TWI843651B - Plates for golf club heads - Google Patents
Plates for golf club heads Download PDFInfo
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- TWI843651B TWI843651B TW112135075A TW112135075A TWI843651B TW I843651 B TWI843651 B TW I843651B TW 112135075 A TW112135075 A TW 112135075A TW 112135075 A TW112135075 A TW 112135075A TW I843651 B TWI843651 B TW I843651B
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Abstract
Description
本發明係關於一種合金,尤其是一種用以製造高爾夫球桿頭的合金,及以該合金所製造的高爾夫球桿頭用之板材。 The present invention relates to an alloy, in particular an alloy for manufacturing golf club heads, and a plate material for golf club heads made of the alloy.
鈦合金因兼具良好的強度及韌性,所以被廣泛的用以作為用以製造高爾夫球桿頭的合金,惟,使用者為了追求更佳的打感,擊球力道越來越強,該習知鈦合金所製成的高爾夫球桿頭開始面臨強度不足的題。有鑑於此,習知用以製造高爾夫球桿頭的合金確實仍有加以改善之必要。 Titanium alloys are widely used as alloys for making golf club heads because of their good strength and toughness. However, in order to pursue a better hitting feel, users are hitting the ball with more and more force, and golf club heads made of titanium alloys are beginning to face the problem of insufficient strength. In view of this, it is known that the alloys used to make golf club heads still need to be improved.
為解決上述問題,本發明的目的是提供一種用以製造高爾夫球桿頭的合金,可使該合金所製成高爾夫球桿頭具有較佳強度者。 In order to solve the above problems, the purpose of the present invention is to provide an alloy for manufacturing a golf club head, which can make the golf club head made of the alloy have better strength.
本發明的又一目的是提供一種高爾夫球桿頭用之板材,其所製成的高爾夫球桿頭打擊面板具有較佳打感者。 Another object of the present invention is to provide a plate material for a golf club head, wherein the golf club head striking panel made therefrom has a better hitting feel.
本發明的高爾夫球桿頭用之板材,係以一用以製造高爾夫球桿頭的合金形成,該用以製造高爾夫球桿頭的合金包含:以重量百分比計為6.5~7.5%之鋁、1.6~2%之鐵、0.12~0.16%之矽、0.05~0.4%之硼、0.05%以下且不為0之氮、0.11~0.15%之氧以及平衡量的鈦,該高爾夫球桿頭板材具有大於等於191ksi的抗拉強度、大於等於179ksi的降伏強度以及大於等於 102GPa的楊氏係數。 The plate material for the golf club head of the present invention is formed of an alloy for manufacturing golf club heads, and the alloy for manufacturing golf club heads includes: by weight percentage, 6.5-7.5% aluminum, 1.6-2% iron, 0.12-0.16% silicon, 0.05-0.4% boron, 0.05% or less and not 0 nitrogen, 0.11-0.15% oxygen, and a balance of titanium. The golf club head plate material has a tensile strength of greater than or equal to 191 ksi, a yield strength of greater than or equal to 179 ksi, and a Young's modulus of greater than or equal to 102 GPa.
據此,本發明的用以製造高爾夫球桿頭的合金,藉由提高鐵元素的含量以及添加硼,以使該合金形成特定的組成配比,藉此可以達到提高該爾夫球桿頭合金的強度的功效,該高爾夫球桿頭具有較佳機械強度的功效。 Accordingly, the alloy used to manufacture golf club heads of the present invention increases the iron content and adds boron to form a specific composition ratio of the alloy, thereby achieving the effect of improving the strength of the golf club head alloy, and the golf club head has the effect of better mechanical strength.
其中,該用以製造高爾夫球桿頭的合金包含以重量百分比計為0.05~0.3%之硼。如此,係可以使該用以製造高爾夫球桿頭的合金具有抗拉強度、降伏強度以及適當的塑性的功效。 The alloy used to manufacture the golf club head contains 0.05-0.3% boron by weight. In this way, the alloy used to manufacture the golf club head can have tensile strength, yield strength and appropriate plasticity.
為讓本發明之上述及其他目的、特徵及優點能更明顯易懂,下文特舉本發明之較佳實施例。 In order to make the above and other purposes, features and advantages of the present invention more clearly understood, the following is a preferred embodiment of the present invention.
