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TWI645927B - Electroplating welding element and preparation method thereof - Google Patents

Electroplating welding element and preparation method thereof Download PDF

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Publication number
TWI645927B
TWI645927B TW107110088A TW107110088A TWI645927B TW I645927 B TWI645927 B TW I645927B TW 107110088 A TW107110088 A TW 107110088A TW 107110088 A TW107110088 A TW 107110088A TW I645927 B TWI645927 B TW I645927B
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metal member
connecting layer
layer
electroplating
metal
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TW107110088A
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Chinese (zh)
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TW201940270A (en
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黃國修
許庭維
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國立臺北科技大學
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Publication of TW201940270A publication Critical patent/TW201940270A/en

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Abstract

一種電鍍熔接元件包括:一第一金屬件、一第二金屬件,以及一連接層,其中該連接層係電鍍於該第一金屬件的表面,且該連接層熔接於該第二金屬件的表面,使該第一金屬件結合於該第二金屬件上。該電鍍熔接元件的製備方法步驟包含:於一第一金屬件的表面上電鍍一連接層;加熱該連接層使該連接層呈熔融狀態;操作該第一金屬件與一第二金屬件接觸,使呈熔融狀態的該連接層熔接於該第二金屬件。藉由電鍍的方式控制該連接層附著於該第一表面的厚度,再以熔接的方式使該連接層附著於該第二金屬件,以達到結合第一金屬件與該第二金屬件的功能。 An electroplating fusion bonding element includes: a first metal member, a second metal member, and a connecting layer, wherein the connecting layer is plated on a surface of the first metal member, and the connecting layer is welded to the second metal member a surface for bonding the first metal member to the second metal member. The method for preparing the electroplating fusion component comprises: plating a connection layer on a surface of a first metal member; heating the connection layer to make the connection layer in a molten state; operating the first metal member to contact a second metal member, The connecting layer in a molten state is welded to the second metal member. Controlling the thickness of the connecting layer attached to the first surface by electroplating, and then attaching the connecting layer to the second metal member by welding to achieve the function of bonding the first metal member and the second metal member .

Description

電鍍熔接元件及其製備方法 Electroplating welding element and preparation method thereof

本發明係與結合二金屬件有關;特別是包含有緊密結合二金屬件的電鍍熔接元件以及其製備方法。 The present invention relates to the incorporation of a bimetal member; in particular, an electroplated fusion splice member comprising a tightly bonded bimetal member and a method of making the same.

焊接,又可稱作銲接、熔接、鎔接,係指以加熱方式接合二金屬的工藝及技術。 Welding, also known as welding, welding, splicing, refers to the process and technique of joining two metals by heating.

焊接主要可區分為兩種途徑以達成接合的目的:其一,藉由加熱欲接合之一第一金屬件使該第一金屬件局部熔化而形成熔池,並使該一第二金屬件的表面與該熔池接觸,當該熔池冷卻凝固後,該第一金屬件便接合於該第二金屬件上;其二,藉由單獨加熱熔點較低的焊料(因此,又稱作點焊),使呈熔融狀態的焊料附著於一第一金屬件的局部表面,而後再將一第二金屬件的表面接觸該熔融狀態的焊料,當該焊料冷卻凝固後,該第一金屬件便接合於該第二金屬件上。 The welding can be mainly divided into two ways to achieve the purpose of joining: First, the first metal piece is locally melted by heating one of the first metal pieces to form a molten pool, and the second metal piece is made The surface is in contact with the molten pool, and when the molten pool is cooled and solidified, the first metal member is joined to the second metal member; and second, by separately heating the solder having a lower melting point (hence, also called spot welding) a solder in a molten state is attached to a partial surface of a first metal member, and then a surface of a second metal member is brought into contact with the molten solder. When the solder is cooled and solidified, the first metal member is bonded. On the second metal member.

由於點焊所需加熱的溫度較低,而所需的加工成本較為低廉,因此較廣為使用。然而點焊亦有其缺點:由於該第一金屬件與該第二金屬件係透過單點或多點的焊料結合,該第一金屬件、該第二金屬件與焊料之間的接觸面積小而使該第一金屬件與該第二金屬件容易分離。 Since the temperature required for spot welding is lower, and the processing cost required is relatively low, it is widely used. However, spot welding has its disadvantages: since the first metal member and the second metal member are combined by a single or multiple points of solder, the contact area between the first metal member and the second metal member and the solder is small. The first metal member and the second metal member are easily separated.

為解決上述問題,有業者以大量熔融狀態的焊料附著於該第一金屬件與該第二金屬件之間,以達到增加焊料與該第一金屬件、該第二金屬件的接觸面積,以強化結合效果。 In order to solve the above problem, a manufacturer attaches a large amount of molten solder between the first metal member and the second metal member to increase the contact area between the solder and the first metal member and the second metal member. Strengthen the combined effect.

