TWI732958B - Electrolyzed water generator - Google Patents
Electrolyzed water generator Download PDFInfo
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- TWI732958B TWI732958B TW106134809A TW106134809A TWI732958B TW I732958 B TWI732958 B TW I732958B TW 106134809 A TW106134809 A TW 106134809A TW 106134809 A TW106134809 A TW 106134809A TW I732958 B TWI732958 B TW I732958B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 172
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 113
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 25
- 239000007787 solid Substances 0.000 claims abstract description 5
- 230000001105 regulatory effect Effects 0.000 claims description 9
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 229920005597 polymer membrane Polymers 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 abstract description 28
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 28
- 230000007935 neutral effect Effects 0.000 abstract description 14
- 230000035622 drinking Effects 0.000 abstract description 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 229920006254 polymer film Polymers 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 35
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 18
- 239000001301 oxygen Substances 0.000 description 18
- 229910052760 oxygen Inorganic materials 0.000 description 18
- 150000002431 hydrogen Chemical class 0.000 description 5
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000008400 supply water Substances 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 230000010365 information processing Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/46115—Electrolytic cell with membranes or diaphragms
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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Abstract
本發明提供一種電解水生成裝置,其能抑制水垢附著的同時,以適於飲用的pH值生成氫溶解濃度高的電解水。電解水生成裝置(1)具備多個用於對水進行電解的電解室(30、40、…)。在各電解室(30、40、…)中配設有:彼此相對配置的第一供電體(31、41、…)及第二供電體(32、42、…);和隔膜(33、43、…),用於將電解室(30、40、…)劃分為第一電極室(30A、40A、…)和第二電極室(30B、40B、…)。隔膜(33)使用固體高分子膜。各電解室(30、40、…)通過使各第一電極室(30A,40A、…)串聯或並聯連通的第一水道(51)和使各第二電極室(30B、40B、…)串聯連通的第二水道(52)來連接。在第二水道(52)的上游側的第二電極室(30B)中生成中性電解水,在下游側的第二電極室(40B)中生成鹼性電解水。 The present invention provides an electrolyzed water generating device, which can suppress the adhesion of scale and at the same time generate electrolyzed water with a high concentration of hydrogen dissolved at a pH value suitable for drinking. The electrolyzed water generator (1) is provided with a plurality of electrolysis chambers (30, 40, ...) for electrolyzing water. Each electrolysis chamber (30, 40, ...) is equipped with: a first power supply body (31, 41, ...) and a second power supply body (32, 42, ...) arranged opposite to each other; and a diaphragm (33, 43) ,...), used to divide the electrolysis chamber (30, 40,...) into a first electrode chamber (30A, 40A,...) and a second electrode chamber (30B, 40B,...). The separator (33) uses a solid polymer film. Each electrolysis chamber (30, 40,...) connects each first electrode chamber (30A, 40A,...) in series or in parallel through a first water channel (51) and each second electrode chamber (30B, 40B,...) in series The connected second water channel (52) is connected. Neutral electrolyzed water is generated in the second electrode chamber (30B) on the upstream side of the second water channel (52), and alkaline electrolyzed water is generated in the second electrode chamber (40B) on the downstream side.
Description
本發明有關於一種通過對水進行電解而生成電解水的電解水生成裝置。 The present invention relates to an electrolyzed water generator that generates electrolyzed water by electrolyzing water.
以往,已知有如下的電解水生成裝置:其具備電解槽,該電解槽具有由隔膜分隔的電解室,該電解水生成裝置通過對供給到電解室中的自來水等進行電解而生成溶解有氫的電解氫水。例如,專利文獻1中公開了如下的電解水生產裝置:其為了提高氫溶解濃度而具備串聯連接的兩個電解槽。
In the past, there has been known an electrolyzed water generator equipped with an electrolytic cell having an electrolytic chamber separated by a diaphragm, and the electrolyzed water generator generates dissolved hydrogen by electrolyzing tap water or the like supplied to the electrolytic chamber. Of electrolyzed hydrogen water. For example,
上述電解水生成裝置具備:第一電解部,相對配置有陰極和陽極;和第二電解部,用於提高生成在第一電解部的陰極側的鹼性水的氫溶解濃度。因此,能夠容易以適於飲用的pH值生成氫溶解濃度高的電解水。 The above-mentioned electrolyzed water generator includes a first electrolysis unit in which a cathode and an anode are opposed to each other, and a second electrolysis unit for increasing the hydrogen dissolved concentration of alkaline water generated on the cathode side of the first electrolysis unit. Therefore, electrolyzed water with a high dissolved hydrogen concentration can be easily produced at a pH suitable for drinking.
