TWI639023B - a method of applying an anti-reflective coating to an optical surface of a mold, a mold having an optical surface transferable to an anti-reflective coating of the lens, and an optical lens manufactured thereby - Google Patents
a method of applying an anti-reflective coating to an optical surface of a mold, a mold having an optical surface transferable to an anti-reflective coating of the lens, and an optical lens manufactured thereby Download PDFInfo
- Publication number
- TWI639023B TWI639023B TW103124225A TW103124225A TWI639023B TW I639023 B TWI639023 B TW I639023B TW 103124225 A TW103124225 A TW 103124225A TW 103124225 A TW103124225 A TW 103124225A TW I639023 B TWI639023 B TW I639023B
- Authority
- TW
- Taiwan
- Prior art keywords
- layer
- refractive index
- superhydrophobic
- mold
- thickness
- Prior art date
Links
- 230000003287 optical effect Effects 0.000 title claims abstract description 108
- 239000006117 anti-reflective coating Substances 0.000 title claims abstract description 63
- 238000000034 method Methods 0.000 title claims abstract description 58
- 239000010410 layer Substances 0.000 claims abstract description 496
- 239000000463 material Substances 0.000 claims abstract description 315
- 230000003075 superhydrophobic effect Effects 0.000 claims abstract description 169
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims abstract description 132
- 239000007822 coupling agent Substances 0.000 claims abstract description 45
- 239000002356 single layer Substances 0.000 claims abstract description 18
- 238000003618 dip coating Methods 0.000 claims abstract description 17
- 238000004528 spin coating Methods 0.000 claims abstract description 17
- 238000007740 vapor deposition Methods 0.000 claims abstract description 15
- 239000000010 aprotic solvent Substances 0.000 claims abstract description 13
- 230000008878 coupling Effects 0.000 claims abstract description 11
- 238000010168 coupling process Methods 0.000 claims abstract description 11
- 238000005859 coupling reaction Methods 0.000 claims abstract description 11
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 67
- 150000002500 ions Chemical class 0.000 claims description 31
- 125000004122 cyclic group Chemical group 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 23
- 238000010438 heat treatment Methods 0.000 claims description 18
- YWXTVBJTVYUHQF-UHFFFAOYSA-N COC(CCCCCCCCCC(CC)NC(CC)CCCCCCCCCC(OC)(OC)OC)(OC)OC Chemical compound COC(CCCCCCCCCC(CC)NC(CC)CCCCCCCCCC(OC)(OC)OC)(OC)OC YWXTVBJTVYUHQF-UHFFFAOYSA-N 0.000 claims description 11
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 9
- 238000000151 deposition Methods 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims description 4
- 230000003667 anti-reflective effect Effects 0.000 description 106
- 238000000576 coating method Methods 0.000 description 97
- 239000011248 coating agent Substances 0.000 description 87
- 239000004033 plastic Substances 0.000 description 18
- 229920003023 plastic Polymers 0.000 description 18
- 239000000243 solution Substances 0.000 description 16
- 229910000831 Steel Inorganic materials 0.000 description 12
- 239000010959 steel Substances 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 239000011247 coating layer Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000000758 substrate Substances 0.000 description 9
- 238000001771 vacuum deposition Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000005266 casting Methods 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 229910000420 cerium oxide Inorganic materials 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 238000000869 ion-assisted deposition Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000006187 pill Substances 0.000 description 3
- 239000006120 scratch resistant coating Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- DBJFSFSBHGPDPG-UHFFFAOYSA-N C(C(=C)C)(=O)OCCCC(C(OC)(OC)OC)CCCCCCCC Chemical compound C(C(=C)C)(=O)OCCCC(C(OC)(OC)OC)CCCCCCCC DBJFSFSBHGPDPG-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- -1 acrylic compound Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 2
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003989 dielectric material Substances 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000004313 glare Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000007142 ring opening reaction Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- BAXOFTOLAUCFNW-UHFFFAOYSA-N 1H-indazole Chemical compound C1=CC=C2C=NNC2=C1 BAXOFTOLAUCFNW-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical group CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 125000006612 decyloxy group Chemical group 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000313 electron-beam-induced deposition Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000013047 polymeric layer Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00865—Applying coatings; tinting; colouring
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/113—Anti-reflection coatings using inorganic layer materials only
- G02B1/115—Multilayers
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ophthalmology & Optometry (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Surface Treatment Of Optical Elements (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/943,570 | 2013-07-16 | ||
| US13/943,570 US9335443B2 (en) | 2011-04-15 | 2013-07-16 | Anti-reflective lenses and methods for manufacturing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201504664A TW201504664A (zh) | 2015-02-01 |
| TWI639023B true TWI639023B (zh) | 2018-10-21 |
Family
ID=52346614
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW103124225A TWI639023B (zh) | 2013-07-16 | 2014-07-15 | a method of applying an anti-reflective coating to an optical surface of a mold, a mold having an optical surface transferable to an anti-reflective coating of the lens, and an optical lens manufactured thereby |
Country Status (3)
| Country | Link |
|---|---|
| AR (1) | AR096903A1 (es) |
| TW (1) | TWI639023B (es) |
| WO (1) | WO2015009349A1 (es) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI738743B (zh) | 2016-03-23 | 2021-09-11 | 美商道康寧公司 | 金屬-聚有機矽氧烷 |
| US20190033491A1 (en) * | 2017-07-28 | 2019-01-31 | Ppg Industries Ohio, Inc. | Multi-layer antireflective coated articles |
| US20200150313A1 (en) * | 2018-11-13 | 2020-05-14 | Quantum Innovations, Inc. | Anti-reflection lens and method for treating a lens to reduce reflections for placental mammals with dichromatic vision |
| US11448797B1 (en) | 2018-11-29 | 2022-09-20 | Quantum Innovations, Inc. | Viewing lens and method for treating lenses to minimize glare and reflections for birds with tetra-chromatic vision |
| US11353630B2 (en) | 2019-03-18 | 2022-06-07 | Quantum Innovations, Inc. | Method for treating a lens to reduce light reflections for animals and devices that view through the ultra violet light spectrum |
| US12147008B2 (en) | 2019-04-25 | 2024-11-19 | Quantum Innovations, Inc. | Thin film optical lens and method for coating a lens |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6986857B2 (en) * | 2001-05-29 | 2006-01-17 | Essilor International Compagnie Generale D'optique | Method for preparing a mold part useful for transferring a coating onto an optical substrate |
| FR2859485B1 (fr) * | 2003-09-04 | 2006-09-15 | Essilor Int | Procede de realisation d'un traitement anti-reflets sur un substrat optique, substrat optique obtenu par ce procede et dispositif de mise en oeuvre du procede |
| US20080113188A1 (en) * | 2006-11-09 | 2008-05-15 | Shah Pratik B | Hydrophobic organic-inorganic hybrid silane coatings |
| US20090075092A1 (en) * | 2007-09-18 | 2009-03-19 | Guardian Industries Corp. | Method of making an antireflective silica coating, resulting product, and photovoltaic device comprising same |
| CN101724342B (zh) * | 2009-12-17 | 2012-09-05 | 复旦大学 | 一种超双亲自清洁涂层材料及其制备方法 |
-
2014
- 2014-05-19 WO PCT/US2014/038600 patent/WO2015009349A1/en not_active Ceased
- 2014-07-14 AR ARP140102588A patent/AR096903A1/es active IP Right Grant
- 2014-07-15 TW TW103124225A patent/TWI639023B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AR096903A1 (es) | 2016-02-03 |
| WO2015009349A1 (en) | 2015-01-22 |
| TW201504664A (zh) | 2015-02-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |