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TWI787361B - Cosmetic composition for hair and scalp for enhancing hair volume and use thereof - Google Patents

Cosmetic composition for hair and scalp for enhancing hair volume and use thereof Download PDF

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TWI787361B
TWI787361B TW107134722A TW107134722A TWI787361B TW I787361 B TWI787361 B TW I787361B TW 107134722 A TW107134722 A TW 107134722A TW 107134722 A TW107134722 A TW 107134722A TW I787361 B TWI787361 B TW I787361B
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hair
cosmetic composition
feeling
hydrophobic polymer
polymer
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TW201919576A (en
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鄭允赫
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南韓商愛茉莉太平洋股份有限公司
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair

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Abstract

本發明涉及增強毛髮的蓬鬆感的毛髮或頭皮用化妝品組合物,更加詳細而言,涉及用於增強毛髮的蓬鬆感的化妝品組合物,其包含藉由增加髮絲中接近於頭皮的毛幹部位的疏水性(Hydrophobicity)來發揮增加毛髮的蓬鬆感的效果的單獨的疏水性聚合物作為有效成分,或者包含疏水性聚合物及非離子性聚合物的混合物作為有效成分。與通常的用於塗布毛髮的化妝品組合物(例如,洗髮精、潤髮乳等)相比,利用本發明的用於增強毛髮的蓬鬆感的化妝品組合物時,具有如下效果,即,毛髮蓬鬆感的形成得到改善(增強毛髮的蓬鬆感)的同時,位於頭上部的頭頂毛髮的彈性感變得豐富,並且所述化妝品組合物的毛髮殘留感得到改善,而且毛髮的收尾塗覆感得到改善。 The present invention relates to a cosmetic composition for hair or scalp that enhances the volume of hair. More specifically, it relates to a cosmetic composition for enhancing the volume of hair, which comprises The hydrophobicity (Hydrophobicity) to exert the effect of increasing the fluffy feeling of the hair is a single hydrophobic polymer as an active ingredient, or a mixture of a hydrophobic polymer and a nonionic polymer is used as an active ingredient. Compared with the usual cosmetic composition for coating hair (for example, shampoo, conditioner, etc.), when the cosmetic composition for enhancing the volume of hair of the present invention is used, it has the effect that the hair While the formation of the fluffy feeling is improved (enhancing the fluffy feeling of the hair), the elastic feeling of the hair on the top of the head becomes richer, and the hair residue feeling of the cosmetic composition is improved, and the finish coating feeling of the hair is improved. improve.

Description

增強毛髮的蓬鬆感的毛髮或頭皮用化妝品組合物及其用途 Cosmetic composition for hair or scalp for enhancing volume of hair and use thereof

本發明涉及增強毛髮的蓬鬆感的毛髮或頭皮用化妝品組合物,更加詳細而言,涉及用於增強毛髮的蓬鬆感的化妝品組合物,其包含藉由增加髮絲中接近於頭皮的毛幹部位的疏水性(Hydrophobicity)來發揮增加毛髮的蓬鬆感的效果的單獨的疏水性聚合物作為有效成分,或者包含疏水性聚合物及非離子性聚合物的混合物作為有效成分。 The present invention relates to a cosmetic composition for hair or scalp that enhances the volume of hair. More specifically, it relates to a cosmetic composition for enhancing the volume of hair, which comprises The hydrophobicity (Hydrophobicity) to exert the effect of increasing the fluffy feeling of the hair is a single hydrophobic polymer as an active ingredient, or a mixture of a hydrophobic polymer and a nonionic polymer is used as an active ingredient.

毛髮是平均厚度為約0.07mm左右的又薄又細的蛋白質結構體,大致可以分為露在皮膚外部的毛幹部(Hair Shaft)和在皮膚內部的毛根部(Hair Root)。頭皮具有與皮膚相似的基本結構和生理機能,頭皮毛囊(Hair Follicle)的特徵在於其比其他部位複雜且有很多皮脂腺。毛根部是在毛囊內部的部分,其是埋沒在頭皮內的部分且深度為2~4mm左右。毛根的最底部像珠子一樣膨脹,該部分稱為毛球(Hair Bulb),毛髮的粗細取決於該部分的大小。 Hair is a thin and thin protein structure with an average thickness of about 0.07mm, and can be roughly divided into the hair shaft (Hair Shaft) exposed outside the skin and the hair root (Hair Root) inside the skin. The scalp has a basic structure and physiological function similar to the skin, and the hair follicle of the scalp is characterized by being more complex than other parts and having many sebaceous glands. The hair root is the part inside the hair follicle, which is the part buried in the scalp and has a depth of about 2~4mm. The very bottom of the hair root expands like a bead. This part is called the hair bulb (Hair Bulb), and the thickness of the hair depends on the size of this part.

放大毛髮的截面可以看出,其分為三個部分,即,最內側且為中心部的毛髓質(Medulla)、包裹毛髓質的毛皮質(Cortex)以及最外部的角質層(Cuticle)。角質層是覆蓋毛髮的表面且包裹著毛髮內部的耐化學性強的部位,由從外側開始稱為上表皮(Epicuticle)、外表皮(Exocuticle)及內表皮(Endocuticle)的 三個層構成。毛皮質存在於角質層的內側,佔據毛髮的大部分(85~90%),其主要成分為角蛋白,由皮質細胞和細胞間結合物質構成,且為親水性而容易受到燙染作用的部位。毛髓質存在於毛髮的中心部,具有一些黑色素粒子,且髓質內有很多大大小小的氣泡,因此含有空氣。 Enlarging the cross-section of the hair, it can be seen that it is divided into three parts, namely, the innermost and central medulla (Medulla), the fur cortex (Cortex) that wraps the hair medulla, and the outermost cuticle (Cuticle) . The cuticle is a highly chemical-resistant part that covers the surface of the hair and wraps the inside of the hair. It is composed of epicuticle, exocuticle, and endocuticle from the outside. Consists of three layers. The fur cortex exists on the inner side of the cuticle and occupies most of the hair (85~90%). Its main component is keratin, which is composed of cortical cells and intercellular binding substances, and is hydrophilic and susceptible to hot dyeing. . The hair medulla exists in the center of the hair, with some melanin particles, and there are many large and small air bubbles in the medulla, so it contains air.

通常,毛髮由稱為角蛋白的蛋白質構成,具體而言,毛髮為含有14~18%的18種氨基酸中的胱胺酸的角蛋白。這些角蛋白在水或中性溶劑等溫和的條件下是非常強的蛋白質的一種,但是在梳理、吹髮時的熱、染色、燙髮等過度的物理化學性處理時會容易受損。最近,由於頻繁的燙髮、染色等物理性、化學性或環境方面的多種因素,使毛髮受損,從而導致毛髮變粗糙,失去光澤,從而使柔順性和柔韌效果降低,並且因摩擦力的增加而使整理毛髮變得困難,而且出現斷髮或髮尖分叉等問題之外,還出現毛髮變細,失去彈性,導致失去活力並下垂,從而失去蓬鬆感的問題。 Generally, hair is composed of a protein called keratin, and specifically, hair is keratin containing 14 to 18% of cystine among 18 kinds of amino acids. These keratins are very strong proteins under mild conditions such as water or neutral solvents, but they are easily damaged by excessive physical and chemical treatments such as combing, heat during blow drying, dyeing, and perms. Recently, the hair is damaged due to physical, chemical or environmental factors such as frequent perms and dyeing, resulting in rough hair and loss of luster, resulting in reduced softness and flexibility, and increased friction This makes it difficult to manage the hair, and in addition to problems such as hair breakage or split ends, the hair becomes thinner and loses elasticity, leading to loss of vitality and drooping, thereby losing volume.

毛髮的蓬鬆感取決於覆蓋(佔據)皮膚的由一個以上的髮絲組成的毛髮整體的總面積。例如,假設有兩個頭型和髮型相似的人,其中一個人的毛髮長度長,而另一個人的毛髮長度短,則與毛髮長度短的人相比,由於毛髮長度長的人的毛髮面積更大,可以說其毛髮的蓬鬆感更大(毛髮的蓬鬆度高)。此外,構成髮辮(Hair Bundle或Hair Tress)的髮絲之間的間距,尤其與接近毛根的毛幹部位(髮莖、毛莖)相比,毛髮末端(髮尖部分)的毛幹部位的髮絲之間的間距越大,毛髮的蓬鬆度越高。即,皮膚上的毛髮整體的面積大且髮辮的髮絲之間的間距大的人,由於毛髮的蓬鬆感增加,通常被認為具有更加豐盛的毛髮。 The fluffiness of the hair depends on the total area of the whole hair consisting of one or more strands covering (occupying) the skin. For example, given two people with similar head shapes and hairstyles, one with long hair length and one with short hair length, the person with the longer hair length will have a larger area of hair compared to the person with the shorter hair length , it can be said that the fluffy feeling of the hair is greater (the fluffy degree of the hair is high). In addition, the distance between the strands of hair constituting the braid (Hair Bundle or Hair Tress) is especially greater than that of the hair shaft at the end of the hair (hair tip) compared to the hair shaft near the hair root (hair shaft, hair shaft). The greater the spacing between hair strands, the more volume the hair will have. That is, a person who has a large overall area of hair on the skin and a large space between the hair strands of the braid is generally considered to have thicker hair because the volume of the hair increases.

就毛髮而言,由於皮膚的老化,尤其由於在室外暴露於紫外線而引起的皮膚或毛髮的老化,或者由於化學性/物理性的損傷而引起缺乏構成毛髮纖維的成分及/或毛髮纖維結構的變形等,導致毛髮纖維的粗細變細,毛髮纖維的強度也變弱,從而會顯示出毛髮蓬鬆感變小的傾向。 In the case of hair, aging of the skin or hair due to aging of the skin, especially due to outdoor exposure to ultraviolet rays, or lack of components constituting the hair fiber and/or hair fiber structure due to chemical/physical damage The thickness of the hair fiber becomes thinner due to deformation and the like, and the strength of the hair fiber also becomes weaker, which tends to show a tendency for the hair to become less fluffy.

尤其,即使是具有相似的頭型和髮型的人,根據毛髮纖維的粗細及強度,毛髮的蓬鬆感會有所不同,例如,如果毛髮纖維的強度變弱,則從頭皮長出的毛髮的從毛根向皮膚外部凸出的毛髮的毛幹部位的末端部位為止的支撐剩餘毛髮的力量會減少。其結果,毛髮整體會發生“下垂”的現象,會帶來感官上的“蓬鬆感看起來下降”、“看起來無力”、“毛髮看起來老化”等美容學上的負面的感覺,從而在髮型等毛髮管理方面也會有困難。 In particular, even among people with similar head shapes and hairstyles, the volume of the hair varies depending on the thickness and strength of the hair fibers. For example, if the strength of the hair fibers becomes weak, the hair growing from the The power to support the remaining hair until the end of the hair shaft where the hair root protrudes to the outside of the skin decreases. As a result, the hair as a whole "sags" and causes cosmetically negative sensations such as "looking less fluffy", "looking weak" and "aging the hair" Hair management, such as hairstyles, may also be difficult.

為了保持並增強毛髮的蓬鬆感,重要的是提高毛髮的彈性,尤其,藉由強化髮根(毛根)來增強毛髮彈性,從而能夠賦予專注於整體髮型的效果。 In order to maintain and enhance the volume of the hair, it is important to increase the elasticity of the hair. In particular, by strengthening the hair root (hair root) to enhance the elasticity of the hair, it is possible to give the effect of focusing on the overall hairstyle.

毛髮可以吸收毛髮重量的40%的液體/氣體狀態的水,毛髮的含水率多受周圍環境的影響。例如,已知暴露在持續高溫狀態的環境、pH變化大的環境、由於毛髮損傷而使毛髮的氫鍵斷裂的環境等時,毛髮的水分含量會增加。 Hair can absorb 40% of the hair's weight in liquid/gas state water, and the moisture content of hair is mostly affected by the surrounding environment. For example, it is known that the moisture content of hair increases when it is exposed to an environment in which a high temperature continues, an environment in which pH changes greatly, an environment in which hydrogen bonds of hair are broken due to hair damage, and the like.

已知毛髮的水合作用(Hydration)的變化會影響纖維的彈性(Fiber Elasticity)。例如,已知毛髮的含水率增加15~10%,則髮絲(Thread)的直徑增加約0.5~1%左右(Maria et al.,Brazilian jr of pharm.,Vol45,n.1,2009)。 It is known that changes in hair hydration (Hydration) affect fiber elasticity (Fiber Elasticity). For example, it is known that when the water content of hair increases by 15-10%, the diameter of the hair (Thread) increases by about 0.5-1% (Maria et al., Brazilian jr of pharm., Vol45, n.1, 2009).

尤其,就毛髮的化學特性而言,鄰近頭皮的毛髮部位和離頭皮遠的毛髮部位不同,接近頭皮的毛髮部位的角質層(Cuticle)是以完整的狀態存在,但毛髮的末端部(Tip)是以幾乎沒有角質層的狀態存在(Bhushan et al.,Progress in Materials Science,53:585-710,2008)。 In particular, in terms of the chemical properties of the hair, the hair part near the scalp is different from the hair part far away from the scalp. The cuticle of the hair part near the scalp is in a complete state, but the tip part of the hair (Tip) It exists in a state with almost no cuticle (Bhushan et al., Progress in Materials Science, 53: 585-710, 2008).

另外,就以洗髮精為代表的用於清洗毛髮或頭皮的組合物而言,其通常的功能在於清洗毛髮和頭皮,但是,最近正在推出除了原本的清洗目的之外還具有附加功能的多種產品,具體而言,正在開發的產品有藉由使用矽來防止毛髮乾燥後毛髮亂飛並提高柔順性的產品、以整理和修復由於染色或燙髮等毛髮處理而受損的毛髮為目的的產品等。然而,現有的產品雖然使用矽而有利於對毛髮提供柔順性、滋潤性、柔韌性、梳理容易性等調理效果,但是對於細的毛髮或受損的毛髮等彈性弱的毛髮,反而會使毛髮過於下塌並下垂,從而在賦予毛髮蓬鬆感的方面具有問題。為了解決這種問題,對用於在清洗時或清洗後改善毛髮的柔順性且恢復及強化受損毛髮的毛髮用化妝品進行了持續的研究。其結果,嘗試並開發了用於賦予強力且持續性的毛髮調理效果的多種方法,並已實用化。 In addition, in the case of compositions for cleaning hair or scalp represented by shampoo, its usual function is to cleanse hair and scalp, but recently, various products that have additional functions in addition to the original cleaning purpose are being released. Products, specifically, products under development include products that prevent hair from flying away after drying and improve softness by using silicon, and products that aim to organize and repair hair damaged by hair treatments such as coloring or perming Wait. However, although existing products use silicon to provide conditioning effects such as softness, moisturization, flexibility, and ease of combing, for hair with weak elasticity such as thin hair or damaged hair, it will make the hair less elastic. Too much sagging and drooping have problems in imparting a fluffy feeling to the hair. In order to solve such problems, research has continued on hair cosmetics for improving the softness of hair and restoring and strengthening damaged hair during or after washing. As a result, various methods for imparting a strong and sustained hair conditioning effect have been tried and developed, and have been put into practical use.

根據現有技術,有在清洗/生髮產品中藉由使用毛髮塗覆成分而在美容方面對是否形成毛髮的蓬鬆感進行表達或訴求的例子,但還沒有明確報導使用具體什麼成分來形成毛髮的蓬鬆感。此外,現有的毛髮化妝品組合物中也試圖單獨使用聚季銨鹽-11、多晶矽、聚氨酯等來賦予毛髮蓬鬆感,但實際蓬鬆感的增強效果還沒有達到令人滿意的水平。 According to the prior art, there are examples of using hair coating ingredients in cleansing/hair growth products to express or appeal for the fluffy feeling of the hair in terms of cosmetics, but there is no clear report on what specific ingredients are used to form the fluffy hair feel. In addition, in existing hair cosmetic compositions, polyquaternium-11, polysilicon, polyurethane, etc. have been used alone to impart volume to hair, but the effect of enhancing volume has not yet reached a satisfactory level.

在這種技術背景下,本發明人為了開發改善毛髮蓬鬆感等毛髮狀態的毛髮用外用劑組合物而不斷努力的結果,與通常的用於塗布毛髮的化妝品組合物(例如,洗髮精、潤髮乳等)相比,利用本發明的包含單獨的疏水性聚合物作為有效成分,或者包含疏水性聚合物及非離子性聚合物的混合物作為有效成分,較佳地包含由異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物及聚季銨鹽-55 組成的疏水性聚合物和作為非離子性聚合物的聚季銨鹽-11的混合物作為有效成分的用於增強毛髮的蓬鬆感的化妝品組合物時,確認具有如下效果,即,毛髮蓬鬆感的形成得到改善(增強毛髮的蓬鬆感)的同時,位於頭上部的頭頂毛髮的彈性感變得豐富,並且化妝品組合物的毛髮殘留感得到改善,而且毛髮的收尾塗覆感得到改善,從而完成了本發明。 Against this technical background, as a result of continuous efforts of the present inventors to develop an external preparation composition for hair that improves the condition of hair such as fluffy hair, it differs from conventional cosmetic compositions for coating hair (for example, shampoo, hair conditioner, etc.), using the present invention comprising a single hydrophobic polymer as an active ingredient, or a mixture of a hydrophobic polymer and a nonionic polymer as an active ingredient, preferably containing isododecane /Butyl Acrylate/Hydroxypropyl Dimethicone Acrylate Copolymer, Vinyl Dimethicone/Methicone Silsesquioxane Crosspolymer and Polyquaternium -55 When the mixture of the hydrophobic polymer and the polyquaternium-11 as the nonionic polymer is used as the cosmetic composition for enhancing the fluffy feeling of the hair as an active ingredient, it is confirmed to have the following effect, that is, the effect of the fluffy feeling of the hair While the formation is improved (increasing the fluffy feeling of the hair), the elastic feeling of the hair on the top of the head becomes rich, and the hair residue feeling of the cosmetic composition is improved, and the finish coating feeling of the hair is improved, thereby completing the this invention.

本發明的目的在於提供用於增強毛髮的蓬鬆感的化妝品組合物。 An object of the present invention is to provide a cosmetic composition for enhancing the volume of hair.

為了達到上述目的,本發明提供用於增強毛髮的蓬鬆感的化妝品組合物,其包含單獨的疏水性聚合物作為有效成分,或者包含疏水性聚合物及非離子性聚合物的混合物作為有效成分,較佳地包含選自異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物及聚季銨鹽-55中的1種以上,更佳地為2種以上,最佳地為3種疏水性聚合物及作為非離子性聚合物的聚季銨鹽-11的混合物作為有效成分。 In order to achieve the above object, the present invention provides a cosmetic composition for enhancing the volume of hair, which comprises a single hydrophobic polymer as an active ingredient, or a mixture of a hydrophobic polymer and a nonionic polymer as an active ingredient, Preferably comprising isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer, vinyl dimethicone/methicone silsesquioxane One or more of alkyl crosslinked polymers and polyquaternium-55, more preferably two or more, most preferably three kinds of hydrophobic polymers and polyquaternium-11 as a nonionic polymer mixture as an active ingredient.

此外,本發明提供單獨的疏水性聚合物或者疏水性聚合物及非離子性聚合物的混合物在製備用於增強毛髮的蓬鬆感的化妝品組合物或化妝品中的用途,尤其提供作為毛髮蓬鬆感增強劑的用途。 In addition, the present invention provides the use of a single hydrophobic polymer or a mixture of a hydrophobic polymer and a nonionic polymer in the preparation of a cosmetic composition or cosmetics for enhancing the volume of hair, especially as a hair volume enhancement product. use of the agent.

與通常的用於塗布毛髮的化妝品組合物(例如,洗髮精、潤髮乳等)相比,利用本發明的用於增強毛髮的蓬鬆感的化妝品組合物時,具有如下效果,即,毛髮蓬鬆感的形成得到改善(增強毛髮的蓬鬆感)的同時,位於頭上部的頭頂 毛髮的彈性感變得豐富,並且所述化妝品組合物的毛髮殘留感得到改善,而且毛髮的收尾塗覆感得到改善。 Compared with the usual cosmetic composition for coating hair (for example, shampoo, conditioner, etc.), when the cosmetic composition for enhancing the volume of hair of the present invention is used, it has the effect that the hair While the formation of volume is improved (increases the volume of the hair), the crown located on the upper part of the head The elastic feeling of the hair becomes rich, and the hair residue feeling of the cosmetic composition is improved, and the finish coating feeling of the hair is improved.

第1圖示出藉由增加髮絲中接近於頭皮的毛幹部位的疏水性而能夠發揮增強毛髮的蓬鬆感的效果的從皮膚或頭皮的毛根向皮膚外部凸出的毛幹部位中接近於毛根的4~6cm的毛髮部位(平均為5cm)。 FIG. 1 shows the skin or the hair shaft protruding from the hair root of the scalp to the outside of the skin, which is close to the hair shaft, which can exert the effect of enhancing the volume of the hair by increasing the hydrophobicity of the hair shaft close to the scalp. The hair part of 4~6cm from the root of the hair (average is 5cm).

第2圖示出將除了從皮膚或頭皮的毛根向皮膚外部凸出的毛幹部位中接近於毛根的4~6cm的毛髮部位(5cm的毛幹部位)之外的髮辮的毛髮部位進行脫色處理的結果。 Figure 2 shows decolorization of braided hair except for the 4-6 cm hair portion (5 cm hair shaft portion) that protrudes from the hair root of the skin or scalp to the outside of the skin. The result of processing.

第3圖示出以異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物對不同髮絲數量的髮辮進行處理後測量髮辮傾斜至45°角度的起始點(point)為止的距離來確認毛髮蓬鬆感是否得到增強的結果((a)髮絲數量:5個;(b)髮絲數量:10個;(c)髮絲數量:20個;(d)髮絲數量:40個;(e)髮絲數量:100個)。 Figure 3 shows the measurement of the inclination of the braids to an angle of 45° after treatment with isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer for braids with different numbers of hairs. ((a) Number of hair strands: 5; (b) Number of hair strands: 10; (c) Number of hair strands: 20; ( d) Number of hair strands: 40 pieces; (e) Number of hair strands: 100 pieces).

第4圖示出評價試驗物質對毛髮的毛幹部位的毛髮蓬鬆感的方法,示出毛髮的蓬鬆感的評價中所利用的不同部位的毛髮的長度。 Fig. 4 shows a method of evaluating the hair volume of the test substance on the hair shaft portion of the hair, and shows the length of hair at different sites used in the evaluation of the volume of the hair.

第5圖示出評價試驗物質對整體毛髮的蓬鬆感的方法,示出毛髮的蓬鬆感的評價中所利用的不同部位的毛髮的長度。 Fig. 5 shows a method of evaluating the volume of the test substance on the whole hair, and shows the length of hair at different parts used in the evaluation of the volume of the hair.

第6圖示出以40~50歲年齡段的成人為對象而對洗髮精組合物的使用感進行感官評價(感官檢查)的結果(其中,第6圖(a)示出現有洗髮精的感官評價的結果,第6圖(b)示出基礎洗髮精的感官評價的結果)。 Fig. 6 shows the results of sensory evaluation (sensory test) of the feeling of use of the shampoo composition for adults aged 40 to 50 (wherein, Fig. 6 (a) shows the results of a conventional shampoo The results of the sensory evaluation of the basic shampoo, Figure 6 (b) shows the results of the sensory evaluation of the basic shampoo).

第7圖示出根據本發明的毛髮蓬鬆感的評價方法將用於增強毛髮的蓬鬆感的洗髮精塗布於以40~50歲年齡段的成人為對象的毛髮後進行使用感 的感官評價的結果,其中所述用於增強毛髮的蓬鬆感的洗髮精是將異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物及聚季銨鹽-55和聚季銨鹽-11添加到基礎洗髮精中來製備(其中,第7圖(a)示出現有洗髮精的感官評價的結果,第7圖(b)示出本發明的實施例8的用於增強毛髮的蓬鬆感的化妝品組合物的感官評價的結果)。 Fig. 7 shows the evaluation method of hair volume according to the present invention. Shampoo for enhancing the volume of hair is applied to the hair of adults aged 40 to 50 to evaluate the feeling of use. The results of the sensory evaluation, wherein the shampoo used to enhance the volume of hair is isododecane / butyl acrylate / hydroxypropyl polydimethylsiloxane acrylate copolymer, vinyl polydimethicone Methicone/Methicone Silsesquioxane Crosspolymer and Polyquaternium-55 and Polyquaternium-11 are added to the base shampoo to prepare (of which, Figure 7 (a) shows the result of the sensory evaluation of the conventional shampoo, and FIG. 7(b) shows the result of the sensory evaluation of the cosmetic composition for enhancing the volume of hair according to Example 8 of the present invention).

最佳實施方式 best practice

只要沒有以其他方式進行定義,本說明書中使用的所有技術性術語及科學性術語具有與本發明所屬技術領域中具有通常知識者通常所理解的含義相同的含義。通常,本說明書中使用的命名法是本技術領域中眾所周知的且是通常使用的。 Unless otherwise defined, all technical terms and scientific terms used in this specification have the same meaning as commonly understood by those having ordinary knowledge in the technical field to which the present invention belongs. In general, the nomenclature used in this specification is well-known and commonly used in the technical field.

下面,對本發明進行更加具體的說明。 Next, the present invention will be described in more detail.

本說明書中表示長度、面積、體積、時間(期間)、濃度、含量、溫度等時所使用的術語“約”是指在該數值或數值範圍內存在最大10%的容許誤差。 The term "about" used in this specification when expressing length, area, volume, time (period), concentration, content, temperature, etc. means that there is a maximum 10% allowable error within the value or range of values.

本說明書整體中,在沒有特別說明的情況下,用於示出特定物質的濃度而使用的“%”是指固體/固體時為(重量/重量)%、固體/液體時為(重量/體積)%、以及液體/液體時為(體積/體積)%。 Throughout this specification, unless otherwise specified, "%" used to indicate the concentration of a specific substance means (weight/weight)% for solid/solid, (weight/volume) for solid/liquid )% and (volume/volume)% for liquid/liquid.

在一個方面,本發明涉及用於增強毛髮的蓬鬆感的化妝品組合物,其包含單獨的疏水性聚合物作為有效成分,或者包含疏水性聚合物及非離子性聚合物的混合物作為有效成分。 In one aspect, the present invention relates to a cosmetic composition for enhancing volume of hair, comprising a hydrophobic polymer alone as an active ingredient, or a mixture of a hydrophobic polymer and a nonionic polymer as an active ingredient.

本發明的特徵在於,所述組合物較佳地包含選自異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物(Isododecane/Butyl Acrylate/Hydroxypropyl Dimethicone Acrylate Copolymer)、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物(Vinyl dimethicone/methicone silsesquioxane crosspolymer)及聚季銨鹽-55(polyquaternium-55,PQ-55)中的1種以上,更佳地為2種以上,最佳地為3種疏水性聚合物和作為非離子性聚合物的聚季銨鹽-11(polyquaternium-11,PQ-11)的混合物作為有效成分。 The present invention is characterized in that the composition preferably comprises isododecane/butyl acrylate/hydroxypropyl polydimethylsiloxane acrylate copolymer (Isododecane/Butyl Acrylate/Hydroxypropyl Dimethicone Acrylate Copolymer), vinyl dimethicone/methicone silsesquioxane crosspolymer (Vinyl dimethicone/methicone silsesquioxane crosspolymer) and polyquaternium-55 (polyquaternium -55, more than one in PQ-55), more preferably more than two, most preferably three kinds of hydrophobic polymers and polyquaternium-11 (polyquaternium-11, PQ-11) mixtures as active ingredients.

本發明的特徵在於,以重量為基準,所述疏水性聚合物及所述非離子性聚合物的混合物是以1~10:1~10,較佳地以1~5:1~5,更佳地以1~5:1~4的重量比混合所述疏水性聚合物及所述非離子性聚合物。較佳地,所述混合物是以5~1000:5~1000:5~1000:5~1000(即,0.05~10:0.05~10:0.05~10:0.05~10),更佳地以5~200:5~200:5~200:100~400(即,0.05~2:0.05~2:0.05~2:1~4),又更佳地以100:100:100:400(即,1:1:1:4)的重量比混合作為疏水性聚合物的異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物、聚季銨鹽-55及作為非離子性聚合物的聚季銨鹽-11。 The present invention is characterized in that, based on weight, the mixture of the hydrophobic polymer and the nonionic polymer is 1~10: 1~10, preferably 1~5: 1~5, more Preferably, the hydrophobic polymer and the nonionic polymer are mixed in a weight ratio of 1-5:1-4. Preferably, the mixture is 5~1000: 5~1000: 5~1000: 5~1000 (ie, 0.05~10: 0.05~10: 0.05~10: 0.05~10), more preferably 5~10: 200: 5~200: 5~200: 100~400 (ie, 0.05~2: 0.05~2: 0.05~2: 1~4), and more preferably 100:100:100:400 (ie, 1: 1:1:4) mix isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer, vinyl dimethicone/ Polymethicone silsesquioxane crosspolymer, polyquaternium-55 and polyquaternium-11 as nonionic polymer.

本發明中,對於所述包含單獨的疏水性聚合物作為有效成分的化妝品組合物,依據化妝品安全相關的規定,考慮了疏水性聚合物的限用量。具體地,以組合物的總重量為基準,所包含的所述疏水性聚合物的量可以為0.005重量%以上,較佳地可以為0.05重量%以上。所述組合物中的疏水性聚合物的含量小於0.005重量%時,作為組合物的有效成分不能顯示出所期望的如下功效,即,增強毛髮的蓬鬆感(提高位於頭上部的頭頂毛髮的彈性感等)、改善組合物的毛髮殘留感(異物感)以及提高毛髮的收尾塗覆感,所述組合物中的疏水性聚合物的含量超過1重量%時,無法充分地溶解在組合物中,從而無法與組合物的其他成分穩定地配合,並且應用在皮膚上時,可能會出現過度的皮膚刺激等穩定性方面的問題。 In the present invention, for the cosmetic composition comprising a single hydrophobic polymer as an active ingredient, the limited amount of the hydrophobic polymer is considered in accordance with regulations related to cosmetic safety. Specifically, based on the total weight of the composition, the amount of the hydrophobic polymer included may be more than 0.005% by weight, preferably more than 0.05% by weight. When the content of the hydrophobic polymer in the composition is less than 0.005% by weight, the desired effect cannot be exhibited as an active ingredient of the composition, that is, enhancing the fluffy feeling of the hair (improving the elastic feeling of the hair on the top of the head) etc.), improving the hair residue feeling (foreign body feeling) of the composition and improving the finish coating feeling of the hair, when the content of the hydrophobic polymer in the composition exceeds 1% by weight, it cannot be fully dissolved in the composition, Therefore, it cannot be stably coordinated with other components of the composition, and when applied on the skin, problems in stability such as excessive skin irritation may occur.

本發明中,對於所述包含疏水性聚合物及非離子性聚合物的混合物的化妝品組合物,依據化妝品安全相關的規定,考慮了疏水性聚合物的限用量。具體地,在保持所述疏水性聚合物及非離子性聚合物的混合重量比的狀態下,以組合物的總重量為基準,所述混合物中包含的所述疏水性聚合物的量可以為0.005~1重量%。所述組合物中的疏水性聚合物的含量小於0.005重量%時,作為組合物的有效成分不能顯示出所期望的如下功效,即,增強毛髮的蓬鬆感(提高位於頭上部的頭頂毛髮的彈性感等)、改善組合物的毛髮殘留感(異物感)以及提高毛髮的收尾塗覆感,所述組合物中的疏水性聚合物的含量超過1重量%時,無法充分地溶解在化妝品組合物中,從而無法與組合物的其他成分穩定地配合,並且應用在皮膚上時,可能會出現過度的皮膚刺激等穩定性方面的問題。 In the present invention, for the cosmetic composition comprising a mixture of a hydrophobic polymer and a nonionic polymer, the limited amount of the hydrophobic polymer is considered in accordance with regulations related to cosmetic safety. Specifically, in a state where the mixing weight ratio of the hydrophobic polymer and the nonionic polymer is maintained, based on the total weight of the composition, the amount of the hydrophobic polymer contained in the mixture can be 0.005~1% by weight. When the content of the hydrophobic polymer in the composition is less than 0.005% by weight, the desired effect cannot be exhibited as an active ingredient of the composition, that is, enhancing the fluffy feeling of the hair (improving the elastic feeling of the hair on the top of the head) etc.), improving the hair residue feeling (foreign body feeling) of the composition, and improving the finishing coating feeling of the hair. When the content of the hydrophobic polymer in the composition exceeds 1% by weight, it cannot be sufficiently dissolved in the cosmetic composition , so that it cannot be stably coordinated with other components of the composition, and when applied on the skin, problems in stability such as excessive skin irritation may occur.

本發明中,對於所述包含疏水性聚合物及非離子性聚合物的混合物的化妝品組合物,依據化妝品安全相關的規定,考慮了非離子性聚合物的限用量。具體地,在保持所述疏水性聚合物及非離子性聚合物的混合重量比的狀態下,以組合物的總重量為基準,所述混合物中包含的所述非離子性聚合物的量可以為0.001~1重量%。所述組合物中的非離子性聚合物的含量小於0.001重量%時,作為組合物的有效成分不能顯示出所期望的如下功效,即,增強毛髮的蓬鬆感(提高位於頭上部的頭頂毛髮的彈性感等)、改善組合物的毛髮殘留感(異物感)以及提高毛髮的收尾塗覆感,所述組合物中的非離子性聚合物的含量超過1重量%時,無法充分地溶解在組合物中,從而無法與組合物的其他成分穩定地配合,並且應用在皮膚上時,可能會出現過度的皮膚刺激等穩定性方面的問題。 In the present invention, for the cosmetic composition comprising a mixture of a hydrophobic polymer and a nonionic polymer, the restricted amount of the nonionic polymer is considered in accordance with regulations related to cosmetic safety. Specifically, in a state where the mixing weight ratio of the hydrophobic polymer and the nonionic polymer is maintained, based on the total weight of the composition, the amount of the nonionic polymer contained in the mixture can be 0.001 to 1% by weight. When the content of the nonionic polymer in the composition is less than 0.001% by weight, the desired effect cannot be exhibited as an active ingredient of the composition, that is, enhancing the fluffy feeling of the hair (improving the elasticity of the hair on the top of the head). sexy, etc.), improving the hair residue feeling (foreign body feeling) of the composition, and improving the finish coating feeling of the hair. When the content of the nonionic polymer in the composition exceeds 1% by weight, it cannot be sufficiently dissolved in the composition Therefore, it cannot be stably coordinated with other components of the composition, and when applied to the skin, stability problems such as excessive skin irritation may occur.

本發明的特徵在於,所述組合物選擇性地吸附於毛髮的毛幹部位,從而藉由增加毛髮的彈性來增強毛髮的蓬鬆感,並且特徵在於,所述毛髮的毛幹部位是從毛根向皮膚外部凸出的毛幹部位中接近於毛根的4~6cm的毛髮部位。 The present invention is characterized in that the composition is selectively adsorbed on the hair shaft portion of the hair, thereby enhancing the fluffy feeling of the hair by increasing the elasticity of the hair, and is characterized in that the hair shaft portion of the hair is from the hair root to the The part of the hair that is 4 to 6 cm close to the root of the hair in the protruding hair shaft outside the skin.

本發明的特徵在於,所述組合物用於提高位於頭上部的頭頂毛髮的彈性感、改善毛髮的殘留感以及提高毛髮的收尾塗覆感,但並不受限於此。其中,毛髮的殘留感是指殘留在毛髮表面的殘留異物感(例如,化妝品組合物等引起的異物感)的程度,毛髮的殘留感越低,則毛髮的殘留感越得到改善,從而具有增加毛髮的清爽感的效果。 The present invention is characterized in that the composition is used to improve the elastic feeling of the crown hair on the upper part of the head, improve the residual feeling of the hair, and improve the finish coating feeling of the hair, but is not limited thereto. Among them, the residual feeling of hair refers to the degree of residual foreign body feeling (for example, foreign body feeling caused by cosmetic composition, etc.) remaining on the hair surface. The effect of refreshing feeling of hair.

本發明的特徵在於,所述組合物為清洗型的毛髮清洗用組合物。 The present invention is characterized in that the composition is a cleansing type hair cleansing composition.

本發明中對所述組合物的劑型化不進行特別的限定,可以是具有毛髮用軟膏、毛髮用營養化妝水、毛髮用按摩霜、護髮膜、生髮水、護髮乳霜(haircream)、潤髮乳、焗油膏、頭皮護理液、洗髮精及潤髮油等劑型的化妝品組合物。這些各種劑型的組合物可以根據上述的各種劑型或者與最終目的相適應地含有通常的化妝品組合物中所配合有的各種成分,所屬技術領域中具有通常知識者可以容易地選定這些成分的種類和量。例如,配合在所述組合物中的成分可以使用油脂成分、保濕劑、潤滑劑、表面活性劑、有機及無機顏料、有機粉體、紫外線吸收劑、防腐劑、殺菌劑、抗氧化劑、植物提取物、pH調節劑、酒精、色素、香料、血液循環促進劑、冷感劑、止汗劑、精製水等。 In the present invention, the dosage form of the composition is not particularly limited, and may include hair ointment, hair nourishing lotion, hair massage cream, hair mask, hair tonic, hair cream (haircream), Cosmetic compositions in dosage forms such as conditioner, conditioner, scalp care solution, shampoo and conditioner. Compositions in these various dosage forms can contain various ingredients that are combined with common cosmetic compositions according to the above-mentioned various dosage forms or adapt to the final purpose, and those skilled in the art can easily select the types and types of these ingredients. quantity. For example, the components to be mixed in the composition can use oil and fat components, moisturizers, lubricants, surfactants, organic and inorganic pigments, organic powders, ultraviolet absorbers, preservatives, fungicides, antioxidants, plant extracts Substances, pH regulators, alcohol, pigments, fragrances, blood circulation promoters, cooling agents, antiperspirants, purified water, etc.

本發明中,為了賦予皮膚或頭皮有用的功能性,可以以適當的含量包含甘油等保濕成分;抗氧化劑等抗氧化/抗老化成分;酪胺酸酶抑制劑、角質再生促進劑等美白成分;紫外線阻斷劑等保護成分;透明質酸、膠原蛋白、彈性蛋白等治癒傷口的成分;消炎劑等抗炎成分等;從而能夠對皮膚或毛髮賦予保濕、抗老化、美白、保護、治癒傷口等功能,但並不限定於此。 In the present invention, in order to impart useful functionality to the skin or scalp, moisturizing ingredients such as glycerin; anti-oxidation/anti-aging ingredients such as antioxidants; whitening ingredients such as tyrosinase inhibitors and keratin regeneration accelerators can be included in an appropriate content; Protective ingredients such as UV blockers; ingredients that heal wounds such as hyaluronic acid, collagen, and elastin; anti-inflammatory ingredients such as anti-inflammatory agents, etc.; thereby moisturizing, anti-aging, whitening, protecting, and healing wounds, etc. function, but is not limited to this.

