TWI639369B - Method for manufacturing a layer of dual-axis circuit pattern and electronic device - Google Patents
Method for manufacturing a layer of dual-axis circuit pattern and electronic device Download PDFInfo
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- TWI639369B TWI639369B TW105126757A TW105126757A TWI639369B TW I639369 B TWI639369 B TW I639369B TW 105126757 A TW105126757 A TW 105126757A TW 105126757 A TW105126757 A TW 105126757A TW I639369 B TWI639369 B TW I639369B
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Abstract
本發明公開一種單層雙軸向電路圖案之製作方法,包括以下步驟:形成一觸媒圖案層於一基板上,其中所述觸媒圖案層包括至少兩個沿第一軸向排列的第一觸媒結構單元及至少兩個沿第二軸向排列的第二觸媒結構單元;形成一第一橋接件用以連接兩個所述第一觸媒結構單元;形成一絕緣層用以覆蓋所述第一橋接件;於所述絕緣層上形成一第二橋接件用以連接兩個所述第二觸媒結構單元;以及利用無電鍍製程於兩個所述第一觸媒結構單元及兩個所述第二觸媒結構單元上鍍覆一層金屬。 The invention discloses a method for fabricating a single-layer biaxial circuit pattern, comprising the steps of: forming a catalyst pattern layer on a substrate, wherein the catalyst pattern layer comprises at least two first rows arranged along a first axis a catalyst structure unit and at least two second catalyst structure units arranged along the second axis; forming a first bridge member for connecting the two first catalyst structure units; forming an insulation layer for covering the a first bridge member; a second bridge member formed on the insulating layer for connecting the two second catalyst structure units; and an electroless plating process for the two of the first catalyst structure units and two The second catalyst structural unit is plated with a layer of metal.
Description
本發明是涉及一種電路圖案之製作方法,且特別是涉及一種單層雙軸向電路圖案之製作方法,以及具有利用此方法所製成的內部電路圖案的電子裝置。 The present invention relates to a method of fabricating a circuit pattern, and more particularly to a method of fabricating a single layer biaxial circuit pattern, and an electronic device having an internal circuit pattern formed by the method.
現今消費性電子產品的市場中,可攜式電子產品諸如個人數位助理(PDA)、行動電話(mobile Phone)、筆記型電腦(notebook)、平板電腦(tablet PC)等,均使用觸控面板(touch panel)作為其資料溝通的界面工具。此外,由於這類的電子產品的設計方向以輕、薄為為主,因此在產品的設計上會希望能省略如鍵盤、滑鼠等傳統的輸入裝置,尤其在講求人性化設計的平板電腦需求的帶動下,觸控面板儼然已成為新的使用者介面而一躍成為關鍵的零組件之一。 In today's consumer electronics market, portable electronic products such as personal digital assistants (PDAs), mobile phones, notebooks, tablet PCs, etc. all use touch panels ( Touch panel) as an interface tool for data communication. In addition, since the design direction of such electronic products is mainly light and thin, it is hoped that the traditional input devices such as keyboards and mice can be omitted in the design of the products, especially in the demand for tablet computers with humanized design. Driven by this, the touch panel has become a new user interface and has become one of the key components.
目前常見的投射電容式觸控面板(Projective Capacitive Touch Panel)的結構中,大致上可分為以下幾種類型:玻璃/薄膜/薄膜(Glass/Film/Film)、玻璃/薄膜(Glass/Film)、單玻璃解決方案(One Glass Solution,OGS)、及單薄膜解決方案(One Film Solution,OFS)。在觸控電極的佈局設計上,常見為單層雙軸向觸控感測結構(Single ITO,SITO),或是單層上下雙面觸控感測結構(Double ITO,DITO)。而在SITO結構中,為使X/Y軸向電極跨接(橋接) 而不產生信號短路,通常在軸向串列的橋接處設計絕緣層,並在絕緣層上在形成橋接導線,使觸控信號得以傳遞,並使X/Y的軸向的觸控感測電極不致產生干擾誤判。 The structure of the currently popular Projective Capacitive Touch Panel can be roughly classified into the following types: glass/film/film (Glass/Film/Film), glass/film (Glass/Film). , One Glass Solution (OGS), and One Film Solution (OFS). In the layout design of the touch electrodes, a single-layer dual-axis touch sensing structure (Single ITO, SITO) or a single-layer upper and lower double-sided touch sensing structure (Double ITO, DITO) is commonly used. In the SITO structure, the X/Y axial electrodes are bridged (bridged). Without generating a signal short circuit, an insulating layer is usually designed at the bridge of the axial series, and a bridge wire is formed on the insulating layer to transmit the touch signal, and the X/Y axial touch sensing electrode is provided. No interference and misjudgment will occur.
在觸控面板之製造過程中,經常使用鍍膜製程來形成金屬層或透明導電層,並搭配微影暨蝕刻製程(包括光阻塗佈、曝光、顯影、蝕刻、去光阻等步驟)將金屬層或透明導電層圖案化,以形成單層雙軸向觸控感測結構。然而,傳統的圖案化過程過於繁複且製造成本較高,尤其在進行多道曝光顯影製程後,容易導致蝕刻穩定度與蝕刻品質不易控制,使觸控面板的良率受影響。 In the manufacturing process of the touch panel, a coating process is often used to form a metal layer or a transparent conductive layer, and the metal is combined with a lithography and etching process (including photoresist coating, exposure, development, etching, photoresist removal, etc.). The layer or transparent conductive layer is patterned to form a single layer biaxial touch sensing structure. However, the conventional patterning process is too complicated and the manufacturing cost is high. Especially after the multi-pass exposure and development process, the etching stability and the etching quality are easily controlled, and the yield of the touch panel is affected.
有鑑於現有技術存在之缺失,本發明人遂以其多年從事相關領域的設計及製造經驗,並積極地研究如何能在有限的資源及時間下將導電薄膜圖案化,終於在各方條件的審慎考量下開發出本發明。 In view of the lack of prior art, the inventors have been engaged in design and manufacturing experience in related fields for many years, and actively studied how to pattern conductive films under limited resources and time, and finally prudently in all conditions. The present invention has been developed in consideration.