專利文獻1:日本專利第4417707號公報 Patent Document 1: Japanese Patent No. 4417707
然而,在專利文獻1所記載的電解水生成裝置中,伴隨水的電解而在第一電解部的陰極室中會析出鈣等水垢。並且,在第一電解部的陰極室中析出的水垢會附著在第一電解部的陰極室下游側的水道上,從而阻礙順暢的水流。即,水垢不僅附著在第二電解部的陰極室上,更附著在用於使第一電解部的陰極室和第二電解部的陰極連通的水道上,從而有可能會阻礙上述鹼性水的順暢流動。
However, in the electrolyzed water generator described in
本發明是鑒於上述情況而提出的,其主要目的在於提供一種電解水生成裝置,其能抑制水垢附著的同時,以適於飲用的pH值生成氫溶解濃度高的電解水。 The present invention is proposed in view of the above circumstances, and its main purpose is to provide an electrolyzed water generator that can suppress the adhesion of scale and generate electrolyzed water with a high concentration of hydrogen dissolved at a pH suitable for drinking.
本發明為具備多個用於對水進行電解的電解室的電解水生成裝置,其特徵在於,在各電解室中配設有:彼此相對配置的第一供電體及第二供電體;和隔膜,用於將電解室劃分為第一供電體側的第一電極室和第二供電體側的第二電極室,各電解室通過使各第一電極室串聯或並聯連通的第一水道和使各第二電極室串聯連通的第二水道來連接,在位於第二水道的上游側的第二電極室中生成中性電解水,在位於第二水道的下游側的第二電極室中生成鹼性電解水。 The present invention is an electrolyzed water generating device provided with a plurality of electrolysis chambers for electrolyzing water, and is characterized in that each electrolysis chamber is provided with: a first power supply body and a second power supply body arranged opposite to each other; and a diaphragm , Used to divide the electrolysis chamber into a first electrode chamber on the side of the first power supply body and a second electrode chamber on the side of the second power supply body. Each second electrode chamber is connected in series with a second water channel to generate neutral electrolyzed water in the second electrode chamber located on the upstream side of the second water channel, and alkali is generated in the second electrode chamber located on the downstream side of the second water channel Electrolyzed water.
在本發明所涉及的電解水生成裝置中,較佳地,各第二電極室內的水流方向相同。 In the electrolyzed water generating device according to the present invention, it is preferable that the direction of water flow in each second electrode chamber is the same.
在本發明所涉及的電解水生成裝置中,較佳地,各電解室沿與水流方向垂直的方向並列設置。 In the electrolyzed water generator according to the present invention, it is preferable that the electrolysis chambers are arranged side by side in a direction perpendicular to the direction of the water flow.
在本發明所涉及的電解水生成裝置中,較佳地,位於第二水道的上游側的電解室由第一電解槽的第一側壁來劃定,第二水道的至少一部分被形成在第一側壁的內部。 In the electrolyzed water generating device according to the present invention, preferably, the electrolysis chamber located on the upstream side of the second water channel is delimited by the first side wall of the first electrolytic tank, and at least a part of the second water channel is formed in the first The inside of the side wall.
在本發明所涉及的電解水生成裝置中,較佳地,第一水道用於使各第一電極室串聯連通,第一水道的至少一部分被形成在第一側壁的內部。 In the electrolyzed water generating device according to the present invention, preferably, the first water channel is used to connect the first electrode chambers in series, and at least a part of the first water channel is formed inside the first side wall.
在本發明所涉及的電解水生成裝置中,較佳地,位於第二水道的下游側的電解室由第二電解槽的第二側壁來劃定,第二水道的至少一部分被形成在第二側壁的內部。 In the electrolyzed water generating device according to the present invention, preferably, the electrolysis chamber located on the downstream side of the second water channel is delimited by the second side wall of the second electrolytic tank, and at least a part of the second water channel is formed in the second The inside of the side wall.
在本發明所涉及的電解水生成裝置中,較佳地,第一水道用於使各第一電極室串聯連通,第一水道的至少一部分被形成在第二側壁的內部。 In the electrolyzed water generating device according to the present invention, preferably, the first water channel is used to connect the first electrode chambers in series, and at least a part of the first water channel is formed inside the second side wall.
