TWI707697B - Use of combination of volatile silicone oil, ethanol, silicone resin, and non-volatile silicone oil in manufacturing composition for shortening drying time and improving softness of hair - Google Patents

Abstract

Disclosed is a composition for drying hair including volatile silicone oil, ethanol, a silicone resin and non-volatile silicone oil. The hair composition interrupts hydrogen bonding between the hair surface and water through hair coating and thus is effective for shortening hair drying time. In addition, when using the composition for drying hair according to an embodiment of the present disclosure repeatedly, the hair is waterproof-coated, which provides an excellent effect of shortening hair drying time. Further, the composition for drying hair is effective for enhancing hair softness and gloss, and thus is useful for hair tidying or hair styling.

Description

The group is prepared with volatile silicone oil, ethanol, silicone resin and non-volatile silicone oil The finished product is used to shorten the drying time and improve the softness of the hair

This manual is about a composition used to shorten hair drying time and improve hair softness.

The reference of the present invention is Korean Patent KR2001-0112154 A.

Generally speaking, hair care products such as shampoo, rinse and treatment are used to remove contaminants from the scalp and hair and maintain clean and beautiful hair. In addition to its use for cleaning purposes, it has been used for other purposes such as easy combing, softness, smoothness, gloss, reduction of hair surface friction, anti-static treatment, and hair protection.

However, if the hair is not dried immediately after using the hair care products, the moisture remaining on the scalp and hair may cause itching, keratosis or inflammation of the scalp. At the same time, the hair dryer, which is often used to dry hair, is inconvenient to use, and sometimes the scalp and hair are damaged by strong hot air. In this case, it is necessary to study a composition that can shorten the hair drying time.

One of the technical problems that this manual intends to solve is to shorten the hair drying time.

Another technical problem to be solved by this manual is to improve the softness and gloss of hair.

Another technical problem to be solved by this manual is to provide a composition for shortening the hair drying time while improving the softness and gloss of the hair.

In a common aspect, a composition for drying hair is provided, which includes volatile silicone oil, ethanol, and silicone resin.

The composition of the specific embodiment of the present specification breaks the hydrogen bond between the hair surface and the water through the hair coating, so it can effectively shorten the hair drying time. Moreover, when the hair composition of the specific embodiment of this specification is repeatedly used to dry the hair, the hair is coated with a waterproof coating, which can provide an excellent effect of shortening the drying time of the hair. In addition, the composition used in the specific embodiments of this specification for drying hair can effectively improve the softness and gloss of the hair, and therefore is useful for hair finishing or hair styling.

Figure 1 is a graph illustrating the effect of reducing the hair drying time when the composition is repeatedly used to dry the hair.

Figure 2 is a diagram illustrating the increase in softness of hair when the composition is repeatedly used to dry the hair.

Exemplary specific embodiments will now be described more fully below.

In one aspect, a composition for drying hair is provided, which contains volatile silicone oil, ethanol, and silicone resin.

In another aspect, a method for drying individual hair is provided, which comprises: applying an effective amount of a composition comprising volatile silicone oil, ethanol, and silicone resin that are effective ingredients for the hair.

In yet another aspect, the use of a composition for drying hair is provided, which includes volatile silicone oil, ethanol, and silicone resin as active ingredients.

In yet another aspect, the use of volatile silicone oil, ethanol and silicone resin for preparing a composition for drying hair is provided.

In yet another aspect, a method for improving the gloss, water resistance, or softness of the main hair is provided, which includes: applying an effective amount of a composition, which includes volatile silicone oil and ethanol that are effective ingredients for the hair And silicone.

In yet another aspect, the use of a composition containing volatile silicone oil, ethanol, and silicone resin as effective ingredients for improving the gloss, water resistance, or softness of hair is provided.

In yet another aspect, volatile silicone oil, ethanol, and silicone resin are provided for the purpose of preparing a composition for improving the gloss, water resistance, or softness of hair.

As in a specific embodiment, the composition may further include non-volatile silicone oil.

