TWI508190B - Thin film transistor and method for manufacturing the same - Google Patents
Thin film transistor and method for manufacturing the same Download PDFInfo
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- TWI508190B TWI508190B TW102105386A TW102105386A TWI508190B TW I508190 B TWI508190 B TW I508190B TW 102105386 A TW102105386 A TW 102105386A TW 102105386 A TW102105386 A TW 102105386A TW I508190 B TWI508190 B TW I508190B
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- 239000010409 thin film Substances 0.000 title claims description 37
- 238000000034 method Methods 0.000 title claims description 29
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000004065 semiconductor Substances 0.000 claims description 43
- 238000000137 annealing Methods 0.000 claims description 16
- 239000010410 layer Substances 0.000 description 97
- 239000000463 material Substances 0.000 description 20
- 239000000758 substrate Substances 0.000 description 20
- 239000003989 dielectric material Substances 0.000 description 10
- 239000011241 protective layer Substances 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000005229 chemical vapour deposition Methods 0.000 description 6
- 238000000206 photolithography Methods 0.000 description 6
- 239000002356 single layer Substances 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 5
- 229910052732 germanium Inorganic materials 0.000 description 5
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000004544 sputter deposition Methods 0.000 description 5
- 238000007736 thin film deposition technique Methods 0.000 description 5
- 239000004642 Polyimide Substances 0.000 description 4
- 229920001721 polyimide Polymers 0.000 description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 3
- 229910052733 gallium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- JAONJTDQXUSBGG-UHFFFAOYSA-N dialuminum;dizinc;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Zn+2].[Zn+2] JAONJTDQXUSBGG-UHFFFAOYSA-N 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910000449 hafnium oxide Inorganic materials 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 230000008054 signal transmission Effects 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- 229910007717 ZnSnO Inorganic materials 0.000 description 1
- IZHOVLXXYOZDLW-UHFFFAOYSA-N [O-2].[Al+3].[Sn+4] Chemical compound [O-2].[Al+3].[Sn+4] IZHOVLXXYOZDLW-UHFFFAOYSA-N 0.000 description 1
- YQNPZKUDUWSYQX-UHFFFAOYSA-N [O-2].[In+3].[Mo+4] Chemical compound [O-2].[In+3].[Mo+4] YQNPZKUDUWSYQX-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- UNRNJMFGIMDYKL-UHFFFAOYSA-N aluminum copper oxygen(2-) Chemical compound [O-2].[Al+3].[Cu+2] UNRNJMFGIMDYKL-UHFFFAOYSA-N 0.000 description 1
- BCZWPKDRLPGFFZ-UHFFFAOYSA-N azanylidynecerium Chemical compound [Ce]#N BCZWPKDRLPGFFZ-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- HPSHZZDEEIEFFA-UHFFFAOYSA-N chromium;oxotin Chemical compound [Cr].[Sn]=O HPSHZZDEEIEFFA-UHFFFAOYSA-N 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- UTDFEXXDUZZCQQ-UHFFFAOYSA-N copper;oxobismuth Chemical compound [Cu].[Bi]=O UTDFEXXDUZZCQQ-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- YZZNJYQZJKSEER-UHFFFAOYSA-N gallium tin Chemical compound [Ga].[Sn] YZZNJYQZJKSEER-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- BDVZHDCXCXJPSO-UHFFFAOYSA-N indium(3+) oxygen(2-) titanium(4+) Chemical compound [O-2].[Ti+4].[In+3] BDVZHDCXCXJPSO-UHFFFAOYSA-N 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002052 molecular layer Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- KYKLWYKWCAYAJY-UHFFFAOYSA-N oxotin;zinc Chemical compound [Zn].[Sn]=O KYKLWYKWCAYAJY-UHFFFAOYSA-N 0.000 description 1
- CAQRFUZAAAEILW-UHFFFAOYSA-N oxygen(2-) tin(4+) titanium(4+) Chemical compound [O--].[O--].[O--].[O--].[Ti+4].[Sn+4] CAQRFUZAAAEILW-UHFFFAOYSA-N 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
- 238000000427 thin-film deposition Methods 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 1
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- Thin Film Transistor (AREA)
Description
本發明是有關於一種氧化物半導體的薄膜電晶體及其製造方法。The present invention relates to a thin film transistor of an oxide semiconductor and a method of manufacturing the same.
