TWI608105B - Titanium for hot rolling - Google Patents
Titanium for hot rolling Download PDFInfo
- Publication number
- TWI608105B TWI608105B TW105124213A TW105124213A TWI608105B TW I608105 B TWI608105 B TW I608105B TW 105124213 A TW105124213 A TW 105124213A TW 105124213 A TW105124213 A TW 105124213A TW I608105 B TWI608105 B TW I608105B
- Authority
- TW
- Taiwan
- Prior art keywords
- titanium
- surface layer
- hot rolling
- base material
- layer portion
- Prior art date
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims description 243
- 239000010936 titanium Substances 0.000 title claims description 233
- 229910052719 titanium Inorganic materials 0.000 title claims description 230
- 238000005098 hot rolling Methods 0.000 title claims description 83
- 239000000463 material Substances 0.000 claims description 201
- 239000002344 surface layer Substances 0.000 claims description 117
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 21
- 229910052742 iron Inorganic materials 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 229910052804 chromium Inorganic materials 0.000 claims description 8
- 229910052726 zirconium Inorganic materials 0.000 claims description 8
- 238000005259 measurement Methods 0.000 claims description 7
- 239000012467 final product Substances 0.000 claims description 5
- 210000001161 mammalian embryo Anatomy 0.000 description 63
- 239000010410 layer Substances 0.000 description 58
- 238000000034 method Methods 0.000 description 52
- 238000002844 melting Methods 0.000 description 32
- 230000008018 melting Effects 0.000 description 32
- 238000010438 heat treatment Methods 0.000 description 27
- 238000012360 testing method Methods 0.000 description 27
- 238000010894 electron beam technology Methods 0.000 description 26
- 238000004519 manufacturing process Methods 0.000 description 26
- 239000002131 composite material Substances 0.000 description 23
- 238000005275 alloying Methods 0.000 description 22
- 239000000956 alloy Substances 0.000 description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 18
- 238000005096 rolling process Methods 0.000 description 18
- 229910045601 alloy Inorganic materials 0.000 description 17
- 239000000155 melt Substances 0.000 description 13
- 238000005554 pickling Methods 0.000 description 13
- 230000007547 defect Effects 0.000 description 12
- 238000012545 processing Methods 0.000 description 12
- 238000007711 solidification Methods 0.000 description 12
- 238000005097 cold rolling Methods 0.000 description 11
- 239000011800 void material Substances 0.000 description 11
- 238000003466 welding Methods 0.000 description 11
- 239000000843 powder Substances 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 238000005520 cutting process Methods 0.000 description 9
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 8
- 239000011261 inert gas Substances 0.000 description 8
- 239000011148 porous material Substances 0.000 description 8
- 238000005266 casting Methods 0.000 description 7
- 239000011651 chromium Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000011162 core material Substances 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 238000005204 segregation Methods 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000012298 atmosphere Substances 0.000 description 6
- 239000010953 base metal Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000005336 cracking Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 238000004381 surface treatment Methods 0.000 description 5
- 229910000975 Carbon steel Inorganic materials 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 238000000137 annealing Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000005452 bending Methods 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 238000005121 nitriding Methods 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000006104 solid solution Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 230000035882 stress Effects 0.000 description 4
- 238000009864 tensile test Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002775 capsule Substances 0.000 description 3
- 239000010962 carbon steel Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000004453 electron probe microanalysis Methods 0.000 description 3
- 210000002257 embryonic structure Anatomy 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000009661 fatigue test Methods 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 150000003608 titanium Chemical class 0.000 description 3
- 208000010392 Bone Fractures Diseases 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- 229910017945 Cu—Ti Inorganic materials 0.000 description 2
- 206010017076 Fracture Diseases 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- 208000013201 Stress fracture Diseases 0.000 description 2
- 229910000905 alloy phase Inorganic materials 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000009703 powder rolling Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910001122 Mischmetal Inorganic materials 0.000 description 1
- 229910020012 Nb—Ti Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910000883 Ti6Al4V Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000004093 laser heating Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- -1 that is Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/02—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling heavy work, e.g. ingots, slabs, blooms, or billets, in which the cross-sectional form is unimportant ; Rolling combined with forging or pressing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K15/00—Electron-beam welding or cutting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/04—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating by means of a rolling mill
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/18—High-melting or refractory metals or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Metal Rolling (AREA)
- Welding Or Cutting Using Electron Beams (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015149394 | 2015-07-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201710518A TW201710518A (zh) | 2017-03-16 |
| TWI608105B true TWI608105B (zh) | 2017-12-11 |
Family
ID=57884558
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW105124213A TWI608105B (zh) | 2015-07-29 | 2016-07-29 | Titanium for hot rolling |
Country Status (3)
| Country | Link |
|---|---|
| JP (2) | JPWO2017018523A1 (ja) |
| TW (1) | TWI608105B (ja) |
| WO (1) | WO2017018523A1 (ja) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119194127B (zh) * | 2024-09-19 | 2025-04-18 | 西北有色金属研究院 | 一种高强钛合金扩散连接用箔材的制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014163087A1 (ja) * | 2013-04-01 | 2014-10-09 | 新日鐵住金株式会社 | 熱間圧延用チタン鋳片およびその製造方法 |
| JP2014233753A (ja) * | 2013-06-05 | 2014-12-15 | 新日鐵住金株式会社 | 分塊工程や精整工程を省略しても熱間圧延後の表面性状に優れた工業用純チタンインゴットおよびその製造方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3500072B2 (ja) * | 1998-07-27 | 2004-02-23 | 新日本製鐵株式会社 | 電解金属箔製造ドラム用チタン材およびその製造方法 |
| JP3802683B2 (ja) * | 1998-07-27 | 2006-07-26 | 新日本製鐵株式会社 | チタンターゲット材用高純度チタン板およびその製造方法 |
| JP4414983B2 (ja) * | 2006-06-15 | 2010-02-17 | 新日本製鐵株式会社 | チタン材の製造方法および熱間圧延用素材 |
| CN103717766B (zh) * | 2011-07-26 | 2016-11-23 | 新日铁住金株式会社 | 钛合金 |
| JP2016128172A (ja) * | 2013-04-01 | 2016-07-14 | 新日鐵住金株式会社 | 表面疵の発生し難いチタン熱間圧延用インゴットおよびその製造方法 |
| US10046373B2 (en) * | 2013-04-01 | 2018-08-14 | Nippon Steel & Sumitomo Metal Corporation | Titanium cast product for hot rolling and method for manufacturing same |
-
2016
- 2016-07-29 TW TW105124213A patent/TWI608105B/zh not_active IP Right Cessation
- 2016-07-29 WO PCT/JP2016/072345 patent/WO2017018523A1/ja not_active Ceased
- 2016-07-29 JP JP2017530943A patent/JPWO2017018523A1/ja active Pending
-
2019
- 2019-02-12 JP JP2019022697A patent/JP6848991B2/ja active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014163087A1 (ja) * | 2013-04-01 | 2014-10-09 | 新日鐵住金株式会社 | 熱間圧延用チタン鋳片およびその製造方法 |
| JP2014233753A (ja) * | 2013-06-05 | 2014-12-15 | 新日鐵住金株式会社 | 分塊工程や精整工程を省略しても熱間圧延後の表面性状に優れた工業用純チタンインゴットおよびその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2017018523A1 (ja) | 2017-12-21 |
| WO2017018523A1 (ja) | 2017-02-02 |
| JP2019115934A (ja) | 2019-07-18 |
| JP6848991B2 (ja) | 2021-03-24 |
| TW201710518A (zh) | 2017-03-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |