TWI754485B - Sound insulation composition material - Google Patents
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本發明係關於一種隔音材組成物。 The present invention relates to a sound insulation material composition.
噪音污染已成為社會問題,世界衛生組織指南中提出,噪音量越大會造成人類發生高血壓的風險也會隨之提升,噪音量每增加十分貝(dB),人類的高血壓發病率就增加6%,並且影響人類的神經系統、使人急躁、易怒、影響睡眠等。噪音量以分貝(dB)來表示聲音強度的單位,噪音量範圍區分如下:40~50分貝(dB)的聲音會干擾睡眠,60~70分貝(dB)會干擾學習,120分貝(dB)以上的噪音量會導致耳痛,甚至聽力永久喪失。大部分的人會選擇使用隔音材料,並透過裝潢的方式達到隔音效果,而隔音材料有例如中國專利公告號CN100343452C「隔音的阻擋系統」,係接露至少一塊透明的丙烯酸酯玻璃板的隔音的阻擋系統,該丙烯酸酯玻璃板含有至少一根嵌入的金屬線,其中,在金屬線表面和透明的丙烯酸酯玻璃基體之間至少部分地設有一個塑料層。 Noise pollution has become a social problem. According to the World Health Organization guidelines, the greater the amount of noise, the higher the risk of high blood pressure in humans. For every decibel (dB) increase in the amount of noise, the incidence of high blood pressure in humans increases by 6. %, and affect the human nervous system, make people irritable, irritable, affect sleep, etc. The amount of noise is expressed in decibels (dB) to express the unit of sound intensity. The range of noise amount is divided as follows: 40~50 decibels (dB) will interfere with sleep, 60~70 decibels (dB) will interfere with learning, 120 decibels (dB) above The amount of noise can cause ear pain and even permanent hearing loss. Most people choose to use sound-insulating materials and achieve sound-insulating effects through decoration. The sound-insulating materials include, for example, Chinese Patent Bulletin No. CN100343452C "Soundproofing Barrier System", which is a soundproofing system that exposes at least one transparent acrylic glass plate. Barrier system, the acrylic glass plate containing at least one embedded metal wire, wherein a plastic layer is at least partially provided between the surface of the metal wire and the transparent acrylic glass substrate.
本發明提出一種隔音材組成物,包括:重量份介於80至90之間的一鐵粉,該鐵份的粒徑有65%的0.075公厘及35%的0.04公厘;重量份介於10至20之間的一高分子材料;重量份介於8至9之間的一耦合劑;重量份介於1至5之間的一相容劑,該相容劑包含一馬來酸酐接枝彈性體。 The present invention provides a sound insulation material composition, comprising: an iron powder between 80 and 90 parts by weight, the particle size of the iron part is 65% of 0.075 mm and 35% of 0.04 mm; 10 to 20 of a polymer material; 8 to 9 parts by weight of a coupling agent; 1 to 5 parts by weight of a compatibilizer, the compatibilizer comprising a maleic anhydride linkage Branch elastomer.
進一步,該鐵粉的粒徑介於0.03mm至0.05mm之間。 Further, the particle size of the iron powder is between 0.03mm and 0.05mm.
進一步,該高分子材料包含下列任一或其組合:聚乙烯、聚丙烯、ABS樹脂、乙烯/醋酸乙烯酯共聚物、聚氯乙烯。 Further, the polymer material comprises any one of the following or a combination thereof: polyethylene, polypropylene, ABS resin, ethylene/vinyl acetate copolymer, polyvinyl chloride.
進一步,該耦合劑包含下列任一或其組合:矽烷耦合劑、鈦系耦合劑。 Further, the coupling agent includes any one of the following or a combination thereof: silane coupling agent, titanium-based coupling agent.
進一步,該馬來酸酐接枝彈性體包含下列任一或其組合:聚乙烯接枝馬來酸酐、聚烯烴彈性體接枝馬來酸酐、SEBS接枝馬來酸酐。 Further, the maleic anhydride grafted elastomer comprises any one of the following or a combination thereof: polyethylene grafted maleic anhydride, polyolefin elastomer grafted maleic anhydride, SEBS grafted maleic anhydride.