在本發明所涉及的電解水生成裝置中,較佳地,被配設在位於第二水道的上游側的電解室中的隔膜為固體高分子膜。 In the electrolyzed water generator according to the present invention, preferably, the diaphragm disposed in the electrolysis chamber located on the upstream side of the second water channel is a solid polymer membrane.
本發明的電解水生成裝置具備多個用於對水進行電解的電解室,在位於第二水道的上游側的第二電極室中生成中性電解水。由於在該上游側的第二電極室中不會產生水垢的析出,因此能夠在上游側的第二電極室和第二水道中抑制水垢的附著。此外,在上游側的第二電極室中生成溶解有因水的電解而產生的氫氣的中性電解水。 The electrolyzed water generator of the present invention includes a plurality of electrolysis chambers for electrolyzing water, and generates neutral electrolyzed water in the second electrode chamber located on the upstream side of the second water channel. Since precipitation of scale does not occur in the second electrode chamber on the upstream side, it is possible to suppress adhesion of scale in the second electrode chamber on the upstream side and the second water channel. In addition, neutral electrolyzed water in which hydrogen gas generated by the electrolysis of water is dissolved is generated in the second electrode chamber on the upstream side.
另一方面,在位於第二水道的下游側的第二電極室中,通過水的電解來提高氫溶解濃度,並且生成還原後的鹼性電解水。伴隨此,雖然在下游側的第二電極室中析出水垢,但該水垢的附著區域被限定在比下游側的第二電極室更靠下游側的水道中,從而也容易採取該水垢的對策。由此,能抑制水垢附著的同時,以適於飲用的pH值生成氫溶解濃度高的電解水。 On the other hand, in the second electrode chamber located on the downstream side of the second water channel, the dissolved hydrogen concentration is increased by the electrolysis of water, and reduced alkaline electrolyzed water is produced. Along with this, although scale precipitates in the second electrode chamber on the downstream side, the adhesion area of the scale is limited to the water channel on the downstream side than the second electrode chamber on the downstream side, and it is easy to take countermeasures against the scale. As a result, while suppressing the adhesion of scales, electrolyzed water with a high dissolved hydrogen concentration can be produced at a pH suitable for drinking.
1、1A:電解水生成裝置 1. 1A: Electrolyzed water generator
20、21、22:供水道 20, 21, 22: water supply channel
23:流量調節閥 23: Flow control valve
3、4:電解槽 3, 4: electrolyzer
30、40:電解室 30, 40: electrolysis room
30A、40A:第一電極室 30A, 40A: the first electrode chamber
30B、40B:第二電極室 30B, 40B: second electrode chamber
31、41:第一供電體 31, 41: the first power supply body
32、42:第二供電體 32, 42: second power supply body
33、43:隔膜 33, 43: Diaphragm
3W:第一側壁 3W: first side wall
4W:第二側壁 4W: second side wall
51:第一水道 51: The First Waterway
51a、51b、51c、51d、52a、52b、52c、52d、53、54:水道 51a, 51b, 51c, 51d, 52a, 52b, 52c, 52d, 53, 54: waterway
52:第二水道 52: Second Waterway
61、62:排水道 61, 62: Drainage channel
63:流道切換閥 63: Runner switching valve
第1圖是表示作為本發明的一實施方式的電解水生成裝置的流道的大致結構的圖。 Fig. 1 is a diagram showing a schematic configuration of a flow path of an electrolyzed water generator as an embodiment of the present invention.
第2圖是表示包括電解槽的第一電極室和第一水道的剖面圖。 Fig. 2 is a cross-sectional view showing a first electrode chamber including an electrolytic cell and a first water channel.
第3圖是表示包括電解槽的第二電極室和第二水道的剖面圖。 Fig. 3 is a cross-sectional view showing a second electrode chamber including an electrolytic cell and a second water channel.
第4圖是表示電解槽和第一水道的變形例的剖面圖。 Fig. 4 is a cross-sectional view showing a modification of the electrolytic cell and the first water channel.
第5圖是表示電解槽和第二水道的變形例的剖面圖。 Fig. 5 is a cross-sectional view showing a modification of the electrolytic cell and the second water channel.
第6圖是表示電解水生成裝置的變形例的流道的大致結構的圖。 Fig. 6 is a diagram showing a schematic configuration of a flow channel of a modification example of the electrolyzed water generator.
下面,基於圖式對本發明的一實施方式進行說明。 Hereinafter, an embodiment of the present invention will be described based on the drawings.
第1圖示出作為本發明的實施方式的電解水生成裝置1的流道的大致結構。電解水生成裝置1例如用於生成家庭飲用水。
Fig. 1 shows a schematic configuration of the flow path of the electrolyzed
電解水生成裝置1具備多個電解槽3、4、…。第1圖中示出具備一對電解槽3、4的電解水生成裝置1。電解水生成裝置1也可以具有三個以上的電解槽3、4、…。
The electrolyzed
電解槽3和電解槽4被串聯連接。電解槽3相對於電解槽4被設置在上游側。
The
電解槽3具有:電解室30,用於對水進行電解;第一供電體31和第二供電體32,被彼此相對配置在電解室30內;和隔膜33,用於將電解室30劃分為第一供電體31側的第一電極室30A和第二供電體32側的第二電極室30B。
The
第一供電體31和第二供電體32中的一個供電體被用作陽極供電體,另一個供電體被用作陰極供電體。通過向電解室30的第一電極室30A和第二電極室30B這兩個供給水,並且對第一供電體31和第二供電體32施加直流電壓,從而在電解室30內產生水的電解。
One of the first
上游側的電解室30的隔膜33使用例如由具有磺酸基的氟樹脂製成的固體高分子膜。在隔膜33的兩面上形成有由鉑製成的鍍層。另一方面,第一供電體31和第二供電體32使用例如在由鈦等製成的膨脹合金等的網狀金屬表面上形成有鉑鍍層的供電體。這種網狀的第一供電體31和第二供電體32能夠夾持隔膜33的同時,使水遍及隔膜33的表面,從而促進電解室30內的電解。
The
隔膜33的鍍層與第一供電體31及第二供電體32抵接並電連接。隔膜33使由電解產生的離子通過。第一供電體31和第二供電體32經由隔膜33電連接。在應用由固體高分子材料製成的隔膜33的電解室30中,電解氫水的pH值不會上升,即,將電解室30內的水保持中性的同時進行電解。
The plating layer of the
通過在電解室30內對水進行電解而產生氫氣和氧氣。例如,在第一供電體31被用作陽極供電體的情況下,在第一電極室30A中產生氧氣,生成溶解有氧氣的中性電解氧水。另一方面,在第二電極室30B中產生氫氣,生成溶解有氫氣的中性電解氫水。在第一供電體31被用作陰極供電體的情況下,在第一電極室30A中產生氫氣,生成溶解有氫氣的中性電解氫水。另一方面,在第二電極室30B中產生氧氣,生成溶解有氧氣的中性電解氧水。
Hydrogen and oxygen are generated by electrolyzing water in the
電解槽4具有:第一供電體41和第二供電體42,被彼此相對配置在用於對水進行電解的電解室40內;和隔膜43,用於將電解室40劃分為第一供電體41側的第一電極室40A和第二供電體42側的第二電極室40B。
The
第一供電體41和第二供電體42中的一個供電體被用作陽極供電體,另一個供電體被用作陰極供電體。通過向電解室40的第一電極室40A和第二電極室40B這兩個供給水,並且對第一供電體41和第二供電體42施加直流電壓,從而在電解室40內產生水的電解。
One of the first
隔膜43例如由聚四氟乙烯(PTFE)親水膜構造。隔著隔膜43相對配置的第一供電體41和第二供電體42使用例如鈦等金屬板。第一供電體41和第二供電體42被配設在由隔膜43隔開的位置上。
The
在上述結構的電解槽4中,隨著電解氫水的pH值上升,即隨著陰極室內的水的鹼性強度升高,發出電解信號。
In the
在第一供電體41被用作陽極供電體的情況下,在第一電極室40A中產生氧氣,生成溶解有氧氣的酸性電解氧水。另一方面,在第二電極室40B中產生氫氣,生成溶解有氫氣的鹼性電解氫水。在第一供電體41被用作陰極供電體的情況下,在第一電極室40A中產生氫氣,生成溶解有氫氣的鹼性電解氫水。另一方面,在第二電極室40B中產生氧氣,生成溶解有氧氣的酸性電解氧水。
In the case where the first
電解水生成裝置1具有:供水道20,用於向電解室30、40供給待電解的水;和排水道61、62,用於從電解室30、40排出電解水。
The electrolyzed
從供水道20向電解水生成裝置1供給原水。雖然通常利用自來水以作為原水,但除此之外可以使用例如井水、地下水等。在電解水生成裝置1被用於生成飲用電解氫水等的情況下,可以在供水道20中適當設置用於淨化原水的淨水盒等。
Raw water is supplied from the
供水道20分支成供水道21和供水道22。供水道21被連接到第一電極室30A的下端部。供水道22被連接到第二電極室30B的下端部。流入到供水道20中的水通過供水道21和22之後,流入到第一電極室30A及第二電極室30B中。
The
排水道61被連接到第一電極室40A的上端部。在第2圖及第4圖所示的電解槽4中,排水道61經由形成在電解槽4的第二側壁4W上的水道53與第一電極室40A連接。由此,從第一電極室40A流出的水流入到排水道61中。
The
排水道62被連接到第二電極室40B的上端部。在第3圖及第5圖所示的電解槽4中,排水道62經由形成在電解槽4的第二側壁4W上的水道54與第二電極室40B連接。由此,從第二電極室40B流出的水流入到排水道62中。
The