As in another specific embodiment, the volatile silicone oil is not particularly limited except for its volatility. The volatile silicone oil may be at least one of chain polysiloxane oil and cyclic polysiloxane oil, but is not limited thereto. Here, the particular embodiment of the chain polysiloxane may include methyl polysiloxane and ethyl siloxane, and the cyclic polysiloxane may include phenyl polysiloxane, methyl Phenyl polysiloxane and methyl cyclosiloxane, especially cyclopentasiloxane or cyclohexasiloxane, but not limited thereto. Moreover, in this article, the silicone resin is a thermoplastic synthetic resin formed from organic derivatives of polymerized silicones, which may have a silicone bond (Si-O bond), in which silicon and oxygen can alternate with each other and may be separated for Q-resin and T-resin. Specific embodiments of the silicone resin may include trimethyl siloxysilicate, phenylpropyl dimethyl siloxysilicate, polyphenyl silsesquioxane, or Polypropylsilsesquioxane (polypropylsilsesquioxane). Moreover, the non-volatile silicone oil is not particularly limited except that it is non-volatile. The non-volatile silicone oil may be selected from at least one of the following groups: polydimethyl siloxane, dimethicone, cyclomethicone ), dimethiconol (dimethiconol), dimethiconcopolyol (dimethiconcopolyol) and silicone elastomer (elastomer), but not limited thereto. Preferably, the non-volatile oil may be dimethicone, but it is not limited thereto. The non-volatile silicone oil (such as dimethylpolysiloxane) may have a viscosity of 0.1% (cs) to 400cs. In particular, it may have the following viscosity: at least 0.1cs, at least 0.15cs, at least 0.2cs, at least 0.25cs, at least 0.3cs, at least 0.35cs, at least 0.4cs, at least 0.45cs, at least 0.5cs, at least 0.55cs , At least 0.6cs, at least 0.65cs, at least 0.7cs, at least 0.8cs, at least 0.9cs, at least 1.0cs, at least 10cs, at least 50cs, at least 90cs, at least 130cs, at least 170cs, at least 210cs, at least 250cs, at least 290cs, at least 310cs, at least 345cs, at least 350cs, at least 355cs, at least 375cs, at least 385cs, at least 395cs or at least 400cs, and at most 400cs, at most 380cs, at most 360cs, at most 355cs, at most 350cs, at most 345cs, at most 320cs, at most 295cs, at most 270cs , At most 225cs, at most 180cs, at most 135cs, at most 90cs, at most 45cs, at most 11cs, at most 5cs, at most 5cs, at most 1cs, at most 0.7cs, at most 0.6cs, at most 0.5cs, at most 0.4cs, at most 0.3cs, at most 0.2 cs, or at most 0.1 cs, but not limited to this. For example, in the composition for drying hair in a specific embodiment, dimethylpolysiloxane may have 0.65 The viscosity of cs or 350cs. In this case, the dimethylpolysiloxane with a viscosity of 0.65cs may be used alone or in combination with a dimethylsiloxane with a viscosity of 350cs.

As another specific embodiment, the composition for drying hair may further comprise selected from the group consisting of dimethylsiloxane alcohol, polyisobutylene, isododecane, C12-C15 alkylbenzoate and At least one of the group consisting of coco-caprylate/caprate. Moreover, the composition herein may contain the volatile oil in an amount of 20-90 wt% based on the total weight of the composition. In particular, the composition may contain the volatile oil in the following amounts: at least 10wt%, at least 15wt%, at least 19wt%, at least 20wt%, at least 25wt%, at least 30wt%, at least 35wt%, at least 40wt%, at least 45wt %, at least 50wt%, at least 55wt%, at least 60wt%, at least 65wt%, at least 70wt%, at least 75wt%, at least 80wt%, at least 85% or at least 90wt%, and up to 90wt%, up to 89wt%, up to 85wt% , Up to 80wt%, up to 79wt%, up to 74wt%, up to 69wt%, up to 64wt%, up to 59wt%, up to 54wt%, up to 49wt%, up to 44wt%, up to 39wt%, up to 34wt%, up to 29wt%, up to 24wt%, at most 21wt%, at most 20wt%, or at most 19wt%, but not limited thereto.