然而,大量的焊料所構成的一連接層不僅厚度厚、增加生產加工,且存在著厚度不均的問題。另外,當該第二金屬件為海綿狀或表面具有多孔結構時,連接層的厚度越厚反而會增加該第一金屬件與該第二金屬件分離的風險。 However, a connection layer composed of a large amount of solder is not only thick in thickness, but also increases production processing, and there is a problem of uneven thickness. In addition, when the second metal member is sponge-like or has a porous structure on the surface, the thicker the connection layer may increase the risk of separating the first metal member from the second metal member.

有鑑於此,本發明之目的在於提供一種電鍍熔接元件以及一種電鍍熔接元件的製備方法,係分別包含有緊密結合二金屬件,以及製備緊密結合二金屬件的製備方法。 In view of the above, an object of the present invention is to provide an electroplating fusion splicing component and a method for preparing the electroplating fusion splicing component, which respectively comprise a tightly bonded bimetal member, and a preparation method for preparing a tightly bonded bimetal member.

緣以達成上述目的,本發明提供的一種電鍍熔接元件包括有:一第一金屬件、一第二金屬件,以及一連接層,其中該連接層係電鍍於該第一金屬件的一第一表面,且該連接層熔接於該第二金屬件的一第二表面,使該第一金屬件結合於該第二金屬件上。 In order to achieve the above object, an electroplating fusion bonding element provided by the present invention includes: a first metal member, a second metal member, and a connecting layer, wherein the connecting layer is plated on the first of the first metal member. a surface, and the connecting layer is welded to a second surface of the second metal member to bond the first metal member to the second metal member.

本發明又提供的一種電鍍熔接元件的製備方法,其步驟包含:A.準備一第一金屬件與一第二金屬件;B.於該第一金屬件的第一表面上電鍍一連接層;C.加熱該連接層使該連接層呈熔融狀態;D.操作該第一金屬件以該第一表面與該第二金屬件的一第二表面接觸,使呈熔融狀態的該連接層熔接於該第二金屬件的該第二表面。 The invention further provides a method for preparing a plating fusion component, the steps comprising: A. preparing a first metal member and a second metal member; B. plating a connecting layer on the first surface of the first metal member; C. heating the connecting layer to make the connecting layer in a molten state; D. operating the first metal member to contact the first surface with a second surface of the second metal member to weld the connecting layer in a molten state to The second surface of the second metal member.

本發明之效果在於藉由電鍍的方式控制該連接層附著於該第一表面的厚度,再以熔接的方式使該連接層附著於該第二表面,以達到結合第一金屬件與該第二金屬件的功能。 The effect of the invention is to control the thickness of the connecting layer attached to the first surface by electroplating, and then attach the connecting layer to the second surface by welding to achieve bonding the first metal piece and the second The function of metal parts.

〔本發明〕 〔this invention〕

100‧‧‧電鍍熔接元件 100‧‧‧Electroplating fusion elements

10‧‧‧第一金屬件 10‧‧‧First metal parts

12‧‧‧第一表面 12‧‧‧ first surface

20‧‧‧第二金屬件 20‧‧‧Second metal parts

22‧‧‧第二表面 22‧‧‧ second surface

30‧‧‧連接層 30‧‧‧Connection layer

40‧‧‧鋅空氣燃料電池 40‧‧‧Zinc air fuel cell

41‧‧‧殼體 41‧‧‧Shell

42‧‧‧陽極導電片 42‧‧‧Anode conductive sheet

43‧‧‧陽極導電網 43‧‧‧Anode conductive mesh

44‧‧‧襯墊 44‧‧‧ cushion

45‧‧‧隔離膜 45‧‧‧Separator

46‧‧‧空氣電極片 46‧‧‧Air electrode

47‧‧‧陰極導電片 47‧‧‧Cathode conductive sheet

48‧‧‧蓋板 48‧‧‧ Cover

49‧‧‧錫層 49‧‧‧ tin layer

圖1為本發明一較佳實施例之電鍍熔接元件的製備方法流程圖。 1 is a flow chart of a method for preparing an electroplated fusion splice component according to a preferred embodiment of the present invention.

圖2為以上述較佳實施例之製備方法所製備的電鍍熔接元件示意圖。 Figure 2 is a schematic view of an electroplated fusion splicing element prepared by the preparation method of the above preferred embodiment.

圖3為圖2的組合側視圖。 Figure 3 is a combined side view of Figure 2.

圖4為應用上述較佳實施例的鋅空氣燃料電池的分解圖。 Figure 4 is an exploded view of a zinc air fuel cell to which the above preferred embodiment is applied.

為能更清楚地說明本發明,茲舉一較佳實施例並配合圖式詳細說明如後。請參圖1至圖3所示,為本發明一較佳實施例之電鍍熔接元件100的製備方法的流程圖,以及該製備方法所製備之電鍍熔接元件100。 In order to explain the present invention more clearly, a preferred embodiment will be described in detail with reference to the drawings. Referring to FIG. 1 to FIG. 3, a flow chart of a method for preparing an electroplated fusion splice component 100 according to a preferred embodiment of the present invention, and an electroplated fusion splice component 100 prepared by the preparation method are shown.

該電鍍熔接元件100包含有:一第一金屬件10、一第二金屬件20,以及一連接層30,其製備方法的步驟包含有:A.準備該第一金屬件10與該第二金屬件20;B.於該第一金屬件10的第一表面12上電鍍該連接層30,其中,該電鍍層的熔點比該第一金屬件10、該第二金屬件20的熔點低;C.加熱該連接層30使該連接層30呈熔融狀態;D.操作該第一金屬件10以該第一表面12與該第二金屬件20的一第二表面22接觸,使 呈熔融狀態的該連接層30熔接於該第二金屬件20的該第二表面22。當該連接層30冷卻凝固後,該第一金屬件10便結合於該第二金屬件20上。 The electroplating frit element 100 includes a first metal member 10, a second metal member 20, and a connecting layer 30. The manufacturing method includes the following steps: A. preparing the first metal member 10 and the second metal The connecting layer 30 is electroplated on the first surface 12 of the first metal member 10, wherein the melting point of the plating layer is lower than the melting points of the first metal member 10 and the second metal member 20; Heating the connecting layer 30 to make the connecting layer 30 in a molten state; D. operating the first metal member 10 to contact the first surface 12 with a second surface 22 of the second metal member 20, so that The connecting layer 30 in a molten state is welded to the second surface 22 of the second metal member 20. After the connecting layer 30 is cooled and solidified, the first metal member 10 is bonded to the second metal member 20.

由於該連接層30係以電鍍的方式結合於該第一金屬件10的該第一表面12上,再以熔接的方式結合該第二金屬件20的該第二表面22上,因此該連接層30不僅可均勻地附著於該第一表面12,且可藉由控制電鍍的參數,例如:施加的電流、電鍍的時間等,控制該連接層30的厚度。使用者可綜合考量該第一金屬件10與該第二金屬件20的質量、該第一表面12與該第二表面22的表面積大小等因素,調整該連接層30的厚度以達到控制生產加工成本,且同時兼顧該第一金屬件10與該第二金屬件20結合效果。 Since the connection layer 30 is bonded to the first surface 12 of the first metal member 10 by electroplating, and then bonded to the second surface 22 of the second metal member 20, the connection layer is Not only can 30 be uniformly attached to the first surface 12, but the thickness of the connection layer 30 can be controlled by controlling parameters of plating, such as applied current, time of plating, and the like. The user can comprehensively consider the quality of the first metal member 10 and the second metal member 20, the surface area of the first surface 12 and the second surface 22, and the like, and adjust the thickness of the connecting layer 30 to control the production and processing. The cost, and at the same time, the combined effect of the first metal member 10 and the second metal member 20.

該電鍍熔接元件可視需求應用於許多不同的領域,以應用於鋅空氣燃料電池40為例,請參圖4所示,鋅空氣燃料電池40包括一殼體41,以及堆疊於殼體41上的一陽極導電片42、一陽極導電網43、一襯墊44、一隔離膜45、一空氣電極片46、一陰極導電片47以及一蓋板48,其中,該空氣電極片46為該第一金屬件,該陰極導電片47作為該第二金屬件,該連接層以錫層49為例但不以此為限制。 The electroplating fusing component can be applied to many different fields as needed, and is applied to the zinc air fuel cell 40 as an example. As shown in FIG. 4, the zinc air fuel cell 40 includes a casing 41 and is stacked on the casing 41. An anode conductive sheet 42, an anode conductive mesh 43, a gasket 44, a separator 45, an air electrode sheet 46, a cathode conductive sheet 47, and a cover plate 48, wherein the air electrode sheet 46 is the first The metal piece, the cathode conductive piece 47 is used as the second metal piece, and the connection layer is exemplified by the tin layer 49, but is not limited thereto.