向供電體31、32和供電體41、42供應的電解電流通過控制部(未圖示)來控制。控制部對供電體31、32和供電體41、42等各部分的控制進行管理。控制部例如具有CPU(Central Processing Unit,中央處理器)和記憶體等,其中,該CPU執行各種運算處理和資訊處理等,該記憶體存儲用於負責CPU操作的程式和各種資訊。
The electrolysis current supplied to the
控制部例如控制第一供電體31、41和第二供電體32、42的極性。
The control unit controls the polarities of the first
通過對第一供電體31、41和第二供電體32、42的極性進行相互變更,從而能夠從排水道61排出電解氫水或電解氧水中的期望的電解水,並且從排水道62排出不需要的電解水。另外,能夠通過使第一供電體31、41和第二供電體32、42作為陽極供電體或陰極供電體發揮功能的時間均勻化,來抑制電解室30和電解室40內的水垢附著。
By changing the polarities of the first
下面,在沒有預先說明的情況下,對第一供電體31、41被用作陽極供電體的情況進行說明,該說明也同樣適用於第一供電體31、41被用作陰極供電體的情況。
Hereinafter, the case where the first
控制部例如根據預先設定的氫溶解濃度而對施加於供電體31、32和供電體41、42的直流電壓進行回饋控制,以使電解電流成為期望值。例如,在電解電流過大情況下控制部降低上述電壓,在電解電流過小的情況下控制部提高上述電壓。由此,能夠適當控制向供電體31、32和供電體41、42供應的電解電流。
The control unit, for example, performs feedback control on the DC voltages applied to the
電解室30的第一電極室30A和電解室40的第一電極室40A通過第一水道51來串聯連通。另外,電解室30的第二電極室30B和電解室40的第二電
極室40B通過第二水道52來串聯連通。如此,由於通過第二水道52來串聯連通用於生成中性電解水的第二電極室30B和用於生成鹼性電解水的第二電極室40B,因此即使在為了提高氫溶解濃度而增加電解電流的情況下,也能抑制電解水的pH值過度上升。因此,能夠以適於飲用的pH值生成氫溶解濃度高的電解水。
The
此外,在第一供電體31、41被用作陽極供電體的情況下,即在第一電極室30A、40A被用作陽極室的情況下,也可以以通過第一水道51並聯連通的方式來構造第一電極室30A和第一電極室40A。在該情況下,由於在第一電極室30A中生成的氧氣不會流入到第一電極室40A中,因此也能向第一供電體41的表面充分地供給水。因此,能夠在電解室40內有效地進行電解,從而能提高氫溶解濃度。
In addition, in the case where the first
電解室30被配設在第二水道52的上游側,電解室40被配設在第二水道52的下游側。即,用於生成中性電解水的第二電極室30B被配設在第二水道52的上游側,用於生成鹼性電解水的第二電極室40B被配設在第二水道52的下游側。由此,在位於上游側的第二電極室30B中不會產生水垢的析出,從而能夠在第二電極室30B和第二水道52中抑制水垢的附著。此外,在上游側的第二電極室中生成溶解有因水的電解而產生的氫氣的中性電解水。
The
另一方面,在位於第二水道52的下游側的第二電極室40B中,通過水的電解來提高氫溶解濃度,並且生成還原後的鹼性電解水。伴隨此,雖然在下游側的第二電極室中隨電解而析出水垢,但該水垢的附著區域被限定在比第二電極室40B更靠下游側的水道中,從而也容易採取該水垢的對策。例如,通過將比第二電極室40B更靠下游側的水道的截面積設定為較大的面積等,能
夠容易進行水垢對策。因此,能抑制水垢附著的同時,以適於飲用的pH值生成氫溶解濃度高的“電解氫水”。
On the other hand, in the
如箭頭30X、40X所示,各第一電極室30A、40A內的水流方向相同。在本實施方式中,第一電極室30A、40A內的水流方向30X、40X為從第一電極室30A、40A的下端部朝向上端部的鉛直方向。因此,由於第一電極室30A、40A中的水流方向30X、40X與第一電極室30A、40A中生成的氧氣的移動方向一致,因此能夠從第一電極室30A、40A有效地排出氧氣。由此,能抑制第一電極室30A、40A中產生的氧氣滯留在第一供電體31、41的表面上。因此,也能向第一供電體31、41的表面充分地供給水,從而能夠在電解室30、40中有效地進行電解並提高氫溶解濃度。
As indicated by
如箭頭30Y、40Y所示,各第二電極室30B、40B內的水流方向相同。在本實施方式中,第二電極室30B、40B內的水流方向30Y、40Y為從第二電極室30B、40B的下端部朝向上端部的鉛直方向。因此,由於第二電極室30B、40B中的水流方向30Y、40Y與第二電極室30B、40B中生成的氫氣的移動方向一致,因此能夠從第二電極室30B、40B有效地排出氫氣。由此,能抑制第二電極室30B、40B中產生的氫氣滯留在第二供電體32、42的表面上。因此,也能向第二供電體32、42的表面充分地供給水,從而能夠在電解室30、40中有效地進行電解並提高氫溶解濃度。
As indicated by
較佳地,電解室30、40被並列設置在與水流方向30X、40X、30Y、40Y垂直的方向上。在這種方式中,容易控制電解水生成裝置1的高度並實現低高度化。
