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TWI796679B - Positive dielectric anisotropy liquid crystal composition, liquid crystal display element or liquid crystal display - Google Patents

Positive dielectric anisotropy liquid crystal composition, liquid crystal display element or liquid crystal display Download PDF

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TWI796679B
TWI796679B TW110115363A TW110115363A TWI796679B TW I796679 B TWI796679 B TW I796679B TW 110115363 A TW110115363 A TW 110115363A TW 110115363 A TW110115363 A TW 110115363A TW I796679 B TWI796679 B TW I796679B
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邢杰浩
王奎
李佳明
鄭曉闊
喬雲霞
鮑永鋒
李明
員國良
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大陸商石家莊誠志永華顯示材料有限公司
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    • C09K19/00—Liquid crystal materials
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    • C09K19/42—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40
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    • G—PHYSICS
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    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/137—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering

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Abstract

本發明公開了一種正介電各向異性向列相液晶組合物，所述液晶組合物包含一種或多種式Ⅰ所示的化合物、以及一種或多種式Ⅱ所示的化合物。該組合物兼具高的透過率、高的介電各向異性、較高的光學各向異性、高的垂直介電各向異性、高的ε ⊥/Δε比值，較寬的向列相溫度範圍，以及抗紫外抗高溫能力強，無殘像缺陷等特徵。本發明還公開了包含該液晶組合物的液晶顯示元件和液晶顯示器。

Figure 110115363-A0101-11-0001-1
；
Figure 110115363-A0101-11-0001-2
。 The invention discloses a positive dielectric anisotropy nematic phase liquid crystal composition, which comprises one or more compounds represented by formula I and one or more compounds represented by formula II. The composition has high transmittance, high dielectric anisotropy, high optical anisotropy, high perpendicular dielectric anisotropy, high ε ⊥ /Δε ratio, wide nematic phase temperature range, as well as strong UV and high temperature resistance, no afterimage defects and other characteristics. The invention also discloses a liquid crystal display element and a liquid crystal display comprising the liquid crystal composition.
Figure 110115363-A0101-11-0001-1
;
Figure 110115363-A0101-11-0001-2
.

Description

正介電各向異性液晶組合物、液晶顯示元件或液晶顯示器Positive dielectric anisotropy liquid crystal composition, liquid crystal display element or liquid crystal display

本發明涉及液晶材料技術領域。更具體地，涉及一種正介電各向異性液晶組合物、液晶顯示元件或液晶顯示器。The invention relates to the technical field of liquid crystal materials. More specifically, it relates to a liquid crystal composition with positive dielectric anisotropy, a liquid crystal display element or a liquid crystal display.

隨著顯示技術的發展，液晶顯示器(Liquid Crystal Display，LCD)等平面顯示裝置因具有高畫質、省電、機身薄及應用範圍廣等優點，而被廣泛的應用於手機、電視、個人數位助理、數位相機、筆記型電腦、桌上型電腦等各種消費性電子產品，成為顯示裝置中的主流。With the development of display technology, liquid crystal displays (Liquid Crystal Display, LCD) and other flat display devices are widely used in mobile phones, televisions, personal Various consumer electronic products such as digital assistants, digital cameras, notebook computers, and desktop computers have become the mainstream of display devices.

隨著數位資訊技術的不斷提高，消費者對液晶顯示裝置的顯示性能有了更高的追求。在筆記型電腦顯示領域，屏占比越來越大，已經從16:9過渡到了16:10，並向更大的顯示面積發展，最終成為全面屏顯示。而伴隨顯示面積的增大，顯示裝置的解析度也需要不斷提高，才能滿足高畫質的需求。2K解析度，乃至4K解析度將逐漸成為主流的筆記型電腦產品必備顯示需求。然而，高解析度導致顯示面板開口率下降，亮度和對比度都將受其影響，出現明顯的下降。With the continuous improvement of digital information technology, consumers have higher pursuit for the display performance of liquid crystal display devices. In the field of notebook computer display, the screen-to-body ratio is getting larger and larger, and has transitioned from 16:9 to 16:10, and is developing to a larger display area, and finally becomes a full-screen display. With the increase of the display area, the resolution of the display device also needs to be continuously improved in order to meet the requirement of high image quality. 2K resolution, and even 4K resolution will gradually become a must-have display requirement for mainstream notebook computer products. However, the high resolution leads to a decrease in the aperture ratio of the display panel, and both brightness and contrast will be affected by it, resulting in a significant decrease.

因此，開發具有高透過率的液晶組合物，以滿足高解析度要求的筆記型電腦顯示面板是亟待解決的技術問題。Therefore, it is an urgent technical problem to develop a liquid crystal composition with high transmittance to meet the high-resolution display panel of a notebook computer.

基於以上事實，本發明的第一個目的在於提供一種兼具高的透過率、高的介電各向異性、較高的光學各向異性、高的垂直介電各向異性、高的ε ⊥/Δε比值，較寬的向列相溫度範圍，以及抗紫外抗高溫能力強，無殘像缺陷的液晶組合物，將其用於高解析度顯示元器件中時，不會降低顯示面板的開口率、亮度和對比度等。 Based on the above facts, the first object of the present invention is to provide a high transmittance, high dielectric anisotropy, high optical anisotropy, high vertical dielectric anisotropy, high ε ⊥ /Δε ratio, wide temperature range of nematic phase, strong UV resistance and high temperature resistance, liquid crystal composition without afterimage defect, when it is used in high-resolution display components, it will not reduce the opening of the display panel rate, brightness and contrast etc.

本發明的第二個目的在於提供一種液晶顯示元件。The second object of the present invention is to provide a liquid crystal display element.

本發明的第三個目的在於提供一種液晶顯示器。The third object of the present invention is to provide a liquid crystal display.

為達到上述第一個目的，本發明採用下述技術方案： 一種正介電各向異性向列相液晶組合物，所述液晶組合物包含一種或多種式Ⅰ所示的化合物、以及一種或多種式Ⅱ所示的化合物：

Figure 02_image001
Ⅰ；
Figure 02_image003
Ⅱ； 其中， R 1表示碳原子數為1-10的烷基；Y 1表示CF 3或OCF 3； R 2、R 3各自獨立地表示碳原子數為1-10的烷基、氟取代的碳原子數為1-10的烷基、碳原子數為1-10的烷氧基、氟取代的碳原子數為1-10的烷氧基、碳原子數為2-10的鏈烯基、氟取代的碳原子數為2-10的鏈烯基、碳原子數為3-8的鏈烯氧基或氟取代的碳原子數為3-8的鏈烯氧基，並且R 2所示基團中任意一個或多個-CH 2-任選被亞環戊基、亞環丁基或亞環丙基替代；Z表示-O-或-S-。 In order to achieve the above-mentioned first object, the present invention adopts the following technical scheme: A kind of positive dielectric anisotropy nematic phase liquid crystal composition, said liquid crystal composition comprises one or more compounds shown in formula I, and one or more Compound shown in formula II:
Figure 02_image001
I;
Figure 02_image003
II; wherein, R 1 represents an alkyl group with 1-10 carbon atoms; Y 1 represents CF 3 or OCF 3 ; R 2 and R 3 independently represent an alkyl group with 1-10 carbon atoms, fluorine-substituted Alkyl group with 1-10 carbon atoms, alkoxy group with 1-10 carbon atoms, alkoxy group with 1-10 carbon atoms substituted by fluorine, alkenyl group with 2-10 carbon atoms, Alkenyl group with 2-10 carbon atoms substituted by fluorine, alkenyloxy group with 3-8 carbon atoms or alkenyloxy group with 3-8 carbon atoms substituted by fluorine, and the group represented by R Any one or more -CH 2 - in the group is optionally replaced by cyclopentylene, cyclobutylene or cyclopropylene; Z represents -O- or -S-.

進一步地，所述式Ⅰ所示的化合物選自式Ⅰ1至Ⅰ6所示的化合物組成的組：

Figure 02_image005
Ⅰ1；
Figure 02_image007
Ⅰ2；
Figure 02_image009
Ⅰ3；
Figure 02_image011
Ⅰ4；
Figure 02_image013
Ⅰ5；
Figure 02_image015
Ⅰ6。 Further, the compound represented by the formula I is selected from the group consisting of compounds represented by the formulas I1 to I6:
Figure 02_image005
I1;
Figure 02_image007
I2;
Figure 02_image009
I3;
Figure 02_image011
I4;
Figure 02_image013
I5;
Figure 02_image015
I6.

進一步地，所述式Ⅱ所示的化合物選自式Ⅱ1至Ⅱ6所示的化合物組成的組：

Figure 02_image017
Ⅱ1；
Figure 02_image019
Ⅱ2；
Figure 02_image021
Ⅱ3；
Figure 02_image023
Ⅱ4；
Figure 02_image025
Ⅱ5；
Figure 02_image027
Ⅱ6； 其中，R 21、R 31各自獨立地表示碳原子數為1~6的烷基。 Further, the compound represented by formula II is selected from the group consisting of compounds represented by formula II1 to II6:
Figure 02_image017
II1;
Figure 02_image019
II2;
Figure 02_image021
II3;
Figure 02_image023
II4;
Figure 02_image025
II5;
Figure 02_image027
II6; wherein, R 21 and R 31 each independently represent an alkyl group having 1 to 6 carbon atoms.

進一步地，所述液晶組合物還包含一種或多種式Ⅲ所示的化合物：

Figure 02_image029
Ⅲ； 其中，R 4、R 5各自獨立地表示碳原子數為1~10的烷基、碳原子數為1~10的烷氧基、碳原子數為2~10的烯基或碳原子數為3~8的烯氧基；
Figure 02_image031
、
Figure 02_image033
各自獨立的表示
Figure 02_image035
或
Figure 02_image037
。 Further, the liquid crystal composition also includes one or more compounds represented by formula III:
Figure 02_image029
Ⅲ; wherein, R 4 and R 5 each independently represent an alkyl group with 1 to 10 carbon atoms, an alkoxy group with 1 to 10 carbon atoms, an alkenyl group with 2 to 10 carbon atoms, or an alkenyl group with 1 to 10 carbon atoms 3-8 alkenyloxy groups;
Figure 02_image031
,
Figure 02_image033
independent expression
Figure 02_image035
or
Figure 02_image037
.

進一步地，所述液晶組合物還包含一種或多種式Ⅳ所示的化合物：

Figure 02_image039
Ⅳ； 其中，R 6表示碳原子數為1~10的烷基、碳原子數為1~10的烷氧基、碳原子數為2~10的烯基或碳原子數為3~8的烯氧基，且R 6所示基團中任意一個或多個-CH 2-被任選的亞環戊基、亞環丁基或亞環丙基替代；
Figure 02_image041
、
Figure 02_image043
各自獨立地表示
Figure 02_image035
、
Figure 02_image037
、
Figure 02_image045
、
Figure 02_image047
或
Figure 02_image049
； X 1、X 2各自獨立地表示H或F；Y 2表示-F、-CF 3或-OCF 3；m表示1或2, 當m表示2時，
Figure 02_image041
可以相同或不同。 Further, the liquid crystal composition also includes one or more compounds represented by formula IV:
Figure 02_image039
Ⅳ; wherein, R 6 represents an alkyl group with 1 to 10 carbon atoms, an alkoxy group with 1 to 10 carbon atoms, an alkenyl group with 2 to 10 carbon atoms or an alkenyl group with 3 to 8 carbon atoms Oxygen, and any one or more -CH 2 - in the group represented by R 6 is replaced by an optional cyclopentylene, cyclobutylene or cyclopropylene;
Figure 02_image041
,
Figure 02_image043
express independently
Figure 02_image035
,
Figure 02_image037
,
Figure 02_image045
,
Figure 02_image047
or
Figure 02_image049
; X 1 and X 2 independently represent H or F; Y 2 represents -F, -CF 3 or -OCF 3 ; m represents 1 or 2, when m represents 2,
Figure 02_image041
Can be the same or different.

進一步地，所述液晶組合物還包含一種或多種式Ⅴ所示的化合物：

Figure 02_image051
Ⅴ； 其中，R 7、R 8各自獨立地表示碳原子數為1~10的烷基、碳原子數為1~10的烷氧基、碳原子數為2~10的烯基、氟取代的碳原子數為2~10的烯基、碳原子數為3~8的烯氧基或氟取代的碳原子數為3~8的烯氧基，且R 7、R 8中任意一個或多個互不相鄰的-CH 2-被任選的亞環戊基、亞環丁基或亞環丙基取代； Z 1表示表示單鍵或-CH 2O-；
Figure 02_image053
、
Figure 02_image055
各自獨立地表示
Figure 02_image035
、
Figure 02_image037
或
Figure 02_image057
； q表示1或2；n表示0或1； 當q表示2時，
Figure 02_image053
可以相同或不同。 Further, the liquid crystal composition also includes one or more compounds represented by formula V:
Figure 02_image051
V; wherein, R 7 and R 8 each independently represent an alkyl group with 1 to 10 carbon atoms, an alkoxy group with 1 to 10 carbon atoms, an alkenyl group with 2 to 10 carbon atoms, or a fluorine-substituted Alkenyl with 2 to 10 carbon atoms, alkenyloxy with 3 to 8 carbon atoms, or alkenyloxy with 3 to 8 carbon atoms substituted by fluorine, and any one or more of R 7 and R 8 -CH 2 - that are not adjacent to each other are optionally substituted by cyclopentylene, cyclobutylene or cyclopropylene; Z 1 represents a single bond or -CH 2 O-;
Figure 02_image053
,
Figure 02_image055
express independently
Figure 02_image035
,
Figure 02_image037
or
Figure 02_image057
; q means 1 or 2; n means 0 or 1; when q means 2,
Figure 02_image053
Can be the same or different.

