TWI752890B - Composition of multi-element and high-efficiency far-infrared mineral base material and its production method - Google Patents

Abstract

A multi-element and high-efficiency far-infrared mineral base material, the composition of which includes SiO2, ZnO, CaO, Al2O3, Fe2O3, K2O, MgO, TiO2 and many other oxide inorganic substances with far-infrared functions, and CeO2, La2O3. Rare earth with the wavelength of life light Elements, and mixed with multi-component fly ash and raw carbon powder will have porous holes to increase drainage, water retention and bonding ability. Burn to a temperature of 1000~1360°C to form a porous structure, according to which it emits far infrared rays (life rays) with a wavelength of 8~14 microns, and achieves pore diameter, pH value, density, specific surface area, and far infrared radiation. The value of the ratio meets the characteristic requirements; and the porous structure is ground into specifications (0.85mm to nanometer scale) required by multiple applications, so as to further provide raw materials as soil conditioners.

Description

Composition of multi-element and high-efficiency far-infrared mineral base material and its production method

The present invention relates to a composition, in particular to a composition of a multi-element high-efficiency far-infrared mineral base material and a manufacturing method thereof.

Press, infrared wavelengths are electromagnetic waves between microwaves and visible light, and their efficacy and applications are quite common, and they are most commonly used in life. The growth of animals and plants has the effect of promoting, so it is called the light of life; in addition, the effect of far-infrared rays includes the release of negative ions (air vitamins), and the multi-effect shock wave causes resonance, which promotes the miniaturization of water molecules and accelerates nutrients for plants. Absorb and grow, and achieve bactericidal and bacteriostatic effects. And the effect of far-infrared shock wave can activate the molecules in the body. When its frequency is consistent with the movement frequency between the molecules and atoms formed by the cell body, the energy will be absorbed by the biological cells, resulting in a resonance effect, which is in line with the biological and physical properties. , chemical properties and other requirements.

Second, at present, agriculture all over the world is facing the problem of soil hardening caused by long-term use of fertilizers, and plants are not easy to grow. In addition, the soil will accumulate water in case of heavy rains for several days, causing the roots of plants to rot and even die. , the excess water will be discharged, and the dew absorbed by the plant leaves will also be absorbed by the calcined soil, so the calcined soil has a moisturizing effect on the soil. Furthermore, calcined soil can release negative ions to drive away anaerobic pests in the soil, thereby reducing the use of pesticides.

Press again, the main contents of the multi-layer far-infrared calcined clay include more than one metal, non-metal and pottery clay to be mixed, and after a high temperature calcination, the aforementioned metal and non-metallic substances can be mixed with each other. The combination of pottery and clay; however, during the calcination process, the degree of oxidation of the metal is different, and the wavelength of the far-infrared rays produced by the metal will also be different, so it will be difficult to control the wavelength of the light that produces life; moreover, the above-mentioned composition is calcined at high temperature. Afterwards, it is impossible to control the pore diameter, pH value, density, and far-infrared emissivity to meet the characteristic requirements; therefore, the effectiveness of this multi-layer far-infrared calcined soil for soil improvement and plant growth promotion is questionable.

The reason is that the main purpose of the present invention is to provide the wavelength of life rays that can be emitted, and to achieve the pore diameter, pH value, density, specific surface area, and far-infrared emissivity values that meet the characteristic requirements, so that it can be effectively used in soil improvement. And a multi-element high-efficiency far-infrared mineral substrate that promotes plant growth.

In order to achieve the above-mentioned purpose, the composition of the present invention includes a plurality of inorganic oxides, rare earth elements, fly ash and raw carbon powder; wherein, the inorganic oxides can generate far-infrared wavelengths, the rare earth elements have the wavelength of life rays, and the fly ash The raw carbon powder has porous holes, which can increase drainage, water retention, air permeability and adhesion; its composition and its weight percentage are: silicon dioxide (SiO2) 35~58%, iron oxide (Fe2O3) 10~20% %, calcium oxide (CaO) 3～10%, aluminum oxide (Al2O3) 3～5%, zinc oxide (ZnO) 1～5%, potassium oxide (K2O) 3～5%, magnesium oxide (MgO) 1～3% %, fly ash 14~30%, green carbon powder 5~10%, titanium dioxide (TiO2) 1~5%, cerium oxide (CeO2) 0.5~1%, and lanthanum oxide (La2O3) 0.1~0.5%; the aforementioned composition After mixing and positioning and shaping, the porous structure is formed by high temperature calcination. The porous structure has a pore diameter of 0.2~0.8 microns, a pH of 6.5~8.5, a density of 0.4~0.6 g/ml, and a specific surface area of 80~ 100 square meters/g, and the far-infrared radiation rate is over 86%.

According to the features disclosed above, in the present invention, the optimum weight percent of the composition is: silicon dioxide (SiO ) 50-51%, iron oxide (Fe O ) 14.8-15%, calcium oxide (CaO) 3%, aluminum oxide ( Al2O3) 4.2~5%, zinc oxide (ZnO) 1~1.5%, potassium oxide (K2O) 3~3.5%, magnesium oxide (MgO) 1%, fly ash 14~15%, raw carbon powder 5%, titanium dioxide (TiO2) 1 to 1.5%, cerium oxide (CeO2) 0.6 to 0.7%, and lanthanum oxide (La2O3) 0.1%; the aforementioned compositions will form porous structures after mixing and positioning molding and high temperature calcination, and the The far-infrared radiation rate of the porous structure can reach more than 94%.

According to the features disclosed above, in the present invention, the manufacturing method of the multi-element high-efficiency far-infrared mineral base material is completed through the following steps according to the composition ratio, including: a). B) Crushing: Use crushing equipment to make the mineral raw materials of the composition into powder; c). Screening: Use screening equipment to screen the above powder to a suitable particle size ; d). Composition preparation: prepare the composition of suitable particle size according to the required ratio; e). Proportion mixing: use mixing equipment to stir the completed composition to form a mixture; f). Positioning Molding: Press the above-mentioned mixture to form a billet by setting equipment; g). Precision calcining: Use a calcining furnace to heat the above-mentioned billet to a temperature of 1000~1360 ° C, so that the viscosity of the aluminum element is suppressed. Eliminate, and then form porous structures; h). High energy detection: use testing equipment to measure the above porous structures to ensure that they reach pore diameter of 0.2~0.8 microns, pH 6.5~8.5, density 0.4~0.6 g/ml, specific surface area of 80~100 square meters/g; i). Classification and pulverization: use pulverization equipment to make the qualified multi-porous structure into powder; j). Nano-grinding: use dry nanometer The rice grinding equipment grinds the above-mentioned powders into various specifications (0.85mm to nanometer grade), and makes a multi-functional and high-efficiency far-infrared mineral base material to further provide raw materials for soil conditioners.

According to the aforementioned features, the crushing equipment in the present invention is a multi-cylinder hydraulic cone crusher.

According to the features disclosed above, the screening equipment in the present invention is a trommel mobile screening machine.

The "multiple and high-efficiency far-infrared mineral substrate" of the present invention, its composition includes SiO2, ZnO, CaO, Al2O3, Fe2O3, K2O, MgO, TiO2 and many other oxide inorganic substances with far-infrared functions, and CeO2, La2O3 with life rays The rare earth element of wavelength, after precise calcination, its porous structure will radiate the life light of 8～14 microns wavelength accordingly, and the growth of animals and plants has the effect of promoting; Since the values of pore size, PH value, density and specific surface area meet the characteristic requirements, using it as the raw material of soil conditioner has the following benefits: (1) it can become an excellent planting bed for probiotics, (2) it can make the soil oxygenated (3) As a porous soil conditioner, it has good drainage, water retention and moisturizing effects. Its drainage rate is 100% and the water retention rate is as high as 80%. (4) It can improve soil compaction and hardening, ( 5) It can form a balanced microbial phase. (6) Far-infrared soil conditioner has multiple effect shock waves, which can cause resonance, promote the miniaturization of water molecules, accelerate the absorption and growth of plants, and achieve sterilization and bacteriostasis. effect, thereby enhancing plant vitality.

The following describes the implementation of the present invention through specific embodiments, and those skilled in the art can easily understand other advantages and effects of the present invention from the contents disclosed in this specification. The present invention can also be implemented or applied by other different specific embodiments, and various details in this specification can also be modified and changed based on different viewpoints and applications without departing from the spirit of the present invention.

The manufacturing steps of the “multiple and high-efficiency far-infrared mineral substrate” of the present invention are shown in FIG. 1; it includes: a). Preliminary screening: It is to carry out the preliminary screening of the base material of the mineral raw materials of each composition; b). Crushing: It is to use crushing equipment to make the mineral raw materials of the composition into powder; c). Screening: the above-mentioned powders are screened to the appropriate particle size by the use of screening equipment; d). Preparation of composition materials: the composition of suitable particle size is prepared according to the required ratio; e). Proportional mixing: it uses mixing equipment to agitate the finished composition to form a mixture; f). Positioning and molding: the above-mentioned mixture is pressed and formed into a blank by the application of setting equipment; g). Precision calcining: the above-mentioned billet is heated to a temperature of 1000~1360 ℃ by a calcining furnace, so that the viscous effect of the aluminum element is eliminated, and then a porous structure is formed; h). High-energy detection: It is to use detection equipment to measure the above-mentioned porous structures to ensure that they achieve qualitative and quantitative results; i). Classification and crushing: It is to use crushing equipment to make the qualified porous structure into powder; j). Nano-grinding: Dry nano-grinding equipment is used to grind the above-mentioned powders into specifications (0.85mm to nano-scale) required for various applications, and to make multi-component high-efficiency far-infrared mineral substrates to further provide post-processing It is used as the raw material of soil conditioner.

