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TWI700034B - Synergistic bactericide composition containing nitrophenol compound and bactericidal active compound - Google Patents

Synergistic bactericide composition containing nitrophenol compound and bactericidal active compound Download PDF

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Publication number
TWI700034B
TWI700034B TW107146792A TW107146792A TWI700034B TW I700034 B TWI700034 B TW I700034B TW 107146792 A TW107146792 A TW 107146792A TW 107146792 A TW107146792 A TW 107146792A TW I700034 B TWI700034 B TW I700034B
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TW
Taiwan
Prior art keywords
compound
group
compounds
nitrophenol
inhibitor
Prior art date
Application number
TW107146792A
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Chinese (zh)
Other versions
TW201929665A (en
Inventor
常岡悟
山本義紀
林孝
Original Assignee
日商日本歐愛特農業科技股份有限公司
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Publication of TW201929665A publication Critical patent/TW201929665A/en
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Publication of TWI700034B publication Critical patent/TWI700034B/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/52—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing groups, e.g. carboxylic acid amidines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
    • A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A—HUMAN NECESSITIES
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    • A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
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    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
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    • A01N41/04—Sulfonic acids; Derivatives thereof
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N47/14—Di-thio analogues thereof
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  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
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  • Environmental Sciences (AREA)
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  • Inorganic Chemistry (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

本發明之課題在於提供一種對於農園藝病原菌具有更進一步優異之防除效果之殺菌劑組成物。 本發明係關於一種協同性殺菌劑組成物，其含有(A)硝基苯酚化合物及(B)殺菌活性化合物。 本發明之病原菌防除方法之特徵在於以前述協同性殺菌劑組成物對農園藝病原菌之生存場所(人類除外)進行處理。 本發明之植物保護方法之特徵在於以前述協同性殺菌劑組成物對農園藝病原菌所寄生之植物或其附近進行處理。 本發明係關於一種硝基苯酚化合物之使用方法，其用以增強殺菌活性。 本發明係關於一種殺菌活性增強劑，其含有硝基苯酚化合物。The subject of the present invention is to provide a fungicide composition having a further excellent control effect on agricultural and horticultural pathogens. The present invention relates to a synergistic bactericide composition, which contains (A) a nitrophenol compound and (B) a bactericidal active compound. The method for controlling pathogens of the present invention is characterized in that the habitat of agricultural and horticultural pathogens (except humans) is treated with the aforementioned synergistic fungicide composition. The plant protection method of the present invention is characterized by treating plants parasitized by agricultural and horticultural pathogens or their vicinity with the aforementioned synergistic fungicide composition. The present invention relates to a method of using a nitrophenol compound to enhance the bactericidal activity. The present invention relates to a bactericidal activity enhancer, which contains a nitrophenol compound.

Description

含有硝基苯酚化合物及殺菌活性化合物之協同性殺菌劑組成物Synergistic bactericide composition containing nitrophenol compound and bactericidal active compound

發明領域 本發明係關於一種含有硝基苯酚化合物及殺菌活性化合物之協同性殺菌劑組成物。Invention field The present invention relates to a synergistic bactericide composition containing nitrophenol compounds and bactericidal active compounds.

發明背景 先前以防除危害農作物之害蟲為目的而進行農藥之開發，且多種藥劑已經實用化。然而，近年來出現了對於既有之農藥敏感性降低之個體群，既有之農藥之對於病害蟲之防除效果顯著降低。Background of the invention Previously, pesticides were developed for the purpose of preventing and eliminating pests that harm crops, and many kinds of chemicals have been put into practical use. However, in recent years, there has been a group of individuals whose susceptibility to existing pesticides has decreased, and the control effect of existing pesticides on pests has been significantly reduced.

就此，為了提高對於此類病害蟲之防除活性而進行了各種開發。例如開發出將2種以上之既有之殺菌活性化合物組合而以協同效應提高了殺菌活性之殺菌劑組成物(專利文獻1)。In this regard, various developments have been made to improve the control activity against such diseases and pests. For example, a bactericidal composition has been developed that combines two or more existing bactericidal active compounds to increase the bactericidal activity by a synergistic effect (Patent Document 1).

另一方面，揭示了硝基苯酚化合物具有植物之生長促進效果(專利文獻2)、BT毒素(殺蟲性蛋白質)之生產促進效果(專利文獻3)，但關於硝基苯酚為殺菌劑之活性增強劑之情況未作任何記載及暗示。 [先前技術文獻] [專利文獻]On the other hand, it is revealed that nitrophenol compounds have the effect of promoting plant growth (Patent Document 2) and the effect of promoting the production of BT toxin (insecticidal protein) (Patent Document 3), but regarding the activity of nitrophenol as a fungicide The situation of the enhancer is not recorded or implied. [Prior Technical Literature] [Patent Literature]

[專利文獻1]日本特開2016-199527號公報 [專利文獻2]中國專利申請公開第104628481號說明書 [專利文獻3]國際公開第2004/013286號[Patent Document 1] JP 2016-199527 A [Patent Document 2] Chinese Patent Application Publication No. 104628481 Specification [Patent Document 3] International Publication No. 2004/013286

發明概要 [發明欲解決之課題]本發明之課題在於一種對於農園藝病原菌具有更進一步優異之防除效果之協同性殺菌劑組成物。 [用以解決課題之手段]Summary of the invention [Problem to be Solved by the Invention] The subject of the present invention is a synergistic fungicide composition having a further excellent control effect on agricultural and horticultural pathogens. [Means to solve the problem]

本發明人為了解決前述課題而反覆銳意研究，結果發現硝基苯酚化合物使殺菌劑之防除活性增強。本發明係基於此種見解而完成者。In order to solve the aforementioned problems, the present inventors have conducted intensive research and found that the nitrophenol compound enhances the control activity of the fungicide. The present invention was completed based on this knowledge.

即，本發明係關於一種下述之含有硝基苯酚化合物及殺菌活性化合物之協同性殺菌劑組成物等。That is, the present invention relates to a synergistic bactericide composition containing a nitrophenol compound and a bactericidal active compound as described below.

項1. 一種協同性殺菌劑組成物，其含有(A)硝基苯酚化合物及(B)殺菌活性化合物。 項2. 如項1記載之協同性殺菌劑組成物，其中(B)殺菌活性化合物為選自於由 (b1)RNA聚合酶抑制劑(A1)、 (b2)β-微管蛋白聚合抑制劑(B1、2、3)、 (b3)類血影蛋白蛋白質之非定域化劑(B5)、 (b4)呼吸鏈複合體II(琥珀酸脫氫酶)抑制劑(C2)、 (b5)呼吸鏈複合體III(泛醌醇(ubiquinol)氧化酶、Qo位點)抑制劑(C3)、 (b6)呼吸鏈複合體III(泛醌還原酶、Qi位點)抑制劑(C4)、 (b7)氧化性磷酸化中之解偶聯劑(C5)、 (b8)呼吸鏈複合體III(泛醌還原酶、Qo位點)抑制劑(C8)、 (b9)磷脂質生物合成之甲基轉移酶抑制劑(F2)、 (b10)細胞膜滲透性之脂肪酸(F4)、 (b11)脂質之恆定性、轉移、蓄積之抑制劑(F9)、 (b12)固醇生物合成中之C14位之去甲基化抑制劑(G1)、 (b13)纖維素合成酶抑制劑(H5)、 (b14)黑色素生物合成中之還原酶抑制劑(I1)、 (b15)黑色素生物合成中之脫水酶抑制劑(I2)、 (b16)黑色素生物合成中之聚酮化合物合成抑制劑(I3)、 (b17)以多作用位點為目標之化合物(M1～11)、 (b18)宿主植物之抵抗性誘導劑(P1、2、3、4、7)、及 (b19)作用機制不明之化合物(U) 所構成群組中之至少一種化合物。 項3. 如項1記載之協同性殺菌劑組成物，其中(B)殺菌活性化合物為選自於由 (b1)RNA聚合酶抑制劑(A1)、 (b2)β-微管蛋白聚合抑制劑(B3)、 (b3)類血影蛋白蛋白質之非定域化劑(B5)、 (b4)呼吸鏈複合體II(琥珀酸脫氫酶)抑制劑(C2)、 (b5)呼吸鏈複合體III(泛醌醇氧化酶、Qo位點)抑制劑(C3)、 (b6)呼吸鏈複合體III(泛醌還原酶、Qi位點)抑制劑(C4)、 (b7)氧化性磷酸化中之解偶聯劑(C5)、 (b8)呼吸鏈複合體III(泛醌還原酶、Qo位點)抑制劑(C8)、 (b9)磷脂質生物合成之甲基轉移酶抑制劑(F2)、 (b10)細胞膜滲透性之脂肪酸(F4)、 (b11)脂質之恆定性、轉移、蓄積之抑制劑(F9)、 (b12)固醇生物合成中之C14位之去甲基化抑制劑(G1)、 (b13)纖維素合成酶抑制劑(H5)、 (b14)黑色素生物合成中之還原酶抑制劑(I1)、 (b15)黑色素生物合成中之脫水酶抑制劑(I2)、 (b16)黑色素生物合成中之聚酮化合物合成抑制劑(I3)、 (b17)以多作用位點為目標之化合物(M1～11)、 (b18)宿主植物之抵抗性誘導劑(P1、7)、 (b19)克絕、克枯爛、環氟菌胺、氟噻唑菌腈、富米綜、特弗喹啉、維利黴素、咪唑

Figure 107146792-A0304-12-0020-4
、氟硫滅、達滅淨、多果定、滅芬農、苯啶菌酮、及picarbutrazox(U) 所構成群組中之至少一種化合物。 項4. 如項1至3中任一項記載之協同性殺菌劑組成物，其中(B)殺菌活性化合物為選自於由 (b1)RNA聚合酶抑制劑(A1)、 (b2)β-微管蛋白聚合抑制劑(B3)、 (b3)類血影蛋白蛋白質之非定域化劑(B5)、 (b4)呼吸鏈複合體II(琥珀酸脫氫酶)抑制劑(C2)、 (b5)呼吸鏈複合體III(泛醌醇氧化酶、Qo位點)抑制劑(C3)、 (b6)呼吸鏈複合體III(泛醌還原酶、Qi位點)抑制劑(C4)、 (b7)氧化性磷酸化中之解偶聯劑(C5)、 (b8)呼吸鏈複合體III(泛醌還原酶、Qo位點)抑制劑(C8)、 (b10)細胞膜滲透性之脂肪酸(F4)、 (b11)脂質之恆定性、轉移、蓄積之抑制劑(F9)、 (b12)固醇生物合成中之C14位之去甲基化抑制劑(G1)、 (b13)纖維素合成酶抑制劑(H5)、 (b17)以多作用位點為目標之化合物(M1、3、5)、 (b18)宿主植物之抵抗性誘導劑(P1、7)、 (b19)克絕、克枯爛、環氟菌胺、氟噻唑菌腈、富米綜、特弗喹啉、維利黴素、咪唑
Figure 107146792-A0304-12-0020-4
、氟硫滅、達滅淨、多果定、滅芬農、苯啶菌酮、及picarbutrazox (U)所構成群組中之至少一種化合物。 項5. 如項4記載之協同性殺菌劑組成物，其中前述(b1)RNA聚合酶抑制劑(A1)為醯基丙胺酸化合物； (b2)β-微管蛋白聚合抑制劑(B3)為乙基胺基噻唑甲醯胺化合物； (b3)類血影蛋白蛋白質之非定域化劑(B5)為吡啶基甲基苯甲醯胺化合物； (b4)呼吸鏈複合體II(琥珀酸脫氫酶)抑制劑(C2)為吡啶甲醯胺化合物； (b5)呼吸鏈複合體III(泛醌醇氧化酶、Qo位點)抑制劑(C3)為甲氧基胺基甲酸酯化合物、甲氧基丙烯酸酯化合物、及氧基亞胺基乙酸化合物、
Figure 107146792-A0304-12-0015-1
唑啶二酮化合物； (b6)呼吸鏈複合體III(泛醌還原酶、Qi位點)抑制劑(C4)為氰基咪唑化合物； (b7)氧化性磷酸化中之解偶聯劑(C5)為2,6-二硝基苯胺化合物； (b8)呼吸鏈複合體III(泛醌還原酶、Qo位點)抑制劑(C8)為三唑并嘧啶胺化合物； (b10)細胞膜滲透性之脂肪酸(F4)為胺基甲酸酯化合物； (b11)脂質之恆定性、轉移、蓄積之抑制劑(F9)為哌啶基噻唑異
Figure 107146792-A0304-12-0015-1
唑啉化合物； (b12)固醇生物合成中之C14位之去甲基化抑制劑(G1)為三唑化合物、及咪唑化合物； (b13)纖維素合成酶抑制劑(H5)為桂皮酸醯胺化合物、及苦杏仁酸醯胺化合物； (b17)以多作用位點為目標之化合物(M1、3、5)為銅化合物、二硫代胺基甲酸酯化合物、及氯腈化合物； (b18)宿主植物之抵抗性誘導劑(P1、7)為苯并噻二唑化合物、乙基膦酸鹽化合物、及氯腈化合物；以及 (b19)作用機制不明之化合物(U)為氰基乙醯胺肟化合物。 項6. 如項1至5中任一項記載之協同性殺菌劑組成物，其中(B)殺菌活性化合物為選自於由滅達樂、右滅達樂、白克列、百克敏、亞托敏、三氟敏、克收欣、啶氧菌酯、賽座滅、凡殺同、辛唑嘧菌胺、扶吉胺、四克利、富馬酸
Figure 107146792-A0304-12-0015-1
咪唑、護汰芬、四氯異苯、鋅錳乃浦、達滅芬、曼普胺、噻唑菌胺)、阿拉酸式苯-S-甲基、氟吡菌胺、霜黴威鹽酸鹽、福賽得、亞磷酸或其鹽、噻哌菌靈、壬基苯酚磺酸銅鹽、及克絕所構成群組中之至少一種化合物。 項7. 如項1至6中任一項記載之協同性殺菌劑組成物，其中前述(A)硝基苯酚化合物為具有1個硝基之苯酚化合物。 項8. 如項1至7中任一項記載之協同性殺菌劑組成物，其中(A)硝基苯酚化合物之摻合比率相對於(B)殺菌活性成分100重量份為1～5000重量份。 項9. 一種病原菌防除方法，其特徵在於以如項1至8中任一項記載之協同性殺菌劑組成物對農園藝病原菌之生存場所(人類除外)進行處理。 項10. 一種病原菌防除方法，其特徵在於以如項1至8中任一項記載之協同性殺菌劑組成物對農園藝病原菌之生存場所進行處理。 項11. 一種植物保護方法，其特徵在於以如項1至8中任一項記載之協同性殺菌劑組成物對農園藝病原菌所寄生之植物或其附近進行處理。 項12. 一種硝基苯酚化合物之使用方法，其用以增強殺菌活性。 項13. 一種硝基苯酚化合物之使用方法，其係用以增強殺菌活性化合物之殺菌活性者(對於人類之應用除外)，且 前述殺菌活性化合物為選自於由滅達樂、右滅達樂、白克列、百克敏、亞托敏、三氟敏、克收欣、啶氧菌酯、賽座滅、凡殺同、辛唑嘧菌胺、扶吉胺、四克利、富馬酸
Figure 107146792-A0304-12-0015-1
咪唑、護汰芬、四氯異苯、鋅錳乃浦、達滅芬、曼普胺、噻唑菌胺、阿拉酸式苯-S-甲基、氟吡菌胺、霜黴威鹽酸鹽、福賽得、亞磷酸或其鹽、噻哌菌靈、壬基苯酚磺酸銅鹽、及克絕所構成群組中之至少一種化合物。 項14. 如項12或13記載之使用方法，其中前述硝基苯酚化合物為具有1個硝基之苯酚化合物。 項15. 一種殺菌活性增強劑，其含有硝基苯酚化合物。 項16. 一種殺菌活性增強劑，其係對殺菌活性化合物含有硝基苯酚化合物者，且 前述殺菌活性化合物為選自於由滅達樂、右滅達樂、白克列、百克敏、亞托敏、三氟敏、克收欣、啶氧菌酯、賽座滅、凡殺同、辛唑嘧菌胺、扶吉胺、四克利、富馬酸
Figure 107146792-A0304-12-0015-1
咪唑、護汰芬、四氯異苯、鋅錳乃浦、達滅芬、曼普胺、噻唑菌胺、阿拉酸式苯-S-甲基、氟吡菌胺、霜黴威鹽酸鹽、福賽得、亞磷酸或其鹽、噻哌菌靈、壬基苯酚磺酸銅鹽、及克絕所構成群組中之至少一種化合物。 項17. 如項15或16記載之殺菌活性增強劑，其中前述硝基苯酚化合物為具有1個硝基之苯酚化合物。 [發明效果]Item 1. A synergistic bactericide composition, which contains (A) a nitrophenol compound and (B) a bactericidal active compound. Item 2. The synergistic bactericide composition as described in Item 1, wherein (B) the bactericidal active compound is selected from (b1) RNA polymerase inhibitor (A1), (b2) β-tubulin polymerization inhibitor (B1, 2, 3), (b3) Spectrin-like protein delocalization agent (B5), (b4) Respiratory chain complex II (succinate dehydrogenase) inhibitor (C2), (b5) Respiratory chain complex III (ubiquinol oxidase, Qo site) inhibitor (C3), (b6) Respiratory chain complex III (ubiquinol reductase, Qi site) inhibitor (C4), ( b7) Uncoupling agent in oxidative phosphorylation (C5), (b8) Respiratory chain complex III (ubiquinone reductase, Qo site) inhibitor (C8), (b9) Methyl group of phospholipid biosynthesis Transferase inhibitor (F2), (b10) fatty acid of cell membrane permeability (F4), (b11) inhibitor of lipid constancy, transfer and accumulation (F9), (b12) C14 in sterol biosynthesis Demethylation inhibitors (G1), (b13) cellulose synthase inhibitors (H5), (b14) reductase inhibitors in melanin biosynthesis (I1), (b15) dehydratase inhibitors in melanin biosynthesis Agents (I2), (b16) Inhibitors of polyketide synthesis in melanin biosynthesis (I3), (b17) Compounds targeting multiple sites of action (M1-11), (b18) Resistance induction of host plants At least one compound in the group consisting of compounds (P1, 2, 3, 4, 7) and (b19) with unknown mechanism of action (U). Item 3. The synergistic bactericide composition according to Item 1, wherein (B) the bactericidal active compound is selected from (b1) RNA polymerase inhibitor (A1), (b2) β-tubulin polymerization inhibitor (B3), (b3) Spectrin-like protein delocalization agent (B5), (b4) Respiratory chain complex II (succinate dehydrogenase) inhibitor (C2), (b5) Respiratory chain complex III (ubiquinone oxidase, Qo site) inhibitor (C3), (b6) respiratory chain complex III (ubiquinone reductase, Qi site) inhibitor (C4), (b7) oxidative phosphorylation Uncoupling agent (C5), (b8) respiratory chain complex III (ubiquinone reductase, Qo site) inhibitor (C8), (b9) phospholipid biosynthesis methyltransferase inhibitor (F2) , (B10) Fatty acid of cell membrane permeability (F4), (b11) Inhibitor of lipid constancy, transfer, accumulation (F9), (b12) Demethylation inhibitor at C14 in sterol biosynthesis ( G1), (b13) Cellulose Synthase Inhibitor (H5), (b14) Reductase Inhibitor in Melanin Biosynthesis (I1), (b15) Dehydratase Inhibitor in Melanin Biosynthesis (I2), (b16 ) Polyketide synthesis inhibitors in melanin biosynthesis (I3), (b17) Compounds that target multiple sites of action (M1-11), (b18) Host plant resistance inducers (P1, 7), (b19) Kejue, Keluotuan, Cyfluoxazone, Fluthiazole, Fumizumab, Tefquinoline, Velimycin, Imidazole
Figure 107146792-A0304-12-0020-4
At least one compound in the group consisting of sulfamethoxazole, tarmethine, docardine, metfennon, fenacinone, and picarbutrazox (U). Item 4. The synergistic bactericide composition according to any one of items 1 to 3, wherein (B) the bactericidal active compound is selected from (b1) RNA polymerase inhibitor (A1), (b2) β- Tubulin polymerization inhibitor (B3), (b3) spectrin-like protein delocalization agent (B5), (b4) respiratory chain complex II (succinate dehydrogenase) inhibitor (C2), ( b5) Respiratory chain complex III (ubiquinol oxidase, Qo site) inhibitor (C3), (b6) Respiratory chain complex III (ubiquinone reductase, Qi site) inhibitor (C4), (b7 ) Uncoupling agent in oxidative phosphorylation (C5), (b8) Respiratory chain complex III (ubiquinone reductase, Qo site) inhibitor (C8), (b10) Cell membrane permeability fatty acid (F4) , (B11) Inhibitors of lipid constancy, transfer and accumulation (F9), (b12) Demethylation inhibitors at C14 in sterol biosynthesis (G1), (b13) Cellulose synthase inhibitors (H5), (b17) Compounds that target multiple sites of action (M1, 3, 5), (b18) Resistance inducers of host plants (P1, 7), (b19) Rejection, elimination, Cyfluxanil, fluthiaconazole, fumizide, tefquinoline, verinomycin, imidazole
Figure 107146792-A0304-12-0020-4
At least one compound in the group consisting of fluorine sulfamethoxazole, tarmethine, docardine, metfennon, fenacinone, and picarbutrazox (U). Item 5. The synergistic bactericide composition according to Item 4, wherein the aforementioned (b1) RNA polymerase inhibitor (A1) is an alanine compound; (b2) β-tubulin polymerization inhibitor (B3) is Ethylaminothiazole carboxamide compound; (b3) Spectrin protein delocalization agent (B5) is a pyridylmethylbenzamide compound; (b4) respiratory chain complex II (succinic acid delocalization) Hydrogenase inhibitor (C2) is a picolinamide compound; (b5) Respiratory chain complex III (ubiquinol oxidase, Qo site) inhibitor (C3) is a methoxy carbamate compound, Methoxyacrylate compounds, and oxyiminoacetic acid compounds,
Figure 107146792-A0304-12-0015-1
Zolidinedione compound; (b6) Respiratory chain complex III (ubiquinone reductase, Qi site) inhibitor (C4) is a cyanoimidazole compound; (b7) Uncoupling agent in oxidative phosphorylation (C5) ) Is a 2,6-dinitroaniline compound; (b8) Respiratory chain complex III (ubiquinone reductase, Qo site) inhibitor (C8) is a triazolopyrimidine compound; (b10) Cell membrane permeability Fatty acid (F4) is a carbamate compound; (b11) The inhibitor of lipid stability, transfer and accumulation (F9) is piperidinyl thiazole iso
Figure 107146792-A0304-12-0015-1
Oxazoline compounds; (b12) C14 demethylation inhibitor (G1) in sterol biosynthesis is triazole compound and imidazole compound; (b13) Cellulose synthase inhibitor (H5) is cinnamic acid Amine compounds and mandelic acid amide compounds; (b17) Compounds (M1, 3, 5) targeting multiple sites of action are copper compounds, dithiocarbamate compounds, and chloronitrile compounds; ( b18) Host plant resistance inducers (P1, 7) are benzothiadiazole compounds, ethyl phosphonate compounds, and chloronitrile compounds; and (b19) compounds with unknown mechanism of action (U) are cyanoethyl Amidoxime compounds. Item 6. The synergistic bactericide composition according to any one of items 1 to 5, wherein (B) the bactericidal active compound is selected from the group consisting of metalol, dexmetalol, beakley, beacamine, and Tomin, Trifluramine, Keshouxin, Picoxystrobin, Cyclostrobin, Fanshaton, Oxystrobin, Fugemide, Tetraclimate, Fumaric Acid
Figure 107146792-A0304-12-0015-1
Imidazole, Hutaifen, Tetrachloroisophenyl, Zinc Manganese Nap, Damiphen, Manpromide, Thiazolamide), Alafenac-S-Methyl, Fluopyram, Propamocarb Hydrochloride At least one compound in the group consisting of, Fosaide, phosphorous acid or its salt, thiaperbendazole, copper nonylphenol sulfonate, and Keju. Item 7. The synergistic fungicide composition according to any one of items 1 to 6, wherein the (A) nitrophenol compound is a phenol compound having one nitro group. Item 8. The synergistic fungicide composition according to any one of items 1 to 7, wherein the blending ratio of (A) the nitrophenol compound is 1 to 5000 parts by weight relative to 100 parts by weight of the (B) bactericidal active ingredient . Item 9. A method for the control of pathogenic bacteria, characterized in that the habitat of agricultural and horticultural pathogens (excluding humans) is treated with the synergistic fungicide composition described in any one of items 1 to 8. Item 10. A method for the control of pathogenic bacteria, which is characterized in that the habitat of agricultural and horticultural pathogens is treated with the synergistic fungicide composition described in any one of items 1 to 8. Item 11. A method for plant protection, characterized in that the synergistic fungicide composition described in any one of items 1 to 8 treats plants parasitized by agricultural and horticultural pathogens or their vicinity. Item 12. A method of using a nitrophenol compound to enhance the bactericidal activity. Item 13. A method of using a nitrophenol compound, which is used to enhance the bactericidal activity of bactericidal active compounds (except for human use), and the aforementioned bactericidal active compound is selected from the group consisting of metal and dexmetal , Bekley, Bekmine, Yatomin, Trifluorosensitizer, Keshouxin, Picoxystrobin, Cyclostrobin, Fanshatong, Oxystrobin, Fugemide, Tetraclimate, Fumaric acid
Figure 107146792-A0304-12-0015-1
Imidazole, Hutaifen, Tetrachloroisophenyl, Zinc Manganese Naipura, Dametifene, Manpromide, Thiazolamide, Alaclofen-S-methyl, Fluopyram, Propamocarb Hydrochloride, At least one compound in the group consisting of Fosaide, phosphorous acid or a salt thereof, thiaperbendazole, copper nonylphenol sulfonate, and ketone. Item 14. The method of use according to Item 12 or 13, wherein the nitrophenol compound is a phenol compound having one nitro group. Item 15. A bactericidal activity enhancer, which contains a nitrophenol compound. Item 16. A bactericidal activity enhancer, which is a bactericidal active compound containing a nitrophenol compound, and the aforementioned bactericidal active compound is selected from the group consisting of metronidazole, dexmidal, bacterol, bekamine, and Yato Allergen, Trifluramine, Keshouxin, Picoxystrobin, Cyclostrobin, Fanshatong, Oxystrobin, Fugemide, Tetraclimate, Fumaric Acid
Figure 107146792-A0304-12-0015-1
Imidazole, Hutaifen, Tetrachloroisophenyl, Zinc Manganese Naipura, Dametifene, Manpromide, Thiazolamide, Alaclofen-S-methyl, Fluopyram, Propamocarb Hydrochloride, At least one compound in the group consisting of Fosaide, phosphorous acid or a salt thereof, thiaperbendazole, copper nonylphenol sulfonate, and ketone. Item 17. The bactericidal activity enhancer according to Item 15 or 16, wherein the nitrophenol compound is a phenol compound having one nitro group. [Invention Effect]

本發明之協同性殺菌劑組成物以低藥量對於農園藝病原菌顯示出效力。The synergistic bactericide composition of the present invention shows efficacy against agricultural and horticultural pathogens at a low dose.

本發明之協同性殺菌劑組成物即便在對既有之殺菌活性化合物獲得了抵抗性之農園藝病原菌，亦顯現出同樣優異之防除效果。The synergistic bactericide composition of the present invention exhibits the same excellent control effect even on agricultural and horticultural pathogens that have acquired resistance to existing bactericidal active compounds.

進一步，根據本發明之協同性殺菌劑組成物，與各自單獨使用了既有之殺菌劑之情形相比，可減少其處理藥量，因此亦可抑制農園藝病原菌對於各殺菌活性化合物之抵抗性之發達。Furthermore, the synergistic bactericide composition according to the present invention can reduce the amount of the treatment agent compared with the case where the existing bactericides are used alone, and therefore can also inhibit the resistance of agricultural and horticultural pathogens to each bactericidal active compound Its developed.

用以實施發明之型態 協同性殺菌劑組成物 關於本發明之含有硝基苯酚化合物及殺菌活性化合物之協同性殺菌劑組成物(以下，亦有時稱為「本發明組成物」)，以下進行說明。Types used to implement the invention Synergistic bactericide composition The synergistic bactericide composition of the present invention containing a nitrophenol compound and a bactericidal active compound (hereinafter, also sometimes referred to as "the composition of the present invention") will be described below.

(A)硝基苯酚化合物 作為(A)硝基苯酚化合物，只要為具有1個以上之硝基及1個以上之羥基(OH基)之芳香環化合物，則無特別限定，該化合物亦可進一步具有上述硝基及羥基以外之取代基。(A) Nitrophenol compound The (A) nitrophenol compound is not particularly limited as long as it is an aromatic ring compound having one or more nitro groups and one or more hydroxyl groups (OH groups), and the compound may further have nitro groups and hydroxyl groups other than the above The substituents.

作為取代基，並無特別限定，例如可列舉：鹵素原子、C1 ～6 烷基、C1 ～6 鹵烷基、C1 ～6 烷氧基、C1 ～6 鹵烷氧基、C2 ～6 烯基、C2 ～6 鹵烯基、C2 ～6 烯氧基、C2 ～6 鹵烯氧基、C2 ～6 炔基、C2 ～6 鹵炔基、C2 ～6 炔氧基、C2 ～6 鹵炔氧基等。The substituent is not particularly limited, and examples thereof include a halogen atom, a C 1 to 6 alkyl group, a C 1 to 6 haloalkyl group, a C 1 to 6 alkoxy group, a C 1 to 6 haloalkoxy group, and C 2 ～ 6alkenyl, C 2 ～6 haloalkenyl, C 2 ～6 alkenyloxy, C 2 ～6 haloalkenyloxy, C 2 ～6 alkynyl, C 2 ～6 haloalkynyl, C 2 ～6 alkyne Oxy, C 2 ～6 haloalkynoxy and the like.

於本說明書中之硝基苯酚化合物中亦可含有已形成鹽之硝基苯酚化合物(硝基苯酚化合物之鹽)。The nitrophenol compound in this specification may also contain a salt-formed nitrophenol compound (a salt of a nitrophenol compound).

作為本說明書中之鹽，例如可列舉：鹼金屬鹽(鈉鹽、鉀鹽等)、鹼土金屬鹽(鈣鹽、鎂鹽等)、銨鹽(氨；嗎啉、哌啶、吡咯啶、低級單、二或三烷基胺、低級單、二或三羥烷基胺等有機胺等)等，宜為水溶性且農藝化學上有利之鹽，更宜為鹼金屬鹽。Examples of the salt in this specification include: alkali metal salts (sodium salt, potassium salt, etc.), alkaline earth metal salts (calcium salt, magnesium salt, etc.), ammonium salt (ammonia; morpholine, piperidine, pyrrolidine, lower Mono-, di- or tri-alkyl amines, lower mono-, di- or tri-hydroxyalkyl amines and other organic amines, etc.), etc., are preferably water-soluble and agrochemically advantageous salts, and more preferably alkali metal salts.

其中，作為該硝基苯酚化合物，例如可列舉下述通式(1)所表示之硝基苯酚化合物或其鹽： [化學式1]

Figure 02_image001
(式中，X表示C-R'基或氮原子； R、及R'相同或不同，表示氫原子、鹵素原子、羥基、硝基、C1 ～6 烷基、C1 ～6 鹵烷基、C1 ～6 烷氧基、C1 ～6 鹵烷氧基、C2 ～6 烯基、C2 ～6 鹵烯基、C2 ～6 烯氧基、C2 ～6 鹵烯氧基、C2 ～6 炔基、C2 ～6 鹵炔基、C2 ～6 炔氧基、或C2 ～6 鹵炔氧基)。Among them, as the nitrophenol compound, for example, a nitrophenol compound represented by the following general formula (1) or a salt thereof: [Chemical formula 1]
Figure 02_image001
(In the formula, X represents a C-R' group or a nitrogen atom; R and R'are the same or different and represent a hydrogen atom, a halogen atom, a hydroxyl group, a nitro group, a C 1 -6 alkyl group, and a C 1 -6 haloalkyl group , C 1 ～6 alkoxy, C 1 ～6 haloalkoxy, C 2 ～6 alkenyl, C 2 ～6 haloalkenyl, C 2 ～6 alkenyloxy, C 2 ～6 haloalkenyloxy, C 2 -6 alkynyl, C 2 -6 haloalkynyl, C 2 -6 alkynyloxy, or C 2 -6 haloalkynyloxy).

進而，作為該硝基苯酚化合物，可列舉下述通式(2)所表示之硝基苯酚化合物或其鹽等： [化學式2]

Figure 02_image003
(式中，R1 、R2 、R3 、R4 、及R5 基相同或不同，表示氫原子、鹵素原子、羥基、硝基、C1 ～6 烷基、C1 ～6 鹵烷基、C1 ～6 烷氧基、C1 ～6 鹵烷氧基、C2 ～6 烯基、C2 ～6 鹵烯基、C2 ～6 烯氧基、C2 ～6 鹵烯氧基、C2 ～6 炔基、C2 ～6 鹵炔基、C2 ～6 炔氧基、或C2 ～6 鹵炔氧基)。Furthermore, as the nitrophenol compound, a nitrophenol compound represented by the following general formula (2) or a salt thereof can be cited: [Chemical formula 2]
Figure 02_image003
(In the formula, R 1 , R 2 , R 3 , R 4 , and R 5 are the same or different, and represent a hydrogen atom, a halogen atom, a hydroxyl group, a nitro group, a C 1 -6 alkyl group, and a C 1 -6 haloalkyl group , C 1 ～6 alkoxy, C 1 ～6 haloalkoxy, C 2 ～6 alkenyl, C 2 ～6 haloalkenyl, C 2 ～6 alkenyloxy, C 2 ～6 haloalkenyloxy, C 2 -6 alkynyl, C 2 -6 haloalkynyl, C 2 -6 alkynyloxy, or C 2 -6 haloalkynyloxy).

以下對於本說明書中之各基進行說明。The following is an explanation of each basis in this specification.

作為鹵素原子，並無特別限定，例如可列舉氟原子、氯原子、溴原子、碘原子等。The halogen atom is not particularly limited, and examples thereof include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom.

作為C1 ～6 烷基，並無特別限定，例如可列舉：甲基、乙基、正丙基、異丙基、正丁基、異丁基、第二丁基、第三丁基、正戊基、異戊基、新戊基、正己基、異己基等碳數1～6之直鏈狀或支鏈狀烷基。再者，於本說明書中，「正(n-)」表示normal，「第二(s-)」表示secondary，「第三(t-)」表示tertiary。The C 1 to 6 alkyl group is not particularly limited, and examples include methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, second butyl, tertiary butyl, n-propyl C1-C6 linear or branched alkyl groups such as pentyl, isopentyl, neopentyl, n-hexyl, and isohexyl. Furthermore, in this manual, "positive (n-)" means normal, "second (s-)" means secondary, and "third (t-)" means tertiary.

作為C1 ～6 鹵烷基，並無特別限定，例如可列舉：氟甲基、氯甲基、溴甲基、碘甲基、二氟甲基、三氟甲基、1-氟乙基、2-氟乙基、2-氯乙基、2,2,2-三氟乙基、五氟乙基、1-氟丙基、2-氯丙基、3-氟丙基、3-氯丙基、1-氟丁基、1-氯丁基、4-氟丁基等經1～9個、宜經1～5個鹵素原子取代之碳數1～6之直鏈狀或支鏈狀烷基。The C 1 -6 haloalkyl group is not particularly limited, and examples include fluoromethyl, chloromethyl, bromomethyl, iodomethyl, difluoromethyl, trifluoromethyl, 1-fluoroethyl, 2-fluoroethyl, 2-chloroethyl, 2,2,2-trifluoroethyl, pentafluoroethyl, 1-fluoropropyl, 2-chloropropyl, 3-fluoropropyl, 3-chloropropyl Radicals, 1-fluorobutyl, 1-chlorobutyl, 4-fluorobutyl, etc., linear or branched alkanes with 1 to 6 carbons substituted by 1 to 9, preferably 1 to 5 halogen atoms base.

作為C1 ～6 烷氧基，並無特別限定，例如可列舉：甲氧基、乙氧基、正丙氧基、異丙氧基、正丁氧基、異丁氧基、第二丁氧基、第三丁氧基、正戊氧基、異戊氧基、新戊氧基、正己氧基、異己氧基等碳數1～6之直鏈狀或支鏈狀烷氧基。The C 1 -6 alkoxy group is not particularly limited, and examples include methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, isobutoxy, and second butoxy A straight-chain or branched alkoxy group with 1 to 6 carbon atoms, such as alkoxy group, tertiary butoxy group, n-pentyloxy group, isopentyloxy group, neopentyloxy group, n-hexyloxy group and isohexyloxy group.

作為C1 ～6 鹵烷氧基，並無特別限定，例如可列舉：氟甲氧基、氯甲氧基、溴甲氧基、碘甲氧基、二氟甲氧基、三氟甲氧基、1-氟乙氧基、2-氟乙氧基、2-氯乙氧基、2,2,2-三氟乙氧基、五氟乙氧基、1-氟丙氧基、2-氯丙氧基、3-氟丙氧基、3-氯丙氧基、1-氟丁基、1-氯丁氧基、4-氟丁氧基等經1～9個、宜為1～5個鹵素原子取代之碳數1～6之直鏈狀或支鏈狀烷氧基The C 1 to 6 haloalkoxy group is not particularly limited, and examples include fluoromethoxy, chloromethoxy, bromomethoxy, iodomethoxy, difluoromethoxy, and trifluoromethoxy , 1-fluoroethoxy, 2-fluoroethoxy, 2-chloroethoxy, 2,2,2-trifluoroethoxy, pentafluoroethoxy, 1-fluoropropoxy, 2-chloro Propoxy, 3-fluoropropoxy, 3-chloropropoxy, 1-fluorobutyl, 1-chlorobutoxy, 4-fluorobutoxy, etc. 1-9, preferably 1-5 Linear or branched alkoxy group with 1 to 6 carbons substituted by halogen atom

作為C2 ～6 烯基，並無特別限定，例如可列舉：乙烯基、1-丙烯基、烯丙基、異丙烯基、1-丁烯基、2-丁烯基、3-丁烯基、1-甲基-2-丙烯基、1,3-丁二烯基等碳數2～6之直鏈狀或支鏈狀烯基。The C 2 to 6 alkenyl group is not particularly limited, and examples include vinyl, 1-propenyl, allyl, isopropenyl, 1-butenyl, 2-butenyl, and 3-butenyl. , 1-methyl-2-propenyl, 1,3-butadienyl and other linear or branched alkenyl groups with 2-6 carbon atoms.

作為C2 ～6 鹵烯基，並無特別限定，例如可列舉：2,2-二氯乙烯基、2,2-二溴乙烯基、3-氯-2-丙烯基、3,3-二氟-2-烯丙基、3,3-二氯-2-烯丙基、4-氯-2-丁烯基、4,4,4-三氟-2-丁烯基、4,4,4-三氯-3-丁烯基、5-氯-3-戊烯基、6-氟-2-己烯基等於任意之位置具有至少1個雙鍵之碳數2～6之直鏈狀或支鏈狀烯基，且經1～13個、宜為1～7個鹵素原子取代之烯基。The C 2 -6 haloalkenyl group is not particularly limited, and examples include 2,2-dichlorovinyl, 2,2-dibromovinyl, 3-chloro-2-propenyl, and 3,3-dichlorovinyl, Fluoro-2-allyl, 3,3-dichloro-2-allyl, 4-chloro-2-butenyl, 4,4,4-trifluoro-2-butenyl, 4,4, 4-trichloro-3-butenyl, 5-chloro-3-pentenyl and 6-fluoro-2-hexenyl are linear chains with at least one double bond and carbon numbers from 2 to 6 at any position Or a branched alkenyl group substituted by 1-13, preferably 1-7, halogen atoms.

作為C2 ～6 烯氧基，並無特別限定，例如可列舉：乙烯氧基、1-丙烯氧基、烯丙氧基、異丙烯氧基、1-丁烯氧基、2-丁烯氧基、3-丁烯氧基、1-甲基-2-丙烯氧基、1,3-丁二烯氧基等碳數2～6之直鏈狀或支鏈狀烯氧基。As the C 2 ~ 6 alkenyloxy group, is not particularly limited, and examples thereof include: vinyl group, 1-propenyloxy, allyloxy, isopropenyloxy, 1-butenyloxy, 2-butene oxide C2-6 linear or branched alkenyloxy groups, such as 3-butenyloxy, 1-methyl-2-propenyloxy, and 1,3-butadienyloxy.

作為C2 ～6 鹵烯氧基，並無特別限定，例如可列舉：2,2-二氯乙烯氧基、2,2-二溴乙烯氧基、3-氯-2-丙烯氧基、3,3-二氟-2-烯丙氧基、3,3-二氯-2-烯丙氧基、4-氯-2-丁烯氧基、4,4,4-三氟-2-丁烯氧基、4,4,4-三氯-3-丁烯氧基、5-氯-3-戊烯氧基、6-氟-2-己烯氧基等於任意之位置具有至少1個雙鍵之碳數2～6之直鏈狀或支鏈狀烯基，且經1～13個、宜為1～7個鹵素原子取代之烯基。The C 2 to 6 haloalkenyloxy group is not particularly limited, and examples include 2,2-dichlorovinyloxy, 2,2-dibromovinyloxy, 3-chloro-2-propenoxy, 3 ,3-Difluoro-2-allyloxy, 3,3-dichloro-2-allyloxy, 4-chloro-2-butenoxy, 4,4,4-trifluoro-2-butan Alkenyloxy, 4,4,4-trichloro-3-butenyloxy, 5-chloro-3-pentenyloxy, 6-fluoro-2-hexenyloxy are equal to any position with at least 1 double The bond has a linear or branched alkenyl group with 2-6 carbon atoms, and an alkenyl group substituted with 1-13, preferably 1-7, halogen atoms.

作為C2 ～6 炔基，例如可列舉：乙炔基、1-丙炔基、2-丙炔基、1-甲基-2-丙炔基、1-丁炔基、2-丁炔基、3-丁炔基等碳數2～6之直鏈狀或支鏈狀炔基。Examples of C 2 to 6 alkynyl groups include ethynyl, 1-propynyl, 2-propynyl, 1-methyl-2-propynyl, 1-butynyl, 2-butynyl, Linear or branched alkynyl groups with 2-6 carbon atoms such as 3-butynyl.

作為C2 ～6 鹵炔基，並無特別限定，例如可列舉：3,3,3-三氟丙炔基、3,3-二氟丙炔基、3,3,3-三氟丁炔基、4,4,4-三氟-2-丁炔基、3,3-二氟-丁炔基等於任意之位置具有至少1個三鍵之碳數2～6之直鏈狀或支鏈狀炔基，且經1～13個、宜為1～7個鹵素原子取代之炔基。The C 2 -6 haloalkynyl group is not particularly limited, and examples thereof include 3,3,3-trifluoropropynyl, 3,3-difluoropropynyl, and 3,3,3-trifluorobutyne Group, 4,4,4-trifluoro-2-butynyl, 3,3-difluoro-butynyl, equal to any position with at least one triple bond, linear or branched chain with 2-6 carbons Like alkynyl, and substituted by 1-13, preferably 1-7 halogen atoms.

作為C2 ～6 炔氧基，並無特別限定，例如可列舉：乙炔氧基、1-丙炔氧基、2-丙炔氧基、1-甲基-2-丙炔氧基、1-丁炔氧基、2-丁炔氧基、3-丁炔氧基等碳數2～6之直鏈狀或支鏈狀炔氧基。As the C 2 ~ 6 alkynyl group, it is not particularly limited, and examples thereof include: ethynyl group, 1-propynyloxy, 2-propynyloxy, 1-methyl-2-propynyloxy, 1 Linear or branched alkynyloxy groups having 2-6 carbon atoms such as butynyloxy, 2-butynyloxy and 3-butynyloxy.

作為C2 ～6 鹵炔氧基，並無特別限定，例如可列舉：3,3,3-三氟丙炔氧基、3,3-二氟丙炔氧基、3,3,3-三氟丁炔氧基、4,4,4-三氟-2-丁炔氧基、3,3-二氟-丁炔氧基等於任意之位置具有至少1個三鍵之碳數2～6之直鏈狀或支鏈狀炔氧基，且經1～13個、宜為1～7個鹵素原子取代之炔氧基。The C 2 to 6 haloalkynyloxy group is not particularly limited, and examples thereof include 3,3,3-trifluoropropynyloxy, 3,3-difluoropropynyloxy, 3,3,3-tri Fluorobutynyloxy, 4,4,4-trifluoro-2-butynyloxy, 3,3-difluoro-butynyloxy are equal to any position with at least one triple bond with carbon number 2-6 A linear or branched alkynyloxy group, which is substituted by 1-13, preferably 1-7, halogen atoms.

作為芳香環化合物，並無特別限定，例如可列舉：苯、萘、蒽等碳環化合物；吡啶、嘧啶、噠

Figure 107146792-A0304-12-0020-4
、吡
Figure 107146792-A0304-12-0020-4
、吡唑等雜環化合物等。The aromatic ring compound is not particularly limited, and examples include: carbocyclic compounds such as benzene, naphthalene, and anthracene; pyridine, pyrimidine, and pyridine
Figure 107146792-A0304-12-0020-4
Pyridine
Figure 107146792-A0304-12-0020-4
, Pyrazole and other heterocyclic compounds.

於前述通式(1)所表示之硝基苯酚化合物中，X宜為C-R'基。In the nitrophenol compound represented by the aforementioned general formula (1), X is preferably a C-R' group.

於前述通式(1)所表示之硝基苯酚化合物中，R宜為氫原子、鹵素原子、C1 ～6 烷基或C1 ～6 烷氧基，更宜為氫原子或甲氧基。In the nitrophenol compound represented by the aforementioned general formula (1), R is preferably a hydrogen atom, a halogen atom, a C 1 -6 alkyl group or a C 1 -6 alkoxy group, and more preferably a hydrogen atom or a methoxy group.

於前述通式(2)所表示之硝基苯酚化合物中，R1 宜為氫原子、鹵素原子、硝基、C1 ～6 烷基或C1 ～6 烷氧基，更宜為氫原子、硝基、或甲氧基。In the nitrophenol compound represented by the aforementioned general formula (2), R 1 is preferably a hydrogen atom, a halogen atom, a nitro group, a C 1 -6 alkyl group or a C 1 -6 alkoxy group, and more preferably a hydrogen atom, Nitro, or methoxy.

於前述通式(2)所表示之硝基苯酚化合物中，R2 宜為氫原子、鹵素原子、硝基、C1 ～6 烷基或C1 ～6 烷氧基，更宜為氫原子、硝基、或甲氧基。In the nitrophenol compound represented by the aforementioned general formula (2), R 2 is preferably a hydrogen atom, a halogen atom, a nitro group, a C 1 -6 alkyl group or a C 1 -6 alkoxy group, and more preferably a hydrogen atom, Nitro, or methoxy.

於前述通式(2)所表示之硝基苯酚化合物中，R3 宜為氫原子、鹵素原子、硝基、C1 ～6 烷基或C1 ～6 烷氧基，更宜為氫原子、硝基、或甲氧基。In the nitrophenol compound represented by the aforementioned general formula (2), R 3 is preferably a hydrogen atom, a halogen atom, a nitro group, a C 1 -6 alkyl group or a C 1 -6 alkoxy group, and more preferably a hydrogen atom, Nitro, or methoxy.

於前述通式(2)所表示之硝基苯酚化合物中，R4 宜為氫原子、鹵素原子、硝基、C1 ～6 烷基或C1 ～6 烷氧基，更宜為氫原子、硝基、或甲氧基。In the nitrophenol compound represented by the aforementioned general formula (2), R 4 is preferably a hydrogen atom, a halogen atom, a nitro group, a C 1 -6 alkyl group or a C 1 -6 alkoxy group, and more preferably a hydrogen atom, Nitro, or methoxy.

於前述通式(2)所表示之硝基苯酚化合物中，R5 宜為氫原子、鹵素原子、硝基、C1 ～6 烷基或C1 ～6 烷氧基，更宜為氫原子、硝基、或甲氧基。In the nitrophenol compound represented by the aforementioned general formula (2), R 5 is preferably a hydrogen atom, a halogen atom, a nitro group, a C 1 -6 alkyl group or a C 1 -6 alkoxy group, more preferably a hydrogen atom, Nitro, or methoxy.

又，其中，尤以4-硝基苯酚、4-硝基苯酚鈉鹽、3-硝基苯酚、3-硝基苯酚鈉鹽、2-硝基苯酚、2-硝基苯酚鈉鹽等硝基苯酚化合物或其鹽；5-硝基愈創木酚、5-硝基愈創木酚鈉鹽、4-硝基愈創木酚、4-硝基愈創木酚鈉鹽等愈創木酚(別名：鄰甲氧基苯酚(Guaiacol))化合物或其鹽為佳。In addition, among them, nitrophenol such as 4-nitrophenol, 4-nitrophenol sodium salt, 3-nitrophenol, 3-nitrophenol sodium salt, 2-nitrophenol, 2-nitrophenol sodium salt, etc. Phenol compound or its salt; 5-nitroguaiacol, 5-nitroguaiacol sodium salt, 4-nitroguaiacol, 4-nitroguaiacol sodium salt and other guaiacols (Alias: Guaiacol) compound or its salt is preferred.

本發明組成物中所含有之硝基苯酚化合物係公知化合物，可使用藉由市售品(ATONIK[註冊商標])或公知之製造方法所製造之化合物。關於其製造方法，例如記載於日本專利特開平10-67716。前述ATONIK係含有4-硝基苯酚(0.3%)、2-硝基苯酚(0.2%)及5-硝基愈創木酚(0.1%)之水溶液。The nitrophenol compound contained in the composition of the present invention is a known compound, and a compound manufactured by a commercially available product (ATONIK [registered trademark]) or a known manufacturing method can be used. The manufacturing method thereof is described in, for example, Japanese Patent Laid-Open No. 10-67716. The aforementioned ATONIK is an aqueous solution containing 4-nitrophenol (0.3%), 2-nitrophenol (0.2%) and 5-nitroguaiacol (0.1%).