液晶顯示器主要由薄膜電晶體基板、彩色濾光片基板及位於兩基板間的液晶分子層所構成。薄膜電晶體基板上配置多個薄膜電晶體,每一薄膜電晶體主要由閘極、閘介電層、半導體層、源極及汲極所組成。半導體層的材料例如可包含非晶矽、多晶矽、微晶矽、單晶矽、有機半導體、氧化物半導體或其他合適的材料。The liquid crystal display is mainly composed of a thin film transistor substrate, a color filter substrate, and a liquid crystal molecular layer between the two substrates. A plurality of thin film transistors are disposed on the thin film transistor substrate, and each of the thin film transistors is mainly composed of a gate, a gate dielectric layer, a semiconductor layer, a source, and a drain. The material of the semiconductor layer may include, for example, an amorphous germanium, a polycrystalline germanium, a microcrystalline germanium, a single crystal germanium, an organic semiconductor, an oxide semiconductor, or other suitable material.
然而,相較於非晶矽薄膜電晶體,氧化物半導體薄膜電晶體具有較高的載子遷移率(Mobility),而擁有較佳的電性表現。而氧化物半導體通常需再進行退火製程,才能夠使薄膜電晶體的電性表現穩定。一般而言,退火製程的溫度需高於350℃以上。However, the oxide semiconductor thin film transistor has higher carrier mobility (Mobility) than the amorphous germanium thin film transistor, and has better electrical performance. Oxide semiconductors usually require an annealing process to stabilize the electrical properties of the thin film transistor. In general, the temperature of the annealing process needs to be higher than 350 ° C.
但於進行退火製程中,若有金屬暴露在高溫爐中,將導致金屬氧化,使得阻抗升高,而嚴重影響訊號傳輸。有鑑於此,亟需一種改良的薄膜電晶體的製造方法,以解決上述問題。However, in the annealing process, if the metal is exposed to the high temperature furnace, the metal will be oxidized, causing the impedance to rise, which seriously affects the signal transmission. In view of the above, there is a need for an improved method of fabricating a thin film transistor to solve the above problems.
本發明的目的在於提供一種薄膜電晶體的製造方法, 其能夠於進行退火製程時,避免源極及汲極氧化而導致阻抗升高的問題。An object of the present invention is to provide a method for manufacturing a thin film transistor, It can avoid the problem of increased impedance caused by oxidation of the source and the drain during the annealing process.
本發明之一態樣為提供一種薄膜電晶體的製造方法,其包含下列步驟。提供源極及汲極。形成圖形絕緣層局部覆蓋源極及汲極,並暴露出一部分源極及一部分汲極。形成氧化物半導體層接觸源極之該部分及汲極之該部分。提供閘極。提供位於氧化物半導體層與閘極間之一閘介電層。One aspect of the present invention provides a method of producing a thin film transistor comprising the following steps. Source and bungee are available. Forming a patterned insulating layer partially covers the source and drain electrodes and exposes a portion of the source and a portion of the drain. The oxide semiconductor layer is formed to contact the portion of the source and the portion of the drain. Provide a gate. A gate dielectric layer is provided between the oxide semiconductor layer and the gate.
根據本發明一實施方式,更包含於形成氧化物半導體層步驟後,進行一退火步驟。According to an embodiment of the present invention, after the step of forming the oxide semiconductor layer, an annealing step is performed.
根據本發明一實施方式,提供閘介電層步驟係於提供源極及汲極步驟前進行。According to an embodiment of the invention, the step of providing a gate dielectric layer is performed prior to the step of providing a source and a drain.
