TWI601696B - Diffusion method - Google Patents
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- TWI601696B TWI601696B TW103106259A TW103106259A TWI601696B TW I601696 B TWI601696 B TW I601696B TW 103106259 A TW103106259 A TW 103106259A TW 103106259 A TW103106259 A TW 103106259A TW I601696 B TWI601696 B TW I601696B
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- ventilation
- slits
- air
- diffusing device
- slit
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- 238000009792 diffusion process Methods 0.000 title description 5
- 238000009423 ventilation Methods 0.000 claims description 24
- 239000012528 membrane Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
- 239000001301 oxygen Substances 0.000 description 12
- 229910052760 oxygen Inorganic materials 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000463 material Substances 0.000 description 8
- 239000002184 metal Substances 0.000 description 6
- 238000011282 treatment Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 3
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 2
- 102100027340 Slit homolog 2 protein Human genes 0.000 description 2
- 101710133576 Slit homolog 2 protein Proteins 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 101700004678 SLIT3 Proteins 0.000 description 1
- 102100027339 Slit homolog 3 protein Human genes 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Landscapes
- Aeration Devices For Treatment Of Activated Polluted Sludge (AREA)
Description
本發明係關於設置於下水處理施設等之槽內的管型膜式散氣裝置,尤其是,與於散氣膜設有多數縫隙之散氣裝置相關。此外,本發明係與利用該散氣裝置之散氣方法相關。 The present invention relates to a tubular membrane type diffusing device provided in a tank for a sewage treatment facility or the like, and particularly relates to a diffusing device having a plurality of slits in a diffusing film. Further, the present invention is related to a gas diffusion method using the air diffusing device.
水處理用之散氣裝置,以使用各種橡膠之膜式散氣裝置為大家所熟知。該等,因為氣泡直徑小,相較於傳統散氣裝置,因為氧移動效率高,而且,不易堵塞,故被利用於眾多水處理。 The air diffusing device for water treatment is well known as a membrane type diffusing device using various rubbers. These, because of the small diameter of the bubble, compared to the conventional air diffusing device, because of the high oxygen mobility and the difficulty in clogging, it is utilized in many water treatments.
散氣裝置所散氣之氣泡的直徑愈小,則氧移動效率愈高。所以,孔徑或縫隙長度必須縮小,然而,此時,壓力損失變大,而使鼓風機的負擔增大。 The smaller the diameter of the air bubbles scattered by the air diffusing device, the higher the oxygen moving efficiency. Therefore, the aperture or the slit length must be reduced, however, at this time, the pressure loss becomes large, and the burden of the blower is increased.
日本特許第4781302號(專利文獻1),記載著利用縫隙長度為2mm以下之管型膜式散氣裝置來使通風阻力成為10kPa以下,而且,以13Nm3/m2/hr以下來執行通風的散氣方法。該專利文獻1之散氣方法,係藉由減少單位膜面之通風量,來防止壓力損失上昇者。 Japanese Patent No. 4,871,302 (Patent Document 1) discloses a tubular membrane type air diffusing device having a slit length of 2 mm or less, and the ventilation resistance is 10 kPa or less, and the ventilation is performed at 13 Nm 3 /m 2 /hr or less. Gas diffusion method. The air diffusion method of Patent Document 1 prevents the increase in pressure loss by reducing the amount of ventilation per unit film surface.
第5圖係專利文獻1所記載之散氣裝置(管型膜擴散器)之一部分的縱剖面側面圖。於構成管型膜擴散器10之樹脂或金屬製管基材11的其中一端側開口部,連結著接頭15。接頭15,具有閉塞前述其中一端側之開口部的第1閉塞部16及第2閉塞部17,於第1閉塞部16及第2閉塞部17之間,形成有通風室20。 Fig. 5 is a longitudinal sectional side view showing a part of a diffusing device (tube type membrane diffuser) described in Patent Document 1. The joint 15 is connected to one end side opening of the resin or metal pipe base material 11 constituting the tubular film diffuser 10. The joint 15 has a first closing portion 16 and a second closing portion 17 that close the opening on the one end side, and a ventilating chamber 20 is formed between the first closing portion 16 and the second closing portion 17.
