TWI757007B - Anti-rat and anti-ant , fire-resistant and firepoof cable, manufacturing method thereod and anti-rat and anti-ant , fire-resistant and firepoof composition - Google Patents

Abstract

An anti-rat and anti-ant, fire-resistant and fireproof composition, a cable, and manufacturing method of making the same are provided. The anti-rat and anti-ant, fire-resistant and fireproof cable includes at least one core cable and a cover layer covering the at least one core cable. The core cable includes a conductor, a fire protection tape and/or an insulation layer in order from the inside to the outside. The cover layer contains 5-10 parts by weight of flame retardant agent, which includes modified zirconium phosphate. The modified zirconium phosphate greatly improves the material compatibility in the coating layer and the flame resistance effect of the coating layer.

Description

Rodent and ant-proof flame-retardant and fire-resistant cable, its manufacturing method, and rodent-ant-proof flame-retardant and fireproof composition

The invention relates to a rodent and ant-proof flame-retardant and fire-resistant cable, a manufacturing method thereof and a rodent- and ant-proof flame-retardant and fire-proof composition, in particular to a rodent and ant-proof flame-retardant and fireproof cable comprising modified zirconium phosphate.

Existing power cables mainly include a cable core and a coating layer covering the cable core. The coating layer is generally formed of plastic, rubber or thermoplastic elastomer, which is difficult to resist rodents (such as mice) and termites. For power cables installed outdoors (such as buried underground), the coating layer is more likely to be damaged by rodents and termites, and once the coating layer is damaged, the inner cable core will be directly exposed; in this way, it is easy to A short-circuit accident occurs, resulting in a sudden power outage, which may cause major safety accidents and economic losses in severe cases.

The flame resistance and fire resistance of the cable is directly related to whether the fire-fighting electrical equipment can work normally in the fire. At present, the fire-resistant cables widely used at home and abroad mainly include magnesium oxide mineral insulated cables and mica tape-wrapped fire-resistant cables. Therefore, the development of fire-resistant and fire-resistant formulations and cables with excellent fire resistance and good processing performance has become the development trend of fire protection technology and people's livelihood.

The technical problem to be solved by the present invention is to provide a ceramicized rodent-ant-proof, fire-resistant and fire-resistant cable aiming at the deficiencies of the prior art.

In order to solve the above-mentioned technical problems, one of the technical solutions adopted by the present invention is to provide a rodent and ant fire-resistant and fire-resistant cable, which includes at least one cable core and a coating layer covering at least one of the cable cores, wherein at least one cable core is The cable core includes a conductor, at least one fireproof tape wrapped outside the conductor and/or an insulating layer wrapped outside the conductor, and the covering layer includes 5 to 10 parts by weight of a flame retardant, which It is characterized in that the flame retardant comprises a modified zirconium phosphate.

Preferably, the coating layer further comprises 100 parts by weight of the coating polymer host material, 10 to 20 parts by weight of a flame retardant filler, 0.5 to 6 parts by weight of a pest repellent, and 5 to 10 parts by weight of a multifunctional adjuvant.

Preferably, the insulating layer comprises 80 to 125 parts by weight of insulating polymer host material, 80 to 185 parts by weight of ceramizer, 10 to 45 parts by weight of flux, 10 to 50 parts by weight of flame retardant, 50 to 80 parts by weight of multifunctional adjuvant and 0 to 15 parts by weight of crosslinking agent.

Preferably, the flame retardant further includes alpha zirconium phosphate, zinc borate and ammonium polyphosphate.

Preferably, the modified zirconium phosphate includes a first layered molecular structure, a second layered molecular structure, and an intercalation between the first layered molecular structure and the second layered molecular structure between modified materials.

Preferably, the modified material is an organic material or an inorganic material, and is selected from the group consisting of N,N-dimethylacetamide, polyhexamethylene biguanide and dodecyldimethylbenzylammonium chloride. at least one of the formed groups.

In order to solve the above-mentioned technical problem, another technical solution adopted by the present invention is to provide a kind of anti-mouse ant fire-resistant and fire-resistant composition, which comprises: 100 parts by weight of a coating polymer main material, 5 to 10 parts by weight of a flame retardant, 10 to 20 parts by weight of flame retardant filler, 0.5 to 6 parts by weight of pest repellent, and 5 to 10 parts by weight of multifunctional adjuvant. Wherein, the flame retardant includes a modified zirconium phosphate, and the modified zirconium phosphate includes a first layered molecular structure, a second layered molecular structure, and an intercalation in the first layered molecular structure. A modified material between the molecular structure and the second layered molecular structure.

In order to solve the above-mentioned technical problem, another technical solution adopted by the present invention is to provide a method for manufacturing a rodent ant fire-resistant and fire-resistant cable, which includes: providing a conductor and wrapping a fire-proof tape in a concentric circle. The conductor is covered by the method or wrapping method; an insulating layer is formed to cover the fireproof tape to obtain at least one cable core; and a coating layer is formed to cover at least one of the cable cores to obtain an anti-mouse ant Fire-resistant and fire-resistant cables.

Preferably, the step of forming a coating layer to cover at least one of the cable cores is to cover a plurality of the cable cores, and further fill the gaps between the plurality of the cable cores with a filler.

Preferably, the fire protection tape is a mica tape, a fiber composite tape or a ceramic tape.

One of the beneficial effects of the present invention is that the rodent and ant-resistant flame-retardant and fire-resistant cable, its manufacturing method, and the rodent-ant and ant-resistant flame-retardant and fire-resistant composition provided by the present invention can pass through "the coating layer comprises 5 to 10 parts by weight of flame retardant. It is characterized in that the flame retardant includes a technical solution of "modified zirconium phosphate", which greatly improves the compatibility of materials in the coating layer and the flame resistance effect of the coating layer.

For a further understanding of the features and technical content of the present invention, please refer to the following detailed descriptions and drawings of the present invention. However, the drawings provided are only for reference and description, and are not intended to limit the present invention.

The following are specific specific examples to illustrate the embodiments disclosed in the present invention related to the "rat and ant-proof flame-retardant and fire-resistant cable and its manufacturing method and rodent-ant and ant-proof flame-retardant and fire-resistant composition". Those skilled in the art can understand the content disclosed in this specification. Advantages and Effects of the Invention. The present invention can be implemented or applied through other different specific embodiments, and various details in this specification can also be modified and changed based on different viewpoints and applications without departing from the concept of the present invention. In addition, the drawings of the present invention are merely schematic illustrations, and are not drawn according to the actual size, and are stated in advance. The following embodiments will further describe the related technical contents of the present invention in detail, but the disclosed contents are not intended to limit the protection scope of the present invention. In addition, the term "or", as used herein, should include any one or a combination of more of the associated listed items, as the case may be.

Referring to FIG. 1 in conjunction with FIG. 2 , the rodent and ant-proof flame-retardant and fire-resistant cable Z according to the first embodiment of the present invention includes at least one cable core 1 for transmitting electrical signals and a coating layer 2 covering the cable core 1 . As shown in FIG. 1 , the cable core 1 includes a conductor 11 and an insulating layer/fireproof tape 12 covering the conductor 11 . Preferably, the thickness of the insulating layer 12 is 1 to 5 mm, more preferably 2 to 4 mm.

As shown in FIG. 2 , according to different purposes, the number of cable cores 1 can also be multiple (such as three or more); when the number of cable cores 1 is multiple, between the cable core 1 and the coating layer 2 It may further comprise filling the gap with air, or may comprise filler 3 (eg various forms of polyethylene, polypropylene, polyvinyl chloride regrind) to maintain the structural integrity of the cable. Besides, as required, the conductor 11 can also be covered with a fireproof tape 13 (refer to FIG. 5 ).

The conductor 11 can be formed by a plurality of wires with the same or different wire diameters (such as copper wires, their composite alloys or their modified wires) by concentric stranding or bundle stranding. The specification of the cable is selected.