進一步地，所述式Ⅴ所示的化合物選自式Ⅴ1至Ⅴ8所示的化合物組成的組：

Figure 02_image059
Ⅴ1；
Figure 02_image061
Ⅴ2；
Figure 02_image063
Ⅴ3；
Figure 02_image065
Ⅴ4；
Figure 02_image067
Ⅴ5；
Figure 02_image069
Ⅴ6；
Figure 02_image071
Ⅴ7；
Figure 02_image073
Ⅴ8； 其中，R 7、R 8各自獨立地表示碳原子數為1~5的烷基、碳原子數為1~5的烷氧基，且R 7中任意一個或多個互不相鄰的-CH 2-被任選的亞環戊基、亞環丁基或亞環丙基取代。 Further, the compound represented by the formula V is selected from the group consisting of compounds represented by the formulas V1 to V8:
Figure 02_image059
V1;
Figure 02_image061
V2;
Figure 02_image063
V3;
Figure 02_image065
V4;
Figure 02_image067
V5;
Figure 02_image069
V6;
Figure 02_image071
V7;
Figure 02_image073
V8; wherein, R 7 and R 8 each independently represent an alkyl group with 1 to 5 carbon atoms, an alkoxy group with 1 to 5 carbon atoms, and any one or more of R 7 that are not adjacent to each other -CH2- is optionally substituted by cyclopentylene, cyclobutylene or cyclopropylene.

進一步地，所述液晶組合物還包含一種或多種式Ⅵ所示的化合物：

Figure 02_image075
Ⅵ； 其中，R 9表示碳原子數為1-10的烷基、碳原子數為1-10的烷氧基、碳原子數為2-10的烯基、碳原子數為3-8的鏈烯氧基，且R 9所示基團中任意一個或多個不相連的-CH 2-任選被亞環戊基、亞環丁基或亞環丙基取代；
Figure 02_image077
、
Figure 02_image079
各自獨立地表示
Figure 02_image035
、
Figure 02_image037
、
Figure 02_image045
、
Figure 02_image049
、
Figure 02_image081
或
Figure 02_image083
； p表示1或2；當p表示2時，
Figure 02_image077
可以相同或不同；X 3、X 4各自獨立地表示H或F。 Further, the liquid crystal composition also includes one or more compounds represented by formula VI:
Figure 02_image075
Ⅵ; wherein, R 9 represents an alkyl group with 1-10 carbon atoms, an alkoxy group with 1-10 carbon atoms, an alkenyl group with 2-10 carbon atoms, a chain with 3-8 carbon atoms Alkenyloxy, and any one or more unconnected -CH 2 - in the group represented by R 9 is optionally substituted by cyclopentylene, cyclobutylene or cyclopropylene;
Figure 02_image077
,
Figure 02_image079
express independently
Figure 02_image035
,
Figure 02_image037
,
Figure 02_image045
,
Figure 02_image049
,
Figure 02_image081
or
Figure 02_image083
; p means 1 or 2; when p means 2,
Figure 02_image077
may be the same or different; X 3 and X 4 each independently represent H or F.

進一步地，所述液晶組合物還包含一種或多種選自式Ⅶ1至式Ⅶ5所示的化合物：

Figure 02_image085
Ⅶ1；
Figure 02_image087
Ⅶ2；
Figure 02_image089
Ⅶ3；
Figure 02_image091
Ⅶ4；
Figure 02_image093
Ⅶ5； 其中，R 10表示碳原子數為1-10的烷基，且R 10所示基團中任意一個或多個不相連的-CH 2-任選被亞環戊基、亞環丁基或亞環丙基取代；R 11表示碳原子數為1-10的烷氧基。 Further, the liquid crystal composition further comprises one or more compounds selected from formula VII1 to formula VII5:
Figure 02_image085
VII1;
Figure 02_image087
VII2;
Figure 02_image089
VII 3;
Figure 02_image091
VII4;
Figure 02_image093
VII5; Wherein, R 10 represents an alkyl group with 1-10 carbon atoms, and any one or more unconnected -CH 2 - in the group represented by R 10 is optionally replaced by cyclopentylene, cyclobutylene or cyclopropylene; R 11 represents an alkoxy group with 1-10 carbon atoms.

本發明還提供一種液晶顯示元件，其包含本發明的液晶組合物，所述液晶顯示元件為有源矩陣定址顯示元件或者無源矩陣定址顯示元件。The present invention also provides a liquid crystal display element, which contains the liquid crystal composition of the present invention, and the liquid crystal display element is an active matrix addressable display element or a passive matrix addressable display element.

本發明還提供一種液晶顯示器，其包含本發明的液晶組合物，所述液晶顯示器為有源矩陣定址顯示器或者無源矩陣定址顯示器。The present invention also provides a liquid crystal display comprising the liquid crystal composition of the present invention, and the liquid crystal display is an active matrix addressing display or a passive matrix addressing display.

本發明的有益效果如下：本發明提供的液晶組合物具有高的透過率、較高的光學各向異性、高的介電各向異性、高的垂直介電常數、高的ε⊥/Δε比值，較寬的向列相溫度範圍，以及抗紫外抗高溫能力強，無殘像缺陷，尤其適用於高解析度（如2K或者更高解析度）的液晶顯示元器件中，不會因為高解析度導致顯示面板開口率下降，進而導致亮度和對比度明顯的下降的問題出現。 本發明的液晶顯示元件、液晶顯示器通過包含前述的本發明的液晶組合物，具有高的對比度、面板輕薄、能耗低、較寬的使用溫度範圍，以及良好的信賴性。 The beneficial effects of the present invention are as follows: the liquid crystal composition provided by the present invention has high transmittance, high optical anisotropy, high dielectric anisotropy, high vertical permittivity, and high ε⊥/Δε ratio , wide temperature range of nematic phase, strong ability of anti-ultraviolet and high temperature resistance, no afterimage defects, especially suitable for high-resolution (such as 2K or higher resolution) liquid crystal display components, and will not be affected by high-resolution The lower the aperture ratio of the display panel, the lower the brightness and the contrast ratio. The liquid crystal display element and the liquid crystal display of the present invention contain the aforementioned liquid crystal composition of the present invention, and have high contrast, light and thin panel, low energy consumption, wide service temperature range, and good reliability.

為了更清楚地說明本發明，下面結合優選實施例對本發明做進一步的說明。本領域技術人員應當理解，下面所具體描述的內容是說明性的而非限制性的，不應以此限制本發明的保護範圍。In order to illustrate the present invention more clearly, the present invention will be further described below in conjunction with preferred embodiments. Those skilled in the art should understand that the content specifically described below is illustrative rather than restrictive, and should not limit the protection scope of the present invention.

[[ 液晶組合物liquid crystal composition ]]

一種正介電各向異性向列相液晶組合物，所述液晶組合物包含一種或多種式Ⅰ所示的化合物、以及一種或多種式Ⅱ所示的化合物：

Figure 02_image001
Ⅰ；
Figure 02_image003
Ⅱ； 其中，R 1表示碳原子數為1-10的烷基；Y 1表示CF 3或OCF 3；R 2、R 3各自獨立地表示碳原子數為1-10的烷基、氟取代的碳原子數為1-10的烷基、碳原子數為1-10的烷氧基、氟取代的碳原子數為1-10的烷氧基、碳原子數為2-10的鏈烯基、氟取代的碳原子數為2-10的鏈烯基、碳原子數為3-8的烯氧基或氟取代的碳原子數為3-8的烯氧基，並且R 2所示基團中任意一個或多個-CH 2-任選被亞環戊基、亞環丁基或亞環丙基替代；Z表示-O-或-S-。 A positive dielectric anisotropy nematic liquid crystal composition comprising one or more compounds represented by formula I and one or more compounds represented by formula II:
Figure 02_image001
I;
Figure 02_image003
II; wherein, R 1 represents an alkyl group with 1-10 carbon atoms; Y 1 represents CF 3 or OCF 3 ; R 2 and R 3 independently represent an alkyl group with 1-10 carbon atoms, fluorine-substituted Alkyl group with 1-10 carbon atoms, alkoxy group with 1-10 carbon atoms, alkoxy group with 1-10 carbon atoms substituted by fluorine, alkenyl group with 2-10 carbon atoms, Alkenyl group with 2-10 carbon atoms substituted by fluorine, alkenyloxy group with 3-8 carbon atoms or alkenyloxy group with 3-8 carbon atoms substituted by fluorine, and in the group represented by R2 Any one or more -CH 2 - is optionally replaced by cyclopentylene, cyclobutylene or cyclopropylene; Z represents -O- or -S-.

在一些優選示例中，前述式Ⅰ所示化合物選自式Ⅰ1至Ⅰ6所示的化合物組成的組：

Figure 02_image005
Ⅰ1；
Figure 02_image007
Ⅰ2；
Figure 02_image009
Ⅰ3；
Figure 02_image011
Ⅰ4；
Figure 02_image013
Ⅰ5；
Figure 02_image015
Ⅰ6。 In some preferred examples, the compound represented by the aforementioned formula I is selected from the group consisting of compounds represented by formulas I1 to I6:
Figure 02_image005
I1;
Figure 02_image007
I2;
Figure 02_image009
I3;
Figure 02_image011
I4;
Figure 02_image013
I5;
Figure 02_image015
I6.

優選地，前述式Ⅱ所示的化合物選自式Ⅱ1至Ⅱ6所示的化合物組成的組：

Figure 02_image095
Ⅱ1；
Figure 02_image097
Ⅱ2；
Figure 02_image099
Ⅱ3；
Figure 02_image101
Ⅱ4；
Figure 02_image102
Ⅱ5；
Figure 02_image104
Ⅱ6； 其中，R 21、R 31各自獨立地表示碳原子數為1~6的烷基。 Preferably, the compound represented by the aforementioned formula II is selected from the group consisting of compounds represented by formula II1 to II6:
Figure 02_image095
II1;
Figure 02_image097
II2;
Figure 02_image099
II3;
Figure 02_image101
II4;
Figure 02_image102
II5;
Figure 02_image104
II6; wherein, R 21 and R 31 each independently represent an alkyl group having 1 to 6 carbon atoms.

本發明所述的液晶組合物，優選地，還包含一種或多種的式Ⅲ所示化合物：

Figure 02_image029
Ⅲ； 其中，R 4、R 5各自獨立地表示碳原子數為1~10的烷基、碳原子數為1~10的烷氧基、碳原子數為2~10的烯基或碳原子數為3~8的烯氧基；
Figure 02_image031
、
Figure 02_image033
各自獨立的表示
Figure 02_image035
或
Figure 02_image037
。 The liquid crystal composition of the present invention, preferably, further comprises one or more compounds represented by formula III:
Figure 02_image029
Ⅲ; wherein, R 4 and R 5 each independently represent an alkyl group with 1 to 10 carbon atoms, an alkoxy group with 1 to 10 carbon atoms, an alkenyl group with 2 to 10 carbon atoms, or an alkenyl group with 1 to 10 carbon atoms 3-8 alkenyloxy groups;
Figure 02_image031
,
Figure 02_image033
independent expression
Figure 02_image035
or
Figure 02_image037
.

式Ⅲ所示的化合物具有旋轉粘度低、與其他化合物互溶性好的特點，有利於提高液晶組合物的回應速度。The compound represented by formula III has the characteristics of low rotational viscosity and good miscibility with other compounds, which is beneficial to improve the response speed of the liquid crystal composition.

優選地，前述式Ⅲ所示的化合物選自式Ⅲ1至Ⅲ13所示的化合物組成的組：

Figure 02_image106
Ⅲ1；
Figure 02_image108
Ⅲ2；
Figure 02_image110
Ⅲ3；
Figure 02_image112
Ⅲ4；
Figure 02_image114
Ⅲ5；
Figure 02_image116
Ⅲ6；
Figure 02_image118
Ⅲ7；
Figure 02_image120
Ⅲ8。 Preferably, the compound represented by the aforementioned formula III is selected from the group consisting of compounds represented by formulas III1 to III13:
Figure 02_image106
III1;
Figure 02_image108
III2;
Figure 02_image110
III3;
Figure 02_image112
III4;
Figure 02_image114
III5;
Figure 02_image116
III6;
Figure 02_image118
III 7;
Figure 02_image120
III8.

本發明所述的液晶組合物，優選地，還包含一種或多種式Ⅳ所示的化合物：

Figure 02_image039
Ⅳ； 其中，R 6表示碳原子數為1~10的烷基、碳原子數為1~10的烷氧基、碳原子數為2~10的烯基或碳原子數為3~8的烯氧基，且R 6所示基團中任意一個或多個-CH 2-被任選的亞環戊基、亞環丁基或亞環丙基替代；
Figure 02_image041
、
Figure 02_image043
各自獨立地表示
Figure 02_image035
、
Figure 02_image037
、
Figure 02_image045
、
Figure 02_image047
或
Figure 02_image049
； X 1、X 2各自獨立地表示H或F；Y 2表示-F、-CF 3或-OCF 3；m表示1或2, 當m表示2時，
Figure 02_image041
可以相同或不同。 The liquid crystal composition of the present invention, preferably, further comprises one or more compounds represented by formula IV:
Figure 02_image039
Ⅳ; wherein, R 6 represents an alkyl group with 1 to 10 carbon atoms, an alkoxy group with 1 to 10 carbon atoms, an alkenyl group with 2 to 10 carbon atoms or an alkenyl group with 3 to 8 carbon atoms Oxygen, and any one or more -CH 2 - in the group represented by R 6 is replaced by an optional cyclopentylene, cyclobutylene or cyclopropylene;
Figure 02_image041
,
Figure 02_image043
express independently
Figure 02_image035
,
Figure 02_image037
,
Figure 02_image045
,
Figure 02_image047
or
Figure 02_image049
; X 1 and X 2 independently represent H or F; Y 2 represents -F, -CF 3 or -OCF 3 ; m represents 1 or 2, when m represents 2,
Figure 02_image041
Can be the same or different.

式Ⅳ所示化合物具有正介電各向異性，能夠降低液晶組合物的閾值電壓，有利於降低電能消耗。The compound represented by formula IV has positive dielectric anisotropy, can reduce the threshold voltage of the liquid crystal composition, and is beneficial to reduce power consumption.

優選地，前述式Ⅳ所示的化合物選自式Ⅳ1至Ⅳ12所示的化合物組成的組：

Figure 02_image123
Ⅳ1；
Figure 02_image125
Ⅳ2；
Figure 02_image127
Ⅳ3；
Figure 02_image129
Ⅳ4；
Figure 02_image131
Ⅳ5；
Figure 02_image133
Ⅳ6；
Figure 02_image135
Ⅳ7；
Figure 02_image137
Ⅳ8；
Figure 02_image139
Ⅳ9；
Figure 02_image141
Ⅳ10；
Figure 02_image143
Ⅳ11；
Figure 02_image145
Ⅳ12； 其中，R 6表示碳原子數為1~10的烷基、且R 6所示基團中任意一個或多個-CH 2-被任選的亞環戊基、亞環丁基或亞環丙基替代。 Preferably, the compound represented by the aforementioned formula IV is selected from the group consisting of compounds represented by formula IV1 to IV12:
Figure 02_image123
IV1;
Figure 02_image125
IV2;
Figure 02_image127
IV 3;
Figure 02_image129
IV 4;
Figure 02_image131
IV5;
Figure 02_image133
IV 6;
Figure 02_image135
IV 7;
Figure 02_image137
IV 8;
Figure 02_image139
IV9;
Figure 02_image141
IV 10;
Figure 02_image143
IV 11;
Figure 02_image145
IV12; wherein, R 6 represents an alkyl group with 1 to 10 carbon atoms, and any one or more -CH 2 - in the groups represented by R 6 is optionally cyclopentylene, cyclobutylene or Cyclopropyl substitution.

進一步優選地，前述式Ⅳ所示的化合物選自式Ⅳ7-1至Ⅳ12-2所示的化合物組成的組：

Figure 02_image147
Ⅳ7-1；
Figure 02_image149
Ⅳ7-2；
Figure 02_image151
Ⅳ7-3；
Figure 02_image153
Ⅳ8-1；
Figure 02_image155
Ⅳ8-2；
Figure 02_image157
Ⅳ8-3；
Figure 02_image159
Ⅳ9-1；
Figure 02_image161
Ⅳ9-2；
Figure 02_image163
Ⅳ9-3；
Figure 02_image165
Ⅳ10-1；
Figure 02_image167
Ⅳ11-1；
Figure 02_image169
Ⅳ12-1；
Figure 02_image171
Ⅳ12-2。 Further preferably, the compound represented by the aforementioned formula IV is selected from the group consisting of compounds represented by formula IV7-1 to IV12-2:
Figure 02_image147
IV 7-1;
Figure 02_image149
IV 7-2;
Figure 02_image151
IV 7-3;
Figure 02_image153
IV8-1;
Figure 02_image155
IV8-2;
Figure 02_image157
IV8-3;
Figure 02_image159
IV9-1;
Figure 02_image161
IV9-2;
Figure 02_image163
IV 9-3;
Figure 02_image165
IV10-1;
Figure 02_image167
IV11-1;
Figure 02_image169
IV12-1;
Figure 02_image171
IV 12-2.

式Ⅳ7-1至Ⅳ12-2所示化合物不僅具有較高的正介電各向異性，同時還具有較高的光學各向異性和清亮點，有利於提高液晶組合物的抗高溫能力。The compounds represented by formulas IV7-1 to IV12-2 not only have high positive dielectric anisotropy, but also have high optical anisotropy and clearing point, which is beneficial to improve the high temperature resistance of the liquid crystal composition.

本發明所述的液晶組合物，優選地，前述液晶組合物還包含一種或多種式Ⅴ所示化合物：

Figure 02_image051
Ⅴ； 其中，R 7、R 8各自獨立地表示碳原子數為1~10的烷基、碳原子數為1~10的烷氧基、碳原子數為2~10的烯基、氟取代的碳原子數為2~10的烯基、碳原子數為3~8的烯氧基或氟取代的碳原子數為3~8的烯氧基，且R 7、R 8中任意一個或多個互不相鄰的-CH 2-被任選的亞環戊基、亞環丁基或亞環丙基取代； Z 1表示表示單鍵或-CH 2O-；
Figure 02_image053
、
Figure 02_image055
各自獨立地表示
Figure 02_image035
、
Figure 02_image037
或
Figure 02_image057
； q表示1或2；n表示0或1； 當q表示2時，
Figure 02_image053
可以相同或不同。 In the liquid crystal composition of the present invention, preferably, the aforementioned liquid crystal composition further comprises one or more compounds represented by formula V:
Figure 02_image051
V; wherein, R 7 and R 8 each independently represent an alkyl group with 1 to 10 carbon atoms, an alkoxy group with 1 to 10 carbon atoms, an alkenyl group with 2 to 10 carbon atoms, or a fluorine-substituted Alkenyl with 2 to 10 carbon atoms, alkenyloxy with 3 to 8 carbon atoms, or alkenyloxy with 3 to 8 carbon atoms substituted by fluorine, and any one or more of R 7 and R 8 -CH 2 - that are not adjacent to each other are optionally substituted by cyclopentylene, cyclobutylene or cyclopropylene; Z 1 represents a single bond or -CH 2 O-;
Figure 02_image053
,
Figure 02_image055
express independently
Figure 02_image035
,
Figure 02_image037
or
Figure 02_image057
; q means 1 or 2; n means 0 or 1; when q means 2,
Figure 02_image053
Can be the same or different.

優選地，前述式Ⅴ所示化合物選自式Ⅴ1至Ⅴ8所示化合物組成的組：

Figure 02_image059
Ⅴ1；
Figure 02_image061
Ⅴ2；
Figure 02_image063
Ⅴ3；
Figure 02_image065
Ⅴ4；
Figure 02_image067
Ⅴ5；
Figure 02_image069
Ⅴ6；
Figure 02_image071
Ⅴ7；
Figure 02_image073
Ⅴ8； 其中，R 7、R 8各自獨立地表示碳原子數為1~5的烷基、碳原子數為1~5的烷氧基，且R 7中任意一個或多個互不相鄰的-CH 2-被任選的亞環戊基、亞環丁基或亞環丙基取代。 Preferably, the compound represented by the aforementioned formula V is selected from the group consisting of compounds represented by the formulas V1 to V8:
Figure 02_image059
V1;
Figure 02_image061
V2;
Figure 02_image063
V3;
Figure 02_image065
V4;
Figure 02_image067
V5;
Figure 02_image069
V6;
Figure 02_image071
V7;
Figure 02_image073
V8; wherein, R 7 and R 8 each independently represent an alkyl group with 1 to 5 carbon atoms, an alkoxy group with 1 to 5 carbon atoms, and any one or more of R 7 that are not adjacent to each other -CH2- is optionally substituted by cyclopentylene, cyclobutylene or cyclopropylene.

式Ⅴ所示化合具有較高的垂直介電常數，有利於提高液晶組合物ε⊥/Δε比值。The compound shown in formula V has a relatively high vertical dielectric constant, which is beneficial to increase the ratio of ε⊥/Δε in the liquid crystal composition.

進一步優選地，前述式Ⅴ所示的化合物選自式Ⅴ2-1至Ⅴ6-3所示的化合物組成的組：

Figure 02_image175
Ⅴ2-1；
Figure 02_image177
Ⅴ2-2；
Figure 02_image179
Ⅴ2-3；
Figure 02_image181
Ⅴ2-4；
Figure 02_image183
Ⅴ4-1；
Figure 02_image185
Ⅴ4-2；
Figure 02_image187
Ⅴ4-3；
Figure 02_image189
Ⅴ4-4；
Figure 02_image191
Ⅴ4-5；
Figure 02_image193
Ⅴ4-6；
Figure 02_image195
Ⅴ4-7；
Figure 02_image197
Ⅴ4-8；
Figure 02_image199
Ⅴ4-9；
Figure 02_image201
Ⅴ4-10；
Figure 02_image203
Ⅴ5-1；
Figure 02_image205
Ⅴ5-2；
Figure 02_image207
Ⅴ5-3；
Figure 02_image209
Ⅴ5-4；
Figure 02_image211
Ⅴ5-5；
Figure 02_image213
Ⅴ6-1；
Figure 02_image215
Ⅴ6-2；
Figure 02_image217
Ⅴ6-3。 Further preferably, the compound represented by the aforementioned formula V is selected from the group consisting of compounds represented by the formulas V2-1 to V6-3:
Figure 02_image175
V2-1;
Figure 02_image177
V2-2;
Figure 02_image179
V2-3;
Figure 02_image181
V2-4;
Figure 02_image183
V4-1;
Figure 02_image185
V4-2;
Figure 02_image187
V4-3;
Figure 02_image189
V4-4;
Figure 02_image191
V4-5;
Figure 02_image193
V4-6;
Figure 02_image195
V4-7;
Figure 02_image197
V4-8;
Figure 02_image199
V4-9;
Figure 02_image201
V4-10;
Figure 02_image203
V5-1;
Figure 02_image205
V5-2;
Figure 02_image207
V5-3;
Figure 02_image209
V5-4;
Figure 02_image211
V5-5;
Figure 02_image213
V6-1;
Figure 02_image215
V6-2;
Figure 02_image217
V6-3.

式Ⅴ2-1至Ⅴ6-3所示化合物不僅具有較高的垂直介電常數，還具有較高的光學各向異性。The compounds represented by the formulas V2-1 to V6-3 not only have a high vertical dielectric constant, but also have a high optical anisotropy.

本發明的液晶組合物，優選地，還包含一種或多種式Ⅵ所示的化合物：

Figure 02_image075
Ⅵ； 其中，R 9表示碳原子數為1-10的烷基、碳原子數為1-10的烷氧基、碳原子數為2-10的烯基、碳原子數為3-8的烯氧基，且R 9所示基團中任意一個或多個不相連的-CH 2-任選被亞環戊基、亞環丁基或亞環丙基取代；
Figure 02_image077
、
Figure 02_image079
各自獨立地表示
Figure 02_image035
、
Figure 02_image037
、
Figure 02_image045
、
Figure 02_image049
、
Figure 02_image081
或
Figure 02_image083
； p表示1或2；當p表示2時，
Figure 02_image077
可以相同或不同；X 3、X 4各自獨立地表示H或F；。 The liquid crystal composition of the present invention, preferably, further comprises one or more compounds represented by formula VI:
Figure 02_image075
Ⅵ; wherein, R 9 represents an alkyl group with 1-10 carbon atoms, an alkoxy group with 1-10 carbon atoms, an alkenyl group with 2-10 carbon atoms, and an alkenyl group with 3-8 carbon atoms Oxygen, and any one or more unconnected -CH 2 - in the group represented by R 9 is optionally substituted by cyclopentylene, cyclobutylene or cyclopropylene;
Figure 02_image077
,
Figure 02_image079
express independently
Figure 02_image035
,
Figure 02_image037
,
Figure 02_image045
,
Figure 02_image049
,
Figure 02_image081
or
Figure 02_image083
; p means 1 or 2; when p means 2,
Figure 02_image077
may be the same or different; X 3 and X 4 each independently represent H or F;

優選地，前述式Ⅵ所示的化合物選自式Ⅵ1至Ⅵ5所示的化合物組成的組：

Figure 02_image219
Ⅵ1；
Figure 02_image221
Ⅵ2；
Figure 02_image223
Ⅵ3；
Figure 02_image225
Ⅵ4；
Figure 02_image227
Ⅵ5； 其中，R 9表示碳原子數為1-10的烷基，且R 9所示基團中任意一個或多個不相連的-CH 2-任選被亞環戊基、亞環丁基或亞環丙基取代。 Preferably, the compound represented by the aforementioned formula VI is selected from the group consisting of compounds represented by formula VI1 to VI5:
Figure 02_image219
VI1;
Figure 02_image221
VI2;
Figure 02_image223
VI 3;
Figure 02_image225
VI 4;
Figure 02_image227
VI5; wherein, R 9 represents an alkyl group with 1-10 carbon atoms, and any one or more unconnected -CH 2 - in the group represented by R 9 is optionally replaced by cyclopentylene, cyclobutylene Or cyclopropylene substitution.

前述式Ⅵ所示的化合物，進一步優選地，式Ⅵ3至Ⅵ5所示化合物具有更高的抗污染能力，有利於降低生產成本。The compound represented by the aforementioned formula VI, more preferably, the compounds represented by the formula VI3 to VI5 have higher anti-pollution ability, which is beneficial to reduce the production cost.

本發明的液晶組合物，優選地，還包含一種或多種選自式Ⅶ1至式Ⅶ5所示化合物：

Figure 02_image085
Ⅶ1；
Figure 02_image087
Ⅶ2；
Figure 02_image089
Ⅶ3；
Figure 02_image091
Ⅶ4；
Figure 02_image093
Ⅶ5； 其中，R 10表示碳原子數為1-10的烷基，且R 10所示基團中任意一個或多個不相連的-CH 2-任選被亞環戊基、亞環丁基或亞環丙基取代；R 11表示碳原子數為1-10的烷氧基。 The liquid crystal composition of the present invention, preferably, further comprises one or more compounds selected from formula VII1 to formula VII5:
Figure 02_image085
VII1;
Figure 02_image087
VII2;
Figure 02_image089
VII 3;
Figure 02_image091
VII4;
Figure 02_image093
VII5; Wherein, R 10 represents an alkyl group with 1-10 carbon atoms, and any one or more unconnected -CH 2 - in the group represented by R 10 is optionally replaced by cyclopentylene, cyclobutylene or cyclopropylene; R 11 represents an alkoxy group with 1-10 carbon atoms.

式Ⅶ1至式Ⅶ5所示的化合物，能夠在不改變液晶組合物介電各向異性的基礎上，提高垂直介電常數。The compounds represented by formula VII1 to formula VII5 can increase the vertical dielectric constant without changing the dielectric anisotropy of the liquid crystal composition.

前述碳原子數為1-10的烷基，可以列舉出，例如，甲基、乙基、正丙基、異丙基、正丁基、異丁基、叔丁基、正戊基、異戊基、己基、庚基、辛基、壬基、癸基等。The aforementioned alkyl group having 1 to 10 carbon atoms includes, for example, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentyl, isopentyl Base, hexyl, heptyl, octyl, nonyl, decyl, etc.

前述的碳原子數為1-10的烷氧基，可以列舉出，例如，甲氧基、乙氧基、正丙氧基、異丙氧基、正丁氧基、異丁氧基、戊氧基、己氧基、庚氧基、辛氧基、壬氧基、癸氧基等。The aforementioned alkoxy groups having 1 to 10 carbon atoms include, for example, methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, isobutoxy, pentyloxy Base, hexyloxy, heptyloxy, octyloxy, nonyloxy, decyloxy, etc.

前述碳原子數為2-10的烯基，可以列舉出，例如，乙烯基、1-丙烯基、1-丁烯基、2-丁烯基、3-丁烯基、1-戊烯基、2-戊烯基、3-戊烯基、4-戊烯基、1-己烯基、2-己烯基、3-己烯基等。The aforementioned alkenyl groups having 2 to 10 carbon atoms include, for example, vinyl, 1-propenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, 1-hexenyl, 2-hexenyl, 3-hexenyl and the like.

前述的氟取代的碳原子數為1-10的烷基、氟取代的碳原子數為1-10的烷氧基、氟取代的碳原子數為2-10的鏈烯基、氟取代的碳原子數為3-8的鏈烯氧基中的“氟取代”可以是單氟取代，或者、二氟取代、三氟取代等多氟取代，也可以是全氟取代，對氟的取代數沒有特別的限定。例如，作為氟取代的碳原子數為1-10的烷基，可以列舉出氟代甲基、二氟甲基、三氟甲基、1-氟代乙基、2-氟代乙基、1,2-二氟乙基、1,1-二氟乙基、1,1,2-三氟乙基、1,1,1,2,2-五氟取代乙基等，但不限於此。The aforementioned fluorine-substituted alkyl group with 1-10 carbon atoms, fluorine-substituted alkoxy group with 1-10 carbon atoms, fluorine-substituted alkenyl group with 2-10 carbon atoms, fluorine-substituted carbon The "fluorine substitution" in the alkenyloxy group with 3-8 atoms can be monofluorine substitution, or polyfluorine substitution such as difluoro substitution, trifluoro substitution, etc., or perfluoro substitution, and there is no substitution number for fluorine. special restrictions. For example, the alkyl group having 1 to 10 carbon atoms substituted by fluorine includes fluoromethyl, difluoromethyl, trifluoromethyl, 1-fluoroethyl, 2-fluoroethyl, 1 , 2-difluoroethyl, 1,1-difluoroethyl, 1,1,2-trifluoroethyl, 1,1,1,2,2-pentafluoroethyl, etc., but not limited thereto.

前述的碳原子數為1~10的烷基中一個或多個不相鄰的-CH 2-被亞環丙基、亞環丁基或亞環戊基取代後得到的基團，可以列舉出，例如環丙基、環丁基、環戊基、甲基亞環丙基、乙基亞環丙基、丙基亞環丙基、異丙基亞環丙基、正丁基亞環丙基、異丁基亞環丙基、叔丁基亞環丙基、甲基亞環丁基、乙基亞環丁基、丙基亞環丁基、異丙基亞環丁基、正丁基亞環丁基、異丁基亞環丁基、叔丁基亞環丁基、甲基亞環戊基、乙基亞環戊基、丙基亞環戊基、異丙基亞環戊基、正丁基亞環戊基、異丁基亞環戊基等。 A group obtained by substituting one or more non-adjacent -CH 2 - in the aforementioned alkyl group with 1 to 10 carbon atoms by cyclopropylene, cyclobutylene or cyclopentylene, including , such as cyclopropyl, cyclobutyl, cyclopentyl, methylcyclopropylene, ethylcyclopropylene, propylcyclopropylene, isopropylcyclopropylene, n-butylcyclopropylene , isobutylcyclopropylene, tert-butylcyclopropylene, methylcyclobutylene, ethylcyclobutylene, propylcyclobutylene, isopropylcyclobutylene, n-butylcyclobutylene Cyclobutyl, isobutylcyclobutylene, t-butylcyclobutylene, methylcyclopentylene, ethylcyclopentylene, propylcyclopentylene, isopropylcyclopentylene, n- Butylcyclopentylene, isobutylcyclopentylene, etc.

本發明液晶組合物介電各向異性Δε為10.0~10.5，光學各向異性Δn為0.124~0.129，優選為0.126~0.128，清亮點Cp為80~90℃，優選為80~85℃。The dielectric anisotropy Δε of the liquid crystal composition of the present invention is 10.0-10.5, the optical anisotropy Δn is 0.124-0.129, preferably 0.126-0.128, and the clearing point Cp is 80-90°C, preferably 80-85°C.

本發明提供的液晶組合物中，除添加劑之外的其他化合物的總質量百分比含量記為100%。In the liquid crystal composition provided by the present invention, the total mass percentage content of other compounds except additives is recorded as 100%.

優選地，所述液晶組合物按照質量百分數包含：Preferably, the liquid crystal composition comprises according to mass percentage:

優選地，式Ⅰ所示化合物的質量百分比含量為7-16%，進一步優選地式Ⅰ所示化合物的質量百分比含量為10-15%。Preferably, the mass percentage content of the compound represented by formula I is 7-16%, and more preferably, the mass percentage content of the compound represented by formula I is 10-15%.

優選地，式Ⅱ所示化合物的質量百分比含量優選為5-10%。Preferably, the mass percentage content of the compound represented by formula II is preferably 5-10%.

優選地，式Ⅰ、式Ⅱ所示化合物的質量百分比含量之和小於25%。Preferably, the sum of the mass percentages of the compounds represented by formula I and formula II is less than 25%.

優選地，式Ⅲ所示化合物的質量百分比含量為40-42%。Preferably, the mass percent content of the compound represented by formula III is 40-42%.

優選地，式Ⅳ所示化合物的質量百分比含量為5-16%。Preferably, the mass percent content of the compound represented by formula IV is 5-16%.

優選地，式Ⅴ所示化合物的質量百分比含量為4-7%。Preferably, the mass percent content of the compound represented by formula V is 4-7%.

優選地，式Ⅵ所示化合物的質量百分比含量為25-34%，進一步優選地式Ⅵ所示化合物的質量百分比含量為31-34%。Preferably, the mass percent content of the compound represented by formula VI is 25-34%, and more preferably, the mass percentage content of the compound represented by formula VI is 31-34%.

優選地，式Ⅶ所示化合物的質量百分比含量為0-4%。Preferably, the mass percent content of the compound represented by formula VII is 0-4%.

本發明的液晶化合物中還可以加入各種功能的摻雜劑，摻雜劑含量優選0.01-1%之間，這些摻雜劑可以列舉出，例如抗氧化劑、紫外線吸收劑、手性劑。Dopants with various functions can also be added to the liquid crystal compound of the present invention, and the dopant content is preferably between 0.01-1%. These dopants can be listed, such as antioxidants, ultraviolet absorbers, and chiral agents.

抗氧化劑可以列舉出：

Figure 02_image229
；
Figure 02_image231
；
Figure 02_image233
；
Figure 02_image235
； t表示1~10的整數。 Antioxidants can be listed as:
Figure 02_image229
;
Figure 02_image231
;
Figure 02_image233
;
Figure 02_image235
; t represents an integer from 1 to 10.

光穩定劑可以列舉：

Figure 02_image237
；
Figure 02_image239
。 Light stabilizers can be exemplified by:
Figure 02_image237
;
Figure 02_image239
.

手性劑（左旋或右旋）優選可以列舉出，例如：

Figure 02_image241
；
Figure 02_image243
；
Figure 02_image245
；
Figure 02_image247
；
Figure 02_image249
。 Chiral agents (left-handed or right-handed) can preferably be listed, for example:
Figure 02_image241
;
Figure 02_image243
;
Figure 02_image245
;
Figure 02_image247
;
Figure 02_image249
.

[[ 液晶顯示元件或液晶顯示器liquid crystal display element or liquid crystal display ]]

為達到上述第二個目的，本發明提供如下技術方案： 一種液晶顯示元件，其包含如上所述的液晶組合物，所述液晶顯示元件為有源矩陣顯示元件或無源矩陣顯示元件。 In order to achieve the above-mentioned second purpose, the present invention provides the following technical solutions: A liquid crystal display element, which comprises the above-mentioned liquid crystal composition, said liquid crystal display element is an active matrix display element or a passive matrix display element.

為達到上述第三個目的，本發明提供如下技術方案： 一種液晶顯示器，其包含如上第一個目的所述的液晶組合物，所述液晶顯示器為有源矩陣顯示器或無源矩陣顯示器。 In order to achieve the above-mentioned third purpose, the present invention provides the following technical solutions: A liquid crystal display comprising the liquid crystal composition as described in the first objective above, the liquid crystal display being an active matrix display or a passive matrix display.

前述有源矩陣顯示元件或顯示器，具體可以列舉出，例如TN-TFT或IPS-TFT或FFS-TFT液晶顯示元件或其他TFT顯示器。The aforementioned active matrix display elements or displays specifically include, for example, TN-TFT or IPS-TFT or FFS-TFT liquid crystal display elements or other TFT displays.

本發明的液晶顯示元件、液晶顯示器通過包含前述的本發明的液晶組合物，具有高的對比度、面板輕薄、能耗低、較寬的使用溫度範圍，以及良好的信賴性。The liquid crystal display element and the liquid crystal display of the present invention contain the aforementioned liquid crystal composition of the present invention, and have high contrast, light and thin panel, low energy consumption, wide service temperature range, and good reliability.

實施例Example

為了更清楚地說明本發明，下面結合實施例對本發明做進一步的說明。本領域技術人員應當理解，下面所具體描述的內容是說明性的而非限制性的，不應以此限制本發明的保護範圍。In order to illustrate the present invention more clearly, the present invention will be further described below in conjunction with the examples. Those skilled in the art should understand that the content specifically described below is illustrative rather than restrictive, and should not limit the protection scope of the present invention.

本說明書中，如無特殊說明，百分比均是指質量百分比，溫度為攝氏度（℃），其他符號的具體意義及測試條件如下： Cp表示液晶清亮點（℃），DSC定量法測試； Δn表示光學各向異性，n o為尋常光的折射率，n e為非尋常光的折射率，測試條件為25±2℃，589nm，阿貝折射儀測試； Δε表示介電各向異性，Δε=ε ∥-ε ⊥，其中，ε ∥為平行於分子軸的介電常數，ε ⊥為垂直於分子軸的介電常數，測試條件為25±0.5℃，20微米垂直盒，INSTEC:ALCT-IR1測試； γ 1表示旋轉粘度（mPa·s），測試條件為25±0.5℃，20微米垂直盒，INSTEC:ALCT-IR1測試； K 11為展曲彈性常數，K 33為彎曲彈性常數，測試條件為：25℃、INSTEC:ALCT-IR1、20微米垂直盒； Tr（%）表示透過率，Tr（%）=100%* 亮態（Vop）亮度/光源亮度，測試設備DMS501，測試條件為25±0.5℃，測試盒為FFS測試盒，電極間距5微米，電極寬度均為3微米，摩擦方向與電極夾角為7°； VHR表示電壓保持率（%），測試條件為60±2℃、電壓為±5V、脈衝寬度為10ms、電壓保持時間166.7ms。測試設備為TOYO Model6254液晶性能綜合測試儀； 殘像：液晶顯示器件的殘像，是在顯示區域內使規定的固定圖案顯示1000小時後，通過目測對進行全畫面均勻顯示時的固有圖案的殘留水準進行以下的4等級評價： ◎無殘留 ○有極少量殘留，為可以容許的水準 △有殘留，為不能允許的水準 ×有殘留，相當差。 In this manual, unless otherwise specified, the percentages refer to mass percentages, and the temperature is in degrees Celsius (°C). The specific meanings and test conditions of other symbols are as follows: Cp means liquid crystal clearing point (°C), tested by DSC quantitative method; Δn means optical Anisotropy, n o is the refractive index of ordinary light, ne is the refractive index of extraordinary light, the test condition is 25±2°C, 589nm, Abbe refractometer test; Δε means dielectric anisotropy, Δε=ε ∥ -ε ⊥ , where, ε ∥ is the dielectric constant parallel to the molecular axis, ε ⊥ is the dielectric constant perpendicular to the molecular axis, the test condition is 25±0.5℃, 20 micron vertical cell, INSTEC: ALCT-IR1 test ; γ 1 is the rotational viscosity (mPa s), the test condition is 25±0.5℃, 20 micron vertical box, INSTEC: ALCT-IR1 test; K 11 is the flexural constant, K 33 is the flexural constant, the test condition is : 25°C, INSTEC: ALCT-IR1, 20 micron vertical cell; Tr (%) means transmittance, Tr (%) = 100%* bright state (Vop) brightness / light source brightness, test equipment DMS501, the test condition is 25± 0.5°C, the test box is an FFS test box, the electrode spacing is 5 microns, the electrode width is 3 microns, the angle between the friction direction and the electrode is 7°; VHR indicates the voltage retention rate (%), the test condition is 60±2 °C, the voltage is ±5V, pulse width 10ms, voltage hold time 166.7ms. The test equipment is TOYO Model6254 liquid crystal performance comprehensive tester; Afterimage: The afterimage of the liquid crystal display device is the residue of the inherent pattern when the full screen is uniformly displayed by visual inspection after the specified fixed pattern is displayed in the display area for 1000 hours The level was evaluated in the following 4 grades: ◎No residue ○There is a very small amount of residue, which is an acceptable level △There is a residue, which is an unacceptable level ×There is a residue, which is quite poor.

