TWI655890B - Fixture for electroplating or electroless plating process and machine - Google Patents
Fixture for electroplating or electroless plating process and machine Download PDFInfo
- Publication number
- TWI655890B TWI655890B TW106132969A TW106132969A TWI655890B TW I655890 B TWI655890 B TW I655890B TW 106132969 A TW106132969 A TW 106132969A TW 106132969 A TW106132969 A TW 106132969A TW I655890 B TWI655890 B TW I655890B
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- TW
- Taiwan
- Prior art keywords
- carrier
- perforations
- cover
- electroless plating
- electroplating
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 114
- 238000007772 electroless plating Methods 0.000 title claims abstract description 100
- 238000009713 electroplating Methods 0.000 title claims abstract description 69
- 239000010410 layer Substances 0.000 claims abstract description 66
- 239000000758 substrate Substances 0.000 claims abstract description 38
- 239000011241 protective layer Substances 0.000 claims abstract description 37
- 239000007788 liquid Substances 0.000 claims description 14
- 230000001681 protective effect Effects 0.000 claims description 8
- 238000007747 plating Methods 0.000 description 29
- 239000002184 metal Substances 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 20
- 238000005516 engineering process Methods 0.000 description 6
- 238000001465 metallisation Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011810 insulating material Substances 0.000 description 4
- 238000005240 physical vapour deposition Methods 0.000 description 4
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- -1 phosphite ions Chemical class 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/06—Suspending or supporting devices for articles to be coated
- C25D17/08—Supporting racks, i.e. not for suspending
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1619—Apparatus for electroless plating
- C23C18/1628—Specific elements or parts of the apparatus
- C23C18/163—Supporting devices for articles to be coated
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/12—Semiconductors
- C25D7/123—Semiconductors first coated with a seed layer or a conductive layer
- C25D7/126—Semiconductors first coated with a seed layer or a conductive layer for solar cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Chemically Coating (AREA)
Abstract
一種用於電鍍或無電鍍製程的治具包括:一載座;一載座保護層,於該電鍍或無電鍍製程進行時裝設於該載座上,並形成有一凹部,該凹部用以承載一待鍍基板;一上蓋保護層,於該電鍍或無電鍍製程進行時與該載座保護層結合以夾持該待鍍基板,藉此該上蓋保護層壓合該待鍍基板之一表面的環形邊緣區域;以及一上蓋,於該電鍍或無電鍍製程進行時與該載座結合以固定該載座保護層及上蓋保護層。 A fixture for an electroplating or electroless plating process includes: a carrier; and a carrier protective layer, which is disposed on the carrier during the electroplating or electroless plating process, and has a recess formed to carry a Substrate to be plated; an upper cover protection layer, which is combined with the carrier protection layer to hold the substrate to be plated during the electroplating or electroless plating process, thereby the upper cover protects and laminates a ring shape on a surface of the substrate to be plated An edge area; and an upper cover, which is combined with the carrier during the electroplating or electroless plating process to fix the carrier protective layer and the upper cover protective layer.
Description
本發明是有關於一種用於電鍍或無電鍍製程的治具及應用其之機台,且特別是有關於一種用於電鍍或無電鍍製程的治具及應用其之機台,其待鍍基板接觸到電鍍或無電鍍製程之處理液的區域只會在欲鍍區域。 The invention relates to a jig for electroplating or electroless plating process and a machine using the same, and particularly relates to a jig for electroplating or electroless plating process and a machine using the same. The substrate to be plated The areas that come into contact with the processing solution of the electroplating or electroless plating process will only be in the areas to be plated.
在太陽能電池的金屬化製程中,通常是以網版印刷正背面電極,搭配高溫燒結來形成正背面金屬接觸。然而,傳統式網印金屬漿料的材料價格過高。近期業者期望以電鍍金屬電極技術來取而代之,但電鍍技術需要憑藉一層晶種層(seed layer)來外加偏壓提供電子,通常是以物理氣相沉積(PVD)例如:濺鍍(Sputter)或蒸鍍(Evaporation)等方式成長晶種層,再搭配電鍍技術來形成金屬化電極。然而,真空設備成本也相對過高。 In the metallization process of solar cells, the front and back electrodes are usually printed by screen printing, and high temperature sintering is used to form the front and back metal contacts. However, the material cost of traditional screen printing metal paste is too high. Recently, the industry expects to replace it with electroplated metal electrode technology, but electroplating technology requires a seed layer to provide electrons with an external bias voltage, usually based on physical vapor deposition (PVD) such as sputtering or vapor deposition. The seed layer is grown by methods such as plating and then combined with electroplating technology to form metallized electrodes. However, the cost of vacuum equipment is relatively high.
因此,使用無電鍍技術(Electroless plating)取代網版印刷或物理氣相沉積(PVD)的技術,得以在電池正背面沉積上第一層的金屬晶種層,再經由直接接觸電鍍或順向偏壓電鍍的方式,完成正背面多層金屬化製程。然而,若以電鍍或無電鍍技術製作太陽能電池之金屬電極時,電池片接觸到電鍍或無電鍍化學溶液的區域,全部區域將覆蓋上金屬鍍層,無法選擇性只有鍍在欲鍍表面,也無法防止電池片的邊緣被鍍上金屬。由於邊緣金屬效應的影響,因此將導致電池片的正面及背面形成短路的現象,造成電池效率低落。 Therefore, using electroless plating technology instead of screen printing or physical vapor deposition (PVD) technology, the first metal seed layer can be deposited on the front and back of the battery, and then directly contact plating or forward bias The method of pressure plating completes the front and back multilayer metallization process. However, if the metal electrode of a solar cell is made by electroplating or electroless plating, the cell contacts the area of the electroplated or electroless chemical solution, and the entire area will be covered with a metal plating layer. Prevent the edges of the cell from being plated with metal. Due to the effect of the edge metal effect, a short circuit phenomenon will be formed on the front and back sides of the battery sheet, resulting in low battery efficiency.
因此,便有需要一種用於電鍍或無電鍍製程的治具及其機台,能克服上述問題。 Therefore, there is a need for a jig and a machine thereof for an electroplating or electroless plating process, which can overcome the above problems.
本發明之一目的是提供一種用於電鍍或無電鍍製程的治具及其機台,其待鍍基板接觸到電鍍或無電鍍製程之處理液的區域只會在欲鍍區域。 An object of the present invention is to provide a jig for use in an electroplating or electroless plating process and a machine thereof. The area where the substrate to be plated contacts the processing solution of the electroplating or electroless plating process is only in the area to be plated.
依據上述之目的,本發明提供一種用於電鍍或無電鍍製程的治具,包括:一載座;一載座保護層,於該電鍍或無電鍍製程進行時裝設於該載座上,並形成有一凹部,該凹部用以承載一待鍍基板;一上蓋保護層,於該電鍍或無電鍍製程進行時與該載座保護層結合以夾持該待鍍基板,藉此該上蓋保護層壓合該待鍍基板之一表面的環形邊緣區域;以及一上蓋,於該電鍍或無電鍍製程進行時與該載座結合以固定該載座保護層及上蓋保護層。 According to the above object, the present invention provides a jig for an electroplating or electroless plating process, including: a carrier; and a carrier protective layer, which is placed on the carrier during the electroplating or electroless plating process and formed. There is a recess, which is used to carry a substrate to be plated; an upper cover protection layer is combined with the carrier protection layer to hold the substrate to be plated when the electroplating or electroless plating process is performed, thereby the upper cover is protected and laminated An annular edge region on one surface of the substrate to be plated; and an upper cover, which is combined with the carrier during the electroplating or electroless plating process to fix the carrier protection layer and the upper cover protection layer.
根據本發明之用於電鍍或無電鍍製程的治具,若以電鍍或無電鍍技術製作太陽能電池之金屬電極時,單片電池片(亦即待鍍基板)接觸到電鍍或無電鍍製程之處理液的區域只會在欲鍍區域。由於單片電池片的邊緣及欲鍍區域之表面的另一面都不會被鍍上金屬,因此不會導致電池片的正面及背面形成短路的現象,造成電池效率低落。 According to the jig for electroplating or electroless plating process according to the present invention, if a metal electrode of a solar cell is produced by electroplating or electroless plating technology, a single cell (that is, a substrate to be plated) contacts the electroplating or electroless plating process. The liquid area will only be in the area to be plated. Since the edges of the single-cell battery and the other side of the surface to be plated are not plated with metal, it will not cause short-circuits on the front and back of the battery, resulting in low battery efficiency.
1‧‧‧治具 1‧‧‧ jig
1’‧‧‧治具 1’‧‧‧Jig
1”‧‧‧治具 1 ”‧‧‧Jig
1'''‧‧‧治具 1 '' '‧‧‧Jig
10‧‧‧待鍍基板 10‧‧‧Substrate to be plated
10a‧‧‧第一待鍍基板 10a‧‧‧First substrate to be plated
10b‧‧‧第二待鍍基板 10b‧‧‧Second substrate to be plated
101‧‧‧表面 101‧‧‧ surface
101a‧‧‧表面 101a‧‧‧ surface
101b‧‧‧表面 101b‧‧‧ surface
1011‧‧‧環形邊緣區域 1011‧‧‧Circular edge area
1011a‧‧‧環形邊緣區域 1011a‧‧‧Circular edge area
1011b‧‧‧環形邊緣區域 1011b‧‧‧Circular edge area
1012‧‧‧欲鍍區域 1012‧‧‧ Area to be plated
1012a‧‧‧欲鍍區域 1012a‧‧‧ Area to be plated
1012b‧‧‧欲鍍區域 1012b‧‧‧ Area to be plated
11‧‧‧載座 11‧‧‧ carrier
111‧‧‧載座穿孔 111‧‧‧Perforated carrier
112‧‧‧正面 112‧‧‧ Front
113‧‧‧背面 113‧‧‧ back
12‧‧‧載座保護層 12‧‧‧ carrier protection layer
12a‧‧‧第一載座保護層 12a‧‧‧First carrier protection layer
12b‧‧‧第二載座保護層 12b‧‧‧Second carrier protection layer
121‧‧‧凹部 121‧‧‧ recess
121a‧‧‧凹部 121a‧‧‧Concave
121b‧‧‧凹部 121b‧‧‧Concave
122‧‧‧載座保護層穿孔 122‧‧‧ Perforation of carrier protection layer
122a‧‧‧載座保護層穿孔 122a‧‧‧Perforated protective cover
122b‧‧‧載座保護層穿孔 122b‧‧‧Perforated protective cover
13‧‧‧上蓋保護層 13‧‧‧ Cover protection
13a‧‧‧第一上蓋保護層 13a‧‧‧First cover
13b‧‧‧第二上蓋保護層 13b‧‧‧Second top cover protective layer
131‧‧‧凸起部 131‧‧‧ raised
131a‧‧‧凸起部 131a‧‧‧ raised
131b‧‧‧凸起部 131b‧‧‧ raised
132‧‧‧上蓋保護層穿孔 132‧‧‧ Perforated protective cover
132a‧‧‧上蓋保護層穿孔 132a‧‧‧ Perforated protective cover
132b‧‧‧上蓋保護層穿孔 132b‧‧‧ Perforated protective cover
14‧‧‧上蓋 14‧‧‧ Upper cover
14a‧‧‧第一上蓋 14a‧‧‧First cover
14b‧‧‧第二上蓋 14b‧‧‧Second top cover
141‧‧‧第一上蓋穿孔 141‧‧‧ Perforation of the first upper cover
141a‧‧‧第一上蓋穿孔 141a‧‧‧perforation of the first cover
141b‧‧‧第一上蓋穿孔 141b‧‧‧ Perforated first cover
142‧‧‧第二上蓋穿孔 142‧‧‧ Perforated second upper cover
142a‧‧‧第二上蓋穿孔 142a‧‧‧ Perforation of the second upper cover
142b‧‧‧第二上蓋穿孔 142b‧‧‧ Perforation of the second upper cover
15‧‧‧螺絲 15‧‧‧Screw
15a‧‧‧螺絲 15a‧‧‧screw
15b‧‧‧螺絲 15b‧‧‧screw
151‧‧‧桿體區域 151‧‧‧ shaft area
152‧‧‧螺帽區域 152‧‧‧Nut area
16‧‧‧導電結構 16‧‧‧ conductive structure
16a‧‧‧第一導電結構 16a‧‧‧First conductive structure
16b‧‧‧第二導電結構 16b‧‧‧Second conductive structure
2‧‧‧機台 2‧‧‧machine
2’‧‧‧機台 2’‧‧‧machine
2”‧‧‧機台 2 ”‧‧‧machine
20‧‧‧待鍍基板 20‧‧‧Substrate to be plated
20’‧‧‧待鍍基板 20’‧‧‧Substrate to be plated
201‧‧‧表面 201‧‧‧ surface
2012‧‧‧欲鍍區域 2012‧‧‧Area to be plated
21‧‧‧第一治具 21‧‧‧The first jig
21’‧‧‧第二治具 21’‧‧‧Second Jig
22‧‧‧槽體 22‧‧‧ trough
23‧‧‧處理液 23‧‧‧treatment fluid
24‧‧‧支架 24‧‧‧ Bracket
241‧‧‧旋轉移動 241‧‧‧Rotate
圖1a為本發明之第一實施例之用於無電鍍製程的治具之平面示意圖。 FIG. 1a is a schematic plan view of a jig for an electroless plating process according to a first embodiment of the present invention.
圖1b為沿圖1a之剖線1b-1b之用於無電鍍製程的治具之組合剖面示意圖。 FIG. 1b is a schematic sectional view of the assembly of the jig used for the electroless plating process along the section line 1b-1b of FIG. 1a.
圖1c為沿圖1a之剖線1c-1c之用於無電鍍製程的治具之組合剖面示意圖。 FIG. 1c is a schematic sectional view of the assembly of the jig used for the electroless plating process along the section line 1c-1c of FIG. 1a.
圖2為本發明之第一實施例之用於無電鍍製程的治具之分解剖面示意圖。 2 is a schematic exploded cross-sectional view of a jig for an electroless plating process according to a first embodiment of the present invention.
圖3為本發明之另一實施例之用於無電鍍製程的治具之平面示意圖。 FIG. 3 is a schematic plan view of a jig for an electroless plating process according to another embodiment of the present invention.
圖4為本發明之第一實施例之用於電鍍製程的治具之剖面示意圖。 4 is a schematic cross-sectional view of a jig for a plating process according to a first embodiment of the present invention.
圖5a及圖5b為本發明之第二實施例之用於無電鍍製程的治具之組合剖面示意圖。 FIG. 5a and FIG. 5b are schematic sectional views of a combination of a jig for an electroless plating process according to a second embodiment of the present invention.
圖6為本發明之第二實施例之用於電鍍製程的治具之剖面示意圖。 FIG. 6 is a schematic cross-sectional view of a jig for a plating process according to a second embodiment of the present invention.
圖7為本發明之第一實施例之用於電鍍或無電鍍製程的機台之剖面示意圖。 FIG. 7 is a schematic cross-sectional view of a machine for a plating or electroless plating process according to a first embodiment of the present invention.
圖8為本發明之第一實施例之用於電鍍或無電鍍製程的機台之局部立體示意圖。 FIG. 8 is a partial perspective view of a machine for a plating or electroless plating process according to the first embodiment of the present invention.
圖9為本發明之第二實施例之用於電鍍或無電鍍製程的機台之局部立體示意圖。 FIG. 9 is a partial perspective view of a machine for a plating or electroless plating process according to a second embodiment of the present invention.
圖10為本發明之第三實施例之用於電鍍或無電鍍製程的機台之局部立體示意圖。 FIG. 10 is a partial perspective view of a machine for a plating or electroless plating process according to a third embodiment of the present invention.
為讓本發明之上述目的、特徵和特點能更明顯易懂,茲配合圖式將本發明相關實施例詳細說明如下。 In order to make the foregoing objects, features, and characteristics of the present invention more comprehensible, the related embodiments of the present invention are described in detail below with reference to the drawings.
圖1a為本發明之第一實施例之用於無電鍍製程的治具之平面示意圖。圖1b為沿圖1a之剖線1b-1b之用於無電鍍製程的治具之組合剖面示意圖。本實施之用於無電鍍製程的治具1是應用於單片太陽能電池片之電極金屬化製程。請參考圖1a及圖1b,用於無電鍍製程的治具1包括:一載座11、一載座保護層12、一上蓋保護層13及一上蓋14。該載座保護層12於該無電鍍製程進行時裝設於該載座11之一正面112上,並形成有一凹部121,該凹部121用以承載一待鍍基板10(例如太陽能電池片)。該上蓋 保護層13於該無電鍍製程進行時與該載座保護層12結合以夾持該待鍍基板10,藉此該上蓋保護層13壓合該待鍍基板10之一表面101的環形邊緣區域1011(該環形邊緣區域1011環繞該表面101的欲鍍區域1012)。特別是該上蓋保護層13與該環型邊緣區域1011之間完全密合不漏液。該上蓋14於該無電鍍製程進行時與該載座11結合以固定該載座保護層12及該上蓋保護層13。該載座11及該上蓋14可為耐熱/耐酸鹼之硬性絕緣材料所製,例如玻璃纖維、耐熱塑膠、或鐵氟龍等。該載座保護層12及該上蓋保護層13可為耐熱/耐酸鹼之軟性絕緣材料所製,例如矽膠或橡膠等。 FIG. 1a is a schematic plan view of a jig for an electroless plating process according to a first embodiment of the present invention. FIG. 1b is a schematic sectional view of the assembly of the jig used for the electroless plating process along the section line 1b-1b of FIG. 1a. The jig 1 for the electroless plating process of the present embodiment is an electrode metallization process applied to a single solar cell. Please refer to FIG. 1 a and FIG. 1 b. The jig 1 used for the electroless plating process includes a carrier 11, a carrier protective layer 12, a cover protective layer 13 and a cover 14. The carrier protection layer 12 is disposed on a front surface 112 of the carrier 11 during the electroless plating process, and a recess 121 is formed to carry a substrate 10 (such as a solar cell) to be plated.该 上盖 The cover The protective layer 13 is combined with the carrier protective layer 12 to hold the substrate 10 to be plated during the electroless plating process, whereby the cover protective layer 13 is pressed against the annular edge region 1011 of one surface 101 of the substrate 10 to be plated. (The annular edge region 1011 surrounds the region 1012 to be plated on the surface 101). In particular, the top cover protective layer 13 and the ring-shaped edge region 1011 are completely in contact with each other without leaking liquid. The upper cover 14 is combined with the carrier 11 during the electroless plating process to fix the carrier protection layer 12 and the upper cover protection layer 13. The carrier 11 and the upper cover 14 can be made of a heat-resistant / acid-resistant hard insulating material, such as glass fiber, heat-resistant plastic, or Teflon. The carrier protection layer 12 and the cover protection layer 13 may be made of a heat-resistant / acid-resistant soft insulating material, such as silicon rubber or rubber.
無電鍍製程一般可稱為自身催化鍍法(Autocatalytic Plating),先在工作物表面形成具有催化力的表面,或是利用工作物表面本身的催化作用,以化學還原方法,使金屬離子成金屬狀態析出。首先次磷酸根(還原劑)被氧化成亞磷酸根離子,釋出的電荷可使金屬離子(例如鎳離子)還原,金屬(例如鎳)沉積在具催化作用的活化表面上,而析出的金屬(例如鎳),又繼續催化反應的進行,所以析出反應連鎖進行,鍍層呈層狀結構,厚度可任意控制。 The electroless plating process can generally be called Autocatalytic Plating. First, a catalytic surface is formed on the surface of the work, or the catalytic action of the surface of the work is used to chemically reduce the metal ions into a metal state. Precipitation. First, hypophosphite (reducing agent) is oxidized to phosphite ions. The released charge can reduce metal ions (such as nickel ions). Metals (such as nickel) are deposited on the catalytically active surface, and the precipitated metal (For example, nickel), and the catalytic reaction continues to proceed, so the precipitation reaction proceeds in a chain, the plating layer has a layered structure, and the thickness can be arbitrarily controlled.
圖1c為沿圖1a之剖線1c-1c之用於無電鍍製程的治具之組合剖面示意圖。請參考圖1c,該上蓋14包括多個第一上蓋穿孔141,該上蓋保護層13包括多個凸起部131,該些凸起部131於該上蓋14與上蓋保護層13結合時分別穿過該些第一上蓋穿孔141而裸露出。該些凸起部131可避免該載座保護層12及該上蓋保護層13緊密結合後不易脫片的問題,進而輕易取出太陽能電池片。 FIG. 1c is a schematic sectional view of the assembly of the jig used for the electroless plating process along the section line 1c-1c of FIG. 1a. 1c, the upper cover 14 includes a plurality of first upper cover perforations 141, the upper cover protective layer 13 includes a plurality of raised portions 131, and the raised portions 131 pass through when the upper cover 14 is combined with the upper protective layer 13 respectively. The first upper covers are exposed through the through holes 141. The raised portions 131 can avoid the problem that the carrier protection layer 12 and the upper cover protection layer 13 are not easily separated after being closely combined, and the solar cell chip can be easily taken out.
圖2為本發明之第一實施例之用於無電鍍製程的治具之分解剖面示意圖。請參考圖2,該上蓋14更包括多個第二上蓋穿孔142,該上蓋14及該載座11的結合方式為以多個螺絲15分別穿過該些第二上蓋穿孔142而鎖入該載座11。該載座11包括多個載座穿孔111,該載座保護層12包括多個載座保護層穿孔122,該上蓋保護層13包括多個上蓋保護層穿孔132,該些載座穿 孔111、該些載座保護層穿孔122、該些上蓋保護層穿孔132及該些第二上蓋穿孔142依序對應而分別供該些螺絲15穿過,每一該些載座保護層穿孔122的孔徑(例如孔徑7mm)及每一該些上蓋保護層穿孔132的孔徑(例如孔徑7mm)大於其對應的該載座穿孔111的孔徑(例如孔徑5mm)及該第二上蓋穿孔142的孔徑(例如孔徑5mm),藉此可避免在治具的鎖緊過程中使該載座保護層12及該上蓋保護層13凸起或翹曲,造成無電鍍製程中漏液的問題。所述第二上蓋穿孔142的孔徑特別是指對應該螺絲15的桿體區域151的直徑,而不是指該螺絲15的螺帽區域152的直徑。 2 is a schematic exploded cross-sectional view of a jig for an electroless plating process according to a first embodiment of the present invention. Please refer to FIG. 2, the upper cover 14 further includes a plurality of second upper cover perforations 142, and the combination of the upper cover 14 and the carrier 11 is to pass a plurality of screws 15 through the second upper cover perforations 142 to lock the load. Block 11. The carrier 11 includes a plurality of carrier perforations 111, the carrier protection layer 12 includes a plurality of carrier protection layer perforations 122, and the cover protection layer 13 includes a plurality of cover protection layer perforations 132. The holes 111, the carrier protective layer perforations 122, the upper cover protective layer perforations 132, and the second upper cover perforations 142 are sequentially correspondingly passed by the screws 15 respectively, and each of the carrier protective layer perforations 122 The aperture diameter (for example, aperture 7mm) and the aperture diameter (for example, aperture 7mm) of each of the cover protective layer perforations 132 are larger than the corresponding aperture diameter (for example, aperture 5mm) of the carrier perforation 111 and the aperture diameter (for example, aperture 5 of the second upper cover) For example, the diameter is 5 mm), thereby preventing the carrier protection layer 12 and the upper cover protection layer 13 from being raised or warped during the fixture locking process, which causes the problem of liquid leakage during the electroless plating process. The hole diameter of the second upper cover perforation 142 particularly refers to the diameter of the shaft region 151 corresponding to the screw 15, rather than the diameter of the nut region 152 of the screw 15.
請再參考圖1a,在本實施例中,該上蓋14為環狀外型,該些第一上蓋穿孔141及該些第二上蓋穿孔142彼此交替地沿環狀路徑排列,且該些第一上蓋穿孔141設置在四個角落。該些第一上蓋穿孔141及該些第二上蓋穿孔142搭配該些凸起部131及該些螺絲15的設計,可產生均勻的定位及鎖合效果。請參考圖3,在另一實施例中,該些第一上蓋穿孔141及該些第二上蓋穿孔142也是彼此交替地沿環狀路徑排列,但是該些第二上蓋穿孔142設置在四個角落。該些第一上蓋穿孔141及該些第二上蓋穿孔142搭配該些凸起部131及該些螺絲15的設計,也可產生均勻的定位及鎖合效果。 Please refer to FIG. 1a again. In this embodiment, the upper cover 14 has a ring shape, the first upper cover perforations 141 and the second upper cover perforations 142 are alternately arranged along a circular path with each other, and the first The upper cover perforations 141 are provided at four corners. The design of the first upper cover perforations 141 and the second upper cover perforations 142 with the protrusions 131 and the screws 15 can produce uniform positioning and locking effects. Please refer to FIG. 3. In another embodiment, the first upper cover perforations 141 and the second upper cover perforations 142 are also alternately arranged along a circular path, but the second upper cover perforations 142 are disposed at four corners. . The design of the first upper cover perforations 141 and the second upper cover perforations 142 in combination with the protrusions 131 and the screws 15 can also produce uniform positioning and locking effects.
圖4為本發明之第一實施例之用於電鍍製程的治具之剖面示意圖。本實施之用於電鍍製程的治具1’是應用於單片太陽能電池片之電極金屬化製程。第一實施例之用於電鍍製程的治具’1大體上類似於第一實施例之用於無電鍍製程的治具1,類似的元件標示類似的標號,其差異在於第一實施例之用於電鍍製程的治具1’更包括一導電結構16,其設置於載座11內,並穿過該載座保護層13而電性接觸該待鍍基板10。該導電結構16更電性連接至外部電源之負極(圖未示)。 4 is a schematic cross-sectional view of a jig for a plating process according to a first embodiment of the present invention. The jig 1 'used in the electroplating process of the present embodiment is an electrode metallization process applied to a single solar cell. The jig '1 for the electroplating process of the first embodiment is substantially similar to the jig 1 for the electroless plating process of the first embodiment. Similar components are marked with similar reference numerals, and the difference lies in the use of the first embodiment. The jig 1 ′ in the electroplating process further includes a conductive structure 16, which is disposed in the carrier 11 and passes through the carrier protective layer 13 to electrically contact the substrate 10 to be plated. The conductive structure 16 is further electrically connected to a negative electrode (not shown) of an external power source.
根據本發明之用於電鍍或無電鍍製程的治具,若以電鍍或無電鍍技術製作太陽能電池之金屬電極時,單片電池片(亦即 待鍍基板)接觸到電鍍或無電鍍製程之處理液的區域只會在欲鍍區域。由於單片電池片的邊緣及欲鍍區域之表面的另一面都不會被鍍上金屬,因此不會導致電池片的正面及背面形成短路的現象,造成電池效率低落。 According to the jig for electroplating or electroless plating process of the present invention, if metal electrodes for solar cells are produced by electroplating or electroless plating, The area where the substrate to be plated comes into contact with the processing solution of the electroplating or electroless plating process is only in the area to be plated. Since the edges of the single-cell battery and the other side of the surface to be plated are not plated with metal, it will not cause short-circuits on the front and back of the battery, resulting in low battery efficiency.
圖5a及圖5b為本發明之第二實施例之用於無電鍍製程的治具之組合剖面示意圖。第二實施例之用於無電鍍製程的治具1”大體上類似於第一實施例之用於無電鍍製程的治具1,類似的元件標示類似的標號,其差異在於第二實施例之用於無電鍍製程的治具1”是應用於雙片太陽能電池片之電極金屬化製程。請參考圖5a及圖5b,該用於無電鍍製程的治具1”包括:一載座11、一第一及一第二載座保護層12a、12b、一第一及一第二上蓋保護層13a、13b、及一第一及一第二上蓋14a、14b。該第一及該第二載座保護層12a、12b分別於該無電鍍製程進行時裝設於該載座11之一正面112及一背面113上,並分別形成有一第一及一第二凹部121a、121b,該第一及該第二凹部121a、121b用以承載一第一及一待鍍基板10a、10b。該第一及該第二上蓋保護層13a、13b於該無電鍍製程進行時分別與該第一及該第二載座保護層11a、11b結合,以分別夾持該第一及該第二待鍍基板10a、10b,藉此該第一及該第二上蓋保護層13a、13b分別壓合該第一待鍍基板10a之一表面101a的環形邊緣區域1011a及該第二待鍍基板10b之一表面101b的環形邊緣區域1011b(該環形邊緣區域1011a、1011b環繞該表面101a、101b的欲鍍區域1012a、1012b)。特別是該第一及該第二上蓋保護層13a、13b與該環型邊緣區域1011a、1011b之間完全密合不漏液。 FIG. 5a and FIG. 5b are schematic sectional views of a combination of a jig for an electroless plating process according to a second embodiment of the present invention. The jig 1 "for the electroless plating process of the second embodiment is substantially similar to the jig 1 for the electroless plating process of the first embodiment. Similar components are denoted by similar reference numerals, and the difference lies in the second embodiment. The jig 1 ”for electroless plating process is an electrode metallization process applied to a two-piece solar cell. Please refer to Fig. 5a and Fig. 5b. The jig 1 "for electroless plating process includes: a carrier 11, a first and a second carrier protective layer 12a, 12b, a first and a second cover protection Layers 13a, 13b, and a first and a second upper cover 14a, 14b. The first and the second carrier protection layers 12a, 12b are respectively disposed on the front surface 112 of the carrier 11 in the electroless plating process. And a back surface 113, and respectively formed with a first and a second recessed portion 121a, 121b, the first and the second recessed portions 121a, 121b are used to carry a first and a substrate to be plated 10a, 10b. And the second upper cover protection layers 13a, 13b are combined with the first and the second carrier protection layers 11a, 11b respectively during the electroless plating process to hold the first and the second substrates 10a to be plated, respectively And 10b, whereby the first and second overlying protective layers 13a and 13b are respectively pressed against the annular edge region 1011a of one surface 101a of the first substrate to be plated 10a and the surface 101b of the second substrate 10b to be plated. An annular edge region 1011b (the annular edge regions 1011a, 1011b surround the to-be-plated regions 1012a, 1012b of the surfaces 101a, 101b). In particular, the first and the second upper cover protective layers 13a, 13b and the ring-shaped edge regions 1011a, 1011b are completely tight and leak-proof.
該第一上蓋14a於該無電鍍製程進行時與該載座11結合以固定該第一載座保護層12a及第一上蓋保護層13a。該第二上蓋14b於該無電鍍製程進行時與該載座11結合以固定該第二載座保護層12b及第二上蓋保護層13b。該載座11及該第一及該第二上蓋14a、14b可為耐熱/耐酸鹼之硬性絕緣材料所製,例如玻璃 纖維、耐熱塑膠等、或鐵氟龍。該第一及該第二載座保護層12a、12b及該第一及該第二上蓋保護層13a、13b可為耐熱/耐酸鹼之軟性絕緣材料所製,例如矽膠或橡膠等。 The first upper cover 14a is combined with the carrier 11 during the electroless plating process to fix the first carrier protection layer 12a and the first upper cover protection layer 13a. The second upper cover 14b is combined with the carrier 11 during the electroless plating process to fix the second carrier protection layer 12b and the second upper cover protection layer 13b. The carrier 11 and the first and second upper covers 14a and 14b may be made of a heat-resistant / acid-resistant hard insulating material, such as glass Fiber, heat-resistant plastic, etc., or Teflon. The first and the second carrier protection layers 12a, 12b and the first and the second upper cover protection layers 13a, 13b may be made of a heat-resistant / acid-resistant soft insulating material, such as silicon rubber or rubber.
在第二實施例中,該用於無電鍍製程的治具1”也包括多個螺絲15a、15b(其類似於圖1b之螺絲15),該第一及該第二上蓋14a、14b也包括多個第一上蓋穿孔141a、141b(類似於圖1b之第一上蓋穿孔141),且該第一及該第二上蓋保護層13a、13b也包括多個凸起部131a、131b(類似於圖1b之凸起部131)。該第一及該第二上蓋14a、14b也更包括多個第二上蓋穿孔142a、142b(類似於圖2之第二上蓋穿孔142)。該載座11也包括多個載座穿孔111a、111b(類似於圖2之載座穿孔111),該第一及該第二載座保護層12a、12b也包括多個載座保護層穿孔122a、122b(類似於圖1b之載座保護層穿孔122),且該第一及該第二上蓋保護層13a、13b也包括多個上蓋保護層穿孔132a、132b(類似於圖1b之上蓋保護層穿孔132)。第二實施例之螺絲、第一上蓋穿孔、凸起部、第二上蓋穿孔、載座穿孔、載座保護層穿孔及上蓋保護層穿孔之功用皆類似於第一實施例之螺絲、第一上蓋穿孔、凸起部、第二上蓋穿孔、載座穿孔、載座保護層穿孔及上蓋保護層穿孔之功用,無庸贅述。 In the second embodiment, the jig 1 "for an electroless plating process also includes a plurality of screws 15a, 15b (which is similar to the screw 15 of FIG. 1b), and the first and second upper covers 14a, 14b also include The plurality of first upper cover perforations 141a, 141b (similar to the first upper cover perforation 141 of FIG. 1b), and the first and the second upper cover protective layers 13a, 13b also include a plurality of protrusions 131a, 131b (similar to FIG. 1b's raised portion 131). The first and second upper covers 14a, 14b also include a plurality of second upper cover perforations 142a, 142b (similar to the second upper cover perforations 142 of FIG. 2). The carrier 11 also includes Multiple carrier perforations 111a, 111b (similar to carrier perforations 111 of FIG. 2), the first and second carrier protective layers 12a, 12b also include multiple carrier perforations 122a, 122b (similar to the figure) 1b's carrier protection layer perforation 122), and the first and second cover protection layers 13a, 13b also include a plurality of cover protection layer perforations 132a, 132b (similar to the cover protection layer perforation 132 of FIG. 1b). Second Examples of the screw, the perforation of the first cover, the protrusion, the perforation of the second cover, the perforation of the carrier, the perforation of the carrier protective layer, and the perforation of the upper protective layer The functions of the screws, the perforation of the first upper cover, the protrusions, the perforation of the second upper cover, the perforation of the carrier, the perforation of the carrier protective layer, and the perforation of the upper cover are similar to the functions of the first embodiment, and need not be described in detail.