作為本發明組成物所含有之殺菌活性化合物，只要為作為對於農業害蟲具有防除效果之化合物已知之化合物，則無特別限定。又，本發明組成物只要發揮本發明之效果，則亦可適當併用其他之殺蟲劑、殺蜱蟎劑、殺菌劑作為農藥原體。The bactericidal active compound contained in the composition of the present invention is not particularly limited as long as it is a compound known as a compound having a control effect on agricultural pests. In addition, as long as the composition of the present invention exerts the effects of the present invention, other insecticides, acaricides, and fungicides may be appropriately used in combination as the agrochemicals.

(B)殺菌活性化合物 作為(B)殺菌活性化合物，並無特別限定，例如可列舉：於基於FRAC(Fungicide Resistance Action Committee；殺菌劑抵抗性對策委員會)之作用分類中，屬於A(核酸合成)、B(有絲核分裂與細胞分裂)、C(呼吸)、D(胺基酸及蛋白質生物合成)、E(訊號傳遞)、F(脂質生物合成或輸送/細胞膜之結構或功能)、G(細胞膜之固醇生物合成)、H(細胞壁生物合成)、I(細胞壁之黑色素生物合成)、P(宿主植物之抵抗性誘導)、M(多作用位點接觸活性化合物)、U(作用機制不明)、未分類之化合物等。其中，宜為下述A群組、B群組、C群組、F群組、G群組、H群組、M群組、U群組，更宜為下述群組(A1)、群組(B1、2、3、B5)、群組(C2、C3、C4、C5、C8)、群組(F4、F9)、群組(G1)、群組(H5)、群組(M1、3、5)、及群組(U)。(B) bactericidal active compound The (B) bactericidal active compound is not particularly limited. For example, it can be listed as A (nucleic acid synthesis) and B (mitotic mitosis) in the function classification based on FRAC (Fungicide Resistance Action Committee; Fungicide Resistance Action Committee). And cell division), C (respiration), D (amino acid and protein biosynthesis), E (signal transmission), F (lipid biosynthesis or transport / structure or function of cell membrane), G (sterol biosynthesis of cell membrane) ), H (cell wall biosynthesis), I (cell wall melanin biosynthesis), P (host plant resistance induction), M (multiple action site contact active compound), U (unknown mechanism of action), unclassified compound Wait. Among them, it should be the following group A, B group, C group, F group, G group, H group, M group, U group, more preferably the following group (A1), group Group (B1, 2, 3, B5), group (C2, C3, C4, C5, C8), group (F4, F9), group (G1), group (H5), group (M1, 3, 5), and group (U).

＜A群組＞ 作為A群組(核酸合成)，例如可列舉：RNA聚合酶抑制劑(A1)、腺苷脫胺酶(adenosine deaminase)(A2)、DNA/RNA生物合成抑制劑(A3)、DNA拓樸異構酶(topoisomerase)(A4)等。＜Group A＞ As group A (nucleic acid synthesis), for example, RNA polymerase inhibitor (A1), adenosine deaminase (A2), DNA/RNA biosynthesis inhibitor (A3), DNA topology Topoisomerase (A4), etc.

RNA聚合酶抑制劑(A1) 作為RNA聚合酶抑制劑，例如可列舉：本達樂(benalaxyl)、右本達樂(benalaxyl-M)、呋霜靈(furalaxyl)、滅達樂(metalaxyl)、右滅達樂(metalaxyl-M)等醯基丙胺酸類；呋醯胺(ofurace)等丁內酯類；歐殺斯(oxadixyl)等

Figure 107146792-A0304-12-0015-1
唑啶酮類等。RNA polymerase inhibitors (A1) As RNA polymerase inhibitors, for example, benalaxyl, benalaxyl-M, furalaxyl, metalaxyl, metalaxyl, Metalaxyl-M and other alanines; ofurace and other butyrolactones; oxadixyl, etc.
Figure 107146792-A0304-12-0015-1
Oxazolidone and so on.

腺苷脫胺酶(A2) 作為腺苷脫胺酶，例如可列舉：福拉比(bupirimate)，二甲嘧酚(dimethirimol)、乙嘧酚(ethirimol)等羥基(2-胺基)嘧啶類等。Adenosine deaminase (A2) Examples of adenosine deaminase include bupirimate, hydroxy (2-amino) pyrimidines such as dimethirimol and ethirimol.

DNA/RNA生物合成抑制劑(A3) 作為DNA/RNA生物合成抑制劑，例如可列舉：

Figure 107146792-A0304-12-0015-1
黴靈(hymexazole)等異
Figure 107146792-A0304-12-0015-1
唑類、辛噻酮(octhilinone)等異二氫噻唑酮類等。DNA/RNA biosynthesis inhibitors (A3) As DNA/RNA biosynthesis inhibitors, for example:
Figure 107146792-A0304-12-0015-1
Hymexazole and other different
Figure 107146792-A0304-12-0015-1
Dihydrothiazolones such as azoles and octhilinone.

DNA拓樸異構酶(A4) 作為DNA拓樸異構酶，例如可列舉：歐索林酸(oxolinic acid)等羧酸類等。DNA topoisomerase (A4) Examples of DNA topoisomerases include carboxylic acids such as oxolinic acid.

＜B群組＞ 作為B群組(有絲核分裂與細胞分裂)，例如可列舉：β-微管蛋白聚合抑制劑(B1、2、3)、細胞分裂抑制劑(B4)、類血影蛋白蛋白質之非定域化劑(B5)、如囊泡運輸(vesicular transport)之肌動蛋白-肌球蛋白-絲束蛋白(actin-myosin-fimbrin)之功能之抑制劑(B6)等。<Group B> As group B (mitosis and cell division), for example, β-tubulin polymerization inhibitors (B1, 2, 3), cell division inhibitors (B4), non-localized spectrin-like proteins Inhibitors (B5), such as inhibitors (B6) of the function of actin-myosin-fimbrin of vesicular transport, etc.

β-微管蛋白聚合抑制劑(B1) 作為β-微管蛋白聚合抑制劑，例如可列舉：免賴得(benomyl)、麥穗靈(fuberidazole)、貝芬替(carbendazim)、涕必靈(thiabendazole)等苯并咪唑類；多保淨(thiophanate)、甲基多保淨(thiophanate-methyl)等多保淨類等。β-tubulin polymerization inhibitor (B1) Examples of β-tubulin polymerization inhibitors include: benomyl, fuberidazole, carbendazim, thiabendazole, and other benzimidazoles; (thiophanate), thiophanate-methyl, etc.

β-微管蛋白聚合抑制劑(B2) 作為β-微管蛋白聚合抑制劑，例如可列舉：乙黴威(diethofencarb)等N-苯基胺基甲酸酯類等。β-tubulin polymerization inhibitor (B2) Examples of β-tubulin polymerization inhibitors include N-phenyl carbamates such as diethofencarb.

β-微管蛋白聚合抑制劑(B3) 作為β-微管蛋白聚合抑制劑，例如可列舉：座賽胺(zoxamide)等甲苯醯胺類；噻唑菌胺(ethaboxam)等乙基胺基噻唑甲醯胺等。β-tubulin polymerization inhibitor (B3) Examples of β-tubulin polymerization inhibitors include toluamides such as zoxamide; ethylaminothiazolemethiamide such as ethaboxam.

細胞分裂抑制劑(B4) 作為細胞分裂抑制劑，例如可列舉：賓客隆(pencycuron)等苯基脲類等。Cell division inhibitor (B4) Examples of cell division inhibitors include phenylureas such as pencycuron and the like.

類血影蛋白蛋白質之非定域化劑(B5) 作為類血影蛋白蛋白質之非定域化劑，例如可列舉氟吡菌胺(fluopicolide)等吡啶基甲基苯甲醯胺類等。Spectrin-like protein delocalization agent (B5) As the delocalizing agent of spectrin-like proteins, for example, pyridylmethylbenzamides such as fluopicolide can be cited.

如囊泡運輸之肌動蛋白-肌球蛋白-絲束蛋白之功能之抑制劑(B6) 作為如囊泡運輸之肌動蛋白-肌球蛋白-絲束蛋白之功能之抑制劑，例如可列舉：氰烯菌酯(phenamacril)等丙烯酸胺基氰酯類；滅芬農(metrafenone)等二苯甲酮；苯啶菌酮(pyriofenone)等苯甲醯基吡啶等。Such as inhibitor of the function of actin-myosin-fibroin of vesicle transport (B6) As inhibitors of the function of actin-myosin-fibroin for vesicle transport, for example, cyanoacrylates such as phenamacril; two such as metrafenone Benzophenone; Pyriofenone and other benzylpyridines.

＜C群組＞ 作為C群組(呼吸)，例如可列舉：呼吸鏈複合體I(NADH氧化酶)抑制劑(C1)、呼吸鏈複合體II(琥珀酸脫氫酶)抑制劑(C2)、呼吸鏈複合體III(泛醌醇氧化酶、Qo位點)抑制劑(C3)、呼吸鏈複合體III(泛醌還原酶、Qi位點)抑制劑(C4)、氧化性磷酸化中之解偶聯劑(C5)、ATP合成中之氧化磷酸化之抑制劑(C6)、ATP生成抑制劑(C7)、呼吸鏈複合體III(泛醌還原酶、Qo位點)抑制劑(C8)等。<C Group> Examples of group C (respiration) include: respiratory chain complex I (NADH oxidase) inhibitor (C1), respiratory chain complex II (succinate dehydrogenase) inhibitor (C2), and respiratory chain complex III (ubiquinol oxidase, Qo site) inhibitor (C3), respiratory chain complex III (ubiquinone reductase, Qi site) inhibitor (C4), uncoupling agent in oxidative phosphorylation ( C5) Inhibitors of oxidative phosphorylation in ATP synthesis (C6), ATP production inhibitors (C7), respiratory chain complex III (ubiquinone reductase, Qo site) inhibitors (C8), etc.

呼吸鏈複合體I(NADH氧化酶)抑制劑(C1) 作為呼吸鏈複合體I(NADH氧化酶)抑制劑，例如可列舉：二氟林(diflumetorim)等嘧啶胺類；脫芬瑞(tolfenpyrad)等吡唑甲醯胺類；芬殺蟎(fenazaquin)等喹唑啉等。Respiratory chain complex I (NADH oxidase) inhibitor (C1) As respiratory chain complex I (NADH oxidase) inhibitors, for example, pyrimidinamines such as diflumetorim; pyrazole methamides such as tolfenpyrad; fenazaquin, etc. Quinazoline and others.

呼吸鏈複合體II(琥珀酸脫氫酶)抑制劑(C2) 作為呼吸鏈複合體II(琥珀酸脫氫酶)抑制劑，例如可列舉：麥鏽靈(benodanil)、福多寧(flutolanil)、滅普寧(mepronil)等苯基苯甲醯胺類；艾索非他滅(isofetamid)等苯基側氧乙基噻吩醯胺類；氟吡菌醯胺(fluopyram)等吡啶基乙基苯甲醯胺類；甲呋醯胺(fenfuram)等呋喃甲醯胺類；萎鏽靈(carboxin)、氧化萎鏽靈(oxicarboxin)等氧硫雜環己二烯甲醯胺(oxathiin carboxamide)類；賽氟滅(thifluzamide)等噻唑甲醯胺類；苯并烯氟菌唑(benzovindiflupyr)、必殺芬(bixafen)、氟茚唑菌胺(fluindapyr)、氟唑菌醯胺(fluxapyroxad)、福拉比(furametpyr)、吡唑萘菌胺(isopyrazam)、噴福芬(penflufen)、吡唑萘菌胺(isopyrazam)、氟唑環菌胺(sedaxane)等吡唑-4-甲醯胺類；吡唑醯胺類殺菌劑(isoflucypram)等N-環丙基-N-苄基吡唑甲醯胺類；氟唑菌醯羥胺(pydiflumetofen)等N-甲氧基(苯基乙基)吡唑甲醯胺類；白克列(boscalid)等吡啶甲醯胺類；吡

Figure 107146792-A0304-12-0020-4
醯胺類殺菌劑(pyraziflumide)等吡
Figure 107146792-A0304-12-0020-4
甲醯胺類等。Respiratory chain complex II (succinate dehydrogenase) inhibitor (C2) As respiratory chain complex II (succinate dehydrogenase) inhibitors, for example, benodanil and flutolanil , Mepronil and other phenylbenzamides; isofetamid and other phenyl pendant oxyethyl thiophene amides; fluopyram and other pyridyl ethyl benzyl Amides; furan carboxamides such as fenfuram; carboxin, oxicarboxin and other oxathiin carboxamides; race Thifluzamide and other thiazole carboxamides; benzovindiflupyr, bixafen, fluindapyr, fluxapyroxad, folabi ( Furametpyr), isopyrazam, penflufen, isopyrazam, sedaxane and other pyrazole-4-methamides; pyrazoles N-cyclopropyl-N-benzylpyrazole carbamides such as amine fungicides (isoflucypram); N-methoxy (phenylethyl) pyrazole carbamides such as pydiflumetofen Class; Boscalid and other picolinamides; Pyridine
Figure 107146792-A0304-12-0020-4
Pyraziflumide and other pyridines
Figure 107146792-A0304-12-0020-4
Formamides, etc.

呼吸鏈複合體III(泛醌醇氧化酶、Qo位點)抑制劑(C3) 作為呼吸鏈複合體III(泛醌醇氧化酶、Qo位點)抑制劑，例如可列舉：亞托敏(azoxystrobin)、啶氧菌酯(picoxystrobin)、烯肟菌酯(enoxastrobin)、唑菌酯(pyraoxystrobin)、丁香菌酯(coumoxystrobin)、氟菌蟎酯(flufenoxystrobin)等甲氧基丙烯酸酯類；Mandestrobin等甲氧基乙醯胺類；肟醚菌胺(orysastrobin)、醚菌胺(dimoxystrobin)、苯氧菌胺(metominostrobin)、烯肟菌胺(fenaminstrobin)等氧基亞胺基乙醯胺類；百克敏(pyraclostrobin)、唑胺菌酯(pyrametostrobin)、三環吡菌威(triclopyricarb)等甲氧基胺基甲酸酯類；克收欣(kresoxim-methyl)、三氟敏(trifloxystrobin)等氧基亞胺基乙酸類；吡菌苯威(pyribencarb)等苄基胺基甲酸酯類；凡殺同(famoxadone)等

Figure 107146792-A0304-12-0015-1
唑啶二酮(oxazolidinedione)類；咪唑菌酮(fenamidone)等咪唑啉酮類；氟嘧菌酯(fluoxastrobin)等二氫二
Figure 107146792-A0304-12-0015-1
Figure 107146792-A0304-12-0020-4
(dihydro dioxazine)類等。Respiratory chain complex III (ubiquinol oxidase, Qo site) inhibitor (C3) As the respiratory chain complex III (ubiquinol oxidase, Qo site) inhibitor, for example, azoxystrobin (azoxystrobin) ), picoxystrobin (picoxystrobin), enoxastrobin (enoxastrobin), pyraoxystrobin (pyraoxystrobin), coumoxystrobin (coumoxystrobin), flufenoxystrobin (flufenoxystrobin) and other methoxy acrylates; Mandestrobin etc. Oxyacetamides; orysastrobin, dimoxystrobin, metominostrobin, fenaminstrobin, and other oxyiminoacetamides; beacamine Methoxycarbamates such as pyraclostrobin, pyrametostrobin, and triclopyricarb; oxyimine such as kresoxim-methyl and trifloxystrobin Glycolic acid; pyribencarb and other benzyl carbamates; famoxadone, etc.
Figure 107146792-A0304-12-0015-1
Oxazolidinediones (oxazolidinedione); imidazolinones such as fenamidone; fluoxastrobin and other dihydrodihydrodiones
Figure 107146792-A0304-12-0015-1
Figure 107146792-A0304-12-0020-4
(dihydro dioxazine) etc.

呼吸鏈複合體III(泛醌還原酶、Qi位點)抑制劑(C4) 作為呼吸鏈複合體III(泛醌還原酶、Qi位點)抑制劑，例如可列舉：賽座滅(cyazofamid)等氰基咪唑；安美速(amisulbrom)等胺磺醯三唑；Fenpicoxamid等吡啶醯胺(picolinamide)類；富米綜(ferimzone)等。Respiratory chain complex III (ubiquinone reductase, Qi site) inhibitor (C4) As inhibitors of respiratory chain complex III (ubiquinone reductase, Qi site), for example, cyanimidazoles such as cyazofamid; sulfonamides such as amisulbrom; pyridinium such as fenpicoxamid Amines (picolinamide); ferimzone, etc.

氧化性磷酸化中之解偶聯劑(C5) 作為氧化性磷酸化中之解偶聯劑，例如可列舉：扶吉胺(fluazinam)等2,6-二硝基苯胺類；消蟎多(meptyl dinocap)、百蟎克(binapacryl)等二硝基苯基丁烯酸類；富米綜(ferimzone)等嘧啶酮腙類等。Uncoupling agent in oxidative phosphorylation (C5) As the uncoupling agent in oxidative phosphorylation, for example, 2,6-dinitroaniline such as fluazinam; dinitroaniline such as meptyl dinocap and binapacryl; Phenyl phenylbutenoic acids; Pyrimidine ketone hydrazones such as ferimzone.

ATP合成中之氧化磷酸化之抑制劑(C6) 作為ATP合成中之氧化磷酸化之抑制劑，例如可列舉：三苯醋錫(fentin acetate)、三苯氯錫(fentin chloride)、三苯羥錫(fentin hydroxide)等三苯基錫化合物等。Inhibitor of oxidative phosphorylation in ATP synthesis (C6) Examples of inhibitors of oxidative phosphorylation in ATP synthesis include triphenyl tin compounds such as fentin acetate, fentin chloride, and fentin hydroxide.

ATP生成抑制劑(C7) 作為ATP生成抑制劑，例如可列舉：矽硫芬(silthiofam)等噻吩甲醯胺類等。ATP production inhibitor (C7) As the ATP production inhibitor, for example, thienocarboxamides such as silthiofam and the like can be cited.

呼吸鏈複合體III(泛醌還原酶、Qo位點)抑制劑(C8) 作為呼吸鏈複合體III(泛醌還原酶、Qo位點)抑制劑，例如可列舉：辛唑嘧菌胺(ametoctradin)等三唑并嘧啶胺等。Respiratory chain complex III (ubiquinone reductase, Qo site) inhibitor (C8) Examples of respiratory chain complex III (ubiquinone reductase, Qo site) inhibitors include triazolopyrimidines such as ametoctradin.

＜D群組＞ 作為D群組(胺基酸及蛋白質生物合成)，例如可列舉：甲硫胺酸生物合成抑制劑(D1)、蛋白質合成抑制劑(D2、3、4、5)等。＜D group＞ Examples of group D (amino acid and protein biosynthesis) include methionine biosynthesis inhibitors (D1), protein synthesis inhibitors (D2, 3, 4, and 5).

甲硫胺酸生物合成抑制劑(D1) 作為甲硫胺酸生物合成抑制劑，例如可列舉：賽普洛(cyprodinil)、滅派林(mepanipyrim)、派美尼(pyrimethanil)等苯胺基嘧啶類等。Methionine biosynthesis inhibitor (D1) Examples of methionine biosynthesis inhibitors include anilinopyrimidines such as cyprodinil, mepanipyrim, and pyrimethanil.

蛋白質合成抑制劑(D2) 作為蛋白質合成抑制劑，例如可列舉：殺稻瘟菌素-S(blasticidin-S)等烯醇吡喃糖醛酸(enopyranuronic acid)抗生素等。Protein synthesis inhibitor (D2) Examples of protein synthesis inhibitors include enolpyranuronic acid antibiotics such as blasticidin-S (blasticidin-S).

蛋白質合成抑制劑(D3) 作為蛋白質合成抑制劑，例如可列舉：嘉賜黴素(kasugamycin)等六吡喃糖基(hexopyranosyl)抗生素等。Protein synthesis inhibitor (D3) Examples of protein synthesis inhibitors include hexopyranosyl antibiotics such as kasugamycin.

蛋白質合成抑制劑(D4) 作為蛋白質合成抑制劑，例如可列舉：鏈黴素(streptmycin)等吡喃葡萄糖抗生素等。Protein synthesis inhibitor (D4) Examples of protein synthesis inhibitors include glucopyranose antibiotics such as streptmycin.

蛋白質合成抑制劑(D5) 作為蛋白質合成抑制劑，例如可列舉：土黴素(oxytetracycline)等四環素抗生素。Protein synthesis inhibitor (D5) Examples of protein synthesis inhibitors include tetracycline antibiotics such as oxytetracycline.

＜E群組＞ 作為E群組(訊號傳遞)，例如可列舉：機制不明之訊號傳遞抑制劑(E1)、滲透壓訊號傳遞中之MAP・組胺酸激酶(os-2、HOG1)(E2)、滲透壓訊號傳遞中之MAP・組胺酸激酶抑制劑(os-1、Daf1)(E3)等。＜E group＞ Examples of group E (signal transmission) include: signal transmission inhibitors (E1) of unknown mechanism, MAP and histidine kinase (os-2, HOG1) (E2) in osmotic signal transmission, and osmotic pressure signals MAP and histidine kinase inhibitors (os-1, Daf1) (E3), etc. during delivery.

機制不明之訊號傳遞抑制劑(E1) 作為機制不明之訊號傳遞抑制劑，例如可列舉：快諾芬(quinoxyfen)等烯丙氧基喹啉；丙氧喹啉(proquinazid)等喹唑啉酮等。Signal transmission inhibitor of unknown mechanism (E1) Examples of signal transmission inhibitors with unknown mechanisms include allyloxyquinolines such as quinoxyfen; quinazolinones such as proquinazid.

滲透壓訊號傳遞中之MAP・組胺酸激酶(os-2、HOG1)(E2) 作為滲透壓訊號傳遞中之MAP・組胺酸激酶抑制劑(os-2、HOG1)，例如可列舉：拌種咯(fenpiclonil)、護汰寧(fludioxonil)等苯基吡咯類等。MAP and histidine kinase (os-2, HOG1) (E2) in osmotic signal transmission Examples of MAP·histidine kinase inhibitors (os-2, HOG1) in the transmission of osmotic pressure signals include phenylpyrroles such as fenpiclonil and fludioxonil.

滲透壓訊號傳遞中之MAP・組胺酸激酶抑制劑(os-1、Daf1)(E3) 作為滲透壓訊號傳遞中之MAP・組胺酸激酶抑制劑(os-1、Daf1)，例如可列舉：克氯得(chlozolinate)、撲滅寧(procymidone)、異菌脲(isoprodione)、免克寧(vinclozolin)、菌核淨(dimethachlone)等二羧醯亞胺類等。MAP and histidine kinase inhibitors (os-1, Daf1) (E3) in osmotic signal transmission As MAP and histidine kinase inhibitors (os-1, Daf1) in the transmission of osmotic pressure signals, for example, chlozolinate, procymidone, isoprodione, and mikenin (vinclozolin), dimethachlone (dimethachlone) and other dicarboxylic imines.

＜F群組＞ 作為F群組(脂質生物合成或傳輸/細胞膜之結構或功能)，例如可列舉：磷脂質生物合成之甲基轉移酶抑制劑(F2)、脂質之過氧化抑制劑(F3)、細胞膜滲透性之脂肪酸(F4)、病原菌細胞膜之微生物攪亂(F6)、細胞膜之攪亂劑(F7)、麥角固醇結合劑(F8)、脂質之恆定性、轉移、蓄積之抑制劑(F9)等。<F group> As group F (lipid biosynthesis or transport/structure or function of cell membrane), for example, methyltransferase inhibitors of phospholipid biosynthesis (F2), lipid peroxidation inhibitors (F3), cell membrane permeability The fatty acid (F4), the microbial disturbance of the cell membrane of pathogenic bacteria (F6), the disrupting agent of the cell membrane (F7), the ergosterol binder (F8), the inhibitor of lipid stability, transfer and accumulation (F9), etc.

磷脂質生物合成之甲基轉移酶抑制劑(F2) 作為磷脂質生物合成之甲基轉移酶抑制劑，例如可列舉：白粉松(pyrazophos)、護粒松(edifenphos)、丙基喜樂松(iprobenfos)等硫代磷酸酯類；亞賜圃(iso-prothiolane)等二硫戊環類等。Methyltransferase inhibitor of phospholipid biosynthesis (F2) As methyltransferase inhibitors for phospholipid biosynthesis, for example, phosphorothioates such as pyrazophos, edifenphos, iprobenfos, etc.; iso- prothiolane) and other dithiolanes.

脂質之過氧化抑制劑(F3) 作為脂質之過氧化抑制劑，例如可列舉：四氯硝基苯(tecnazen)、大克爛(dicloran)、五氯硝苯(quintozene)、聯苯(biphenyl)、脫克松(tolclofos-methyl)、地茂散(chloroneb)等芳香族烴；依得利(etridiazole)等1,2,4-噻二唑類等。Lipid peroxidation inhibitor (F3) Examples of lipid peroxidation inhibitors include: tecnazen, dicloran, quintozene, biphenyl, and tolclofos-methyl , Chloroneb and other aromatic hydrocarbons; etridiazole and other 1,2,4-thiadiazoles.

