TWI625776B - Semiconductor device manufacturing method, semiconductor device, and protective tape - Google Patents
Semiconductor device manufacturing method, semiconductor device, and protective tape Download PDFInfo
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Abstract
本發明提供一種可減少突起電極之破損之半導體裝置之製造方法。 The present invention provides a method of fabricating a semiconductor device capable of reducing breakage of a bump electrode.
本發明之半導體裝置之製造方法具有:保護帶貼附步驟,其係於形成有突起電極之晶圓面貼附具有接著劑層之保護帶;研磨處理步驟,其係對保護帶貼附面之相反面進行研磨處理;黏著帶貼附步驟,其係於研磨處理面貼附黏著帶;切晶處理步驟,其係對貼附有黏著帶之晶圓進行切晶處理而獲得單片半導體晶片;及硬化步驟,其係使接著劑層硬化;且硬化步驟係於切晶處理步驟前進行。 A method of manufacturing a semiconductor device according to the present invention includes: a protective tape attaching step of attaching a protective tape having an adhesive layer to a wafer surface on which a protruding electrode is formed; and a polishing processing step of attaching a protective tape to the surface The opposite side is subjected to a grinding treatment; the adhesive tape attaching step is performed by attaching an adhesive tape to the polishing treatment surface; and the dicing treatment step is performed by performing a dicing treatment on the wafer to which the adhesive tape is attached to obtain a single semiconductor wafer; And a hardening step of hardening the adhesive layer; and the hardening step is performed before the dicing step.
Description
本發明係關於一種將前續步驟後之晶圓切分為單個半導體晶片之半導體裝置之製造方法。 The present invention relates to a method of fabricating a semiconductor device that diced a wafer after a previous step into individual semiconductor wafers.
先前,倒裝晶片構裝用之半導體製造程序之後續步驟係以如下方式進行。首先,於形成有複數個突起電極之晶圓之突起電極形成面貼合被稱為背面研磨帶之黏著片或黏著帶,並於該狀態下將突起電極形成面之相反面研削至特定厚度。研削結束後,將背面研磨帶剝離,將晶圓切晶(dicing)而製成單個半導體晶片。繼而,將半導體晶片倒裝晶片構裝於另一半導體晶片或基板上。又,使先供給型或後供給型之底膠硬化而對半導體晶片進行補強。 Previously, the subsequent steps of the semiconductor fabrication process for flip chip fabrication were performed as follows. First, an adhesive sheet or an adhesive tape called a back surface polishing tape is bonded to a bump electrode forming surface of a wafer on which a plurality of bump electrodes are formed, and in this state, the opposite surface of the bump electrode forming surface is ground to a specific thickness. After the grinding is completed, the back surface polishing tape is peeled off, and the wafer is diced to form a single semiconductor wafer. The semiconductor wafer is then flip-chip mounted onto another semiconductor wafer or substrate. Further, the first supply type or the post supply type primer is cured to reinforce the semiconductor wafer.
然而,近年來,半導體晶片之厚度變薄為50μmt以下,故而於切晶、拾取、構裝等後續步驟中,有因外部壓力而導致半導體晶片之突起電極破損之情況。 However, in recent years, the thickness of the semiconductor wafer has been reduced to 50 μm or less. Therefore, in the subsequent steps such as dicing, picking, and mounting, the protruding electrodes of the semiconductor wafer may be damaged due to external pressure.
[專利文獻1]日本特開2005-28734號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2005-28734
本發明係鑒於上述先前之實際情況而提出者,提供一種可減少突起電極之破損之半導體裝置之製造方法。 The present invention has been made in view of the above-described actual circumstances, and provides a method of manufacturing a semiconductor device capable of reducing damage of a bump electrode.
為了解決上述課題,本發明之半導體裝置之製造方法之特徵在於具有:貼附步驟,其係於形成有突起電極之晶圓面貼附具有接著劑層之保護帶;研磨處理步驟,其係對上述保護帶貼附面之相反面進行研磨處理;黏著帶貼附步驟,其係於上述研磨處理面貼附黏著帶;切晶處理步驟,其係對貼附有上述黏著帶之晶圓進行切晶處理而獲得單片半導體晶片;及硬化步驟,其係使上述接著劑層硬化;且上述硬化步驟係於上述切晶處理步驟前進行。 In order to solve the above problems, a method of manufacturing a semiconductor device according to the present invention is characterized in that: a bonding step of attaching a protective tape having an adhesive layer to a wafer surface on which a bump electrode is formed; and a polishing process step Grinding treatment is performed on the opposite side of the protective tape attachment surface; the adhesive tape attaching step is attached to the polishing treatment surface to adhere the adhesive tape; and the crystal cutting treatment step is to cut the wafer to which the adhesive tape is attached a single-piece semiconductor wafer obtained by crystal treatment; and a hardening step of hardening the above-mentioned adhesive layer; and the hardening step is performed before the above-described crystal cutting treatment step.
又,本發明之半導體裝置之特徵在於具備:半導體晶片,其具有突起電極與形成於突起電極形成面之接著劑層;及電路基板,其具有與上述突起電極對向之電極。 Moreover, the semiconductor device of the present invention includes a semiconductor wafer including a bump electrode and an adhesive layer formed on a surface on which the bump electrode is formed, and a circuit substrate having an electrode facing the bump electrode.
又,本發明係一種上述半導體裝置之製造方法中所使用之保護帶,其特徵在於:將接著劑層、熱塑性樹脂層、及基材膜層依序積層而成。 Moreover, the present invention is a protective tape used in the method for producing a semiconductor device described above, characterized in that the adhesive layer, the thermoplastic resin layer, and the base film layer are sequentially laminated.
根據本發明,於切晶處理步驟前使形成有突起電極之晶圓面之接著劑層硬化而對突起電極進行補強,故而於切晶、拾取、構裝等後續步驟中,可減少突起電極之破損。 According to the present invention, the adhesive layer of the wafer surface on which the bump electrode is formed is hardened to reinforce the bump electrode before the dicing step, so that the bump electrode can be reduced in subsequent steps such as dicing, picking, and mounting. damaged.