液晶組合物的製備方法如下：將各液晶單體按照一定配比稱量後放入不銹鋼燒杯中，將裝有各液晶單體的不銹鋼燒杯置於磁力攪拌儀器上加熱融化，待不銹鋼燒杯中的液晶單體大部份融化後，往不銹鋼燒杯中加入磁力轉子，將混合物攪拌均勻，冷卻到室溫後即得液晶組合物。The preparation method of the liquid crystal composition is as follows: put each liquid crystal monomer into a stainless steel beaker after weighing according to a certain proportion, place the stainless steel beaker containing each liquid crystal monomer on a magnetic stirring apparatus to heat and melt, and wait for the liquid crystal monomer in the stainless steel beaker to melt. After most of the liquid crystal monomers are melted, a magnetic rotor is added to the stainless steel beaker, the mixture is stirred evenly, and the liquid crystal composition is obtained after cooling to room temperature.

本發明實施例液晶單體結構用代碼表示，液晶環結構、端基、連接基團的代碼表示方法見下表1、表2。 表1 環結構的對應代碼 環結構 對應代碼

Figure 02_image251
C
Figure 02_image253
 P
Figure 02_image255
 G
Figure 02_image257
 Gi
Figure 02_image259
 A
Figure 02_image261
 D
Figure 02_image263
 Y
Figure 02_image265
 Sb
Figure 02_image267
 Sc 表2 端基與連結基團的對應代碼 端基與連結基團 對應代碼 C nH 2n+1- n- -C nH 2n- -n- C nH 2n+1O- nO- -C nH 2nO- -nO- -CF 3 -T -OCF 3 -OT -CF 2O- -Q- -CH 2O- -O- -O- -B- -F -F -CN -CN -CH 2CH 2- -E- -CH=CH- -V- -CH=CH 2 -V -C≡C- -W- -COO- -Z- -CH=CH-C nH 2n+1 Vn-
Figure 02_image269
 Cp-
Figure 02_image271
 Cpr-
Figure 02_image273
 Cpr1- The structure of the liquid crystal monomer in the embodiment of the present invention is represented by a code, and the code representation methods of the liquid crystal ring structure, terminal group, and linking group are shown in Table 1 and Table 2 below. Table 1 Corresponding codes of the ring structure ring structure corresponding code
Figure 02_image251
 C
Figure 02_image253
 P
Figure 02_image255
 G
Figure 02_image257
 Gi
Figure 02_image259
 A
Figure 02_image261
 D.
Figure 02_image263
 Y
Figure 02_image265
 Sb
Figure 02_image267
 sc Table 2 Corresponding codes of terminal groups and linking groups End group and linking group corresponding code C n H 2n+1 - n- -C n H 2n - -n- C n H 2n+1 O- nO- -C n H 2n O- -nO- -CF 3 -T -OCF 3 -OT -CF 2 O- -Q- -CH 2 O- -O- -O- -B- -F -F -CN -CN -CH 2 CH 2 - -E- -CH=CH- -V- -CH=CH 2 -V -C≡C- -W- -COO- -Z- -CH=CH-C n H 2n+1 Vn-
Figure 02_image269
 Cp-
Figure 02_image271
 Cpr-
Figure 02_image273
 Cpr1-

舉例：

Figure 02_image275
，其代碼為CPWP-3-OT；
Figure 02_image276
，其代碼為CPWP-3-T；
Figure 02_image278
，其代碼為Sb-CpO-O4；
Figure 02_image280
，其代碼為Sc-CpO-O4；
Figure 02_image282
，其代碼為CC-3-V1；
Figure 02_image284
，其代碼為PP-1-2V1；
Figure 02_image286
，其代碼為CPY-2-O2；
Figure 02_image288
，其代碼為CCY-3-O2；
Figure 02_image290
，其代碼為PGUQU-3-F;
Figure 02_image292
，其代碼為PGUQY-3-F。 Example:
Figure 02_image275
, whose code is CPWP-3-OT;
Figure 02_image276
, whose code is CPWP-3-T;
Figure 02_image278
, whose code is Sb-CpO-O4;
Figure 02_image280
, whose code is Sc-CpO-O4;
Figure 02_image282
, whose code is CC-3-V1;
Figure 02_image284
, whose code is PP-1-2V1;
Figure 02_image286
, whose code is CPY-2-O2;
Figure 02_image288
, whose code is CCY-3-O2;
Figure 02_image290
, whose code is PGUQU-3-F;
Figure 02_image292
, whose code is PGUQY-3-F.

實施例Example 11

液晶組合物的配方及相應的性能如下表3所示。 表3 實施例1液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份） Ⅰ CPWP-3-OT 7 Ⅰ CPWP-3-T 7 Ⅱ Sb-2O-O5 5 Ⅱ Sc-2O-O5 5 Ⅲ CC-3-V 42 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 7 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 5 Δε[1KHz, 25℃]：10.3 ε ⊥[1KHz, 25℃]：5.6 Δn[589nm, 25℃]：0.126 Cp：80.8℃ γ 1： 68mPa.s K 11：13.6 K 33：13.0 γ 1/ K 11：5.00 ε ⊥/Δε：0.544 The formula and corresponding properties of the liquid crystal composition are shown in Table 3 below. Table 3 The formula and corresponding properties of the liquid crystal composition of Example 1 category LCD monomer code Content (parts by mass) I CPWP-3-OT 7 I CPWP-3-T 7 II Sb-2O-O5 5 II Sc-2O-O5 5 III CC-3-V 42 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 7 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 5 Δε[1KHz, 25℃]: 10.3 ε ⊥ [1KHz, 25℃]: 5.6 Δn[589nm, 25℃]: 0.126 Cp: 80.8℃ γ 1 : 68mPa.s K 11 : 13.6 K 33 : 13.0 γ 1 / K 11 : 5.00 ε⊥ /Δε: 0.544

實施例Example 22

液晶組合物的配方及相應的性能如下表4所示。 表4 實施例2液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份） Ⅰ CPWP-3-T 5 Ⅰ CPWP-4-T 5 Ⅰ CPWP-5-T 5 Ⅱ Sb-CpO-O4 3 Ⅱ Sb-CprO-O4 3 Ⅱ Sc- CpO –O2 2 Ⅱ Sc- CprO –O3 2 Ⅲ CC-3-V 42 Ⅵ PGUQU-3-F 6 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-3-F 5 Ⅵ DPUQU-4-F 5 Ⅵ DGUQU-3-F 4 Ⅵ DGUQU-4-F 4 Ⅵ APUQU-3-F 4 Δε[1KHz, 25℃]：10.4 ε ⊥[1KHz, 25℃]：5.5 Δn[589nm, 25℃]：0.127 Cp：80.0℃ γ 1： 70mPa.s K 11：15.5 K 33：13.8 γ 1/ K 11：4.52 ε ⊥/Δε：0.529 The formula and corresponding properties of the liquid crystal composition are shown in Table 4 below. Table 4 The formula and corresponding properties of the liquid crystal composition of Example 2 category LCD monomer code Content (parts by mass) I CPWP-3-T 5 I CPWP-4-T 5 I CPWP-5-T 5 II Sb-CpO-O4 3 II Sb-CprO-O4 3 II Sc-CpO-O2 2 II Sc-CprO-O3 2 III CC-3-V 42 Ⅵ PGUQU-3-F 6 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-3-F 5 Ⅵ DPUQU-4-F 5 Ⅵ DGUQU-3-F 4 Ⅵ DGUQU-4-F 4 Ⅵ APUQU-3-F 4 Δε[1KHz, 25℃]: 10.4 ε ⊥ [1KHz, 25℃]: 5.5 Δn[589nm, 25℃]: 0.127 Cp: 80.0℃ γ 1 : 70mPa.s K 11 : 15.5 K 33 : 13.8 γ 1 / K 11 : 4.52 ε⊥ /Δε: 0.529

實施例Example 33

液晶組合物的配方及相應的性能如下表5所示。 表5 實施例3液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份） Ⅰ CPWP-3-OT 6 Ⅰ CPWP-4-OT 5 Ⅰ CPWP-5-OT 5 Ⅱ Sb-CpO-O4 2.5 Ⅱ Sb-CprO-O4 2.5 Ⅱ Sc- CpO –O2 2 Ⅱ Sc- CprO –O3 2 Ⅲ CC-3-V 42 Ⅵ PGUQU-3-F 6 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-3-F 5 Ⅵ DPUQU-4-F 5 Ⅵ DGUQU-3-F 4 Ⅵ DGUQU-4-F 4 Ⅵ APUQU-3-F 4 Δε[1KHz, 25℃]：10.0 ε ⊥[1KHz, 25℃]：5.3 Δn[589nm, 25℃]：0.126 Cp：81.5℃ γ 1： 66mPa.s K 11：14.6 K 33：13.4 γ 1/ K 11：4.52 ε ⊥/Δε：0.530 The formula and corresponding properties of the liquid crystal composition are shown in Table 5 below. Table 5 The formula and corresponding properties of the liquid crystal composition of Example 3 category LCD monomer code Content (parts by mass) I CPWP-3-OT 6 I CPWP-4-OT 5 I CPWP-5-OT 5 II Sb-CpO-O4 2.5 II Sb-CprO-O4 2.5 II Sc-CpO-O2 2 II Sc-CprO-O3 2 III CC-3-V 42 Ⅵ PGUQU-3-F 6 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-3-F 5 Ⅵ DPUQU-4-F 5 Ⅵ DGUQU-3-F 4 Ⅵ DGUQU-4-F 4 Ⅵ APUQU-3-F 4 Δε[1KHz, 25℃]: 10.0 ε ⊥ [1KHz, 25℃]: 5.3 Δn[589nm, 25℃]: 0.126 Cp: 81.5℃ γ 1 : 66mPa.s K 11 : 14.6 K 33 : 13.4 γ 1 / K 11 : 4.52ε⊥ /Δε: 0.530

實施例Example 44

液晶組合物的配方及相應的性能如下表6所示。 表6 實施例4液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份） Ⅰ CPWP-3-OT 5 Ⅰ CPWP-3-T 5 Ⅱ Sb-2O-O5 5 Ⅱ Sc-2O-O5 5 Ⅲ CC-3-V 42 Ⅳ CCPU-3-F 2 Ⅳ CCPU-4-F 2 Ⅳ PPGU-Cp-F 1 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 5 Δε[1KHz, 25℃]：10.4 ε ⊥[1KHz, 25℃]：5.6 Δn[589nm, 25℃]：0.124 Cp：83.6℃ γ 1： 72mPa.s K 11：13.5 K 33：13.4 γ 1/ K 11：5.33 ε ⊥/Δε：0.538 The formula and corresponding properties of the liquid crystal composition are shown in Table 6 below. Table 6 The formulation and corresponding performance of the liquid crystal composition of Example 4 category LCD monomer code Content (parts by mass) I CPWP-3-OT 5 I CPWP-3-T 5 II Sb-2O-O5 5 II Sc-2O-O5 5 III CC-3-V 42 IV CCPU-3-F 2 IV CCPU-4-F 2 IV PPGU-Cp-F 1 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 5 Δε[1KHz, 25℃]: 10.4 ε ⊥ [1KHz, 25℃]: 5.6 Δn[589nm, 25℃]: 0.124 Cp: 83.6℃ γ 1 : 72mPa.s K 11 : 13.5 K 33 : 13.4 γ 1 / K 11 : 5.33 ε⊥ /Δε: 0.538

實施例Example 55

液晶組合物的配方及相應的性能如下表7所示。 表7 實施例5液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份） Ⅰ CPWP-3-OT 5 Ⅰ CPWP-3-T 5 Ⅱ Sb-2O-O5 5 Ⅱ Sc-2O-O5 5 Ⅲ CC-3-V 42 Ⅳ CPUP-3-OT 2 Ⅳ CPUP-3-T 2 Ⅳ PPGU-Cp-F 1 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 5 Δε[1KHz, 25℃]：10.4 ε ⊥[1KHz, 25℃]：5.5 Δn[589nm, 25℃]：0.126 Cp：82.9℃ γ 1： 73mPa.s K 11：13.5 K 33：13.5 γ 1/ K 11：5.40 ε ⊥/Δε：0.529 The formula and corresponding properties of the liquid crystal composition are shown in Table 7 below. Table 7 The formulation and corresponding performance of the liquid crystal composition of Example 5 category LCD monomer code Content (parts by mass) I CPWP-3-OT 5 I CPWP-3-T 5 II Sb-2O-O5 5 II Sc-2O-O5 5 III CC-3-V 42 IV CPUP-3-OT 2 IV CPUP-3-T 2 IV PPGU-Cp-F 1 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 5 Δε[1KHz, 25℃]: 10.4 ε ⊥ [1KHz, 25℃]: 5.5 Δn[589nm, 25℃]: 0.126 Cp: 82.9℃ γ 1 : 73mPa.s K 11 : 13.5 K 33 : 13.5 γ 1 / K 11 : 5.40 ε⊥ /Δε: 0.529