細胞膜滲透性之脂肪酸(F4) 作為細胞膜滲透性之脂肪酸，例如可列舉：胺丙威(prothiocarb)、3-碘-2-丙炔基-N-丁基胺基甲酸酯(iodocarb)、霜黴威(propamocarb)、霜黴威鹽酸鹽(propamocarb hydrochloride salt)等胺基甲酸酯類等。Cell membrane permeability fatty acids (F4) Examples of fatty acids for cell membrane permeability include: prothiocarb, 3-iodo-2-propynyl-N-butylcarbamate (iodocarb), propamocarb, and downy mildew Carbamates such as propamocarb hydrochloride salt.

病原菌細胞膜之微生物攪亂(F6) 作為病原菌細胞膜之微生物攪亂，例如可列舉：芽孢枯草桿菌(Bacillus amyloliquefaciens)(synonym Bacillus subtilis)菌株(strains)：QSR713 FZB24 MBI600 D747等芽孢桿菌屬(Bacillus屬)及產生之殺菌性脂肽(lipopeptide)類。Microbial disturbance of pathogen cell membrane (F6) Examples of microbial disturbances in the cell membrane of pathogenic bacteria include: Bacillus amyloliquefaciens (synonym Bacillus subtilis) strains: QSR713 FZB24 MBI600 D747 and other Bacillus species (Bacillus genus) and the produced bactericidal lipopeptide (lipopeptide) class.

細胞膜之攪亂劑(F7) 作為細胞膜之攪亂劑，例如可列舉：如丁香酚(eugenol)、香葉草醇(geraniol)、瑞香草酚(thymol)之類萜化合物、或包含該等化合物之植物萃取液、精油等萜烴類、萜醇類、及萜酚類等。Membrane Disruptor (F7) As a disrupting agent for cell membranes, for example, terpene compounds such as eugenol, geraniol, and thymol, or plant extracts containing these compounds, essential oils and other terpene hydrocarbons , Terpene alcohols, and terpene phenols.

麥角固醇結合劑(F8) 作為麥角固醇結合劑，例如可列舉：遊黴素(natamycin)等放射菌塔爾鏈黴菌(Streptomyces natalensis或S. chattanoogensis)所產生之兩性親媒巨環內酯系抗真菌性抗生素等。Ergosterol binder (F8) As the ergosterol binder, for example, an amphiphilic, amphiphilic macrolide antifungal antibiotic produced by the actinomycete Streptomyces natalensis (Streptomyces natalensis or S. chattanoogensis) such as natamycin and the like can be cited.

脂質之恆定性、轉移、蓄積之抑制劑(F9) 作為脂質之恆定性、轉移、蓄積之抑制劑，例如可列舉：噻哌菌靈(oxathiapiproline)等哌啶基噻唑異

Figure 107146792-A0304-12-0015-1
唑啉類等。Inhibitors of lipid constancy, transfer, and accumulation (F9) As inhibitors of lipid constancy, transfer, and accumulation, for example, piperidinyl thiazole isopropanol such as oxathiapiproline
Figure 107146792-A0304-12-0015-1
Oxazolines and so on.

＜G群組＞ 作為G群組(細胞膜之固醇生物合成)，例如可列舉：固醇生物合成中之C14位之去甲基化之抑制劑(G1)、固醇生物合成中之Δ14還原酶與Δ8→Δ7異構酶(G2)、C4位之去甲基化中之3-酮還原酶抑制劑(G3)、固醇生物合成中之角鯊烯環氧酶(squalene epoxidase)之抑制劑(G4)等。<G group> As G group (sterol biosynthesis of cell membrane), for example, C14 demethylation inhibitor (G1) in sterol biosynthesis, Δ14 reductase and Δ8→Δ7 in sterol biosynthesis Isomerase (G2), 3-ketoreductase inhibitor (G3) in demethylation of C4 position, inhibitor of squalene epoxidase (G4) in sterol biosynthesis, etc. .

固醇生物合成中之C14位之去甲基化之抑制劑(G1) 作為固醇生物合成中之C14位之去甲基化之抑制劑，例如可列舉：阿紮康唑(azaconazole)、比多農(bitertanol)、溴克座(bromuconazole)、環克座(cyproconazole)、待克利(difenoconazole)、達克利(diniconazole)、依普座(epoxiconazole)、乙環唑(etaconazole)、芬克座(fenbuconazole)、氟喹唑(fluquinconazole)、護矽得(flusilazole)、護汰芬(flutriafol)、菲克利(hexaconazole)、易胺座(imibenzonazole)、種菌唑(ipconazole)、滅特座(metconazole)、邁克尼(miclobutanil)、平克座(penconazole)、普克利(propiconazole)、矽氟唑(simeconazole)、得克利(tebuconazole)、四克利(tetraconazole)、三泰芬(triadimefon)、三泰隆(triadimenol)、滅菌唑(triticonazole)等三唑類；丙硫菌唑(prothioconazole)等三唑啉硫酮(triazolinethione)類；賽福寧(triforine)等哌

Figure 107146792-A0304-12-0020-4
類、比芬諾(pyrifenox)、啶菌噁唑(pyrisoxazole)等吡啶類；尼瑞莫(nuarimol)、芬瑞莫(fenarimol)等嘧啶類；依滅列(imazalil)、賽福座(triflumizole)、稻瘟酯(pefurazoate)、
Figure 107146792-A0304-12-0015-1
咪唑(oxpoconazole)、
Figure 107146792-A0304-12-0015-1
咪唑富馬酸鹽(oxpoconazole fumarate)、撲克拉(prochloraz)等咪唑類等。Inhibitors of C14 demethylation in sterol biosynthesis (G1) As inhibitors of C14 demethylation in sterol biosynthesis, examples include: azaconazole, ratio Bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, epoxiconazole, etaconazole, fencke fenbuconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, imibenzonazole, ipconazole, metconazole, Miclobutanil, penconazole, propiconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol , Triticonazole (triticonazole) and other triazoles; prothioconazole (triazolinethione) such as prothioconazole (triazolinethione); Saifen (triforine) and other piper
Figure 107146792-A0304-12-0020-4
Pyrimidines such as pyrifenox, pyrifenox and pyrisoxazole; pyrimidines such as nuarimol and fenarimol; imazalil, triflumizole , Pefurazoate,
Figure 107146792-A0304-12-0015-1
Imidazole (oxpoconazole),
Figure 107146792-A0304-12-0015-1
Imidazoles such as oxpoconazole fumarate and prochloraz.

固醇生物合成中之Δ14還原酶與Δ8→Δ7異構酶(G2) 作為固醇生物合成中之Δ14還原酶與Δ8→Δ7異構酶，例如可列舉：十二嗎啉(aldimorph)、芬普福(fenpropimorph)、三得芬(tridemorph)、嗎菌靈(dodemorph)等嗎啉類；苯鏽啶(fenpropidin)、粉病靈(piperalin)等哌啶類；葚孢菌素(spiroxamine)等螺縮酮胺類等。Δ14 reductase and Δ8→Δ7 isomerase (G2) in sterol biosynthesis Examples of Δ14 reductase and Δ8→Δ7 isomerase in sterol biosynthesis include: aldimorph, fenpropimorph, tridemorph, dodemorph Morpholines; piperidines such as fenpropidin and piperalin; spiroketal amines such as spiroxamine.

C4位之去甲基化中之3-酮還原酶抑制劑(G3) 作為C4位之去甲基化中之3-酮還原酶抑制劑，例如可列舉：環醯菌胺(fenhexamid)等羥基醯替苯胺類；胺苯吡菌酮(fenpyrazamine)等胺基吡唑酮(aminopyrazolinone)等。3-ketoreductase inhibitor (G3) in the demethylation of C4 Examples of 3-ketoreductase inhibitors in the demethylation of C4 position include: hydroxyanilides such as fenhexamid; and aminopyrazolones such as fenpyrazamine (aminopyrazolinone) and so on.

固醇生物合成中之角鯊烯環氧酶之抑制劑(G4) 作為固醇生物合成中之角鯊烯環氧酶之抑制劑，例如可列舉：萘替芬(naftifine)、特比萘芬(terbinafine)等硫代胺基甲酸酯類；稗草畏(pyributicarb)等硫代胺基甲酸酯類等。Inhibitor of squalene epoxidase in sterol biosynthesis (G4) As inhibitors of squalene epoxidase in sterol biosynthesis, for example, thiocarbamates such as naftifine and terbinafine; pyributicarb And other thiocarbamates.

＜H群組＞ 作為H群組(細胞壁生物合成)，例如可列舉：甲殼素生物合成抑制劑(H4)、纖維素合成抑制劑(H5)等。＜H group＞ Examples of group H (cell wall biosynthesis) include chitin biosynthesis inhibitors (H4), cellulose synthesis inhibitors (H5), and the like.

甲殼素生物合成抑制劑(H4) 作為甲殼素生物合成抑制劑，例如可列舉：多氧菌素B(polyoxine B)等肽基嘧啶核苷(peptidyl pyrimidine nucleoside)等。Chitin biosynthesis inhibitor (H4) Examples of chitin biosynthesis inhibitors include peptidyl pyrimidine nucleoside such as polyoxine B and the like.

纖維素合成抑制劑(H5) 作為纖維素合成抑制劑，例如可列舉：達滅芬(dimethomorph)、氟嗎啉(flumorph)、丁吡嗎啉(pyrimorph)等桂皮酸醯胺類；曼普胺(mandipropamide)等苦杏仁酸醯胺類；纈黴威(iprovalicarb)、苯噻菌胺(benthiavalicarb)、纈菌胺(valifenalate)等纈胺醯胺胺基甲酸酯類等。Cellulose Synthesis Inhibitor (H5) Examples of cellulose synthesis inhibitors include cinnamic acid amides such as dimethomorph, flumorph, and pyrimorph; mandelic acid such as mandipropamide Amines; Valinyl carbamates such as iprovalicarb, benthiavalicarb, and valifenalate.

＜I群組＞ 作為I群組(細胞壁之黑色素生物合成)，例如可列舉：黑色素生物合成中之還原酶抑制劑(I1)、黑色素生物合成中之脫水酶抑制(I2)、黑色素生物合成中之聚酮化合物合成抑制(I3)等。＜I group＞ As group I (melanin biosynthesis of cell wall), for example, reductase inhibitors in melanin biosynthesis (I1), dehydratase inhibition in melanin biosynthesis (I2), and polyketide synthesis in melanin biosynthesis Inhibition (I3) and so on.

黑色素生物合成中之還原酶抑制劑(I1) 作為黑色素生物合成中之還原酶抑制劑，例如可列舉：四氯苯酞(fthalide)等異苯并呋喃酮；百快隆(pyroquilon)等吡咯并喹啉；三賽唑(tricyclazole)等三唑苯并噻唑等。Reductase inhibitor in melanin biosynthesis (I1) Examples of reductase inhibitors in melanin biosynthesis include: isobenzofuranone such as tetrachlorophthalide; pyrroloquinoline such as pyroquilon; triazole such as tricyclazole Benzothiazole and others.

黑色素生物合成中之脫水酶抑制(I2) 作為黑色素生物合成中之脫水酶抑制，例如可列舉：二氯西莫(diclocymet)等甲醯胺；加普胺(carpropamid)等環丙基甲醯胺；芬諾尼(fenoxanil)等丙醯胺等。Inhibition of dehydratase in melanin biosynthesis (I2) Examples of dehydratase inhibition in melanin biosynthesis include: diclocymet and other formamides; carpropamid and other cyclopropylformamides; and fenoxanil and other acetamides Wait.

黑色素生物合成中之聚酮化合物合成抑制劑(I3) 作為黑色素生物合成中之聚酮化合物合成抑制劑，例如可列舉托普洛卡(tolprocarb)等胺基甲酸三氟乙酯等。Polyketide synthesis inhibitor in melanin biosynthesis (I3) Examples of polyketide synthesis inhibitors in melanin biosynthesis include trifluoroethyl carbamate such as tolprocarb.

＜M群組＞ 以多作用位點為目標之化合物(M) 作為以多作用位點為目標之化合物(M)，例如可列舉：銅化合物(M1)、硫磺系化合物(M2)、二硫代胺基甲酸酯系化合物及其關聯化合物(M3)、鄰苯二甲醯亞胺系化合物(M4)、氯腈系化合物(M5)、磺醯胺系化合物(M6)、雙胍系化合物(M7)、三

Figure 107146792-A0304-12-0020-4
系化合物(M8)、蒽醌系化合物(M9)、喹
Figure 107146792-A0304-12-0015-1
啉系化合物(M10)、馬來醯亞胺系化合物(M11)等。作為以多作用位點為目標之化合物(M)，宜為M1、M3及M5。<M group> Compounds (M) targeting multiple sites of action As compounds (M) targeting multiple sites of action, for example, copper compounds (M1), sulfur compounds (M2), and disulfides can be cited Carbamate compounds and related compounds (M3), phthalimide compounds (M4), chloronitrile compounds (M5), sulfonamide compounds (M6), biguanide compounds ( M7), three
Figure 107146792-A0304-12-0020-4
Series compound (M8), anthraquinone series compound (M9), quinone
Figure 107146792-A0304-12-0015-1
The morpholine compound (M10), the maleimine compound (M11), and the like. As the compound (M) targeting multiple sites of action, M1, M3, and M5 are preferable.

銅化合物(M1) 作為銅化合物，例如可列舉：DBEDC(胺磺銅)、鹼性氯化銅(copper oxychloride)、鹼性硫酸銅(copper sulfate)、氫氧化銅(copper hydroxide)、壬基苯酚磺酸銅(copper nonylphenol sulfonate)等無機化合物(不包括硫磺)等。Copper compound (M1) Examples of copper compounds include: DBEDC (copper sulfonate), alkaline copper chloride (copper oxychloride), alkaline copper sulfate (copper sulfate), copper hydroxide (copper hydroxide), copper nonylphenol sulfonate (copper Nonylphenol sulfonate) and other inorganic compounds (excluding sulfur), etc.

硫磺系化合物(M2) 作為硫磺系化合物，如可列舉：硫磺(sulpher)、石灰硫磺合劑(lime sulfur)等無機化合物(不包括銅)等。Sulfur compounds (M2) Examples of sulfur-based compounds include inorganic compounds (excluding copper) such as sulpher and lime sulfur.

二硫代胺基甲酸酯系化合物及其相關化合物(M3) 作為二硫代胺基甲酸酯系化合物及其相關化合物，例如可列舉：福美鐵(ferbam)、免得爛(metiram)、得恩地(thiram)、鋅錳乃浦(mancozeb)、甲基鋅乃浦(propineb)、鋅乃浦(zineb)、鋅噻唑(zinc thiazole)、錳乃浦(maneb)、福美鋅(ziram)等二硫代胺基甲酸酯類及類似體等。Dithiocarbamate compounds and related compounds (M3) As dithiocarbamate-based compounds and related compounds, for example, ferbam, metiram, thiram, mancozeb, methyl zincate Dithiocarbamates such as propineb, zineb, zinc thiazole, maneb, and ziram and the like.

鄰苯二甲醯亞胺系化合物(M4) 作為鄰苯二甲醯亞胺系化合物，例如可列舉：蓋普丹(captan)、四氯丹(captafol)、福爾培(folpet)等鄰苯二甲醯亞胺類等。Phthalic acid imine compounds (M4) Examples of the phthalimide-based compound include phthalimides such as captan, captafol, and folpet.

氯腈系化合物(M5) 作為氯腈系化合物，例如可列舉：四氯異苯(chlorothalonil)等氯腈類(鄰苯二腈類)等。Chloronitrile compounds (M5) Examples of the chloronitrile compound include chloronitriles (phthalonitriles) such as chlorothalonil and the like.

磺醯胺系化合物(M6) 作為磺醯胺系化合物，例如可列舉：益發靈(dichlofluanid)、託福寧(tolylfluanid)等磺醯胺類等。Sulfonamide compounds (M6) Examples of sulfonamide-based compounds include sulfonamides such as dichlofluanid and tolylfluanid.

雙胍系化合物(M7) 作為雙胍系化合物，例如可列舉：雙胍鹽(guazatine)、克熱淨(iminoctadine)等雙胍類等。Biguanide compounds (M7) Examples of the biguanide-based compound include biguanide such as guazatine and iminoctadine.

三

Figure 107146792-A0304-12-0020-4
系化合物(M8) 作為三
Figure 107146792-A0304-12-0020-4
系化合物，例如可列舉：敵菌靈(anilazine)等三
Figure 107146792-A0304-12-0020-4
類等。three
Figure 107146792-A0304-12-0020-4
Series compound (M8) as three
Figure 107146792-A0304-12-0020-4
Series compounds, for example, anilazine (anilazine) and other three
Figure 107146792-A0304-12-0020-4
Class etc.

蒽醌系化合物(M9) 作為蒽醌系化合物，例如可列舉：腈硫醌(dithianon)等醌類(蒽醌類)等。Anthraquinone compounds (M9) Examples of anthraquinone compounds include quinones (anthraquinones) such as dithianon.

喹

Figure 107146792-A0304-12-0015-1
啉系化合物(M10) 作為喹
Figure 107146792-A0304-12-0015-1
啉系化合物，例如可列舉：滅蟎猛(chinomethionat)、甲基克殺蟎(quinomethionate)等喹
Figure 107146792-A0304-12-0015-1
啉類等。Quinine
Figure 107146792-A0304-12-0015-1
Morinoline compound (M10) as quinone
Figure 107146792-A0304-12-0015-1
The morpholine compound, for example, quinones such as chinomethionat and quinomethionate
Figure 107146792-A0304-12-0015-1
Phyrins and so on.

馬來醯亞胺系化合物(M11) 作為馬來醯亞胺系化合物，例如可列舉：氟醯亞胺(fluoroimide)等馬來醯亞胺系化合物(M11)等。Maleimide compounds (M11) Examples of the maleimide compound include maleimide compounds (M11) such as fluoroimide and the like.

馬來醯亞胺系化合物(M12) 作為硫代胺基甲酸酯化合物，例如可列舉：滅速克(methasulfocarb)等硫代胺基甲酸酯等。Maleimide compound (M12) As a thiocarbamate compound, a thiocarbamate, such as methasulfocarb, etc. are mentioned, for example.

＜P群組＞ 作為P群組(宿主植物之抵抗性誘導劑)，例如可列舉：刺激水楊酸路徑之抵抗性誘導劑(P1)、宿主植物之抵抗性誘導劑(P2、3、4)、誘導宿主植物之抵抗性之植物萃取液(P5)、誘導宿主植物之抵抗性之微生物及微生物製劑(P6)等。<P group> As the P group (resistance inducers of host plants), for example, resistance inducers (P1) that stimulate the salicylic acid pathway, resistance inducers of host plants (P2, 3, 4), and host plants are induced The resistant plant extracts (P5), microorganisms and microbial preparations (P6) that induce host plant resistance, etc.

刺激水楊酸路徑之抵抗性誘導劑(P1) 作為刺進水楊酸路徑之抵抗性誘導劑(水楊酸訊號傳遞)，例如可列舉：阿拉酸式苯-S-甲基(acibenzolar-S-methyl)等苯并噻二唑BTH等。Resistance inducer to stimulate the salicylic acid pathway (P1) As a resistance inducer (salicylic acid signal transmission) that penetrates the salicylic acid pathway, for example, benzothiadiazole BTH such as acibenzolar-S-methyl can be cited.

宿主植物之抵抗性誘導劑(P2) 作為宿主植物之抵抗性誘導劑(水楊酸訊號傳遞)，例如可列舉：撲殺熱(probenazole)等苯并異噻唑等。Host plant resistance inducer (P2) As resistance inducers (salicylic acid signal transmission) of host plants, for example, benzisothiazoles such as probenazole and the like can be cited.

宿主植物之抵抗性誘導劑(P3) 作為宿主植物之抵抗性誘導劑(水楊酸訊號傳遞)，例如可列舉：異噻菌胺(isothianil)、噻醯菌胺(thiadinil)等噻二唑甲醯胺等。Host plant resistance inducer (P3) As resistance inducers (salicylic acid signal transmission) of host plants, for example, thiadiazole methamide such as isothianil and thiadinil can be cited.

宿主植物之抵抗性誘導劑(P4) 作為宿主植物之抵抗性誘導劑(多糖類誘導子(elicitor)、天然物)，例如可列舉：昆布醣(laminarin)等多糖類等。Host plant resistance inducer (P4) Examples of host plant resistance inducers (polysaccharide elicitor (elicitor), natural products) include polysaccharides such as laminarin and the like.

誘導宿主植物之抵抗性之植物萃取液(P5) 誘導宿主植物之抵抗性之植物萃取液(蒽醌誘導子、植物萃取物)，例如可列舉：如大虎杖(Reynoutria sachalinensis)(虎杖(Giant knotweed))之虎杖屬(大虎杖)植物之萃取液、精油等。Plant extract that induces host plant resistance (P5) Plant extracts (anthraquinone elicitors, plant extracts) that induce the resistance of host plants, for example: extracts of plants of the genus Polygonum cuspidatum (Reynoutria sachalinensis) (Giant knotweed) , Essential oils, etc.

誘導宿主植物之抵抗性之微生物及微生物製劑(P6) 作為誘導宿主植物之抵抗性之微生物及微生物製劑(微生物誘導子、微生物)，例如可列舉：蕈狀桿菌(Bacillus mycoides)或其製劑等臘狀桿菌(Bacillus cereus)等。Microorganisms and microbial agents that induce host plant resistance (P6) Examples of microorganisms and microorganism preparations (microorganism inducers, microorganisms) that induce the resistance of host plants include Bacillus cereus such as Bacillus mycoides or preparations thereof.

宿主植物之抵抗性誘導劑(P7) 作為宿主植物之抵抗性誘導劑(膦酸酯)，例如可列舉：疫黴靈(fosetyl)、福賽得 (fosetyl-al)等乙基膦酸鹽類；亞磷酸(phosphorous acid)、亞磷酸鹽等。Host plant resistance inducer (P7) As resistance inducers (phosphonates) of host plants, for example, ethyl phosphonates such as fosetyl and fosetyl-al; phosphorous acid and phosphorous acid Salt etc.

此外，作用機制不明之化合物(群組：Unknown mode of action)(U) 此外，作為作用機制不明之化合物(群組：Unknown mode of action)，可列舉：克絕(cymoxanil)等氰基乙醯胺肟；克枯爛(teclofthalam)等鄰苯二甲酸(phthalamic acid)類；環氟菌胺(cyflufenamide)等苯基乙醯胺；氟噻唑菌腈(fluthianil)等氰基亞甲基噻唑啶；特弗喹啉(tebufloquin)等乙酸4-喹啉；維利黴素(validamycin)等吡喃葡萄糖抗生素；咪唑

Figure 107146792-A0304-12-0020-4
(triazoxide)等苯并三
Figure 107146792-A0304-12-0020-4
類；氟硫滅(flusulfamide)等苯磺醯胺類；達滅淨(diclomezine)等噠
Figure 107146792-A0304-12-0020-4
酮(pyridazinone)類；多果定(dodine)等胍類；picarbutrazox等四唑基肟等。In addition, compounds with unknown mechanism of action (group: Unknown mode of action) (U) In addition, as compounds with unknown mechanism of action (group: Unknown mode of action), cyanoacetone such as cymoxanil may be mentioned. Amidoxime; phthalamic acid such as teclofthalam; phenylacetamide such as cyflufenamide; cyanomethylene thiazolidine such as fluthianil; 4-quinoline acetate such as tebufloquin; glucopyranose antibiotics such as validamycin; imidazole
Figure 107146792-A0304-12-0020-4
(triazoxide) and other benzotriazole
Figure 107146792-A0304-12-0020-4
Class; flusulfamide and other benzenesulfonamides; diclomezine, etc.
Figure 107146792-A0304-12-0020-4
Ketones (pyridazinone); dodine and other guanidines; picarbutrazox and other tetrazolyl oximes.

其中，更宜之殺菌劑為滅達樂、右滅達樂、白克列、百克敏、亞托敏、三氟敏、克收欣、啶氧菌酯、賽座滅、凡殺同、辛唑嘧菌胺、扶吉胺、四克利、富馬酸

Figure 107146792-A0304-12-0015-1
咪唑、護汰芬、四氯異苯、鋅錳乃浦、達滅芬、曼普胺、噻唑菌胺、氟吡菌胺、霜黴威鹽酸鹽、福賽得、亞磷酸或其鹽、噻哌菌靈、壬基苯酚磺酸銅鹽及克絕。Among them, the more suitable bactericides are metalox, dexmetalol, beclet, beacamine, ytomin, trifluramine, ketoxin, picoxystrobin, phenoxystrobin, phenoxystrobin, and Xin Pyraclostrobin, fugemide, tetraclimate, fumaric acid
Figure 107146792-A0304-12-0015-1
Imidazole, Hutaifen, Tetrachloroisophenyl, Zinc Manganese Naipur, Dametifene, Manpromide, Thiazolamide, Fluopyram, Propamocarb Hydrochloride, Fosaide, Phosphorous Acid or Its Salts, Thiiperbendazole, copper salt of nonylphenol sulfonate, and extinction.

