the spike aging (T6) treatment, and the time of the pre-aging treatment is about 1/48 to about 1/12 of the time of the spike aging treatment. It should be understood that the temperature and time of the spike aging treatment vary according to different material compositions. For example, the spike aging treatment of 6XXX series aluminum alloys may be performed at a temperature of about 180°C for about 8 hours to about 10 hours, or at a temperature of about 160°C for about 16 hours to about 20 hours; and the spike aging treatment of 7XXX series aluminum alloys may be performed at a temperature of about 120°C for about 24 hours.

操作120所製得之預時效鋁合金具有預時效強度,且預時效強度係低於尖峰時效強度的約90%。在鋁合金為6XXX系鋁合金的一些實施例中,預時效鋁合金的預時效強度為尖峰時效強度的約50%至約90%。在鋁合金為7XXX系鋁合金的一些實施例中,預時效鋁合金的預時效強度為尖峰時效強度的約50%至約90%。須理解的是,預時效強度係指鋁合金經過預時效處理後的降伏強度,而尖峰時效強度係指鋁合金經過尖峰時效處理後的降伏強度。 The pre-aged aluminum alloy produced by operation 120 has a pre-aging strength, and the pre-aging strength is less than about 90% of the peak aging strength. In some embodiments where the aluminum alloy is a 6XXX series aluminum alloy, the pre-aging strength of the pre-aged aluminum alloy is about 50% to about 90% of the peak aging strength. In some embodiments where the aluminum alloy is a 7XXX series aluminum alloy, the pre-aging strength of the pre-aged aluminum alloy is about 50% to about 90% of the peak aging strength. It should be understood that the pre-aging strength refers to the yield strength of the aluminum alloy after the pre-aging treatment, and the peak aging strength refers to the yield strength of the aluminum alloy after the peak aging treatment.

接著,進行操作130,對預時效鋁合金進行時效成形處理,以獲得時效成形鋁合金。在一些實施例中,時效成形處理的溫度為約180℃至約280℃。若時效成形處理的溫度太低(例如小於約180℃),則無法有效提高鋁合金的延展性;時效成形處理的溫度太高(例如大於約280℃),則無法在時效成形製程中有效提高鋁合金的強度。操作130所製得之時效成形鋁合金具有時效成形強度,且時 效成形強度大於預時效強度。經過時效成形處理的時效成形鋁合金不須再進行時效熱處理。須理解的是,時效成形強度係指鋁合金經過時效成形處理後的降伏強度。 Next, operation 130 is performed to perform an aging forming treatment on the pre-aged aluminum alloy to obtain an aged formed aluminum alloy. In some embodiments, the temperature of the aging forming treatment is about 180°C to about 280°C. If the temperature of the aging forming treatment is too low (e.g., less than about 180°C), the ductility of the aluminum alloy cannot be effectively improved; if the temperature of the aging forming treatment is too high (e.g., greater than about 280°C), the strength of the aluminum alloy cannot be effectively improved during the aging forming process. The aged formed aluminum alloy obtained by operation 130 has an aging forming strength, and the aging forming strength is greater than the pre-aging strength. The aged formed aluminum alloy that has undergone the aging forming treatment does not need to undergo an aging heat treatment. It should be understood that the aging forming strength refers to the yield strength of the aluminum alloy after the aging forming treatment.

然後,進行操作140,對時效成形鋁合金進行塗漆烘烤處理,以獲得鋁合金。在一些實施例中,塗漆烘烤處理包含以185℃持溫20分鐘。操作140所製得之鋁合金的強度大於時效成形強度。在一些實施例中,在操作140之前,對時效成形鋁合金進行自然時效處理。自然時效處理包含在室溫下存放至少一週。 Then, operation 140 is performed to perform a paint baking treatment on the aged formed aluminum alloy to obtain an aluminum alloy. In some embodiments, the paint baking treatment includes holding the temperature at 185°C for 20 minutes. The strength of the aluminum alloy obtained by operation 140 is greater than the aging forming strength. In some embodiments, before operation 140, the aged formed aluminum alloy is subjected to a natural aging treatment. The natural aging treatment includes storage at room temperature for at least one week.