根據本發明一實施方式,提供閘介電層步驟係於提供源極及汲極步驟後進行。According to an embodiment of the invention, the step of providing a gate dielectric layer is performed after the step of providing a source and a drain.
根據本發明一實施方式,形成圖形絕緣層步驟包含:形成一絕緣層全面覆蓋源極及汲極;於絕緣層中形成至少一開口暴露出源極之該部分及汲極之該部分。According to an embodiment of the invention, the step of forming the pattern insulating layer comprises: forming an insulating layer covering the source and the drain in a comprehensive manner; and forming at least one opening in the insulating layer to expose the portion of the source and the portion of the drain.
根據本發明一實施方式,形成圖形絕緣層步驟包含:形成一絕緣層全面覆蓋源極及汲極;於絕緣層中形成一第一開口及一第二開口分別露出源極之該部分及該汲極之該部分。According to an embodiment of the invention, the step of forming the pattern insulating layer comprises: forming an insulating layer covering the source and the drain in a comprehensive manner; forming a first opening and a second opening in the insulating layer respectively exposing the portion of the source and the 汲This part of the pole.
本發明之另一態樣為提供一種薄膜電晶體,其包含源極及汲極、圖形絕緣層、氧化物半導體層、閘極與閘介電層。圖形絕緣層局部覆蓋源極及汲極,其中圖形絕緣層具有至少一開口露出一部分源極及一部分汲極。氧化物半導 體層接觸源極之該部分及汲極之該部分。閘介電層位於氧化物半導體層與閘極之間。Another aspect of the present invention provides a thin film transistor comprising a source and a drain, a pattern insulating layer, an oxide semiconductor layer, a gate and a gate dielectric layer. The patterned insulating layer partially covers the source and the drain, wherein the patterned insulating layer has at least one opening exposing a portion of the source and a portion of the drain. Oxide semiconductor The bulk layer contacts the portion of the source and the portion of the drain. The gate dielectric layer is between the oxide semiconductor layer and the gate.
根據本發明一實施方式,開口大致對準閘極。According to an embodiment of the invention, the opening is substantially aligned with the gate.
根據本發明一實施方式,圖形絕緣層只具有一開口,該開口之長度大於源極及汲極之一間距。According to an embodiment of the invention, the pattern insulating layer has only one opening, and the length of the opening is greater than a distance between the source and the drain.
根據本發明一實施方式,閘介電層位於源極及汲極之下。根據本發明一實施方式,開口包含一第一開口及一第二開口分別露出源極之該部分及汲極之該部分。According to an embodiment of the invention, the gate dielectric layer is under the source and the drain. According to an embodiment of the invention, the opening includes a first opening and a second opening respectively exposing the portion of the source and the portion of the drain.
根據本發明一實施方式,閘介電層位於源極及汲極之上。According to an embodiment of the invention, the gate dielectric layer is above the source and drain.
本發明之實施方式是先形成一圖形絕緣層局部覆蓋源極及汲極,再依序形成氧化物半導體層接觸暴露出的部分源極及部分汲極,以及進行退火製程。如此一來,在進行退火製程時,源極及汲極被圖形絕緣層及氧化物半導體層所覆蓋而完全未露出,故可避免源極及汲極發生氧化。In the embodiment of the present invention, a pattern insulating layer is partially formed to cover the source and the drain, and then a portion of the source and a portion of the drain exposed by the oxide semiconductor layer are sequentially formed, and an annealing process is performed. In this way, when the annealing process is performed, the source and the drain are covered by the pattern insulating layer and the oxide semiconductor layer, and are not exposed at all, so that oxidation of the source and the drain can be avoided.
以下將以圖式揭露本發明之複數個實施方式,為明確說明起見,許多實務上的細節將在以下敘述中一併說明。然而,應瞭解到,這些實務上的細節不應用以限制本發明。也就是說,在本發明部分實施方式中,這些實務上的細節是非必要的。此外,為簡化圖式起見,一些習知慣用的結構與元件在圖式中將以簡單示意的方式繪示之。The embodiments of the present invention are disclosed in the following drawings, and the details of However, it should be understood that these practical details are not intended to limit the invention. That is, in some embodiments of the invention, these practical details are not necessary. In addition, some of the conventional structures and elements are shown in the drawings in a simplified schematic manner in order to simplify the drawings.