10‧‧‧保護帶 10‧‧‧Protective zone
11‧‧‧接著劑層 11‧‧‧ adhesive layer
12‧‧‧熱塑性樹脂層 12‧‧‧ thermoplastic resin layer
13‧‧‧基材膜層 13‧‧‧Substrate film
21‧‧‧晶圓 21‧‧‧ wafer
22‧‧‧突起電極 22‧‧‧ protruding electrode
30‧‧‧黏著帶 30‧‧‧Adhesive tape
31‧‧‧黏著劑層 31‧‧‧Adhesive layer
32‧‧‧基材膜層 32‧‧‧Substrate film
圖1係表示保護帶之概略之剖面圖。 Fig. 1 is a schematic cross-sectional view showing a protective tape.
圖2係表示保護帶貼附步驟之概略之剖面圖。 Fig. 2 is a schematic cross-sectional view showing a step of attaching a protective tape.
圖3係表示研磨步驟之概略之剖面圖。 Fig. 3 is a schematic cross-sectional view showing a grinding step.
圖4係表示黏著帶貼附步驟之概略之剖面圖。 Fig. 4 is a schematic cross-sectional view showing the step of attaching the adhesive tape.
圖5係表示保護帶剝離步驟之概略之剖面圖。 Fig. 5 is a schematic cross-sectional view showing a step of peeling off the protective tape.
圖6係表示硬化步驟之概略之剖面圖。 Fig. 6 is a schematic cross-sectional view showing a hardening step.
圖7係表示切晶處理步驟之概略之剖面圖。 Fig. 7 is a schematic cross-sectional view showing a dicing process step.
圖8係表示延伸步驟之概略之剖面圖。 Fig. 8 is a schematic cross-sectional view showing an extension step.
圖9係表示拾取步驟之概略之剖面圖。 Fig. 9 is a schematic cross-sectional view showing a pickup step.
圖10係表示構裝步驟之概略之剖面圖。 Figure 10 is a cross-sectional view showing the outline of the constitutional steps.
以下,按照下述順序對於本發明之實施形態詳細地進行說明。 Hereinafter, embodiments of the present invention will be described in detail in the following order.
1.半導體裝置之製造方法 1. Method of manufacturing a semiconductor device
2.實施例 2. Examples
<1.半導體裝置之製造方法> <1. Method of Manufacturing Semiconductor Device>
本實施形態之半導體裝置之製造方法具有:保護帶貼附步驟,其係於形成有突起電極之晶圓面貼附具有接著劑層之保護帶;研磨處理步驟,其係對保護帶貼附面之相反面進行研磨處理;黏著帶貼附步驟,其係於研磨處理面貼附黏著帶;切晶處理步驟,其係對貼附有黏著帶之晶圓進行切晶處理而獲得單片半導體晶片;及硬化步驟,其係使接著劑層硬化;且硬化步驟係於切晶處理步驟前進行。即,硬化步驟係於研磨處理步驟、黏著帶貼附步驟、或切晶處理步驟中之任一步驟前進行。 A method of manufacturing a semiconductor device according to the present embodiment includes a protective tape attaching step of attaching a protective tape having an adhesive layer to a wafer surface on which a bump electrode is formed, and a polishing processing step of attaching a protective tape to the protective tape The opposite side is subjected to a grinding process; the adhesive tape attaching step is to attach the adhesive tape to the polishing treatment surface; and the dicing treatment step is to perform a dicing process on the wafer to which the adhesive tape is attached to obtain a single semiconductor wafer And a hardening step of hardening the adhesive layer; and the hardening step is performed before the dicing step. That is, the hardening step is performed before any of the steps of the grinding treatment step, the adhesive tape attaching step, or the dicing treatment step.
保護帶之接著劑層之接著劑例如可使用熱陰離子硬化型、熱陽離子硬化型、熱自由基硬化型等熱硬化型,光陽離子硬化型、光自由基硬化型等光硬化型,或將該等併用而大致同樣地使用之熱/光硬化型者。 As the adhesive for the adhesive layer of the protective tape, for example, a thermosetting type such as a thermal anion curing type, a thermal cation hardening type, or a thermal radical curing type, a photocuring type such as a photocation hardening type or a photo radical curing type, or the like may be used. A heat/light hardening type that is used in the same manner as the above.
又,保護帶較佳為依序積層有接著劑層、熱塑性樹脂層、及基材膜層,且於研磨處理步驟後,進而具有將熱塑性樹脂層及基材膜層剝離之剝離步驟。即,剝離步驟係於研磨處理步驟、黏著帶貼附步驟、或切晶處理步驟中之任一步驟後進行。藉此,可將接著劑層轉黏於形成有突起電極之晶圓面,可對突起電極形成面進行補強。 Further, the protective tape preferably has an adhesive layer, a thermoplastic resin layer, and a base film layer laminated in this order, and further has a peeling step of peeling off the thermoplastic resin layer and the base film layer after the polishing treatment step. That is, the peeling step is performed after any one of the polishing treatment step, the adhesive tape attaching step, or the crystal cutting treatment step. Thereby, the adhesive layer can be transferred to the wafer surface on which the bump electrode is formed, and the bump electrode forming surface can be reinforced.
又,較佳為於剝離步驟後,進而具有將突起電極上之接著劑之殘渣去除之去除步驟。藉此,可防止構裝時之連接不良。又,去除步驟較佳為於硬化步驟後進行。藉此,可簡便地去除接著劑之殘渣。 Moreover, it is preferable to have a removal step of removing the residue of the adhesive on the bump electrode after the peeling step. Thereby, it is possible to prevent poor connection at the time of construction. Further, the removing step is preferably performed after the hardening step. Thereby, the residue of the adhesive can be easily removed.
根據此種半導體裝置之製造方法,於切晶處理步驟前使形成有突起電極之晶圓面之接著劑層硬化而對突起電極進行補強,故而於切晶、拾取、構裝等後續步驟中,可減少突起電極之破損。 According to the method of manufacturing a semiconductor device, the adhesive layer on the wafer surface on which the bump electrode is formed is cured before the dicing step, and the bump electrode is reinforced. Therefore, in subsequent steps such as dicing, picking, and mounting, The damage of the protruding electrodes can be reduced.