空氣電極片46具有多孔結構,藉由電鍍的方式可使該錫層49均勻地包覆於該空氣電極片46欲與該陰極導電片47連接的表面,而後,加熱該錫層49使其呈熔融狀態後熔接於該陰極導電片47的表面,即可以達到結合該空氣電極片46與該陰極導電片47。 The air electrode sheet 46 has a porous structure, and the tin layer 49 is uniformly coated on the surface of the air electrode sheet 46 to be connected to the cathode conductive sheet 47 by electroplating, and then the tin layer 49 is heated to be After being melted, it is welded to the surface of the cathode conductive sheet 47, that is, the air electrode sheet 46 and the cathode conductive sheet 47 can be bonded.

相較於以點焊或以螺栓鎖固方式所結合之該空氣電極片46與該陰極導電片47,藉由先電鍍錫層49再以熔接的方式所結合的該空氣電極片46與該陰極導電片47不僅較為牢固而不會分離,且結合的接觸面積大,使該空氣電極片46與該陰極導電片47之間的阻抗值大幅下降, 此外,更可減少鋅空氣燃料電池40之電解液自該空氣電極片46與該陰極導電片47之間滲漏所造成的漏夜、鏽蝕等問題。 Compared with the air electrode sheet 46 and the cathode conductive sheet 47 which are combined by spot welding or bolt locking, the air electrode sheet 46 and the cathode are bonded by first plating the tin layer 49 by fusion bonding. The conductive sheet 47 is not only relatively strong but not separated, and the combined contact area is large, so that the impedance value between the air electrode sheet 46 and the cathode conductive sheet 47 is greatly reduced. In addition, problems such as leakage, rust, and the like caused by leakage of the electrolyte of the zinc-air fuel cell 40 from between the air electrode sheet 46 and the cathode conductive sheet 47 can be further reduced.

以上所述僅為本發明較佳可行實施例而已,舉凡應用本發明說明書及申請專利範圍所為之等效變化,理應包含在本發明之專利範圍內。 The above is only a preferred embodiment of the present invention, and equivalent changes to the scope of the present invention and the scope of the patent application are intended to be included in the scope of the present invention.

Claims (3)

一種電鍍熔接元件,包含有:一第一金屬件;一第二金屬件;以及一連接層,係電鍍於該第一金屬件的一第一表面,且該連接層熔接於該第二金屬件的一第二表面,使該第一金屬件結合於該第二金屬件上;其中,該第一金屬件為具有多孔結構的一空氣電極片,該第二金屬件為一陰極導電片。 An electroplating fusion splicing component comprising: a first metal member; a second metal member; and a connecting layer plated on a first surface of the first metal member, and the connecting layer is welded to the second metal member And a second surface, the first metal member is bonded to the second metal member; wherein the first metal member is an air electrode sheet having a porous structure, and the second metal member is a cathode conductive sheet. 如請求項1所述之電鍍熔接元件,其中該連接層為錫層。 The electroplated fusion element of claim 1, wherein the connection layer is a tin layer. 一種電鍍熔接元件的製備方法,其步驟包含:A.準備一第一金屬件與一第二金屬件,其中,該第一金屬件為具有多孔結構的一空氣電極片,該第二金屬件為一陰極導電片;B.於該第一金屬件的第一表面上電鍍一連接層;C.加熱該連接層使該連接層呈熔融狀態;D.操作該第一金屬件以該第一表面與該第二金屬件的一第二表面接觸,使呈熔融狀態的該連接層熔接於該第二金屬件的該第二表面。 A method for preparing a plating fusion component, the method comprising: A. preparing a first metal member and a second metal member, wherein the first metal member is an air electrode sheet having a porous structure, and the second metal member is a cathode conductive sheet; B. electroplating a connection layer on the first surface of the first metal member; C. heating the connection layer to make the connection layer in a molten state; D. operating the first metal member to the first surface Contacting a second surface of the second metal member to weld the connecting layer in a molten state to the second surface of the second metal member.
TW107110088A 2018-03-23 2018-03-23 Electroplating welding element and preparation method thereof TWI645927B (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101094744A (en) * 2004-05-11 2007-12-26 通用汽车公司 Laser welding of conductive coated metallic bipolar plates
DE102011010457A1 (en) * 2011-02-05 2011-10-06 Daimler Ag Producing an accumulator made of electrochemical cells with each metallic tap pole, comprises electrically connecting the tap pole of an individual lines, and connecting a positive tap pole of the cell, which consists of a first metal

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101094744A (en) * 2004-05-11 2007-12-26 通用汽车公司 Laser welding of conductive coated metallic bipolar plates
DE102011010457A1 (en) * 2011-02-05 2011-10-06 Daimler Ag Producing an accumulator made of electrochemical cells with each metallic tap pole, comprises electrically connecting the tap pole of an individual lines, and connecting a positive tap pole of the cell, which consists of a first metal

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