第1圖係顯示本發明一實施方式之薄膜電晶體基板之 製造方法的流程圖。第2A圖係顯示依照本發明一實施方式之薄膜電晶體基板的上視示意圖。其中,薄膜電晶體基板的電路佈局(layout)可作適當的變動,並不限於第2A圖例示者。第2B圖係顯示沿第2A圖之2B-2B'線段的薄膜電晶體的剖面示意圖。一般而言,薄膜電晶體的類型例如為頂閘型或底閘型。在底閘型薄膜電晶體的類型中,閘極是位於半導體層之下方;在頂閘型薄膜電晶體的類型中,閘極是位於半導體層之上方。第2A-2B圖例示者為底閘型的薄膜電晶體,但不以此為限。1 is a view showing a thin film transistor substrate according to an embodiment of the present invention. Flow chart of the manufacturing method. 2A is a top plan view showing a thin film transistor substrate in accordance with an embodiment of the present invention. The circuit layout of the thin film transistor substrate can be appropriately changed, and is not limited to the example of FIG. 2A. Fig. 2B is a schematic cross-sectional view showing the thin film transistor along line 2B-2B' of Fig. 2A. In general, the type of thin film transistor is, for example, a top gate type or a bottom gate type. In the type of bottom gate type thin film transistor, the gate is located below the semiconductor layer; in the type of top gate type thin film transistor, the gate is located above the semiconductor layer. 2A-2B is an example of a bottom gate type thin film transistor, but is not limited thereto.
在步驟10中,提供一基材110,如第2B圖所示。基材110需具有足夠的機械強度,其可例如為玻璃、石英、透明高分子材料或其他合適的材質。In step 10, a substrate 110 is provided, as shown in Figure 2B. The substrate 110 needs to have sufficient mechanical strength, which may be, for example, glass, quartz, a transparent polymer material, or other suitable material.
在步驟20中,形成一閘極120於基材110,如第2A-2B圖所示。如第2A圖所示,於形成閘極120時,可同時形成多條相互平行的掃描線SL於基材110上。當然,也可同時形成共通電極線(未繪示)於基材110上。共同電極線可平行於掃描線SL之延伸方向。例如可利用濺鍍(sputtering)、蒸鍍(evaporation)製程或其他薄膜沉積技術先形成一層金屬層(未繪示)於基材110上,再利用微影蝕刻製程形成閘極120與掃描線SL。In step 20, a gate 120 is formed on the substrate 110 as shown in Figures 2A-2B. As shown in FIG. 2A, when the gate 120 is formed, a plurality of mutually parallel scanning lines SL can be simultaneously formed on the substrate 110. Of course, a common electrode line (not shown) may be simultaneously formed on the substrate 110. The common electrode line may be parallel to the extending direction of the scanning line SL. For example, a metal layer (not shown) may be formed on the substrate 110 by sputtering, evaporation, or other thin film deposition techniques, and the gate 120 and the scan line SL are formed by a photolithography process. .
在步驟30中,形成閘介電層130覆蓋閘極120,如第2B圖所示。當然,閘介電層130也可覆蓋多條掃描線SL。閘介電層130可為單層或多層結構,其材料可包含有機介電材、無機介電材或上述之組合。有機介電材料例如為聚亞醯胺(Polyimide,PI)、其他適合的材料或上述之組合;無機 介電材料例如為氧化矽、氮化矽、氮氧化矽、其他適合的材料或上述之組合。可利用化學氣相沉積法(chemical vapor deposition,CVD)或其他合適的薄膜沉積技術形成閘介電層130。In step 30, gate dielectric layer 130 is formed to cover gate 120, as shown in FIG. 2B. Of course, the gate dielectric layer 130 can also cover a plurality of scan lines SL. The gate dielectric layer 130 may be a single layer or a multilayer structure, and the material thereof may include an organic dielectric material, an inorganic dielectric material, or a combination thereof. The organic dielectric material is, for example, Polyimide (PI), other suitable materials or a combination thereof; inorganic The dielectric material is, for example, yttria, tantalum nitride, ytterbium oxynitride, other suitable materials, or a combination thereof. The gate dielectric layer 130 can be formed using chemical vapor deposition (CVD) or other suitable thin film deposition techniques.