本發明用以製造高爾夫球桿頭的合金的一較佳實施例,係包含鋁(Al)、鐵(Fe)、矽(Si)、硼(B)、氮(N)、氧(O)以及平衡量的鈦(Ti)。如此,該高爾夫球桿頭合金可以形成一鈦合金,該高爾夫球桿頭合金可成型為高爾夫球桿頭之一桿頭本體或一打擊面板,本發明不予限制。 A preferred embodiment of the alloy used to manufacture golf club heads of the present invention includes aluminum (Al), iron (Fe), silicon (Si), boron (B), nitrogen (N), oxygen (O) and a balanced amount of titanium (Ti). In this way, the golf club head alloy can form a titanium alloy, and the golf club head alloy can be formed into a club head body or a striking panel of a golf club head, which is not limited by the present invention.
具體而言,該合金係包含以重量百分比計為6.5~7.5%之鋁、1.6~2%之鐵、0.12~0.16%之矽、0.05~0.4%之硼、0.05%以下且不為0之氮、0.11~0.15%之氧,以及平衡量的鈦。 Specifically, the alloy contains 6.5-7.5% aluminum, 1.6-2% iron, 0.12-0.16% silicon, 0.05-0.4% boron, 0.05% or less but not 0% nitrogen, 0.11-0.15% oxygen, and the balance of titanium in weight percentage.
進一步來說,鋁金屬可以穩定鈦合金的α相,可以提升高爾夫球桿頭合金製成桿頭的成型率。然而,過高的鋁會導致桿頭的脆化,過低的 鋁又會使得成型率不佳。因此,該合金較佳包含不超過7.5%之鋁,使得該用以製造高爾夫球桿頭的合金製成桿頭時,具有較佳的成型率以及較佳的強度。 Furthermore, aluminum metal can stabilize the α phase of titanium alloy and improve the forming rate of golf club head alloy. However, too much aluminum will cause the embrittlement of the club head, and too little aluminum will result in poor forming rate. Therefore, the alloy preferably contains no more than 7.5% aluminum, so that the alloy used to make golf club heads has a better forming rate and better strength when the club head is made.
另,合金晶體中的原子會因為局部不規則的排列,而造成晶體晶格排列的錯位移動稱為差排滑移(Dislocation),差排滑移被視為合金中的缺陷,係會造成金屬的變形,如果可以避免差排滑移的發生就可以使金屬硬化。而鐵原子可對上述差排滑移形成阻礙,因此,添加鐵可以提升合金的抗拉強度。另,添加矽可以使該合金所形成的桿頭具有預定的強度。 In addition, the atoms in the alloy crystal will cause the dislocation of the crystal lattice arrangement due to the local irregular arrangement, which is called dislocation slip. Dislocation slip is regarded as a defect in the alloy and will cause metal deformation. If dislocation slip can be avoided, the metal can be hardened. Iron atoms can form a barrier to the above dislocation slip, so adding iron can improve the tensile strength of the alloy. In addition, adding silicon can make the club head formed by the alloy have a predetermined strength.
特別注意的是,硼元素能夠有效的細化鈦合金的晶粒,藉此可以使鈦合金具有較佳的成形能力,此外,在鈦合金中添加硼形成的TiB相可以提高鈦合金的強度,惟,過高的TiB相可能會導致鈦合金脆度的上升,即,使該鈦合金的塑性下降,因此,該合金較佳包含不超過0.4%之硼,在另一實施例中,該合金包含0.05~0.3%之硼,如此,可以使該用以製造高爾夫球桿頭的合金具有抗拉強度、降伏強度以及適當的塑性。 It is particularly noted that boron can effectively refine the grains of titanium alloys, thereby making titanium alloys have better forming ability. In addition, the TiB phase formed by adding boron to titanium alloys can improve the strength of titanium alloys. However, too high a TiB phase may lead to an increase in the brittleness of titanium alloys, that is, a decrease in the plasticity of the titanium alloy. Therefore, the alloy preferably contains no more than 0.4% boron. In another embodiment, the alloy contains 0.05-0.3% boron. In this way, the alloy used to manufacture golf club heads can have tensile strength, yield strength and appropriate plasticity.
另,氧為α相的穩定元素,可以提升高爾夫球桿頭合金製成桿頭的成型率外,氧元素可以佔據鈦晶體晶格的間隙位置(Interstitial)。進一步言,合金的強度即為合金的抗變形能力,而合金的差排滑移會造成合金的變形,因此,當氧元素佔據晶格的間隙位置後,可以阻擋差排滑移而使得合金的變形不易發生,而可以達到提升強度的效果。此外,一般在形成合金的過程中,氧元素通常為不可避免的雜質,而僅佔非常微小的量。相較於此,本發明高爾夫球桿頭合金中藉由將氧添加至0.11~0.15%,可使該合金具有較佳的強度。 In addition, oxygen is a stabilizing element of the α phase, which can improve the forming rate of the golf club head alloy. In addition, the oxygen element can occupy the interstitial position of the titanium crystal lattice. Furthermore, the strength of the alloy is the alloy's ability to resist deformation, and the dislocation slip of the alloy will cause the alloy to deform. Therefore, when the oxygen element occupies the interstitial position of the lattice, it can prevent the dislocation slip and make the alloy less likely to deform, thereby achieving the effect of improving the strength. In addition, in the process of forming the alloy, the oxygen element is usually an unavoidable impurity and only occupies a very small amount. In contrast, by adding oxygen to 0.11~0.15% in the golf club head alloy of the present invention, the alloy can have better strength.
為了證實以本發明高用以製造爾夫球桿頭的合金組成確實具有良好的強度,遂測量以第1表所示的習知鈦合金(第1組)以及本發明的鈦合金(第2組)分別製成六個高爾夫球桿頭用之板材,並將各高爾夫球桿 頭用之板材分別經進行600℃時效處理1小時後的機械性質,其結果如第2表所示。 In order to prove that the alloy composition used to manufacture golf club heads of the present invention does have good strength, six golf club head plates were made of the known titanium alloy (Group 1) shown in Table 1 and the titanium alloy of the present invention (Group 2), and the mechanical properties of each golf club head plate were measured after aging treatment at 600℃ for 1 hour. The results are shown in Table 2.
依據上述試驗結果可知,以本發明高爾夫球桿頭合金(第2組)的抗拉強度、降伏強度及楊氏係數,皆高於習知鈦合金(第1組)。再者,相較於習知鈦合金,本發明高爾夫球桿頭合金藉由添加硼以及提高鐵的含量,進而可以提升該合金所製成的高爾夫球桿頭的強度。 According to the above test results, the tensile strength, yield strength and Young's modulus of the golf club head alloy (Group 2) of the present invention are all higher than those of the conventional titanium alloy (Group 1). Furthermore, compared with the conventional titanium alloy, the golf club head alloy of the present invention can enhance the strength of the golf club head made of the alloy by adding boron and increasing the iron content.
綜上所述,本發明的用以製造高爾夫球桿頭的合金,藉由提高鐵元素的含量以及添加硼,以使該合金形成特定的組成配比,藉此可以達到提高該爾夫球桿頭合金的強度的功效。此外,本發明的合金製造的高爾夫球桿頭用之板材,具有較佳的機械性質,係可以使所製成之高爾夫球桿頭打擊面板達到具有良好打感的功效。 In summary, the alloy used to manufacture golf club heads of the present invention increases the iron content and adds boron to form a specific composition ratio of the alloy, thereby achieving the effect of improving the strength of the golf club head alloy. In addition, the plate material used for golf club heads manufactured by the alloy of the present invention has better mechanical properties, which can make the golf club head striking panel have the effect of having a good hitting feel.
雖然本發明已利用上述較佳實施例揭示,然其並非用以限定本發明,任何熟習此技藝者在不脫離本發明之精神和範圍之內,相對上述實施例進行各種更動與修改仍屬本發明所保護之技術範疇,因此本發明之保護範圍當包含後附之申請專利範圍所記載的文義及均等範圍內之所有變更。 Although the present invention has been disclosed using the above preferred embodiments, they are not intended to limit the present invention. Any person skilled in the art may make various changes and modifications to the above embodiments without departing from the spirit and scope of the present invention, and these changes and modifications are still within the technical scope protected by the present invention. Therefore, the protection scope of the present invention shall include all changes within the meaning and equivalent scope recorded in the attached patent application scope.
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| TW112135075A TWI843651B (en) | 2023-09-14 | 2023-09-14 | Plates for golf club heads |
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| TW112135075A TWI843651B (en) | 2023-09-14 | 2023-09-14 | Plates for golf club heads |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101386932A (en) * | 2007-09-14 | 2009-03-18 | 大同特殊钢株式会社 | Low density titanium alloy, golf club head, and process for prouducing low density titanium alloy part |
| TW202100768A (en) * | 2019-06-21 | 2021-01-01 | 大田精密工業股份有限公司 | Titanium alloy casting material and method for preparing the same including aluminum, zirconium, molybdenum, vanadium, iron, boron, silicon, hydrogen, oxygen, nitrogen, carbon, titanium and inevitable impurities |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101386932A (en) * | 2007-09-14 | 2009-03-18 | 大同特殊钢株式会社 | Low density titanium alloy, golf club head, and process for prouducing low density titanium alloy part |
| TW202100768A (en) * | 2019-06-21 | 2021-01-01 | 大田精密工業股份有限公司 | Titanium alloy casting material and method for preparing the same including aluminum, zirconium, molybdenum, vanadium, iron, boron, silicon, hydrogen, oxygen, nitrogen, carbon, titanium and inevitable impurities |
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