本發明從提高生產效益的角度出發,主要目的在於提供一種可有效降低製程困難度與製程成本的單層雙軸向電路圖案之製作方法,以及具有利用此方法所製成的內部電路圖案的電子裝置。 The invention aims to provide a method for manufacturing a single-layer biaxial circuit pattern capable of effectively reducing process difficulty and process cost, and an electronic having an internal circuit pattern formed by the method, from the viewpoint of improving production efficiency. Device.
根據本發明之一較佳實施例,所述單層雙軸向電路圖案之製作方法包括以下步驟:形成一觸媒圖案層於一基板上,其中所述觸媒圖案層包括至少兩個沿第一軸向排列的第一觸媒結構單元及至少兩個沿第二軸向排列的第二觸媒結構單元,所述第二軸向與所述第一軸向大致垂直;形成一第一橋接件用以連接兩個所述第一觸媒結構單元;形成一絕緣層用以覆蓋所述第一橋接件;於所述絕緣層上形成一第二橋接件用以連接兩個所述第二觸媒結構單元;以及利用無電鍍製程於兩個所述第一觸媒結構單元及兩個所述第二觸媒結構單元上鍍覆一層金屬,其中兩個所述第一觸媒結構單元及兩個所述第二觸媒結構單元中之觸媒能觸發金屬離子還 原沉積。 According to a preferred embodiment of the present invention, the method for fabricating the single-layer biaxial circuit pattern includes the steps of: forming a catalyst pattern layer on a substrate, wherein the catalyst pattern layer includes at least two An axially aligned first catalyst structural unit and at least two second catalytic structural units arranged along the second axial direction, the second axial direction being substantially perpendicular to the first axial direction; forming a first bridge a member for connecting two of the first catalyst structure units; forming an insulating layer for covering the first bridge member; forming a second bridge member on the insulating layer for connecting the two second portions a catalyst structure unit; and plating a layer of metal on the two first catalyst structure units and the two catalyst structure units by using an electroless plating process, wherein the two first catalyst structure units and The catalyst in the two second catalyst structural units can trigger metal ions Original deposit.
根據本發明之另一較佳實施例,所述單層雙軸向電路圖案之製作方法包括以下步驟:形成至少兩個沿第一軸向排列的第一觸媒結構單元於一基板上;形成一第一橋接件用以連接兩個所述第一觸媒結構單元;形成一絕緣層於用以覆蓋所述第一橋接件;形成至少兩個沿第二軸向排列的第二觸媒結構單元於所述基板上,所述第二軸向與所述第一軸向大致垂直;於所述絕緣層上形成一第二橋接件用以連接兩個所述第二觸媒結構單元;以及利用無電鍍製程於兩個所述第一觸媒結構單元及兩個所述第二觸媒結構單元上鍍覆一層金屬,其中兩個所述第一觸媒結構單元及兩個所述第二觸媒結構單元中之觸媒能觸發金屬離子還原沉積。 According to another preferred embodiment of the present invention, the method for fabricating the single-layer biaxial circuit pattern includes the steps of: forming at least two first catalyst structural units arranged along the first axial direction on a substrate; forming a first bridge member for connecting the two first catalyst structure units; an insulating layer for covering the first bridge member; and at least two second catalyst structures arranged along the second axial direction Unit on the substrate, the second axial direction is substantially perpendicular to the first axial direction; forming a second bridge on the insulating layer for connecting the two second catalyst structural units; Coating a layer of metal on the two first catalyst structural units and the two second catalytic structural units by an electroless plating process, wherein the two first catalytic structural units and the two second The catalyst in the catalytic unit can trigger metal ion reduction deposition.
根據本發明之再一較佳實施例,所述電子裝置使用一帶有單層雙軸向電路圖案的結構件,其特徵在於,所述帶有單層雙軸向電路圖案的結構件包括一基板、至少兩個第一導電結構單元、一第一橋接件、一絕緣層、至少兩個第二導電結構單元以及一第二橋接件。兩個所述第一導電結構單元沿第一軸向排列於所述基板上,其中每一所述第一導電結構單元包括一第一觸媒結構單元與一覆蓋於所述第一觸媒結構單元表面的一部分的金屬薄膜;所述第一橋接件由任一所述第一觸媒結構單元的前緣延伸至另一所述第一觸媒結構單元的前緣;所述絕緣層覆蓋於所述第一橋接件的表面;兩個所述第二導電結構單元沿與所述第一軸向大致垂直的第二軸向排列於所述基板上,其中每一所述第二導電結構單元包括一第二觸媒結構單元與一覆蓋於所述第二觸媒結構單元表面的一部分的金屬薄膜;所述第二橋接件由任一所述第二觸媒結構單元的前緣延伸跨過所述絕緣層至另一所述第二觸媒結構單元的前緣。 According to still another preferred embodiment of the present invention, the electronic device uses a structural member having a single-layer biaxial circuit pattern, wherein the structural member having a single-layer biaxial circuit pattern includes a substrate At least two first conductive structural units, a first bridge, an insulating layer, at least two second conductive structural units, and a second bridge. Two of the first conductive structural units are arranged on the substrate along a first axial direction, wherein each of the first conductive structural units comprises a first catalytic structure unit and a first catalyst structure a metal film of a portion of the surface of the cell; the first bridge extending from a leading edge of any of the first catalyst structural units to a leading edge of another of the first catalyst structural units; the insulating layer covering a surface of the first bridge member; two of the second conductive structural units are arranged on the substrate along a second axial direction substantially perpendicular to the first axial direction, wherein each of the second conductive structural units a second catalyst structure unit and a metal film covering a portion of a surface of the second catalyst structure unit; the second bridge member extending across a leading edge of any of the second catalyst structure units The insulating layer is to a leading edge of another of the second catalyst structural units.