在步驟40中,形成源極140a及汲極140b於閘介電層130上,如第2A-2B圖所示。如第2A圖所示,於形成源極140a及汲極140b時,可同時形成多條相互平行的資料線DL。資料線DL與掃描線SL相互垂直交錯,以定義基材110之多個次畫素區。例如可利用濺鍍(sputtering)、蒸鍍(evaporation)製程或其他薄膜沉積技術先形成一層金屬層(未繪示)於閘介電層130上,再利用微影蝕刻製程形成源極140a、汲極140b與資料線DL。閘極120、源極140a及汲極140b可為單層或多層結構,其材料可為金屬或金屬化合物。金屬材料包含鉬(Mo)、鉻(Cr)、鋁(Al)、釹(Nd)、鈦(Ti)、銅(Cu)、銀(Ag)、金(Au)、鋅(Zn)、銦(In)、鎵(Ga)、其他合適的材料或上述的組合。金屬化合物材料包含金屬合金、金屬氧化物、金屬氮化物、金屬氮氧化物、其他合適的材料或上述的組合。In step 40, source 140a and drain 140b are formed on gate dielectric layer 130 as shown in FIG. 2A-2B. As shown in FIG. 2A, when the source 140a and the drain 140b are formed, a plurality of mutually parallel data lines DL can be simultaneously formed. The data line DL and the scan line SL are vertically interdigitated to define a plurality of sub-pixel regions of the substrate 110. For example, a metal layer (not shown) may be formed on the gate dielectric layer 130 by sputtering, evaporation, or other thin film deposition techniques, and the source 140a may be formed by a photolithography process. The pole 140b and the data line DL. The gate 120, the source 140a, and the drain 140b may be a single layer or a multilayer structure, and the material may be a metal or a metal compound. The metal material includes molybdenum (Mo), chromium (Cr), aluminum (Al), niobium (Nd), titanium (Ti), copper (Cu), silver (Ag), gold (Au), zinc (Zn), indium ( In), gallium (Ga), other suitable materials, or a combination of the above. The metal compound material comprises a metal alloy, a metal oxide, a metal nitride, a metal oxynitride, other suitable materials, or a combination thereof.
在步驟50中,形成圖形絕緣層150局部覆蓋源極140a及汲極140b,並暴露出一部分的源極140a及一部分的汲極140b,如第2B圖所示。當然,圖形絕緣層150可全面覆蓋與源極140a、汲極140b同層的資料線DL。圖形絕緣層150係用以保護源極140a、汲極140b及同層的其他元件(如資料線DL)不受後續退火製程(即步驟70)影響而氧化。因此,汲極140b與透明電極的接觸阻抗、資料線DL 的阻抗等將不會受到退火製程影響。圖形絕緣層150的材質可為單層或多層結構,其材料可包含耐高溫的有機介電材、無機介電材或上述之組合。有機介電材料例如為聚亞醯胺(Polyimide,PI)、其他適合的材料或上述之組合;無機介電材料例如為氧化矽、氮化矽、氮氧化矽、其他適合的材料或上述之組合。In step 50, the patterned insulating layer 150 is partially covered with the source 140a and the drain 140b, and a portion of the source 140a and a portion of the drain 140b are exposed, as shown in FIG. 2B. Of course, the graphic insulating layer 150 can completely cover the data lines DL in the same layer as the source 140a and the drain 140b. The patterned insulating layer 150 is used to protect the source 140a, the drain 140b, and other components of the same layer (such as the data line DL) from oxidation by the subsequent annealing process (ie, step 70). Therefore, the contact resistance of the drain electrode 140b and the transparent electrode, the data line DL The impedance etc. will not be affected by the annealing process. The material of the graphic insulating layer 150 may be a single layer or a multilayer structure, and the material thereof may include a high temperature resistant organic dielectric material, an inorganic dielectric material, or a combination thereof. The organic dielectric material is, for example, Polyimide (PI), other suitable materials, or a combination thereof; the inorganic dielectric material is, for example, cerium oxide, cerium nitride, cerium oxynitride, other suitable materials, or a combination thereof. .