圖6為本發明之第二實施例之用於電鍍製程的治具之剖面示意圖。本實施之用於電鍍製程的治具1'''是應用於雙片太陽能電池片之電極金屬化製程。第二實施例之用於電鍍製程的治具大體上類似於第二實施例之用於無電鍍製程的治具1”,類似的元件標示類似的標號,其差異在於第二實施例之用於電鍍製程的治具1'''更包括一第一及一第二導電結構16a、16b,其設置於載座11內,並分別穿過該第一及該第二載座保護層12a、12b而電性接觸該第一及該第二待鍍基板10a、10b。該第一及該第二導電結構16a、16b更分別電性連接至外部電源之負極(圖未示)。 FIG. 6 is a schematic cross-sectional view of a jig for a plating process according to a second embodiment of the present invention. The jig 1 '' 'used in the electroplating process of the present embodiment is an electrode metallization process applied to a two-piece solar cell. The jig used for the electroplating process of the second embodiment is substantially similar to the jig 1 ”used for the electroless plating process of the second embodiment. Similar components are labeled with similar reference numerals, and the difference lies in the use of the second embodiment. The jig 1 '' 'for the electroplating process further includes a first and a second conductive structure 16a, 16b, which are disposed in the carrier 11 and pass through the first and the second carrier protection layers 12a and 12b, respectively. The first and second substrates 10a and 10b are electrically contacted. The first and the second conductive structures 16a and 16b are respectively electrically connected to a negative electrode (not shown) of an external power source.
根據本發明之用於電鍍或無電鍍製程的治具,若以 電鍍或無電鍍技術製作太陽能電池之金屬電極時,雙片電池片(亦即第一及第二待鍍基板)之任一片接觸到電鍍或無電鍍製程之處理液的區域只會在欲鍍區域。由於雙片電池片之任一片的邊緣及欲鍍區域之表面的另一面都不會被鍍上金屬,因此不會導致電池片的正面及背面形成短路的現象,造成電池效率低落。 According to the invention, the jig used for electroplating or electroless plating process, if When electroplating or electroless plating is used to make metal electrodes for solar cells, the area where any one of the two battery cells (that is, the first and second substrates to be plated) comes into contact with the processing solution of the electroplating or electroless plating process is only in the area to be plated . Since the edge of any one of the two-cell battery and the other side of the surface to be plated will not be plated with metal, it will not cause a short circuit between the front and back of the battery, resulting in low battery efficiency.
圖7為本發明之第一實施例之用於電鍍或無電鍍製程的機台之剖面示意圖。圖8為本發明之第一實施例之用於電鍍或無電鍍製程的機台之局部立體示意圖。請參考圖7及圖8,該用於電鍍或無電鍍製程的機台2包括:一槽體22及一第一治具21。該槽體22用於容納該電鍍或無電鍍製程之一處理液23。該第一治具21可為本發明之用於無電鍍製程的治具1、用於電鍍的治具1’、用於無電鍍的治具1”、或用於電鍍的治具1''',該第一治具21是用於將該至少一待鍍基板20浸入該槽體22所容納之該處理液23中。在本實施例中,該第一治具21是以用於無電鍍製程的治具1”為例作說明,如圖7所示。該用於電鍍或無電鍍製程的機台2更包括:一支架24,其與該第一治具21連接。該支架24用以帶動該第一治具21於該處理液23中移動,例如旋轉或線性移動。 FIG. 7 is a schematic cross-sectional view of a machine for a plating or electroless plating process according to a first embodiment of the present invention. FIG. 8 is a partial perspective view of a machine for a plating or electroless plating process according to the first embodiment of the present invention. Please refer to FIG. 7 and FIG. 8. The machine 2 used for the electroplating or electroless plating process includes a tank 22 and a first jig 21. The tank 22 is used for containing a processing solution 23 in one of the electroplating or electroless plating processes. The first jig 21 may be a jig 1 for an electroless plating process according to the present invention, a jig 1 for electroplating, a jig 1 for electroless plating, or a jig 1 for electroplating. ', The first jig 21 is used to immerse the at least one substrate 20 to be plated in the processing liquid 23 contained in the tank body 22. In this embodiment, the first jig 21 is used for The jig 1 "of the electroplating process is taken as an example for illustration, as shown in FIG. 7. The machine 2 for the electroplating or electroless plating process further includes a bracket 24 connected to the first jig 21. The bracket 24 is used for driving the first jig 21 to move in the processing liquid 23, such as rotating or linearly moving.
當進行電鍍製程時,該電鍍製程之處理液23可為電鍍液(提供沉積金屬的離子),用以將一金屬層以電鍍方式形成在該待鍍基板20之一表面201的欲鍍區域2012上;當進行無電鍍製程時,根據不同階段,該無電鍍製程之處理液23可為敏化液、活化液、或無電鍍液(提供欲鍍上金屬之離子),用以將一金屬層以無電鍍方式形成在該待鍍基板20之一表面201的欲鍍區域2012上。 When the electroplating process is performed, the processing solution 23 of the electroplating process may be a plating solution (providing metal ions) for forming a metal layer on a surface 201 of a surface 201 of the substrate 20 to be plated by electroplating. When the electroless plating process is carried out, according to different stages, the treatment liquid 23 of the electroless plating process may be a sensitizing solution, an activating solution, or an electroless plating solution (providing ions to be plated with metal) to apply a metal layer. An electroless plating method is formed on a region to be plated 2012 of one surface 201 of the substrate 20 to be plated.
圖9為本發明之第二實施例之用於電鍍或無電鍍製程的機台之局部立體示意圖。請參考圖9及圖7,第二實施例之用於電鍍或無電鍍製程的機台2’大體上類似於第二實施例之用於電鍍或無電鍍製程的機台2,類似的元件標示類似的標號,其差異在於第二實施例之用於電鍍或無電鍍製程的機台2’更包括:至少一第二治具21’,該第二治具21’可為本發明之用於無電鍍製程的治 具1、用於電鍍的治具1’、用於無電鍍的治具1”、或用於電鍍的治具1''',該至少一第二治具21’也是用於將至少一待鍍基板20’浸入該槽體22所容納之該處理液23中,且該支架24也與該第二治具21’連接。該支架24用以使該第一治具21及該至少一第二治具21’於該處理液23中移動,例如旋轉移動241。該第一治具21及該至少一第二治具21’是以其法線方向垂直於該旋轉移動241的切線方向而排列,特別適用於縱向鍍液循環之系統,例如在鍍液槽體中,其鍍液噴孔由下往上噴出的狀況。該用於電鍍或無電鍍製程的機台2’可增加更多電池片同時進行電鍍或無電鍍製程,以加大產能。 FIG. 9 is a partial perspective view of a machine for a plating or electroless plating process according to a second embodiment of the present invention. Please refer to FIG. 9 and FIG. 7. The machine 2 ′ for the electroplating or electroless plating process of the second embodiment is substantially similar to the machine 2 for the electroplating or electroless plating process of the second embodiment. Similar components are marked. Similar reference numerals differ in that the machine 2 'used for the electroplating or electroless plating process in the second embodiment further includes at least a second jig 21', and the second jig 21 'can be used in the present invention. Treatment of electroless plating process Jig 1, jig 1 'for electroplating, jig 1 "for electroless plating, or jig 1'" for electroplating, the at least one second jig 21 'is also used to place at least one The plated substrate 20 'is immersed in the processing liquid 23 accommodated in the tank body 22, and the bracket 24 is also connected to the second jig 21'. The bracket 24 is used for the first jig 21 and the at least one first The two jigs 21 'move in the processing liquid 23, such as a rotational movement 241. The first jig 21 and the at least one second jig 21' have their normal directions perpendicular to the tangent direction of the rotational movement 241. The arrangement is especially suitable for the system of vertical plating solution circulation, for example, in the case of the plating solution tank, the spraying holes of the plating solution are sprayed from the bottom to the top. The machine 2 'for the plating or electroless plating process can be added more Cells are plated or electroless-plated at the same time to increase production capacity.
圖10為本發明之第三實施例之用於電鍍或無電鍍製程的機台之局部立體示意圖。請參考圖10,第三實施例之用於電鍍或無電鍍製程的機台2”大體上類似於第二實施例之用於電鍍或無電鍍製程的機台2’,類似的元件標示類似的標號,其差異在於第三實施例之用於電鍍或無電鍍製程的機台2”之該第一治具21及該至少一第二治具21’是以其法線方向平行於該旋轉移動241的切線方向而排列,特別適用於二種系統包括橫向鍍液循環或縱向鍍液循環之系統,例如在鍍液槽體中,其鍍液噴孔由一側壁往對向側壁方向噴出的狀況,或是在鍍液槽體中,其鍍液噴孔由下往上噴出的狀況。該用於電鍍或無電鍍製程的機台2”可增加更多電池片同時進行電鍍或無電鍍製程,以加大產能。 FIG. 10 is a partial perspective view of a machine for a plating or electroless plating process according to a third embodiment of the present invention. Please refer to FIG. 10. The machine 2 ′ used for the electroplating or electroless plating process of the third embodiment is substantially similar to the machine 2 ′ used for the electroplating or electroless plating process of the second embodiment. The difference is that the first jig 21 and the at least one second jig 21 'of the machine 2 "for the electroplating or electroless plating process of the third embodiment are moved in parallel with the direction of the normal line 241 is arranged in a tangential direction, and is particularly suitable for two systems including a horizontal plating liquid circulation or a vertical plating liquid circulation system. For example, in a plating solution tank, the plating solution spray holes are sprayed from one side to the opposite side. Or, in the plating solution tank, the plating solution spray holes are sprayed from bottom to top. This machine 2 "for electroplating or electroless plating process can add more battery cells to perform electroplating or electroless plating process at the same time to increase production capacity.
綜上所述,乃僅記載本發明為呈現解決問題所採用的技術手段之較佳實施方式或實施例而已,並非用來限定本發明專利實施之範圍。即凡與本發明專利申請範圍文義相符,或依本發明專利範圍所做的均等變化與修飾,皆為本發明專利範圍所涵蓋。 In summary, it is only a description of the preferred implementations or examples of the technical means adopted by the present invention to solve the problem, and is not intended to limit the scope of patent implementation of the present invention. That is, all changes and modifications that are consistent with the meaning of the scope of patent application of the present invention, or made according to the scope of patent of the present invention, are covered by the scope of patent of the present invention.
Claims (8)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW106132969A TWI655890B (en) | 2017-09-26 | 2017-09-26 | Fixture for electroplating or electroless plating process and machine |
| CN201710993455.1A CN109554745A (en) | 2017-09-26 | 2017-10-23 | Fixtures and their machines for electroplating or electroless plating |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW106132969A TWI655890B (en) | 2017-09-26 | 2017-09-26 | Fixture for electroplating or electroless plating process and machine |
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| Publication Number | Publication Date |
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| TWI655890B true TWI655890B (en) | 2019-04-01 |
| TW201916766A TW201916766A (en) | 2019-04-16 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201546336A (en) * | 2014-06-12 | 2015-12-16 | Taiwan Green Point Entpr Co | An electroplating holder and an assembly of the electroplating holder and the electroplating rack |
| TW201723237A (en) * | 2015-12-16 | 2017-07-01 | 茂迪股份有限公司 | Electroplating cathode fixture and electroplating device for a solar cell |
-
2017
- 2017-09-26 TW TW106132969A patent/TWI655890B/en not_active IP Right Cessation
- 2017-10-23 CN CN201710993455.1A patent/CN109554745A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201546336A (en) * | 2014-06-12 | 2015-12-16 | Taiwan Green Point Entpr Co | An electroplating holder and an assembly of the electroplating holder and the electroplating rack |
| TW201723237A (en) * | 2015-12-16 | 2017-07-01 | 茂迪股份有限公司 | Electroplating cathode fixture and electroplating device for a solar cell |
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| CN109554745A (en) | 2019-04-02 |
| TW201916766A (en) | 2019-04-16 |
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