本發明至少具有以下有益效果:本發明實施例所提供的單層雙軸向電路圖案之製作方法透過“同時印刷形成沿第一軸向排列 的第一觸媒結構單元及沿第二軸向排列的第二觸媒結構單元,而後再利用無電鍍製程於第一和第二觸媒結構單元的外表面上沉積一層金屬薄膜”以及“先後印刷形成沿第一軸向排列的第一觸媒結構單元及沿第二軸向排列的第二觸媒結構單元,而後再利用無電鍍製程於第一和第二觸媒結構單元的外表面上沉積一層金屬薄膜”的流程設計,可有效將繁複、耗時的製程步驟精簡化,以降低製程困難度及提升製程良率。 The present invention has at least the following beneficial effects: the method for fabricating the single-layer biaxial circuit pattern provided by the embodiment of the present invention is arranged by "simultaneous printing to form along the first axial direction. a first catalyst structure unit and a second catalyst structure unit arranged along the second axis, and then depositing a metal film on the outer surface of the first and second catalyst structure units by using an electroless plating process and Printing forms a first catalyst structural unit arranged along the first axial direction and a second catalytic structural unit arranged along the second axial direction, and then using an electroless plating process on the outer surfaces of the first and second catalytic structural units The process of depositing a layer of metal film can effectively simplify complicated and time-consuming process steps to reduce process difficulty and improve process yield.
為使能更進一步瞭解本發明之特徵及技術內容,請參閱以下有關本發明之詳細說明與附圖,但是此等說明與所附圖式僅係用來說明本發明,而非對本發明的權利範圍作任何的限制。 The detailed description of the present invention and the accompanying drawings are to be understood by the claims The scope is subject to any restrictions.
S101~S105‧‧‧步驟 S101~S105‧‧‧Steps
S201~S206‧‧‧步驟 S201~S206‧‧‧Steps
100‧‧‧帶有單層雙軸向電路圖案的結構件 100‧‧‧Structural parts with single-layer biaxial circuit pattern
1‧‧‧觸媒圖案層 1‧‧‧catalyst pattern layer
11‧‧‧第一觸媒結構單元 11‧‧‧First Catalyst Structure Unit
11’‧‧‧第一導電結構單元 11'‧‧‧First Conductive Structural Unit
12‧‧‧第二觸媒結構單元 12‧‧‧Second catalyst structural unit
12’‧‧‧第二導電結構單元 12'‧‧‧Second conductive structural unit
13‧‧‧平坦層 13‧‧‧flat layer
2‧‧‧基板 2‧‧‧Substrate
3‧‧‧第一橋接件 3‧‧‧First bridge
4‧‧‧絕緣層 4‧‧‧Insulation
5‧‧‧第二橋接件 5‧‧‧Second bridge
M‧‧‧金屬層 M‧‧‧ metal layer
D‧‧‧段差結構 D‧‧‧ step structure
圖1為本發明第一實施例之單層雙軸向電路圖案之製作方法的流程圖。 1 is a flow chart showing a method of fabricating a single-layer biaxial circuit pattern according to a first embodiment of the present invention.
圖2A至圖2E為本發明第一實施例之單層雙軸向電路圖案之製作方法之第一種實施方式的製程示意圖。 2A to 2E are schematic diagrams showing a process of a first embodiment of a method for fabricating a single-layer biaxial circuit pattern according to a first embodiment of the present invention.
圖3為圖2中沿Ⅲ-Ⅲ的剖面圖。 Figure 3 is a cross-sectional view taken along line III-III of Figure 2.
圖4A至圖4E為本發明第一實施例之單層雙軸向電路圖案之製作方法之第二種實施方式的製程示意圖。 4A to 4E are schematic diagrams showing a process of a second embodiment of a method for fabricating a single-layer biaxial circuit pattern according to a first embodiment of the present invention.
圖5為圖4中沿V-V的剖面圖。 Figure 5 is a cross-sectional view taken along line V-V of Figure 4;
圖6A至圖6E為本發明第一實施例之單層雙軸向電路圖案之製作方法之第三種實施方式的製程示意圖。 6A-6E are schematic diagrams showing processes of a third embodiment of a method for fabricating a single-layer biaxial circuit pattern according to a first embodiment of the present invention.
圖7為圖6中沿Ⅶ-Ⅶ的剖面圖。 Figure 7 is a cross-sectional view taken along line VII-VII of Figure 6.
圖8A至圖8E為本發明第一實施例之單層雙軸向電路圖案之製作方法之第四種實施方式的製程示意圖。 8A to 8E are schematic diagrams showing processes of a fourth embodiment of a method for fabricating a single-layer biaxial circuit pattern according to a first embodiment of the present invention.
圖9為本發明第二實施例之單層雙軸向電路圖案之製作方法的流程圖。 9 is a flow chart showing a method of fabricating a single-layer biaxial circuit pattern according to a second embodiment of the present invention.
圖10A至圖10E為本發明第二實施例之單層雙軸向電路圖案之製 作方法的製程示意圖。 10A to 10E are diagrams showing a single-layer biaxial circuit pattern according to a second embodiment of the present invention; A schematic diagram of the process of the method.
本發明揭露一種創新方法用以製作電子裝置所需的單層雙軸向電路圖案,所述電子裝置例如是筆記型電腦、平板電腦、智慧型手機、股票機、或其他具有觸控功能或通訊功能的電子裝置。值得一提的是,本創新方法用於製作形狀較複雜且尺寸較細小的電路圖案時,具有降低製程困難度與製程成本以及提升製程良率的優勢;再者,本創新方法的操作過程簡單且非常便於實施,具有廣泛的應用前景。 The invention discloses an innovative method for fabricating a single-layer biaxial circuit pattern required for an electronic device, such as a notebook computer, a tablet computer, a smart phone, a stock machine, or other touch function or communication. Functional electronic device. It is worth mentioning that this innovative method has the advantages of reducing process difficulty and process cost and improving process yield when manufacturing circuit patterns with complicated shapes and small dimensions; further, the operation method of the innovative method is simple. It is very easy to implement and has broad application prospects.