第2閉塞部17,具備有與空氣供應源連結之第1通風口18a的通風管18,於通風室20之周壁21,形成有複數之第2通風口19。管基材11之另一端側開口部11a處於開放狀態。 The second closing portion 17 is provided with a ventilation pipe 18 having a first ventilation port 18a connected to an air supply source, and a plurality of second ventilation ports 19 are formed in the peripheral wall 21 of the ventilation chamber 20. The other end side opening portion 11a of the tube base material 11 is in an open state.
管基材11及接頭15之外表面整體,為彈性薄膜(彈性膜)25所覆蓋。彈性薄膜25,係由乙丙橡膠等所構成之厚度約1.0~3.0mm的薄膜。 The entire outer surface of the tube base material 11 and the joint 15 is covered by an elastic film (elastic film) 25. The elastic film 25 is a film made of ethylene propylene rubber or the like and having a thickness of about 1.0 to 3.0 mm.
於彈性薄膜25之表面,形成有多數縫隙26。縫隙26之分布寬度,以儘可能發生口徑均一之氣泡的觀點而言,以長度2mm以下為佳,最好為1mm以下。縫隙26之分布密度為1~100條/cm2。 On the surface of the elastic film 25, a plurality of slits 26 are formed. The distribution width of the slits 26 is preferably 2 mm or less in length, and preferably 1 mm or less from the viewpoint of generating bubbles having a uniform diameter as much as possible. The distribution density of the slits 26 is 1 to 100 strips/cm 2 .
覆蓋於管基材開口部11a附近及其上的彈性薄膜25,係從外側被以金屬帶31束緊來加以固定,覆蓋於接頭之第1閉塞部17及其上之彈性薄膜25,係從外側被以金屬帶32束緊來加以固定。以金屬帶31、32固定之部分以外,未被固定。 The elastic film 25 covering the vicinity of the tube substrate opening portion 11a and the upper portion thereof is fixed by the metal tape 31 from the outside, and covers the first closing portion 17 of the joint and the elastic film 25 thereon. The outer side is fixed by a metal band 32. The portion fixed by the metal strips 31, 32 is not fixed.
[專利文獻1]日本特許第4781302號 [Patent Document 1] Japanese Patent No. 4,801,302
為了以高BOD容積負荷(例如,2kg/m3/d以上)使生物處理槽進行運轉,通風量必須增多,專利文獻1之散氣方法時,因為單位散氣裝置之通風量較少,散氣裝置數量必須增多,而提高成本。此外,有空間限制時,有時無法設置足夠數量之散氣裝置。 In order to operate the biological treatment tank with a high BOD volumetric load (for example, 2 kg/m 3 /d or more), the amount of ventilation must be increased. When the gas diffusion method of Patent Document 1 is used, the ventilation amount of the unit air diffusing device is small, The number of gas devices must be increased to increase costs. In addition, when there is space limitation, sometimes a sufficient number of air diffusers cannot be set.
本發明之目的,係在提供可以發生大量微細氣泡,而且,即使通風量較多,壓力損失上昇也較小的散氣裝置、以及利用該散氣裝置之散氣方法。 An object of the present invention is to provide a diffusing device which can generate a large amount of fine air bubbles and which has a small amount of ventilation, and which has a small increase in pressure loss, and a diffusing method using the diffusing device.
本發明之散氣裝置,係對於具有管基材、及覆蓋於該管基材之形成有用來產生微細氣泡之多數縫隙之彈性膜的管型膜式散氣裝置,以單位膜面積通風量為15Nm3/m2/hr以上來進行通風的散氣方法,其特徵為:該縫隙,係配列為交錯狀,長度為0.5mm以下,每1m2膜面設有20萬~60萬條。 The air diffusing device of the present invention is a tubular film type air diffusing device having a tube base material and an elastic film formed on the tube base material and forming a plurality of slits for generating fine bubbles, and the ventilation amount per unit membrane area is A method of diffusing air for ventilation of 15 Nm 3 /m 2 /hr or more is characterized in that the slits are arranged in a staggered manner and have a length of 0.5 mm or less, and 200,000 to 600,000 sheets per 1 m 2 of the film surface.
最好,該縫隙之長度為0.3~0.5mm。 Preferably, the length of the slit is 0.3 to 0.5 mm.
單位膜面積通風量以15~40Nm3/m2/hr為佳。 The ventilation per unit membrane area is preferably 15 to 40 Nm 3 /m 2 /hr.
藉由設置於彈性膜之縫隙長度為0.5mm以下、每1m2膜面之縫隙數為20萬~60萬條/m2,即使高通風量,壓力損失也不會上昇太大而可產生微細氣泡,進而 得到高氧移動效率。藉由使用厚度0.5~3.0mm之聚胺甲酸酯、EPDM、或矽氧橡膠做為彈性膜,即使縫隙數較多,也可以得到充份強度。 The gap length of the elastic film is 0.5 mm or less, and the number of slits per 1 m 2 of the film surface is 200,000 to 600,000 pieces/m 2 , and even if the ventilation volume is high, the pressure loss does not rise too much, and fine bubbles can be generated. In turn, high oxygen mobility is obtained. By using a polyurethane having a thickness of 0.5 to 3.0 mm, EPDM, or a silicone rubber as an elastic film, even if the number of slits is large, a sufficient strength can be obtained.
2‧‧‧縫隙 2‧‧‧ gap
3‧‧‧縫隙 3‧‧‧ gap
10‧‧‧管型膜擴散器 10‧‧‧ tubular membrane diffuser
11‧‧‧管基材 11‧‧‧Tube substrate
11a‧‧‧開口部 11a‧‧‧ Opening
15‧‧‧接頭 15‧‧‧Connector
16‧‧‧第1閉塞部 16‧‧‧1st occlusion department
17‧‧‧第2閉塞部 17‧‧‧2nd occlusion department
18‧‧‧通風管 18‧‧‧ ventilation pipe
18a‧‧‧第1通風口 18a‧‧‧1st vent
19‧‧‧第2通風口 19‧‧‧2nd vent
20‧‧‧通風室 20‧‧‧Ventilation room
21‧‧‧周壁 21‧‧‧Week wall
25‧‧‧彈性薄膜 25‧‧‧elastic film
26‧‧‧縫隙 26‧‧‧ gap
31‧‧‧金屬帶 31‧‧‧Metal strip
32‧‧‧金屬帶 32‧‧‧Metal strip
第1圖係實施方式之散氣裝置的縫隙配置說明圖。 Fig. 1 is an explanatory view showing a slit arrangement of a diffusing device of an embodiment.
第2圖係實施方式之散氣裝置的縫隙配置說明圖。 Fig. 2 is an explanatory view showing a slit arrangement of the diffusing device of the embodiment.
第3圖係實施方式之散氣裝置的縫隙配置說明圖。 Fig. 3 is an explanatory view showing a slit arrangement of the diffusing device of the embodiment.
第4圖係實施方式之散氣裝置的縫隙配置說明圖。 Fig. 4 is an explanatory view showing a slit arrangement of the diffusing device of the embodiment.
第5圖係傳統例之散氣裝置的部分剖面圖。 Fig. 5 is a partial sectional view showing a conventional air diffusing device.
以下,參照第1圖~第4圖,針對實施方式進行說明。 Hereinafter, an embodiment will be described with reference to FIGS. 1 to 4 .
本發明之散氣裝置,與前述第5圖之散氣裝置相同,係具有管基材、及覆蓋該管基材之彈性膜,於該彈性膜配設有多數縫隙者。管基材,以直徑50~120mm、長度500~1000mm程度者為佳。 The air diffusing device of the present invention has a tube base material and an elastic film covering the tube base material, and a plurality of slits are disposed in the elastic film, similarly to the air diffusing device of the fifth embodiment. The tube substrate is preferably 50 to 120 mm in diameter and 500 to 1000 mm in length.
本發明時,縫隙之長度為0.5mm以下,最好為0.3~0.5mm,彈性膜之每1m2膜面設有20萬~60萬條,以設有20萬~40萬條者為佳。 In the present invention, the length of the slit is 0.5 mm or less, preferably 0.3 to 0.5 mm, and the elastic film is provided with 200,000 to 600,000 sheets per 1 m 2 of the film surface, preferably 200,000 to 400,000.
彈性膜,以由聚胺甲酸酯、乙丙橡膠、或矽氧橡膠,厚度0.5~3mm,尤其是,0.5~1mm所構成者為 佳。 The elastic film is composed of polyurethane, ethylene propylene rubber, or silicone rubber, and has a thickness of 0.5 to 3 mm, especially 0.5 to 1 mm. good.
縫隙,如第1圖及第2圖所示,可以全部採用平行配列,也可以如第3圖及第4圖所示,配設成交叉狀。第1圖之L係表示縫隙2之長度。 The slits may be arranged in parallel as shown in Figs. 1 and 2, or may be arranged in a cross shape as shown in Figs. 3 and 4 . L in the first figure shows the length of the slit 2.
第1圖及第2圖時,係將所有縫隙2配列於圖之左右方向(以下,也稱為X方向)。第1圖時,縫隙2係配列成交錯狀,第2圖時,縫隙2係配列成格子狀。 In the first and second figures, all the slits 2 are arranged in the left-right direction of the figure (hereinafter, also referred to as the X direction). In the first drawing, the slits 2 are arranged in a staggered manner, and in the second drawing, the slits 2 are arranged in a lattice shape.
第3圖時,X方向之縫隙2及Y方向(與X垂直相交之方向)之縫隙3,皆交互地配列於X方向以及Y方向之任一方向。 In Fig. 3, the slit 2 in the X direction and the slit 3 in the Y direction (the direction perpendicular to X) are alternately arranged in either of the X direction and the Y direction.
第4圖時,以2條X方向縫隙2、2及2條Y方向縫隙3、3做為一組,將X方向之一組及Y方向之一組交互地配列於X方向及Y方向。第4圖時,以2條縫隙做為一組,然而,也可以3條以上之縫隙做為一組。 In the fourth drawing, the two X-direction slits 2, 2 and the two Y-direction slits 3, 3 are grouped together, and one of the X-direction groups and the Y-direction group are alternately arranged in the X direction and the Y direction. In the fourth figure, two slits are used as a group, however, three or more slits may be used as one group.
第1圖~第4圖所示之縫隙的配列係一例,本發明也可以為圖示以外的縫隙配列。 The arrangement of the slits shown in Figs. 1 to 4 is an example, and the present invention may be arranged in a slit other than the illustration.
本發明之散氣方法時,對於該散氣裝置,以單位膜面積通風量(每1m2膜之通風量)為15Nm3/m2/hr以上來進行通風,以15~40Nm3/m2/hr為佳。藉此,散氣裝置產生微細氣泡,而且,壓損之增大獲得抑制。 When the air diffusing method of the present invention, for the air diffuser, in the area of ventilation unit membrane (the amount of ventilation per 1m 2 film) was changed 15Nm 3 / m 2 / hr or more to be ventilated, to 15 ~ 40Nm 3 / m 2 /hr is better. Thereby, the air diffusing device generates fine bubbles, and the increase in pressure loss is suppressed.
[實施例] [Examples]
[實施例1~3、比較例1~5] [Examples 1 to 3, Comparative Examples 1 to 5]
對直徑90mm、長度760mm之圓筒形管基材,裝設第1圖所示之表1之構成的彈性膜(膜面積0.18m2、厚度0.8mm、材質聚胺甲酸酯),來構成散氣裝置。將各散氣裝置浸漬於裝滿清水之水槽(槽容量1.6m3(1m×0.4m×深度4m))。其次,比較例4以外,通風量為6Nm3/hr(33Nm3/m2/hr),只有比較例4以通風量為2Nm3/hr(11Nm3/m2/hr)來進行空氣之通風,測定壓力損失。 For a cylindrical tube substrate having a diameter of 90 mm and a length of 760 mm, an elastic film (film area: 0.18 m 2 , thickness: 0.8 mm, material polyurethane) having the composition shown in Table 1 shown in Fig. 1 was attached. Air diffuser. Each air diffusing device was immersed in a water tank filled with clean water (slot capacity: 1.6 m 3 (1 m × 0.4 m × depth 4 m)). Next, in addition to Comparative Example 4, the ventilation amount was 6 Nm 3 /hr (33 Nm 3 /m 2 /hr), and only Comparative Example 4 was ventilated with air at a ventilation amount of 2 Nm 3 /hr (11 Nm 3 /m 2 /hr). , measure the pressure loss.
氧移動效率(以kLa計算)、壓力損失、由該等所求取之氧溶解動力效率、及氧移動量如表1所示。 The oxygen mobility (calculated as kLa), the pressure loss, the oxygen dissolution power efficiency obtained by the above, and the oxygen movement amount are shown in Table 1.