The main material of the insulating layer 12 includes a polyolefin resin and/or a silicone resin insulating polymer main material, and further includes a ceramizer, a flux, a flame retardant, a multifunctional auxiliary agent, and a crosslinking agent. Preferably, the material of the insulating layer 12 includes 80 to 125 parts by weight of insulating polymer host material, 80 to 185 parts by weight of ceramizer, 10 to 45 parts by weight of flux, and 10 to 50 parts by weight of flame retardant. , 50 to 80 parts by weight of a multifunctional adjuvant and 0 to 15 parts by weight of a crosslinking agent. The insulating layer 12 may be formed by extrusion molding using the aforementioned materials. However, these details only describe possible embodiments of the cable core 1 and are not intended to limit the invention.

In more detail, the ceramizer includes magnesium oxide and nanomica powder; the flux includes ultrafine zinc borate, activated glass powder and/or silicone oil; the flame retardant includes: ultrafine zinc borate and/or ammonium polyphosphate; Multifunctional auxiliary agents include magnesium powder, zinc oxide and/or titanium dioxide; cross-linking agents include silane cross-linking agents and/or peroxides; cross-linking agents are mainly silane cross-linking agents. Besides, the insulating layer 12 may also include modified zirconium phosphate.

Specifically, the insulating polymer main material of the insulating layer 12 can be a mixed material of polyolefin resin and/or silicone resin material, which can be 80 to 125 parts by weight of polyolefin resin and 0 to 25 parts by weight of silicone resin material. Or 80 to 100 parts by weight of silicone resin material with 0 to 25 parts by weight of polyolefin resin. Silicone resin material has Si-N-Si bond or Si-O-Si bond in the molecular structure, which provides better water and gas barrier, high temperature resistance, chemical corrosion resistance, abrasion resistance and weather resistance, which can improve the cable's resistance to outdoor environment. The endurance of the cable is to improve the adaptability of the cable to the outdoor environment.

Furthermore, silicone resin materials have advantages in electrical insulation, ceramization rate, and ceramic strength, etc., but due to their high cost, their application scope and dosage are not large. The cost of polyolefin is low and the application range is wide. The use of suitable silane coupling agent can have good compatibility with silicone resin materials. When used in combination with polyolefin or silicone resin materials, it can supplement the cost, performance and cost. Balance gap.

The coating layer 2 includes a coating polymer main material, a flame retardant filler, a modified zirconium phosphate flame retardant, a pest repellent and a multifunctional auxiliary agent. Preferably, the coating layer 2 comprises 100 parts by weight of the coating polymer host material, 10 to 20 parts by weight of a flame retardant filler, 5 to 10 parts by weight of a modified zirconium phosphate flame retardant, 0.5 to 6 parts by weight of A pest repellent and 5 to 10 parts by weight of a multifunctional adjuvant.

Specifically, the coating polymer main material of the coating layer 2 is polyolefin resin, Low-Smoke-Free-Halogen (LSFH) or thermoplastic elastomer or polyvinyl chloride (PVC), for example, Polyolefin resins such as: polyethylene (PE), ethylene vinyl acetate copolymer (EVA), ethylene propylene diene rubber (EPDM), polyvinyl acetate (PVAc), polyethylene (PE) is further subdivided into linear low density poly Ethylene (LLDPE), low density polyethylene (LDPE), high density polyethylene (HDPE), medium density polyethylene (MDPE), preferably low density polyethylene and medium density polyethylene.

In more detail, the flame retardant of the coating layer 2 includes a modified zirconium phosphate, and further includes alpha zirconium phosphate, zinc borate and ammonium polyphosphate as required.

Referring to FIGS. 3A to 3B , the modified zirconium phosphate of the present invention can be modified by organic materials or inorganic materials. As shown in FIG. 3A , the selected zirconium phosphate of the present invention is a layered structure, which at least includes a first layered molecule The structure 501 and the second layered molecular structure 502 may further include a multi-layered molecular structure, such as the third layered molecular structure 503, as shown in FIG. 3B, the modified material 600 is intercalated in the first layered molecular structure 501 And between the second layer of zirconium phosphate 502, and between the second layered molecular structure 502 and the third layered molecular structure 503, through intercalation modification to increase the network crosslinking of the structure, improve the structural stability, and provide Better flame retardant effect and synergistic effect with other flame retardants.