以下是通過特定的具體實例來說明本發明所揭露有關“單層雙軸向電路圖案之製作方法”的實施方式,本領域技術人員可由本說明書所公開的內容瞭解本發明的優點與技術效果。本發明可通過其他不同的具體實施例加以施行或應用,本說明書中的各項細節亦可基於不同觀點與應用,在不悖離本發明的精神下進行各種修飾與變更。另外,本發明的圖式僅為簡單示意說明,並非依實際尺寸的描繪,先予敘明。以下的實施方式將進一步詳細說明本發明的相關技術內容,但所揭示的內容並非用以限制本發明的技術範疇。 The following is a specific embodiment to illustrate the implementation of the "method of manufacturing a single-layer biaxial circuit pattern" disclosed by the present invention. Those skilled in the art can understand the advantages and technical effects of the present invention from the contents disclosed in the specification. The present invention can be implemented or applied in various other specific embodiments, and various modifications and changes can be made without departing from the spirit and scope of the invention. In addition, the drawings of the present invention are merely illustrative and are not described in terms of actual dimensions. The following embodiments will further explain the related technical content of the present invention, but the disclosure is not intended to limit the technical scope of the present invention.
請一併參閱圖1至圖2E,圖1為本發明第一實施例之單層雙軸向電路圖案之製作方法的流程圖,圖2A至2E為本發明所述單層雙軸向電路圖案之製作方法之第一種實施方式的製程示意圖。 Please refer to FIG. 1 to FIG. 2E. FIG. 1 is a flowchart of a method for fabricating a single-layer biaxial circuit pattern according to a first embodiment of the present invention, and FIGS. 2A to 2E are single-layer biaxial circuit patterns according to the present invention. A schematic diagram of a process of the first embodiment of the method of fabrication.
本實施例所提供的單層雙軸向電路圖案之製作方法首先執行步驟S101:形成一觸媒圖案層1於一基板2上,觸媒圖案層1包括至少兩個沿第一軸向排列的第一觸媒結構單元11及至少兩個沿大致垂直於第一軸向之第二軸向排列的第二觸媒結構單元12。實務上,觸媒圖案層1可依照預定的電路圖案並透過網印(screen printing)方式形成於基板2上,觸媒圖案層1的厚度介於0.1μm至30μm,其中第一和第二觸媒結構單元11、12可具有任何合適的幾何形狀,例如正方形、矩形、菱形、梯形、六邊形等,然本發明並不限制於此。 The method for fabricating the single-layer biaxial circuit pattern provided in this embodiment first performs step S101: forming a catalyst pattern layer 1 on a substrate 2, and the catalyst pattern layer 1 includes at least two arranged along the first axial direction. The first catalyst structure unit 11 and at least two second catalyst structure units 12 arranged along a second axis substantially perpendicular to the first axis. In practice, the catalyst pattern layer 1 can follow a predetermined circuit pattern and pass through the screen (screen The printing method is formed on the substrate 2, and the thickness of the catalyst pattern layer 1 is between 0.1 μm and 30 μm, wherein the first and second catalyst structural units 11, 12 may have any suitable geometric shape, such as a square, a rectangle, a diamond , trapezoidal, hexagonal, etc., but the invention is not limited thereto.
本實施例中,基板2可以塑膠基板,且材料可以是聚碳酸酯(PC)、聚丙烯(PP)、丙烯晴-丁二烯-苯乙烯共聚合物(ABS)、聚對苯二甲酸乙二酯(PET)、聚醯亞胺(PI)等,然本發明並不限制於此。觸媒圖案層1包含觸媒與硬化劑,具體地說,觸媒圖案層1的材料是使用樹脂材料與觸媒和硬化劑混合所形成的樹脂組成物,其中觸媒能在無電鍍製程(或稱化學鍍製程)中觸發金屬沉積,而觸媒的種類可根據欲鍍金屬而改變,例如,觸媒可以是鈀觸媒、銀觸媒、碳觸媒、或其組合,硬化劑不僅能幫助包含觸媒的樹脂組成物的成型,還能使觸媒圖案層1與基板2之間具有良好的接著力。 In this embodiment, the substrate 2 can be a plastic substrate, and the material can be polycarbonate (PC), polypropylene (PP), acrylonitrile-butadiene-styrene copolymer (ABS), polyethylene terephthalate. Diester (PET), polyimine (PI), etc., but the invention is not limited thereto. The catalyst pattern layer 1 contains a catalyst and a hardener. Specifically, the material of the catalyst pattern layer 1 is a resin composition formed by mixing a resin material with a catalyst and a hardener, wherein the catalyst can be in an electroless plating process ( Metal plating is triggered in the electroless plating process, and the type of the catalyst can be changed according to the metal to be plated. For example, the catalyst can be a palladium catalyst, a silver catalyst, a carbon catalyst, or a combination thereof, and the hardener can not only The molding of the resin composition containing the catalyst is assisted, and a good adhesion between the catalyst pattern layer 1 and the substrate 2 is also achieved.
較佳地,觸媒圖案層1中之觸媒是採用鈀觸媒,例如硫酸鈀、氯化鈀、二氯二氨鈀、二氯四氨鈀、二氨亞硝酸鈀等,然本發明並不限制於此;硬化劑的含量介於1%至10%,且硬化劑可選自於脂肪胺類、環狀脂肪胺類、聚醯胺類、芳香族胺類、酸酐類、路易士酸類、咪唑類硬化劑、或其組合。 Preferably, the catalyst in the catalyst pattern layer 1 is a palladium catalyst, such as palladium sulfate, palladium chloride, dichlorodiammine palladium, dichlorotetraammine palladium, palladium diamine nitrite, etc. The content of the hardener is from 1% to 10%, and the hardener may be selected from the group consisting of fatty amines, cyclic aliphatic amines, polyamines, aromatic amines, acid anhydrides, and Lewis acids. , an imidazole hardener, or a combination thereof.
更進一步來說,觸媒圖案層1可利用以下方式製作:首先,將網版(圖未示)置於基板2上方,其中網版具有一相對於預定的電路圖案的鏤空圖形;接著,利用刮刀(圖未示)從網版上方擠壓包含觸媒的樹脂組成物,以使其通過網版並轉印到基板2表面上;然後,根據所用的樹脂材料進行熱處理及/或光照固化處理,以使所述樹脂組成物固化成型。 Furthermore, the catalyst pattern layer 1 can be fabricated in the following manner: First, a screen (not shown) is placed over the substrate 2, wherein the screen has a hollow pattern relative to a predetermined circuit pattern; A doctor blade (not shown) extrudes the resin composition containing the catalyst from above the screen to pass through the screen and transfer onto the surface of the substrate 2; then, heat treatment and/or light curing treatment is performed according to the resin material used. To cure the resin composition.