Preferably, the
第2圖示出劃定出電解室30、40的電解槽(第一電解槽)3和電解槽(第二電解槽)4的剖面。第2圖中示出包括第一電極室30A、40A和第一水道51的剖面。電解槽3和4例如通過樹脂成型而形成。位於第一水道51的上游側的電解室30由電解槽3的第一側壁3W來劃定。第一水道51包括水道51a、51b。水道51a以與第一電極室30A連通的方式被形成在第一側壁3W的內部。即,第一水道51的至少一部分被形成在第一側壁3W的內部。由此,能簡化電解水生成裝置1的結構,並能實現成本降低。水道51b連接水道51a和第一電極室40A。水道51b例如由橡膠製的管等構造,並被配設在電解槽3、4的外側。
FIG. 2 shows the cross section of the electrolytic tank (first electrolytic tank) 3 and the electrolytic tank (second electrolytic tank) 4 that define the
第3圖中示出包括電解槽3和電解槽4的第二電極室30B、40B及第二水道52的剖面。位於第二水道52的上游側的電解室30由電解槽3的第一側壁3W來劃定。第二水道52包括水道52a、52b。水道52a以與第二電極室30B連通的方式被形成在第一側壁3W的內部。即,第二水道52的至少一部分被形成在第一側壁3W的內部。由此,能簡化電解水生成裝置1的結構,並能實現成本降低。水道52b連接水道52a和第二電極室40B。水道52b例如由橡膠製的管等構造,並被配設在電解槽3、4的外側。
FIG. 3 shows the cross section of the
第4圖及第5圖示出第2圖及第3圖所示的電解槽3、4的變形例。第4圖及第5圖所示的電解槽3、4與第2圖及第3圖所示的電解槽3、4的不同點在於,第一水道51和第二水道52的至少一部分被形成在第二側壁4W的內部。
Figures 4 and 5 show modified examples of the
第4圖中示出包括電解槽3和電解槽4的第一電極室30A、40A及第一水道51的剖面。位於第一水道51的下游側的電解室40由電解槽4的第二側壁4W來劃定。第一水道51包括水道51c、51d。水道51c連接第一電極室30A和水道51d。水道51c例如由橡膠製的管等構造,並被配設在電解槽3、4的外側。
水道51d以與第一電極室40A連通的方式被形成在第二側壁4W的內部。即,第一水道51的至少一部分被形成在第二側壁4W的內部。由此,能簡化電解水生成裝置1的結構,並能實現成本降低。
FIG. 4 shows a cross section of the
第5圖中示出包括電解槽3和電解槽4的第二電極室30B、40B及第二水道52的剖面。位於第二水道52的上游側的電解室30由電解槽3的第一側壁3W來劃定。第二水道52包括水道52c、52d。水道52c連接第二電極室30B和水道52d。水道52c例如由橡膠製的管等構造,並被配設在電解槽3、4的外側。水道52d以與第二電極室40B連通的方式被形成在第二側壁4W的內部。即,第二水道52的至少一部分被形成在第二側壁4W的內部。由此,能簡化電解水生成裝置1的結構,並能實現成本降低。
FIG. 5 shows a cross section of the
如第1圖所示,在本實施方式中,較佳地,在供水道21、22的路徑中設置有流量調節閥23。流量調節閥23用於調節流過供水道21、22的水量。通過流量調節閥23來調節流入到第一電解室30A和第二電極室30B中的水量。
As shown in FIG. 1, in this embodiment, it is preferable that a
在本實施方式中,較佳地,在第一電極室40A及第二電極室40B與排水道61、62之間設置有流道切換閥63。流道切換閥63選擇性地切換第一電極室40A及第二電極室40B與排水道61、62之間的連接。
In this embodiment, preferably, a flow
通過使第一供電體31、41及第二供電體32、42的極性切換和利用流道切換閥63的流道切換同步進行,從而能夠從一個排水道(例如,排水道62)不斷排出用戶選擇的電解水(第1圖中為電解氫水)。
By synchronizing the polarity switching of the first
當切換第一供電體31、41及第二供電體32、42的極性時,較佳地,由控制部使流量調節閥23和流道切換閥63連動操作的形式。由此,能夠在極性的切換前後充分確保向連接到排水道62的電極室供給的水供給量的同時,
控制向連接到排水道61的電極室供給的水供給量,從而有效地利用水。例如,如日本專利第5809208號公報中記載的那樣,較佳地,流量調節閥23和流道切換閥63為被一體形成且由單向電動機連動驅動的形式。即,流量調節閥23和流道切換閥63由圓筒狀的外筒體和內筒體等構造。在內筒體的內側及外側形成有構造流量調節閥23和流道切換閥63的流道,並且各流道被構造為與流量調節閥23和流道切換閥63的操作狀態相應地適當交叉。這種閥裝置被稱為“雙自動切換交叉水道閥(弁)”,其有助於簡化電解水生成裝置1的結構和控制,並且進一步提高電解水生成裝置1的商品價值。關於該電解水生成裝置1,如第2圖至第5圖所示,通過在電解槽3的第一側壁3W和電解槽4的第二側壁4W上設置水道53、54,能夠將流量調節閥23和流道切換閥63相鄰配置在電解槽3和電解槽4的下方,從而能夠進一步簡化電解水生成裝置1的結構。