進一步,包括重量份介於0.1至0.5之間的一助劑,該助劑包含下列任一或其組合:聚乙烯臘、硬脂酸醯胺、硬脂酸鋅、硬脂酸鎂、硬脂酸鈣。 Further, it includes an adjuvant between 0.1 and 0.5 parts by weight, the adjuvant comprising any of the following or a combination thereof: polyethylene wax, amide stearate, zinc stearate, magnesium stearate, stearic acid calcium.
進一步,包括重量份介於5至10之間的一阻燃劑,該阻燃劑包含一磷氮系阻燃劑。 Further, a flame retardant is included between 5 and 10 parts by weight, and the flame retardant includes a phosphorus-nitrogen-based flame retardant.
進一步,該磷氮系阻燃劑的磷含量的重量份介於18.3%至18.5%之間、該磷氮系阻燃劑的氮含量的重量份介於10.1%至10.3%之間、該磷氮系阻燃劑的平均粒徑介於3微米至6微米之間。 Further, the phosphorus content of the phosphorus-nitrogen flame retardant is between 18.3% and 18.5% by weight, the nitrogen content of the phosphorus-nitrogen flame retardant is between 10.1% and 10.3% by weight, the phosphorus The average particle size of nitrogen-based flame retardants is between 3 microns and 6 microns.
上述技術特徵具有下列之優點: The above technical features have the following advantages:
1.本發明將鐵粉、高分子材料、耦合劑及相容劑製作成隔音材組成物,透過隔音材組成物貼附於壁面、地面或天花板等建築物上,提升隔音效果。 1. In the present invention, iron powder, polymer materials, coupling agents and compatibilizers are made into sound-insulating material compositions, and the sound-insulating material compositions are attached to buildings such as walls, floors or ceilings to improve the sound-insulating effect.
2.本發明隔音材組成物添加阻燃劑,使隔音材組成物具有阻燃防火的效果。 2. The sound insulation material composition of the present invention is added with a flame retardant, so that the sound insulation material composition has the effect of flame retardant and fire prevention.
3.本發明隔音材組成物在頻率125(Hz)至4000(Hz)時,隔音效果皆可高於STC 27測試規範。 3. When the frequency of the sound insulation material composition of the present invention is from 125 (Hz) to 4000 (Hz), the sound insulation effect can be higher than the STC 27 test specification.
[第一圖]係本發明隔音材組成物與STC 27測試規範在不同頻率下的分貝曲線圖。 [The first picture] is a decibel curve diagram of the sound insulation material composition of the present invention and the STC 27 test specification at different frequencies.
綜合上述技術特徵,本發明隔音材組成物的主要功效將可於下述實施例清楚呈現。 In view of the above technical features, the main effects of the sound insulation material composition of the present invention will be clearly presented in the following examples.
本發明提出一種隔音材組成物,包括:重量份介於80至90之間的一鐵粉、重量份介於10至20之間的一高分子材料、重量份介於8至9之間的一耦合劑;重量份介於1至5之間的一相容劑、重量份介於0.1至0.5之間的一助劑、重量份介於5至10之間的一阻燃劑。 The present invention provides a sound-insulating material composition, comprising: an iron powder between 80 and 90 parts by weight, a polymer material between 10 and 20 parts by weight, and a polymer material between 8 and 9 parts by weight. A coupling agent; a compatibilizer between 1 and 5 parts by weight, an auxiliary agent between 0.1 and 0.5 parts by weight, and a flame retardant between 5 and 10 parts by weight.
該鐵粉的粒徑介於0.005公厘至0.1公厘之間,最佳該鐵粉的粒徑介於0.03公厘至0.05公厘之間,而該鐵粉的粒徑分別有65%的0.075公厘與35%的0.04公厘兩種所組成。 The particle size of the iron powder is between 0.005 mm and 0.1 mm, the optimum particle size of the iron powder is between 0.03 mm and 0.05 mm, and the particle size of the iron powder is 65% It consists of 0.075mm and 35% of 0.04mm.
該高分子材料包含下列任一或其組合:聚乙烯、聚丙烯、ABS樹脂、乙烯/醋酸乙烯酯共聚物(EVA)、聚氯乙烯。 The polymer material comprises any one of the following or a combination thereof: polyethylene, polypropylene, ABS resin, ethylene/vinyl acetate copolymer (EVA), polyvinyl chloride.