Furthermore, the modified material 600 can be an organic material or an inorganic material, for example, can be N,N-dimethylacetamide, polyhexamethylene biguanide, dodecyldimethylbenzyl Ammonium chloride, hexachlorocyclotriphosphazene (HCCTP), hexaphenoxycyclotriphosphazene (HTCTP), dicyandiamide (DICY) or other cationic (surface) surfactants, such as Cetyltrimethylammonium bromide (hexadecyltrimethylammonium bromide, cetyltrimethylammonium bromide, CTAB). Depending on the requirements, the layered zirconium phosphate can be α-type zirconium phosphate (α-ZrP) or methylamine-modified methylamine-zirconium phosphate precursor. After modification, the layered structure of α-ZrP can play a better role in heat insulation and smoke suppression, and promote the formation of carbon while increasing the thermal stability of the carbon layer, providing better flame retardancy and smoke suppression.

In more detail, generally, the unmodified zirconium phosphate has poor compatibility with the polymer host material and cannot be uniformly dispersed, resulting in an unpredictable overall flame resistance effect. By using amine and alkane intercalation modification, the compatibility of zirconium phosphate and the polymer host material can be improved, the zirconium phosphate sheet material can be uniformly dispersed in the polymer host material, and the physical strength can be improved. The invention uses zirconium phosphate modified by intercalation of organic and inorganic materials, so as to greatly improve the compatibility and take into account the flame resistance effect and physical strength.

In addition, the decomposition temperature of zirconium phosphate is higher than 345°C, which is higher than that of natural antibacterial agents. It has better thermal stability, can be applied to high temperature processing, and has good environmental tolerance. environment, and has no drug resistance, and the effect is longer lasting, which can greatly slow down the erosion of the coating layer by bacteria and mold2.

In a specific embodiment of the present invention, dodecyl dimethyl benzyl ammonium chloride is used as the modified material, which is intercalated between the α zirconium phosphate layer structure, and the modified zirconium phosphate shows long-term performance. Antibacterial properties, the minimum inhibitory concentrations against Escherichia coli and Staphylococcus aureus were 800 mg/L and 100 mg/L, respectively, and the minimum bactericidal concentrations were 1000 mg/L and 150 mg/L, respectively, showing good antibacterial activity. The thermal decomposition temperature of high-quality zirconium phosphate is higher than 345 °C, and it has excellent thermal stability. However, the present invention is not limited to the above-mentioned examples.

In another specific embodiment of the present invention, methylamine is used to spread the zirconium phosphate interlayer spacing to obtain a methylamine-zirconium phosphate precursor, and then a quaternary phosphonium salt is used as a modified material to intercalate between methylamine-zirconium phosphate. During this time, the modified zirconium phosphate showed excellent antibacterial and flame retardant effects, and the performance was stable and long-lasting. However, the present invention is not limited to the above-mentioned examples.

In addition, the modified zirconium phosphate not only provides the aforementioned functions, but the modified zirconium phosphate and ammonium polyphosphate in the flame retardant composition can also improve the carbonization quality and quantity of the polymer host material, which can increase the density of the material. It is more compact and dense, and the flame retardant effect of the coating layer 2 is improved.

On the other hand, the flame retardant fillers are mainly magnesium hydroxide (MTH) and aluminum hydroxide (ATH). The zinc borate in the flame retardant is ultrafine zinc borate, such as ultrafine zinc borate with a particle size of 0.5 to 1.5 μm. There is also a synergistic effect between the ultrafine zinc borate and the aluminum hydroxide of the flame retardant filler.

Multifunctional auxiliary agents include alpha zirconium phosphate, organically modified zirconium phosphate, magnesium strong powder (talc), zinc oxide, titanium dioxide (titanium dioxide). Zirconium phosphate, magnesium powder and ultra-fine zinc borate all have good thermal stability, and can provide synergy when the composition is used, strengthen the Young's modulus of the polymer host material, and their thermal stability. , effectively improve the flame retardant effect, make the degree of ceramicization higher, and can replace most of the antioxidant functions, so there is no need to add additional antioxidants.

