TWI738312B - Horizontal cracking vaporization device - Google Patents
Horizontal cracking vaporization device Download PDFInfo
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- TWI738312B TWI738312B TW109114420A TW109114420A TWI738312B TW I738312 B TWI738312 B TW I738312B TW 109114420 A TW109114420 A TW 109114420A TW 109114420 A TW109114420 A TW 109114420A TW I738312 B TWI738312 B TW I738312B
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- 238000005336 cracking Methods 0.000 title claims abstract description 52
- 230000008016 vaporization Effects 0.000 title claims abstract description 32
- 238000009834 vaporization Methods 0.000 title claims abstract description 28
- 238000010438 heat treatment Methods 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 13
- 238000000197 pyrolysis Methods 0.000 claims abstract description 8
- 238000002347 injection Methods 0.000 claims description 8
- 239000007924 injection Substances 0.000 claims description 8
- 239000000779 smoke Substances 0.000 abstract description 6
- 239000002341 toxic gas Substances 0.000 abstract description 6
- 238000001816 cooling Methods 0.000 abstract description 4
- 238000005086 pumping Methods 0.000 abstract 1
- 230000000712 assembly Effects 0.000 description 9
- 238000000429 assembly Methods 0.000 description 9
- 239000002699 waste material Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
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- Processing Of Solid Wastes (AREA)
Abstract
本發明係一種臥式裂解汽化裝置,其係包括有一加熱座以及兩桶體,該兩桶體分別為一第一桶體及一第二桶體,該第一桶體能轉動地設於該加熱座內,該第二桶體與該第一桶體相連接並同步轉動,各該桶體設有至少一螺旋導料片,該至少一螺旋導料片設於該桶體內部,且該兩桶體的螺旋導料片的螺旋方向相同,藉由上述的技術特徵,本發明透過該兩桶體可相互分離,進而區分成用於進行裂解的第一桶體,以及用於降溫、抽除煙塵與有毒氣體的第二桶體,有效改進現有裂解爐容易造成工作環境汙染,以及熱能利用效率不佳的問題,藉以提供一種臥式裂解汽化裝置。The present invention is a horizontal cracking vaporization device, which includes a heating seat and two barrels. The two barrels are respectively a first barrel and a second barrel. The first barrel is rotatably arranged on the heating In the seat, the second barrel body is connected to the first barrel body and rotates synchronously, each barrel body is provided with at least one spiral material guide piece, the at least one spiral material guide piece is arranged inside the barrel body, and the two The spiral direction of the spiral guide piece of the barrel body is the same. With the above technical characteristics, the two barrels can be separated from each other through the present invention, and then divided into the first barrel for pyrolysis, and for cooling and pumping. The second barrel of smoke and toxic gases can effectively improve the existing cracking furnaces that are likely to cause pollution to the working environment and the problem of poor heat utilization efficiency, thereby providing a horizontal cracking and vaporizing device.
Description
本發明涉及一種裂解爐,尤指一種臥式裂解汽化裝置。 The invention relates to a cracking furnace, in particular to a horizontal cracking and vaporizing device.
裂解(pyrolysis)係指有機物質於無氧氣存在下的高溫分解反應,透過有機工業廢料(例如廢塑料)的裂解反應,產生可回收再利用的資源如油氣(合成氣)等。 Pyrolysis refers to the pyrolysis reaction of organic substances in the absence of oxygen. Through the pyrolysis reaction of organic industrial wastes (such as waste plastics), recyclable resources such as oil and gas (syngas) are generated.