該耦合劑包含下列任一或其組合:矽烷耦合劑、鈦系耦合劑。 The coupling agent includes any one of the following or a combination thereof: silane coupling agent, titanium-based coupling agent.
該相容劑用量為該鐵粉的重量份的1%,該相容劑包含一馬來酸酐接枝彈性體,該馬來酸酐接枝彈性體包含下列任一或其組合:聚乙烯接枝馬來酸酐(PP-g-MA)、聚烯烴彈性體接枝馬來酸酐(POE-g-MA)、SEBS接枝馬來酸酐(SEBS-g-MA)。 The amount of the compatibilizer is 1% of the weight of the iron powder, the compatibilizer comprises a maleic anhydride grafted elastomer, and the maleic anhydride grafted elastomer comprises any one of the following or a combination thereof: polyethylene grafting Maleic anhydride (PP-g-MA), polyolefin elastomer grafted maleic anhydride (POE-g-MA), SEBS grafted maleic anhydride (SEBS-g-MA).
該助劑包含下列任一或其組合:聚乙烯臘(PE-WAX)、硬脂酸醯胺(EBS)、硬脂酸鋅、硬脂酸鎂、硬脂酸鈣。 The adjuvant comprises any one of the following or a combination thereof: polyethylene wax (PE-WAX), amide stearate (EBS), zinc stearate, magnesium stearate, calcium stearate.
該阻燃劑包含一磷氮系阻燃劑,該磷氮系阻燃劑的磷含量的重量份介於18.3%至18.5%之間、該磷氮系阻燃劑的氮含量的重量份介於10.1%至10.3%之間、該磷氮系阻燃劑的平均粒徑介於3微米至6微米之間。 The flame retardant comprises a phosphorus-nitrogen flame retardant, the phosphorus content of the phosphorus-nitrogen flame retardant is between 18.3% and 18.5% by weight, and the nitrogen content of the phosphorus-nitrogen flame retardant is between 18.3% and 18.5% by weight. Between 10.1% and 10.3%, the average particle size of the phosphorus-nitrogen-based flame retardant is between 3 microns and 6 microns.
上述隔音材組成物製作成的一隔音板狀結構,該隔音板狀結構厚度介於1至10公厘之間,上述隔音材組成物可運用貼附於壁面、地面或天花板等,透過上述隔音板狀結構,提升隔音效果。 A sound-insulating panel-like structure made from the above-mentioned sound-insulating material composition, the thickness of the sound-insulating panel-like structure is between 1 and 10 mm, and the above-mentioned sound-insulating material composition can be attached to a wall surface, a floor or a ceiling, etc., through the above-mentioned sound insulating The plate-like structure improves the sound insulation effect.
要說明的是,本發明採用高分子當作基材,經混摻高比例的表面改性處理鐵粉,再加上相容化耦合處理及加工助劑應用,可使高分子/鐵粉複材界面間的緻密度更加,且單位密集面密度更大,故會有更優異的隔音效能,並能夠同時提供優異的耐燃性。隔音材料之結構,主要限制空氣聲波自材料一側通過材料傳遞至另一側。藉由隔音材料之微結構需限制空氣聲波之傳遞,以防止音能進入一空間內,故隔音材料需具有微結構較緻密與較高相對密度,不同於吸音材料之微結構。隔音機制縱向聲波以音速傳播,當聲波接觸到隔音材料時,一部份聲波反射,另一部份聲波進入隔音材料內。以能量觀點而言,入射音能量大部份轉換成隔音材料之振動能量。 It should be noted that, in the present invention, the polymer is used as the base material, and a high proportion of surface-modified iron powder is mixed, coupled with the compatibilization coupling treatment and the application of processing aids, so that the polymer/iron powder can be compounded. The density between the material interfaces is higher, and the density per unit density is higher, so it will have better sound insulation performance and can provide excellent flame resistance at the same time. The structure of the sound insulation material mainly restricts the transmission of air sound waves from one side of the material to the other side through the material. The microstructure of the sound insulation material needs to limit the transmission of air sound waves to prevent sound energy from entering a space. Therefore, the sound insulation material needs to have a denser microstructure and a higher relative density, which is different from the microstructure of sound absorbing materials. Sound insulation mechanism Longitudinal sound waves travel at the speed of sound. When the sound waves contact the sound insulation material, part of the sound waves are reflected, and the other part of the sound waves enter the sound insulation material. From the energy point of view, most of the incident sound energy is converted into the vibration energy of the sound insulation material.