Further, the pest repellent mainly contains a spicy component and a bitter component. Spicy and bitter components stimulate the senses, such as biological receptors, nerve conduction systems, etc. The spicy ingredient may be a natural ingredient, such as capsaicin and its analogs, and preferably capsaicin; as the analog of capsaicin, dihydrocapsaicin, nordihydrocapsaicin, homodihydrocapsaicin, and high capsaicin can be exemplified White. The spicy component can also be obtained by artificial synthesis, and is preferably N-vanillylnonanamide (N-vanillylnonanamide, Nonivamide).

In addition, the bitter component may be denatonium benzoate. From the viewpoint of use effect and long-term effect, the spicy ingredient may contain 10 wt% to 30 wt% of capsaicin and dihydrocapsaicin, preferably dihydrocapsaicin, and 70 wt% to 90 wt% of N-Nonanoate vanillamide. However, the present invention is not limited to the above-mentioned examples. It is worth noting that, compared with dihydrocapsaicin, the molecular structure of capsaicin contains double bonds, which are easier to be decomposed by light.

In this embodiment, based on the total weight of the pest repellent being 100 wt %, the content of the spicy ingredient may be 10 wt % to 20 wt %, for example, 11 wt %, 12 wt %, 13 wt %, 14 wt % wt%, 15 wt%, 16 wt%, 17 wt%, 18 wt% or 19 wt%; the content of bitter ingredients may be 10 wt% to 50 wt%, such as 15 wt%, 20 wt%, 25 wt%, 30 wt%, 35 wt%, 40 wt% or 45 wt%. When capsaicin is used as a spicy ingredient, capsaicin can exist in the coating layer 2 in the form of microcapsules, that is, the coating layer 2 has a plurality of uniformly distributed capsaicin microcapsules (not shown); as a material for the microcapsules , polyvinyl chloride, polyolefins such as polyethylene and ethylene-vinyl acetate (poly(ethylene-co-vinyl acetate), EVA) can be cited. Thereby, the capsaicin can be prevented from migrating to the surface of the coating layer 2 and precipitating, and being carried out of the coating layer 2 by moisture, so as to ensure the use effect of the capsaicin.

It is worth noting that the repellent effects of pest repellents on pests include at least: 1. Capsaicin emits a pungent odor, making mice and other harmful organisms (such as termites) afraid to approach the cable; 2. When mice and other When rodents gnaw on the cable, capsaicin can give them a burning and tingling sensation, making them feel uncomfortable and reluctant to gnaw on the cable; 3. When mice and other rodents gnaw on the cable, they will feel benzene The strong bitter taste brought by denatonium is repugnant to the cable gnawing. In addition, when the spicy ingredients and bitter ingredients are used together, it can still play an effective preventive role in some rodents with innate sensory impairments, such as the inability to perceive bitter taste. In addition, in the presence of the bitter ingredient, the amount of the spicy ingredient used can be reduced, so the pest repellent is not irritating to humans.

In some embodiments, the pest repellent may include an insect repellent component. When the cable is eaten by termites, it will contact the insect repellent component and be poisoned and die; based on the total weight of the pest repellent being 100 wt %, The content of the insect repellent may be 0.5 wt% to 5 wt%, and preferably 1 wt% to 3 wt%. Examples of insect repellent ingredients for pest repellents include: pyrethrum (Pyrethrum or Pyrethrin), Permethrin, Allethrin, Tetramethrin, Dimenin ( Deltamethrin), Cymerthrin and Fenvalerate. However, the present invention is not limited to the above-mentioned examples.

In some embodiments, the pest repellent may include a cooling sensation component to enhance the use effect of capsaicin, that is, the cooling effect produced by the cooling sensation component has a synergistic effect on the burning sensation caused by capsaicin. The content of the cooling sensation component may be 0.5 wt% to 5 wt%, and preferably 1 wt% to 3 wt%, based on 100 wt% of the total weight of the pest repellent. The cooling sensation component may be menthol or a derivative thereof; examples of the menthol derivative include menthyl lactate, menthone-glycerol ketal, and monomethyl succinate ) and p-menthane-3,8-diol. However, the present invention is not limited to the above-mentioned examples.