以下,對具體之半導體裝置之製造方法進行說明。作為具體例所示之半導體裝置之製造方法如下,即保護帶之接著劑層為熱硬化型,且於黏著帶貼附步驟與切晶處理步驟之間進行硬化步驟。即,作為具體例所示之半導體裝置之製造方法具有:保護帶貼附步驟(A),其係貼附具有接著劑層之保護帶;研磨步驟(B);黏著帶貼附步驟(C);保護帶剝離步驟(D);硬化步驟(E),其係使接著劑層硬化;切晶處理步驟(F);延伸(expanded)步驟(G);拾取步驟(H);及構裝步驟(I)。 Hereinafter, a method of manufacturing a specific semiconductor device will be described. The manufacturing method of the semiconductor device shown as a specific example is as follows, that is, the adhesive layer of the protective tape is a thermosetting type, and a hardening step is performed between the adhesive tape attaching step and the dicing processing step. That is, the manufacturing method of the semiconductor device shown as a specific example has a protective tape attaching step (A) to which a protective tape having an adhesive layer is attached, a polishing step (B), and an adhesive tape attaching step (C) a protective tape stripping step (D); a hardening step (E) for hardening the adhesive layer; a dicing treatment step (F); an extended step (G); a picking step (H); and a coating step (I).
[保護帶] [protective tape]
圖1係表示保護帶之概略之剖面圖。保護帶10係被稱為背面研磨帶(Back Grind Tape)者,且於研磨步驟中,保護晶圓免受刮傷、破裂、污染等。如圖1所示,保護帶10依序積層有接著劑層11、熱塑性樹脂層12、及基材膜層13。 Fig. 1 is a schematic cross-sectional view showing a protective tape. The protective tape 10 is referred to as a Back Grind Tape, and protects the wafer from scratches, cracks, contamination, and the like in the polishing step. As shown in FIG. 1, the protective tape 10 is sequentially laminated with an adhesive layer 11, a thermoplastic resin layer 12, and a base film layer 13.
作為接著劑層11,只要為熱硬化型者,則並無特別限定,例如可使用陽離子硬化型接著劑、自由基硬化性樹脂等。陽離子硬化型接著劑含有熱陽離子聚合起始劑、及陽離子聚合起始劑,又,自由基硬化型接著劑含有自由基硬化性樹脂、及熱自由基聚合起始劑。 The adhesive layer 11 is not particularly limited as long as it is a thermosetting type, and for example, a cationic curing adhesive or a radical curable resin can be used. The cation-curing adhesive contains a thermal cationic polymerization initiator and a cationic polymerization initiator, and the radical-curable adhesive contains a radical curable resin and a thermal radical polymerization initiator.
作為陽離子硬化性樹脂,例如可列舉:雙酚A型環氧樹脂、雙酚F型環氧樹脂、酚醛清漆型環氧樹脂、氧環丁烷樹脂(oxetane resin)、脂環式環氧樹脂、及其等之改質環氧樹脂等,該等可單獨使用1種,亦可併用2種以上。 Examples of the cation curable resin include bisphenol A type epoxy resin, bisphenol F type epoxy resin, novolak type epoxy resin, oxetane resin, and alicyclic epoxy resin. And the like, etc., which may be used alone or in combination of two or more.
作為熱陽離子聚合起始劑,例如可列舉:苄基鋶鹽、噻吩鎓鹽、四氫噻吩鎓鹽、苄基銨鹽、吡啶鎓鹽、肼鎓鹽、羧酸酯、磺酸酯、胺醯亞胺等,該等可單獨使用1種,亦可併用2種以上。 Examples of the thermal cationic polymerization initiator include a benzyl sulfonium salt, a thiophene sulfonium salt, a tetrahydrothiophene sulfonium salt, a benzyl ammonium salt, a pyridinium salt, a phosphonium salt, a carboxylic acid ester, a sulfonate, and an amine hydrazine. The imine or the like may be used alone or in combination of two or more.
作為自由基硬化性樹脂,例如可列舉:環氧(甲基)丙烯酸酯類、(甲基)丙烯酸胺酯類、(甲基)丙烯酸酯低聚物等,該等可單獨使用1種,亦可併用2種以上。 Examples of the radically curable resin include epoxy (meth) acrylates, (meth) acrylate amides, and (meth) acrylate oligomers, and these may be used alone or in combination. Two or more types can be used in combination.
作為熱自由基聚合起始劑,可列舉:過氧化物、偶氮化合物等。作為過氧化物,可列舉:過氧化雙乙醯基化合物、過氧酯化合物、過氧化氫化合物、過氧化二碳酸酯化合物、過氧縮酮化合物、過氧化二烷基化合物、及過氧化酮化合物等,該等可單獨使用1種,亦可併用2種以上。 Examples of the thermal radical polymerization initiator include a peroxide and an azo compound. Examples of the peroxide include a peroxydiethyl fluorenyl compound, a peroxyester compound, a hydrogen peroxide compound, a peroxydicarbonate compound, a peroxyketal compound, a dialkyl peroxide compound, and a ketone peroxide. For the compound or the like, one type may be used alone or two or more types may be used in combination.
又,於接著劑中,作為其他成分,亦可根據目的適當調配膜形成樹脂、硬化促進劑、矽烷偶合劑、無機填料、丙烯酸橡膠等彈性體、碳黑等顏料。作為膜形成樹脂,例如可列舉:苯氧基樹脂、胺酯樹脂(urethane resin)、聚酯樹脂、苯乙烯-異戊二烯樹脂、丁腈樹脂(nitrile butadiene resin)等。 Further, as the other component, a film forming resin, a curing accelerator, a decane coupling agent, an inorganic filler, an elastomer such as an acryl rubber, or a pigment such as carbon black may be appropriately blended as the other component. Examples of the film-forming resin include a phenoxy resin, an urethane resin, a polyester resin, a styrene-isoprene resin, a nitrile butadiene resin, and the like.