在一實施方式中,形成圖形絕緣層150步驟包含先形成一絕緣層(未繪示)全面覆蓋源極140a及汲極140b,再於絕緣層中形成至少一開口150'暴露出部分源極140a及部分汲極140b,如第2B圖所示。開口150'的位置係為氧化物半導體預定與源極140a、汲極140b接觸的區域。例如可利用化學氣相沉積法(chemical vapor deposition,CVD)或其他合適的薄膜沉積技術形成絕緣層(未繪示),再利用微影蝕刻製程形成開口150'。In one embodiment, the step of forming the pattern insulating layer 150 includes forming an insulating layer (not shown) to completely cover the source 140a and the drain 140b, and forming at least one opening 150' in the insulating layer to expose a portion of the source 140a. And part of the drain 140b, as shown in Figure 2B. The position of the opening 150' is a region where the oxide semiconductor is intended to be in contact with the source 140a and the drain 140b. For example, an insulating layer (not shown) may be formed by chemical vapor deposition (CVD) or other suitable thin film deposition technique, and the opening 150' may be formed by a photolithography process.
在另一實施方式中,如第3圖所示,先形成一絕緣層(未繪示)全面覆蓋源極140a及汲極140b,再於絕緣層中形成一第一開口150'a與一第二開口150'b分別露出一部分源極140a及一部分汲極140b。當然,於實際應用中,圖形絕緣層150的開口數量及位置不限於第2B圖及第3圖例示者。In another embodiment, as shown in FIG. 3, an insulating layer (not shown) is formed to completely cover the source 140a and the drain 140b, and a first opening 150'a and a first layer are formed in the insulating layer. The two openings 150'b expose a portion of the source 140a and a portion of the drain 140b, respectively. Of course, in practical applications, the number and position of the openings of the pattern insulating layer 150 are not limited to those illustrated in FIGS. 2B and 3 .
在步驟60中,形成氧化物半導體層160接觸源極140a之該部分及汲極140b之該部分,如第2A-2B圖所示。氧化物半導體層160可為單層或多層結構,其材質可例如為氧化鋅(ZnO)、氧化鋅錫(ZnSnO)、氧化鉻錫(CdSnO)、氧化鎵錫(GaSnO)、氧化鈦錫(TiSnO)、氧化銦鎵鋅(InGaZnO)、氧化銦鋅(InZnO)、氧化銅鋁(CuAlO)、氧化鍶銅(SrCuO)、 硫氧化鑭銅(LaCuOS)、其他適合的材料或上述之組合。例如可使用濺鍍(Sputtering)製程先形成氧化物半導體材料層(未繪示)全面覆蓋圖形絕緣層150、源極140a之該部分與汲極140b之該部分,再進行微影蝕刻製程形成氧化物半導體層160。In step 60, the oxide semiconductor layer 160 is formed to contact the portion of the source 140a and the portion of the drain 140b as shown in FIG. 2A-2B. The oxide semiconductor layer 160 may be a single layer or a multilayer structure, and may be made of, for example, zinc oxide (ZnO), zinc tin oxide (ZnSnO), chromium tin oxide (CdSnO), gallium tin oxide (GaSnO), or titanium oxide tin (TiSnO). ), indium gallium zinc oxide (InGaZnO), indium zinc oxide (InZnO), copper aluminum oxide (CuAlO), copper bismuth oxide (SrCuO), Beryllium oxysulfide (LaCuOS), other suitable materials or combinations thereof. For example, a sputtering semiconductor (Sputtering) process may be used to form an oxide semiconductor material layer (not shown) to completely cover the portion of the pattern insulating layer 150, the source 140a, and the drain 140b, and then perform a photolithography process to form an oxide. Semiconductor layer 160.