接著,執行步驟S102:形成一第一橋接件3用以連接兩個第一觸媒結構單元11。實務上,可利用網印或噴塗(spraying)方式來塗佈第一橋接件3的材料,而後再進行熱處理及/或光照固化處理以使其固化成型;從結構上來看,因為觸媒圖案層1相對於基板2 存在段差,其中兩個第一觸媒結構單元11之間形成有一段差結構D,所以第一橋接件3會由任一第一觸媒結構單元11的前緣沿段差結構D延伸至另一第一觸媒結構單元11的前緣。本實施例中,第一橋接件3的材料可以是導電油墨,例如銀系、銅系、碳系導電油墨等,然本發明並不限制於此。 Next, step S102 is performed to form a first bridge 3 for connecting the two first catalyst structure units 11. In practice, the material of the first bridge member 3 may be coated by screen printing or spraying, and then subjected to heat treatment and/or light curing treatment to cure the film; structurally, because of the catalyst pattern layer 1 relative to the substrate 2 There is a step difference in which a difference structure D is formed between the two first catalyst structure units 11, so that the first bridge member 3 is extended from the leading edge of any of the first catalyst structure units 11 along the step difference structure D to another The leading edge of a catalyst structure unit 11. In this embodiment, the material of the first bridge member 3 may be a conductive ink, such as a silver-based, copper-based, carbon-based conductive ink, etc., but the invention is not limited thereto.
然後,執行步驟S103:形成一絕緣層4用以覆蓋第一橋接件3。實務上,可利用網印或噴塗方式來塗佈絕緣層4的材料,而後再進行熱處理及/或光照固化處理以使其固化成型,其中因為段差結構D的存在,所以絕緣層4會順著段差結構D的構型而形成於第一橋接件3的表面上。本實施例中,絕緣層4的材料可以是絕緣油墨,然本發明並不限制於此;另外,絕緣層4並未完全覆蓋住第一橋接件3,第一橋接件3的邊緣外露於絕緣層4。 Then, step S103 is performed to form an insulating layer 4 for covering the first bridge 3. In practice, the material of the insulating layer 4 can be coated by screen printing or spraying, and then heat-treated and/or light-cured to form a solidified molding, wherein the insulating layer 4 is followed by the existence of the step structure D. The configuration of the step structure D is formed on the surface of the first bridge 3. In this embodiment, the material of the insulating layer 4 may be an insulating ink, but the invention is not limited thereto; in addition, the insulating layer 4 does not completely cover the first bridge member 3, and the edge of the first bridge member 3 is exposed to the insulation. Layer 4.
此後,執行步驟S104:於絕緣層4上形成一第二橋接件5用以連接兩個第二觸媒結構單元12。實務上,可利用網印或噴塗方式來塗佈第二橋接件5的材料,而後再進行熱處理及/或光照固化處理以使其固化成型,其中第二橋接件5由任一第二觸媒結構單元12的前緣延伸跨過絕緣層4至另一第二觸媒結構單元12的前緣。第二橋接件5視需求可採用與觸媒圖案層1相同的材料,亦可採用與第一橋接件3相同的材料。 Thereafter, step S104 is performed to form a second bridge member 5 on the insulating layer 4 for connecting the two second catalyst structure units 12. In practice, the material of the second bridge member 5 can be coated by screen printing or spraying, and then subjected to heat treatment and/or light curing treatment to cure the molding, wherein the second bridge member 5 is composed of any second catalyst. The leading edge of the structural unit 12 extends across the leading edge of the insulating layer 4 to the other second catalyst structure unit 12. The second bridge member 5 may be made of the same material as the catalyst pattern layer 1 as needed, or may be made of the same material as the first bridge member 3.
最後,執行步驟S105:利用無電鍍(electroless plating)製程於兩個第一觸媒結構單元11及兩個第二觸媒結構單元12上鍍覆一層金屬。實務上,可將印有觸媒圖案層1的基板2浸置於含有欲鍍金屬離子(如金、銀、銅、鎳、鋁、鉻等)的化學鍍液中,待反應一段時間(如5分鐘)後,鍍液中之金屬離子便會透過觸媒的催化作用還原析出於觸媒圖案層1上,形成帶有單層雙軸向電路圖案的結構件。 Finally, step S105 is performed: a layer of metal is plated on the two first catalyst structure units 11 and the two second catalyst structure units 12 by an electroless plating process. In practice, the substrate 2 printed with the catalyst pattern layer 1 may be immersed in an electroless plating solution containing metal ions (such as gold, silver, copper, nickel, aluminum, chromium, etc.) to be reacted for a certain period of time (eg, After 5 minutes), the metal ions in the plating solution are reductively deposited on the catalyst pattern layer 1 by the catalytic action of the catalyst to form a structural member having a single-layer biaxial circuit pattern.
請參閱圖3,更進一步來說,第一觸媒結構單元11上因為沉積有金屬薄膜M而形成第一導電結構單元11’,且兩個第一導電 結構單元11’藉由第一橋接件3產生電性連結;須說明的是,第一橋接件3的邊緣外露部分在進行無電鍍製程時亦有機會被金屬薄膜M所覆蓋。類似地,第二觸媒結構單元12上因為沉積有金屬薄膜M而形成第二導電結構單元12’,第二橋接件5上因為沉積有金屬薄膜M而可以讓兩個第二導電結構單元12’之間產生電性連結。 Referring to FIG. 3, further, the first conductive structure unit 11 is formed on the first catalyst structure unit 11 by depositing the metal thin film M, and the two first conductive layers are formed. The structural unit 11' is electrically connected by the first bridge member 3; it should be noted that the exposed portion of the edge of the first bridge member 3 also has a chance to be covered by the metal film M during the electroless plating process. Similarly, the second conductive structural unit 12' is formed on the second catalyst structure unit 12 because the metal thin film M is deposited, and the second conductive structural unit 12 can be made on the second bridge 5 due to the deposition of the metal thin film M. 'An electrical connection between the '.