Referring to FIG. 4 , and in conjunction with FIG. 5 , the present invention further provides a method for manufacturing a mouse and ant fire-resistant and fire-resistant cable, which includes: S100 providing a conductor 11 (such as copper, alloyed copper, graphene-modified copper, aluminum, copper, etc.) Aluminum alloy, etc.), a plurality of wires can be combined in a bundled or multiple twisted manner, and a fireproof tape 13 (mica tape, fiber composite tape or ceramic tape) is wound in a concentric longitudinal wrapping method or winding Covering the conductor 11 in a wrapping manner; S200 forming an insulating layer 12 to wrap the fireproof tape 13 to obtain at least one cable core 1 ; S300 forming a coating layer 2 to wrap at least one of the cable cores 1 .

Besides, S300 can also coat a plurality of the cable cores, and fill the gaps between the plurality of cable cores with fillers (as shown in FIG. 2 ).

Specifically, the conductor can be copper, alloyed copper, graphene-modified copper, aluminum, copper-aluminum alloy and other materials. The fireproof tape can be mica tape, fiber composite tape or ceramic tape, or the fireproof tape can also be designed with the same formula as the insulating layer. The mica tape can be synthetic mica tape and natural mica tape, because the temperature resistance of mica is up to 1300. ℃, and the maximum temperature resistance of the fiber composite tape can reach more than 2000 ℃, so it can prevent fire from invading the inside of the cable core 1 for a period of time. The ceramic tape is a fireproof tape mixed with polyolefin or silicone rubber and high-efficiency ceramic-forming materials. It can start to be ceramicized after a high temperature of 500 ° C, and is sintered into a shell to become an insulator within a certain period of time.

[Advantageous effects of the embodiment]

One of the beneficial effects of the present invention is that the rodent and ant-resistant flame-retardant and fire-resistant cable, its manufacturing method, and the rodent-ant and ant-resistant flame-retardant and fire-resistant composition provided by the present invention can pass through "the coating layer comprises 5 to 10 parts by weight of flame retardant. It is characterized in that the flame retardant includes a technical solution of "modified zirconium phosphate", which greatly improves the compatibility of materials in the coating layer and the flame resistance effect of the coating layer.

Further, the present invention passes through "the modified zirconium phosphate includes modified zirconium phosphate including a first layered molecular structure, a second layered molecular structure, and an intercalation in the first layer. The modified material "between the lamellar molecular structure and the second layered molecular structure" provides excellent thermal stability. Compared with the prior art, generally the unmodified zirconium phosphate itself has a close or no separation between layers, resulting in The compatibility with the polymer main material is poor and cannot be uniformly dispersed, resulting in poor overall flame resistance. The present invention uses the zirconium phosphate modified by the intercalation of organic and inorganic materials, which has a larger interlayer distance and can create a barrier space , so that the distance between the layers during combustion greatly reduces the heat conduction through the material, so as to greatly improve the compatibility and flame resistance.

In addition, the modified zirconium phosphate can slow down the erosion of the coating layer by bacteria and mold, and has good antibacterial activity.

In addition, the modified zirconium phosphate and ammonium polyphosphate in the flame retardant composition can further improve the carbonization quality and quantity of the polymer main material, and improve the flame retardant effect of the coating layer 2. In the specific composition of the present invention, , It also provides synergy, strengthens the Young's modulus of the composition material and the polymer main material, and its thermal stability, effectively improves the flame retardant effect, makes the degree of ceramicization higher, and can replace most of the antioxidant functions. , so there is no need to add additional antioxidants.

The contents disclosed above are only preferred feasible embodiments of the present invention, and are not intended to limit the scope of the present invention. Therefore, any equivalent technical changes made by using the contents of the description and drawings of the present invention are included in the application of the present invention. within the scope of the patent.

Z: anti-mouse ant fire-resistant fire-resistant cable 1: cable core 11: Conductor 12: Insulation layer/Fireproof tape 13: Fire belt 2: coating layer 3: Filler 501: The first layered molecular structure 502: Second layered molecular structure 503: The third layered molecular structure 600: Modified material

FIG. 1 is a schematic cross-sectional view of the structure of the rodent and ant fire-resistant and fire-resistant cable according to the present invention.

FIG. 2 is another structural schematic diagram of the rodent-ant and fire-resistant fire-resistant cable according to the present invention.

3A is a schematic diagram of the layered structure of the zirconium phosphate of the present invention.

3B is a schematic diagram of the modified intercalation of the zirconium phosphate layered structure of the present invention.

Fig. 4 is a flow chart of the manufacturing method of the rodent-ant-proof fire-resistant and fire-resistant cable of the present invention.

FIG. 5 is another structural schematic diagram of the rodent and ant fire-resistant and fire-resistant cable according to the present invention.

Z: anti-mouse ant fire-resistant fire-resistant cable

1: cable core

11: Conductor

12: Insulation layer/Fireproof tape

2: coating layer

Claims (9)

A fire-resistant and fire-resistant composition for preventing rats and ants, comprising: 100 parts by weight of a coating polymer main material; 5 to 10 parts by weight of a flame retardant; 10 to 20 parts by weight of a flame retardant filler; 0.5 to 6 parts by weight of harmful organisms A repellent; and 5 to 10 parts by weight of a multifunctional adjuvant; wherein the flame retardant includes a modified zirconium phosphate, and the modified zirconium phosphate includes a modified zirconium phosphate including a first Layered molecular structure, a second layered molecular structure, and a modified material intercalated between the first layered molecular structure and the second layered molecular structure; wherein the modified material is an organic material or inorganic material and selected from N,N-dimethylacetamide, polyhexamethylene biguanide, dodecyldimethylbenzylammonium chloride, hexachlorocyclotriphosphazene, hexaphenoxy At least one of the group consisting of cyclotriphosphazene, dicyandiamide and cetyltrimethylammonium bromide. The anti-mouse ant fire-resistant and fire-resistant composition according to claim 1, wherein the flame retardant further comprises alpha zirconium phosphate, zinc borate and ammonium polyphosphate. A mouse and ant-proof fire-resistant and fire-resistant cable, comprising: at least one cable core, which includes a conductor, at least one fireproof tape and/or an insulating layer wrapped around the conductor; and a coating layer, which covers at least one The cable core, and the coating layer comprises the rodent and ant-proof flame-retardant and fire-resistant composition according to claim 1. The rodent and ant-proof fire-resistant and fire-resistant cable according to claim 3, wherein at least one of the fireproof tapes is a mica tape, a fiber composite tape or a ceramic tape, and is wrapped around the the conductor. The rodent and ant fire-resistant fire-resistant cable according to claim 3, wherein the material of at least one of the fireproof tape and/or the insulating layer comprises 80 to 125 parts by weight of insulation Polymer host material, 80 to 185 parts by weight of ceramizer, 10 to 45 parts by weight of flux, 10 to 50 parts by weight of flame retardant, 50 to 80 parts by weight of multifunctional auxiliary, and 0 to 15 parts by weight crosslinking agent. The mouse and ant-proof fire-resistant and fire-resistant cable according to claim 3, wherein the flame retardant further comprises alpha zirconium phosphate, zinc borate and ammonium polyphosphate. A method for manufacturing a rodent and ant-proof fire-resistant and fire-resistant cable, comprising: providing a conductor, and wrapping at least one fireproof tape on the conductor in a longitudinal wrapping manner or wrapping manner; forming an insulating layer to coat at least one of the fireproof tapes to obtain at least one cable core; and to form a coating layer to coat at least one of the cable cores to obtain a rodent and ant-proof fire-resistant and fire-resistant cable; wherein, the coating layer comprises the rodent and ant-proof cable according to claim 1. Fire-resistant and fire-resistant composition. The method for manufacturing a rodent-ant-resistant, flame-resistant and fire-resistant cable according to claim 7, wherein the step of forming a coating layer to coat at least one of the cable cores is to coat a plurality of the cable cores and further fill them with a filler A space between a plurality of the cable cores. The method for manufacturing a rat and ant fire-resistant and fire-resistant cable according to claim 7, wherein the fireproof tape is a mica tape, a fiber composite tape or a ceramic tape.

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