方法100係藉由預時效處理對經固溶處理後的鋁合金進行人工時效處理,其所獲得的預時效鋁合金的強度未達尖峰時效處理後的強度,代表鋁合金能在後續時效成形處理中持續析出強化相。故時效成形處理後所獲得的時效成形鋁合金具有比預時效鋁合金更高的強度。然後,在塗漆烘烤處理後所製得之鋁合金還可進一步提升強度。因此,方法100可製得具有較高強度的鋁合金,且同時縮短製程所耗費的時間,減少耗能及製程成本。 Method 100 performs artificial aging treatment on the aluminum alloy after solution treatment by pre-aging treatment. The strength of the obtained pre-aged aluminum alloy does not reach the strength after peak aging treatment, which means that the aluminum alloy can continue to precipitate strengthening phases in the subsequent aging forming treatment. Therefore, the aged formed aluminum alloy obtained after the aging forming treatment has higher strength than the pre-aged aluminum alloy. Then, the aluminum alloy obtained after the paint baking treatment can further improve the strength. Therefore, method 100 can produce an aluminum alloy with higher strength, and at the same time shorten the time spent in the process, reduce energy consumption and process costs.

以下利用數個實施例以說明本發明之應用,然其並非用以限定本發明,本發明技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾。 Several embodiments are used below to illustrate the application of the present invention, but they are not intended to limit the present invention. People with ordinary knowledge in the technical field of the present invention can make various changes and modifications without departing from the spirit and scope of the present invention.

實施例一 Implementation Example 1

實施例一係對固溶熱處理後的AA6111鋁合金進 行成形製程,其中AA6111鋁合金的成份包含0.6wt%至1.1wt%的矽、小於0.4wt%的鐵、0.5wt%至0.9wt%的銅、0.1wt%至0.45wt%的錳、0.5wt%至1.0wt%的鎂、小於0.1wt%的鉻、小於0.1wt%的鈦及平衡量的鋁。AA6111鋁合金的尖峰時效處理條件為180℃持溫480分鐘。 Embodiment 1 is to perform a forming process on the AA6111 aluminum alloy after solution heat treatment, wherein the composition of the AA6111 aluminum alloy includes 0.6wt% to 1.1wt% silicon, less than 0.4wt% iron, 0.5wt% to 0.9wt% copper, 0.1wt% to 0.45wt% manganese, 0.5wt% to 1.0wt% magnesium, less than 0.1wt% chromium, less than 0.1wt% titanium and a balance of aluminum. The peak aging treatment condition of the AA6111 aluminum alloy is 180℃ for 480 minutes.

實施例一先對AA6111鋁合金材料進行180℃持溫10分鐘的預時效處理;接著,進行250℃持溫2分鐘的時效成形處理;然後,經過自然時效1周後,再進行185℃持溫20分鐘的塗漆烘烤處理,以製得實施例一的鋁合金。實施例一的鋁合金在製程中各階段的降伏強度、抗拉強度及延伸率係如表一所示。 In Example 1, the AA6111 aluminum alloy material is first subjected to a pre-aging treatment at 180°C for 10 minutes; then, an aging forming treatment is performed at 250°C for 2 minutes; then, after natural aging for 1 week, a paint baking treatment is performed at 185°C for 20 minutes to obtain the aluminum alloy of Example 1. The yield strength, tensile strength and elongation of the aluminum alloy of Example 1 at each stage of the manufacturing process are shown in Table 1.

比較例一至三 Comparison Examples 1 to 3

比較例一至三係使用與實施例一相同的AA6111鋁合金,並進行與實施例一相似的製程。比較例一至三與實施例一的差異在於,比較例一係先對AA6111鋁合金材料進行180℃持溫480分鐘的尖峰時效處理;比較例二係先對AA6111鋁合金材料進行180℃持溫60分鐘的預時效處理,且將時效成形處理的溫度調整為200℃;而比較例三則是將時效成形處理的溫度提高為300℃。比較例一至三的鋁合金在製程中各階段的降伏強度、抗拉強度及延伸率係如表一所示。 Comparative Examples 1 to 3 use the same AA6111 aluminum alloy as Example 1 and perform a similar process as Example 1. The difference between Comparative Examples 1 to 3 and Example 1 is that Comparative Example 1 first performs a peak aging treatment at 180°C for 480 minutes on the AA6111 aluminum alloy material; Comparative Example 2 first performs a pre-aging treatment at 180°C for 60 minutes on the AA6111 aluminum alloy material, and adjusts the aging forming treatment temperature to 200°C; and Comparative Example 3 increases the aging forming treatment temperature to 300°C. The yield strength, tensile strength and elongation of the aluminum alloys of Comparative Examples 1 to 3 at each stage of the process are shown in Table 1.