本實施例中,無電鍍製程中所採用的鍍液可以是鹼性鍍液(如氯化銅鍍液),其中鍍液的溫度介於20℃至100℃,鍍液的酸鹼值介於9至14;無電鍍製程的反應時間介於5至500分鐘,然實際的反應時間可根據欲鍍薄膜的厚度做調整。 In this embodiment, the plating solution used in the electroless plating process may be an alkaline plating solution (such as a copper chloride plating solution), wherein the temperature of the plating solution is between 20 ° C and 100 ° C, and the pH value of the plating solution is between 9 to 14; the electroless plating process has a reaction time of 5 to 500 minutes, but the actual reaction time can be adjusted according to the thickness of the film to be coated.
如上所述,在介紹完本實施例所提供的單層雙軸向電路圖案之製作方法的主要流程後,下面將進一步介紹所述方法的幾個不同的實施方式。 As described above, after the main flow of the method for fabricating the single-layer biaxial circuit pattern provided by the embodiment is introduced, several different embodiments of the method will be further described below.
請一併參閱圖1及圖4A至圖4E,其中圖4A至4E為本發明所述單層雙軸向電路圖案之製作方法之第二種實施方式的製程示意圖。此一實施方式的特點主要在於:步驟S101中,於形成觸媒圖案層1時,在兩個第一觸媒結構單元11之間進一步形成一平坦層13作為第一橋接件3的基底;如此一來,可避免第一觸媒結構單元11表面與基板2表面產生段差,進而可防止第一橋接件3從彎折處斷裂。 Referring to FIG. 1 and FIG. 4A to FIG. 4E , FIG. 4A to FIG. 4E are schematic diagrams showing a process of a second embodiment of a method for fabricating a single-layer biaxial circuit pattern according to the present invention. The embodiment is mainly characterized in that, in step S101, when the catalyst pattern layer 1 is formed, a flat layer 13 is further formed between the two first catalyst structure units 11 as a base of the first bridge member 3; As a result, a step difference between the surface of the first catalyst structure unit 11 and the surface of the substrate 2 can be avoided, thereby preventing the first bridge member 3 from being broken from the bend.
請再參閱圖5,從結構上來看,因為平坦層13的厚度與第一觸媒結構單元11的厚度相同,所以觸媒圖案層1表面與基板2表面之間不存在段差,且第一橋接件3可由任一第一觸媒結構單元11的前緣筆直延伸至另一第一觸媒結構單元11的前緣,同時絕緣層4平整地覆蓋於第一橋接件3的表面上。 Referring to FIG. 5 again, from the structural point of view, since the thickness of the flat layer 13 is the same as the thickness of the first catalyst structure unit 11, there is no step difference between the surface of the catalyst pattern layer 1 and the surface of the substrate 2, and the first bridge The member 3 may extend straight from the leading edge of any of the first catalyst structure units 11 to the leading edge of the other first catalyst structure unit 11 while the insulating layer 4 covers the surface of the first bridge member 3 in a flat manner.
請一併參閱圖1及圖6A至圖6E,其中圖6A至圖6E為本發明所述單層雙軸向電路圖案之製作方法之第三種實施方式的製程示意圖。此一實施方式的特點主要在於:步驟S103中,將絕緣層 4的寬度加大,使其由任一第二觸媒結構單元12的前緣延伸至另一第二觸媒結構單元12的前緣;如此一來,可使第二橋接件5的彎折程度趨於平緩,進而可防止第二橋接件5從彎折處斷裂。 Please refer to FIG. 1 and FIG. 6A to FIG. 6E , wherein FIG. 6A to FIG. 6E are schematic diagrams of processes of a third embodiment of a method for fabricating a single-layer biaxial circuit pattern according to the present invention. The feature of this embodiment is mainly that: in step S103, the insulating layer is The width of 4 is increased to extend from the leading edge of any second catalyst structure unit 12 to the leading edge of the other second catalyst structure unit 12; thus, the second bridge member 5 can be bent The degree tends to be gentle, which in turn prevents the second bridge 5 from breaking from the bend.
請再參閱圖7,從結構上來看,第一橋接件3表面與基板2表面存在段差,第二觸媒結構單元12表面與基板2表面亦存在段差,而透過加大絕緣層4的寬度,可一併填補第一橋接件3表面、第二觸媒結構單元12表面與基板2表面之間的段差。 Referring to FIG. 7 , structurally, there is a difference between the surface of the first bridge member 3 and the surface of the substrate 2 , and the surface of the second catalyst structure unit 12 and the surface of the substrate 2 also have a step difference, and the width of the insulating layer 4 is increased. The step difference between the surface of the first bridge member 3, the surface of the second catalyst structure unit 12, and the surface of the substrate 2 can be filled.
請一併參閱圖1及圖8A至圖8E,其中圖8A至圖8E為本發明所述單層雙軸向電路圖案之製作方法之第四種實施方式的製程示意圖。此一實施方式的特點主要在於:步驟S104中,第二橋接件5是採用與第一橋接件3相同的材料,即第一和第二橋接件3、5的材料都是導電油墨。須說明的是,因為第二橋接件5中沒有觸媒存在,所以在無電鍍製程中第二橋接件5上沒有金屬薄膜的沉積。 Please refer to FIG. 1 and FIG. 8A to FIG. 8E , wherein FIG. 8A to FIG. 8E are schematic diagrams showing a process of a fourth embodiment of a method for fabricating a single-layer biaxial circuit pattern according to the present invention. The feature of this embodiment is mainly that in the step S104, the second bridge member 5 is made of the same material as the first bridge member 3, that is, the materials of the first and second bridge members 3, 5 are all conductive ink. It should be noted that since there is no catalyst in the second bridge member 5, there is no deposition of the metal film on the second bridge member 5 in the electroless plating process.