實施例Example 66

液晶組合物的配方及相應的性能如下表8所示。 表8 實施例6液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份） Ⅰ CPWP-3-OT 5 Ⅰ CPWP-3-T 5 Ⅱ Sb-2O-O5 3 Ⅱ Sc-2O-O5 2 Ⅲ CC-3-V 41 Ⅳ PGU-2-F 2 Ⅳ CCPU-3-F 3 Ⅳ PPGU-Cp-F 1 Ⅴ PY-2O-O2 4 Ⅴ PY-2O-O4 3 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 3 Δε[1KHz, 25℃]：10.1 ε ⊥[1KHz, 25℃]：5.4 Δn[589nm, 25℃]：0.126 Cp：80.2℃ γ 1： 70mPa.s K 11：13.3 K 33：13.4 γ 1/ K 11：5.26 ε ⊥/Δε：0.535 The formula and corresponding properties of the liquid crystal composition are shown in Table 8 below. Table 8 The formulation and corresponding properties of the liquid crystal composition of Example 6 category LCD monomer code Content (parts by mass) I CPWP-3-OT 5 I CPWP-3-T 5 II Sb-2O-O5 3 II Sc-2O-O5 2 III CC-3-V 41 IV PGU-2-F 2 IV CCPU-3-F 3 IV PPGU-Cp-F 1 Ⅴ PY-2O-O2 4 Ⅴ PY-2O-O4 3 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 3 Δε[1KHz, 25℃]: 10.1 ε ⊥ [1KHz, 25℃]: 5.4 Δn[589nm, 25℃]: 0.126 Cp: 80.2℃ γ 1 : 70mPa.s K 11 : 13.3 K 33 : 13.4 γ 1 / K 11 : 5.26ε⊥ /Δε: 0.535

實施例Example 77

液晶組合物的配方及相應的性能如下表9所示。 表9 實施例7液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份） Ⅰ CPWP-3-OT 5 Ⅰ CPWP-3-T 5 Ⅱ Sb-2O-O5 3 Ⅱ Sc-2O-O5 2 Ⅲ CC-3-V 40 Ⅳ PGU-2-F 3 Ⅳ PGU-3-F 3 Ⅳ CCPU-2-F 3 Ⅳ CCPU-3-F 3 Ⅳ CCPU-4-F 3 Ⅳ PPGU-Cp-F 1 Ⅴ PY-2O-O2 2 Ⅴ PY-2O-O4 2 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 5 Ⅵ DGUQU-3-F 5 Ⅵ DGUQU-4-F 5 Δε[1KHz, 25℃]：10.1 ε ⊥[1KHz, 25℃]：5.0 Δn[589nm, 25℃]：0.129 Cp：87.3℃ γ 1： 75mPa.s K 11：13.9 K 33：13.8 γ 1/ K 11：5.40 ε ⊥/Δε：0.495 The formula and corresponding properties of the liquid crystal composition are shown in Table 9 below. Table 9 The formula and corresponding performance of the liquid crystal composition of Example 7 category LCD monomer code Content (parts by mass) I CPWP-3-OT 5 I CPWP-3-T 5 II Sb-2O-O5 3 II Sc-2O-O5 2 III CC-3-V 40 IV PGU-2-F 3 IV PGU-3-F 3 IV CCPU-2-F 3 IV CCPU-3-F 3 IV CCPU-4-F 3 IV PPGU-Cp-F 1 Ⅴ PY-2O-O2 2 Ⅴ PY-2O-O4 2 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 5 Ⅵ DGUQU-3-F 5 Ⅵ DGUQU-4-F 5 Δε[1KHz, 25℃]: 10.1 ε ⊥ [1KHz, 25℃]: 5.0 Δn[589nm, 25℃]: 0.129 Cp: 87.3℃ γ 1 : 75mPa.s K 11 : 13.9 K 33 : 13.8 γ 1 / K 11 : 5.40 ε⊥ /Δε: 0.495

實施例Example 88

液晶組合物的配方及相應的性能如下表10所示。 表10 實施例8液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份） Ⅰ CPWP-3-OT 3 Ⅰ CPWP-3-T 4 Ⅱ Sb-2O-O5 3 Ⅱ Sc-2O-O5 2 Ⅲ CC-3-V 40 Ⅳ PGU-2-F 2 Ⅳ CCPU-3-F 2 Ⅳ PPGU-Cp-F 1 Ⅴ PY-2O-O2 4 Ⅴ PY-2O-O4 3 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 4 Ⅶ PGUQY-3-O2 4 Δε[1KHz, 25℃]：10.0 ε ⊥[1KHz, 25℃]：5.6 Δn[589nm, 25℃]：0.128 Cp：80.3℃ γ 1： 80mPa.s K 11：12.9 K 33：13.6 γ 1/ K 11：6.20 ε ⊥/Δε：0.560 The formula and corresponding properties of the liquid crystal composition are shown in Table 10 below. Table 10 The formula and corresponding properties of the liquid crystal composition of Example 8 category LCD monomer code Content (parts by mass) I CPWP-3-OT 3 I CPWP-3-T 4 II Sb-2O-O5 3 II Sc-2O-O5 2 III CC-3-V 40 IV PGU-2-F 2 IV CCPU-3-F 2 IV PPGU-Cp-F 1 Ⅴ PY-2O-O2 4 Ⅴ PY-2O-O4 3 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 4 VII PGUQY-3-O2 4 Δε[1KHz, 25℃]: 10.0 ε ⊥ [1KHz, 25℃]: 5.6 Δn[589nm, 25℃]: 0.128 Cp: 80.3℃ γ 1 : 80mPa.s K 11 : 12.9 K 33 : 13.6 γ 1 / K 11 : 6.20 ε⊥ /Δε: 0.560

對比例comparative example 11

液晶組合物的配方及相應的性能如下表11所示。 表11 對比例1液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份）   CPWP-3-2 5   CPWP-3-O2 5 Ⅱ Sb-2O-O5 3 Ⅱ Sc-2O-O5 2 Ⅲ CC-3-V 41 Ⅳ PGU-2-F 2 Ⅳ CCPU-3-F 3 Ⅳ PPGU-Cp-F 1 Ⅴ PY-2O-O2 4 Ⅴ PY-2O-O4 3 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 3 Δε[1KHz, 25℃]：9.3 ε ⊥[1KHz, 25℃]：5.3 Δn[589nm, 25℃]：0.131 Cp：86.2℃ γ 1： 78mPa.s K 11：13.7 K 33：13.9 γ 1/ K 11：5.69 ε ⊥/Δε：0.570 The formula and corresponding properties of the liquid crystal composition are shown in Table 11 below. Table 11 The formulation and corresponding properties of the liquid crystal composition of Comparative Example 1 category LCD monomer code Content (parts by mass) CPWP-3-2 5 CPWP-3-O2 5 II Sb-2O-O5 3 II Sc-2O-O5 2 III CC-3-V 41 IV PGU-2-F 2 IV CCPU-3-F 3 IV PPGU-Cp-F 1 Ⅴ PY-2O-O2 4 Ⅴ PY-2O-O4 3 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 3 Δε[1KHz, 25℃]: 9.3 ε ⊥ [1KHz, 25℃]: 5.3 Δn[589nm, 25℃]: 0.131 Cp: 86.2℃ γ 1 : 78mPa.s K 11 : 13.7 K 33 : 13.9 γ 1 / K 11 : 5.69 ε⊥ /Δε: 0.570

與實施例6相比，對比例1液晶組合物中，不包含式Ⅰ所示化合物。使用結構相近的CPWP-3-2、CPWP-3-O2等量替代式Ⅰ所示化合物。雖然結構相近，但性能相差很大，對比例1液晶組合物介電各向異性相對於實施例6下降十分明顯，需要更大的驅動電壓才能將液晶分子完全驅動，從而消耗更多的電能。與實施例6相比，如果在相同的驅動電壓下，由於對比例1的液晶組合物無法完全驅動將降低其透過率，透過率降低便需要增加背光亮度才能獲得滿足需求的畫面亮度，從而消耗更多的電能。旋轉粘度的增加，也將使對比例1液晶組合物的回應速度變慢。Compared with Example 6, the liquid crystal composition of Comparative Example 1 does not contain the compound represented by formula I. Use equivalent amounts of CPWP-3-2 and CPWP-3-O2 with similar structures to replace the compounds shown in formula I. Although the structures are similar, the properties are quite different. The dielectric anisotropy of the liquid crystal composition of Comparative Example 1 is significantly lower than that of Example 6, and a larger driving voltage is required to fully drive the liquid crystal molecules, thereby consuming more electric energy. Compared with Example 6, if the liquid crystal composition of Comparative Example 1 cannot be fully driven at the same driving voltage, its transmittance will be reduced, and the decrease in transmittance will require increasing the brightness of the backlight to obtain a screen brightness that meets the requirements, thereby consuming More power. The increase of rotational viscosity will also slow down the response speed of the liquid crystal composition of Comparative Example 1.

對比例comparative example 22

液晶組合物的配方及相應的性能如下表12所示。 表12 對比例2液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份） Ⅰ CPWP-3-OT 5 Ⅰ CPWP-3-T 5 Ⅲ CC-3-V 41 Ⅳ PGU-2-F 2 Ⅳ CCPU-3-F 3 Ⅳ PPGU-Cp-F 1 Ⅴ PY-2O-O2 4 Ⅴ PY-2O-O4 8 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 3 Δε[1KHz, 25℃]：10.4 ε ⊥[1KHz, 25℃]：5.0 Δn[589nm, 25℃]：0.126 Cp：80.4℃ γ 1： 68mPa.s K 11：13.6 K 33：13.6 γ 1/ K 11：5.00 ε ⊥/Δε：0.480 The formula and corresponding properties of the liquid crystal composition are shown in Table 12 below. Table 12 The formula and corresponding properties of the liquid crystal composition of Comparative Example 2 category LCD monomer code Content (parts by mass) I CPWP-3-OT 5 I CPWP-3-T 5 III CC-3-V 41 IV PGU-2-F 2 IV CCPU-3-F 3 IV PPGU-Cp-F 1 Ⅴ PY-2O-O2 4 Ⅴ PY-2O-O4 8 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 3 Δε[1KHz, 25℃]: 10.4 ε ⊥ [1KHz, 25℃]: 5.0 Δn[589nm, 25℃]: 0.126 Cp: 80.4℃ γ 1 : 68mPa.s K 11 : 13.6 K 33 : 13.6 γ 1 / K 11 : 5.00 ε⊥ /Δε: 0.480

與實施例6相比，對比例2液晶組合物中，不包含式Ⅱ所示化合物，使用化合物PY-2O-O4替代式Ⅱ所示化合物。組合物Δε增大的同時，ε ⊥反而減小，進而ε ⊥/Δε減小，將導致對比例2液晶組合物透過率降低。 Compared with Example 6, the liquid crystal composition of Comparative Example 2 does not contain the compound represented by Formula II, and the compound represented by Formula II is replaced by the compound PY-2O-O4. When the composition Δε increases, ε ⊥ decreases instead, and then ε ⊥ /Δε decreases, which will lead to a decrease in the transmittance of the liquid crystal composition of Comparative Example 2.

對比例comparative example 33

液晶組合物的配方及相應的性能如下表13所示。 表13 對比例3液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份）   CPWP-3-2 5   CPWP-3-O2 5 Ⅲ CC-3-V 41 Ⅳ PGU-2-F 2 Ⅳ CCPU-3-F 3 Ⅳ PPGU-Cp-F 1 Ⅴ PY-2O-O2 4 Ⅴ PY-2O-O4 8 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 3 Δε[1KHz, 25℃]：9.5 ε ⊥[1KHz, 25℃]：5.0 Δn[589nm, 25℃]：0.130 Cp：86.4℃ γ 1： 76mPa.s K 11：13.9 K 33：14.2 γ 1/ K 11：5.47 ε ⊥/Δε：0.526 The formula and corresponding properties of the liquid crystal composition are shown in Table 13 below. Table 13 The formula and corresponding properties of the liquid crystal composition of Comparative Example 3 category LCD monomer code Content (parts by mass) CPWP-3-2 5 CPWP-3-O2 5 III CC-3-V 41 IV PGU-2-F 2 IV CCPU-3-F 3 IV PPGU-Cp-F 1 Ⅴ PY-2O-O2 4 Ⅴ PY-2O-O4 8 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 6 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 3 Δε[1KHz, 25℃]: 9.5 ε ⊥ [1KHz, 25℃]: 5.0 Δn[589nm, 25℃]: 0.130 Cp: 86.4℃ γ 1 : 76mPa.s K 11 : 13.9 K 33 : 14.2 γ 1 / K 11 : 5.47ε⊥ /Δε: 0.526

與實施例6相比，對比例3液晶組合物中，不包含式Ⅰ、式Ⅱ所示化合物。對比例4液晶組合物介電各向異性相對於實施例6下降明顯，需要更大的驅動電壓才能將液晶分子完全驅動，從而消耗更多的電能。與實施例6相比，如果在相同的驅動電壓下，由於對比例1的液晶組合物無法完全驅動將降低其透過率，透過率降低便需要增加背光亮度才能獲得滿足需求的畫面亮度，從而消耗更多的電能。Compared with Example 6, the liquid crystal composition of Comparative Example 3 does not contain the compounds represented by formula I and formula II. The dielectric anisotropy of the liquid crystal composition of Comparative Example 4 is significantly lower than that of Example 6, and a higher driving voltage is required to fully drive the liquid crystal molecules, thereby consuming more electric energy. Compared with Example 6, if the liquid crystal composition of Comparative Example 1 cannot be fully driven at the same driving voltage, its transmittance will be reduced, and the decrease in transmittance will require increasing the brightness of the backlight to obtain a screen brightness that meets the requirements, thereby consuming More electricity.

對比例comparative example 44

液晶組合物的配方及相應的性能如下表14所示。 表14 對比例4液晶組合物的配方及相應的性能 類別 液晶單體代碼 含量（質量份） Ⅰ CPWP-3-OT 8 Ⅰ CPWP-3-T 8 Ⅱ Sb-2O-O5 5 Ⅱ Sc-2O-O5 5 Ⅲ CC-3-V 41 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 7 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 4 Δε[1KHz, 25℃]：10.3 ε ⊥[1KHz, 25℃]：5.5 Δn[589nm, 25℃]：0.128 Cp：82.6℃ γ 1： 70mPa.s K 11：14.1 K 33：13.3 γ 1/ K 11：4.96 ε ⊥/Δε：0.534 The formula and corresponding properties of the liquid crystal composition are shown in Table 14 below. Table 14 Formula and corresponding properties of the liquid crystal composition of Comparative Example 4 category LCD monomer code Content (parts by mass) I CPWP-3-OT 8 I CPWP-3-T 8 II Sb-2O-O5 5 II Sc-2O-O5 5 III CC-3-V 41 Ⅵ PGUQU-3-F 5 Ⅵ PGUQU-4-F 5 Ⅵ DPUQU-4-F 7 Ⅵ DGUQU-3-F 6 Ⅵ DGUQU-4-F 6 Ⅵ APUQU-3-F 4 Δε[1KHz, 25℃]: 10.3 ε ⊥ [1KHz, 25℃]: 5.5 Δn[589nm, 25℃]: 0.128 Cp: 82.6℃ γ 1 : 70mPa.s K 11 : 14.1 K 33 : 13.3 γ 1 / K 11 : 4.96ε⊥ /Δε: 0.534

與實施例1相比，對比例4液晶組合物中，式Ⅰ、式Ⅱ所示化合物的質量百分比含量之和為26%。對比例各項參數雖然與實施例相同或相近，但低溫儲存過程中出現晶析現象，具體低溫儲存情況見表15。Compared with Example 1, in the liquid crystal composition of Comparative Example 4, the sum of the mass percentages of the compounds represented by Formula I and Formula II is 26%. Although the parameters of the comparative example are the same or close to those of the examples, crystallization occurs during low-temperature storage. The specific low-temperature storage conditions are shown in Table 15.

下述的表15為實施例、對比例液晶組合物低溫儲存實驗資料。The following Table 15 is the low-temperature storage experiment data of the liquid crystal compositions of the examples and comparative examples.

低溫儲存實驗，使用5ml玻璃瓶和4μm液晶測試盒分別進行測試。分別取1ml實施例、對比例液晶組合物放入5ml玻璃瓶中，作為第一組低溫儲存實驗。將實施例、對比例液晶組合物灌注液晶測試盒中，作為第二組低溫儲存實驗。將灌注了液晶組合物的玻璃瓶放置在-20℃手套箱，將灌注了液晶組合物的液晶測試盒分別放置在-20℃、-30℃手套箱。 表15 實施例、對比例低溫儲存實驗資料   -20℃玻璃瓶 -20℃測試盒 -30℃測試盒 實施例1 480小時無晶析 720小時無晶析 720小時無晶析 實施例2 480小時無晶析 720小時無晶析 720小時無晶析 實施例3 480小時無晶析 720小時無晶析 720小時無晶析 實施例4 480小時無晶析 720小時無晶析 720小時無晶析 實施例5 480小時無晶析 720小時無晶析 720小時無晶析 實施例6 480小時無晶析 720小時無晶析 720小時無晶析 實施例7 480小時無晶析 720小時無晶析 720小時無晶析 實施例8 480小時無晶析 720小時無晶析 720小時無晶析 對比例1 480小時無晶析 720小時無晶析 48小時出現晶析 對比例2 120小時出現晶析 240小時出現晶析 120小時出現晶析 對比例3 120小時出現晶析 240小時出現晶析 120小時出現晶析 對比例4 24小時出現晶析 48小時出現晶析 24小時出現晶析 For the low-temperature storage experiment, a 5ml glass bottle and a 4μm liquid crystal test box were used for testing. Take 1ml of the liquid crystal composition of Example and Comparative Example respectively and put them into 5ml glass bottles as the first set of low-temperature storage experiments. The liquid crystal compositions of the examples and comparative examples were poured into the liquid crystal test box as the second set of low temperature storage experiments. The glass bottle filled with the liquid crystal composition was placed in a -20°C glove box, and the liquid crystal test box filled with the liquid crystal composition was placed in a -20°C and -30°C glove box, respectively. Table 15 embodiment, comparative example low temperature storage experiment data -20℃ glass bottle -20℃ test box -30℃ test box Example 1 480 hours without crystallization 720 hours without crystallization 720 hours without crystallization Example 2 480 hours without crystallization 720 hours without crystallization 720 hours without crystallization Example 3 480 hours without crystallization 720 hours without crystallization 720 hours without crystallization Example 4 480 hours without crystallization 720 hours without crystallization 720 hours without crystallization Example 5 480 hours without crystallization 720 hours without crystallization 720 hours without crystallization Example 6 480 hours without crystallization 720 hours without crystallization 720 hours without crystallization Example 7 480 hours without crystallization 720 hours without crystallization 720 hours without crystallization Example 8 480 hours without crystallization 720 hours without crystallization 720 hours without crystallization Comparative example 1 480 hours without crystallization 720 hours without crystallization Crystallization occurred in 48 hours Comparative example 2 Crystallization occurred in 120 hours Crystallization occurred in 240 hours Crystallization occurred in 120 hours Comparative example 3 Crystallization occurred in 120 hours Crystallization occurred in 240 hours Crystallization occurred in 120 hours Comparative example 4 Crystallization occurs within 24 hours Crystallization occurred in 48 hours Crystallization occurs within 24 hours

從上述表15可以看出，本發明實施例液晶組合物具有更寬的向列相溫度範圍。It can be seen from the above Table 15 that the liquid crystal composition of the embodiment of the present invention has a wider temperature range of the nematic phase.

下述的表16為實施例、對比例液晶組合物信賴性測試資料。The following Table 16 is the reliability test data of the liquid crystal compositions of the examples and comparative examples.

液晶組合物在液晶顯示元件或液晶顯示器生產過程中的信賴性通過紫外老化試驗並進行VHR測試來進行，液晶組合物紫外試驗前後的VHR資料變化越小，抗紫外能力越強。因此，通過比較各個實施例、對比例在試驗前後的VHR資料的變化來判斷抗紫外能力。The reliability of the liquid crystal composition in the production process of the liquid crystal display element or liquid crystal display is carried out through the ultraviolet aging test and the VHR test. The smaller the change of the VHR data before and after the ultraviolet test of the liquid crystal composition, the stronger the anti-ultraviolet ability. Therefore, the anti-ultraviolet ability is judged by comparing the changes of the VHR data of each embodiment and comparative examples before and after the test.

液晶組合物工作過程中的信賴性可以通過背光老化試驗並進行VHR測試來進行。在長時間的背光照射下，液晶組合物將長時間處在可見光、紫外線和60~70℃的工作環境中，受到外界環境的破壞。液晶組合物背光試驗前後的VHR資料變化越小，抗外界環境破壞能力越強。因此，通過比較各個實施例、對比例在試驗前後的VHR資料的變化來判斷抗外界環境破壞能力。The reliability of the liquid crystal composition in the working process can be tested by backlight aging test and VHR test. Under long-term backlight irradiation, the liquid crystal composition will be exposed to visible light, ultraviolet rays and a working environment of 60-70°C for a long time, and will be damaged by the external environment. The smaller the change in VHR data before and after the backlight test of the liquid crystal composition, the stronger the ability to resist external environmental damage. Therefore, by comparing the changes of the VHR data of each embodiment and comparative examples before and after the test, the ability to resist damage from the external environment can be judged.

首先，在進行紫外、背光老化試驗之前，測定液晶組合物的VHR資料作為初始VHR資料，然後，對液晶組合物進行紫外、背光老化試驗，在試驗後再次測定液晶組合物的VHR資料。First, before the UV and backlight aging test, measure the VHR data of the liquid crystal composition as the initial VHR data, then carry out the UV and backlight aging test on the liquid crystal composition, and measure the VHR data of the liquid crystal composition again after the test.

紫外老化試驗：將液晶組合物灌入相應測試盒中，在波長為365nm的紫外燈下照射5000mJ能量。Ultraviolet aging test: pour the liquid crystal composition into a corresponding test box, and irradiate 5000mJ energy under an ultraviolet lamp with a wavelength of 365nm.

背光試驗：將液晶組合物灌入相應測試盒中，封口，放到光強為25000nit的背光上進行背光老化試驗，老化1000H後進行VHR測試。Backlight test: pour the liquid crystal composition into the corresponding test box, seal it, and put it on a backlight with a light intensity of 25000 nit to perform a backlight aging test. After aging for 1000 hours, perform a VHR test.

在老化試驗後VHR資料相對於初始VHR資料變化越小，說明該液晶組合物抗外界環境破壞能力越強，因此，該液晶組合物的信賴性就越高。The smaller the change of the VHR data after the aging test relative to the initial VHR data, the stronger the ability of the liquid crystal composition to resist damage from the external environment, therefore, the higher the reliability of the liquid crystal composition.

另外，將實施例1~8、對比例1~4液晶組合物灌注入液晶測試盒，進行殘像測試，測試結果一併示於下述的表16中。 表16 實施例1~8、對比例1~4液晶組合物信賴性測試資料   VHR（初始） VHR（紫外） VHR（背光1000H） 殘像 實施例1 96.45 93.25 82.51 ◎ 實施例2 96.77 93.59 82.68 ◎ 實施例3 96.51 93.15 82.04 ◎ 實施例4 96.39 94.28 83.42 ◎ 實施例5 96.29 94.55 83.61 ◎ 實施例6 96.55 94.35 83.15 ◎ 實施例7 96.62 94.24 83.28 ◎ 實施例8 96.48 94.66 83.49 ◎ 對比例1 96.38 94.32 83.22 ◎ 對比例2 96.52 94.46 80.15 ○ 對比例3 96.34 94.18 76.84 ○ 對比例4 96.51 93.21 82.43 ◎ In addition, the liquid crystal compositions of Examples 1-8 and Comparative Examples 1-4 were poured into the liquid crystal test box, and the afterimage test was performed, and the test results are shown in Table 16 below. Table 16 Reliability test data of liquid crystal compositions of Examples 1-8 and Comparative Examples 1-4 VHR (initial) VHR (ultraviolet) VHR (backlight 1000H) afterimage Example 1 96.45 93.25 82.51 ◎ Example 2 96.77 93.59 82.68 ◎ Example 3 96.51 93.15 82.04 ◎ Example 4 96.39 94.28 83.42 ◎ Example 5 96.29 94.55 83.61 ◎ Example 6 96.55 94.35 83.15 ◎ Example 7 96.62 94.24 83.28 ◎ Example 8 96.48 94.66 83.49 ◎ Comparative example 1 96.38 94.32 83.22 ◎ Comparative example 2 96.52 94.46 80.15 ○ Comparative example 3 96.34 94.18 76.84 ○ Comparative example 4 96.51 93.21 82.43 ◎

從上述表16可以看出，本發明的實施例液晶組合物紫外、背光後的VHR下降較小，具有較高的抗紫外抗高溫能力，對殘像缺陷改善明顯。It can be seen from the above Table 16 that the liquid crystal composition of the embodiment of the present invention has a small decrease in VHR after ultraviolet light and backlight, has high anti-ultraviolet and high temperature resistance, and has obvious improvement on afterimage defects.

下述的表17為實施例、對比例液晶組合物透過率測試資料。 表17 實施例6、對比例1~3液晶組合物透過率測試資料   Δε ε ⊥ ε ⊥/Δε Tr（%） Δn d（μm） 實施例6 10.1 5.4 0.535 42.85 0.126 2.7 對比例1 9.3 5.3 0.570 33.64 0.131 2.6 對比例2 10.4 5.0 0.480 36.76 0.126 2.7 對比例3 9.5 5.0 0.526 31.34 0.130 2.6 The following Table 17 is the transmittance test data of the liquid crystal compositions of the examples and comparative examples. Table 17 Test data of transmittance of liquid crystal compositions of Example 6 and Comparative Examples 1-3 Δε ε ⊥ ε ⊥ /Δε Tr (%) Δn d (μm) Example 6 10.1 5.4 0.535 42.85 0.126 2.7 Comparative example 1 9.3 5.3 0.570 33.64 0.131 2.6 Comparative example 2 10.4 5.0 0.480 36.76 0.126 2.7 Comparative example 3 9.5 5.0 0.526 31.34 0.130 2.6

對實施例與對比例液晶組合物採用3.5V電壓驅動，延遲量為340nm的設計進行測試。由於對比例1、3介電各向異性較小，需要更大的電壓才能完全驅動，消耗更多的電能。採用與實施例6、對比例2相同的驅動電壓，對比例1、3無法完全驅動，透過率較小。實施例6與對比例2相比，垂直介電常數、ε⊥/Δε比值都更大，透過率更高。透過率的提高有利於背光的充分利用，從而降低背光亮度，降低能耗。The liquid crystal compositions of the examples and the comparative examples were driven by a voltage of 3.5V, and the retardation was designed to be 340nm. Since the dielectric anisotropy of Comparative Examples 1 and 3 is small, a larger voltage is required to fully drive and consume more electric energy. Using the same driving voltage as in Example 6 and Comparative Example 2, Comparative Examples 1 and 3 cannot be fully driven, and the transmittance is relatively small. Compared with Comparative Example 2, Example 6 has larger vertical permittivity, ε⊥/Δε ratio, and higher transmittance. The increase of the transmittance is conducive to the full use of the backlight, thereby reducing the brightness of the backlight and reducing energy consumption.

綜上所述，本發明的液晶組合物具有高的透過率、較高的光學各向異性、高的介電各向異性、高的垂直介電常數、高的ε⊥/Δε比值，較寬的向列相溫度範圍，以及抗紫外抗高溫能力強，無殘像缺陷的液晶組合物。本發明的液晶顯示元件、液晶顯示器通過包含前述的本發明的液晶組合物，具有高的對比度、面板輕薄、能耗低、較寬的使用溫度範圍，以及良好的信賴性。In summary, the liquid crystal composition of the present invention has high transmittance, high optical anisotropy, high dielectric anisotropy, high vertical permittivity, high ε⊥/Δε ratio, and a wide It is a liquid crystal composition with excellent nematic phase temperature range, strong UV resistance and high temperature resistance, and no afterimage defect. The liquid crystal display element and the liquid crystal display of the present invention contain the aforementioned liquid crystal composition of the present invention, and have high contrast, light and thin panel, low energy consumption, wide service temperature range, and good reliability.

顯然，本發明的上述實施例僅僅是為清楚地說明本發明所作的舉例，而並非是對本發明的實施方式的限定，對於所屬領域的普通技術人員來說，在上述說明的基礎上還可以做出其它不同形式的變化或變動，這裡無法對所有的實施方式予以窮舉，凡是屬於本發明的技術方案所引伸出的顯而易見的變化或變動仍處於本發明的保護範圍之列。Apparently, the above-mentioned embodiments of the present invention are only examples for clearly illustrating the present invention, and are not intended to limit the implementation of the present invention. Those of ordinary skill in the art can also make It is impossible to exhaustively list all the implementation modes here, and any obvious changes or changes derived from the technical solutions of the present invention are still within the scope of protection of the present invention.

無。none.

無。none.

Figure 110115363-A0101-11-0001-3
Figure 110115363-A0101-11-0001-3

無。none.

Claims (9)

一種正介電各向異性向列相液晶組合物，其特徵在於，所述液晶組合物包含一種或多種式I所示的化合物、以及一種或多種式Ⅱ所示的化合物：所述式I所示的化合物選自式I1至I6所示的化合物組成的組：
Figure 110115363-A0305-02-0042-1
Figure 110115363-A0305-02-0042-2
Figure 110115363-A0305-02-0042-3
Figure 110115363-A0305-02-0042-9
Figure 110115363-A0305-02-0042-5
Figure 110115363-A0305-02-0042-6
 所述式Ⅱ所示的化合物選自式Ⅱ1至Ⅱ6所示的化合物組成的組：
Figure 110115363-A0305-02-0042-7
 其中，R21、R31各自獨立地表示碳原子數為1~6的烷基。 A positive dielectric anisotropy nematic liquid crystal composition, characterized in that the liquid crystal composition comprises one or more compounds represented by formula I and one or more compounds represented by formula II: the compound represented by formula I The compounds shown are selected from the group consisting of compounds shown in formulas I1 to I6:
Figure 110115363-A0305-02-0042-1
Figure 110115363-A0305-02-0042-2
Figure 110115363-A0305-02-0042-3
Figure 110115363-A0305-02-0042-9
Figure 110115363-A0305-02-0042-5
Figure 110115363-A0305-02-0042-6
 The compound represented by the formula II is selected from the group consisting of compounds represented by the formula II1 to II6:
Figure 110115363-A0305-02-0042-7
 Wherein, R 21 and R 31 each independently represent an alkyl group having 1 to 6 carbon atoms. 根據請求項1所述的液晶組合物，其中，所述液晶組合物還包含一種或多種式Ⅲ所示的化合物：
Figure 110115363-A0305-02-0042-8
 其中，R4、R5各自獨立地表示碳原子數為1~10的烷基、碳原子數為1~10的烷氧基、碳原子數為2~10的烯基或碳原子數為3~8的烯氧基；
Figure 110115363-A0305-02-0043-10
、
Figure 110115363-A0305-02-0043-11
各自獨立的表示
Figure 110115363-A0305-02-0043-13
或
Figure 110115363-A0305-02-0043-14
。 The liquid crystal composition according to claim 1, wherein the liquid crystal composition further comprises one or more compounds represented by formula III:
Figure 110115363-A0305-02-0042-8
 Wherein, R 4 and R 5 each independently represent an alkyl group with 1 to 10 carbon atoms, an alkoxy group with 1 to 10 carbon atoms, an alkenyl group with 2 to 10 carbon atoms, or an alkenyl group with 3 carbon atoms. ~8 alkenyloxy groups;
Figure 110115363-A0305-02-0043-10
,
Figure 110115363-A0305-02-0043-11
independent expression
Figure 110115363-A0305-02-0043-13
or
Figure 110115363-A0305-02-0043-14
. 根據請求項1所述的液晶組合物，其中，所述液晶組合物還包含一種或多種式Ⅳ所示的化合物：
Figure 110115363-A0305-02-0043-12
 其中，R6表示碳原子數為1~10的烷基、碳原子數為1~10的烷氧基、碳原子數為2~10的烯基或碳原子數為3~8的烯氧基，且R6所示基團中任意一個或多個-CH2-被任選的亞環戊基、亞環丁基或亞環丙基替代；
Figure 110115363-A0305-02-0043-18
、
Figure 110115363-A0305-02-0043-19
各自獨立地表示
Figure 110115363-A0305-02-0043-20
、
Figure 110115363-A0305-02-0043-21
、
Figure 110115363-A0305-02-0043-23
、
Figure 110115363-A0305-02-0043-15
 X1、X2各自獨立地表示H或F；Y2表示-F、-CF3或-OCF3；m表示1或2，當m表示2時，
Figure 110115363-A0305-02-0043-17
可以相同或不同。 The liquid crystal composition according to claim 1, wherein the liquid crystal composition further comprises one or more compounds represented by formula IV:
Figure 110115363-A0305-02-0043-12
 Wherein, R represents an alkyl group with 1 to 10 carbon atoms, an alkoxy group with 1 to 10 carbon atoms, an alkenyl group with 2 to 10 carbon atoms or an alkenyloxy group with 3 to 8 carbon atoms , and any one or more -CH 2 - in the group represented by R 6 is replaced by an optional cyclopentylene, cyclobutylene or cyclopropylene;
Figure 110115363-A0305-02-0043-18
,
Figure 110115363-A0305-02-0043-19
express independently
Figure 110115363-A0305-02-0043-20
,
Figure 110115363-A0305-02-0043-21
,
Figure 110115363-A0305-02-0043-23
,
Figure 110115363-A0305-02-0043-15
 X 1 and X 2 each independently represent H or F; Y 2 represents -F, -CF 3 or -OCF 3 ; m represents 1 or 2, when m represents 2,
Figure 110115363-A0305-02-0043-17
Can be the same or different. 根據請求項1所述的液晶組合物，其中，所述液晶組合物還包含一種或多種式V所示的化合物：
Figure 110115363-A0305-02-0043-16
 其中，R7、R8各自獨立地表示碳原子數為1~10的烷基、碳原子數為1~10的烷氧基、碳原子數為2~10的烯基、氟取代的碳原子數為2~10的烯基、碳原子 數為3~8的烯氧基或氟取代的碳原子數為3~8的烯氧基，且R7、R8中任意一個或多個互不相鄰的-CH2-被任選的亞環戊基、亞環丁基或亞環丙基取代；Z1表示表示單鍵或-CH2O-；
Figure 110115363-A0305-02-0044-30
、
Figure 110115363-A0305-02-0044-31
各自獨立地表示
Figure 110115363-A0305-02-0044-28
、
Figure 110115363-A0305-02-0044-27
或
Figure 110115363-A0305-02-0044-26
；q表示1或2；n表示0或1；當q表示2時，
Figure 110115363-A0305-02-0044-29
可以相同或不同。 The liquid crystal composition according to claim 1, wherein the liquid crystal composition further comprises one or more compounds represented by formula V:
Figure 110115363-A0305-02-0043-16
 Wherein, R 7 and R 8 each independently represent an alkyl group with 1 to 10 carbon atoms, an alkoxy group with 1 to 10 carbon atoms, an alkenyl group with 2 to 10 carbon atoms, or a carbon atom substituted by fluorine. Alkenyl with 2 to 10 carbon atoms, alkenyloxy with 3 to 8 carbon atoms, or alkenyloxy with 3 to 8 carbon atoms substituted by fluorine, and any one or more of R 7 and R 8 are mutually exclusive Adjacent -CH 2 - is optionally substituted by cyclopentylene, cyclobutylene or cyclopropylene; Z 1 represents a single bond or -CH 2 O-;
Figure 110115363-A0305-02-0044-30
,
Figure 110115363-A0305-02-0044-31
express independently
Figure 110115363-A0305-02-0044-28
,
Figure 110115363-A0305-02-0044-27
or
Figure 110115363-A0305-02-0044-26
;q means 1 or 2; n means 0 or 1; when q means 2,
Figure 110115363-A0305-02-0044-29
Can be the same or different. 根據請求項4所述的液晶組合物，其中，所述式V所示的化合物選自式V1至V8所示的化合物組成的組，
Figure 110115363-A0305-02-0044-24
 其中，R7、R8各自獨立地表示碳原子數為1~5的烷基、碳原子數為1~5的烷氧基，且R7中任意一個或多個互不相鄰的-CH2-被任選的亞環戊基、亞環丁基或亞環丙基取代。 The liquid crystal composition according to claim 4, wherein the compound represented by the formula V is selected from the group consisting of compounds represented by the formulas V1 to V8,
Figure 110115363-A0305-02-0044-24
 Wherein, R 7 and R 8 each independently represent an alkyl group with 1 to 5 carbon atoms, an alkoxy group with 1 to 5 carbon atoms, and any one or more non-adjacent -CH in R 7 2 - Substituted by optional cyclopentylene, cyclobutylene or cyclopropylene. 根據請求項1所述的液晶組合物，其中，所述液晶組合物還包含一種或多種式Ⅵ所示的化合物：
Figure 110115363-A0305-02-0044-25
 其中，R9表示碳原子數為1-10的烷基、碳原子數為1-10的烷氧基、碳原子數為2-10的烯基、碳原子數為3-8的鏈烯氧基，且R9所示基團中任意一個或多個不相連的-CH2-任選被亞環戊基、亞環丁基或亞環丙基取代；
Figure 110115363-A0305-02-0045-34
、
Figure 110115363-A0305-02-0045-35
各自獨立地表示
Figure 110115363-A0305-02-0045-36
、
Figure 110115363-A0305-02-0045-37
、
Figure 110115363-A0305-02-0045-38
、
Figure 110115363-A0305-02-0045-32
 p表示1或2；當p表示2時，
Figure 110115363-A0305-02-0045-39
可以相同或不同；X3、X4各自獨立地表示H或F。 The liquid crystal composition according to claim 1, wherein the liquid crystal composition further comprises one or more compounds represented by formula VI:
Figure 110115363-A0305-02-0044-25
 Wherein, R represents an alkyl group with 1-10 carbon atoms, an alkoxy group with 1-10 carbon atoms, an alkenyl group with 2-10 carbon atoms, and an alkenyloxy group with 3-8 carbon atoms. group, and any one or more unconnected -CH 2 - in the group represented by R 9 is optionally substituted by cyclopentylene, cyclobutylene or cyclopropylene;
Figure 110115363-A0305-02-0045-34
,
Figure 110115363-A0305-02-0045-35
express independently
Figure 110115363-A0305-02-0045-36
,
Figure 110115363-A0305-02-0045-37
,
Figure 110115363-A0305-02-0045-38
,
Figure 110115363-A0305-02-0045-32
 p means 1 or 2; when p means 2,
Figure 110115363-A0305-02-0045-39
may be the same or different; X 3 and X 4 each independently represent H or F. 根據請求項6所述的液晶組合物，其中，所述液晶組合物還包含一種或多種選自式Ⅶ1至式Ⅶ5所示的化合物：
Figure 110115363-A0305-02-0045-33
Figure 110115363-A0305-02-0045-40
Figure 110115363-A0305-02-0045-41
Figure 110115363-A0305-02-0045-42
Figure 110115363-A0305-02-0045-43
 其中，R10表示碳原子數為1-10的烷基，且R10所示基團中任意一個或多個不相連的-CH2-任選被亞環戊基、亞環丁基或亞環丙基取代；R11表示碳原子數為1-10的烷氧基。 The liquid crystal composition according to Claim 6, wherein the liquid crystal composition further comprises one or more compounds selected from formula VII1 to formula VII5:
Figure 110115363-A0305-02-0045-33
Figure 110115363-A0305-02-0045-40
Figure 110115363-A0305-02-0045-41
Figure 110115363-A0305-02-0045-42
Figure 110115363-A0305-02-0045-43
 Wherein, R 10 represents an alkyl group with 1-10 carbon atoms, and any one or more unconnected -CH 2 - in the groups represented by R 10 are optionally replaced by cyclopentylene, cyclobutylene or Cyclopropyl substitution; R 11 represents an alkoxy group with 1-10 carbon atoms. 一種液晶顯示元件，其包含請求項1~7中任一項所述的液晶組合物，所述顯示元件為有源矩陣顯示元件或無源矩陣顯示元件。 A liquid crystal display element, which comprises the liquid crystal composition described in any one of claims 1 to 7, and the display element is an active matrix display element or a passive matrix display element. 一種液晶顯示器，其包含請求項1~7中任一項所述的液晶組合物，所述液晶顯示器為有源矩陣顯示器或無源矩陣顯示器。 A liquid crystal display comprising the liquid crystal composition described in any one of claim items 1 to 7, the liquid crystal display being an active matrix display or a passive matrix display.
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