As still another specific embodiment, the composition may include cyclohexasiloxane and cyclopentasiloxane as non-volatile silicone oils. The composition may contain 100-250 parts by weight of cyclopentasiloxane based on 100 parts by weight of cyclohexasiloxane. For example, cyclopentasiloxane may be present in the following amounts based on 100 parts by weight of cyclohexasiloxane: at least 100 parts by weight, at least 130 parts by weight, at least 150 parts by weight, at least 170 parts by weight, at least 190 parts by weight , At least 210 parts by weight, at least 230 parts by weight, at least 240 parts by weight or at least 250 parts by weight, and at most 250 parts by weight, at most 240 parts by weight The amount is at most 220 parts by weight, at most 200 parts by weight, at most 180 parts by weight, at most 160 parts by weight, at most 140 parts by weight, at most 120 parts by weight, at most 110 parts by weight or at most 100 parts by weight.

As yet another specific embodiment, the composition may include 10-50 wt% ethanol based on the total weight of the composition. In particular, the composition may contain ethanol in the following amounts: at least 10wt%, at least 15wt%, at least 20wt%, at least 25wt%, at least 30wt%, at least 35wt%, at least 40wt%, at least 45wt% or at least 50wt%, and to At most 50wt%, at most 46wt%, at most 41wt%, at most 36wt%, at most 31wt%, at most 26wt%, at most 21wt%, at most 16wt%, at most 11wt% or at most 10wt%.

As yet another specific embodiment, the composition may include 0.2-10 wt% of the silicone resin based on the total weight of the composition. In particular, the composition may contain the silicone resin in the following amounts: at least 0.1wt%, at least 0.2wt%, at least 1wt%, at least 1.1wt%, at least 1.2wt%, at least 1.3wt%, at least 1.4wt%, at least 1.5wt%, at least 1.6wt%, at least 1.7wt%, at least 1.8wt%, at least 1.9wt%, at least 2.0wt%, at least 2.1wt%, at least 2.2wt%, at least 2.3wt%, at least 2.5wt%, at least 2.7wt%, at least 3.0wt%, at least 5.0wt%, at least 7.0wt%, at least 9.0wt% or at least 10.0wt%, and at most 10.0wt%, at most 9wt%, at most 8.0wt%, at most 6.0wt%, at most 4.0wt%, at most 3.0wt%, at most 2.9wt%, at most 2.8wt, at most 2.6wt%, at most 2.5wt%, at most 2.4wt%, at most 2.3wt%, at most 2.2wt%, at most 2.1wt%, at most 2.0 wt%, at most 1.9wt%, at most 1.8wt%, at most 1.7wt%, at most 1.5wt%, at most 1.3wt%, at most 1.1wt%, at most 1.0wt%, at most 0.5wt%, at most 0.3wt% or at most 0.1 wt%.

As still another specific embodiment, the composition for drying hair may contain 5-15 wt% of the non-volatile silicone oil based on the total weight of the composition. For example, it is used to dry hair The composition may contain the non-volatile silicone oil in the following amounts: at least 5wt%, at least 6wt%, at least 7wt%, at least 8wt%, at least 9wt%, at least 10wt%, at least 11wt%, at least 12wt%, at least 13wt%, at least 14wt % Or at least 15wt% and at most 15wt%, at most 14wt%, at most 13wt%, at most 12wt%, at most 11wt%, at most 10wt%, at most 9wt%, at most 8wt%, at most 7wt%, at most 6wt% or at most 5wt%, But it is not limited to this.

As another specific embodiment, the composition for drying hair may improve the hair drying speed. For example, the hair drying time may be reduced by at least 15% compared to the hair drying time before the composition is applied to the hair.

In this article, as yet another specific embodiment, the composition for drying hair may include at least one selected from the group consisting of the purpose of improving the glossiness of the hair, improving the water resistance of the hair, and improving the softness of the hair .

When the composition is repeatedly applied, a coating film is formed on the surface of the hair to enhance the waterproof effect, thereby further shortening the hair drying time.

Herein, as yet another specific embodiment, the composition for drying hair may have an anhydrous formula, such as a mist formula.

As still another specific embodiment, the composition may be a cosmetic composition. For example, the cosmetic composition may be formulated into a solution (solution), suspension (suspension), emulsion (emulsion), paste (paste), gel (gel), cream (cream), lotion (lotion), Powder (powder), soap (soap), surfactant-containing cleanser, oil (oil), powder foundation (powder foundation), emulsified foundation (emulsified foundation), wax foundation (wax foundation) ), leave-on type formulation, mist or spray, but not limited to this. More specifically, the cosmetics group The finished product may be formulated into: cleaning agents, such as shampoo, conditioner or body cleanser; hair finishing agents, such as tonic, gel or moose; Hair cosmetic composition, such as hair nourishing water, hair essence, hair serum, scalp treatment, hair treatment, Hair conditioner (hair conditioner), shampoo (hair shampoo), hair lotion (hair lotion), hair growing agent (hair growing agent) or hair dyeing agent (hair dyeing agent); base cosmetic agent, Such as oil-in-water (O/W) or water-in-oil (W/O) cosmetics. In addition to the above basic ingredients, the composition may further include other ingredients appropriately selected by those skilled in the art based on special uses or the types of other ingredients. For example, the composition may further include UV protection agents, hair conditioning agents, fragrances, and the like.

The cosmetic composition may include a cosmetically acceptable medium or base. Therefore, the composition may be provided in any formulation suitable for topical application, such as solutions, gels, solid or non-aqueous slurry products, emulsions, suspensions, microemulsions, microcapsules dispersed in an aqueous phase, and oil-containing phases. (microcapsules), particles (microgranules) or ionic (liposomes) and/or non-ionic vesicle dispersant, or cream, skin toner, skin refiner, Skin balancer, softener, water lotion, skin hydrator, lotion, powder, ointment, spray or concealer stick The form. The composition may be obtained by conventional methods.

When the formulation is a solution or emulsion, it may contain solvents, solubilizers or emulsifiers as carrier components, and its specific examples include water, ethanol, isopropanol, ethyl carbonate, ethyl acetate Ester, benzyl alcohol, benzyl benzoate, propylene glycol, 1,3-butanediol oil, glycerol aliphatic ester, polyethylene glycol or sorbitan fatty acid ester.

When the formulation is a suspension, it may contain the following as carrier ingredients: liquid diluent, such as water, ethanol or propylene glycol; suspending agent, such as ethoxylated isosteary alcohol, polyoxyethylene sorbitol Ester (polyoxyethylene sorbitol ester) and polyoxyethylene sorbitan ester (polyoxyethylene sorbitan ester); microcrystalline cellulose (microcrystalline cellulose); aluminum metahydroxide (aluminum metahydroxide), bentonite (bentonite), agar (agar) or Tragacanth (tragacanth).

When the formula is an ointment, cream or gel, it may contain the following as carrier ingredients: animal oil, vegetable oil, wax, paraffin, starch, tragacanth, cellulose derivatives, polyethylene glycol, silicone, bentonite , Silicon dioxide, talc or zinc oxide.

When the formula is a powder or spray, it may contain the following as carrier ingredients: lactose, talc, silica, aluminum hydroxide, calcium silicate or polyamide powder. In particular, in the case of a spray, the formulation may further contain a propellant, such as chlorofluorohydrocarbon, propane/butane or dimethyl ether.

As in a specific embodiment, the cosmetic composition may further include a thickening agent. The thickener used in the cosmetic composition of a specific embodiment may include methyl cellulose, carboxymethyl cellulose, carboxymethyl hydroxyguanine, hydroxymethyl cellulose, hydroxyethyl cellulose, and carboxyvinyl. Base polymer, polyquaternium, cetearyl alcohol, stearic acid, carrageenan, etc. Preferably, at least one selected from the group consisting of carboxymethyl cellulose, carboxyvinyl polymer and polyquaternary ammonium salt may be used, and carboxyvinyl polymer is the best.

As another specific embodiment, if necessary, the cosmetic composition may further include suitable bases and additives, and the types and quantities of these ingredients may be easily selected by those skilled in the art. If necessary, acceptable additives can be incorporated. For example, the cosmetic composition may further include a preservative, pigment or additives conventionally used in this field.