又,接著劑層11之最低熔融黏度較佳為500Pa.s以上且15000Pa.s以下。若最低熔融黏度過低,則於保護帶貼附步驟(A)中,有產生空隙之情況,若最低熔融黏度過高,則無法使突起電極貫通接著劑層,而難以將接著劑填充於突起電極間。 Moreover, the lowest melt viscosity of the adhesive layer 11 is preferably 500 Pa. Above s and 15000Pa. s below. If the minimum melt viscosity is too low, voids may occur in the protective tape attaching step (A). If the minimum melt viscosity is too high, the protruding electrode cannot penetrate the adhesive layer, and it is difficult to fill the adhesive with the adhesive. Between the electrodes.
又,接著劑層11於60℃之彈性模數為1GPa以上且10GPa以下,較佳為1GPa以上且5GPa以下。無論彈性模數過大或過小,接著劑層11對突起電極之埋入性均變差。 Further, the elastic modulus of the adhesive layer 11 at 60 ° C is 1 GPa or more and 10 GPa or less, preferably 1 GPa or more and 5 GPa or less. Regardless of whether the elastic modulus is too large or too small, the embedding property of the adhesive layer 11 to the bump electrodes is deteriorated.
又,接著劑層11之厚度為形成於晶圓之突起電極之高度之10%以上且80%以下,較佳為30%以上且60%以下。若接著劑層11之厚度過小,則無法獲得補強突起電極之效果,若厚度過大,則有突起電極未貫通之情況。 Further, the thickness of the adhesive layer 11 is 10% or more and 80% or less, preferably 30% or more and 60% or less of the height of the bump electrode formed on the wafer. If the thickness of the adhesive layer 11 is too small, the effect of reinforcing the bump electrode cannot be obtained, and if the thickness is too large, the bump electrode may not penetrate.
作為熱塑性樹脂層12,可列舉:乙烯-乙酸乙烯酯共聚物(EVA:Ethylene Vinyl Acetate)、聚乙烯、聚丙烯、聚醯胺、聚縮醛、聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、氟樹脂、聚苯硫醚、聚苯乙烯、ABS樹脂、丙烯酸系樹脂、聚碳酸酯、聚胺酯、聚氯乙烯、聚苯醚等,該等可單獨使用1種,亦可併用2種以上。 Examples of the thermoplastic resin layer 12 include ethylene-vinyl acetate copolymer (EVA: Ethylene Vinyl Acetate), polyethylene, polypropylene, polyamine, polyacetal, polyethylene terephthalate, and polyparaphenylene. Butylene dicarboxylate, fluororesin, polyphenylene sulfide, polystyrene, ABS resin, acrylic resin, polycarbonate, polyurethane, polyvinyl chloride, polyphenylene ether, etc., which may be used alone or in combination. Use two or more types.
作為基材膜層13,可使用聚對苯二甲酸乙二酯、聚乙烯、 聚丙烯、聚酯等塑膠膜、或由紙、布、不織布等構成之多孔質基材。 As the base film layer 13, polyethylene terephthalate, polyethylene, or the like can be used. A plastic film such as polypropylene or polyester, or a porous substrate composed of paper, cloth, non-woven fabric or the like.
再者,保護帶並不限於上述構成,亦可於各層之表面或鄰接之層間形成其他層。 Further, the protective tape is not limited to the above configuration, and other layers may be formed on the surface of each layer or between adjacent layers.
[(A)保護帶貼附步驟] [(A) Protective tape attachment step]
圖2係表示保護帶貼附步驟之概略之剖面圖。於保護帶貼附步驟中,於形成有突起電極22之晶圓21面貼附保護帶10。 Fig. 2 is a schematic cross-sectional view showing a step of attaching a protective tape. In the protective tape attaching step, the protective tape 10 is attached to the surface of the wafer 21 on which the bump electrodes 22 are formed.
晶圓21具有形成於矽等之半導體表面之積體電路、及被稱為凸塊之連接用之突起電極22。晶圓21之厚度並無特別限定,較佳為200μm以上且1000μm以下。 The wafer 21 has an integrated circuit formed on the surface of a semiconductor such as germanium, and a bump electrode 22 for connection of bumps. The thickness of the wafer 21 is not particularly limited, but is preferably 200 μm or more and 1000 μm or less.
作為突起電極22,並無特別限定,例如可列舉:藉由焊料獲得之低熔點凸塊或高熔點凸塊、錫凸塊、銀-錫凸塊、銀-錫-銅凸塊、金凸塊、銅凸塊等。又,突起電極22之高度並無特別限制,較佳為10μm以上且200μm以下。 The bump electrode 22 is not particularly limited, and examples thereof include low melting point bumps or high melting point bumps obtained by solder, tin bumps, silver-tin bumps, silver-tin-copper bumps, and gold bumps. , copper bumps, etc. Further, the height of the bump electrode 22 is not particularly limited, but is preferably 10 μm or more and 200 μm or less.
保護帶10係於使突起電極22之形成面與接著劑層11接觸之狀態下進行貼合。保護帶10之接著劑層11之厚度為突起電極22之高度之10%以上且80%以下,故而突起電極22穿透接著劑層11而埋入至熱塑性樹脂層12。 The protective tape 10 is bonded in a state where the formation surface of the bump electrode 22 is in contact with the adhesive layer 11. The thickness of the adhesive layer 11 of the protective tape 10 is 10% or more and 80% or less of the height of the bump electrode 22, so that the bump electrode 22 penetrates the adhesive layer 11 and is buried in the thermoplastic resin layer 12.
於保護帶貼附步驟中,較佳為使用真空加壓式貼合機將保護帶層疊於晶圓面。藉此,可一面抑制空隙之產生,一面將接著劑填充至突起電極間。又,就減少空隙、提高晶圓密接性及防止晶圓研削後之翹曲之觀點而言,貼附溫度為25℃以上且100℃以下,較佳為40℃以上且80℃以下。 In the protective tape attaching step, it is preferable to laminate the protective tape on the wafer surface using a vacuum pressurizing laminator. Thereby, the adhesive can be filled between the bump electrodes while suppressing the occurrence of voids. Further, from the viewpoint of reducing voids, improving wafer adhesion, and preventing warpage after wafer grinding, the bonding temperature is 25° C. or higher and 100° C. or lower, preferably 40° C. or higher and 80° C. or lower.