本發明中，必須將硝基苯酚化合物與殺菌活性化合物之任一種以上進行併用。藉由將硝基苯酚化合物與殺菌活性化合物進行併用，而對於農園藝病原菌顯現出顯著之防除效果。所謂協同性殺菌劑組成物，係指具有協同性防除效果(協同效應)之殺菌劑組成物。In the present invention, any one or more of the nitrophenol compound and the bactericidal active compound must be used in combination. The combined use of nitrophenol compounds and bactericidal active compounds shows a significant control effect on agricultural and horticultural pathogens. The so-called synergistic bactericide composition refers to a bactericide composition with a synergistic control effect (synergistic effect).

於本發明中，相對於通式(1)之硝基苯酚化合物100重量份，摻合殺菌活性化合通常0.1～20000重量份、宜為1～10000重量份、更宜為5～5000重量份。In the present invention, with respect to 100 parts by weight of the nitrophenol compound of the general formula (1), the blending of the bactericidal active compound is usually 0.1 to 20000 parts by weight, preferably 1 to 10000 parts by weight, and more preferably 5 to 5000 parts by weight.

於本發明組成物中，可不添加其他成分而僅摻合硝基苯酚化合物與殺菌活性化合物，但通常可混合固體載體、液體載體、氣體狀載體(噴射劑)，且視需要添加界面活性劑、其他之製劑用助劑，依據通常之製劑化方法製劑成油劑、乳劑、水合劑、懸浮劑、粒劑、粉劑、霧劑、煙霧劑等而使用。In the composition of the present invention, only nitrophenol compound and bactericidal active compound can be blended without adding other ingredients, but usually solid carrier, liquid carrier, gaseous carrier (propellant) can be mixed, and surfactants, Other preparation auxiliaries are formulated into oils, emulsions, hydrations, suspensions, granules, powders, mists, aerosols, etc. according to the usual preparation methods.

於該等製劑中，通常可含有通常以重量比計0.01～95重量%、宜為0.1～50重量%之作為有效成分之硝基苯酚化合物及殺菌活性化合物之合計量。These preparations usually contain 0.01-95% by weight, preferably 0.1-50% by weight, of the total amount of the nitrophenol compound and the bactericidal active compound as the active ingredient.

作為製劑化時所使用之固體載體，例如可列舉：黏土類(高嶺黏土、矽藻土、合成含水氧化矽、膨潤土、Fubasami黏土、酸性白土等)、滑石類、陶瓷、其他之無機礦物(矽藻土、石英、硫磺、活性碳、碳酸鈣、水合二氧化矽等)、化學肥料(硫酸銨、磷酸銨、硝酸銨、尿素、氯化銨(muriate)等)等微粉末或粒狀物等。Examples of solid carriers used for formulation include clays (kaolin clay, diatomaceous earth, synthetic hydrous silica, bentonite, Fubasami clay, acid clay, etc.), talc, ceramics, and other inorganic minerals (silica Algae earth, quartz, sulfur, activated carbon, calcium carbonate, hydrated silica, etc.), chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride (muriate), etc.) and other fine powder or granular materials, etc. .

作為液體載體，例如可列舉：水、醇類(甲醇、乙醇等)、酮類(丙酮、甲基乙基酮等)、芳香族烴類(苯、甲苯、二甲苯、乙基苯、甲基萘等)、脂肪族烴類(己烷、環己烷、煤油、柴油等)、酯類(乙酸乙酯、乙酸丁酯等)、腈類(乙腈、異丁腈等)、醚類(二異丙醚、二噁烷等)、醯胺類(N,N-二甲基甲醯胺、N,N-二甲基乙醯胺等)、鹵化烴類(二氯甲烷、三氯乙烷、四氯化碳等)、二甲基亞碸、大豆油、棉籽油等植物油等。As the liquid carrier, for example, water, alcohols (methanol, ethanol, etc.), ketones (acetone, methyl ethyl ketone, etc.), aromatic hydrocarbons (benzene, toluene, xylene, ethylbenzene, methyl Naphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, kerosene, diesel, etc.), esters (ethyl acetate, butyl acetate, etc.), nitriles (acetonitrile, isobutyronitrile, etc.), ethers (two Isopropyl ether, dioxane, etc.), amides (N,N-dimethylformamide, N,N-dimethylacetamide, etc.), halogenated hydrocarbons (dichloromethane, trichloroethane, etc.) , Carbon tetrachloride, etc.), dimethyl sulfide, soybean oil, cottonseed oil and other vegetable oils.

作為氣體狀載體，例如可列舉：丁烷氣體、LPG(液化石油氣體)、二甲醚、二氧化碳氣體等。Examples of the gaseous carrier include butane gas, LPG (liquefied petroleum gas), dimethyl ether, and carbon dioxide gas.

作為界面活性劑，例如可列舉：烷基硫酸酯類、烷磺酸鹽、烷基芳基磺酸鹽、烷基芳基醚類及其聚氧乙烯化物、聚伸乙基二醇醚類、多元醇酯類、糖醇衍生物等。As surfactants, for example, alkyl sulfates, alkane sulfonates, alkyl aryl sulfonates, alkyl aryl ethers and their polyoxyethylene products, polyethylene glycol ethers, Polyol esters, sugar alcohol derivatives, etc.

作為製劑用助劑，例如可列舉：固著劑、分散劑、穩定劑等。Examples of auxiliary agents for formulations include fixing agents, dispersants, stabilizers, and the like.

作為固著劑及/或分散劑，例如可列舉：酪蛋白、明膠、多糖類(澱粉、阿拉伯膠、纖維素衍生物、海藻酸等)、木質素衍生物、膨潤土、糖類、合成水溶性高分子(聚乙烯醇、聚乙烯吡咯啶酮、聚丙烯酸類等)。作為穩定劑，例如可列舉：PAP(酸性磷酸異丙酯)、BHT(2,6-二-第三丁基-4-甲基苯酚)、BHA(2-第三丁基-4-甲氧基苯酚與3-第三丁基-4-甲氧基苯酚之混合物)、植物油、礦物油、脂肪酸或其酯等。Examples of fixing and/or dispersing agents include: casein, gelatin, polysaccharides (starch, acacia, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonite, sugars, synthetic high water solubility Molecules (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, etc.). Examples of stabilizers include PAP (acid isopropyl phosphate), BHT (2,6-di-tert-butyl-4-methylphenol), BHA (2-tert-butyl-4-methoxy Phenol and 3-tert-butyl-4-methoxyphenol), vegetable oil, mineral oil, fatty acid or its ester, etc.

本發明之殺菌劑可直接使用或利用水等進行稀釋而使用。又，亦可與其他殺蟲劑、殺線蟲劑、殺蜱蟎劑、殺菌劑、除草劑、植物生長調節劑、協力劑、土壌改良劑、動物用飼料等進行混合，或者不混合而同時使用。The bactericide of the present invention can be used directly or diluted with water or the like. In addition, it can also be mixed with other insecticides, nematicides, acaricides, fungicides, herbicides, plant growth regulators, synergists, soil conditioners, animal feed, etc., or used at the same time without mixing .

於使用本發明組成物作為農業用殺菌劑之情形時，其施用量通常每1000m2 為0.1g～500g、宜為1～100g。於將乳劑、水合劑、懸浮劑等形態之本發明協同性殺菌劑組成物利用水稀釋而使用之情形時，其施用濃度通常為1～1000ppm、宜為10～500ppm，粒劑、粉劑等不進行任何稀釋而以製劑之狀態直接施用。更具體而言，硝基苯酚化合物之施用濃度可通常為0.5～800ppm左右、宜為12.5～400ppm左右、更宜為100～200ppm左右，殺菌活性化合物之施用濃度可通常為0.1～200ppm左右、宜為0.1～50ppm左右、更宜為0.4～20ppm左右。When using the composition of the present invention as an agricultural fungicide, the application amount is usually 0.1 g to 500 g, preferably 1 to 100 g per 1000 m 2 . When the synergistic bactericide composition of the present invention in the form of emulsion, hydrating agent, suspension, etc. is diluted with water and used, the application concentration is usually 1 to 1000 ppm, preferably 10 to 500 ppm, and granules, powders, etc. Make any dilution and apply directly in the state of preparation. More specifically, the application concentration of the nitrophenol compound may usually be about 0.5-800 ppm, preferably about 12.5-400 ppm, more preferably about 100-200 ppm, and the application concentration of the bactericidal active compound may usually be about 0.1-200 ppm. It is about 0.1-50 ppm, more preferably about 0.4-20 ppm.

該等之施用量、施用濃度均視製劑之種類、施用時期、施用場所、施用方法、害蟲之種類、被害程度等狀況而不同，可不限定於前述範圍而增加或者減少。The application amount and application concentration vary depending on the type of formulation, application period, application place, application method, type of pests, degree of damage, and other conditions, and may be increased or decreased without being limited to the aforementioned range.

對使本發明之協同性殺菌劑組成物含有硝基苯酚化合物與殺菌活性化合物並使用其之情況進行了說明，但亦可預先製備將硝基苯酚化合物與殺菌活性化合物分開含有之組成物，於防除農園藝病原菌時將該等2種組成物依序或同時使用，宜為同時使用。於該情形時，硝基苯酚化合物及殺菌活性化合物可以與前述相同之比例併用。The case where the synergistic bactericide composition of the present invention contains a nitrophenol compound and a bactericidal active compound and uses them has been described, but a composition that separately contains the nitrophenol compound and the bactericidal active compound can also be prepared in advance. When controlling agricultural and horticultural pathogens, these two compositions are used in sequence or at the same time, preferably at the same time. In this case, the nitrophenol compound and the bactericidal active compound can be used in combination in the same ratio as described above.

本發明之協同性殺菌劑組成物可藉由施用形態來防除由真菌類、真細菌(eubacteria)類、及植物病毒類引起之植物之病害。The synergistic bactericide composition of the present invention can prevent and control plant diseases caused by fungi, eubacteria, and plant viruses through application forms.

作為本發明之協同性殺菌劑組成物可防除之真細菌類，例如可列舉屬於以下之屬之病原菌。Examples of the eubacteria that can be controlled by the synergistic bactericide composition of the present invention include pathogenic bacteria belonging to the following genera.

可列舉：伯克氏菌(Burkholderia)屬菌、例如 稻穀枯細菌病(Burkholderia gladioli)、 稻苗立枯細菌病(Burkholderia plantarii)； 伊文氏桿菌(Erwinia)屬菌、例如 蘿蔔軟腐病(Erwinia carotovora spp. carotovora)； 假單胞菌(Pseudomonas)屬菌、例如 黃瓜斑點細菌病(Pseudomonas syringae pv. lachrymans)、 蘿蔔黑斑細菌病(Pseudomonas syringae pv. maculicola)、 白菜黑斑細菌病(Pseudomonas cannabina pv. alisalensis)、 萵苣腐敗病(Pseudomonas cichorii)、 菊花斑點細菌病(Pseudomonas cichorii)； 黃單胞桿菌(Xanthomonas)屬菌、例如 捲心菜黑腐病(Xanthomonas campestris pv. campestris)、 稻白葉枯病(Xanthomonas oryzae pv. oryzae)、 柑橘潰瘍病(Xanthomonas citri supsp. citri)； 雷氏菌(Ralstonia)屬菌、例如 茄科蔬菜青枯病(Ralstonia solanacearum)； 食酸菌(Acidovorax)屬菌、例如 西瓜果實污斑細菌病(Acidovorax avenae spp. citrulli)、 稻褐條病(Acidovorax avenae spp. avenae)； 布倫勒氏菌(Brenneria)屬菌、例如 桃穿孔細菌病(Brenneria nigrifluens); 棒形桿菌(Clavibacter)屬菌、例如 番茄潰瘍病(Clavibacter michiganensis spp. michiganensis); 鏈黴菌(Streptomyces)屬菌、例如 馬鈴薯瘡痂病(Streptomyces scabies) 等。Examples include: Burkholderia (Burkholderia) bacteria, such as Rice blight bacterial disease (Burkholderia gladioli), Burkholderia plantarii of rice seedlings; Erwinia bacteria, such as Turnip soft rot (Erwinia carotovora spp. carotovora); Pseudomonas (Pseudomonas) bacteria, such as Cucumber spot bacterial disease (Pseudomonas syringae pv. lachrymans), Radish black spot bacterial disease (Pseudomonas syringae pv. maculicola), Pseudomonas cannabina pv. alisalensis, Lettuce spoilage (Pseudomonas cichorii), Chrysanthemum spot bacterial disease (Pseudomonas cichorii); Xanthomonas bacteria, such as Cabbage black rot (Xanthomonas campestris pv. campestris), Rice bacterial blight (Xanthomonas oryzae pv. oryzae), Citrus canker (Xanthomonas citri supsp. citri); Ralstonia bacteria, such as Solanaceous vegetable bacterial wilt (Ralstonia solanacearum); Acidovorax bacteria, such as Watermelon fruit stain bacterial disease (Acidovorax avenae spp. citrulli), Rice brown streak disease (Acidovorax avenae spp. avenae); Brenneria bacteria, such as Peach perforation bacterial disease (Brenneria nigrifluens); Clavibacter bacteria, such as Tomato canker (Clavibacter michiganensis spp. michiganensis); Streptomyces (Streptomyces) genus bacteria, such as Potato scabs (Streptomyces scabies) Wait.

作為本發明之協同性殺菌劑組成物可防除之真菌類，例如可列舉屬於以下之屬之病原菌。Examples of fungi that can be controlled by the synergistic bactericide composition of the present invention include pathogenic bacteria belonging to the following genera.

