TWI635122B - 液晶配向處理劑、液晶配向膜及液晶顯示元件 - Google Patents

液晶配向處理劑、液晶配向膜及液晶顯示元件 Download PDF

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Publication number: TWI635122B
Authority: TW; Taiwan
Prior art keywords: ring; liquid crystal; group; crystal alignment; treatment agent
Prior art date: 2014-11-13

Application number

TW104137540A

Other languages

English (en)

Chinese (zh)

Other versions

TW201634589A (zh

Inventor

橋本淳

若林暁子

三木徳俊

保坂和義

中家直樹

Original Assignee

日商日產化學工業股份有限公司

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2014-11-13

Filing date

2015-11-13

Publication date

2018-09-11

2015-11-13 Application filed by 日商日產化學工業股份有限公司 filed Critical 日商日產化學工業股份有限公司

2016-10-01 Publication of TW201634589A publication Critical patent/TW201634589A/zh

2018-09-11 Application granted granted Critical

2018-09-11 Publication of TWI635122B publication Critical patent/TWI635122B/zh

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239000004973 liquid crystal related substance Substances 0.000 title claims abstract description 406
239000003795 chemical substances by application Substances 0.000 title claims abstract description 152
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239000004615 ingredient Substances 0.000 claims abstract description 11
239000011964 heteropoly acid Substances 0.000 claims abstract description 9
-1 polyhydroxystyrene Polymers 0.000 claims description 120
125000004432 carbon atom Chemical group C* 0.000 claims description 77
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 74
229920001721 polyimide Polymers 0.000 claims description 65
239000004642 Polyimide Substances 0.000 claims description 54
125000000217 alkyl group Chemical group 0.000 claims description 45
239000002904 solvent Substances 0.000 claims description 45
239000000758 substrate Substances 0.000 claims description 44
238000000034 method Methods 0.000 claims description 42
150000000000 tetracarboxylic acids Chemical class 0.000 claims description 35
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 33
239000002243 precursor Substances 0.000 claims description 31
239000000203 mixture Substances 0.000 claims description 27
239000002253 acid Substances 0.000 claims description 26
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YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 18
229910052799 carbon Inorganic materials 0.000 claims description 18
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 18
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 17
125000002971 oxazolyl group Chemical group 0.000 claims description 17
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YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 15
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125000001931 aliphatic group Chemical group 0.000 claims description 14
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125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims description 7
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125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims description 7
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125000002183 isoquinolinyl group Chemical group C1(=NC=CC2=CC=CC=C12)* 0.000 claims description 7
IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 claims description 7
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235000012000 cholesterol Nutrition 0.000 claims description 6
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RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 5
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239000007983 Tris buffer Chemical group 0.000 claims description 5
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WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
ZIPLUEXSCPLCEI-UHFFFAOYSA-N iminomethylideneazanide Chemical compound [NH-]C#N ZIPLUEXSCPLCEI-UHFFFAOYSA-N 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000000463 material Substances 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate group Chemical group C(C(=C)C)(=O)[O-] CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
GQKZBCPTCWJTAS-UHFFFAOYSA-N methoxymethylbenzene Chemical compound COCC1=CC=CC=C1 GQKZBCPTCWJTAS-UHFFFAOYSA-N 0.000 description 1
HSDFKDZBJMDHFF-UHFFFAOYSA-N methyl 3-ethoxypropanoate Chemical compound CCOCCC(=O)OC HSDFKDZBJMDHFF-UHFFFAOYSA-N 0.000 description 1
CWKLZLBVOJRSOM-UHFFFAOYSA-N methyl pyruvate Chemical compound COC(=O)C(C)=O CWKLZLBVOJRSOM-UHFFFAOYSA-N 0.000 description 1
239000000178 monomer Substances 0.000 description 1
PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
MQWFLKHKWJMCEN-UHFFFAOYSA-N n'-[3-[dimethoxy(methyl)silyl]propyl]ethane-1,2-diamine Chemical compound CO[Si](C)(OC)CCCNCCN MQWFLKHKWJMCEN-UHFFFAOYSA-N 0.000 description 1
LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 description 1
LIBWSLLLJZULCP-UHFFFAOYSA-N n-(3-triethoxysilylpropyl)aniline Chemical compound CCO[Si](OCC)(OCC)CCCNC1=CC=CC=C1 LIBWSLLLJZULCP-UHFFFAOYSA-N 0.000 description 1
ILRLVKWBBFWKTN-UHFFFAOYSA-N n-benzyl-3-triethoxysilylpropan-1-amine Chemical compound CCO[Si](OCC)(OCC)CCCNCC1=CC=CC=C1 ILRLVKWBBFWKTN-UHFFFAOYSA-N 0.000 description 1
CLYWMXVFAMGARU-UHFFFAOYSA-N n-benzyl-3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCNCC1=CC=CC=C1 CLYWMXVFAMGARU-UHFFFAOYSA-N 0.000 description 1
229940017144 n-butyl lactate Drugs 0.000 description 1
DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
OBKARQMATMRWQZ-UHFFFAOYSA-N naphthalene-1,2,5,6-tetracarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)C=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 OBKARQMATMRWQZ-UHFFFAOYSA-N 0.000 description 1
OLAPPGSPBNVTRF-UHFFFAOYSA-N naphthalene-1,4,5,8-tetracarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=C(C(O)=O)C2=C1C(O)=O OLAPPGSPBNVTRF-UHFFFAOYSA-N 0.000 description 1
OKBVMLGZPNDWJK-UHFFFAOYSA-N naphthalene-1,4-diamine Chemical compound C1=CC=C2C(N)=CC=C(N)C2=C1 OKBVMLGZPNDWJK-UHFFFAOYSA-N 0.000 description 1
KQSABULTKYLFEV-UHFFFAOYSA-N naphthalene-1,5-diamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1N KQSABULTKYLFEV-UHFFFAOYSA-N 0.000 description 1
DOBFTMLCEYUAQC-UHFFFAOYSA-N naphthalene-2,3,6,7-tetracarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)C=C2C=C(C(O)=O)C(C(=O)O)=CC2=C1 DOBFTMLCEYUAQC-UHFFFAOYSA-N 0.000 description 1
GOGZBMRXLADNEV-UHFFFAOYSA-N naphthalene-2,6-diamine Chemical compound C1=C(N)C=CC2=CC(N)=CC=C21 GOGZBMRXLADNEV-UHFFFAOYSA-N 0.000 description 1
HBJPJUGOYJOSLR-UHFFFAOYSA-N naphthalene-2,7-diamine Chemical compound C1=CC(N)=CC2=CC(N)=CC=C21 HBJPJUGOYJOSLR-UHFFFAOYSA-N 0.000 description 1
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
229920001778 nylon Polymers 0.000 description 1
OURNLUUIQWKTRH-UHFFFAOYSA-N oxirane;phenol Chemical compound C1CO1.OC1=CC=CC=C1.OC1=CC=CC=C1 OURNLUUIQWKTRH-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
230000002093 peripheral effect Effects 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
239000004417 polycarbonate Substances 0.000 description 1
229920000515 polycarbonate Polymers 0.000 description 1
238000006068 polycondensation reaction Methods 0.000 description 1
229920000193 polymethacrylate Polymers 0.000 description 1
229920000166 polytrimethylene carbonate Polymers 0.000 description 1
238000011085 pressure filtration Methods 0.000 description 1
230000008569 process Effects 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
NTUCQKRAQSWLOP-UHFFFAOYSA-N propan-2-yloxymethylbenzene Chemical compound CC(C)OCC1=CC=CC=C1 NTUCQKRAQSWLOP-UHFFFAOYSA-N 0.000 description 1
ILVGAIQLOCKNQA-UHFFFAOYSA-N propyl 2-hydroxypropanoate Chemical class CCCOC(=O)C(C)O ILVGAIQLOCKNQA-UHFFFAOYSA-N 0.000 description 1
RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
JREWFSHZWRKNBM-UHFFFAOYSA-N pyridine-2,3,4,5-tetracarboxylic acid Chemical compound OC(=O)C1=CN=C(C(O)=O)C(C(O)=O)=C1C(O)=O JREWFSHZWRKNBM-UHFFFAOYSA-N 0.000 description 1
230000005855 radiation Effects 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
230000004044 response Effects 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
238000005070 sampling Methods 0.000 description 1
238000007650 screen-printing Methods 0.000 description 1
150000003335 secondary amines Chemical group 0.000 description 1
208000012201 sexual and gender identity disease Diseases 0.000 description 1
208000015891 sexual disease Diseases 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
230000007480 spreading Effects 0.000 description 1
238000003892 spreading Methods 0.000 description 1
LZOZLBFZGFLFBV-UHFFFAOYSA-N sulfene Chemical compound C=S(=O)=O LZOZLBFZGFLFBV-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1
150000003512 tertiary amines Chemical group 0.000 description 1
UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
IIYFAKIEWZDVMP-NJFSPNSNSA-N tridecane Chemical group CCCCCCCCCCCC[14CH3] IIYFAKIEWZDVMP-NJFSPNSNSA-N 0.000 description 1
SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
239000013638 trimer Substances 0.000 description 1
238000002604 ultrasonography Methods 0.000 description 1
238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
KLNPWTHGTVSSEU-UHFFFAOYSA-N undecane-1,11-diamine Chemical compound NCCCCCCCCCCCN KLNPWTHGTVSSEU-UHFFFAOYSA-N 0.000 description 1
150000003671 uranium compounds Chemical class 0.000 description 1
229940070710 valerate Drugs 0.000 description 1
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
239000013585 weight reducing agent Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers

Landscapes

Physics & Mathematics (AREA)
Chemical & Material Sciences (AREA)
Nonlinear Science (AREA)
Mathematical Physics (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Medicinal Chemistry (AREA)
Spectroscopy & Molecular Physics (AREA)
Health & Medical Sciences (AREA)
Crystallography & Structural Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
General Physics & Mathematics (AREA)
Optics & Photonics (AREA)
Liquid Crystal (AREA)
Compositions Of Macromolecular Compounds (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

TW104137540A 2014-11-13 2015-11-13 液晶配向處理劑、液晶配向膜及液晶顯示元件 TWI635122B (zh)

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KR (1)	KR102482056B1 (ja)
CN (1)	CN107003566B (ja)
TW (1)	TWI635122B (ja)
WO (1)	WO2016076413A1 (ja)

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JP2019070747A (ja) *	2017-10-10	2019-05-09	シャープ株式会社	液晶表示装置
CN113260910B (zh) *	2018-12-27	2024-11-19	日产化学株式会社	液晶取向处理剂、液晶取向膜以及液晶显示元件
WO2022256951A1 (en) *	2021-06-07	2022-12-15	Dupont Electronics, Inc.	Polymers for use in electronic devices

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JP3201172B2 (ja)	1994-09-08	2001-08-20	ジェイエスアール株式会社	液晶配向剤
JP3405607B2 (ja) *	1994-10-13	2003-05-12	触媒化成工業株式会社	配向膜形成用塗布液および液晶表示セル
JP2980080B2 (ja)	1997-10-09	1999-11-22	ジェイエスアール株式会社	液晶配向剤
JP5003682B2 (ja) *	2006-07-28	2012-08-15	日産化学工業株式会社	液晶配向処理剤及びそれを用いた液晶表示素子
CN101600989B (zh) *	2006-11-01	2012-01-25	日产化学工业株式会社	液晶定向处理剂及使用了该处理剂的液晶显示元件
KR101536028B1 (ko) *	2008-01-11	2015-07-10	닛산 가가쿠 고교 가부시키 가이샤	액정 배향 처리제, 및 그것을 사용한 액정 표시 소자
TWI554599B (zh) *	2012-03-08	2016-10-21	Dainippon Ink & Chemicals	Liquid crystal display device

2015
- 2015-11-13 JP JP2016559113A patent/JP6575770B2/ja active Active
- 2015-11-13 CN CN201580061921.1A patent/CN107003566B/zh active Active
- 2015-11-13 TW TW104137540A patent/TWI635122B/zh active
- 2015-11-13 WO PCT/JP2015/081948 patent/WO2016076413A1/ja not_active Ceased
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CN107003566A (zh)	2017-08-01
KR20170072223A (ko)	2017-06-26
JPWO2016076413A1 (ja)	2017-08-24
CN107003566B (zh)	2020-12-04
JP6575770B2 (ja)	2019-09-18
KR102482056B1 (ko)	2022-12-27
WO2016076413A1 (ja)	2016-05-19
TW201634589A (zh)	2016-10-01

Publication	Publication Date	Title
CN104136542B (zh)	2016-05-25	组合物、液晶取向处理剂、液晶取向膜及液晶显示元件
KR102224531B1 (ko)	2021-03-05	액정 배향 처리제, 액정 배향막 및 액정 표시 소자
CN105164579B (zh)	2018-03-09	聚合物、液晶取向处理剂、液晶取向膜和液晶表示元件
TWI628232B (zh)	2018-07-01	液晶配向處理劑、液晶配向膜及液晶顯示元件
TWI638008B (zh)	2018-10-11	Liquid crystal alignment treatment agent, liquid crystal alignment film, and liquid crystal display element
CN105074557B (zh)	2018-08-07	液晶取向处理剂、液晶取向膜和液晶表示元件
JP2018028694A (ja)	2018-02-22	組成物及び樹脂皮膜
TWI623518B (zh)	2018-05-11	Liquid crystal alignment treatment agent, liquid crystal alignment film, and liquid crystal display element
CN104956259A (zh)	2015-09-30	液晶取向处理剂、液晶取向膜及液晶显示元件
WO2012008464A1 (ja)	2012-01-19	液晶配向処理剤、液晶配向膜及び液晶表示素子
JPWO2015012368A1 (ja)	2017-03-02	液晶表示素子、液晶配向処理剤、及び液晶配向膜
TWI635122B (zh)	2018-09-11	液晶配向處理劑、液晶配向膜及液晶顯示元件
KR20140120353A (ko)	2014-10-13	액정 배향 처리제, 액정 배향막 및 액정 표시 소자
CN105190415B (zh)	2017-11-10	液晶取向处理剂、液晶取向膜和液晶表示元件
TWI588190B (zh)	2017-06-21	Liquid crystal alignment treatment agent, liquid crystal alignment film and liquid crystal display element