Continuing from the above, in the above-mentioned step d). In the preparation of the composition, the composition includes a plurality of oxidized inorganic substances that can generate far-infrared wavelengths, rare earth elements with the wavelength of life rays, and porous holes to increase drainage, water retention, air permeability and Adhesive fly ash and raw carbon powder; and the multi-element high-efficiency far-infrared mineral substrate of the present invention, its composition and its weight percentage are further shown in FIG. 2, including: silicon dioxide (SiO2) 35~58%, Iron Oxide (Fe2O3) 10~20%, Calcium Oxide (CaO) 3~10%, Alumina (Al2O3) 3~5%, Zinc Oxide (ZnO) 1~5%, Titanium Dioxide (TiO2) 1~5%, Oxide Cerium (CeO2) 0.5~1%, Lanthanum oxide (La2O3) 0.1~0.5%, Magnesium oxide (MgO) 1~3%, Potassium oxide (K2O) 3~5%, raw carbon powder 5~10%, and pulverized coal Ash 14~30%; moreover, the aforementioned step h). High energy detection, then to ensure that it must reach pore size of 0.2~0.8 microns, pH 6.5~8.5, density 0.4~0.6 g/ml, specific surface area 80~100 m2/g, and the far-infrared radiation rate is more than 86%.

In the present invention, the aforementioned constituents are mixed and combined into base materials of different proportions according to different weight percentages, and after positioning molding and precision calcination at 1000～1360° C., the far-infrared radiation rate thereof is detected, as shown in the following table: In order to select more representative 10 groups of substrates according to the experimental method of 100 groups, the ratio of the composition and the comparison of the emissivity: Substrate/Comparative Group Comparison group (1) Comparison group (2) Comparison group (3) Comparison group (4) Comparison group (5) Comparison group (6) Comparison group (7) Comparison group (8) Comparison group (9) Comparison group (10) silica 41 43 43 45 47 48 50 51 53 55 Iron oxide 16.5 17 13 14 14 15 14.8 15 13 12.4 Calcium Oxide 4 4 5 3 5 3 3 3 3 3 Alumina 3.5 4 4 3 3 4 5 4.2 3.2 3 Zinc oxide 2 2 3 3.5 3.5 2.5 1.5 1 2 2 Potassium oxide 3 3 5 4 3 3 3 3.5 3 3 Magnesium oxide 3 3 2.5 2.5 2 1.5 1 1 1 1 fly ash 20 18 17 16 14 15 15 14 14 14 raw toner 5 5 5 5 5 5 5 5 5 5 Titanium dioxide 1 1 1.5 3 2.5 2 1 1.5 2 1 Ceria 0.7 0.7 0.7 0.5 0.6 0.8 0.6 0.7 0.5 0.5 Lanthanum oxide 0.3 0.3 0.3 0.5 0.4 0.2 0.1 0.1 0.3 0.1 Emissivity% 86.3 88.7 87.9 87.4 89.6 94.3 95.2 94.8 91.3 88.6 **This table selects 10 representative groups from 100 groups according to the experimental plan method for reference and comparison