在另一個方面,本發明涉及毛髮的毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆感的評價方法[以下簡稱為“毛髮蓬鬆感的評價方法1”],其包括以下(1)至(5)的步驟。 In another aspect, the present invention relates to a method for evaluating the bulkiness of the hair portion of 4 to 6 cm close to the hair root in the hair shaft portion of the hair [hereinafter referred to simply as "Evaluation Method 1 for Fluffy Hair Feeling"], which includes the following (1 ) to (5) steps.

(1)將髮辮的毛髮的毛幹部位中接近於毛根的0.5~1.5cm,較佳地為0.8~1.2cm,更佳地為1cm的毛髮部位黏附在與地面(水平面)垂直的平板上進行固定;(2)傾斜所述步驟(1)的髮辮,使其與所述水平面形成規定角度,較佳地形成40~50°的角度,更佳地形成44~46°的角度,最佳地形成45°的角度;(3)在所述髮辮與所述水平面形成規定角度的時刻,較佳地形成40~50°的角度,更佳地形成44~46°的角度,最佳地形成45°的角度的時刻,從距離髮辮的毛根末端部分0.5~1.5cm,較佳地為0.8~1.2cm,更佳地為1cm的內側毛髮部位開始,將該內側毛髮部位作為基準點(1),測量至位於與所述水平面平行的方向的延長線上的髮辮內側毛髮部分(基準點(2))的長度(RS1);(4)對所述髮辮測量從基準點(2)開始至位於該基準點(2)的垂直方向的延長線上的髮辮的外側毛髮部分(基準點(3))的長度(RS2);以及(5)藉由下述數學式1對髮辮計算RS3,從而評價毛髮的蓬鬆度:[數學式1]RS3=RS2/RS1 (1) Attach 0.5-1.5cm, preferably 0.8-1.2cm, and more preferably 1cm of the hair shaft of the braided hair close to the hair root on a flat plate perpendicular to the ground (horizontal plane) Fix; (2) tilt the braid of the step (1) to form a prescribed angle with the horizontal plane, preferably form an angle of 40-50°, more preferably form an angle of 44-46°, and most preferably Preferably form an angle of 45°; (3) when the braid forms a prescribed angle with the horizontal plane, preferably form an angle of 40-50°, more preferably form an angle of 44-46°, the best When forming an angle of 45°, start from the inner hair part 0.5 ~ 1.5 cm, preferably 0.8 ~ 1.2 cm, more preferably 1 cm from the end of the hair root of the braid, and use this inner hair part as a reference point (1), measuring to the length (RS1) of the inner hair part of the tresses (reference point (2)) on the extension line of the direction parallel to the horizontal plane; (4) measuring the tresses from the reference point (2) ) to the length (RS2) of the outer hair part of the braid (the reference point (3)) on the extension line in the vertical direction of the reference point (2); and (5) a pair of braids by the following mathematical formula Calculate RS3 to evaluate the fluffiness of hair: [mathematical formula 1] RS3=RS2/RS1

所述RS3為1以上時,評價為毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆度高,RS3小於1時,評價為毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆度低。 When the above-mentioned RS3 is 1 or more, it is evaluated that the hair portion of 4 to 6 cm close to the root of the hair shaft has high volume, and when RS3 is less than 1, it is evaluated that the hair portion of 4 to 6 cm close to the root of the hair shaft is high. The bulkiness is low.

本發明的特徵在於,所述毛幹部位是從毛根向皮膚外部凸出的毛幹部位中接近於毛根的4~6cm的毛髮部位,較佳地為5cm的毛髮部位。 The feature of the present invention is that the hair shaft part is the hair part of 4-6 cm close to the hair root among the hair shaft parts protruding from the hair root to the outside of the skin, preferably the hair part of 5 cm.

本發明的特徵在於,所述髮辮的髮絲數量為80~120,較佳地為90~110。 The feature of the present invention is that the number of hair strands in the braid is 80-120, preferably 90-110.

本發明的特徵在於,所述髮辮是將除了從毛根向皮膚外部凸出的毛幹部位中接近於毛根的4~6cm的毛髮部位、較佳地為5cm的毛髮部位之外的毛髮部位進行脫色處理的。 The feature of the present invention is that the braiding is carried out on all the hair parts except the hair part of 4~6 cm close to the hair root, preferably the hair part of 5 cm in the hair shaft protruding from the hair root to the outside of the skin. decolorized.

本發明的特徵在於,所述水平面和平板用網格(grid)進行標記。 The present invention is characterized in that the horizontal plane and the plate are marked with a grid.

另一個方面,本發明涉及毛髮整體的蓬鬆感的評價方法[以下簡稱為“毛髮蓬鬆感的評價方法2”],其包括以下(1)至(9)的步驟。 On the other hand, the present invention relates to a method for evaluating the bulkiness of the entire hair [hereinafter simply referred to as "method 2 for evaluating volume of hair"] comprising the following steps (1) to (9).

(1)將髮辮放到水平面上,使毛根部位朝上;(2)將從所述髮辮的毛根末端部分至毛莖(毛幹部位)的起始部分的0.5~1.5cm,較佳地為0.8~1.2cm,更佳地為1cm的長度定義為R0;(3)將距離所述R0為1.8~2.2cm,較佳地為1.9~2.1cm,更佳地為2cm的部分定義為R1;(4)將距離所述R0為2.5~3.5cm,較佳地為2.8~3.2cm,更佳地為3cm的部分定義為R3;(5)將距離所述R0為5.5~6.5cm,較佳地為5.8~6.2cm,更佳地為6cm的部分定義為M6;(6)將距離所述R0為8.5~9.5cm,較佳地為8.8~9.2cm,更佳地為9cm的部分定義為M9;(7)將從所述R3部分的髮辮的直徑中減去所述R1部分的髮辮的直徑的數值定義為dR;(8)將從所述M9部分的髮辮的直徑中減去所述M6部分的髮辮的直徑的數值定義為dM;以及(9)所述dR超過10時,評價毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆感變化量為大,所述dM超過10時,評價除了毛幹部位中接近於毛根的4~6cm的毛髮部位之外的其他毛髮部位的蓬鬆感變化量為小。 (1) Put the braid on a horizontal surface, so that the hair root is facing upward; (2) Place the 0.5~1.5cm from the end of the hair root of the braid to the beginning of the hair stem (hair shaft), preferably The ground is 0.8 ~ 1.2cm, more preferably the length of 1cm is defined as R0; (3) the distance from the R0 is 1.8 ~ 2.2cm, preferably 1.9 ~ 2.1cm, more preferably the part of 2cm is defined as R1; (4) defining the part that is 2.5 to 3.5 cm from R0, preferably 2.8 to 3.2 cm, and more preferably 3 cm, as R3; (5) 5.5 to 6.5 cm from R0, Preferably 5.8~6.2cm, more preferably 6cm part is defined as M6; (6) the distance from the R0 is 8.5~9.5cm, preferably 8.8~9.2cm, more preferably 9cm part It is defined as M9; (7) the value of subtracting the diameter of the braid of the R1 part from the diameter of the braid of the R3 part is defined as dR; (8) the diameter of the braid of the M9 part is defined as dR; The numerical value of the diameter of the braid minus the M6 part is defined as dM; and (9) when the dR exceeds 10, the amount of change in the fluffy feeling of the hair part of 4-6 cm close to the hair root in the hair shaft is evaluated as Large, when the dM exceeds 10, it is evaluated that the amount of change in the volume of other hair parts is small except for the hair part of 4 to 6 cm close to the hair root in the hair shaft part.

本發明中的特徵在於,所述步驟(9)中,所述dR為6~10時,評價毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆感變化量為保持在適當水平,所述dR為2~5時,評價所述毛髮部位的蓬鬆感變化量為略有變化,所述dR為0~1時,評價所述毛髮部位的蓬鬆感變化量幾乎沒有變化。 The present invention is characterized in that, in the step (9), when the dR is 6 to 10, it is evaluated that the amount of change in the fluffy feeling of the hair part of 4 to 6 cm close to the hair root in the hair shaft is maintained at an appropriate level, When the dR is 2 to 5, it is estimated that the amount of change in the volume of the hair part is slightly changed, and when the dR is 0 to 1, it is evaluated that the amount of change in the volume of the hair site is almost unchanged.

本發明的特徵在於,所述毛幹部位是從毛根向皮膚外部凸出的毛幹部位中接近於毛根的4~6cm的毛髮部位,較佳地為5cm的毛髮部位。 The feature of the present invention is that the hair shaft part is the hair part of 4-6 cm close to the hair root among the hair shaft parts protruding from the hair root to the outside of the skin, preferably the hair part of 5 cm.

本發明的特徵在於,所述髮辮的髮絲數量為80~120,較佳地為90~110。 The feature of the present invention is that the number of hair strands in the braid is 80-120, preferably 90-110.

本發明的特徵在於,所述水平面和平板用網格(grid)進行標記。 The present invention is characterized in that the horizontal plane and the plate are marked with a grid.

另一個方面,本發明涉及增強毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆感的物質的篩選方法,其包括以下(1)至(6)的步驟。 In another aspect, the present invention relates to a screening method for a substance that enhances the fluffy feeling of the 4-6 cm hair part close to the hair root in the hair shaft part, which includes the following steps (1) to (6).

(1)分別將髮辮的毛髮的毛幹部位中距離毛根0.5~1.5cm,較佳地為0.8~1.2cm,更佳地為1cm處的毛髮部位黏附在與地面(水平面)垂直的平板上進行固定,其中所述髮辮分別是以推定為增強毛髮的蓬鬆感的試驗物質處理的髮辮(髮辮1)和以不會對毛髮的蓬鬆感施加變化的物質處理的髮辮(髮辮2);(2)傾斜所述步驟(1)的髮辮1和髮辮2,使其分別與所述水平面形成規定角度,較佳地形成40~50°的角度,更佳地形成44~46°的角度,最佳地形成45°的角度;(3)在所述髮辮與所述水平面形成規定角度的時刻,較佳地形成40~50°的角度,更佳地形成44~46°的角度,最佳地形成45°的角度的時刻,從距離髮辮的毛根末端部分0.5~1.5cm,較佳地為0.8~1.2cm,更佳地為1cm的內側毛髮部位開始,將該內側毛髮部位作為基準點(1),測量至位於與所述水平面平行的方向的延長線上的髮辮的內側毛髮部分(基準點(2))的長度(RS1); (4)對所述髮辮1和髮辮2分別測量從基準點(2)開始至位於該基準點(2)的垂直方向的延長線上的髮辮的外側毛髮部分(基準點(3))的長度(RS2);(5)藉由下述數學式1分別對髮辮1和髮辮2計算RS3,從而評價髮辮的蓬鬆度:[數學式1]RS3=RS2/RS1 (1) The hair shaft of the braided hair is 0.5~1.5cm away from the hair root, preferably 0.8~1.2cm, and more preferably 1cm away from the hair part on a flat plate perpendicular to the ground (horizontal plane) Fixation was carried out in which the braids were treated with a test substance presumed to enhance the volume of hair (braid 1) and with a substance that did not change the volume of hair (braid 1). 2); (2) Tilting the braid 1 and braid 2 of the step (1) to form a prescribed angle with the horizontal plane respectively, preferably an angle of 40° to 50°, more preferably an angle of 44° to the horizontal plane. An angle of 46°, preferably forming an angle of 45°; (3) when the braid forms a prescribed angle with the horizontal plane, preferably forming an angle of 40-50°, more preferably forming an angle of 44-46° The angle of °, the best moment to form an angle of 45 °, starts from the inner hair part of 0.5 ~ 1.5 cm, preferably 0.8 ~ 1.2 cm, and more preferably 1 cm from the end of the hair root of the braid. The inner hair part is used as a reference point (1), and the length (RS1) is measured to the inner hair part of the tress (reference point (2)) on the extension line of the direction parallel to the horizontal plane; (4) Measure the outer hair part (reference point (3)) of the tresses on the extension line of the trestle from the reference point (2) to the extension line of the vertical direction of the reference point (2) respectively for the described tresses 1 and tresses 2 (5) Calculate RS3 for braid 1 and braid 2 by the following mathematical formula 1, so as to evaluate the bulkiness of the braid: [Mathematical formula 1] RS3=RS2/RS1

所述RS3為1以上時,評價為毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆度高,RS3小於1時,評價為毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆度低;以及(6)比較分別在所述步驟(5)中得到的髮辮1和髮辮2的RS3,然後髮辮1的毛髮蓬鬆度高於髮辮2的毛髮蓬鬆度時,將所述試驗物質決定為增強毛髮的蓬鬆感的物質。 When the above-mentioned RS3 is 1 or more, it is evaluated that the hair portion of 4 to 6 cm close to the root of the hair shaft has high volume, and when RS3 is less than 1, it is evaluated that the hair portion of 4 to 6 cm close to the root of the hair shaft is high. and (6) compare the RS3 of braid 1 and braid 2 obtained in said step (5), and then when the bulkiness of braid 1 is higher than that of braid 2, The test substance was determined to enhance the volume of hair.