由表一所示,在125頻率(Hz)時,該STC 27隔音規範為11分貝(dB)、該隔音板狀結構為27.8分貝(dB);在500頻率(Hz)時,該STC 27隔音規範為27分貝(dB)、該隔音板狀結構為28.8分貝(dB);在1600頻率(Hz)時,該STC 27隔音規範為31分貝(dB)、該隔音板狀結構為34.0分貝(dB);在4000頻率(Hz)時,該STC 27隔音規範為31分貝(dB)、該隔音板狀結構為39.8分貝(dB)。上述隔音板狀結構的 頻率(Hz)由125至4000皆高於STC 27測試規範,由此可得知上述隔音板狀結構的隔音效果皆優於STC 27測試規範且皆低於40分貝(dB)至50分貝(dB)的會干擾睡眠範圍,因此可防止噪音干擾睡眠。 As shown in Table 1, at 125 frequency (Hz), the sound insulation specification of the STC 27 is 11 decibels (dB), and the sound insulation panel structure is 27.8 decibels (dB); at 500 frequency (Hz), the STC 27 sound insulation Specifications are 27 decibels (dB), the baffle is 28.8 decibels (dB); at 1600 frequency (Hz), the STC 27 noise isolation specification is 31 decibels (dB), the baffle is 34.0 decibels (dB) ); at 4000 frequency (Hz), the STC 27 sound insulation specification is 31 decibels (dB) and the sound insulation panel structure is 39.8 decibels (dB). of the above-mentioned sound-insulating panel-like structure The frequency (Hz) from 125 to 4000 is higher than the STC 27 test specification. It can be seen that the sound insulation effect of the above sound insulation panel structure is better than the STC 27 test specification and is lower than 40 decibels (dB) to 50 decibels (dB). ) will interfere with sleep range, thus preventing noise from disturbing sleep.
綜合上述實施例之說明,當可充分瞭解本發明之操作、使用及本發明產生之功效,惟以上所述實施例僅係為本發明之較佳實施例,當不能以此限定本發明實施之範圍,即依本發明申請專利範圍及發明說明內容所作簡單的等效變化與修飾,皆屬本發明涵蓋之範圍內。 Based on the descriptions of the above-mentioned embodiments, one can fully understand the operation, use and effects of the present invention, but the above-mentioned embodiments are only preferred embodiments of the present invention, which should not limit the implementation of the present invention. Scope, that is, simple equivalent changes and modifications made according to the scope of the patent application of the present invention and the contents of the description of the invention, all fall within the scope of the present invention.
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| CN1738860A (en) * | 2003-01-23 | 2006-02-22 | 三星阿托菲纳株式会社 | Sound-absorbing polypropylene resin composition containing nanoclay |
| CN102002190A (en) * | 2010-09-28 | 2011-04-06 | 南京乐金熊猫电器有限公司 | Polypropylene modified sound isolation material and preparation method thereof |
| CN104744789A (en) * | 2013-12-30 | 2015-07-01 | 比亚迪股份有限公司 | Sound and heat insulation composition and preparation method thereof |
| CN105440414A (en) * | 2015-12-29 | 2016-03-30 | 昆明钢铁控股有限公司 | Composite sound-insulation material and preparation method thereof |
| CN109233082A (en) * | 2018-08-24 | 2019-01-18 | 株洲时代新材料科技股份有限公司 | A kind of environmental protection flame retardant acoustic material and preparation method thereof, application |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1738860A (en) * | 2003-01-23 | 2006-02-22 | 三星阿托菲纳株式会社 | Sound-absorbing polypropylene resin composition containing nanoclay |
| CN102002190A (en) * | 2010-09-28 | 2011-04-06 | 南京乐金熊猫电器有限公司 | Polypropylene modified sound isolation material and preparation method thereof |
| CN104744789A (en) * | 2013-12-30 | 2015-07-01 | 比亚迪股份有限公司 | Sound and heat insulation composition and preparation method thereof |
| CN105440414A (en) * | 2015-12-29 | 2016-03-30 | 昆明钢铁控股有限公司 | Composite sound-insulation material and preparation method thereof |
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