Comparing the emissivity of each group in the table above, it can be seen that the 7th and 8th groups have the highest emissivity, and the composition ratio of the 7th group is: silicon dioxide (SiO2) 50%, iron oxide (Fe2O3) 14.8% , calcium oxide (CaO) 3%, aluminum oxide (Al2O3) 5%, zinc oxide (ZnO) 1.5%, potassium oxide (K2O) 3% , magnesium oxide (MgO) 1%, fly ash 15%, raw carbon powder 5%, titanium dioxide (TiO2) 1%, cerium oxide (CeO2) 0.6%, and lanthanum oxide (La2O3) 0.1%, the far-infrared The emissivity will reach 95.2%; and the composition ratio of group 8 is: silicon dioxide (SiO2) 51%, iron oxide (Fe2O3) 15%, calcium oxide (CaO) 3%, aluminum oxide (Al2O3) 4.2 %, zinc oxide (ZnO) 1%, potassium oxide (K2O) 3.5%, magnesium oxide (MgO) 1%, fly ash 14%, green carbon powder 5%, titanium dioxide (TiO2) 1.5%, cerium oxide (CeO2) 0.7%, and lanthanum oxide (La2O3) 0.1%, the far-infrared radiation rate will reach 95.2% after testing; Furthermore, from the composition ratios of the two groups with the highest radiation rate, the best composition is sorted out. The weight percentages are: silicon dioxide (SiO2) 50~51%, iron oxide (Fe2O3) 14.8~15%, calcium oxide (CaO) 3%, aluminum oxide (Al2O3) 4.2~5%, zinc oxide (ZnO) 1~ 1.5%, potassium oxide (K2O) 3~3.5%, magnesium oxide (MgO) 1%, fly ash 14~15%, green carbon powder 5%, titanium dioxide (TiO2) 1~1.5%, cerium oxide (CeO2) 0.6 ~0.7%, and lanthanum oxide (La2O3) 0.1%; and the aforementioned composition will form a porous structure after mixing and positioning molding and high-temperature calcination, and the far-infrared emission rate of the porous structure can reach 94% above.

Bearing the above, the aforementioned crushing equipment is a multi-cylinder hydraulic cone crusher; when it works, it drives the coupling, the transmission shaft and the cone part through the rotation of the motor, and makes the eccentric shaft do periodic swing motion under the axis line ; After the material enters the crushing chamber from the feeding port, it is crushed by the mutual impact of the eccentric shaft and the rolling mortar wall, grinding, and rubbing. In addition, the aforementioned screening equipment is a drum mobile screening machine; its mechanism is mainly composed of a motor, a reducer, a drum device, a frame, and an inlet and outlet; the drum device is installed obliquely on the frame, and the motor is decelerated. The machine is connected with the drum device, and the drum device is driven to rotate around its axis. When the material enters the drum device, the material is screened by the centrifugal force and jigging action of the drum rotation. Due to the inclination and rotation of the drum device, the screen surface is The material is turned and rolled, so that the qualified material is discharged through the screen on the outer circle of the drum, and the unqualified material is discharged through the end of the drum.

As shown in FIG. 3, it is a schematic diagram of the finished product after positioning molding and precision calcining in the present invention; the above figure shows that the composition of the mixture is pressed by a setting equipment to form a blank 10, because the composition is passed through a coarse screen before pressing. , crushing and sieving process, so the surface of the blank 10 is very fine and smooth; and the following figure shows that the positioning and shaping blank 10 is heated to a temperature of 1000~1360 ℃ in a calcining furnace, then the composition The viscous effect of the aluminum element disappears, thereby forming a porous structure 20, and its pore diameter 21 will reach the characteristic requirements of 0.2 to 0.8 microns; moreover, the multi-element high-efficiency far-infrared mineral base material of the present invention forms as many as The photo of the pore structure magnified by 2,000 times is shown in Figure 4A, the magnification of 1,000 times is shown in Figure 4B, and the magnification of 500 times is shown in Figure 4C; this photo was commissioned by the Materials and Engineering Laboratory of the Industrial Technology Research Institute, a consortium Using an electron microscope, for the multi-element high-efficiency far-infrared mineral substrate of the present invention, the pore structure shown in the photo has a pore diameter of 0.2-0.8 microns, which will emit wavelengths of 8-14 microns. Infrared rays (life rays), which in turn have the effect of promoting the growth of animals and plants.

Because in the present invention, its composition includes a number of oxide inorganic substances with far-infrared function, and rare earth elements with the wavelength of life light, so after precision calcination, the porous structure will emit 8-14 microns wavelength accordingly. The light of life can promote the growth of animals and plants; the far-infrared rays emitted also include the release of negative ions, and the multi-effect shock wave causes resonance, which promotes the miniaturization of water molecules, accelerates the absorption and growth of plants, and achieves sterilization. , Antibacterial effect. Furthermore, the multi-element and high-efficiency far-infrared mineral base material, because the values of pore diameter, pH value, density, and specific surface area meet the characteristic requirements, it is used as the raw material of soil conditioner, and has (1) excellent plants that can become probiotics. (2) high oxygen content in the soil, (3) as a porous soil conditioner, with good drainage, water retention and moisturizing effects, its drainage rate is 100%, and the water retention rate is also as high as 80%, (4 ) can improve soil compaction and hardening, (5) can form a balanced microbial phase, (6) far-infrared soil conditioner, with multi-effect shock waves, can cause resonance, promote the miniaturization of water molecular clusters, and accelerate nutrient absorption by plants. Growth, and achieve the effect of bactericidal, antibacterial, and then enhance the vitality of plants.