[(B)研磨步驟] [(B) Grinding step]
圖3係表示研磨步驟之概略之剖面圖。於研磨步驟中,對保護帶10貼附面之相反面進行研磨處理。將貼附有保護帶10之晶圓21之相反面固定於研削裝置而進行研磨。研磨通常係進行至晶圓21之厚度成為50μm以上且600μm以下,但於本實施形態中,由於藉由接著劑層11而補強突起電極22,故而亦可研磨至50μm以下之厚度。 Fig. 3 is a schematic cross-sectional view showing a grinding step. In the grinding step, the opposite side of the attachment surface of the protective tape 10 is subjected to a grinding treatment. The opposite surface of the wafer 21 to which the protective tape 10 is attached is fixed to the grinding device for polishing. The polishing is usually carried out until the thickness of the wafer 21 is 50 μm or more and 600 μm or less. However, in the present embodiment, since the bump electrode 22 is reinforced by the adhesive layer 11, it can be polished to a thickness of 50 μm or less.
[(C)黏著帶貼附步驟] [(C) Adhesive tape attachment step]
圖4係表示黏著帶貼附步驟之概略之剖面圖。於黏著帶貼附步驟中,於研磨處理面貼附黏著帶30。黏著帶30係被稱為切晶帶(Dicing Tape)者,係於切晶步驟(F)中,用以保護、固定晶圓21,並保持至拾取步驟(H)之帶。 Fig. 4 is a schematic cross-sectional view showing the step of attaching the adhesive tape. In the adhesive tape attaching step, the adhesive tape 30 is attached to the polishing treatment surface. The adhesive tape 30, which is called a Dicing Tape, is used in the dicing step (F) to protect and fix the wafer 21 and to hold the tape to the picking step (H).
作為黏著帶30,並無特別限定,可使用公知者。通常,黏著帶30具有黏著劑層31、及基材膜層32。作為黏著劑層31,例如可列舉:聚乙烯系、丙烯酸系、橡膠系、胺酯系等之黏著劑。又,作為基材膜層32,可使用聚對苯二甲酸乙二酯、聚乙烯、聚丙烯、聚酯等塑膠膜、或由紙、布、不織布等構成之多孔質基材。又,作為黏著帶之貼附裝置及條件,並無特別限定,可使用公知之裝置及條件。 The adhesive tape 30 is not particularly limited, and a known one can be used. Generally, the adhesive tape 30 has an adhesive layer 31 and a base film layer 32. Examples of the pressure-sensitive adhesive layer 31 include an adhesive such as a polyethylene-based, acrylic-based, rubber-based or amine-ester-based adhesive. Further, as the base film layer 32, a plastic film such as polyethylene terephthalate, polyethylene, polypropylene, or polyester, or a porous substrate made of paper, cloth, or nonwoven fabric can be used. Moreover, the attachment means and conditions of the adhesive tape are not particularly limited, and known devices and conditions can be used.
[(D)保護帶剝離步驟] [(D) Protective tape stripping step]
圖5係表示保護帶剝離步驟之概略之剖面圖。於保護帶剝離步驟中,將保護帶10之熱塑性樹脂層12及基材膜層13剝離。即,將熱塑性樹脂層12及基材膜層13去除,於晶圓21上僅殘留接著劑層11。 Fig. 5 is a schematic cross-sectional view showing a step of peeling off the protective tape. In the protective tape peeling step, the thermoplastic resin layer 12 and the base film layer 13 of the protective tape 10 are peeled off. That is, the thermoplastic resin layer 12 and the base film layer 13 are removed, and only the adhesive layer 11 remains on the wafer 21.
[(E)硬化步驟] [(E) hardening step]
圖6係表示硬化步驟之概略之剖面圖。於硬化步驟中,使接著劑層11硬化。作為硬化方法及硬化條件,可使用使熱硬化型接著劑硬化之公知之方法。 Fig. 6 is a schematic cross-sectional view showing a hardening step. In the hardening step, the adhesive layer 11 is hardened. As the curing method and the curing conditions, a known method of curing the thermosetting adhesive can be used.
又,較佳為於硬化步驟後進而具有將突起電極22上之接著劑之殘渣去除之去除步驟。藉此,可防止構裝時之連接不良。又,於去除步驟中,較佳為使用研磨粒進行研磨。藉此,可將接著劑之殘渣完全去除。又,研磨粒之平均粒徑較佳為3μm以下。藉此,可抑制突起電極22之削磨。 Further, it is preferable to further have a step of removing the residue of the adhesive on the bump electrode 22 after the hardening step. Thereby, it is possible to prevent poor connection at the time of construction. Further, in the removing step, it is preferred to use abrasive grains for polishing. Thereby, the residue of the adhesive can be completely removed. Further, the average particle diameter of the abrasive grains is preferably 3 μm or less. Thereby, the grinding of the bump electrode 22 can be suppressed.
[(F)切晶處理步驟] [(F) Crystal cutting process step]
圖7係表示切晶處理步驟之概略之剖面圖。於切晶處理步驟中,對貼附有黏著帶30之晶圓21進行切晶處理而獲得單片半導體晶片。作為切晶方法,並無特別限定,例如可使用利用晶圓切割機對晶圓21進行切削而將其切出等公知之方法。 Fig. 7 is a schematic cross-sectional view showing a dicing process step. In the dicing step, the wafer 21 to which the adhesive tape 30 is attached is subjected to a dicing process to obtain a single semiconductor wafer. The dicing method is not particularly limited, and for example, a known method such as cutting the wafer 21 by a wafer dicing machine and cutting it out can be used.
[(G)延伸步驟] [(G) Extension Step]
圖8係表示延伸步驟之概略之剖面圖。於延伸步驟中,例如將貼合有經分割之複數個半導體晶片之黏著帶30於放射方向上延伸,而擴大每個半導體晶片之間隔。 Fig. 8 is a schematic cross-sectional view showing an extension step. In the extending step, for example, the adhesive tape 30 to which the divided plurality of semiconductor wafers are bonded is extended in the radial direction to expand the interval between each semiconductor wafer.