現有裂解爐係包括一加熱座以及一裂解桶體,該裂解桶體係結合於該加熱座中,透過該加熱座提供熱能,提高溫度,使容置於該裂解桶體內部的廢料發生裂解反應,然而,由於廢料裂解後會產生煙塵及如戴奧辛等有毒氣體,當裂解反應完成後,工作人員打開所述裂解桶體,會導致煙塵及有毒氣體擴散至工作環境中,此外,使用現有裂解爐完成裂解反應後,工作人員必須等到現有裂解爐初步降溫之後,才能取出該裂解桶體中的固態產物,如焦炭,而重新填入未裂解的廢料後又需重新加熱,使該裂解桶體不能穩定處於高溫狀態,具有浪費熱能的問題。 The existing cracking furnace system includes a heating base and a cracking barrel. The cracking barrel system is integrated in the heating base. The heating base provides heat energy to increase the temperature and cause the waste contained in the cracking barrel to undergo a cracking reaction. However, since the waste material is cracked will produce smoke and toxic gases such as dioxin, when the cracking reaction is completed, the staff opens the cracking barrel, which will cause the smoke and toxic gases to diffuse into the working environment. In addition, the existing cracking furnace is used to complete the process. After the cracking reaction, the staff must wait for the initial cooling of the existing cracking furnace before taking out the solid products in the cracking barrel, such as coke, and re-heating after refilling the uncracked waste, so that the cracking barrel cannot be stabilized Being in a high temperature state has the problem of wasting heat energy.
綜上所述,現有裂解爐具有容易造成工作環境汙染,以及熱能利用效率不佳的問題,因此,現有裂解爐具有需加以改進之處。 In summary, the existing cracking furnace has the problems of easily causing pollution to the working environment and poor heat energy utilization efficiency. Therefore, the existing cracking furnace has areas that need to be improved.
為解決現有裂解爐具有容易造成工作環境汙染,以及熱能利用效率不佳的問題,本發明提供一種臥式裂解汽化裝置,可有效改進上述問題,進一步說明如下。 In order to solve the problems of existing cracking furnaces that easily cause pollution to the working environment and poor heat energy utilization efficiency, the present invention provides a horizontal cracking vaporization device, which can effectively improve the above problems, which are further described as follows.
本發明係一種臥式裂解汽化裝置,其係包括有:一加熱座;以及 兩桶體,分別為一第一桶體及一第二桶體,該第一桶體能轉動地設於該加熱座內,各該桶體設有一閘門組件及至少一螺旋導料片,其中該第一桶體的閘門組件設於該第一桶體的一端,且該端及該閘門組件伸出該加熱座,該兩桶體的閘門組件可拆卸地相連接,使該第二桶體可與該第一桶體相連接並同步轉動,該至少一螺旋導料片設於該桶體內部,且該兩桶體的螺旋導料片的螺旋方向相同;其中各該桶體包括依序連通的一容置段、一漸縮段及一銜接段,其中各桶體的該容置段的內徑大於該銜接段的內徑,該漸縮段連接於該容置段及該銜接段之間,各該桶體包括有複數個所述螺旋導料片以及複數個導料斜片,該複數個螺旋導料片分別固設於該容置段或該銜接段的內側壁上,該複數個導料斜片間隔地固設於該漸縮段的內側壁上。 The present invention is a horizontal cracking vaporization device, which includes: a heating seat; and The two barrels are respectively a first barrel and a second barrel. The first barrel is rotatably arranged in the heating seat. Each barrel is provided with a gate assembly and at least one spiral guide piece, wherein the The gate assembly of the first barrel is arranged at one end of the first barrel, and the end and the gate assembly extend out of the heating seat. The gate assemblies of the two barrels are detachably connected, so that the second barrel can be It is connected to the first barrel and rotates synchronously, the at least one spiral guide piece is arranged inside the barrel, and the spiral directions of the spiral guide pieces of the two barrels are the same; wherein each barrel includes sequential communication An accommodating section, a tapered section and a connecting section of each barrel, wherein the inner diameter of the accommodating section of each barrel is greater than the inner diameter of the connecting section, and the tapered section is connected to the accommodating section and the connecting section In between, each barrel includes a plurality of the spiral material guide pieces and a plurality of material guide oblique pieces, and the plurality of spiral material guide pieces are respectively fixed on the inner side wall of the containing section or the connecting section. A material guide inclined piece is fixedly arranged on the inner side wall of the tapered section at intervals.