表一

Figure 112137861-A0305-02-0013-1
Table 1
Figure 112137861-A0305-02-0013-1

如表一所示,實施例一的鋁合金在進行預時效處理後的降伏強度僅181MPa,且抗拉強度僅為298MPa,其低於比較例一在進行尖峰時效處理後的降伏強度(334MPa)及抗拉強度(398MPa)。實施例一的鋁合金在經過時效成形處理後的降伏強度提升至261MPa,且抗拉強度 提升至312MPa;再經過自然時效及塗漆烘烤處理後,降伏強度進一步提升至297MPa,且抗拉強度提升至355MPa。 As shown in Table 1, the yield strength of the aluminum alloy of Example 1 after pre-aging treatment is only 181MPa, and the tensile strength is only 298MPa, which is lower than the yield strength (334MPa) and tensile strength (398MPa) of Comparative Example 1 after spike aging treatment. The yield strength of the aluminum alloy of Example 1 after aging forming treatment is increased to 261MPa, and the tensile strength is increased to 312MPa; after natural aging and paint baking treatment, the yield strength is further increased to 297MPa, and the tensile strength is increased to 355MPa.

比較例一的鋁合金在尖峰時效處理後降伏強度達334MPa,且抗拉強度達398MPa,但經過時效成形處理後,降伏強度降為289MPa,且抗拉強度降為348MPa;再經自然時效及塗漆烘烤處理後,降伏強度回升至302MPa,且抗拉強度回升至356MPa。比較例一的製程為回歸與再時效成形(Retrogression and Re-Aging Forming,RRA Forming)製程。 The aluminum alloy of Comparative Example 1 has a yield strength of 334MPa and a tensile strength of 398MPa after peak aging treatment, but after aging forming treatment, the yield strength drops to 289MPa and the tensile strength drops to 348MPa; after natural aging and paint baking treatment, the yield strength rises back to 302MPa and the tensile strength rises back to 356MPa. The process of Comparative Example 1 is a Retrogression and Re-Aging Forming (RRA Forming) process.

比較例二的鋁合金延長預時效處理的時間,故在預時效處理後的降伏強度為271MPa,且抗拉強度為338MPa;但在經過時效成形處理後,降伏強度降為254MPa,且抗拉強度降為314MPa;再經自然時效及塗漆烘烤處理後,降伏強度回升至278MPa,且抗拉強度回升至345MPa。故比較例二亦為RRA成形製程,但性能較差。 The aluminum alloy in Comparative Example 2 extends the pre-aging time, so the yield strength after pre-aging is 271MPa, and the tensile strength is 338MPa; but after aging forming treatment, the yield strength drops to 254MPa, and the tensile strength drops to 314MPa; after natural aging and paint baking treatment, the yield strength rises back to 278MPa, and the tensile strength rises back to 345MPa. Therefore, Comparative Example 2 is also an RRA forming process, but the performance is poor.

比較例三以較高溫的300℃進行時效成形處理後,其降伏強度提升至257MPa,且抗拉強度維持298MPa;再經過自然時效及塗漆烘烤處理後,降伏強度僅提升至268MPa,且抗拉強度僅提升至304MPa。由此可知,較高溫的時效成形處理無法有效提高鋁合金的強度。 In comparison example 3, after aging treatment at a relatively high temperature of 300°C, the yield strength increased to 257MPa, and the tensile strength remained at 298MPa; after natural aging and paint baking treatment, the yield strength only increased to 268MPa, and the tensile strength only increased to 304MPa. It can be seen that the relatively high temperature aging treatment cannot effectively improve the strength of aluminum alloys.