可列舉：交鏈孢(Alternaria)屬菌、例如 捲心菜黑斑病(Alternaria brassicae)、 捲心菜黑煤病(Alternaria brassicicola)、 馬鈴薯早疫病(Alternari solani)、 白菜黑斑病(Alternaria brassicae、Alternaria brassicicola)、 南瓜黑斑病(Alternaria cucumerina)、 茄子褐斑病(Alternaria solani)、 黃瓜黑斑病(Alternaria cucumerina)、 蘋果斑點落葉病(Alternaria alternata)、 胡蘿蔔黑葉枯病(Alternaria dauci)、 胡蘿蔔黑斑病(Alternaria radicina)、 草莓黑斑病(Alternaria alternata)、 洋蔥近似黑斑病(Alternaria porri)、 梨黑斑病(Alternaria kikuchiana)、 洋蔥黑斑病(Alternaria sp.)、 蔥黑斑病(Alternaria porri)； 金擔子菌(Aureobasidium)屬菌、例如 柿煤病(Aureobasidium pullulans)； 葡萄孢菌(Botrytis)屬菌、例如 草莓灰黴病(Botrytis cinerea)、 洋蔥小菌核性腐敗病(Botrytis squamosa)、 洋蔥灰色腐敗病(Botrytis allii)、 韭蔥白斑葉枯病(Botrytis byssoidea)、 蔥小菌核腐敗病(Botrytis squamosa)； 炭疽菌(Colletotrichum)屬菌、例如 小麥炭疽病(Colletotrichum graminicola)、 馬鈴薯炭疽病(Colletotrichum atramentarium )、 小松菜炭疽病(Colletotrichum higginsianum)、 紅豆炭疽病(Colletotrichum phaseolorum)、 茶炭疽病(Colletotrichum theae-sinensis)、 腰豆炭疽病(Colletotrichum lindemuthiamum)、 大豆炭疽病(Colletotrichum truncatum)、 菠菜炭疽病(Colletotrichum spinaciae)、 黃瓜炭疽病(Colletotrichum lagenarium)、 西瓜炭疽病(Colletotrichum orbiculare)、 辣椒・甜椒炭疽病(Colletotrichum gloeosporioides)、 草莓炭疽病(Colletotrichum acutatum)、 蘆筍炭疽病(Colletotrichum gloeosporioides)、 西洋梨炭疽病(Colletotrichum gloeosporioides)、 芒果炭疽病(Colletotrichum gloeosporioides)、 柿污染果病(Colletotrichum ssp.)、 洋蔥炭疽病(Colletotrichum circinans)、 柑橘炭疽病(Colletotrichum gloeosporioides)、 柑橘鏽果病(Colletotrichum gloeosporioides)、 梨葉炭疽病(Colletotrichum gloeosporioides)、 蔥炭疽病(Colletotrichum circinans)； 煤炱菌(Capnodium)屬菌、例如 板栗煤病(Capnodium salicinum)、 柑橘煤病(Capnodium salicinum)； 刺殼煤菌(Capnophaeum)屬菌、例如 柿煤病(Capnophaeum fuliginoides)； 尾孢菌(Cercospora)屬菌、例如 紅豆褐斑病(Cercospora canescens)、 腰豆褐斑病(Cercospora canescens)、 大豆紫斑病(Cercospora kikuchii)、 菠菜褐斑病(Cercospora beticola)、 蘆筍褐斑病(Cercospora asparagi)、 柿角斑病(Cercospora kakivora)、 柿角斑落葉病(Cercospora kaki)； 分枝孢子菌(Cladosporium)屬菌、例如 洋蔥黃斑病(Cladosporium alliicepae)、 梅黑星病(Cladosporium carpophilum)、 柿煤病(Cladosporium herbarum)、 桃黑星病(Cladosporium carpophilum)； 旋孢腔菌(Cochliobolus)屬菌、例如 稻胡麻葉枯病(Cochliobolus miyabeanus)； 棒孢菌(Corynespora)屬菌、例如 黃瓜褐斑病(Corynespora cassiicola)、 甜瓜褐斑病(Corynespora cassiicola)； 桑生冠毛菌(Cristulariella)屬菌、例如 蘋果環紋葉枯病(Cristulariella moricola)； 雙殼菌(Diplocarpon)屬菌、例如 蘋果褐斑病(Diplocarpon mali)、 薔薇黑星病(Diplocarpon rosae)； 間座殼(Diaporthe)屬菌、例如 柑橘黑點病(Diaporthe citri)； 痂囊腔菌(Elsinoe)屬菌、例如 葡萄黑痘病(Elsinoe ampelina)、 柑橘瘡痂病(Elsinoe fawcettii)； 白粉菌(Erysiphe)屬菌、例如 大麥白粉病(Erysiphe graminis f. sp. tritici)、 小麥白粉病(Erysiphe graminis f. sp. hordei)、 紅豆白粉病(Erisiphe pisi)、 胡蘿蔔白粉病(Erysiphe heraclei)； 鐮菌(Fusarium)屬菌、例如 胡蘿蔔萎凋病(Fusarium oxysporum)、 番茄萎凋病(Fusarium oxysporum f. sp. lycopersici)、 草莓萎黃病(Fusarium oxysporum)、 洋蔥乾腐病(Fusarium oxysporum f. sp. cerae)、 梅心腐病(Fusarium lateritium)、 桃赤黴病(Fusarium oxysporum)、 黃瓜莖腐病(Fusarium oxysporum f. sp. cucumerinum)、 甜瓜莖腐病(Fusarium oxysporum f. sp. melonis)； 褐孢黴(Fulvia)屬菌、例如 番茄葉黴病(Fulvia fulva)； 黑星孢(Fusicladium)屬菌、例如 柿黑星病(Fusicladium levieri)； 黑星孢(Gaeumannomyces)屬菌、例如 水稻立枯病(Gaeumannomyces graminis var. graminis)、 大麥立枯病(Gaeumannomyces graminis var. tritici)； 赤黴菌(Gibberella)屬菌、例如 水稻徒長病(Gibberella fujikuroi)、 桃赤黴病(Gibberella zeae)； 炭疽病菌(Glomerella)屬菌、例如 梅炭疽病(Glomerella cingulata)、 梅葉炭疽病(Glomerella mume)、 櫻桃炭疽病(Glomerella cingulata)、 葡萄晩腐病(Glomerella cingulata)、 蘋果炭疽病(Glomerella cingulata)、 柿污染果病(Glomerella sp.)、 梨炭疽病(Glomerella cingulata)、 柿葉炭疽病(Glomerella cingulata)、 草莓炭疽病(Glomerella cingulata)、 板栗炭疽病(Glomerella cingulata)； 內生真菌(Gloesporium)屬菌、例如 柿炭疽病(Gloeosporium kaki)、 桃炭疽病(Gloeosporium laeticolor)、 茼蒿炭疽病(Gloeosporium chrysanthemi、Gloeosporium carthami)、 蒟蒻炭疽病(Gloeosporium conjac)； 裸孢子囊菌(Gymnosporangium)屬菌、例如 梨赤星病(Gymnosporangium asiaticum)、 蘋果赤星病(Gymnosporangium yamadae)； 不休白雙胞鏽(Leucotelium)屬菌、例如 梅白銹病(Leucotelium prunipersicae)、 桃白銹病(Leucotelium prunipersicae)； 細盾黴(Leptothyrium)屬菌、例如 梨煤點病(Leptothyrium pomi)； 白粉病菌(Microsphaera)屬菌、例如 板栗白粉病(Microsphaera alphitoides)； 盤單毛孢(Monochaetia)屬菌、例如 板栗葉枯病(Monochaetia monochaeta)、 柿煤病(Microxyphium sp.)、 柿紅葉枯病(Monochaetia dispyri)、 板栗葉枯病(Monochaetia monochaeta)； 球腔菌(Mycosphaerella)屬菌、例如 柑橘黃斑病(Mycosphaerella citri、Mycosphaerella horii)、 柑橘雀斑病(Mycosphaerella pinodes)、 蔥黑葉枯病(Mycosphaerella allicina)、 柿圓星落葉病(Mycosphaerella nawae)、 草莓蛇目病(Mycosphaerella fragariae)； 鏈核盤菌(Monilinia)屬菌、例如 梅灰星病(Monilinia fructicola、Monilinia laxa)、 櫻桃灰星病(Monilinia fructicola)、 梨灰星病(Monilinia fructigena)、 桃灰星病(Monilinia fructicola)； Morenoella屬菌、例如 板栗褐斑病(Morenoella quercina)； 擬粉孢(Oidiopsis)屬菌、例如 番茄白粉病(Oidiopsis sicula)、 辣椒・甜椒白粉病(Oidiopsis sicula)； 蘋果白澀病菌(Podosphaera)屬菌、例如 櫻桃白粉病(Podosphaera tridactyla)、 蘋果白粉病(Podosphaera leucotricha)、 梅白粉病(Podosphaera tridactyla、 洋蔥露菌病(Peronospora destructor)、 蔥露菌病(Peronospora destructor)； 梨孢(Pyriclaria)屬菌、例如 稻瘟病(Pyricularia oryzae)、 菠菜露菌病(Peronospora effusa)、 黃瓜擬莖點黴根腐病(Phomopsis sp.)、 桃擬莖點黴腐敗病(Phomopsis sp.)、 葡萄黑腐病(Phyllosticta ampelicida)、 葡萄莖腐病(Phomopsis viticola)、 葡萄露菌病(Plasmopara viticola)、 梨輪紋病(Physalospora piricola)、 桃白粉病(Podosphaera tridactyla)、 柿縮葉病(Physalospora kaki)、 柿白粉病(Phyllactinia kakikola)、 柿葉枯病(Pestalotia diospyri)、 桃穿孔病(Phyllosticta persicae)、 小麥雲形病(Phynchosporium secalis f. sp. hordei)； 多孢菌(Pleospora)屬菌、例如 洋蔥葉枯病(Pleospora herbarum)、 紅三葉草葉枯病(Pleospora herbarum)、 蘋果褐色葉枯病(Pleospora herbarum)； 層鏽菌(Phakopsora)屬菌、例如 大豆銹病(Phakopsora pachyrhizi)； 擬莖點黴(Phomopsis)屬菌、例如 蘆筍莖枯病(Phomopsis asparagi)、 柿黑點病(Phomopsis kakivora)； 球針殼(Phyllactinia)屬菌、例如 西洋梨白粉病(Phyllactinia mali)、 梨白粉病(Phyllactinia pyri)； 葉點黴(Phyllosticta)屬菌、例如 紅豆褐紋病(Phyllosticta phaseolina)、 草莓輪紋病(Phyllosticta fragariicola)、 梅圓星病(Pyllosticta mume)； 疫黴(Phytophthora)屬菌、例如 西瓜疫病(Phytophthora cryptogea)、 辣椒、甜椒疫病(Phytophthora capsici)、 番茄疫病(Phytophthora infestans)、 馬鈴薯疫病(Phytophthora infestans)、 茄疫病(Phytophthora infestans)、 茄褐色腐敗病(Phytophthora capsici)、 草莓疫病(Phytophthora nicotianae var. parasitica)、 洋蔥白色疫病(Phytophthora parri)、 洋蔥疫病(Phytophthora nicotianae)、 蔥疫病(Phytophthora nicotianae)、 黃瓜疫病(Phytophthora melonis)、 西洋梨疫病(Phytophthora cactorum、phytophthora syringae)、 梨疫病(Phytophthoracactorum、Phytophthora syringae)、 柑橘褐色腐敗病(Phytophthora citrophthora)、 蘋果疫病(Phytophthora cactorum、Phytophthora cambivola、Phytophthora syringae)、 蔥白色疫病(Phythoththora parri)； 假小尾孢(Pseudocercosporella)屬菌、例如 小麥眼紋病(Pseudocercosporella herpotrichoides)、 蘿蔔白斑病(Pseudocercosporella capsellae)； 假尾孢(Pseudocercospora)屬菌、例如 柿黑斑病(Pseudocercospora fuliginosa)、 梅穿孔病(Pseudocercospora circumscissa)、 葡萄褐斑病(Pseudocercospora vitis)、 桃穿孔病(Pseudocercospora circumscissa)； 假霜黴(Pseudoperonospora)屬菌、例如 西瓜露菌病(Pseudoperonospora cubensis)、 黃瓜露菌病(Pseudoperonospora cubensis)、 南瓜露菌病(Pseudoperonospora cubensis)、 甜瓜露菌病(Pseudoperonospora cubensis)； 梨孢菌(Pyricularia)屬菌、例如 稻瘟病(Pyricularia oryzae)、 大麥稻瘟病(Pyricularia grisea)； 柄鏽菌(Puccinia)屬菌、例如 洋蔥銹病(Puccinia allii)、 洋蔥小菌核病(Puccinia allii)、 韭蔥銹病(Puccinia allii)、 大蔥銹病(Puccinia allii)、 蘆筍銹病(Puccinia asparagi-lucidi)、 小麥黑銹病(Puccinia graminis)、 茼蒿銹病(Puccinia cnicioleracei)； 腐黴(Pythium)屬菌、例如 草莓果實腐敗病(Pythium ultimum var. ultimum)、 黃瓜苗立枯病(Phythium cucurbitacearum)； 黑黴菌(Rhizopus)屬菌、例如 櫻桃黑黴菌(Rhizopus nigricans)、 桃黑黴菌(Rhizopus nigricans)、 黃瓜苗立枯病(Rhyzoctonia solani)； 絲核菌(Rhizoctonia)屬菌、例如 水稻紋枯病(Rhizoctonia solani)； 白紋病菌(Rosellinia)屬菌、例如 梅白紋羽病(Rosellinia necatrix)； 煤炱菌(Scorias)屬菌、例如 柿煤病(Scorias communis)、 山桃煤病(Scorias cylindrica)； 痂圓孢(Sphaceloma)屬菌、例如 梅瘡痂病(Sphaceloma pruni-domesticae)、 石榴瘡痂病(Sphaceloma punicae)、 花生瘡痂病(Sphaceloma arachidis)； 單絲殼(Sphaerotheca)屬菌、例如 梅白粉病(Sphaerotheca pannosa)、 西瓜白粉病(Sphaerotheca fuliginea)； 疣絲孢(Stenella)屬菌、例如 桃煤黴菌(Stenella sp.)； 殼針孢(Sptoria)屬菌、例如 洋蔥黑點葉枯病(Septoria alliacea)、 草莓白星病(Septoria fragariae)、 甘薯白星病(Septoria bataticola)、 小麥葉枯病(Septoria tritici)、 蒟蒻褐斑病(Septoria perillae)； 核盤菌(Sclerotinia)屬菌、例如 黃瓜菌核病(Sclerotinia sclerotiorum)、 腰豆菌核病(Sclerotinia sclerotiorum)、 胡蘿蔔菌核病(Sclerotinia intermedia、Sclerotinia sclerotiorum)、 草莓菌核病(Sclerotinia sclerotiorum)、 蔥小菌核病(Sclerotinia allii)、 梅菌核病(Sclerotinia sclerotiorum)、 櫻桃菌核病(Sclerotinia sclerotiorum)、 葡萄枝枯菌核病(Sclerotinia sclerotiorum)、 番茄菌核病(Sclerotinia sclerotiorum)、 茼蒿菌核病(Sclerotinia sclerotiorum)、 洋蔥菌核病(Sclerotinia sclerotiorum)、 茄子菌核病(Sclerotinia sclerotiorum)、 西瓜菌核病(Sclerotinia sclerotiorum)、 甜瓜菌核病(Sclerotinia sclerotiorum)、 辣椒・甜椒菌核病(Sclerotinia sclerotiorum)、 桃菌核病(Sclerotinia sclerotiorum)、 白菜菌核病(Sclerotinia sclerotiorum)、 捲心菜菌核病(Sclerotinia sclerotiorum)、 紅豆菌核病(Sclerotinia sclerotiorum)； 疣絲孢(Stenella)屬菌、例如 西洋梨煤黴菌(Stenella sp.)、 桃煤黴菌(Stenella sp.)； 單絲殼(Sphaerotheca)屬菌、例如 黃瓜白粉病(Sphaerotheca fuliginea)、 草莓白粉病(Sphaerotheca humuli)、 桃白粉病(Sphaerotheca pannosa)、 西瓜白粉病(Sphaerotheca fuliginea)； 亡革菌(Thanatephorus)屬菌、例如 馬鈴薯黑痣病(Thanatephorus cucumeris)、 茄子褐色斑點病(Thanatephorus cucumeris)； 多綹孢(Tripospermum)屬菌、例如 柿煤病(Tripospermum juglandis)； 鉤絲殼(Uncinula)屬菌、例如 葡萄白粉病(Uncinula necator)； 輪枝菌(Verticillium)屬菌、例如 草莓萎凋病(Verticillium dahliae)； 黑星菌(Venturia)屬菌、例如 西洋梨黑星病(Venturia pirina)、 梨黑星病(Venturia nashicola)、 蘋果黑星病(Venturia inaequalis)； 接瓶黴(Zygophiala)屬菌、例如 蘋果煤點病(Zygophiala jamaicensis)、 柿煤點病(Zygophiala jamaicensis) 等。Examples include: Alternaria (Alternaria) bacteria, such as Cabbage black spot (Alternaria brassicae), Cabbage black coal disease (Alternaria brassicicola), Early potato blight (Alternari solani), Cabbage black spot (Alternaria brassicae, Alternaria brassicicola), Pumpkin black spot (Alternaria cucumerina), Eggplant brown spot (Alternaria solani), Cucumber black spot (Alternaria cucumerina), Apple spotted leaf disease (Alternaria alternata), Carrot black leaf blight (Alternaria dauci), Carrot black spot (Alternaria radicina), Strawberry black spot (Alternaria alternata), Onion is similar to black spot (Alternaria porri), Pear black spot (Alternaria kikuchiana), Onion black spot (Alternaria sp.), Onion black spot (Alternaria porri); Aureobasidium (Aureobasidium) bacteria, such as Persimmon coal disease (Aureobasidium pullulans); Bacteria of the genus Botrytis, such as Strawberry gray mold (Botrytis cinerea), Onion small sclerotia (Botrytis squamosa), Onion gray putrefaction (Botrytis allii), Leek white spot leaf blight (Botrytis byssoidea), Botrytis squamosa (Botrytis squamosa); Colletotrichum (Colletotrichum) bacteria, for example Wheat anthracnose (Colletotrichum graminicola), Potato anthracnose (Colletotrichum atramentarium), Komatsu anthracnose (Colletotrichum higginsianum), Red bean anthracnose (Colletotrichum phaseolorum), Tea anthracnose (Colletotrichum theae-sinensis), Kidney bean anthracnose (Colletotrichum lindemuthiamum), Soy anthracnose (Colletotrichum truncatum), Spinach anthracnose (Colletotrichum spinaciae), Cucumber anthracnose (Colletotrichum lagenarium), Watermelon anthracnose (Colletotrichum orbiculare), Capsicum and sweet pepper anthracnose (Colletotrichum gloeosporioides), Strawberry anthracnose (Colletotrichum acutatum), Asparagus anthracnose (Colletotrichum gloeosporioides), Western pear anthracnose (Colletotrichum gloeosporioides), Mango anthracnose (Colletotrichum gloeosporioides), Persimmon contaminated fruit disease (Colletotrichum ssp.), Onion anthracnose (Colletotrichum circinans), Citrus anthracnose (Colletotrichum gloeosporioides), Citrus rust disease (Colletotrichum gloeosporioides), Pear leaf anthracnose (Colletotrichum gloeosporioides), Onion anthracnose (Colletotrichum circinans); Capnodium bacteria, such as Chestnut coal disease (Capnodium salicinum), Citrus coal disease (Capnodium salicinum); Capnophaeum (Capnophaeum) bacteria, such as Persimmon coal disease (Capnophaeum fuliginoides); Cercospora (Cercospora) bacteria, such as Red bean brown spot (Cercospora canescens), Kidney bean brown spot (Cercospora canescens), Soybean purple spot (Cercospora kikuchii), Spinach brown spot (Cercospora beticola), Asparagus brown spot (Cercospora asparagi), Persimmon angular spot disease (Cercospora kakivora), Cercospora kaki (Cercospora kaki); Cladosporium bacteria, such as Onion Macular Disease (Cladosporium alliicepae), Plum scab (Cladosporium carpophilum), Persimmon coal disease (Cladosporium herbarum), Peach scab (Cladosporium carpophilum); Cochliobolus bacteria, such as Rice flax leaf blight (Cochliobolus miyabeanus); Corynespora (Corynespora) bacteria, such as Cucumber brown spot disease (Corynespora cassiicola), Melon brown spot disease (Corynespora cassiicola); Cristulariella (Cristulariella) bacteria, such as Apple ring leaf blight (Cristulariella moricola); Diplocarpon bacteria, such as Apple brown spot disease (Diplocarpon mali), Rose scab (Diplocarpon rosae); Diaporthe bacteria, such as Citrus black spot (Diaporthe citri); Elsinoe bacteria, such as Grape black pox (Elsinoe ampelina), Citrus scab (Elsinoe fawcettii); Erysiphe bacteria, such as Barley powdery mildew (Erysiphe graminis f. sp. tritici), Wheat powdery mildew (Erysiphe graminis f. sp. hordei), Red bean powdery mildew (Erisiphe pisi), Carrot powdery mildew (Erysiphe heraclei); Fusarium (Fusarium) bacteria, such as Carrot wilt (Fusarium oxysporum), Tomato blight (Fusarium oxysporum f. sp. lycopersici), Strawberry chlorosis (Fusarium oxysporum), Onion dry rot (Fusarium oxysporum f. sp. cerae), Plum heart rot (Fusarium lateritium), Peach head blight (Fusarium oxysporum), Cucumber stem rot (Fusarium oxysporum f. sp. cucumerinum), Melon stem rot (Fusarium oxysporum f. sp. melonis); Fulvia bacteria, such as Tomato leaf mold (Fulvia fulva); Fusicladium (Fusicladium) bacteria, such as Persimmon scab (Fusicladium levieri); Gaeumannomyces (Gaeumannomyces) bacteria, such as Rice blast (Gaeumannomyces graminis var. graminis), Barley blight (Gaeumannomyces graminis var. tritici); Gibberella (Gibberella) genus bacteria, such as Gibberella fujikuroi, Peach head blight (Gibberella zeae); Glomerella bacteria, such as Plum anthracnose (Glomerella cingulata), Plum leaf anthracnose (Glomerella mume), Cherry anthracnose (Glomerella cingulata), Grape night rot (Glomerella cingulata), Apple anthracnose (Glomerella cingulata), Persimmon contaminated fruit disease (Glomerella sp.), Pear anthracnose (Glomerella cingulata), Persimmon leaf anthracnose (Glomerella cingulata), Strawberry anthracnose (Glomerella cingulata), Chestnut anthracnose (Glomerella cingulata); Endophytic fungi (Gloesporium) genus bacteria, such as Persimmon anthracnose (Gloeosporium kaki), Peach anthracnose (Gloeosporium laeticolor), Chrysanthemum anthracnose (Gloeosporium chrysanthemi, Gloeosporium carthami), Konjac anthracnose (Gloeosporium conjac); Gymnosporangium (Gymnosporangium) bacteria, such as Pear brown spot disease (Gymnosporangium asiaticum), Apple brown spot disease (Gymnosporangium yamadae); Leucotelium bacteria, such as Plum white rust (Leucotelium prunipersicae), Peach white rust (Leucotelium prunipersicae); Leptothyrium (Leptothyrium) bacteria, such as Pear coal spot disease (Leptothyrium pomi); Microsphaera bacteria, such as Chestnut powdery mildew (Microsphaera alphitoides); Monochaetia bacteria, such as Chestnut leaf blight (Monochaetia monochaeta), Persimmon coal disease (Microxyphium sp.), Persimmon red leaf blight (Monochaetia dispyri), Chestnut leaf blight (Monochaetia monochaeta); Mycosphaerella (Mycosphaerella) bacteria, such as Citrus macular disease (Mycosphaerella citri, Mycosphaerella horii), Citrus freckles (Mycosphaerella pinodes), Onion black leaf blight (Mycosphaerella allicina), Persimmon round star leaf disease (Mycosphaerella nawae), Strawberry Snake Disease (Mycosphaerella fragariae); Sclerotium sclerotium (Monilinia) genus bacteria, such as Plum gray star disease (Monilinia fructicola, Monilinia laxa), Cherry gray star disease (Monilinia fructicola), Pear Grey Star Disease (Monilinia fructigena), Peach Grey Star Disease (Monilinia fructicola); Morenoella bacteria, for example Chestnut brown spot (Morenoella quercina); Oidiopsis bacteria, such as Tomato powdery mildew (Oidiopsis sicula), Pepper and sweet pepper powdery mildew (Oidiopsis sicula); Podosphaera bacteria, such as Cherry powdery mildew (Podosphaera tridactyla), Apple powdery mildew (Podosphaera leucotricha), Plum powdery mildew (Podosphaera tridactyla, Peronospora destructor (Peronospora destructor), Peronospora destructor (Peronospora destructor); Pyriclaria (Pyriclaria) bacteria, for example Rice blast (Pyricularia oryzae), Spinach effusa (Peronospora effusa), Cucumber Phomopsis sp., Peach Phomopsis sp. sp., Grape black rot (Phyllosticta ampelicida), Grape stem rot (Phomopsis viticola), Staphylococcus disease (Plasmopara viticola), Pear ring disease (Physalospora piricola), Peach powdery mildew (Podosphaera tridactyla), Physalospora kaki, Persimmon powdery mildew (Phyllactinia kakikola), Persimmon leaf blight (Pestalotia diospyri), Peach perforation (Phyllosticta persicae), Wheat cloud disease (Phynchosporium secalis f. sp. hordei); Pleospora bacteria, such as Onion leaf blight (Pleospora herbarum), Red clover leaf blight (Pleospora herbarum), Apple brown leaf blight (Pleospora herbarum); Phakopsora bacteria, such as Soybean rust (Phakopsora pachyrhizi); Phomopsis bacteria, such as Asparagus stem blight (Phomopsis asparagi), Persimmon black spot disease (Phomopsis kakivora); Phyllactinia bacteria, such as Western pear powdery mildew (Phyllactinia mali), Pear powdery mildew (Phyllactinia pyri); Phyllosticta (Phyllosticta) bacteria, such as Phyllosticta phaseolina (Phyllosticta phaseolina), Strawberry ring disease (Phyllosticta fragariicola), Pyllosticta mume; Phytophthora (Phytophthora) bacteria, such as Watermelon blight (Phytophthora cryptogea), Pepper, sweet pepper blight (Phytophthora capsici), Tomato blight (Phytophthora infestans), Potato blight (Phytophthora infestans), Eggplant blight (Phytophthora infestans), Eggplant brown putrefaction (Phytophthora capsici), Strawberry blight (Phytophthora nicotianae var. parasitica), Onion white blight (Phytophthora parri), Onion blight (Phytophthora nicotianae), Onion blight (Phytophthora nicotianae), Cucumber blight (Phytophthora melonis), Western pear blight (Phytophthora cactorum, phytophthora syringae), Pear blight (Phytophthoracactorum, Phytophthora syringae), Citrus brown putrefaction (Phytophthora citrophthora), Apple blight (Phytophthora cactorum, Phytophthora cambivola, Phytophthora syringae), Onion white blight (Phythoththora parri); Pseudocercosporella (Pseudocercosporella) bacteria, such as Wheat eye pattern (Pseudocercosporella herpotrichoides), Turnip white spot disease (Pseudocercosporella capsellae); Pseudocercospora (Pseudocercospora) bacteria, such as Persimmon black spot (Pseudocercospora fuliginosa), Plum perforation (Pseudocercospora circumscissa), Pseudocercospora vitis (Pseudocercospora vitis), Peach perforation (Pseudocercospora circumscissa); Pseudoperonospora (Pseudoperonospora) bacteria, such as Pseudoperonospora cubensis (Pseudoperonospora cubensis), Cucumber show disease (Pseudoperonospora cubensis), Pseudoperonospora cubensis (Pseudoperonospora cubensis), Pseudoperonospora cubensis (Pseudoperonospora cubensis); Pyricularia (Pyricularia) genus bacteria, such as Rice blast (Pyricularia oryzae), Barley rice blast (Pyricularia grisea); Puccinia bacteria, such as Onion rust (Puccinia allii), Puccinia allii (Puccinia allii), Leek rust (Puccinia allii), Green onion rust (Puccinia allii), Asparagus rust (Puccinia asparagi-lucidi), Wheat black rust (Puccinia graminis), Puccinia cnicioleracei (Puccinia cnicioleracei); Pythium (Pythium) bacteria, such as Strawberry fruit spoilage (Pythium ultimum var. ultimum), Cucumber seedling blight (Phythium cucurbitacearum); Rhizopus bacteria, such as Cherry black mold (Rhizopus nigricans), Peach black mold (Rhizopus nigricans), Cucumber seedling blight (Rhyzoctonia solani); Rhizoctonia bacteria, such as Rice sheath blight (Rhizoctonia solani); Rosellinia bacteria, such as Plum white pattern feather disease (Rosellinia necatrix); Scorias bacteria, such as Persimmon coal disease (Scorias communis), Mountain peach coal disease (Scorias cylindrica); Sphaceloma bacteria, such as Sphaceloma pruni-domesticae, Pomegranate scab (Sphaceloma punicae), Peanut scab (Sphaceloma arachidis); Sphaerotheca (Sphaerotheca) bacteria, such as Plum powdery mildew (Sphaerotheca pannosa), Watermelon powdery mildew (Sphaerotheca fuliginea); Stenella bacteria, such as Peach coal mold (Stenella sp.); Sptoria (Sptoria) bacteria, such as Onion black spot leaf blight (Septoria alliacea), Strawberry white spot disease (Septoria fragariae), Sweet potato white spot disease (Septoria bataticola), Wheat leaf blight (Septoria tritici), Konjac brown spot (Septoria perillae); Sclerotinia (Sclerotinia) genus bacteria, such as Cucumber sclerotinia (Sclerotinia sclerotiorum), Kidney bean sclerotinia (Sclerotinia sclerotiorum), Carrot Sclerotinia (Sclerotinia intermedia, Sclerotiorum), Strawberry sclerotinia (Sclerotinia sclerotiorum), Sclerotinia allii (Sclerotinia allii), Sclerotinia sclerotiorum (Sclerotinia sclerotiorum), Cherry sclerotinia (Sclerotinia sclerotiorum), Grape branch sclerotinia sclerotiorum (Sclerotinia sclerotiorum), Tomato sclerotinia (Sclerotinia sclerotiorum), Sclerotinia sclerotiorum (Sclerotinia sclerotiorum), Onion sclerotinia (Sclerotinia sclerotiorum), Eggplant sclerotinia (Sclerotinia sclerotiorum), Watermelon sclerotinia (Sclerotinia sclerotiorum), Melon sclerotinia (Sclerotinia sclerotiorum), Pepper and sweet pepper sclerotinia sclerotiorum (Sclerotinia sclerotiorum), Peach Sclerotium (Sclerotinia sclerotiorum), Sclerotinia sclerotiorum (Sclerotinia sclerotiorum), Sclerotinia sclerotiorum (Sclerotinia sclerotiorum), Sclerotinia sclerotiorum (Sclerotinia sclerotiorum); Stenella bacteria, such as Stenella sp., Peach coal mold (Stenella sp.); Sphaerotheca (Sphaerotheca) bacteria, such as Cucumber powdery mildew (Sphaerotheca fuliginea), Strawberry powdery mildew (Sphaerotheca humuli), Peach powdery mildew (Sphaerotheca pannosa), Watermelon powdery mildew (Sphaerotheca fuliginea); Thanatephorus bacteria, such as Potato mole disease (Thanatephorus cucumeris), Eggplant brown spot disease (Thanatephorus cucumeris); Tripospermum (Tripospermum) bacteria, such as Persimmon coal disease (Tripospermum juglandis); Uncinula bacteria, such as Grape powdery mildew (Uncinula necator); Verticillium (Verticillium) bacteria, such as Strawberry blight (Verticillium dahliae); Venturia bacteria, such as Western pear scab (Venturia pirina), Pear scab (Venturia nashicola), Apple scab (Venturia inaequalis); Zygophiala bacteria, such as Apple coal spot disease (Zygophiala jamaicensis), Persimmon coal spot disease (Zygophiala jamaicensis) Wait.

作為本發明之協同性殺菌劑組成物可防除之植物病毒，並無特別限定，例如可列舉：菸草花葉病毒(Tobamovirus)屬、馬鈴薯X病毒(Potexvirus)屬、香石竹潛隱病毒(Carlavirus)屬、南瓜花葉病毒(Cucumovirus)屬、香石竹斑駁病毒(Carmovirus)屬等。The plant viruses that can be controlled by the synergistic fungicide composition of the present invention are not particularly limited, and examples include: Tobamovirus, Potato X virus, Carlavirus Genus, Cucumovirus (Cucumovirus), Carmovirus (Carmovirus), etc.

具體而言， 作為菸草花葉病毒(Tobamovirus)屬病毒，例如可列舉： 菸草花葉病毒(Tobacco mosaic virus, TMV)、 番茄花葉病毒(Tomato mosaic virus , ToMV)、 黃瓜綠斑駁花葉病毒(Kyuri green mottle mosaic virus , KGMMV)、 辣椒輕斑駁病毒(Pepper mild mottle virus , PMMoV)、 西瓜綠斑駁花葉病毒(Cucumber green mottle mosaic virus , CGMMV)等。 作為馬鈴薯X病毒(Potexvirus)屬病毒，例如可列舉： 車前草花葉病毒(Plantago asiatica mosaic virus , PlAMV)、 馬鈴薯X病毒(Potato virus X, PVX)等。 作為香石竹潛隱病毒(Carlavirus)屬病毒，例如可列舉： 馬鈴薯M病毒(Potato virus M, PVM)等。 作為南瓜花葉病毒(Cucumovirus)屬病毒，例如可列舉： 黃瓜花葉病毒(Cucumber mosaic virus , CMV)等。 作為香石竹斑駁病毒(Carmovirus)屬病毒，例如可列舉： 甜瓜壞死斑點病毒(Melon necrotic spot virus, MNSV)等。in particular, As a virus of the genus Tobamovirus, for example: Tobacco mosaic virus (TMV), Tomato mosaic virus (Tomato mosaic virus, ToMV), Kyuri green mottle mosaic virus (KGMMV), Pepper mild mottle virus (Pepper mild mottle virus, PMMoV), Watermelon green mottle mosaic virus (Cucumber green mottle mosaic virus, CGMMV), etc. As a virus of the Potato X virus (Potexvirus) genus, for example: Plantago asiatica mosaic virus (Plantago asiatica mosaic virus, PlAMV), Potato virus X (PVX), etc. As a virus of the genus Carlavirus, for example: Potato virus M (PVM) and so on. As a virus of the genus Cucumovirus (Cucumovirus), for example: Cucumber mosaic virus (CMV), etc. As a virus of the genus Carmovirus, for example: Melon necrotic spot virus (MNSV), etc.

作為可使用本發明之協同性殺菌劑組成物之有用植物，並無特別限定，例如可列舉：稻、大麥、小麥、黑麥、燕麥、玉米等穀類；大豆、小豆、蠶豆、豌豆、菜豆、花生等豆類； 蘋果、柑橘類、梨、葡萄、桃、梅、櫻桃、胡桃、栗、扁桃、香蕉、草莓等果樹/果實類； 捲心菜、番茄、菠菜、青花菜、萵苣、洋蔥、蔥、甜椒、茄子、胡椒等葉/果菜類； 胡蘿蔔、馬鈴薯、甘薯、芋頭、蘿蔔、藕、蔓菁、牛蒡、大蒜等根菜類； 棉、麻、甜菜(beet)、啤酒花、甘蔗、菾菜、橄欖、橡膠、咖啡、菸草、茶等加工用作物； 南瓜、黃瓜、香瓜(oriental melon)、西瓜、甜瓜(melon)等瓜類； 果園草、高粱、梯牧草、苜蓿、紫苜蓿等牧草類； 高麗草、剪股穎(Bentgrass)等草類； 熏衣草、迷迭香、百里香、洋芹、胡椒、生薑等香料鑒賞用作物； 菊、薔薇、康乃馨、蘭等花卉類； 銀杏樹、櫻類、珊瑚木等庭木； 薩哈林冷杉(Abies sachalinensis)類、魚鱗雲杉(Picea jezoensis)類、松類、羅漢柏、杉、檜等林木等。The useful plants that can use the synergistic fungicide composition of the present invention are not particularly limited, and examples include: rice, barley, wheat, rye, oats, corn and other cereals; soybeans, adzuki beans, broad beans, peas, kidney beans, Legumes such as peanuts; Apples, citrus, pears, grapes, peaches, plums, cherries, walnuts, chestnuts, almonds, bananas, strawberries and other fruit trees/fruits; Cabbage, tomato, spinach, broccoli, lettuce, onion, onion, sweet pepper, eggplant, pepper and other leaves/fruit vegetables; Root vegetables such as carrot, potato, sweet potato, taro, radish, lotus root, vine, burdock, garlic; Processed products such as cotton, hemp, beet, hops, sugar cane, salami, olives, rubber, coffee, tobacco, tea, etc.; Pumpkin, cucumber, oriental melon (oriental melon), watermelon, melon (melon) and other melons; Orchard grass, sorghum, timothy grass, alfalfa, alfalfa and other pastures; Grasses such as Korean grass and Bentgrass; Lavender, rosemary, thyme, parsley, pepper, ginger and other spices for appreciation; Chrysanthemum, rose, carnation, orchid and other flowers; Garden trees such as ginkgo, cherry tree, coral tree, etc.; Abies sachalinensis (Abies sachalinensis), Picea jezoensis (Picea jezoensis), pines, cypress, cedar, juniper and other forest trees.

本發明之協同性殺菌劑組成物可藉由對此類農園藝病原菌之生存場所、或者農園藝病原菌所寄生之植物或其附近進行處理來保護上述植物。The synergistic fungicide composition of the present invention can protect the plants by treating the living place of such agricultural and horticultural pathogens, or the plants parasitized by the agricultural and horticultural pathogens or their vicinity.

所謂病害蟲之生存場所、或者病害蟲所寄生之植物或其附近，可施用於應驅除之病害蟲所棲息之植被、尤其是莖、葉、種子、球根或種薯(以下，將種子、球根或種薯簡稱為種子)；果實等。作為施用方法，例如可列舉：對於葉面或莖之散佈、或噴霧、種子處理(例如，浸種或粒劑之種子粉衣等)、土壤施用(例如，粒劑之田間散佈或田間噴霧等)等。The so-called living places of pests, or plants parasitic by pests or their vicinity, can be applied to the vegetation inhabited by pests that should be repelled, especially stems, leaves, seeds, bulbs or seed potatoes (hereinafter, the seeds, bulbs Or seed potatoes are called seeds for short); fruits, etc. Examples of application methods include: spraying on leaves or stems, or spraying, seed treatment (for example, seed soaking or seed powder coating of granules, etc.), and soil application (for example, field spreading or spraying of granules, etc.) Wait.

含有硝基苯酚化合物之殺菌活性增強劑 上述硝基苯酚化合物可藉由添加至公知之殺菌劑中而增強殺菌活性。即，為了增強殺菌活性，可使用硝基苯酚化合物。 [實施例]Bactericidal activity enhancer containing nitrophenol compound The above-mentioned nitrophenol compound can be added to a known bactericide to enhance the bactericidal activity. That is, in order to enhance the bactericidal activity, a nitrophenol compound can be used. [Example]

以下，揭示實施例、比較例、製劑例、及試驗例更進一步明確本發明，但本發明並不限定於該等。Hereinafter, examples, comparative examples, formulation examples, and test examples are disclosed to further clarify the present invention, but the present invention is not limited to these.

將製劑例示於下文。再者，所謂「份」係指「重量份」。The formulation is exemplified below. Furthermore, the so-called "parts" means "parts by weight".

參考製劑例1(乳劑) 使本發明組成物各10份溶解於45份Solvesso150及35份N-甲基吡咯啶酮中，於其中添加乳化劑(商品名：Sorpol 3005X，東邦化學(股)製造)10份，進行攪拌混合而獲得各10%乳劑。Reference preparation example 1 (emulsion) Dissolve 10 parts of the composition of the present invention in 45 parts of Solvesso150 and 35 parts of N-methylpyrrolidone, add 10 parts of emulsifier (trade name: Sorpol 3005X, manufactured by Toho Chemical Co., Ltd.), and stir and mix And obtain each 10% emulsion.

參考製劑例2(水合劑) 將本發明組成物各20份添加至混合月桂基硫酸鈉2份、木質素磺酸鈉4份、合成含水氧化矽微粉末20份及黏土54份所得者中，利用果汁攪拌器進行攪拌混合而獲得20%水合劑。Reference preparation example 2 (hydration agent) Add 20 parts of each of the composition of the present invention to the mixture of 2 parts of sodium lauryl sulfate, 4 parts of sodium lignosulfonate, 20 parts of synthetic hydrous silica micropowder and 54 parts of clay, and use a juice blender to stir and mix. Obtain 20% hydrating agent.

參考製劑例3(粒劑) 於本發明組成物各5份中添加十二烷基苯磺酸鈉2份、膨潤土10份及黏土83份並充分攪拌混合。添加適用量之水，進一步進行攪拌，利用造粒機進行造粒，進行通風乾燥而獲得5%粒劑。Reference preparation example 3 (granules) Add 2 parts of sodium dodecylbenzene sulfonate, 10 parts of bentonite and 83 parts of clay to each 5 parts of the composition of the present invention, and stir and mix them thoroughly. Add an appropriate amount of water, further stir, granulate with a granulator, and ventilate and dry to obtain 5% granules.

參考製劑例4(粉劑) 使本發明組成物各1份溶解於適當量之丙酮中，於其中添加合成含水氧化矽微粉末5份、酸性磷酸異丙酯(PAP)0.3份及黏土93.7份，利用果汁攪拌器進行攪拌混合，將丙酮蒸發去除，獲得1%粉劑。Reference preparation example 4 (powder) Dissolve 1 part each of the composition of the present invention in an appropriate amount of acetone, add 5 parts of synthetic hydrous silica micropowder, 0.3 part of acidic isopropyl phosphate (PAP) and 93.7 parts of clay, and stir and mix with a juice blender , The acetone is evaporated and removed to obtain 1% powder.

參考製劑例5(懸浮劑) 將本發明組成物各20份、含有聚氧乙烯三苯乙烯基苯基醚磷酸酯三乙醇胺3份及Rhodorsil 426R 0.2份之水20份進行混合，使用球磨機進行濕式粉碎後，與含有丙二醇8份及三仙膠0.32份之水60份進行混合，獲得20%水中懸濁液。Reference preparation example 5 (suspension) 20 parts of each of the composition of the present invention, 3 parts of polyoxyethylene tristyryl phenyl ether phosphate triethanolamine and 20 parts of water containing 0.2 parts of Rhodorsil 426R are mixed, and after wet pulverization using a ball mill, it is mixed with 8 parts containing propylene glycol 8 30 parts and 0.32 parts of Sanxian Gum and 60 parts of water are mixed to obtain a 20% suspension in water.

＜硝基苯酚化合物＞ 製劑A 使4-硝基苯酚鈉鹽(旭化學工業(股)製造)0.9份、2-硝基苯酚鈉鹽(旭化學工業(股)製造)0.6份、5-硝基愈創木酚鈉鹽(旭化學工業(股)製造)0.3份溶解於水998.2份中，製備水溶劑。以下將該水溶劑稱為「製劑A」。＜Nitrophenol compound＞ Formulation A Make 4-nitrophenol sodium salt (made by Asahi Chemical Industry Co., Ltd.) 0.9 parts, 2-nitrophenol sodium salt (made by Asahi Chemical Industry Co., Ltd.) 0.6 parts, 5-nitroguaiacol sodium salt ( 0.3 part of Asahi Chemical Industry Co., Ltd.) was dissolved in 998.2 parts of water to prepare a water solvent. Hereinafter, this water solvent is referred to as "formulation A".

製劑B 使4-硝基苯酚鈉鹽(旭化學工業(股)製造)0.9份溶解於水999.1份中而製備水溶劑。以下將該水溶劑稱為「製劑B」。Formulation B 0.9 parts of 4-nitrophenol sodium salt (manufactured by Asahi Chemical Industry Co., Ltd.) was dissolved in 999.1 parts of water to prepare a water solvent. Hereinafter, this water solvent is referred to as "formulation B".

製劑C 使2-硝基苯酚鈉鹽(旭化學工業(股)製造)0.6份溶解於水999.4份中而製備水溶劑。以下將該水溶劑稱為「製劑C」。Formulation C 0.6 parts of 2-nitrophenol sodium salt (manufactured by Asahi Chemical Industry Co., Ltd.) was dissolved in 999.4 parts of water to prepare a water solvent. Hereinafter, this water solvent is referred to as "formulation C".

製劑D 使5-硝基愈創木酚鈉鹽(旭化學工業(股)製造)0.3份溶解於水999.7份中而製備水溶劑。以下將該水溶劑稱為「製劑D」。Formulation D 0.3 part of 5-nitroguaiacol sodium salt (manufactured by Asahi Chemical Industry Co., Ltd.) was dissolved in 999.7 parts of water to prepare a water solvent. Hereinafter, this water solvent is referred to as "formulation D".

＜殺菌活性化合物＞ 製劑E 準備BASF Agro(股)製造之Naria(註冊商標)WDG(含有百克敏6.8重量%與白克列13.6重量%之顆粒水合劑)作為含有百克敏與白克列之顆粒水合劑。將該製劑設為「製劑E」。＜Fungicide active compound＞ Formulation E Prepared Naria (registered trademark) WDG (a granular hydrating agent containing 6.8% by weight of beacamine and 13.6% by weight of beacrine) manufactured by BASF Agro (stock) as a granular hydrating agent containing beacamine and beacrine. Let this formulation be "formulation E".

製劑F 準備BASF Agro(股)製造之Fronside(註冊商標)SC(含有扶吉胺39.5重量%之懸浮劑)作為含有扶吉胺之懸浮劑。將該製劑設為「製劑F」。Formulation F Prepare Fronside (registered trademark) SC (a suspending agent containing 39.5 wt% fugeeamine) manufactured by BASF Agro (stock) as a fugeeline-containing suspending agent. Let this formulation be "formulation F".

製劑G 準備日本農藥(股)製造之Major(註冊商標)Flowable(含有啶氧菌酯22.5重量%之懸浮劑)作為含有啶氧菌酯之懸浮劑。將該製劑設為「製劑G」。Formulation G Prepared Major (registered trademark) Flowable (a suspension containing picoxystrobin 22.5 wt%) manufactured by Japan Agricultural Chemicals Co., Ltd. as a suspension containing picoxystrobin. Let this formulation be "formulation G".

製劑H 準備ISK BIOSCIENCES(股)製造之Ranman(註冊商標)Flowable(含有賽座滅9.4重量%之懸浮劑)作為含有賽座滅之懸浮劑。將該製劑設為「製劑H」。Formulation H Prepare Ranman (registered trademark) Flowable (containing 9.4% by weight of the suspension agent) manufactured by ISK BIOSCIENCES (stock) as the suspension agent containing the suspension agent. Let this formulation be "formulation H".

製劑I 準備日產化學工業(股)製造之Horizon(註冊商標)DF劑(含有凡殺同22.5重量%與克絕30重量%之DF劑)作為含有凡殺同與克絕之DF劑。將該製劑設為「製劑I」。Formulation I Horizon (registered trademark) DF agent (containing 22.5 wt% and 30% by weight of DF) manufactured by Nissan Chemical Industry Co., Ltd. is prepared as a DF agent containing LF and KJ. This formulation is referred to as "Formulation I".

製劑J 準備Bayer Cropscience製造之Flint(註冊商標)Flowable 25(含有三氟敏25重量%之懸浮劑)作為含有三氟敏之懸浮劑。將該製劑設為「製劑J」。Formulation J Prepare Flint (registered trademark) Flowable 25 (a suspending agent containing 25% by weight of trifluorosensitive) manufactured by Bayer Cropscience as a suspending agent containing trifluorosensitive. Let this formulation be "formulation J".

製劑K 準備住友化學(股)製造之Dakonil(註冊商標)1000(含有四氯異苯40重量%之水合劑)作為含有四氯異苯之水合劑。將該製劑設為「製劑K」。Formulation K Prepare Dakonil (registered trademark) 1000 (a hydrating agent containing 40% by weight of tetrachloroisobenzene) manufactured by Sumitomo Chemical Co., Ltd. as a hydrating agent containing tetrachloroisobenzene. Let this formulation be "formulation K".

製劑L 準備Kumiai Chemical Industry(股)製造之Propose(註冊商標)顆粒水合劑(含有苯噻菌胺5重量%與四氯異苯50重量%之顆粒水合劑)作為含有苯噻菌胺與四氯異苯之顆粒水合劑。將該製劑設為「製劑L」。Formulation L Prepare Propose (registered trademark) granular hydrating agent manufactured by Kumiai Chemical Industry Co., Ltd. (a granular hydrating agent containing 5% by weight of Benthiasamide and 50% by weight of tetrachloroisophenyl) as containing Benthiasamide and tetrachloroisobenzene The particle hydrating agent. Let this formulation be "formulation L".

製劑M 準備日產化學工業(股)製造之Storobi(註冊商標)DF(含有克收欣50重量%之DF劑)作為含有克收欣之DF劑。將該製劑設為「製劑M」。Formulation M Prepare Storobi (registered trademark) DF (containing 50% by weight of Keshouxin) manufactured by Nissan Chemical Industry Co., Ltd. as the DF agent containing Keshouxin. Let this formulation be "formulation M".

製劑N 使亞磷酸二氫鉀560重量份溶解於純水440份中，設為合計1000重量份。將該製劑設為「製劑N」。Formulation N 560 parts by weight of potassium dihydrogen phosphite was dissolved in 440 parts of pure water to make a total of 1000 parts by weight. Let this formulation be "formulation N".

製劑O 準備日本曹達(股)製造之Etofin(註冊商標)Flowable(含有噻唑菌胺12.5重量%之懸浮劑)作為含有噻唑菌胺之懸浮劑。將該製劑設為「製劑O」。Formulation O Prepare Etofin (registered trademark) Flowable (containing 12.5% by weight of ethaboxam) manufactured by Japan Soda (stock) as a suspension containing ethaboxam. Let this formulation be "formulation O".

製劑P 準備BASF Agro(股)製造之Zanpro(註冊商標)DM Flowable(含有辛唑嘧菌胺27重量%與達滅芬20.3重量%之懸浮劑)作為含有辛唑嘧菌胺與達滅芬之懸浮劑。將該製劑設為「製劑P」。Formulation P Prepared Zanpro (registered trademark) DM Flowable (a suspending agent containing 27% by weight of azoxystrobin and 20.3% by weight of azoxystrobin) manufactured by BASF Agro (stocks) as a suspending agent containing oxystrobin and damefene . Let this formulation be "formulation P".

製劑Q 準備北興化學工業(股)製造之Festival(註冊商標)C水合劑(含有達滅芬15重量%、鹼性氯化銅58.8重量%之水合劑)作為含有達滅芬與鹼性氯化銅之水合劑。將該製劑設為「製劑Q」。Formulation Q Prepared Festival (registered trademark) C hydrating agent (a hydrating agent containing 15% by weight of damefene and 58.8% by weight of basic copper chloride) manufactured by Beixing Chemical Industry Co., Ltd. as a hydrating agent containing damefene and basic copper chloride Hydrating agent. Let this formulation be "formulation Q".

製劑R 準備Syngenta Japan(股)製造之Amistar(註冊商標)20 Flowable(含有亞托敏20重量%之懸浮劑)作為含有亞托敏之懸浮劑。將該製劑設為「製劑R」。Formulation R Prepare Amistar (registered trademark) 20 Flowable (containing 20% by weight of subtilisin) manufactured by Syngenta Japan (stock) as a suspension containing subtilisin. Let this formulation be "formulation R".

製劑S 準備Dow Chemical Japan(股)製造之Jimandaisen(註冊商標)水合劑(含有鋅錳乃浦80重量%之水合劑)作為含有鋅錳乃浦之水合劑。將該製劑設為「製劑S」。Formulation S Prepare Jimandaisen (registered trademark) hydrating agent (a hydrating agent containing 80% by weight of zinc manganese Naiura) manufactured by Dow Chemical Japan (Stock) as a hydrating agent containing zinc manganese Naiura. Let this formulation be "formulation S".

製劑T 準備Bayer Cropscience(股)製造之Arieti(註冊商標)水合劑(含有80重量%之水合劑)作為含有福賽得之水合劑。將該製劑設為「製劑T」。Formulation T Arieti (registered trademark) hydrating agent (containing 80% by weight of hydrating agent) manufactured by Bayer Cropscience (stock) was prepared as a hydrating agent containing Fosaide. Let this formulation be "formulation T".

製劑U 準備Bayer Cropscience(股)製造之Reliable(註冊商標)Flowable(含有氟吡菌胺5.5重量%與霜黴威鹽酸鹽55.5%之懸浮劑)作為含有氟吡菌胺與霜黴威鹽酸鹽之懸浮劑。將該製劑設為「製劑U」。Formulation U Prepare Reliable (registered trademark) Flowable (a suspension containing fluopyram 5.5% by weight and propamocarb hydrochloride 55.5%) manufactured by Bayer Cropscience (stocks) as the one containing fluopyram and propamocarb hydrochloride Suspending agent. Let this formulation be "formulation U".

製劑V 準備OAT Agrio(股)製造之Yonepon(含有壬基苯酚磺酸銅鹽30重量%之液劑)作為含有壬基苯酚磺酸銅鹽之液劑。將該製劑設為「製劑V」。Formulation V Prepare Yonepon (a liquid containing 30% by weight of copper nonylphenol sulfonate) manufactured by OAT Agrio as a liquid containing copper nonylphenol sulfonate. Let this formulation be "formulation V".

製劑W 準備Arysta Lifescience(股)製造之Salbatore(註冊商標)ME(含有四克利11.6重量份之液劑)作為含有四克利之液劑。將該製劑設為「製劑W」。Formulation W A Salbatore (registered trademark) ME (a liquid containing 11.6 parts by weight of four keli) manufactured by Arysta Lifescience (stock) was prepared as a liquid containing four keli. Let this formulation be "formulation W".

製劑X 使護汰芬(Sigma公司製造)50重量份溶解於950重量份之二甲基亞碸(東京化成製)中。將該製劑設為「製劑X」。Formulation X Fifty parts by weight of Hutaifen (manufactured by Sigma) was dissolved in 950 parts by weight of dimethylsulfoxide (manufactured by Tokyo Chemical Industry). Let this formulation be "formulation X".

製劑Y 使阿拉酸式苯-S-甲基(和光純藥製造)10重量份溶解於990重量份之二甲基亞碸(東京化成製造)中。將該製劑設為「製劑Y」。Formulation Y 10 parts by weight of aralic benzene-S-methyl (manufactured by Wako Pure Chemical Industries, Ltd.) was dissolved in 990 parts by weight of dimethyl sulfoxide (manufactured by Tokyo Chemical Industry). Let this formulation be "formulation Y".

實施例1 將前述製劑E(百克敏68000ppm、白克列136000ppm)與製劑A(硝基苯酚化合物18000ppm)進行混合，製備本發明組成物之製劑E＋A。Example 1 The aforementioned formulation E (Bacamine 68000 ppm, Baikira 136000 ppm) and formulation A (nitrophenol compound 18000 ppm) were mixed to prepare formulation E+A of the composition of the present invention.

實施例2～35 將製劑E分別替代為表1～6所記載之製劑F、製劑G、製劑H、製劑I、製劑J、製劑K、製劑L、製劑M、製劑N、製劑O、製劑P、製劑Q、製劑R、製劑S、製劑T、製劑U、製劑V、製劑W、製劑X、及製劑Y，除此以外，藉由與實施例1相同之方法分別製備表1～6所記載之稀釋濃度之製劑F＋A、製劑G＋A、製劑H＋A、製劑I＋A、製劑J＋A、製劑K＋A、製劑L＋A、製劑M＋A、製劑N＋A、製劑O＋A、製劑P＋A、製劑Q＋A、製劑R＋A、製劑S＋A、製劑T＋A、製劑U＋A、製劑V＋A、製劑W＋A、製劑X＋A、及製劑Y＋A｡Examples 2～35 Replace formulation E with formulation F, formulation G, formulation H, formulation I, formulation J, formulation K, formulation L, formulation M, formulation N, formulation O, formulation P, formulation Q, formulation described in Tables 1 to 6, respectively Except for R, preparation S, preparation T, preparation U, preparation V, preparation W, preparation X, and preparation Y, the preparations of the dilution concentrations described in Tables 1 to 6 were prepared by the same method as in Example 1 F+A, preparation G+A, preparation H+A, preparation I+A, preparation J+A, preparation K+A, preparation L+A, preparation M+A, preparation N+A, preparation O+A, preparation P+A, preparation Q+A, preparation R+A, preparation S+A, preparation T+A, preparation U+A, preparation V+A, Preparation W+A, preparation X+A, and preparation Y+A.

試驗例1：對於番茄疫病之效力試驗 將生長至約15葉期之番茄(品種：大型福壽)之上位3～5片葉以距離前端5cm之方式剪取併用於試驗。藥劑係將所剪取之枝葉於藥液中進行浸漬處理。處理後，於基礎瓊脂培養基中將葉背朝上進行靜置，進行風乾。番茄疫病菌(Phytophthora infestans)之胞子懸濁液係以成為1×105 之密度之方式利用pH值7.0之磷酸緩衝液所製備。於製備1小時後將胞子懸濁液對剪取葉進行散佈處理。試驗區係每個試驗區設置3個區。管理係於晝：15℃、夜12℃、照明12小時之條件下生長7天。其後，以發病面積對各藥劑之效果進行評價。其結果為表1。Test Example 1: Efficacy test against tomato blight. The upper 3 to 5 leaves of tomato (variety: large Fushou) grown to the 15 leaf stage were cut at a distance of 5 cm from the tip and used for the test. The medicine system immerses the cut branches and leaves in the medicine solution. After the treatment, the leaves are left standing in the basic agar medium with their backs facing up and air-dried. The spore suspension of Phytophthora infestans was prepared with a phosphate buffer of pH 7.0 in a density of 1×10 5 . One hour after preparation, the spore suspension was used to spread the cut leaves. There are 3 zones in each test zone. The management system is grown for 7 days under the conditions of day: 15℃, 12℃ at night and 12 hours of lighting. Thereafter, the effect of each drug was evaluated based on the area of the disease. The results are shown in Table 1.

又，根據Colby式(Weeds, 15, 20-22 (1967))算出本發明之殺菌劑組成物所期待之有效度(E)，求出計算後之有效度(%)。In addition, the expected effectiveness (E) of the fungicide composition of the present invention was calculated according to the Colby formula (Weeds, 15, 20-22 (1967)), and the calculated effectiveness (%) was obtained.

E=x＋y－(x・y/100) 數式中，E係以%表示將硝基苯酚化合物及殺菌活性化合物以各自之濃度p及q使用之情形時所期待之有效度者。x表示將硝基苯酚化合物以濃度p使用時之有效度，y表示將殺菌活性化合物以濃度q使用時之有效度。E=x＋y－(x・y/100) In the formula, E represents the expected effectiveness when the nitrophenol compound and the bactericidal active compound are used at their respective concentrations p and q in %. x represents the effectiveness when the nitrophenol compound is used at the concentration p, and y represents the effectiveness when the bactericidal active compound is used at the concentration q.

將藉由前述Colby式所求出之理論值(%)一併示於表1及表2。表1及表2中之數值係有效度(%)。於本說明書中，若實際上將本發明之硝基苯酚化合物及殺菌活性化合物進行過混合處理時之防除效果高於該E(期待值)，則可謂該組合顯示出協同效應。The theoretical value (%) obtained by the aforementioned Colby formula is shown in Table 1 and Table 2. The values in Table 1 and Table 2 are valid (%). In this specification, if the control effect of the nitrophenol compound and the bactericidal active compound of the present invention is actually higher than the E (expected value) when the nitrophenol compound and the bactericidal active compound of the present invention are mixed, it can be said that the combination shows a synergistic effect.

[表1]

Figure 107146792-A0304-0001
[Table 1]
Figure 107146792-A0304-0001

[表2]

Figure 107146792-A0304-0002
[Table 2]
Figure 107146792-A0304-0002

＜試驗結果＞ 可知本發明之協同性殺菌劑組成物(實施例1～18)之防除率(%)之數值(實測值)比理論值大，具有協同效應。藉由將硝基苯酚化合物與殺菌劑進行併用，與僅既有之殺菌劑時相比，對於農園藝病原菌之防除效果得到了提高。＜Test result＞ It can be seen that the control rate (%) value (measured value) of the synergistic bactericide composition (Examples 1-18) of the present invention is larger than the theoretical value and has a synergistic effect. By using a nitrophenol compound in combination with a fungicide, the effect of preventing and controlling agricultural and horticultural pathogens is improved compared to when only the existing fungicide is used.

試驗例2：對於黃瓜白粉病之效力試驗 於7cm罐中裝填肥料(商品名：愛菜1號、Katakura & Co-op Agri(股)製造)，播種黃瓜。於第3片葉展開之時點選出生長中庸之株來用於試驗。藥劑稀釋後，藉由噴霧器以每株4ml之方式平均地進行散佈，並充分地風乾。黃瓜白粉病(Podosphaera xanthii或Sphaerotheca fuliginea)之胞子懸濁液係以成為1×105 之密度之方式利用pH值7.0之磷酸緩衝液所製備。胞子懸濁液係於株之表面平均地利用噴霧器進行散佈處理。試驗區係每個試驗區設置3個區。於晝：25℃、夜20℃之室內管理7天後，以發病面積來評價各藥劑之效果。其結果示於表3。Test Example 2: Effect test on cucumber powdery mildew A 7 cm pot was filled with fertilizer (trade name: Aicai No. 1, manufactured by Katakura & Co-op Agri (Stock)), and cucumber was sown. At the time when the third leaf was unfolded, the mean-growing plant was selected for the test. After the medicament is diluted, it is spread evenly by a sprayer with 4ml per plant, and it is fully air-dried. The spore suspension of cucumber powdery mildew (Podosphaera xanthii or Sphaerotheca fuliginea) was prepared with a density of 1×10 5 using a phosphate buffer of pH 7.0. The spore suspension is spread evenly on the surface of the strain using a sprayer. There are 3 zones in each test zone. Day: After 7 days of indoor management at 25°C and 20°C at night, the effect of each agent was evaluated by the area of the disease. The results are shown in Table 3.