請一併參閱圖9及圖10A至圖10E,圖9為本發明第二實施例之單層雙軸向電路圖案之製作方法的流程圖,圖10A至圖10E為本發明所述單層雙軸向電路圖案之製作方法的製程示意圖。 Please refer to FIG. 9 and FIG. 10A to FIG. 10E. FIG. 9 is a flowchart of a method for fabricating a single-layer biaxial circuit pattern according to a second embodiment of the present invention, and FIG. 10A to FIG. 10E are single-layer doubles according to the present invention. A schematic diagram of a process for fabricating an axial circuit pattern.
須說明的是,本實施例所提供的單層雙軸向電路圖案之製作方法的相關技術細節大致與第一實施例相同,兩者間的主要差異在於:第一實施例是同時印刷形成沿第一軸向排列的第一觸媒結構單元11及沿第二軸向排列的第二觸媒結構單元12,而後再利用無電鍍製程於第一和第二觸媒結構單元11、12的外表面上沉積一層金屬薄膜;本實施例則是先後印刷形成沿第一軸向排列的第一觸媒結構單元11及沿第二軸向排列的第二觸媒結構單元12,而後再利用無電鍍製程於第一和第二觸媒結構單元11、12的外表面上沉積一層金屬薄膜。 It should be noted that the related technical details of the method for fabricating the single-layer biaxial circuit pattern provided by this embodiment are substantially the same as those of the first embodiment, and the main difference between the two is that the first embodiment is simultaneous printing forming along the edge. a first axially arranged first catalyst structure unit 11 and a second catalyst structure unit 12 arranged along the second axial direction, and then using an electroless plating process outside the first and second catalyst structure units 11, 12 A metal film is deposited on the surface; in this embodiment, the first catalyst structure unit 11 arranged along the first axial direction and the second catalyst structure unit 12 arranged along the second axial direction are sequentially printed, and then the electroless plating is utilized. The process deposits a thin metal film on the outer surfaces of the first and second catalyst structural units 11, 12.
本實施例所提供的單層雙軸向電路圖案之製作方法包括:步驟201:形成至少兩個沿第一軸向排列的第一觸媒結構單元11於一基板2上;步驟202:形成一第一橋接件3用以連接兩個第一觸媒結構單元11;步驟203:形成一絕緣層4用以覆蓋第一橋接件3;步驟204:形成至少兩個沿第二軸向排列的第二觸媒結構單元12於基板2上;步驟205:於絕緣層4上形成一第二橋接件5用以連接兩個第二觸媒結構單元12;以及步驟206:利用無電鍍製程於兩個第一觸媒結構單元11及兩個第二觸媒結構單元12上鍍覆一層金屬。 The method for fabricating the single-layer biaxial circuit pattern provided in this embodiment includes: Step 201: forming at least two first catalyst structure units 11 arranged along the first axial direction on a substrate 2; Step 202: forming a The first bridge member 3 is used to connect the two first catalyst structure units 11; Step 203: an insulating layer 4 is formed to cover the first bridge member 3; Step 204: forming at least two rows arranged along the second axis The second catalyst structure unit 12 is on the substrate 2; Step 205: forming a second bridge member 5 on the insulating layer 4 for connecting the two second catalyst structure units 12; and Step 206: using an electroless plating process on the two The first catalyst structure unit 11 and the two second catalyst structure units 12 are plated with a layer of metal.
須說明的是,本實施例所提供的單層雙軸向電路圖案之製作方法也可以有上述的多個不同的實施方式,即在兩個第一觸媒結構單元11之間進一步形成一平坦層13及/或將絕緣層4加寬及/或替換第二橋接件5的材料等,其相關技術細節可參考第一實施例所述內容,於此不多加贅述。 It should be noted that the method for fabricating the single-layer biaxial circuit pattern provided in this embodiment may also have a plurality of different embodiments described above, that is, a flat is further formed between the two first catalyst structure units 11. The layer 13 and/or the material of the second bridge member 5 is widened and/or replaced. For the related technical details, reference may be made to the content of the first embodiment, and details are not described herein.
請參閱圖3、圖5、及圖7,利用上述第一和第二實施例所提供的單層雙軸向電路圖案之製作方法,可形成帶有單層雙軸向電路圖案的結構件100,其可作為電路基材或天線基材以應用於電子裝置(如具有觸控功能的電子裝置或通訊裝置)。所述帶有單層雙軸向電路圖案的結構件100包括一基板2、至少兩個第一導電結構單元11’、至少兩個第二導電結構單元12’、一第一橋接件3、一絕緣層4、及一第二橋接件5。 Referring to FIG. 3, FIG. 5, and FIG. 7, the structural member 100 with a single-layer biaxial circuit pattern can be formed by the method for fabricating the single-layer biaxial circuit pattern provided by the first and second embodiments. It can be used as a circuit substrate or an antenna substrate for an electronic device (such as an electronic device or a communication device with a touch function). The structural member 100 with a single-layer biaxial circuit pattern includes a substrate 2, at least two first conductive structural units 11', at least two second conductive structural units 12', a first bridge 3, and a The insulating layer 4 and a second bridge member 5.
具體地說,兩個第一導電結構單元11’沿第一軸向(如X軸)排列,其中每一第一導電結構單元11’由一第一觸媒結構單元11與一覆蓋於第一觸媒結構單元11外表面的至少一部分的金屬薄膜M組成;兩個第二導電結構單元12’沿與第一軸向大致垂直的第二軸向(如Y軸)排列,其中每一第二導電結構單元12’由一第二觸媒結 構單元12與一覆蓋於第二觸媒結構單元12外表面的至少一部分的金屬薄膜M組成;第一橋接件3由任一第一觸媒結構單元11的前緣延伸至另一第一觸媒結構單元11的前緣,絕緣層4覆蓋於第一橋接件3表面,第二橋接件5由任一第二觸媒結構單元12的前緣延伸跨過絕緣層4至另一第二觸媒結構單元12的前緣。 Specifically, the two first conductive structural units 11' are arranged along a first axial direction (such as an X axis), wherein each of the first conductive structural units 11' is covered by a first catalytic structure unit 11 and a first a metal thin film M of at least a portion of an outer surface of the catalyst structural unit 11; two second conductive structural units 12' are arranged along a second axial direction (such as a Y-axis) substantially perpendicular to the first axial direction, wherein each second The conductive structural unit 12' is composed of a second catalyst The structure unit 12 is composed of a metal film M covering at least a portion of the outer surface of the second catalyst structure unit 12; the first bridge member 3 is extended from the leading edge of any of the first catalyst structure units 11 to another first contact The leading edge of the dielectric unit 11, the insulating layer 4 covers the surface of the first bridge 3, and the second bridge 5 extends from the leading edge of any of the second catalyst unit 12 across the insulating layer 4 to another second contact The leading edge of the media structure unit 12.
對於所述帶有單層雙軸向電路圖案的結構件100的一個態樣,如圖3所示,第一觸媒結構單元11表面與基板2表面之間具有一段差結構D,第一橋接件3由任一第一觸媒結構單元11的前緣沿段差結構D延伸至另一第一觸媒結構單元11的前緣,且絕緣層4順著段差結構D的構型而形成於第一橋接件3的表面上。 For one aspect of the structural member 100 with a single-layer biaxial circuit pattern, as shown in FIG. 3, the surface of the first catalyst structure unit 11 and the surface of the substrate 2 have a difference structure D, the first bridge The member 3 extends from the leading edge of any first catalyst structure unit 11 along the step structure D to the leading edge of the other first catalyst structure unit 11, and the insulating layer 4 is formed along the configuration of the step structure D. On the surface of a bridge 3.
對於所述帶有單層雙軸向電路圖案的結構件100的另一個態樣,如圖5所示,兩個第一導電結構單元11’之間具有一平坦層13,且平坦層13的厚度與第一觸媒結構單元11的厚度相同;第一橋接件3由任一第一觸媒結構單元11的前緣筆直延伸至另一第一觸媒結構單元11的前緣,同時絕緣層4平整地覆蓋於第一橋接件3的表面上。 For another aspect of the structural member 100 with a single-layer biaxial circuit pattern, as shown in FIG. 5, a flat layer 13 is disposed between the two first conductive structural units 11', and the flat layer 13 is The thickness is the same as the thickness of the first catalyst structure unit 11; the first bridge 3 extends straight from the leading edge of any of the first catalyst structure units 11 to the leading edge of the other first catalyst structure unit 11, while the insulating layer 4 covers the surface of the first bridge 3 flatly.
對於所述帶有單層雙軸向電路圖案的結構件100的再一個態樣,可將絕緣層4的寬度加大,如圖7所示,使其由任一第二觸媒結構單元12的前緣延伸至另一第二觸媒結構單元12的前緣;如此一來,可使第二橋接件5的彎折程度趨於平緩,進而可防止第二橋接件5從彎折處斷裂。 For still another aspect of the structural member 100 with a single-layer biaxial circuit pattern, the width of the insulating layer 4 can be increased, as shown in FIG. 7, by any of the second catalyst structural units 12. The leading edge extends to the leading edge of the other second catalyst structure unit 12; thus, the degree of bending of the second bridge member 5 can be made gentle, thereby preventing the second bridge member 5 from being broken from the bend. .
對於所述帶有單層雙軸向電路圖案的結構件100的再另一個態樣,第一和第二橋接件3、5的材料都是導電油墨。對於所述帶有單層雙軸向電路圖案的結構件100的再另一個態樣,第一橋接件3的材料為導電油墨,第一橋接件3的材料與第一和第二觸媒結構單元11、12相同,且第一橋接件3的表面上亦具有一金屬薄膜M。 In still another aspect of the structural member 100 with a single layer biaxial circuit pattern, the materials of the first and second bridge members 3, 5 are all conductive inks. In still another aspect of the structural member 100 with a single-layer biaxial circuit pattern, the material of the first bridge 3 is a conductive ink, the material of the first bridge 3 and the first and second catalyst structures. The units 11, 12 are identical, and the surface of the first bridge 3 also has a metal film M.
本發明實施例所提供的單層雙軸向電路圖案之製作方法透過“同時印刷形成沿第一軸向排列的第一觸媒結構單元及沿第二軸向排列的第二觸媒結構單元,而後再利用無電鍍製程於第一和第二觸媒結構單元的外表面上沉積一層金屬薄膜”以及“先後印刷形成沿第一軸向排列的第一觸媒結構單元及沿第二軸向排列的第二觸媒結構單元,而後再利用無電鍍製程於第一和第二觸媒結構單元的外表面上沉積一層金屬薄膜”的流程設計,可有效將繁複、耗時的製程步驟精簡化,以降低製程困難度及提升製程良率。 The method for fabricating the single-layer biaxial circuit pattern provided by the embodiment of the present invention is to form a first catalyst structure unit arranged along the first axial direction and a second catalyst structure unit arranged along the second axial direction by simultaneous printing. And then depositing a metal film on the outer surface of the first and second catalyst structural units by using an electroless plating process and "sequentially printing to form first catalyst structural units arranged along the first axial direction and arranged along the second axial direction The process of designing the second catalyst structure unit and then depositing a metal film on the outer surface of the first and second catalyst structural units by using an electroless plating process can effectively simplify complicated and time-consuming process steps. To reduce process difficulty and improve process yield.
承上述,所述單層雙軸向電路圖案之製作方法的操作過程簡單且非常便於實施,其不但具有廣泛的應用前景,還適合工業化量產。 In view of the above, the manufacturing method of the single-layer biaxial circuit pattern is simple and very easy to implement, and has wide application prospects, and is also suitable for industrial mass production.
以上所述僅為本發明的實施例,其並非用以限定本發明的專利保護範圍。任何熟習相像技藝者,在不脫離本發明的精神與範圍內,所作的更動及潤飾的等效替換,仍為本發明的專利保護範圍內。 The above is only an embodiment of the present invention, and is not intended to limit the scope of the invention. It is still within the scope of patent protection of the present invention to make any substitutions and modifications of the modifications made by those skilled in the art without departing from the spirit and scope of the invention.
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