本發明的特徵在於,所述毛幹部位是從毛根向皮膚外部凸出的毛幹部位中接近於毛根的4~6cm的毛髮部位,較佳地為5cm的毛髮部位。 The feature of the present invention is that the hair shaft part is the hair part of 4-6 cm close to the hair root among the hair shaft parts protruding from the hair root to the outside of the skin, preferably the hair part of 5 cm.

本發明的特徵在於,所述髮辮的髮絲數量為80~120,較佳地為90~110。 The feature of the present invention is that the number of hair strands in the braid is 80-120, preferably 90-110.

本發明的特徵在於,所述髮辮是用快乾膠將約25cm的黑毛中的從毛根末端起約1cm的毛髮部位進行黏合來製造的。 The feature of the present invention is that the braid is made by bonding the hair part of about 1 cm from the end of the hair root in about 25 cm of black hair with quick-drying glue.

本發明的特徵在於,所述髮辮是將除了從毛根向皮膚外部凸出的毛幹部位中接近於毛根的4~6cm的毛髮部位、較佳地為5cm的毛髮部位之外的毛髮部位進行脫色處理的。 The feature of the present invention is that the braiding is carried out on all the hair parts except the hair part of 4~6 cm close to the hair root, preferably the hair part of 5 cm in the hair shaft protruding from the hair root to the outside of the skin. decolorized.

本發明的特徵在於,所述水平面和平板用網格(grid)進行標記。 The present invention is characterized in that the horizontal plane and the plate are marked with a grid.

另一個方面,本發明涉及增強毛髮整體的蓬鬆感的物質的篩選方法,其包括以下(1)至(10)的步驟。 In another aspect, the present invention relates to a screening method for a substance that enhances the bulkiness of the hair as a whole, comprising the following steps (1) to (10).

(1)將髮辮放到水平面上,使毛根部位朝上,其中所述髮辮分別是以推定為增強毛髮的蓬鬆感的試驗物質處理的髮辮(髮辮1)和以不會對毛髮的蓬鬆感施加變化的對照物質(例如,蒸餾水)處理的髮辮(髮辮2);(2)分別將從所述髮辮1和髮辮2的毛根末端部分至毛莖(毛幹部位)的起始部分的0.5~1.5cm,較佳地為0.8~1.2cm,更佳地為1cm的長度定義為R0;(3)分別將距離所述髮辮1和髮辮2的R0為1.8~2.2cm,較佳地為1.9~2.1cm,更佳地為2cm的部分定義為R1;(4)分別將距離所述髮辮1和髮辮2的R0為2.5~3.5cm,較佳地為2.8~3.2cm,更佳地為3cm的部分定義為R3;(5)分別將距離所述髮辮1和髮辮2的R0為5.5~6.5cm,較佳地為5.8~6.2cm,更佳地為6cm的部分定義為M6;(6)分別將距離所述髮辮1和髮辮2的R0為8.5~9.5cm,較佳地為8.8~9.2cm,更佳地為9cm的部分定義為M9;(7)分別將從所述髮辮1和髮辮2的所述R3部分的髮辮的直徑中減去所述R1部分的髮辮的直徑的數值定義為dR;(8)分別將從所述髮辮1和髮辮2的所述M9部分的髮辮的直徑中減去所述M6部分的髮辮的直徑的數值定義為dM;(9)所述髮辮1和髮辮2的所述dR分別超過10時,評價毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆感變化量為大,所述dM分別超過10時,評價除了毛幹部位中接近於毛根的4~6cm的毛髮部位之外的其他毛髮部位的蓬鬆感變化量為小;以及(10)分別對所述步驟(7)至步驟(9)中得到的髮辮1和髮辮2的dR及dM進行比較後,髮辮1的毛髮蓬鬆度高於髮辮2的毛髮蓬鬆度時,將所述試驗物質決定為增強毛髮的蓬鬆感的物質。 (1) Put the braids on a horizontal surface with the hair roots facing up, wherein the braids are the braids treated with the test substance presumed to enhance the fluffy feeling of the hair (braid 1) and the braids that do not affect the hair. Fluffy feeling to the tresses (braids 2) treated with a variable control substance (for example, distilled water); 0.5 ~ 1.5cm of the initial part, preferably 0.8 ~ 1.2cm, more preferably the length of 1cm is defined as R0; (3) R0 is 1.8 ~ 1.8 ~ 2.2cm, preferably 1.9~2.1cm, more preferably the part of 2cm is defined as R1; (4) R0 is 2.5~3.5cm from the braid 1 and braid 2 respectively, preferably 2.8~3.2cm, more preferably 3cm is defined as R3; (5) R0 is 5.5~6.5cm, preferably 5.8~6.2cm, more preferably The part where the ground is 6cm is defined as M6; (6) the R0 at a distance from the braid 1 and the braid 2 is 8.5 to 9.5cm, preferably 8.8 to 9.2cm, and more preferably 9cm, as M9; (7) the value of subtracting the diameter of the braid of the R1 part from the diameter of the braid of the R3 part of the braid 1 and the braid 2 is defined as dR; (8) respectively The numerical value of subtracting the diameter of the braid of the M6 part from the diameter of the braid of the M9 part of the braid 1 and the braid 2 is defined as dM; (9) the braid 1 and the braid 2 When the dR of each exceeds 10, it is evaluated that the amount of change in the fluffy feeling of the 4-6 cm hair part close to the hair root in the hair shaft part is large. The amount of fluffy change in hair parts other than the hair parts of 4 to 6 cm is small; and (10) dR and After the dM comparison, if the bulkiness of the hair of the braid 1 is higher than that of the braid 2, the test substance was determined to be a substance that enhances the bulkiness of the hair.

本發明中的特徵在於,所述步驟(9)中,所述dR為6~10時,評價毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆感變化量為保持在適當水平,所述dR為2~5時,評價所述毛髮部位的蓬鬆感變化量為略有變化,所述dR為0~1時,評價所述毛髮部位的蓬鬆感變化量幾乎沒有變化。 The present invention is characterized in that, in the step (9), when the dR is 6 to 10, it is evaluated that the amount of change in the fluffy feeling of the hair part of 4 to 6 cm close to the hair root in the hair shaft is maintained at an appropriate level, When the dR is 2 to 5, it is estimated that the amount of change in the volume of the hair part is slightly changed, and when the dR is 0 to 1, it is evaluated that the amount of change in the volume of the hair site is almost unchanged.

本發明的特徵在於,所述毛幹部位是從毛根向皮膚外部凸出的毛幹部位中接近於毛根的4~6cm的毛髮部位,較佳地為5cm的毛髮部位。 The feature of the present invention is that the hair shaft part is the hair part of 4-6 cm close to the hair root among the hair shaft parts protruding from the hair root to the outside of the skin, preferably the hair part of 5 cm.

本發明的特徵在於,所述髮辮的髮絲數量為80~120,較佳地為90~110。 The feature of the present invention is that the number of hair strands in the braid is 80-120, preferably 90-110.

本發明的特徵在於,所述髮辮是用快乾膠將約25cm的黑毛中的從毛根末端起約1cm的毛髮部位進行黏合來製造的。 The feature of the present invention is that the braid is made by bonding the hair part of about 1 cm from the end of the hair root in about 25 cm of black hair with quick-drying glue.

本發明的特徵在於,所述水平面和平板用網格(grid)進行標記。 The present invention is characterized in that the horizontal plane and the plate are marked with a grid.

具體實施方式 detailed description

下面,藉由實施例對本發明進行更加詳細的說明。這些實施例只是用於例示本發明,不可解釋為本發明的範圍受限於這些實施例,這對於所屬技術領域中具有通常知識者而言是顯而易見的。 Below, the present invention will be described in more detail by means of examples. These examples are only for illustrating the present invention, and should not be construed as limiting the scope of the present invention to these examples, which is obvious to those skilled in the art.

實施例1:藉由少量的試驗物質來改善毛髮的蓬鬆感的功效評價中所適合的髮辮的髮絲數量的確認 Example 1: Confirmation of the number of strands of tresses suitable for the efficacy evaluation of improving the volume of hair with a small amount of test substance

毛髮用劑型的評估中使用的常規髮辮(Tress)的髮絲數量多,從而評價劑型時所使用的原料的浪費嚴重,並且難以進行髮辮間毛髮蓬鬆感的評價,從而製造了藉由少量的試驗物質(原料)來改善毛髮蓬鬆感的功效評價中所適合的髮辮。 The amount of conventional tress (tress) used in the evaluation of hair dosage forms is large, so the waste of raw materials used in the evaluation of dosage forms is serious, and it is difficult to evaluate the fluffy feeling of hair between tresses. The hair braids that are suitable for the evaluation of the efficacy of improving the volume of hair with the test substance (raw material).

首先,以賦予蓬鬆感的BMAS-AP(異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物(Isododecane/Butyl Acrylate/Hydroxypropyl Dimethicone Acrylate Copolymer))對不同髮絲數量的髮辮進行處理,然後測量髮 辮傾斜至45°角度的起始點(point)為止的距離來確認毛髮蓬鬆感是否得到增強,從而確認藉由少量的試驗物質來增強毛髮蓬鬆感的水平的評價中所適合的髮辮的髮絲數量。具體試驗方法為如下。 First, BMAS-AP (Isododecane/Butyl Acrylate/Hydroxypropyl Dimethicone Acrylate Copolymer) that imparts a fluffy feel to different hair strands number of braids to process, then measure hair The distance from the start point (point) at which the braids are inclined to an angle of 45° is confirmed to confirm whether the hair volume is enhanced, thereby confirming the hair volume of the hair braids suitable for the evaluation of the level of enhancing the hair volume by a small amount of the test substance. number of wires. The specific test method is as follows.

(1)用快乾膠將長度約25cm的黑毛中的從毛根末端起約1cm的毛髮部位進行黏合,從而製造分別由5個、10個、20個、40個、80個及100個髮絲數量構成的長髮辮([選項1]:將除了從毛根向皮膚外部凸出的毛幹(毛莖)部位中的4~6cm(5cm的毛幹部位)之外的毛髮部位進行脫色處理(用脫色劑(第一劑:第二劑=3:1)進行處理30分鐘)。藉由脫色處理減少髮辮原有的蓬鬆感,能夠更加明確地確認經過試驗物質處理後的毛髮、尤其是毛髮的毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆感是否增減;[選項2]:對屬從毛根向皮膚外部凸出的毛幹部位的末端部分的髮辮的末端部(tip region)進行染色處理。藉由染色處理,髮辮的末端部分的親水性(Hydrophilicity)變高,相對而言,接近於毛根的毛髮部位的疏水性(Hydrophobicity)變高,從而能夠精確地評價接近於毛根的毛髮部位的疏水性/親水性特性對毛髮的蓬鬆感所引起的影響)。 (1) Use quick-drying glue to glue the hair part about 1 cm from the end of the hair root in the black hair with a length of about 25 cm, so as to make 5, 10, 20, 40, 80 and 100 hair parts respectively. Long braids made up of strands ([Option 1]: Decolorize the hair except for the 4~6cm of the hair shaft (hair shaft) that protrudes from the hair root to the outside of the skin (hair shaft part of 5cm) (Treat with a decolorizing agent (the first dose: the second dose = 3: 1) for 30 minutes). The original fluffy feeling of the braids can be reduced by the decolorization treatment, and the hair treated with the test substance can be more clearly confirmed, especially In the hair shaft part of the hair, whether the fluffy feeling of the 4~6cm hair part close to the hair root increases or decreases; [Option 2]: For the end of the braid, which is the end part of the hair shaft protruding from the hair root to the outside of the skin The tip region is dyed. By dyeing, the hydrophilicity (Hydrophilicity) of the end part of the braid becomes higher, and relatively speaking, the hydrophobicity (Hydrophobicity) of the hair part close to the hair root becomes higher, so that it is possible to accurately The effect of the hydrophobic/hydrophilic properties of the hair region close to the hair root on the volume of the hair was evaluated).

(2)以適當含量(例如2g)的試驗物質(對照組:蒸餾水)對長髮辮的距離毛根末端約5cm的毛幹部位進行處理後,揉搓約20次進行塗布(參考圖2)。 (2) After treating the hair shaft of long braids about 5 cm from the end of the hair root with an appropriate amount (for example, 2 g) of the test substance (control group: distilled water), rub it about 20 times and apply it (refer to FIG. 2 ).

(3)將塗布有試驗物質的長髮辮的毛幹部位用流水清洗並使其完全乾燥後(使用吹風機),在常溫(18~25℃)下放置約30分鐘。 (3) After washing the hair shaft part of the dreadlock coated with the test substance with running water and completely drying it (using a hair dryer), leave it at room temperature (18-25° C.) for about 30 minutes.