AA6111鋁合金的主要析出強化相為棒狀的β”相,棒狀析出相的長軸方向為面心立方鋁基材的<001>方向。 因此,在穿透式電子顯微鏡中,以鋁基材的<001>方向進行分析時,在投影中可觀察到兩組垂直的細長條析出相與一組顆粒狀析出析,其皆為棒狀的β”相。以實施例一及比較例一的結果可理解,以實施例一的時效成形製程及比較例一的RRA成形製程所生成的析出物都是棒狀的β”相,且兩者析出相之密度相似,故析出強化貢獻比例相近。因此,實施例一與比較例一的鋁合金性能相近。實施例一的鋁合金之強度雖不高於比較例一的鋁合金之強度,但以預時效處理取代尖峰時效處理可使此階段的時間縮短約48倍。 The main precipitation strengthening phase of AA6111 aluminum alloy is the rod-shaped β” phase, and the long axis direction of the rod-shaped precipitation phase is the <001> direction of the face-centered cubic aluminum matrix. Therefore, in the transmission electron microscope, when analyzing in the <001> direction of the aluminum matrix, two groups of vertical thin strip precipitation phases and one group of granular precipitation can be observed in the projection, all of which are rod-shaped β” phases. From the results of Example 1 and Comparative Example 1, it can be understood that the precipitates generated by the aging forming process of Example 1 and the RRA forming process of Comparative Example 1 are both rod-shaped β" phases, and the density of the precipitated phases of the two is similar, so the precipitation strengthening contribution ratio is similar. Therefore, the performance of the aluminum alloys of Example 1 and Comparative Example 1 is similar. Although the strength of the aluminum alloy of Example 1 is not higher than that of the aluminum alloy of Comparative Example 1, replacing the peak aging treatment with pre-aging treatment can shorten the time of this stage by about 48 times.

實施例二 Implementation Example 2

實施例二係對固溶熱處理後的AA7075鋁合金進行成形製程,其中AA7075鋁合金的成份包含小於0.4wt%的矽、小於0.5wt%的鐵、1.2wt%至2.0wt%的銅、小於0.3wt%的錳、2.1wt%至2.9wt%的鎂、0.18wt%至0.28wt%的鉻、5.1wt%至6.1wt%的鋅、小於0.2wt%的鈦、小於0.05wt%的鋯及平衡量的鋁。AA7075鋁合金的尖峰時效處理條件為120℃持溫24小時。 Embodiment 2 is to perform a forming process on the AA7075 aluminum alloy after solution heat treatment, wherein the composition of the AA7075 aluminum alloy includes less than 0.4wt% silicon, less than 0.5wt% iron, 1.2wt% to 2.0wt% copper, less than 0.3wt% manganese, 2.1wt% to 2.9wt% magnesium, 0.18wt% to 0.28wt% chromium, 5.1wt% to 6.1wt% zinc, less than 0.2wt% titanium, less than 0.05wt% zirconium and a balance of aluminum. The peak aging treatment condition of the AA7075 aluminum alloy is 120℃ for 24 hours.

實施例二先對AA7075鋁合金材料進行120℃持溫2小時的預時效處理;接著,進行225℃持溫2分鐘的時效成形處理;然後,經過自然時效1周後,再進行185℃持溫20分鐘的塗漆烘烤處理,以製得實施例二的鋁合金。 實施例二的鋁合金在製程中各階段的降伏強度、抗拉強度及延伸率係如表二所示。 In Example 2, the AA7075 aluminum alloy material is first subjected to a pre-aging treatment at 120°C for 2 hours; then, an aging forming treatment is performed at 225°C for 2 minutes; then, after natural aging for 1 week, a paint baking treatment is performed at 185°C for 20 minutes to obtain the aluminum alloy of Example 2. The yield strength, tensile strength and elongation of the aluminum alloy of Example 2 at each stage of the manufacturing process are shown in Table 2.

比較例四及五 Comparison Examples 4 and 5

比較例四及五係使用與實施例二相同的AA7075鋁合金,並進行與實施例二相似的製程。比較例四及五與實施例二的差異在於,比較例四係先對AA7075鋁合金材料進行120℃持溫24小時的尖峰時效處理;而比較例五則是將時效成形處理的溫度提高為300℃。比較例四及五的鋁合金在製程中各階段的降伏強度、抗拉強度及延伸率係如表二所示。 Comparative Examples 4 and 5 use the same AA7075 aluminum alloy as Example 2 and perform a similar process as Example 2. The difference between Comparative Examples 4 and 5 and Example 2 is that Comparative Example 4 first performs a peak aging treatment at 120°C for 24 hours on the AA7075 aluminum alloy material; while Comparative Example 5 increases the temperature of the aging forming treatment to 300°C. The yield strength, tensile strength and elongation of the aluminum alloys of Comparative Examples 4 and 5 at each stage of the process are shown in Table 2.