如表1所示,實施例1~3時,相較於傳統被廣泛使用之比較例1,得到1.5倍以上之氧溶解動力效率及氧移動量。 As shown in Table 1, in the examples 1 to 3, the oxygen dissolution power efficiency and the oxygen movement amount were 1.5 times or more as compared with the conventionally used comparative example 1.
縫隙長度為1mm之比較例2、及縫隙數為15萬/m2之比較例3時,相較於比較例1,性能雖然獲得提 升,但是,都只停留於1.2倍程度。 In Comparative Example 2 in which the slit length was 1 mm and Comparative Example 3 in which the number of slits was 150,000/m 2 , the performance was improved as compared with Comparative Example 1, but only stayed at 1.2 times.
通風量較少之比較例4時,動力效率雖然比實施例1~3高,然而,氧移動量減少成比較例1之6成程度。所以,例如,以BOD容積負荷2kg/m3/d運轉生物處理槽時,考慮污泥中之溶解效率降低的話,氧供應不足,而必須增多散氣裝置數量。 In the case of Comparative Example 4 in which the amount of ventilation was small, the power efficiency was higher than that of Examples 1 to 3. However, the amount of oxygen movement was reduced to about 60% of Comparative Example 1. Therefore, for example, when the biological treatment tank is operated at a BOD volume load of 2 kg/m 3 /d, if the dissolution efficiency in the sludge is lowered, the oxygen supply is insufficient, and the number of the diffuser must be increased.
縫隙數為較多之80萬/m2的比較例5時,壓力損失雖然降低,然而,氧移動效率降低,氧移動量之提升停留於比較例1之1.3倍程度。此外,觀察從散氣裝置之氣泡發生方式時,確認到以下之情形,因為縫隙太過密集,所發生之氣泡會合於膜表面而粗大化。 In Comparative Example 5 in which the number of slits was 800,000/m 2 , the pressure loss was lowered, but the oxygen mobility was lowered, and the increase in the amount of oxygen movement was maintained at 1.3 times that of Comparative Example 1. Further, when observing the bubble generation mode from the air diffusing device, it was confirmed that the gap was too dense, and the generated bubbles were combined with the film surface to be coarsened.
以上,係以特定形態來針對本發明進行詳細說明,然而,只要在未背離本發明之意圖及範圍,相關業者當然可以進行各式各樣的變更。 The present invention has been described in detail with reference to the preferred embodiments thereof. However, various modifications may be made by those skilled in the art without departing from the spirit and scope of the invention.
本專利申請案,係以2012年11月26日所提出申請之日本特許出願2012-257569為基礎,其整體可以被引用來做為本專利之論述。 This patent application is based on Japanese Patent Application No. 2012-257569, filed on Nov. 26, 2012, which is hereby incorporated by reference in its entirety.
2‧‧‧縫隙 2‧‧‧ gap
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| TW103106259A TWI601696B (en) | 2014-02-25 | 2014-02-25 | Diffusion method |
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| TW103106259A TWI601696B (en) | 2014-02-25 | 2014-02-25 | Diffusion method |
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| TW201532973A TW201532973A (en) | 2015-09-01 |
| TWI601696B true TWI601696B (en) | 2017-10-11 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006061817A (en) * | 2004-08-26 | 2006-03-09 | Jfe Engineering Kk | Air diffuser |
| JP2008221158A (en) * | 2007-03-14 | 2008-09-25 | Daicen Membrane Systems Ltd | Aeration method and water treatment operation method |
| TW200920473A (en) * | 2007-10-10 | 2009-05-16 | Toray Industries | Microbubble diffuser pipe, microbubble diffuser device and soaking type membrane separation device |
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2014
- 2014-02-25 TW TW103106259A patent/TWI601696B/en active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006061817A (en) * | 2004-08-26 | 2006-03-09 | Jfe Engineering Kk | Air diffuser |
| JP2008221158A (en) * | 2007-03-14 | 2008-09-25 | Daicen Membrane Systems Ltd | Aeration method and water treatment operation method |
| TW200920473A (en) * | 2007-10-10 | 2009-05-16 | Toray Industries | Microbubble diffuser pipe, microbubble diffuser device and soaking type membrane separation device |
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| Publication number | Publication date |
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| TW201532973A (en) | 2015-09-01 |
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