(4)完成所述步驟(3),然後使髮辮與水平面形成平行,並將其固定,使得將從毛髮末端起4~6cm的毛幹部位(從皮膚或頭皮的毛根向皮膚外部凸出的毛幹部位中接近於毛根的4~6cm的毛髮部位)處(存在黏合劑的部位的外側)作為起始點O。 (4) Complete the step (3), then make the braid parallel to the horizontal plane, and fix it so that the hair shaft part (protruding from the hair root of the skin or scalp to the outside of the skin) will be 4 to 6 cm from the end of the hair. In the hair shaft part of the 4~6cm hair part close to the hair root) (the outer side of the part where the adhesive is present) was used as the starting point O.

(5)使其自然地向水平面方向傾斜,記錄與水平面形成45°的角度的點(A),並測量作為毛幹部位處的起始點O至與水平面形成45°的角度的點(A)的長度(O-A),從而確認適合於毛髮的蓬鬆感的評價中的髮辮的髮絲數量。 (5) Let it incline naturally to the horizontal plane, record the point (A) forming an angle of 45° with the horizontal plane, and measure the point (A) as the starting point O at the hair shaft position to form a 45° angle with the horizontal plane ) length (O-A), thereby confirming the number of strands of tresses suitable for the evaluation of the fluffy feel of the hair.

Figure 107134722-A0305-02-0019-1
Figure 107134722-A0305-02-0019-1

其結果,如表1及第3圖中所示,與經蒸餾水處理的髮辮相比,經BMAS-AP處理的髮辮的O-A長度整體上顯示為更長,從而顯示為藉由肉眼也能夠明確地確認毛髮蓬鬆感的變化,尤其髮絲數量為100個至小於150個時,最有利於確認毛髮蓬鬆感的變化。 As a result, as shown in Table 1 and Figure 3, compared with the braids treated with distilled water, the O-A length of the braids treated with BMAS-AP was shown to be longer as a whole, thus showing that it can also be seen by the naked eye. It is most beneficial to confirm the change in the fluffy feeling of hair clearly, especially when the number of hair strands is 100 to less than 150.

將髮辮的髮絲數量設為100個,對下述表2的試驗物質中的7種原料進行毛髮蓬鬆感的增減水平的評價。 The number of strands of braided hair was set to 100, and the level of increase or decrease in the fluffy feeling of hair was evaluated for 7 kinds of raw materials among the test substances in Table 2 below.

Figure 107134722-A0305-02-0019-2
Figure 107134722-A0305-02-0019-2
Figure 107134722-A0305-02-0020-3
Figure 107134722-A0305-02-0020-3

其結果,如下述表3中所示,確認異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物(BMAS-AP)的提高毛髮蓬鬆感的效果最優異,乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物(KSP-101)、丙烯酸酯類/C10-30烷醇丙烯酸酯交聯聚合物(SC-200)、聚丙基矽倍半氧烷/異十二烷(DC680)等的提高毛髮蓬鬆感的效果也優異。 As a result, as shown in the following Table 3, it was confirmed that isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer (BMAS-AP) has the most excellent effect of improving the fluffy feeling of hair, Vinyl Dimethicone/Methicone Silsesquioxane Crosspolymer (KSP-101), Acrylates/C10-30 Alkyl Acrylate Crosspolymer (SC-200 ), polypropylsilsesquioxane/isododecane (DC680), etc. are also excellent in the effect of improving the volume of hair.

Figure 107134722-A0305-02-0020-4
Figure 107134722-A0305-02-0020-4
Figure 107134722-A0305-02-0021-5
Figure 107134722-A0305-02-0021-5

[參考例1]:利用髮辮的毛髮蓬鬆感的評價方法及增加毛髮蓬鬆感的物質的篩選方法的確立 [Reference Example 1]: Establishment of an evaluation method for hair volume using braids and a screening method for substances that increase hair volume

人的頭部形狀是平緩的橢圓形,因此除了頭頂部分之外,毛孔中生長出的毛髮所形成的傾斜度有多種。例如,當人以立正的姿勢站立時,頭頂的皮膚面與毛髮(毛根部位)形成的傾斜度(角度)為90°,但頭側面皮膚或頭後面皮膚與毛髮(毛根部位)形成的傾斜度接近於0°。因此,為了使用髮辮評價毛髮的蓬鬆感,有必要考慮頭皮面和毛髮所形成的傾斜度。毛髮的傾斜度有必要考慮毛髮的位置、傾斜(彎折)起始的點、毛根至所述彎折起始的點的長度的影響。此外,毛髮的蓬鬆感必然會受到毛髮整體的體積和重量的影響,因此還有必要考慮這些因素。 The shape of the human head is a gentle oval, so except for the top part of the head, there are various inclinations formed by the hair growing from the pores. For example, when a person stands at attention, the inclination (angle) between the skin on the top of the head and the hair (hair root) is 90°, but the inclination between the skin on the side of the head or the skin on the back of the head and the hair (hair root) is 90°. close to 0°. Therefore, in order to evaluate the volume of hair using braids, it is necessary to consider the inclination formed by the scalp surface and the hair. The inclination of the hair needs to consider the influence of the position of the hair, the point where the inclination (bend) starts, and the length from the hair root to the point where the bend starts. In addition, the volume and weight of the hair will inevitably be affected by the overall volume and weight of the hair, so it is necessary to take these factors into account.

[毛髮蓬鬆感的評價方法1]:接近於頭皮的毛幹部位的毛髮蓬鬆感的評價方法 [Evaluation Method 1 for Fluffy Hair Feeling]: Evaluation Method for Fluffy Hair Feeling in the Hair Shaft Area Close to the Scalp

首先,確立了接近於頭皮的毛幹部位的毛髮蓬鬆感的評價方法。 First, an evaluation method for the fluffy feeling of the hair in the hair shaft region close to the scalp was established.

(1)基於試驗例1的結果,將髮辮的髮絲數量設為100個。 (1) Based on the results of Test Example 1, the number of strands of braids was set to 100.

(2)對用於固定髮辮的適當的點進行確認的結果,較佳地將髮辮的毛幹部位中的距離毛根約1cm的位置的毛髮部位黏附在平板上進行固定,以使其與地面(水平面)形成直角。 (2) As a result of confirming the appropriate point for fixing the braid, it is preferable to adhere and fix the hair part at a position about 1 cm from the hair root in the hair shaft part of the braid on a flat plate so that it can be fixed with the braid. The ground (horizontal plane) forms a right angle.

(3)確認能夠最小化由毛髮自身的體積和重量所引起的鋪展效果的傾斜角度的結果,較佳地使髮辮與所述水平面形成約45°的角度。 (3) As a result of confirming the angle of inclination capable of minimizing the spreading effect caused by the volume and weight of the hair itself, it is preferable to make the tresses form an angle of about 45° with the horizontal plane.

(4)所述髮辮與所述水平面形成約45°的角度時,從距離髮辮的毛根末端部分約1cm的內側毛髮部位開始,將該內側毛髮部位作為基準點(1),測量 至位於與所述水平面平行的方向的延長線上的髮辮的內側毛髮部分(基準點(2))的長度(RS1), (4) When the braid forms an angle of about 45° with the horizontal plane, start from the inner hair part about 1 cm away from the end of the hair root of the braid, and use the inner hair part as a reference point (1), measure to the length (RS1) of the inner hair part of the tress (reference point (2)) lying on the extension of the direction parallel to said horizontal plane,

(5)對所述髮辮測量從基準點(2)開始至位於該基準點(2)的垂直方向的延長線上的髮辮的外側毛髮部分(基準點(3))的長度(RS2), (5) measuring the length (RS2) of the outer hair portion of the tress (reference point (3)) from the reference point (2) to the extension of the tress in the vertical direction of the reference point (2),

(6)計算毛髮的蓬鬆度RS3(=RS2/RS1),從而能夠顯著地確認毛幹部位中接近於毛根的4~6cm的毛髮部位的蓬鬆感的變化(參考第4圖)。 (6) Calculate the bulkiness RS3 (=RS2/RS1) of the hair, so that the change in bulkiness of the hair portion of 4 to 6 cm close to the hair root can be remarkably confirmed in the hair shaft (see FIG. 4 ).

[毛髮蓬鬆感的評價方法2]:毛髮整體的蓬鬆感的評價方法 [Evaluation Method 2 for Fluffy Feeling of Hair]: Evaluation Method for Fluffy Feeling of Overall Hair

確立了評價毛髮整體的蓬鬆感的方法。 A method for evaluating the bulkiness of the overall hair has been established.

(1)與毛髮蓬鬆感的評價方法1相同,將髮辮的髮絲數量設為100個。 (1) The number of strands of braids was set to 100 in the same manner as in the evaluation method 1 of the fluffy feeling of hair.

(2)將髮辮放在水平面上,使毛根部位朝上。 (2) Place the braid on a horizontal surface with the root of the hair facing up.

(3)定義特定的毛髮位置(點)。 (3) Define a specific hair position (point).

R0:從髮辮的毛根末端部分至毛莖(毛幹部位)的起始點的0.5~1.5cm,較佳地為0.8~1.2cm,更佳地為1cm的長度;R1:距離所述R0為1.8~2.2cm,較佳地為1.9~2.1cm,更佳地為2cm的點;R3:距離所述R0為2.5~3.5cm,較佳地為2.8~3.2cm,更佳地為3cm的點;M6:距離所述R0為5.5~6.5cm,較佳地為5.8~6.2cm,更佳地為6cm的點;以及M9:距離所述R0為8.5~9.5cm,較佳地為8.8~9.2cm,更佳地為9cm的點。 R0: 0.5-1.5 cm from the end of the hair root of the braid to the starting point of the hair stem (hair shaft), preferably 0.8-1.2 cm, more preferably 1 cm; R1: the distance from the R0 1.8~2.2cm, preferably 1.9~2.1cm, more preferably 2cm; R3: the distance from R0 is 2.5~3.5cm, preferably 2.8~3.2cm, more preferably 3cm point; M6: the distance from the R0 is 5.5~6.5cm, preferably 5.8~6.2cm, more preferably 6cm; and M9: the distance from the R0 is 8.5~9.5cm, preferably 8.8~ 9.2 cm, more preferably 9 cm points.

(4)為了顯示出試驗物質所引起的毛髮蓬鬆感的整體變化,計算了下述指數值。 (4) In order to show the overall change in the fluffy feeling of hair caused by the test substances, the following index values were calculated.

dR:從所述R3點的髮辮的直徑中減去所述R1點的髮辮的直徑的值;以及dM:從所述M9點的髮辮的直徑中減去所述M6點的髮辮的直徑的值。 dR: the value of subtracting the diameter of the braid at point R1 from the diameter of the braid at point R3; and dM: subtracting the braid at point M6 from the diameter of the braid at point M9 The value of the diameter.

藉由所述dR及dM值,能夠顯著地確認毛幹部位中接近於毛根的4~6cm的毛髮部位和除此之外的毛髮部位的蓬鬆感的變化(參考第5圖)。 From the above-mentioned dR and dM values, it is possible to remarkably confirm the change in volume of the 4-6 cm hair part close to the hair root and other hair parts in the hair shaft part (refer to FIG. 5 ).

試驗例2:根據本發明的毛髮蓬鬆感的評價方法1及2的毛髮蓬鬆感的增強效果的確認 Test Example 2: Confirmation of the Effect of Enhancing the Fluffy Feeling of Hair According to Evaluation Methods 1 and 2 of the Fluffy Feeling of Hair of the Present Invention

依據上述毛髮蓬鬆感的評價方法1及2,利用髮辮對表2的試驗物質中的6種原料(BMAS-AP、KSP-101、Styleze W-10、ADM 8301 E、BELSIL PF 200及SC-200)實施毛髮蓬鬆感的增減水平的評價及使用感的感官評價。其中,對毛髮的蓬鬆感的增減水平進行評價時所使用的疏水性(Hydrophobicity)指標是藉由如下方法測量並示出的,即,使用移液管在經過各原料的處理(及清洗)的髮辮上滴落蒸餾水(約50μl),並在毛髮的毛根(hair root)和髮尖(hair tip)以秒的單位測量蒸餾水完全被吸收所需要的時間(s)。 According to the evaluation methods 1 and 2 of the above-mentioned fluffy feeling of hair, 6 kinds of raw materials (BMAS-AP, KSP-101, Styleze W-10, ADM 8301 E, BELSIL PF 200 and SC- 200) The evaluation of the level of increase and decrease in the fluffy feeling of hair and the sensory evaluation of the feeling of use are carried out. Among them, the hydrophobicity (Hydrophobicity) index used when evaluating the level of increase or decrease in the fluffy feeling of hair is measured and shown by the following method, that is, after the processing (and washing) of each raw material using a pipette Distilled water (approximately 50 μl) was dropped on the braids of the hair, and the time (s) required for the distilled water to be completely absorbed was measured in seconds at the hair root and hair tip of the hair.

對所述髮辮的使用感的感官評價是以專業小組的感官評分(sensory score)為基準,並以粗糙度、殘留感及塗覆感進行評價,各數值是以5分制的評價分數進行評價([1]粗糙度:0分-沒有粗糙感,5分-感到非常粗糙;[2]殘留感:0分-沒有殘留感,5分-強的殘留感;[3]塗覆感:0分-沒有塗覆感,5分-強的塗覆感)。 The sensory evaluation of the use feeling of the braids is based on the sensory score of a professional panel, and is evaluated by roughness, residual feeling and coating feeling, and each value is based on a 5-point evaluation score. Evaluation ([1] roughness: 0 points - no rough feeling, 5 points - very rough feeling; [2] residual feeling: 0 points - no residual feeling, 5 points - strong residual feeling; [3] coating feeling: 0 points - no coating feeling, 5 points - strong coating feeling).