The preservative may be exemplified by phenoxyethanol or 1,2-hexanediol, and the fragrance may be exemplified by artificial fragrance.

As still another specific embodiment, the cosmetic composition may include a compound selected from water-soluble vitamins, oil-soluble vitamins, polypeptides, polysaccharides, sphingolipids, and seaweed extracts. In addition to these, other ingredients that may be used in combination with the cosmetic composition may include oils and fats, moisturizers, lubricants, surfactants, organic and inorganic pigments, organic powders, UV absorbers, preservatives, sterilants, antiseptics Oxidants, plant extracts, pH adjusters, ethanol, pigments, fragrances, blood flow stimulants, coolants, antiperspirants, purified water, etc.

The other ingredients that may be used in combination with the cosmetic composition are not limited to the above. Any ingredient can be used without departing from the purpose and effect of this manual.

In yet another aspect, a method for quickly drying hair is provided, which comprises applying the composition for drying hair to the hair.

As a specific embodiment, the method for quickly drying hair may include applying the composition to the hair after cleaning the hair. As another embodiment, the method for quickly drying hair may include drying the hair after applying the composition to the hair. For example, it is possible to dry the hair by using a dryer.

This embodiment and a test example will now be described. The following examples and test examples are for illustrative purposes and are not intended to limit the scope of this specification.

[Example 1] Preparation of a composition that shortens the hair drying time and a comparative composition

As shown in Table 1 below, the composition systems of Examples 1-6 and Comparative Examples 1 and 2 were prepared. The raw materials are dispersed and introduced in the order shown below, and are stirred after each raw material is introduced until a homogeneous phase is obtained. Examples 1 and 6 are non-water mist formulations, Comparative Example 1 is an essence formulation containing a large amount of high-viscosity non-volatile silicone oil, and Comparative Example 2 is a two-layer oil mist formulation containing oil and water.

[Test Example 1] Measuring the effect of shortening the hair drying time

The test to determine the effect of shortening the hair drying time is performed as follows.

First, clean 3g of hair tresses with 2g deep cleansing and balancing shampoo from Amos Professional Co., Ltd. (trade name natural black hair from Phoenix Korea Co., Ltd.). Then, wipe the cleaned hair tress with WipeAll (simulating drying with a towel), as shown in Table 1, each of the compositions of Examples 1-6 and Comparative Examples 1 and 2 was applied to the Hair band. After that, a blow dryer was used to measure the time for the hair to completely dry (drying temperature: 50-70°C). The process of cleaning with shampoo, applying each composition and drying with a hair dryer was repeated five times. The results are shown in Table 2 below.

As can be seen in Table 2, compared to the water-containing formulation of Comparative Example 2, the anhydrous formulations of Examples 1-6 show a shorter hair drying time. When comparing Examples 1-6 with Comparative Example 1, the use of high-content high-viscosity silicone oil showed a long hair drying time. Moreover, when the composition is repeatedly applied five times, the hair drying time is further shortened (Figure 1).

[Test Example 2] Measuring the effect of improving the softness of hair

First, clean 3g of hair tresses with 2g deep cleansing and balancing shampoo from Amos Professional Co., Ltd. (trade name natural black hair from Phoenix Korea Co., Ltd.). Then, wipe the cleaned hair tress with WipeAll (simulating drying with a towel), as shown in Table 1, each of the compositions of Examples 1-6 and Comparative Examples 1 and 2 was applied to the Hair band. Then, use a hair dryer to completely dry the hair, and measure the strength when physically loosening the tangled hair by using a tensile strength measuring system. When the pulling force at both ends of the pulled hair increases, the tensile strength of the hair is measured until the hair is broken, and the length, stress and tension of the stretched hair are measured. In particular, a tensile strength measurement system (physical property tester: CR-500DX, SUN SCIENTIFIC CO., LTD., Japan) is reset to zero, and the hair extension distance to be measured on a measuring instrument is fixed It is 10cm. After the hair is allowed to stand under constant temperature (30±2°C) and humidity (40%) conditions for at least 30 minutes, the hair (thickness: 70-80 μm) is placed in the system for measurement.

The results are shown in Table 3 below.