[(H)拾取步驟] [(H) Pickup step]
圖9係表示拾取步驟之概略之剖面圖。於拾取步驟中,自黏著帶30之下表面將貼合固定於黏著帶30上之半導體晶片頂出並剝離,利用筒夾(collet)吸附該經剝離之半導體晶片。所拾取之半導體晶片被收納於晶片托盤,或搬送至倒裝晶片接合機之晶片搭載噴嘴。 Fig. 9 is a schematic cross-sectional view showing a pickup step. In the picking step, the semiconductor wafer attached to the adhesive tape 30 is ejected and peeled off from the lower surface of the adhesive tape 30, and the peeled semiconductor wafer is adsorbed by a collet. The picked semiconductor wafer is stored in a wafer tray or transferred to a wafer mounting nozzle of a flip chip bonding machine.
[(I)構裝步驟] [(I) Construction Steps]
圖10係表示構裝步驟之概略之剖面圖。於構裝步驟中,例如使用NCF(Non Conductive Film,非導電性膜)等電路連接材料將半導體晶片與電路基板進行連接。作為電路基板,並無特別限定,可使用聚醯亞胺基板、玻璃環氧基板等塑膠基板、陶瓷基板等。又,作為連接方法,可利用使用加熱接合機、回焊爐等之公知之方法。又,於該構裝步驟中,於半導體晶片之突起電極形成面形成有接著劑層11,故而可抑制空隙。 Figure 10 is a cross-sectional view showing the outline of the constitutional steps. In the structuring step, the semiconductor wafer is connected to the circuit substrate using, for example, a circuit connecting material such as NCF (Non Conductive Film). The circuit board is not particularly limited, and a plastic substrate such as a polyimide substrate or a glass epoxy substrate, a ceramic substrate, or the like can be used. Further, as the connection method, a known method using a heating bonding machine, a reflow furnace, or the like can be used. Further, in the bonding step, the adhesive layer 11 is formed on the surface on which the bump electrode is formed on the semiconductor wafer, so that the void can be suppressed.
藉由以上之方法,可良率良好地獲得具有優異之連接可靠性之半導體裝置。又,所獲得之半導體裝置具備:半導體晶片,其具有突起電極與形成於突起電極形成面之接著劑層;及電路基板,其具有與突起電極對向之電極。於半導體晶片之突起電極形成面形成有接著劑層11,故而可獲得優異之連接可靠性。 According to the above method, a semiconductor device having excellent connection reliability can be obtained with good yield. Further, the obtained semiconductor device includes a semiconductor wafer having a bump electrode and an adhesive layer formed on the surface on which the bump electrode is formed, and a circuit substrate having an electrode facing the bump electrode. Since the adhesive layer 11 is formed on the bump electrode forming surface of the semiconductor wafer, excellent connection reliability can be obtained.
[實施例] [Examples]
<2.實施例> <2. Example>
以下,對本發明之實施例進行說明。於本實施例中,製作積層有接著劑層、及熱塑性樹脂層之保護帶。然後,將保護帶貼附於形成有凸塊之晶圓面,觀察接著劑於凸塊間之填充狀態而對上述貼附方法進行評價。又,觀察凸塊而對凸塊上之接著劑之殘渣去除方法進行評價。再者,本發明並不限定於該等實施例。 Hereinafter, embodiments of the invention will be described. In the present embodiment, a protective tape in which an adhesive layer and a thermoplastic resin layer were laminated was produced. Then, the protective tape was attached to the wafer surface on which the bumps were formed, and the adhesion method was evaluated by observing the filling state of the adhesive between the bumps. Further, the bump was observed to evaluate the residue removal method of the adhesive on the bump. Furthermore, the invention is not limited to the embodiments.
<2.1關於保護帶之貼附方法> <2.1 About the attachment method of the protective tape>
對在形成有凸塊之晶圓面貼附保護帶時之接著劑層之最低熔融黏度之影響進行研究。 The effect of the lowest melt viscosity of the adhesive layer when the protective tape was attached to the wafer surface on which the bump was formed was investigated.
[貼附方法1] [attachment method 1]
製作於由PET(Polyethylene Terephthalate)構成之覆蓋膜上依序積層有由EVA(Ethylene Vinyl Acetate)構成之熱塑性樹脂層與彈性模數為2.5GPa及最低熔融黏度為50000Pa.s之厚度30μm之接著劑層的保護帶。 The thermoplastic resin layer composed of EVA (Ethylene Vinyl Acetate) is laminated on the cover film made of PET (Polyethylene Terephthalate) with an elastic modulus of 2.5 GPa and a minimum melt viscosity of 50,000 Pa. a protective tape of an adhesive layer of 30 μm thick.
將保護帶之接著劑層面貼附於形成有焊料凸塊(=250μm,H=150μm,間距=250μm)之晶圓(尺寸:5cm×5cm×50μmt),利用真空加壓式貼合機進行層疊。然後,於160℃之烘箱內固化1小時。觀察接著劑於凸塊間之填充狀態,結果焊料凸塊未貫通接著劑層。 Attaching the adhesive layer of the protective tape to the solder bumps formed ( Wafers (size: 5 cm × 5 cm × 50 μm) of = 250 μm, H = 150 μm, pitch = 250 μm) were laminated by a vacuum press type laminator. Then, it was cured in an oven at 160 ° C for 1 hour. The filling state of the adhesive between the bumps was observed, and as a result, the solder bump did not penetrate the adhesive layer.
[貼附方法2] [attachment method 2]
將接著劑層之彈性模數設為2.5GPa,將最低熔融黏度設為15000Pa.s,除此以外,以與貼附方法1相同之方式製作保護帶。然後,以與貼附方法1相同之方式層疊於晶圓並使其固化。觀察接著劑於凸塊間之填充狀態,結果接著劑以良好之狀態填充於凸塊間。然而,於凸塊上存在接著劑之殘渣。 The elastic modulus of the adhesive layer was set to 2.5 GPa, and the lowest melt viscosity was set to 15000 Pa. In addition to this, a protective tape was produced in the same manner as the attaching method 1. Then, it is laminated on the wafer and cured in the same manner as in the attachment method 1. The filling state of the adhesive between the bumps was observed, and as a result, the adhesive was filled between the bumps in a good state. However, there is a residue of the adhesive on the bump.