其結果,如表4所示,依據上述毛髮的評價方法1及評價方法2的基準,確認BMAS-AP、KSP-101、Styleze W-10及SC-200的提高毛髮的蓬鬆感的效果是適當的,並且在使用感方面也得到了令人滿意的水平。 As a result, as shown in Table 4, it was confirmed that BMAS-AP, KSP-101, Styleze W-10, and SC-200 are suitable for improving the fluffy feeling of hair based on the criteria of Evaluation Method 1 and Evaluation Method 2 above. and achieved a satisfactory level in terms of usability.

Figure 107134722-A0305-02-0024-6
Figure 107134722-A0305-02-0024-6

參考表4確認到,就根據評價方法1的RS3值為1以上的BMAS-AP、KSP-101、Styleze W-10及SC-200而言,接近於毛根的4~6cm的毛髮部位的蓬鬆度高,就RS3值小於1的蒸餾水、ADM 8301 E、BELSIL PF 200而言,接近於毛根的4~6cm的毛髮部位的蓬鬆度低。 With reference to Table 4, it was confirmed that BMAS-AP, KSP-101, Styleze W-10, and SC-200 whose RS3 value was 1 or more according to evaluation method 1, the bulkiness of the hair part of 4~6 cm close to the hair root High, for distilled water with RS3 value less than 1, ADM 8301 E, BELSIL PF 200, the volume of the hair part close to the hair root 4~6cm is low.

另外,就根據評價方法2的dR值為10以上的BMAS-AP、KSP-101、Styleze W-10及SC-200而言,接近於毛根的4~6cm的毛髮部位的蓬鬆度顯示出明顯的增加,就dR值小於10的ADM 8301 E、BELSIL PF 200而言,除了接近於毛根的4~6cm的毛髮部位之外的毛髮部位的毛髮的蓬鬆感的增加效果顯示為大。這樣的結果也符合表3的結果。 In addition, for BMAS-AP, KSP-101, Styleze W-10, and SC-200 whose dR value was 10 or more according to the evaluation method 2, the bulkiness of the hair part of 4~6 cm close to the root of the hair showed a remarkable bulkiness. For ADM 8301 E and BELSIL PF 200 with a dR value of less than 10, the effect of increasing the volume of the hair in hair parts other than the hair part of 4 to 6 cm close to the hair root was shown to be large. This result is also consistent with the results in Table 3.

試驗例3:包含增強毛髮的蓬鬆感的物質的洗髮精組合物的增強毛髮的蓬鬆感的功效、穩定度及使用感的評價 Test Example 3: Evaluation of hair volume-enhancing efficacy, stability, and use feeling of a shampoo composition containing a hair volume-enhancing substance

[參考例2]:基礎洗髮精組分的決定 [Reference Example 2]: Determination of Basic Shampoo Components

以40~50歲年齡段的成人(senior)為對象,將基礎洗髮精的候選物塗布在毛髮上,然後以9分制對使用感進行感官評價(9分制的評價分數基準是以“[1分]非常低-[5分]一般-[9分]非常高”來確認)(未示出數據)。 For adults (senior) in the age group of 40 to 50 years old, the candidates for the basic shampoo are applied to the hair, and then the sensory evaluation is performed on the sense of use on a 9-point scale (the evaluation score of the 9-point system is based on " [1 point] very low - [5 points] average - [9 points] very high" to confirm) (data not shown).

如第6圖所示,根據20名成人的平均分數的感官評價結果,選擇8種項目(泡沫程度、清洗程度、清洗時的柔順度、清潔度、乾燥時的柔順度、平整度、定型、蓬鬆感)中顯示為優異的基礎洗髮精候選物作為用於後續實驗的基本劑型(比較例1)。由此,如下述表5~8所示,製備共同含有所選的所述基礎洗髮精的主要成分的洗髮精組合物。 As shown in Figure 6, according to the sensory evaluation results of the average scores of 20 adults, select 8 items (foam degree, degree of cleaning, softness when washing, cleanliness, softness when drying, flatness, setting, Fluffy feel) showed excellent base shampoo candidates as the basic dosage form for subsequent experiments (Comparative Example 1). Thus, as shown in the following Tables 5 to 8, shampoo compositions containing the selected main components of the basic shampoo were prepared.

具體而言,製備洗髮精組合物來確認各組合物是否具有提高毛髮蓬鬆感的效果以及使用感方面是否有改善效果,其中所述洗髮精組合物是以不同的組合包含所述基礎洗髮精和試驗例1及2中最終篩選的作為疏水性聚合物的異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物(BMAS-AP)、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物(KSP-101)及聚季銨鹽-55(PQ-55;Styleze W-10)的洗髮精組合物,以及以不同的組合包含所述基礎洗髮精和所述疏水性聚合物及作為非離子性聚合物的聚季銨鹽-11(PQ-11)的洗髮精組合物。 Specifically, shampoo compositions are prepared to confirm whether each composition has the effect of improving the fluffy feeling of hair and whether there is an effect of improving the feeling of use, wherein the shampoo composition contains the basic shampoo in different combinations. Isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer (BMAS-AP), vinyl poly Shampoo Composition of Dimethicone/Methicone Silsesquioxane Crosspolymer (KSP-101) and Polyquaternium-55 (PQ-55; Styleze W-10) , and shampoo compositions comprising said base shampoo and said hydrophobic polymer and polyquaternium-11 (PQ-11) as a nonionic polymer in various combinations.

表2及表5~8的試驗物質中,本發明中所使用的聚季銨鹽-11為乙烯吡咯烷酮和季化甲基丙烯酸二甲氨基乙酯的共聚物,主要由乙烯吡咯烷酮和N,N-二甲氨基甲基丙烯酸乙酯的共聚物的二乙基硫酸鹽構成的共聚物的20%水溶液。 Among the test substances of Table 2 and Tables 5 to 8, the polyquaternium-11 used in the present invention is a copolymer of vinylpyrrolidone and quaternized dimethylaminoethyl methacrylate, mainly composed of vinylpyrrolidone and N,N - A 20% aqueous solution of a copolymer of diethylsulfate of a copolymer of dimethylaminoethyl methacrylate.

Figure 107134722-A0305-02-0025-7
Figure 107134722-A0305-02-0025-7
Figure 107134722-A0305-02-0026-8
Figure 107134722-A0305-02-0026-8

Figure 107134722-A0305-02-0026-9
Figure 107134722-A0305-02-0026-9
Figure 107134722-A0305-02-0027-10
Figure 107134722-A0305-02-0027-10

Figure 107134722-A0305-02-0027-11
Figure 107134722-A0305-02-0027-11
Figure 107134722-A0305-02-0028-12
Figure 107134722-A0305-02-0028-12

Figure 107134722-A0305-02-0028-13
Figure 107134722-A0305-02-0028-13
Figure 107134722-A0305-02-0029-14
Figure 107134722-A0305-02-0029-14

<包含增加毛髮的蓬鬆感的物質的洗髮精組合物的增強毛髮蓬鬆感的功效的評價> <Evaluation of Fluffy-enhancing Effect of Shampoo Composition Containing Fluffy-Increasing Substance>

利用如表5~8所示的組分製備的洗髮精組合物,對髮辮的增強毛髮的蓬鬆感的功效進行評價(參考所述毛髮蓬鬆感的評價方法1~2)。 Using the shampoo compositions prepared from the components shown in Tables 5 to 8, the effect of enhancing the volume of the hair braids was evaluated (refer to the evaluation methods 1 to 2 for the volume of the hair).

其結果,如表9~12中所示,塗布包含選自異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物(BMAS-AP)、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物(KSP-101)及聚季銨鹽-55(PQ-55;Styleze W-10)中的疏水性聚合物的洗髮精組合物(實施例8~15)的髮辮的提高毛髮蓬鬆感的效果優異。 As a result, as shown in Tables 9 to 12, the coatings consisted of isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer (BMAS-AP), vinyl polydimethylsiloxane Hydrophobic polymers in Polysiloxane/Methicone Silsesquioxane Crosspolymer (KSP-101) and Polyquaternium-55 (PQ-55; Styleze W-10) The hair essence compositions (Examples 8 to 15) were excellent in the effect of improving the fluffiness of the hair.

尤其,確認塗布包含3種疏水性聚合物的混合物,即包含混合有異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物及聚季銨鹽-55的混合物的洗髮精組合物(實施例8、12~15)的髮辮的提高毛髮蓬鬆感的效果最為優異。 In particular, it was confirmed that the coating contained a mixture of three hydrophobic polymers, that is, a mixture of isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer, vinyl dimethicone The shampoo composition (Example 8, 12~15) of the mixture of alkane/polymethylsiloxane silsesquioxane crosslinked polymer and polyquaternium-55 improves the fluffy feeling of hair The effect is the most excellent.

Figure 107134722-A0305-02-0030-16
Figure 107134722-A0305-02-0030-16

Figure 107134722-A0305-02-0030-17
Figure 107134722-A0305-02-0030-17

表11

Figure 107134722-A0305-02-0031-18
Table 11
Figure 107134722-A0305-02-0031-18

Figure 107134722-A0305-02-0031-19
Figure 107134722-A0305-02-0031-19

<包含增加毛髮的蓬鬆感的物質的洗髮精組合物的穩定度評價> <Evaluation of Stability of Shampoo Composition Containing a Material That Increases Volume of Hair>

對如表5~8所示的組分製備的洗髮精組合物的穩定度進行評價。 The stability of the shampoo composition prepared from the components shown in Tables 5-8 was evaluated.

其結果,如表13~16所示,製備實施例1~15後,組合物的外觀上沒有形成分離層,從而確認組合物的穩定度非常高。 As a result, as shown in Tables 13 to 16, after Preparation Examples 1 to 15, no separation layer was formed on the appearance of the composition, and it was confirmed that the stability of the composition was very high.

表13

Figure 107134722-A0305-02-0032-20
Table 13
Figure 107134722-A0305-02-0032-20

Figure 107134722-A0305-02-0032-21
Figure 107134722-A0305-02-0032-21

Figure 107134722-A0305-02-0032-22
Figure 107134722-A0305-02-0032-22

Figure 107134722-A0305-02-0032-23
Figure 107134722-A0305-02-0032-23

<包含增加毛髮的蓬鬆感的物質的洗髮精組合物的使用感評價(感官檢查)> <Evaluation of Feeling in Use (Sensory Test) of Shampoo Composition Containing a Material That Increases Fluffy Feel of Hair>

利用如表5~8所示的成分製備的洗髮精組合物,對髮辮實施感官評價(10分制的評價分數基準是以“[1分]非常低-[5分]一般-[10分]非常高”來確認)。 Using the shampoo composition prepared from the ingredients shown in Tables 5 to 8, perform a sensory evaluation on the tresses (the 10-point evaluation score basis is "[1 point] very low-[5 points] general-[10 points] Score] very high" to confirm).

其結果,如表17~20中所示,以重量為基準,將包含以1:1:1:4混合作為疏水性組合物的異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物及聚季銨鹽-55和作為非離子性聚合物的聚季銨鹽-11的混合物的洗髮精組合物(實施例8)塗布於髮辮上時,在使用感方面也得到了最好的評價(位於頭上部的頭頂毛髮的彈 性感及收尾塗覆感得到提高,並且洗髮精組合物在毛髮上的黏糊感及殘留感得到減少)。 As a result, as shown in Tables 17 to 20, on a weight basis, Isododecane/butyl acrylate/hydroxypropyl polydimethyl Silicone Acrylate Copolymer, Vinyl Dimethicone/Methicone Silsesquioxane Crosspolymer and Polyquaternium-55 and Polyquaternium as Nonionic Polymer When the shampoo composition (Example 8) of the mixture of ammonium salt-11 was applied to the dreadlocks, it also obtained the best evaluation in terms of use feeling (the elasticity of the hair on the top of the head). Sensitivity and finish are improved, and stickiness and residue of the shampoo composition on the hair are reduced).

Figure 107134722-A0305-02-0033-24
Figure 107134722-A0305-02-0033-24

Figure 107134722-A0305-02-0033-25
Figure 107134722-A0305-02-0033-25

Figure 107134722-A0305-02-0033-26
Figure 107134722-A0305-02-0033-26

Figure 107134722-A0305-02-0033-27
Figure 107134722-A0305-02-0033-27
Figure 107134722-A0305-02-0034-28
Figure 107134722-A0305-02-0034-28

將實際試驗對象人員作為對象,對最終篩選的異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物及聚季銨鹽-55和聚季銨鹽-11的組合的提高毛髮蓬鬆感的能力進行評價。 Taking actual test subjects as objects, the final screening of isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer, vinyl dimethicone/polymethicone The combination of oxane silsesquioxane crosspolymer and polyquaternium-55 and polyquaternium-11 was evaluated for its ability to improve hair volume.

具體而言,以20名40~50歲年齡段的成人為對象,以重量為基準,將包含以1:1:1:4混合的異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物及聚季銨鹽-55和聚季銨鹽-11的混合物的洗髮精組合物(實施例8)塗布於試驗對象人員的毛髮上後,以6分制對使用感實施感官評價(6分制的評價分數基準是以“[1分]非常低-[3分]一般-[6分]非常高”來確認)。 Specifically, 20 adults in the age group of 40 to 50 years of age were selected as objects, and a mixture of isododecane/butyl acrylate/hydroxypropyl polydimethylmethanol at a ratio of 1:1:1:4 was used as a weight basis. Polysiloxane Acrylate Copolymer, Vinyl Dimethicone/Methicone Silsesquioxane Crosspolymer and Blend of Polyquaternium-55 and Polyquaternium-11 After the shampoo composition (Example 8) was applied on the hair of the test subject, sensory evaluation was carried out on the sense of use with a 6-point system (the evaluation score standard of the 6-point system is "[1 point] very low-[ 3 points] average - [6 points] very high" to confirm).

其結果,如第7圖所示,根據20名成人的平均分數的感官評價,與現有的洗髮精相比,實施例8的洗髮精組合物在位於頭上部的頭頂毛髮的彈性感及毛髮的收尾塗覆感方面顯示出優勢,從而增強毛髮的蓬鬆感的效果非常優異。 As a result, as shown in FIG. 7, according to the sensory evaluation of the average score of 20 adults, compared with the conventional shampoo, the shampoo composition of Example 8 has a feeling of elasticity and It shows an advantage in the finish coating feeling of the hair, and the effect of enhancing the fluffy feeling of the hair is excellent.

本發明的包含單獨的疏水性聚合物作為有效成分,或者包含疏水性聚合物及非離子性聚合物的混合物作為有效成分的化妝品組合物可以產品化為多種劑型的化妝品,考慮到所要實現的產品的功能性、費用及其他條件,可以以適當的含量比例進行控制。 The cosmetic composition of the present invention comprising a single hydrophobic polymer as an active ingredient, or a mixture of a hydrophobic polymer and a nonionic polymer as an active ingredient can be produced into cosmetics in various dosage forms, considering the desired product The functionality, cost and other conditions can be controlled at an appropriate content ratio.

劑型例1:毛髮用軟膏 Formulation example 1: Ointment for hair

混合包含油相成分和水相成分的表21的成分,從而製備包含本發明的疏水性聚合物,或者包含疏水性聚合物及非離子性聚合物的混合物的毛髮用軟膏。 The components in Table 21 including the oil phase component and the water phase component were mixed to prepare an ointment for hair containing the hydrophobic polymer of the present invention or a mixture of a hydrophobic polymer and a nonionic polymer.

Figure 107134722-A0305-02-0035-29
Figure 107134722-A0305-02-0035-29

劑型例2:毛髮用營養化妝水 Formulation Example 2: Nutritious lotion for hair

混合包括油相成分和水相成分的表22的成分,從而製備包含本發明的疏水性聚合物,或者疏水性聚合物及非離子性聚合物的混合物的毛髮用營養化妝水。 The components in Table 22 including the oil phase component and the water phase component were mixed to prepare a nutrient lotion for hair containing the hydrophobic polymer of the present invention or a mixture of a hydrophobic polymer and a nonionic polymer.

Figure 107134722-A0305-02-0035-30
Figure 107134722-A0305-02-0035-30
Figure 107134722-A0305-02-0036-31
Figure 107134722-A0305-02-0036-31

劑型例3:毛髮用按摩霜 Dosage Form Example 3: Massage Cream for Hair

混合包括油相成分和水相成分的表23的成分,從而製備包含本發明的疏水性聚合物,或者疏水性聚合物及非離子性聚合物的混合物的毛髮用按摩霜。 The components in Table 23 including the oil phase component and the water phase component were mixed to prepare a massage cream for hair containing the hydrophobic polymer of the present invention or a mixture of a hydrophobic polymer and a nonionic polymer.

Figure 107134722-A0305-02-0036-32
Figure 107134722-A0305-02-0036-32

劑型例4:護髮膜 Dosage Form Example 4: Hair Mask

混合包括油相成分和水相成分的表24的成分,從而製備包含本發明的疏水性聚合物,或者疏水性聚合物及非離子性聚合物的混合物的護髮膜。 The ingredients of Table 24, including the oil phase ingredients and the water phase ingredients, were mixed to prepare a hair care mask comprising the hydrophobic polymer of the present invention, or a mixture of a hydrophobic polymer and a nonionic polymer.

表24

Figure 107134722-A0305-02-0037-33
Table 24
Figure 107134722-A0305-02-0037-33

劑型例5:生髮水 Dosage Form Example 5: Hair Tonic

根據表25中所記載的組分,以通常的方法製備包含本發明的疏水性聚合物,或者疏水性聚合物及非離子性聚合物的混合物的生髮水。 According to the components described in Table 25, hair tonics containing the hydrophobic polymer of the present invention or a mixture of a hydrophobic polymer and a nonionic polymer were prepared by a usual method.

Figure 107134722-A0305-02-0037-34
Figure 107134722-A0305-02-0037-34

劑型例6:護髮乳霜(haircream) Formulation example 6: hair cream (haircream)

根據表26中所記載的組分,以通常的方法製備包含本發明的疏水性聚合物,或者疏水性聚合物及非離子性聚合物的混合物的護髮乳霜(haircream)。 According to the components described in Table 26, a hair cream (haircream) containing the hydrophobic polymer of the present invention or a mixture of a hydrophobic polymer and a nonionic polymer was prepared by a usual method.

Figure 107134722-A0305-02-0037-35
Figure 107134722-A0305-02-0037-35
Figure 107134722-A0305-02-0038-36
Figure 107134722-A0305-02-0038-36

劑型例7:潤髮乳及焗油膏 Dosage Form Example 7: Conditioner and Baking Cream

根據表27中所記載的組分,以通常的方法製備包含本發明的疏水性聚合物,或者疏水性聚合物及非離子性聚合物的混合物的潤髮乳及焗油膏。 According to the components described in Table 27, the hair conditioner and the hair conditioner containing the hydrophobic polymer of the present invention, or a mixture of a hydrophobic polymer and a nonionic polymer were prepared by a usual method.

Figure 107134722-A0305-02-0038-37
Figure 107134722-A0305-02-0038-37

劑型例8:洗髮精 Dosage Form Example 8: Shampoo

混合包括油相成分和水相成分的表28的成分,從而製備包含本發明的疏水性聚合物,或者疏水性聚合物及非離子性聚合物的混合物的洗髮精。 The components in Table 28 including oil phase components and water phase components were mixed to prepare a shampoo comprising the hydrophobic polymer of the present invention, or a mixture of a hydrophobic polymer and a nonionic polymer.

Figure 107134722-A0305-02-0038-38
Figure 107134722-A0305-02-0038-38
Figure 107134722-A0305-02-0039-39
Figure 107134722-A0305-02-0039-39

以上,對本發明的特定部分進行了詳細的記述,本領域具有通常知識的技術人員明確知道這些具體的記述僅僅是較佳地的實施方式,本發明的範圍不受限於此。因此,本發明的實質性範圍是根據的申請專利範圍和其等價物所定義。 Above, specific parts of the present invention have been described in detail, and it is clear to those skilled in the art that these specific descriptions are only preferred embodiments, and the scope of the present invention is not limited thereto. Accordingly, the substantive scope of the present invention is defined in accordance with the appended claims and their equivalents.

Claims (11)

一種用於增強毛髮的蓬鬆感的化妝品組合物,其包含一疏水性聚合物以及一非離子性聚合物作為有效成分,其中該疏水性聚合物及該非離子性聚合物是以3~9:4~2的重量比進行混合,且以該化妝品組合物的總重量為基準,該疏水性聚合物的含量為0.005~1重量%,且該非離子性聚合物的含量為0.001~1重量%,其中該疏水性聚合物為選自異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物及聚季銨鹽-55(PQ-55)中的一種以上,其中該非離子性聚合物為聚季銨鹽-11(PQ11)。 A cosmetic composition for enhancing the fluffy feeling of hair, which comprises a hydrophobic polymer and a nonionic polymer as active ingredients, wherein the ratio of the hydrophobic polymer and the nonionic polymer is 3~9:4 ~2 weight ratio for mixing, and based on the total weight of the cosmetic composition, the content of the hydrophobic polymer is 0.005 to 1% by weight, and the content of the nonionic polymer is 0.001 to 1% by weight, wherein The hydrophobic polymer is selected from isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer, vinyl dimethicone/polymethicone silicone One or more of semioxane crosslinked polymers and polyquaternium-55 (PQ-55), wherein the nonionic polymer is polyquaternium-11 (PQ11). 如請求項1所述的化妝品組合物,其中以重量為基準,該疏水性聚合物及該非離子性聚合物是以3~3.6:4~2進行混合。 The cosmetic composition according to claim 1, wherein the hydrophobic polymer and the nonionic polymer are mixed in a ratio of 3~3.6:4~2 on a weight basis. 如請求項2所述的化妝品組合物,其中以重量為基準,該疏水性聚合物及該非離子性聚合物是以3:4進行混合。 The cosmetic composition according to claim 2, wherein the hydrophobic polymer and the nonionic polymer are mixed in a ratio of 3:4 on a weight basis. 如請求項1所述的化妝品組合物,其中以該化妝品組合物的總重量為基準,該疏水性聚合物的含量為0.15~0.9重量%,且該非離子性聚合物的含量為0.2重量%。 The cosmetic composition according to claim 1, wherein based on the total weight of the cosmetic composition, the content of the hydrophobic polymer is 0.15-0.9% by weight, and the content of the nonionic polymer is 0.2% by weight. 如請求項1所述的化妝品組合物,其中該疏水性聚合物為異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物及聚季銨鹽-55(PQ-55)的混合物。 The cosmetic composition as claimed in item 1, wherein the hydrophobic polymer is isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer, vinyl dimethicone A mixture of alkane/methicone silsesquioxane crosspolymer and polyquaternium-55 (PQ-55). 如請求項1所述的化妝品組合物,其中該化妝品組合物為清洗型的毛髮清洗用組合物。 The cosmetic composition according to claim 1, wherein the cosmetic composition is a cleansing type hair cleansing composition. 如請求項1所述的化妝品組合物,其中該化妝品組合物 劑型化為選自毛髮用軟膏、毛髮用營養化妝水、毛髮用按摩霜、護髮膜、生髮水、護髮乳霜(haircream)、潤髮乳、焗油膏、頭皮護理液、洗髮精及潤髮油中的任一種。 The cosmetic composition as claimed in item 1, wherein the cosmetic composition The dosage form is selected from hair ointment, hair nourishing lotion, hair massage cream, hair care mask, hair tonic, hair cream (haircream), conditioner, hair cream, scalp care solution, shampoo and Any of the pomades. 一種如請求項1所述的化妝品組合物在製備用於增強該毛髮的蓬鬆感的化妝品組合物或化妝品中的用途。 A use of the cosmetic composition as described in Claim 1 in the preparation of a cosmetic composition or cosmetics for enhancing the volume of the hair. 一種如請求項1所述的化妝品組合物在製備用於提高位於頭上部的頭頂毛髮的彈性感、改善毛髮的殘留感以及提高毛髮的收尾塗覆感的化妝品組合物或化妝品中的用途。 A use of the cosmetic composition as described in claim 1 in the preparation of a cosmetic composition or cosmetics for improving the elastic feeling of the hair on the top of the head, improving the residual feeling of the hair, and improving the finish coating feeling of the hair. 一種疏水性聚合物及非離子性聚合物的混合物在製備用於增強毛髮的蓬鬆感的化妝品組合物或化妝品中的用途,其中該疏水性聚合物及該非離子性聚合物是以3~9:4~2的重量比進行混合,其中該疏水性聚合物為選自異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物及聚季銨鹽-55(PQ-55)中的一種以上,其中該非離子性聚合物為聚季銨鹽-11(PQ11)。 A use of a mixture of a hydrophobic polymer and a nonionic polymer in the preparation of a cosmetic composition or cosmetics for enhancing the fluffy feel of hair, wherein the hydrophobic polymer and the nonionic polymer are based on 3~9: 4~2 weight ratio for mixing, wherein the hydrophobic polymer is selected from isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer, vinyl dimethicone One or more of alkane/polymethicone silsesquioxane crosslinked polymer and polyquaternium-55 (PQ-55), wherein the nonionic polymer is polyquaternium-11 (PQ11) . 如請求項10所述的用途,其中該疏水性聚合物為異十二烷/丙烯酸丁酯/羥丙基聚二甲基矽氧烷丙烯酸酯共聚物、乙烯基聚二甲基矽氧烷/聚甲基矽氧烷矽倍半氧烷交聯聚合物及聚季銨鹽-55(PQ-55)的混合物。 Use as described in claim item 10, wherein the hydrophobic polymer is isododecane/butyl acrylate/hydroxypropyl dimethicone acrylate copolymer, vinyl dimethicone/ A blend of methicone silsesquioxane crosspolymer and polyquaternium-55 (PQ-55).
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