As can be seen in Table 3, compared to Examples 1-3, the examples containing high-viscosity dimethylpolysiloxane (350cs dimethylpolysiloxane) or oil and silicone resin show that the composition is repeatedly applied to the hair The softness is significantly increased.

[Test Example 3] Feeling evaluation

Each of the compositions of Examples 1-6 and Comparative Example 2 was evaluated by the following perception of the hair drying time reduction effect and the hair care effect. 21 women were selected and asked to use each composition five times. Then, the maintenance effect of each composition and the effect of shortening the hair drying time were evaluated according to the following criteria. The results are shown in Table 4 below.

<The effect of shortening the drying time>

Evaluation criteria: 5-excellent, 4-good, 3-satisfactory, 2-bad, 1-poor

<hair care and finishing effect>

Evaluation items: hair softness/hair gloss/hair strength/easy styling

Evaluation criteria: 5-excellent, 4-good, 3-satisfactory, 2-bad, 1-poor

As shown in Table 4, when using the composition of this manual, it is possible to obtain a high level of all items, including the effect of shortening the hair drying time, hair softness, hair gloss, hair strength and ease of styling. Therefore, it can be seen that the composition of the present specification can effectively shorten the hair drying time while improving the excellent effects of hair care and finishing and making the hair easy to style.

[Production Example 1] Shampoo

[Preparation Example 2] Conditioner

Claims (18)

A composition prepared from volatile silicone oil, ethanol, silicone resin, and non-volatile silicone oil is used for drying hair and improving the softness of hair, wherein the non-volatile silicone oil has a viscosity between 250-400 cs Non-volatile silicone oil. The use according to claim 1, wherein the non-volatile silicone oil further comprises another non-volatile silicone oil with a viscosity between 0.1-45 cs. The use according to claim 1, wherein the volatile silicone oil is selected from at least one of the following group consisting of: methyl polysiloxane, ethyl polysiloxane, phenyl polysiloxane , Methyl phenyl polysiloxane and methyl cyclosiloxane. The use according to claim 3, wherein the volatile silicone oil is cyclopentasiloxane or cyclohexasiloxane. The use according to claim 1, wherein the silicone resin is selected from at least one of the following groups: trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate Acid salt, polyphenyl silsesquioxane and polypropyl silsesquioxane. The use according to claim 1, wherein the non-volatile silicone oil is selected from at least one of the following groups: dimethicone, cyclomethicone, dimethylsiloxane , Dimethylsiloxane copolyol and silicone synthetic rubber. The use according to claim 1, wherein the composition further comprises at least one selected from the group consisting of polyisobutylene, isododecane, C12-C15 alkyl benzoate and coconut Oleyl caprylate/caprate. The use according to claim 1, wherein the volatile silicone oil is included in an amount of 20-90 wt% based on the total weight of the composition. The use according to claim 4, wherein the volatile silicone oil includes cyclohexasiloxane and cyclopentasiloxane, and 100-250 parts by weight of cyclopentasiloxane based on 100 parts by weight of cyclohexasiloxane Department is included. The use according to claim 1, wherein the ethanol is included in an amount of 10-50 wt% based on the total weight of the composition. The use according to claim 1, wherein the silicone resin is included in an amount of 0.2-10 wt% based on the total weight of the composition. The use according to claim 1, wherein the non-volatile silicone oil is included in an amount of 5-15 wt% based on the total weight of the composition. The use according to any one of claims 1 to 12, wherein the composition shortens the hair drying time by at least 15% compared to a control group without the composition. The use according to any one of claims 1 to 12, wherein the composition improves hair gloss and improves hair water resistance. The use according to any one of claims 1 to 12, wherein the composition is an anhydrous formula. A method for quickly drying hair and improving the softness of hair, comprising a composition applied to the hair, the composition comprising volatile silicone oil, ethanol, silicone resin and non-volatile silicone oil, wherein the non-volatile silicone oil has one Non-volatile silicone oil with viscosity between 250-400cs. The method for quickly drying hair and improving the softness of hair according to claim 16, wherein the composition is applied to the hair after cleaning the hair. The method for quickly drying hair and improving the softness of hair as described in claim 16, which further comprises drying the hair after applying the composition to the hair.

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