[貼附方法3] [attachment method 3]
將接著劑層之彈性模數設為2.5GPa,將最低熔融黏度設為2000Pa.s,除此以外,以與貼附方法1相同之方式製作保護帶。然後,以與貼附方法1相同之方式層疊於晶圓並使其固化。觀察接著劑於凸塊間之填充狀態,結果接著劑以良好之狀態填充於凸塊間。然而,於凸塊上存在接著劑之殘渣。 The elastic modulus of the adhesive layer was set to 2.5 GPa, and the lowest melt viscosity was set to 2000 Pa. In addition to this, a protective tape was produced in the same manner as the attaching method 1. Then, it is laminated on the wafer and cured in the same manner as in the attachment method 1. The filling state of the adhesive between the bumps was observed, and as a result, the adhesive was filled between the bumps in a good state. However, there is a residue of the adhesive on the bump.
[貼附方法4] [attachment method 4]
將接著劑層之彈性模數設為2.5GPa,將最低熔融黏度設為500Pa.s,除此以外,以與貼附方法1相同之方式製作保護帶。然後,以與貼附方法1 相同之方式層疊於晶圓並使其固化。觀察接著劑於凸塊間之填充狀態,結果接著劑以良好之狀態填充於凸塊間。然而,於凸塊上存在接著劑之殘渣。 The elastic modulus of the adhesive layer was set to 2.5 GPa, and the lowest melt viscosity was set to 500 Pa. In addition to this, a protective tape was produced in the same manner as the attaching method 1. Then, with the attachment method 1 The same method is laminated on the wafer and cured. The filling state of the adhesive between the bumps was observed, and as a result, the adhesive was filled between the bumps in a good state. However, there is a residue of the adhesive on the bump.
[貼附方法5] [attachment method 5]
將接著劑層之彈性模數設為2.5GPa,將最低熔融黏度設為100Pa.s,除此以外,以與貼附方法1相同之方式製作保護帶。然後,以與貼附方法1相同之方式層疊於晶圓並使其固化。觀察接著劑於凸塊間之填充狀態,結果於凸塊根部附近之接著劑產生空隙。 The elastic modulus of the adhesive layer was set to 2.5 GPa, and the lowest melt viscosity was set to 100 Pa. In addition to this, a protective tape was produced in the same manner as the attaching method 1. Then, it is laminated on the wafer and cured in the same manner as in the attachment method 1. The filling state of the adhesive between the bumps was observed, and as a result, voids were generated in the adhesive near the root of the bump.
[貼附方法6] [attachment method 6]
將接著劑層之彈性模數設為2.5GPa,將最低熔融黏度設為500Pa.s,除此以外,以與貼附方法1相同之方式製作保護帶。又,利用加壓式貼合機進行層疊,除此以外,以與貼附方法1相同之方式使其固化。觀察接著劑於凸塊間之填充狀態,結果於凸塊根部附近之接著劑產生空隙。 The elastic modulus of the adhesive layer was set to 2.5 GPa, and the lowest melt viscosity was set to 500 Pa. In addition to this, a protective tape was produced in the same manner as the attaching method 1. Further, it was laminated in the same manner as in the attachment method 1 except that it was laminated by a pressure bonding machine. The filling state of the adhesive between the bumps was observed, and as a result, voids were generated in the adhesive near the root of the bump.
將貼附方法1~6之評價結果一覽地示於表1中。 The evaluation results of the attachment methods 1 to 6 are shown in Table 1.
於如貼附方法1般接著劑層之最低熔融黏度過高之情形時,凸塊未貫通接著劑層,於如貼附方法5般接著劑層之最低熔融黏度過低之情形時,於凸塊根部附近產生空隙。又,於如貼附方法6般利用加壓 式貼合機層疊保護帶之情形時,亦於凸塊根部附近產生空隙。 When the lowest melt viscosity of the adhesive layer is too high as in the attaching method 1, the bump does not penetrate the adhesive layer, and when the lowest melt viscosity of the adhesive layer is too low as in the attaching method 5, the convexity is convex. A void is created near the root of the block. Moreover, the pressure is applied as in the attachment method 6 When the type of laminating machine is laminated with a protective tape, a gap is also generated in the vicinity of the root of the bump.
另一方面,於如貼附方法2~4般接著劑層之最低熔融黏度為500Pa.s以上且50000Pa.s以下,並利用真空加壓式貼合機層疊保護帶之情形時,可使接著劑以良好之狀態填充於凸塊間。 On the other hand, the minimum melt viscosity of the adhesive layer is 500Pa as in the attachment method 2~4. Above s and 50000Pa. In the case where the protective tape is laminated by a vacuum pressurizing laminator, the adhesive can be filled between the bumps in a good state.
<2.1關於殘渣之去除方法> <2.1 About the removal method of residue>
對利用貼附方法3貼附有保護帶的晶圓之凸塊上之接著劑之殘渣之去除方法進行研究。 The method of removing the residue of the adhesive on the bump of the wafer to which the protective tape was attached by the attaching method 3 was examined.
[去除方法1] [Removal method 1]
使用電漿乾式洗淨裝置(samco公司製造,氣體:Ar/H),於直接電漿模式下歷時15分鐘將晶圓之凸塊形成面洗淨。觀察凸塊,結果接著劑之殘渣未被去除。 The bump forming surface of the wafer was washed in a direct plasma mode for 15 minutes using a plasma dry cleaning apparatus (manufactured by Samco, gas: Ar/H). The bumps were observed, and as a result, the residue of the adhesive was not removed.