進一步,上述臥式裂解汽化裝置,其中各該閘門組件包括有一本體及一閘門,該本體內部與相對應桶體內部相連通,該閘門係能插入該至少一螺旋導料片內部,並隔絕該閘門兩側的空間。 Further, in the above-mentioned horizontal cracking vaporization device, each of the gate components includes a body and a gate, the inside of the body communicates with the inside of the corresponding barrel, and the gate can be inserted into the inside of the at least one spiral guide piece and is isolated The space on both sides of the gate.
進一步,上述臥式裂解汽化裝置,其中各該閘門組件設有複數個閘門組件導料片,各該閘門組件導料片呈螺旋狀地固設於該閘門組件的本體的內側壁上,且各該閘門組件導料片的螺旋方向與所述螺旋導料片的螺旋方向相同。 Further, in the above-mentioned horizontal cracking vaporization device, each of the gate components is provided with a plurality of gate component guide pieces, and each of the gate component guide pieces is helically fixed on the inner side wall of the body of the gate assembly, and each The spiral direction of the guide piece of the gate assembly is the same as the spiral direction of the spiral guide piece.
進一步,上述臥式裂解汽化裝置,其中該加熱座包括有兩輪座組,該兩輪座組間隔地設於該加熱座內,且該第一桶體設於該兩輪座組上,而能在該兩輪座組上轉動。 Further, in the above-mentioned horizontal cracking and vaporization device, the heating seat includes two wheel seat sets, the two wheel seat sets are arranged in the heating seat at intervals, and the first barrel is arranged on the two wheel seat sets, and It can rotate on the two-wheel seat set.
再進一步,上述臥式裂解汽化裝置,其中該臥式裂解汽化裝置還包括有兩輔助輪座組,該兩輔助輪座組間隔地設於地面上,並與該加熱座相間隔,該第二桶體係設於該兩輔助輪座組上,而能在該兩輔助輪座組上轉動。 Still further, the above-mentioned horizontal cracking and vaporization device, wherein the horizontal cracking and vaporization device further includes two auxiliary wheel seat sets, the two auxiliary wheel seat sets are arranged on the ground at intervals and spaced apart from the heating seat, and the second The barrel system is arranged on the two auxiliary wheel seat sets, and can rotate on the two auxiliary wheel seat sets.
較佳的是,上述臥式裂解汽化裝置,其中該第二桶體設有一注料口,該注料口貫穿設於該第二桶體的容置段上。 Preferably, in the above-mentioned horizontal cracking and vaporization device, the second barrel is provided with an injection port, and the injection port penetrates the accommodating section of the second barrel.
較佳的是,上述臥式裂解汽化裝置,其中該第一桶體的兩端均伸出該加熱座,該臥式裂解汽化裝置具有一抽氣管,該抽氣管自該第一桶體遠離該第二桶體的一端伸入該第一桶體,該抽氣管中具有一刮刀,該刮刀伸入該第一桶體中,且該刮刀延伸至靠近該第一桶體內側壁的位置。 Preferably, in the above-mentioned horizontal cracking and vaporization device, both ends of the first barrel body extend out of the heating seat, and the horizontal cracking and vaporization device has an exhaust pipe which is away from the first barrel body. One end of the second barrel extends into the first barrel, and the suction pipe has a scraper, the scraper extends into the first barrel, and the scraper extends to a position close to the inner wall of the first barrel.
較佳的是,上述臥式裂解汽化裝置,其中該臥式裂解汽化裝置包括有複數個所述第二桶體,其中一第二桶體透過其閘門組件與該第一桶體的閘門組件相連接。 Preferably, the above-mentioned horizontal cracking and vaporization device, wherein the horizontal cracking and vaporization device includes a plurality of the second barrels, wherein a second barrel passes through its gate assembly to be in contact with the gate assembly of the first barrel. connect.
藉由上述的技術特徵,本發明透過該兩桶體可相互分離,進而區分成用於進行裂解的第一桶體,以及用於備料、降溫、抽除煙塵與有毒氣體的第二桶體,有效改進現有裂解爐容易造成工作環境汙染,以及熱能利用效率不佳的問題,藉以提供一種臥式裂解汽化裝置。 With the above technical features, the two barrels of the present invention can be separated from each other, and then divided into a first barrel used for cracking, and a second barrel used for material preparation, cooling, and removal of smoke and toxic gases. Effectively improving the existing cracking furnace is likely to cause pollution to the working environment and the problem of poor heat utilization efficiency, thereby providing a horizontal cracking vaporization device.
10:加熱座 10: Heating seat
11:加熱室 11: Heating chamber
12:輪座組 12: Wheel seat set
20:第一桶體 20: The first barrel
30:第二桶體 30: second barrel
201,301:容置段 201,301: containment section
202,302:漸縮段 202,302: tapered segment
203,303:銜接段 203,303: Convergence section
21,31:閘門組件 21, 31: Gate assembly
210,310:本體 210,310: body
211,311:閘門 211,311: Gate
212,312:閘門組件導料片 212,312: Gate assembly guide
22,32:螺旋導料片 22, 32: Spiral guide piece
23,33:導料斜片 23, 33: guide inclined piece
34:注料口 34: Injection port
40:驅動組件 40: drive components
401:鏈條 401: Chain
50:輔助輪座組 50: auxiliary wheel seat group
60:抽氣管 60: Exhaust pipe
61:刮刀 61: Scraper
70:料斗 70: Hopper
圖1係本發明第一較佳實施例局部剖面的外觀側視圖。 Fig. 1 is a partial cross-sectional side view of the external appearance of the first preferred embodiment of the present invention.
圖2係本發明第一較佳實施例局部放大的側視分解圖。 Fig. 2 is a partially enlarged side exploded view of the first preferred embodiment of the present invention.
圖3係本發明第一較佳實施例的操作示意圖。 Fig. 3 is a schematic diagram of the operation of the first preferred embodiment of the present invention.
圖4係本發明第二較佳實施例局部剖面的外觀側視圖。 Fig. 4 is a partial cross-sectional side view of the appearance of the second preferred embodiment of the present invention.
為能詳細瞭解本發明的技術特徵及實用功效,並且能依照說明書的內容來實現,茲進一步以圖式所示的較佳實施例詳細說明如後: In order to understand the technical features and practical effects of the present invention in detail, and to implement it in accordance with the content of the specification, the preferred embodiment shown in the drawings is further described in detail as follows:
本發明係一種臥式裂解汽化裝置,其第一較佳實施例係如圖1至圖3所示,係包括一加熱座10以及兩桶體20、30,其中:
The present invention is a horizontal cracking vaporization device. The first preferred embodiment is shown in Figs. 1 to 3, and includes a
該加熱座10包括有一加熱室11以及兩輪座組12,如圖1所示,該加熱室11形成於該加熱座10內部,該兩輪座組12間隔地設於該加熱室11中。
The
該兩桶體20、30分別為一第一桶體20及一第二桶體30,該第一桶體20係能轉動地設於該加熱座10內;該第二桶體30與該第一桶體20伸出該加熱座10的該至少一端相連接並同步轉動;各該桶體20、30設有一閘門組件21、31及至少一螺旋導料片22、32,其中該第一桶體20的閘門組件21設於該第一桶體20的一端,且該端及該閘門組件21伸出該加熱座10,且該兩桶體20、30的閘門組件21、31可拆卸地相連接,使該第二桶體30與該第一桶體20相連接並同步轉動,且各該閘門組件21、31包括有一本體210、310及一閘門211、311,該本體210、310內部與相對應桶體20、30內部相連通,該閘門211、311可插入該本體210、310內部,並隔絕該閘門211、311兩側的空間,且該兩桶體20、30的螺旋導料片22、32的螺旋方向相同,也就是均為左旋或均為右旋。
The two
在本發明的第一較佳實施例中,該第一桶體20係設於該兩輪座組12上,而能在該兩輪座組12上轉動,該第一桶體20的兩端均伸出該加熱座10,且其中遠離所述閘門組件21的一端與一驅動組件40相連接,該驅動組件40透過至少一鏈條401帶動該第一桶體20轉動;該臥式裂解汽化裝置還包括有兩輔助輪座組50,該兩輔助輪座組50間隔地設於地面上,並與該加熱座10相間隔,該第二桶體30係設於該兩輔助輪座組50上,而能在該兩輔助輪座組50上轉動。
In the first preferred embodiment of the present invention, the
進一步,如圖1及圖2所示,各該桶體20、30包括依序連通的一容置段201、301、一漸縮段202、302及一銜接段302、303,其中各桶體20、30的該容置段201、301的內徑大於該銜接段203、303的內徑,該漸縮段202、302連接於該容置段201、301及該銜接段203、303之間,且各該桶體20、30包括有複數個所述螺旋導料片22、32以及複數個導料斜片23、33,該複數個螺旋導料
片22、32分別固設於該容置段201、301或該銜接段203、303的內側壁上,在本發明的第一較佳實施例中,該容置段201、301及該銜接段203、303的內側壁上分別有四個螺旋導料片22、32;該複數個導料斜片23、33間隔地固設於該漸縮段202、302的內側壁上。
Further, as shown in FIGS. 1 and 2, each of the
較佳的是,在本發明的第一較佳實施例中,如圖2所示,該兩桶體20、30的閘門組件21、31分別設有複數個閘門組件導料片212、312,各該閘門組件導料片212、312呈螺旋狀地固設於該閘門組件21、31的本體210、310的內側壁上,且各該閘門組件導料片212、312的螺旋方向與所述螺旋導料片22、32的螺旋方向相同。
Preferably, in the first preferred embodiment of the present invention, as shown in FIG. 2, the
藉由上述的技術特徵,利用該第二桶體30作為一備料桶,工作人員可先將待裂解廢料填入該第二桶體30,接著透過該兩桶體20、30的閘門組件21、31連接該兩桶體20、30,且各該閘門組件21、31的閘門211、311呈開啟狀態,然後透過該驅動組件40作動,使該兩桶體20、30轉動,所述螺旋導料片22、32及閘門組件導料片212、312即能在該兩桶體20、30轉動過程中,將待裂解廢料經由該兩閘門組件21、31的本體210、310輸送至該第一桶體20的容置段201中,接著關閉所述閘門211、311,並透過該加熱座10對該第一桶體20進行加熱,即可進行裂解反應。
With the above technical features, using the
裂解反應完成後,將所述閘門211、311再次開啟,並透過該驅動組件40驅使該兩桶體20、30反向轉動,則所述螺旋導料片22、32及閘門組件導料片212、312即能在該兩桶體20、30轉動過程中,將裂解後的固態產物經由該兩閘門組件21、31的本體210、310輸送至該第二桶體30的容置段301中,接著關閉所述閘門211、311,並使該兩閘門組件21、31相分離,即可將該第二桶體30分離,並移至他處待該第二桶體30中的溫度降低,以進行後續處理,且能另外透過外部裝置將煙塵及有毒氣體自該第二桶體30中抽出,在此同時,工作
人員可將另一已填入待裂解廢料的第二桶體30與該第一桶體20相連接後,將所述廢料輸送至該第一桶體20中,在該第一桶體20溫度降低之前,進行另一次的裂解反應,藉以提高熱能利用效率。
After the cracking reaction is completed, the
進一步,請參閱如圖2及圖3所示,在本發明的第一較佳實施例中,該第二桶體30進一步設有一注料口34,該注料口34貫穿設於該第二桶體30的容置段301上,在備料的過程中,即該第二桶體30與該第一桶體20連接之前,該注料口34可與一料斗70相連接,方便工作人員將待裂解廢料自該料斗70注入該第二桶體30的容置段301中,完成後將該料斗70分離,再將該第二桶體30透過所設有之閘門組件31與該第一桶體20的閘門組件21相連接,以進行上述輸送作業。
Further, please refer to Figures 2 and 3, in the first preferred embodiment of the present invention, the
進一步,請參閱如圖4所示,在本發明的第二較佳實施例中,該臥式裂解汽化裝置具有一抽氣管60,該抽氣管60自該第一桶體20遠離該第二桶體30的一端伸入該第一桶體20,該抽氣管60抽氣的技術手段及功效為現有技術,故不在此加以詳述,該抽氣管60中具有一刮刀61,該刮刀61伸入該第一桶體20中,且該刮刀61延伸至靠近該第一桶體20內側壁的位置,當該第一桶體20內側壁上形成積碳時,由於積碳具有一厚度,故積碳隨著該第一桶體20轉動的過程中,就會與該刮刀61相抵靠,進而被該刮刀61刮除,而從該第一桶體20的內側壁上剝落;在本發明的第二較佳實施例中,該刮刀61係可由操作人員進入該第一桶體20加以組裝。
Further, please refer to FIG. 4, in the second preferred embodiment of the present invention, the horizontal cracking vaporization device has an
藉由上述的技術特徵,本發明透過該兩桶體20、30可相互分離,進而區分成用於進行裂解的第一桶體20,以及用於備料、降溫、抽除煙塵與有毒氣體的第二桶體30,有效改進現有裂解爐容易造成工作環境汙染,以及熱能利用效率不佳的問題,藉以提供一種臥式裂解汽化裝置。
With the above technical features, the present invention can be separated from each other through the two
以上所述,僅是本發明的較佳實施例,並非對本發明任何形式上的限制,任何所屬技術領域中具有通常知識者,若在不脫離本發明所提技術方案的範圍內,利用本發明所揭示技術內容所作出局部更動或修飾的等效實施例,並且未脫離本發明的技術方案內容,均仍屬本發明的技術方案的範圍內。 The above are only preferred embodiments of the present invention, and do not limit the present invention in any form. Anyone with ordinary knowledge in the relevant technical field can use the present invention without departing from the scope of the technical solution proposed by the present invention. The disclosed technical content has partially changed or modified equivalent embodiments without departing from the technical solution content of the present invention, and all still fall within the scope of the technical solution of the present invention.
10:加熱座 10: Heating seat
11:加熱室 11: Heating chamber
12:輪座組 12: Wheel seat set
20:第一桶體 20: The first barrel
30:第二桶體 30: second barrel
201:容置段 201: Containment Section
202:漸縮段 202: tapered segment
203:銜接段 203: Convergence
21,31:閘門組件 21, 31: Gate assembly
210,310:本體 210,310: body
211,311:閘門 211,311: Gate
22,32:螺旋導料片 22, 32: Spiral guide piece
23,33:導料斜片 23, 33: guide inclined piece
40:驅動組件 40: drive components
401:鏈條 401: Chain
50:輔助輪座組 50: auxiliary wheel seat group
Claims (8)
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| TW109114420A TWI738312B (en) | 2020-04-29 | 2020-04-29 | Horizontal cracking vaporization device |
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| TWI835446B (en) * | 2022-12-02 | 2024-03-11 | 陳宣榮 | Reciprocating smoke tube scraping device |
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| CN108384564A (en) * | 2018-03-16 | 2018-08-10 | 商丘中清环保科技有限公司 | Waste old, plastics low temperature tiny structure cleavage method |
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| CN206545002U (en) * | 2017-03-16 | 2017-10-10 | 任宪君 | A kind of three sections of uninterrupted formula waste plastic oil-refining reactors |
| CN108384564A (en) * | 2018-03-16 | 2018-08-10 | 商丘中清环保科技有限公司 | Waste old, plastics low temperature tiny structure cleavage method |
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