表二

Figure 112137861-A0305-02-0017-2
Table 2
Figure 112137861-A0305-02-0017-2

如表二所示,實施例二的鋁合金在進行預時效處理後的降伏強度僅291MPa,且抗拉強度僅為551MPa,其低於比較例四在進行尖峰時效處理後的降伏強度(439MPa)及抗拉強度(576MPa)。實施例二的鋁合金在經過時效成形處理後的降伏強度提升至389MPa,且抗拉強度提升至563MPa;再經過自然時效及塗漆烘烤處理後,降伏強度進一步提升至482MPa,且抗拉強度提升至627MPa。 As shown in Table 2, the yield strength of the aluminum alloy of Example 2 after pre-aging treatment is only 291MPa, and the tensile strength is only 551MPa, which is lower than the yield strength (439MPa) and tensile strength (576MPa) of Comparative Example 4 after peak aging treatment. The yield strength of the aluminum alloy of Example 2 after aging forming treatment is increased to 389MPa, and the tensile strength is increased to 563MPa; after natural aging and paint baking treatment, the yield strength is further increased to 482MPa, and the tensile strength is increased to 627MPa.

比較例四的鋁合金在尖峰時效處理後降伏強度達439MPa,且抗拉強度達576MPa,但經過時效成形處 理後,降伏強度降為406MPa,且抗拉強度降為541MPa;再經自然時效及塗漆烘烤處理後,降伏強度回升至466MPa,且抗拉強度回升至572MPa。比較例四的製程為RRA成形製程。 The aluminum alloy of Comparative Example 4 has a yield strength of 439MPa and a tensile strength of 576MPa after peak aging treatment, but after aging forming treatment, the yield strength drops to 406MPa and the tensile strength drops to 541MPa; after natural aging and paint baking treatment, the yield strength rises to 466MPa and the tensile strength rises to 572MPa. The process of Comparative Example 4 is RRA forming process.

比較例五以較高溫的300℃進行時效成形處理後,其降伏強度降至257MPa,且抗拉強度降至418MPa;再經過自然時效及塗漆烘烤處理後,降伏強度回升至279MPa,且抗拉強度回升至503MPa。由此可知,較高溫的時效成形處理無法有效提高鋁合金的強度。 After the comparative example 5 was subjected to aging forming treatment at a relatively high temperature of 300℃, its yield strength dropped to 257MPa, and its tensile strength dropped to 418MPa; after natural aging and paint baking treatment, its yield strength recovered to 279MPa, and its tensile strength recovered to 503MPa. It can be seen that the relatively high temperature aging forming treatment cannot effectively improve the strength of aluminum alloy.

AA7075鋁合金的主要析出強化相為η’相,其尺寸不大於10nm,而粗大的片狀η相(尺寸為10nm以上)須盡量避免生成。然而,根據穿透式電子顯微鏡的檢測結果,實施例二在經過預時效處理後的析出強化相以η’相及GP zone為主,其密度較低且尺寸較小,但GP zone的強化效果較差。在經過時效成形處理後,析出強化相以η’相及η相為主,其密度較高且尺寸略大,雖然仍有GP zone存在,但已可提供較佳的析出強化效果。最後,再經過自然時效及塗漆烘烤後,析出強化相以η’相及η相為主,其密度達到最高,且幾乎沒有GP zone存在,故可使鋁合金具有較高強度。 The main precipitation strengthening phase of AA7075 aluminum alloy is η' phase, whose size is no more than 10nm, and the coarse lamellar η phase (size is more than 10nm) should be avoided as much as possible. However, according to the detection results of transmission electron microscope, the precipitation strengthening phase of Example 2 after pre-aging treatment is mainly η' phase and GP zone, whose density is low and size is small, but the strengthening effect of GP zone is poor. After aging forming treatment, the precipitation strengthening phase is mainly η' phase and η phase, whose density is high and size is slightly larger. Although GP zone still exists, it can provide better precipitation strengthening effect. Finally, after natural aging and paint baking, the precipitated strengthening phases are mainly η’ phase and η phase, and their density reaches the highest, and there is almost no GP zone, so the aluminum alloy can have higher strength.