[去除方法2] [Removal method 2]
使用電漿乾式洗淨裝置(samco公司製造,氣體:Ar/H),於直接電漿模式下歷時30分鐘將晶圓之凸塊形成面洗淨。觀察凸塊,結果接著劑之殘渣未被去除。 The bump forming surface of the wafer was washed in a direct plasma mode for 30 minutes using a plasma dry cleaning apparatus (manufactured by Samco, gas: Ar/H). The bumps were observed, and as a result, the residue of the adhesive was not removed.
[去除方法3] [Removal method 3]
使用電漿乾式洗淨裝置(samco公司製造,氣體:Ar/H),於反應性離子蝕刻模式下歷時15分鐘將晶圓之凸塊形成面洗淨。觀察凸塊,結果接著劑之殘渣未被去除。 The bump forming surface of the wafer was washed in a reactive ion etching mode for 15 minutes using a plasma dry cleaning apparatus (manufactured by Samco, gas: Ar/H). The bumps were observed, and as a result, the residue of the adhesive was not removed.
[去除方法4] [Removal method 4]
使用電漿乾式洗淨裝置(samco公司製造,氣體:Ar/H),於反應性離子蝕刻模式下歷時30分鐘將晶圓之凸塊形成面洗淨。觀察凸塊,結果接著 劑之殘渣未被去除。 The bump forming surface of the wafer was washed in a reactive ion etching mode for 30 minutes using a plasma dry cleaning apparatus (manufactured by Samco, gas: Ar/H). Observing the bumps, the result is then The residue of the agent was not removed.
[去除方法5] [Removal method 5]
使用研磨機(Struers公司製造),利用平均粒徑(D50)為9μm之研磨粒歷時5分鐘對晶圓之凸塊形成面進行研磨。觀察凸塊,結果雖然接著劑之殘渣被去除,但可看到凸塊削磨。 The bump forming surface of the wafer was polished using a grinder (manufactured by Struers) using abrasive grains having an average particle diameter (D50) of 9 μm for 5 minutes. The bumps were observed, and as a result, although the residue of the adhesive was removed, the bump grinding was observed.
[去除方法6] [Removal method 6]
使用研磨機(Struers公司製造),利用平均粒徑(D50)為3μm之研磨粒歷時5分鐘對晶圓之凸塊形成面進行研磨。觀察凸塊,結果雖然接著劑之殘渣幾乎被去除,但一部分未被去除。又,未看到凸塊削磨。 The bump forming surface of the wafer was polished using a grinder (manufactured by Struers) using an abrasive grain having an average particle diameter (D50) of 3 μm for 5 minutes. The bump was observed, and as a result, although the residue of the adhesive was almost removed, a part was not removed. Also, no bump grinding was observed.
[去除方法7] [Removal method 7]
使用研磨機(Struers公司製造),利用平均粒徑(D50)為1μm之研磨粒歷時5分鐘對晶圓之凸塊形成面進行研磨。觀察凸塊,結果接著劑之殘渣被去除,亦未看到凸塊削磨。 The bump forming surface of the wafer was polished using a grinder (manufactured by Struers) using an abrasive grain having an average particle diameter (D50) of 1 μm for 5 minutes. The bumps were observed, and as a result, the residue of the adhesive was removed, and no bump grinding was observed.
[去除方法8] [Removal method 8]
不貼附保護帶,利用研磨紙對形成有凸塊之晶圓面研磨5分鐘。觀察凸塊,結果雖然接著劑之殘渣被去除,但於凸塊之根部附近可看到裂痕之產生。 The protective tape was not attached, and the wafer surface on which the bumps were formed was polished by the abrasive paper for 5 minutes. The bump was observed, and as a result, although the residue of the adhesive was removed, the occurrence of cracks was observed in the vicinity of the root of the bump.
將去除方法1~8之評價結果一覽地示於表2中。 The evaluation results of the removal methods 1 to 8 are shown in Table 2 in a list.
於如去除方法1~4般使用電漿乾式洗淨裝置之情形時,未能去除凸塊上之接著劑之殘渣。又,於如去除方法8般不貼附保護帶而利用研磨紙進行研磨之情形時,於凸塊之根部附近產生裂痕。 When the plasma dry cleaning device was used as in the removal methods 1 to 4, the residue of the adhesive on the bump was not removed. Further, in the case where the protective tape is attached without the protective tape as in the removal method 8, a crack is generated in the vicinity of the root portion of the bump.
另一方面,於如去除方法5~7般使用研磨粒進行研磨之情形時,可去除凸塊上之接著劑之殘渣。又,藉由使用平均粒徑為3μm以下之研磨粒,可抑制凸塊削磨。 On the other hand, in the case where the abrasive grains are used for polishing as in the removal methods 5 to 7, the residue of the adhesive on the bumps can be removed. Further, by using abrasive grains having an average particle diameter of 3 μm or less, the bump grinding can be suppressed.
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| JP6816918B2 (en) * | 2015-11-04 | 2021-01-20 | リンテック株式会社 | Manufacturing method of semiconductor devices |
| JP6989269B2 (en) * | 2016-05-11 | 2022-01-05 | 積水化学工業株式会社 | Manufacturing method of semiconductor package |
| JP6820724B2 (en) * | 2016-11-18 | 2021-01-27 | 積水化学工業株式会社 | Semiconductor device manufacturing method and protective tape |
| KR101877897B1 (en) * | 2017-03-06 | 2018-07-12 | 엘비세미콘 주식회사 | Methods of fabricating bump structure |
| KR102030398B1 (en) * | 2017-07-28 | 2019-10-10 | (주) 예스티 | A method and system for dicing wafer |
| KR102030409B1 (en) * | 2017-07-28 | 2019-10-10 | (주) 예스티 | A method and system for dicing wafer |
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| WO2020085220A1 (en) * | 2018-10-22 | 2020-04-30 | リンテック株式会社 | Semiconductor device manufacturing method |
| CN114930503A (en) * | 2019-12-27 | 2022-08-19 | 琳得科株式会社 | Kit and method for manufacturing semiconductor chip |
| WO2021171898A1 (en) * | 2020-02-27 | 2021-09-02 | リンテック株式会社 | Protective coating formation sheet, method for producing chip equipped with protective coating, and layered product |
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