To sum up, the technical means disclosed in the present invention do meet the requirements for invention patents such as "novelty", "progressiveness", "environmental protection" and "availability for industrial use". Encourage invention, no sense of morality.

However, the drawings and descriptions disclosed above are only preferred embodiments of the present invention. For those who are familiar with the art, modifications or equivalent changes made in accordance with the spirit of this case should still be included in the within the scope of the patent application in this case.

10: Blanks

20: Porous structure

21: Pore size

FIG. 1 is a block diagram showing the steps of the manufacturing method of the present invention. Figure 2 is a schematic diagram of the weight percentage of the composition in the present invention. FIG. 3 is a schematic diagram of the finished product of the present invention after positioning molding and precision calcination. 4A to 4C are electron microscope images of the porous structure of the present invention.

Claims (5)

A multi-element high-efficiency far-infrared mineral base material, its composition and its weight percentage are: silicon dioxide (SiO2) 35～58%, iron oxide (Fe2O3) 10～20%, calcium oxide (CaO) 3～10%, Alumina (Al2O3) 3~5%, zinc oxide (ZnO) 1~5%, potassium oxide (K2O) 3~5%, magnesium oxide (MgO) 1~3%, fly ash 14~30%, and raw materials Carbon powder 5~10%, titanium dioxide (TiO2) 1~5%, cerium oxide (CeO2) 0.5~1%, and lanthanum oxide (La2O3) 0.1~0.5%; After the composition is mixed and positioned and molded, it is calcined at a high temperature to form a porous structure, the porous structure has a pore diameter of 0.2-0.8 microns, a pH of 6.5-8.5, a density of 0.4-0.6 g/ml, and a ratio of 0.4 to 0.6 g/ml. The surface area is 80~100 square meters/g, and the far-infrared radiation rate is over 86%. The multi-element and high-efficiency far-infrared mineral substrate described in the first item of the patent application scope, wherein, the optimum weight percentage of the composition is: silicon dioxide (SiO2) 50-51%, iron oxide (Fe2O3) 14.8-15% %, calcium oxide (CaO) 3%, alumina (Al2O3) 4~5%, zinc oxide (ZnO) 1~1.5%, potassium oxide (K2O) 3~3.5%, magnesium oxide (MgO) 1%, pulverized coal Ash 14~15%, green carbon powder 5%, titanium dioxide (TiO2) 1~1.5%, cerium oxide (CeO2) 0.6~0.7%, and lanthanum oxide (La2O3) 0.1%; the composition is mixed and positioned to shape After high temperature calcination, a porous structure is formed, and the far-infrared radiation rate of the porous structure will reach more than 94%. A method for producing a multi-element and high-efficiency far-infrared mineral base material, which is completed through the following steps according to the composition ratio described in item 1 of the patent application scope, comprising: a). Preliminary screening: perform preliminary screening of the raw material base materials of the mineral soil of the composition; b). Crushing: use crushing equipment to make the mineral raw materials of the composition into powder; c). Screening: use screening equipment to screen the above-mentioned powder to a suitable particle size; d). Preparation of ingredients: prepare ingredients of suitable particle size according to the required ratio; e). Proportional mixing: use mixing equipment to stir the finished composition to form a mixture; f). Positioning and shaping: the above-mentioned mixtures are pressed together to form blanks by means of shaping equipment; g). Precision calcining: the above-mentioned billet is heated to a temperature of 1000～1360 ℃ by a calcining furnace, so that the viscous effect of aluminum element is eliminated, and then a porous structure is formed; h). High-energy detection: use detection equipment to measure the above-mentioned porous structures to ensure that they have a pore diameter of 0.2~0.8 microns, pH 6.5~8.5, density 0.4~0.6 g/ml, specific surface area 80~100 m2/g, and the far-infrared radiation rate is more than 86%; i). Classification and crushing: use crushing equipment to make the porous structure that has passed the test into powder; and j). Nano-grinding: Use dry nano-grinding equipment to grind the above-mentioned powders into specifications (0.85mm to nano-grade) for various application requirements, and make multi-component high-efficiency far-infrared mineral substrates to further provide back-end As a raw material for soil conditioners. The method for manufacturing a multi-element and high-efficiency far-infrared mineral base material as described in item 3 of the scope of the patent application, wherein the crushing equipment is a multi-cylinder hydraulic cone crusher. The method for manufacturing a multi-element and high-efficiency far-infrared mineral base material as described in item 4 of the scope of the patent application, wherein the screening equipment is a tumble mobile screening machine.

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