將與試驗例1同樣地藉由Colby式所求出之理論值(%)一併示於表3。表3中之數值係有效度(%)。The theoretical value (%) calculated by Colby's equation in the same manner as in Test Example 1 is shown in Table 3. The values in Table 3 are valid (%).

[表3]

Figure 107146792-A0304-0003
[table 3]
Figure 107146792-A0304-0003

＜試驗結果＞ 可知本發明之協同性殺菌劑組成物(實施例19)之防除率(%)之數值(實測值)比理論值大，具有協同效應。藉由將硝基苯酚化合物與殺菌劑進行併用，與僅既有之殺菌劑時相比，對於農園藝病原菌之防除效果得到了提高。＜Test result＞ It can be seen that the control rate (%) value (measured value) of the synergistic bactericide composition of the present invention (Example 19) is larger than the theoretical value and has a synergistic effect. By using a nitrophenol compound in combination with a fungicide, the effect of preventing and controlling agricultural and horticultural pathogens is improved compared to when only the existing fungicide is used.

試驗例3：對於黃瓜白粉病之效力試驗 於7cm罐中裝填肥料(商品名：愛菜1號、Katakura & Co-op Agri(股)製造)，播種黃瓜。於第3片葉展開之時點選出生長中庸之株來用於試驗。使下述表4所示之藥劑溶解於Tween(註冊商標)20之10重量%水溶液(水溶液係使用純水)中溶解後，藉由噴霧器以每株4ml之方式平均地散佈，並充分地風乾。黃瓜白粉病(Podosphaera xanthii)之胞子懸濁液係以成為1×105 之密度之方式利用pH值7.0之磷酸緩衝液所製備。胞子懸濁液係於株之表面平均地利用噴霧器進行散佈處理。試驗區係每個試驗區設置3個區。於晝：25℃、夜20℃之室內管理7天後，以發病面積評價各藥劑之效果。其結果示於表3。Test Example 3: Effect test on cucumber powdery mildew A 7 cm pot was filled with fertilizer (trade name: Aicai No. 1, manufactured by Katakura & Co-op Agri (stock)), and cucumber was sown. At the time when the third leaf was unfolded, the mean-growing plant was selected for the test. Dissolve the agents shown in Table 4 below in a 10% by weight aqueous solution of Tween (registered trademark) 20 (pure water is used for the aqueous solution), and then disperse them evenly in 4 ml per plant with a sprayer, and air dry them sufficiently . The spore suspension of cucumber powdery mildew (Podosphaera xanthii) was prepared with a phosphate buffer of pH 7.0 in a density of 1×10 5 . The spore suspension is spread evenly on the surface of the strain using a sprayer. There are 3 zones in each test zone. Day: After 7 days of indoor management at 25°C and 20°C at night, the effect of each agent was evaluated based on the diseased area. The results are shown in Table 3.

將與試驗例1同樣地藉由Colby式所求出之理論值(%)一併示於表4。表4中之數值係有效度(%)。The theoretical value (%) obtained by Colby's equation in the same manner as in Test Example 1 is shown in Table 4. The values in Table 4 are valid (%).

[表4]

Figure 107146792-A0304-0004
[Table 4]
Figure 107146792-A0304-0004

＜試驗結果＞ 可知本發明之協同性殺菌劑組成物(實施例20)之防除率(%)之數值(實測值)比理論值大，具有協同效應。藉由將硝基苯酚化合物與殺菌劑進行併用，與僅既有之殺菌劑時相比，對於農園藝病原菌之防除效果得到了提高。＜Test result＞ It can be seen that the control rate (%) value (measured value) of the synergistic bactericide composition of the present invention (Example 20) is larger than the theoretical value and has a synergistic effect. By using a nitrophenol compound in combination with a fungicide, the effect of preventing and controlling agricultural and horticultural pathogens is improved compared to when only the existing fungicide is used.

試驗例4：對於十字花科黑斑細菌病之效力試驗 使用噴槍(Olympus PB-408、1.0 kgf/cm2 )將製備成下述表5所示之特定濃度之藥劑以6 ml/8株之散佈水量散佈至於裝填有愛菜1號肥料之136孔之孔盤中所生長之約3.5葉期的白菜(無雙)。散佈後，靜置於設定為約25℃之室內(16L/8D)。於散佈2天後，將十字花科黑斑細菌病菌(Pseudomonas cannabina pv. alisalensis)之菌液進行噴霧接種。菌液係使用蒸餾水以成為1×108 cfu/ml之方式進行稀釋所製備。接種後之白菜係於25℃之恆溫高濕室中靜置24小時。其後，靜置於25℃之檢測室中。於接種約7天後，將株整體之發病程度以下述基準進行調查，算出防除效價。 [基準] 0：未發病 1：於葉面積之未滿5%發現發病 2：於葉面積之5%以上且未達25%發現發病 3：於葉面積之25%以上且未達50%發現發病 4：於葉面積之50%以上發現發病 將其結果示於表5。Test Example 4: Effectiveness test for cruciferous black spot bacterial disease. Using a spray gun (Olympus PB-408, 1.0 kgf/cm 2 ), the specific concentration shown in Table 5 below was prepared at 6 ml/8 strains. The amount of spraying water is spread to about 3.5-leaf Chinese cabbage (Wushuang) grown in a 136-hole orifice plate filled with Aicai No. 1 fertilizer. After spreading, place it in a room (16L/8D) set at about 25°C. After spreading for 2 days, spray inoculation with the bacterial solution of Pseudomonas cannabina pv. alisalensis. The bacterial liquid is prepared by diluting distilled water to become 1×10 8 cfu/ml. After the inoculation, the white cuisine was placed in a constant temperature and high humidity room at 25°C for 24 hours. After that, it was placed in a testing room at 25°C. About 7 days after the inoculation, the disease severity of the entire strain was investigated based on the following criteria, and the control potency was calculated. [Criteria] 0: No disease 1: The disease is detected in less than 5% of the leaf area 2: The disease is detected in more than 5% of the leaf area and less than 25% 3: The disease is detected in more than 25% of the leaf area and less than 50% Incidence 4: The disease was found to be more than 50% of the leaf area. The results are shown in Table 5.

將與試驗例1同樣地藉由Colby式所求出之理論值(%)一併示於表5。表5中之數值係有效度(%)。 [表5]

Figure 107146792-A0304-0005
The theoretical value (%) calculated by Colby's equation in the same manner as in Test Example 1 is shown in Table 5. The values in Table 5 are valid (%). [table 5]
Figure 107146792-A0304-0005

＜試驗結果＞ 可知本發明之協同性殺菌劑組成物(實施例21～29)之防除率(%)之數值(實測值)比理論值大，具有協同效應。藉由將硝基苯酚化合物與殺菌劑進行併用，與僅既有之殺菌劑時相比，對於農園藝病原菌之防除效果得到了提高。＜Test result＞ It can be seen that the control rate (%) value (measured value) of the synergistic bactericide composition of the present invention (Examples 21 to 29) is larger than the theoretical value and has a synergistic effect. By using a nitrophenol compound in combination with a fungicide, the effect of preventing and controlling agricultural and horticultural pathogens is improved compared to when only the existing fungicide is used.

試驗例5：對於黃瓜白粉病之效力試驗 使用旋轉散佈塔，將製備成下述表6所示之特定濃度之藥劑以4.52 ml/株之散佈水量散佈至於裝填有愛菜1號肥料之7.5cm罐中生長至1.2葉期之黃瓜(品種：鈴成)。散佈後，於25℃之室內(16L/8D)靜置2天。於散佈2天後，將黃瓜白粉病菌(Podosphaera xanthii)分生子懸濁液2ml進行噴霧接種。分生子懸濁液係藉由將第一葉整體發病白粉病之黃瓜之葉3片浸漬於100ml之0.01%Tween(註冊商標)20水溶液中並振盪30分鐘來進行調整。接種後於平均維持在25℃之室內培養。接種11天後，將株整體之發病程度與無處理區進行比較，藉此算出防除效價。將其結果示於表6。Test Example 5: Effect test on cucumber powdery mildew Using a rotating dispersion tower, disperse the medicine prepared to the specific concentration shown in Table 6 below with a dispersing amount of 4.52 ml/plant to the cucumber (variety: Lingcheng). After spreading, let it stand for 2 days in a room (16L/8D) at 25°C. Two days after spreading, 2 ml of cucumber powdery mildew (Podosphaera xanthii) meristem suspension was sprayed inoculated. The meristem suspension was adjusted by immersing 3 leaves of cucumber with powdery mildew on the first leaf in 100 ml of 0.01% Tween (registered trademark) 20 aqueous solution and shaking for 30 minutes. After inoculation, they were cultured in an average room maintained at 25°C. Eleven days after the inoculation, the disease severity of the entire strain was compared with the untreated area to calculate the control titer. The results are shown in Table 6.

將與試驗例1同樣地藉由Colby式所求出之理論值(%)一併示於表6。表6中之數值係有效度(%)。 [表6]

Figure 107146792-A0304-0006
The theoretical value (%) obtained by Colby's equation in the same manner as in Test Example 1 is shown in Table 6. The values in Table 6 are validity (%). [Table 6]
Figure 107146792-A0304-0006

＜試驗結果＞ 可知本發明之協同性殺菌劑組成物(實施例30～35)之防除率(%)之數值(實測值)比理論值大，具有協同效應。藉由將硝基苯酚化合物與殺菌劑進行併用，與僅既有之殺菌劑時相比，對於農園藝病原菌之防除效果得到了提高。＜Test result＞ It can be seen that the control rate (%) value (measured value) of the synergistic bactericide composition of the present invention (Examples 30 to 35) is larger than the theoretical value, and has a synergistic effect. By using a nitrophenol compound in combination with a fungicide, the effect of preventing and controlling agricultural and horticultural pathogens is improved compared to when only the existing fungicide is used.

Claims (7)

一種協同性殺菌劑組成物，其含有(A)硝基苯酚化合物及(B)殺菌活性化合物；前述(A)硝基苯酚化合物為具有1個硝基之苯酚化合物，且為下述通式(2)所表示之硝基苯酚化合物或其鹽，
Figure 107146792-A0305-02-0072-1
 (式中，R1、R2、R3、R4、及R5基相同或不同，表示氫原子、鹵素原子、羥基、硝基、C1~6烷基、C1~6鹵烷基、C1~6烷氧基、C1~6鹵烷氧基、C2~6烯基、C2~6鹵烯基、C2~6烯氧基、C2~6鹵烯氧基、C2~6炔基、C2~6鹵炔基、C2~6炔氧基、或C2~6鹵炔氧基)；及前述(B)殺菌活性化合物為選自於由下述所構成群組中之至少一種化合物，(b1)作為RNA聚合酶抑制劑(A1)之醯基丙胺酸化合物、(b2)作為β-微管蛋白聚合抑制劑(B3)之乙基胺基噻唑甲醯胺化合物、 (b3)作為類血影蛋白蛋白質之非定域化劑(B5)之吡啶基甲基苯甲醯胺化合物、(b4)作為呼吸鏈複合體II(琥珀酸脫氫酶)抑制劑(C2)之吡啶甲醯胺化合物、(b5)作為呼吸鏈複合體III(泛醌醇(ubiquinol)氧化酶、Qo位點)抑制劑(C3)之甲氧基胺基甲酸酯化合物(惟，排除百克敏(pyraclostrobin))、甲氧基丙烯酸酯化合物、及氧亞胺基乙酸化合物、
Figure 107146792-A0305-02-0073-4
唑啶二酮(oxazolidinedione)化合物、(b6)作為呼吸鏈複合體III(泛醌還原酶、Qi位點)抑制劑(C4)之氰基咪唑化合物、(b7)作為氧化性磷酸化中之解偶聯劑(C5)之2,6-二硝基苯胺化合物、(b8)作為呼吸鏈複合體III(泛醌還原酶、Qo位點)抑制劑(C8)之三唑并嘧啶胺化合物、(b10)作為細胞膜滲透性之脂肪酸(F4)之胺基甲酸酯化合物、(b11)作為脂質之恆定性、轉移、蓄積之抑制劑(F9)之哌啶基噻唑異
Figure 107146792-A0305-02-0073-5
唑啉化合物、(b12)作為固醇生物合成中之C14位之去甲基化抑制劑(G1)之三唑化合物、及咪唑化合物、(b13)作為纖維素合成酶抑制劑(H5)之桂皮酸醯胺化合物、及苦杏仁酸醯胺化合物、(b17)作為以多作用位點為目標之化合物(M1、3、5) 之銅化合物、二硫代胺基甲酸酯化合物(惟，排除鋅錳乃浦(mancozeb))、及氯腈(chloronitrile)化合物、(b18)作為宿主植物之抵抗性誘導劑(P1、7)之苯并噻二唑化合物、乙基膦酸鹽化合物、及氯腈化合物、及(b19)作為作用機制不明之化合物(U)之氰基乙醯胺肟化合物。 A synergistic bactericide composition containing (A) a nitrophenol compound and (B) a bactericidal active compound; the aforementioned (A) nitrophenol compound is a phenol compound with one nitro group, and is of the following general formula ( 2) The represented nitrophenol compound or its salt,
Figure 107146792-A0305-02-0072-1
 (In the formula, R 1 , R 2 , R 3 , R 4 , and R 5 are the same or different, and represent a hydrogen atom, a halogen atom, a hydroxyl group, a nitro group, a C 1-6 alkyl group, and a C 1-6 haloalkyl group , C 1~6 alkoxy, C 1~6 haloalkoxy, C 2~6 alkenyl, C 2~6 haloalkenyl, C 2~6 alkenyloxy, C 2~6 haloalkenyloxy, C 2~6 alkynyl, C 2~6 haloalkynyl, C 2~6 alkynyloxy, or C 2~6 haloalkynyloxy); and the aforementioned (B) bactericidal active compound is selected from the following At least one compound constituting the group, (b1) an alanine compound as an RNA polymerase inhibitor (A1), and (b2) an ethylaminothiazole as a β-tubulin polymerization inhibitor (B3) Amide compound, (b3) as a delocalization agent of spectrin-like protein (B5) pyridylmethylbenzamide compound, (b4) as a respiratory chain complex II (succinate dehydrogenase) inhibition (C2) picolinamide compound, (b5) as respiratory chain complex III (ubiquinol (ubiquinol) oxidase, Qo site) inhibitor (C3) methoxy carbamate compound ( However, excluding pyraclostrobin), methoxy acrylate compounds, and oxyimino acetic acid compounds,
Figure 107146792-A0305-02-0073-4
Oxazolidinedione compound, (b6) as a respiratory chain complex III (ubiquinone reductase, Qi site) inhibitor (C4) as a cyanoimidazole compound, (b7) as a solution in oxidative phosphorylation Coupling agent (C5) 2,6-dinitroaniline compound, (b8) as respiratory chain complex III (ubiquinone reductase, Qo site) inhibitor (C8) triazolopyrimidine compound, ( b10) Carbamate compound of fatty acid (F4) as cell membrane permeability, (b11) piperidinyl thiazole is used as inhibitor of lipid stability, transfer and accumulation (F9)
Figure 107146792-A0305-02-0073-5
Oxazoline compounds, (b12) triazole compounds as C14 demethylation inhibitors (G1) in sterol biosynthesis, and imidazole compounds, (b13) cinnamon as cellulose synthase inhibitors (H5) Acid amide compounds, and mandelic acid amide compounds, (b17) as the target compound (M1, 3, 5) copper compounds, dithiocarbamate compounds (except Mancozeb (mancozeb), chloronitrile compounds, (b18) benzothiadiazole compounds, ethyl phosphonate compounds, and chlorine as host plant resistance inducers (P1, 7) Nitrile compound, and (b19) cyanoacetamide oxime compound as compound (U) whose mechanism of action is unknown. 如請求項1之協同性殺菌劑組成物，其中(B)殺菌活性化合物為選自於由滅達樂(metalaxyl)、右滅達樂(metalaxyl-M)、白克列(boscalid)、、亞托敏(Azoxystrobin)、三氟敏(trifloxystrobin)、克收欣(kresoxim-methyl)、啶氧菌酯(picoxystrobin)、賽座滅(cyazofamid)、凡殺同(famoxadone)、辛唑嘧菌胺(ametoctradin)、扶吉胺(fluazinam)、四克利(tetraconazole)、富馬酸
Figure 107146792-A0305-02-0074-6
咪唑(oxpoconazole fumarate)、護汰芬(flutriafol)、四氯異苯(chlorothalonil)、、達滅芬(dimethomorph)、曼普胺(mandipropamid)、噻唑菌胺(ethaboxam)、阿拉酸式苯-S-甲基(acibenzolar-S-methyl)、氟吡菌胺(fluopicolide)、霜黴威鹽酸鹽(propamocarb hydrochloride salt)、福賽得(fosetyl-al)、亞磷酸或其鹽、噻哌菌靈(oxathiapiproline)、壬基苯酚磺酸銅鹽、及克絕(cymoxanil)所構成群組中之至少一種化合物。 Such as the synergistic bactericide composition of claim 1, wherein (B) the bactericidal active compound is selected from the group consisting of metalaxyl, metalaxyl-M, boscalid, and Azoxystrobin, trifloxystrobin, kresoxim-methyl, picoxystrobin, cyazofamid, famoxadone, oxazoxystrobin ametoctradin), fluazinam, tetraconazole, fumaric acid
Figure 107146792-A0305-02-0074-6
Imidazole (oxpoconazole fumarate), flutriafol, chlorothalonil, dimethomorph, mandipropamid, ethaboxam (ethaboxam), azoxybenzene-S- Methyl (acibenzolar-S-methyl), fluopicolide, propamocarb hydrochloride salt, fosetyl-al, phosphorous acid or its salt, thioperanil ( oxathiapiproline), copper nonylphenol sulfonate, and at least one compound in the group consisting of cymoxanil. 如請求項1或2之協同性殺菌劑組成物，其中(A)硝基苯酚化合物之摻合比率相對於(B)殺菌活性 成分100重量份為1~5000重量份。 Such as the synergistic bactericide composition of claim 1 or 2, wherein the blending ratio of (A) nitrophenol compound is relative to (B) bactericidal activity 100 parts by weight of the ingredients are 1 to 5000 parts by weight. 一種病原菌防除方法，其特徵在於以如請求項1或2之協同性殺菌劑組成物對農園藝病原菌之生存場所(人類除外)進行處理。 A method for controlling pathogenic bacteria, which is characterized in that the living place (except for humans) of agricultural and horticultural pathogenic bacteria is treated with the synergistic fungicide composition as claimed in claim 1 or 2. 一種植物保護方法，其特徵在於以如請求項1或2之協同性殺菌劑組成物對農園藝病原菌所寄生之植物或其附近進行處理。 A method for plant protection, characterized in that the synergistic fungicide composition as claimed in claim 1 or 2 is used to treat plants parasitized by agricultural and horticultural pathogens or their vicinity. 一種硝基苯酚化合物之使用方法，其係用以增強殺菌活性化合物之殺菌活性者(對於人類之應用除外)；前述硝基苯酚化合物為具有1個硝基之苯酚化合物，且為下述通式(2)所表示之硝基苯酚化合物或其鹽，
Figure 107146792-A0305-02-0075-2
 (式中，R1、R2、R3、R4、及R5基相同或不同，表示氫原子、鹵素原子、羥基、硝基、C1~6烷基、C1~6鹵烷基、C1~6烷氧基、C1~6鹵烷氧基、C2~6烯基、C2~6鹵烯基、C2~6烯氧基、C2~6鹵烯氧基、C2~6炔基、C2~6鹵炔基、 C2~6炔氧基、或C2~6鹵炔氧基)；及前述殺菌活性化合物為選自於由滅達樂、右滅達樂、白克列、亞托敏、三氟敏、克收欣、啶氧菌酯、賽座滅、凡殺同、辛唑嘧菌胺、扶吉胺、四克利、富馬酸
Figure 107146792-A0305-02-0076-7
咪唑、護汰芬、四氯異苯、達滅芬、曼普胺、噻唑菌胺、阿拉酸式苯-S-甲基、氟吡菌胺、霜黴威鹽酸鹽、福賽得、亞磷酸或其鹽、噻哌菌靈、壬基苯酚磺酸銅鹽、及克絕所構成群組中之至少一種化合物。 A method for using nitrophenol compounds, which is used to enhance the bactericidal activity of bactericidal active compounds (except for human applications); the aforementioned nitrophenol compound is a phenol compound with 1 nitro group and is of the following general formula (2) The nitrophenol compound or salt thereof,
Figure 107146792-A0305-02-0075-2
 (In the formula, R 1 , R 2 , R 3 , R 4 , and R 5 are the same or different, and represent a hydrogen atom, a halogen atom, a hydroxyl group, a nitro group, a C 1-6 alkyl group, and a C 1-6 haloalkyl group , C 1~6 alkoxy, C 1~6 haloalkoxy, C 2~6 alkenyl, C 2~6 haloalkenyl, C 2~6 alkenyloxy, C 2~6 haloalkenyloxy, C 2~6 alkynyl, C 2~6 haloalkynyl, C 2~6 alkynyloxy, or C 2~6 haloalkynyloxy); and the aforementioned bactericidal active compound is selected from the group consisting of metronidazole and dexamethasone Dalak, Bekley, Yatomin, Trifluramine, Keshouxin, Picoxystrobin, Cerazolin, Fanshatong, Oxystrobin, Fugemide, Tetraclimate, Fumaric Acid
Figure 107146792-A0305-02-0076-7
Imidazole, Hutaifen, Tetrachloroisophenyl, Dametifene, Mamprol, ethaboxam, Alafenac-S-methyl, fluopyram, propamocarb hydrochloride, forsaide, sub At least one compound in the group consisting of phosphoric acid or its salt, thiaperbendazole, copper nonylphenol sulfonate, and KJJ 一種殺菌活性增強劑，其係對殺菌活性化合物含有硝基苯酚化合物者；前述硝基苯酚化合物為具有1個硝基之苯酚化合物，且為下述通式(2)所表示之硝基苯酚化合物或其鹽，
Figure 107146792-A0305-02-0076-3
 (式中，R1、R2、R3、R4、及R5基相同或不同，表示氫原子、鹵素原子、羥基、硝基、C1~6烷基、C1~6鹵烷基、C1~6烷氧基、C1~6鹵烷氧基、C2~6烯基、C2~6鹵烯基、C2~6烯氧基、C2~6鹵烯氧基、C2~6炔基、C2~6鹵炔基、 C2~6炔氧基、或C2~6鹵炔氧基)；及前述殺菌活性化合物為選自於由滅達樂、右滅達樂、白克列、亞托敏、三氟敏、克收欣、啶氧菌酯、賽座滅、凡殺同、辛唑嘧菌胺、扶吉胺、四克利、富馬酸
Figure 107146792-A0305-02-0077-8
咪唑、護汰芬、四氯異苯、達滅芬、曼普胺、噻唑菌胺、阿拉酸式苯-S-甲基、氟吡菌胺、霜黴威鹽酸鹽、福賽得、亞磷酸或其鹽、噻哌菌靈、壬基苯酚磺酸銅鹽、及克絕所構成群組中之至少一種化合物。 A bactericidal activity enhancer, which contains a nitrophenol compound to the bactericidal active compound; the aforementioned nitrophenol compound is a phenol compound with one nitro group, and is a nitrophenol compound represented by the following general formula (2) Or its salt,
Figure 107146792-A0305-02-0076-3
 (In the formula, R 1 , R 2 , R 3 , R 4 , and R 5 are the same or different, and represent a hydrogen atom, a halogen atom, a hydroxyl group, a nitro group, a C 1-6 alkyl group, and a C 1-6 haloalkyl group , C 1~6 alkoxy, C 1~6 haloalkoxy, C 2~6 alkenyl, C 2~6 haloalkenyl, C 2~6 alkenyloxy, C 2~6 haloalkenyloxy, C 2~6 alkynyl, C 2~6 haloalkynyl, C 2~6 alkynyloxy, or C 2~6 haloalkynyloxy); and the aforementioned bactericidal active compound is selected from the group consisting of metronidazole and dexamethasone Dalak, Bekley, Yatomin, Trifluramine, Keshouxin, Picoxystrobin, Cerazolin, Fanshatong, Oxystrobin, Fugemide, Tetraclimate, Fumaric Acid
Figure 107146792-A0305-02-0077-8
Imidazole, Hutaifen, Tetrachloroisophenyl, Dametifene, Mamprol, ethaboxam, Alafenac-S-methyl, fluopyram, propamocarb hydrochloride, forsaide, sub At least one compound in the group consisting of phosphoric acid or its salt, thiaperbendazole, copper nonylphenol sulfonate, and KJJ.
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