When the polarities of the first
第6圖示出作為電解水生成裝置1的變形例的電解水生成裝置1A。電解水生成裝置1A與電解水生成裝置1的不同點在於,沿水流方向30X、40X、30Y、40Y即鉛直方向排列配設有電解室30、40。電解水生成裝置1A中的以下未說明的結構與電解水生成裝置1相同。
FIG. 6 shows an electrolyzed
由於在電解水生成裝置1A中沿鉛直方向排列配設有電解室30、40,因此能控制電解水生成裝置1A的接地面積,從而能提高電解水生成裝置1A在狹小的廚房等中的設置自由度。
Since the
以上,雖然對本發明的實施方式進行了詳細說明,但本發明不限定於上述的具體實施方式,可以變更為多種方式來實施。即,電解水生成裝置1至少具備多個用於對水進行電解的電解室30、40、…,在各電解室30、
40、…中配設有:彼此相對配置的第一供電體31、41、…及第二供電體32、42、…;以及隔膜33、43、…,用於將電解室30、40、…劃分為第一供電體31、41、…側的第一電極室30A、40A和第二供電體32、42、…側的第二電極室30B、40B、…,各電解室30、40通過使各第一電極室30A、40A、…串聯或並聯連通的第一水道51和使各第二電極室30B、40B串聯連通的第二水道52來連接,在位於第二水道52的上游側的第二電極室30B中生成中性電解水、在位於第二水道52的下游側的第二電極室40B中生成鹼性電解水。
As mentioned above, although the embodiments of the present invention have been described in detail, the present invention is not limited to the specific embodiments described above, and can be implemented in a variety of ways. That is, the electrolyzed
此外,在電解水生成裝置1包括三個以上的電解室的情況下,對最上游側的電解室應用電解室30,對最下游側的電解室應用電解室40。能夠對被配設在最上游側的電解室與最下游側的電解室之間的電解室應用與電解室30或電解室40相同的結構。在該情況下,較佳地,以生成中性電解水的電解室30不會位於生成鹼性電解水的電解室40的下游側的方式配置各電解室。
In addition, when the electrolyzed
1:電解水生成裝置 1: Electrolyzed water generator
20、21、22:供水道 20, 21, 22: water supply channel
23:流量調節閥 23: Flow control valve
3、4:電解槽 3, 4: electrolyzer
30、40:電解室 30, 40: electrolysis room
30A、40A:第一電極室 30A, 40A: the first electrode chamber
30B、40B:第二電極室 30B, 40B: second electrode chamber
31、41:第一供電體 31, 41: the first power supply body
32、42:第二供電體 32, 42: second power supply body
33、43:隔膜 33, 43: Diaphragm
51:第一水道 51: The First Waterway
52:第二水道 52: Second Waterway
61、62:排水道 61, 62: Drainage channel
63:流道切換閥 63: Runner switching valve
Claims (8)
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| JP2016-200973 | 2016-10-12 | ||
| JP2016200973A JP6825871B2 (en) | 2016-10-12 | 2016-10-12 | Electrolyzed water generator |
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| TW201813931A TW201813931A (en) | 2018-04-16 |
| TWI732958B true TWI732958B (en) | 2021-07-11 |
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| KR (1) | KR102475480B1 (en) |
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| JP6577973B2 (en) * | 2017-04-26 | 2019-09-18 | 株式会社日本トリム | Electrolyzed water generator |
| JP6968128B2 (en) * | 2019-07-18 | 2021-11-17 | 株式会社日本トリム | Valve device and electrolyzed water generator |
| JP7407369B2 (en) * | 2020-06-26 | 2024-01-04 | パナソニックIpマネジメント株式会社 | Electrolyzed water generator and cleaning method for electrolyzed water generator |
| JP7261260B2 (en) * | 2021-04-01 | 2023-04-19 | 株式会社日本トリム | electrolytic cell |
| JP6984061B1 (en) * | 2021-05-27 | 2021-12-17 | 株式会社日本トリム | Electrolyzed water generator |
| KR102805551B1 (en) * | 2022-07-25 | 2025-05-13 | (주) 테크윈 | Wastewater treatment apparatus producing oxidizing agent and treating organic pollutants and wastewater treatment method using the same |
| KR20250051399A (en) | 2023-10-10 | 2025-04-17 | 주식회사 하이놀시스템 | Electrolyzed water generation device and control method |
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| TW201625489A (en) * | 2015-01-07 | 2016-07-16 | Nihon Trim Co Ltd | Electrolytic water generator |
| TW201632469A (en) * | 2015-03-06 | 2016-09-16 | Nihon Trim Co Ltd | Electrolytic water generating apparatus |
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| JP4417707B2 (en) | 2003-07-08 | 2010-02-17 | 九州日立マクセル株式会社 | Water conditioner |
| CN101624227B (en) * | 2009-06-16 | 2011-06-08 | 杨国锋 | Flow-type electrolyzed water manufacturing device |
| CN102917984B (en) * | 2011-04-27 | 2014-09-10 | 日本多宁股份有限公司 | Electrolyzed water generator |
| CN104418409A (en) * | 2013-08-27 | 2015-03-18 | 天津日望环境技术有限公司 | Strongly-alkaline (acidic) electrolytic water generation device |
| JP5639724B1 (en) * | 2014-03-17 | 2014-12-10 | 株式会社日本トリム | ELECTROLYTIC WATER GENERATING DEVICE AND MANUFACTURING METHOD THEREOF |
| JP6412447B2 (en) * | 2015-03-09 | 2018-10-24 | 株式会社日本トリム | Electrolyzed water generator |
| JP6169762B1 (en) * | 2016-08-02 | 2017-07-26 | MiZ株式会社 | Hydrogen water generation method |
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| TW201632469A (en) * | 2015-03-06 | 2016-09-16 | Nihon Trim Co Ltd | Electrolytic water generating apparatus |
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| KR20190058464A (en) | 2019-05-29 |
| JP6825871B2 (en) | 2021-02-03 |
| WO2018070230A1 (en) | 2018-04-19 |
| JP2018061929A (en) | 2018-04-19 |
| KR102475480B1 (en) | 2022-12-07 |
| CN109661375A (en) | 2019-04-19 |
| TW201813931A (en) | 2018-04-16 |
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