相較之下,雖然比較例四生成的析出物亦同時包含η’相及η相,但比較例四包含較多粗大的η相,故比較例四的析出強化效果較差。此外,比較例四經過尖峰時效處理後的析出強化相包含η’相、η相及GP zone,其中GP zone的存在代表η’相未充分生成,且GP zone的析出強化效應不如η’相,故比較例四之尖峰時效的析出強化效果略低於實施例二。因此,實施例二的鋁合金強度也確實略高於比較例四,且實施例二以預時效處理取代尖峰時效處理可使此階段的時間縮短約12倍。 In comparison, although the precipitates generated in Example 4 also contain both η' phase and η phase, Example 4 contains more coarse η phase, so the precipitation strengthening effect of Example 4 is poor. In addition, the precipitation strengthening phases of Example 4 after spike aging treatment include η' phase, η phase and GP zone, among which the existence of GP zone means that the η' phase is not fully generated, and the precipitation strengthening effect of GP zone is not as good as that of η' phase, so the precipitation strengthening effect of spike aging in Example 4 is slightly lower than that in Example 2. Therefore, the strength of the aluminum alloy in Example 2 is indeed slightly higher than that in Example 4, and the use of pre-aging treatment instead of spike aging treatment in Example 2 can shorten the time of this stage by about 12 times.

實施例三 Implementation Example 3

實施例三係對固溶熱處理後的AA6016鋁合金進行成形製程,其中AA6111鋁合金的成份包含1.0wt%至1.5wt%的矽、小於0.5wt%的鐵、小於0.2wt%的銅、小於0.2wt%的錳、0.25wt%至0.6wt%的鎂、小於0.1wt%的鉻、小於0.15wt%的鈦及平衡量的鋁。 Embodiment 3 is to perform a forming process on the AA6016 aluminum alloy after solution heat treatment, wherein the composition of the AA6111 aluminum alloy includes 1.0wt% to 1.5wt% silicon, less than 0.5wt% iron, less than 0.2wt% copper, less than 0.2wt% manganese, 0.25wt% to 0.6wt% magnesium, less than 0.1wt% chromium, less than 0.15wt% titanium and a balance of aluminum.

實施例三先對AA6016鋁合金材料進行180℃持溫10分鐘的預時效處理;接著,進行200℃持溫2分鐘的時效成形處理;然後,經過自然時效1周後,再進行185℃持溫20分鐘的塗漆烘烤處理,以製得實施例三的鋁合金。實施例三的鋁合金在製程中各階段的降伏強度、抗拉強度及延伸率係如表三所示。 In Example 3, the AA6016 aluminum alloy material is first subjected to a pre-aging treatment at 180°C for 10 minutes; then, an aging forming treatment is performed at 200°C for 2 minutes; then, after natural aging for 1 week, a paint baking treatment is performed at 185°C for 20 minutes to obtain the aluminum alloy of Example 3. The yield strength, tensile strength and elongation of the aluminum alloy of Example 3 at each stage of the manufacturing process are shown in Table 3.

Figure 112137861-A0305-02-0019-3
Figure 112137861-A0305-02-0019-3

如表三所示,實施例三的鋁合金在進行預時效處理後的降伏強度僅137MPa,且抗拉強度僅為230MPa;接著,經過時效成形處理後的降伏強度提升至161MPa,且抗拉強度提升至246MPa;再經過自然時效及塗漆烘烤處理後,降伏強度進一步提升至216MPa,且抗拉強度提升至279MPa。 As shown in Table 3, the yield strength of the aluminum alloy of Example 3 after pre-aging treatment is only 137MPa, and the tensile strength is only 230MPa; then, after aging forming treatment, the yield strength is increased to 161MPa, and the tensile strength is increased to 246MPa; after natural aging and paint baking treatment, the yield strength is further increased to 216MPa, and the tensile strength is increased to 279MPa.

根據上述實施例,本發明結合預時效處理及時效成形處理,以使鋁合金在成形過程中可持續析出強化相,而使強度逐步上升,且在塗漆烘烤處理後,獲得具有高強度並適用為車用部件的鋁合金。藉此,可在較短的製程時間內,製得具有高強度的鋁合金,故可節省製程成本及能源的耗費。 According to the above-mentioned embodiments, the present invention combines pre-aging treatment and aging forming treatment, so that the aluminum alloy can continuously precipitate strengthening phases during the forming process, so that the strength gradually increases, and after the painting and baking treatment, an aluminum alloy with high strength suitable for automotive parts is obtained. In this way, an aluminum alloy with high strength can be produced in a shorter process time, so the process cost and energy consumption can be saved.

雖然本發明已以數個實施例揭露如上,然其並非用以限定本發明,在本發明所屬技術領域中任何具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 Although the present invention has been disclosed as above with several embodiments, they are not intended to limit the present invention. Anyone with ordinary knowledge in the technical field to which the present invention belongs can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the scope of protection of the present invention shall be subject to the scope of the patent application attached hereto.

100:方法 100:Methods

110,120,130,140:操作 110,120,130,140: Operation

Claims (6)

一種鋁合金的製造方法,包含:提供一鋁合金材料,其中該鋁合金材料為6XXX系鋁合金或7XXX系鋁合金;對該鋁合金材料進行一預時效處理,以獲得一預時效鋁合金,其中該預時效鋁合金之降伏強度為一預時效強度,該預時效處理的溫度與一尖峰時效(T6)處理的溫度相同,且該預時效處理的時間為該尖峰時效(T6)處理的時間的1/48倍至1/12倍;對該預時效鋁合金進行一時效成形處理,以獲得一時效成形鋁合金,其中該時效成形鋁合金之降伏強度為一時效成形強度,且該時效成形強度不小於該預時效強度;以及對該時效成形鋁合金進行一塗漆烘烤處理,以獲得該鋁合金,其中該鋁合金之一降伏強度不小於該時效成形強度。 A method for manufacturing an aluminum alloy comprises: providing an aluminum alloy material, wherein the aluminum alloy material is a 6XXX series aluminum alloy or a 7XXX series aluminum alloy; performing a pre-aging treatment on the aluminum alloy material to obtain a pre-aged aluminum alloy, wherein the yield strength of the pre-aged aluminum alloy is a pre-aging strength, the temperature of the pre-aging treatment is the same as the temperature of a spike aging (T6) treatment, and the time of the pre-aging treatment is the peak aging (T6) treatment. 6) 1/48 to 1/12 of the treatment time; performing an aging forming treatment on the pre-aged aluminum alloy to obtain an aging formed aluminum alloy, wherein the yield strength of the aging formed aluminum alloy is an aging forming strength, and the aging forming strength is not less than the pre-aging strength; and performing a paint baking treatment on the aging formed aluminum alloy to obtain the aluminum alloy, wherein a yield strength of the aluminum alloy is not less than the aging forming strength. 如請求項1所述之鋁合金的製造方法,更包含:對一鋁合金原料進行一固溶熱處理,以獲得該鋁合金材料。 The method for manufacturing the aluminum alloy as described in claim 1 further comprises: performing a solid solution heat treatment on an aluminum alloy raw material to obtain the aluminum alloy material. 如請求項1所述之鋁合金的製造方法,其中該預時效強度低於一尖峰時效強度的90%。 A method for manufacturing an aluminum alloy as described in claim 1, wherein the pre-aging strength is less than 90% of a peak aging strength. 如請求項1所述之鋁合金的製造方法,其中該時效成形處理的一溫度為180℃至280℃。 The method for manufacturing an aluminum alloy as described in claim 1, wherein the temperature of the aging forming treatment is 180°C to 280°C. 如請求項1所述之鋁合金的製造方法,更包含:在進行該塗漆烘烤處理之前,對該時效成形鋁合金進行一自然時效處理,其中該自然時效處理包含在室溫下存放至少一週。 The method for manufacturing the aluminum alloy as described in claim 1 further comprises: before the paint baking treatment, the aged formed aluminum alloy is subjected to a natural aging treatment, wherein the natural aging treatment comprises storage at room temperature for at least one week. 如請求項1所述之鋁合金的製造方法,其中該時效成形鋁合金不進行一時效熱處理。 A method for manufacturing an aluminum alloy as described in claim 1, wherein the aged formed aluminum alloy does not undergo an aging heat treatment.
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CN110088315A (en) * 2016-12-16 2019-08-02 诺维尔里斯公司 It is resistant to the high intensity and high formable aluminium alloy and its manufacturing method of natural aging hardening
CN111705274A (en) * 2020-06-15 2020-09-25 北京科技大学 A kind of processing method of Al-Zn-Mg-(Cu) alloy material

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* Cited by examiner, † Cited by third party
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CN110088315A (en) * 2016-12-16 2019-08-02 诺维尔里斯公司 It is resistant to the high intensity and high formable aluminium alloy and its manufacturing method of natural aging hardening
CN111705274A (en) * 2020-06-15 2020-09-25 北京科技大学 A kind of processing method of Al-Zn-Mg-(Cu) alloy material

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