在步驟70中,對氧化物半導體層160進行退火製程。具體而言,是將包含氧化物半導體層160與被覆有圖形絕緣層150的源極140a及汲極140b的層疊結構置入一高溫爐中進行退火處理,而可得到電性較為穩定的氧化物半導體層160。退火製程的溫度例如為約350℃至約400℃。In step 70, the oxide semiconductor layer 160 is subjected to an annealing process. Specifically, the laminated structure including the oxide semiconductor layer 160 and the source 140a and the drain electrode 140b coated with the pattern insulating layer 150 is placed in a high temperature furnace for annealing treatment, whereby an electrically stable oxide can be obtained. Semiconductor layer 160. The temperature of the annealing process is, for example, from about 350 ° C to about 400 ° C.
值得一提的是,由於本發明之實施方式是依序形成源極140a及汲極140b、形成圖形絕緣層150、形成氧化物半導體層160以及進行退火製程,故退火完成的氧化物半導體層160不會直接接觸濕製程,而能夠避免氧化物半導體層160的電性受到濕製程影響。It is worth mentioning that, since the embodiment of the present invention sequentially forms the source 140a and the drain 140b, forms the pattern insulating layer 150, forms the oxide semiconductor layer 160, and performs an annealing process, the annealed oxide semiconductor layer 160 is completed. The wet process is not directly contacted, and the electrical properties of the oxide semiconductor layer 160 can be prevented from being affected by the wet process.
在步驟80中,形成保護層170覆蓋圖形絕緣層150與氧化物半導體層160,如第2B圖所示。保護層170具有一接觸孔170'暴露出一部分的汲極140b。保護層170為單層或多層結構,其材料可包含有機介電材、無機介電材或上述之組合,請參考上述閘介電層130所例示的材料。例如可利用化學氣相沉積法(chemical vapor deposition,CVD)或其他合適的薄膜沉積技術形成保護材料層(未繪示),再利用微影蝕刻製程形成接觸孔170'。In step 80, a protective layer 170 is formed to cover the pattern insulating layer 150 and the oxide semiconductor layer 160 as shown in FIG. 2B. The protective layer 170 has a contact hole 170' exposing a portion of the drain 140b. The protective layer 170 is a single layer or a multilayer structure, and the material thereof may include an organic dielectric material, an inorganic dielectric material, or a combination thereof. Please refer to the material illustrated by the gate dielectric layer 130. For example, a protective material layer (not shown) may be formed by chemical vapor deposition (CVD) or other suitable thin film deposition technique, and the contact hole 170' may be formed by a photolithography process.
在步驟90中,形成透明電極180於保護層170上及接觸孔170'中,使透明電極180連接汲極140b,如第2A-2B 圖所示。透明電極180可為單層或多層結構,其材料可例如為氧化銦錫(ITO)、氧化鉿(HfOx)、氧化鋁鋅(AZO)、氧化鋁錫(ATO)、氧化鎵鋅(GZO)、氧化銦鈦(ITiO)、氧化銦鉬(IMO)或其他透明導電材料。例如可先以濺鍍(Sputtering)製程或其他薄膜沉積技術形成一層透明導電層(未繪示)於保護層170上,再利用微影蝕刻製程形成透明電極180。In step 90, a transparent electrode 180 is formed on the protective layer 170 and in the contact hole 170', so that the transparent electrode 180 is connected to the drain 140b, such as 2A-2B. The figure shows. The transparent electrode 180 may be a single layer or a multilayer structure, and the material thereof may be, for example, indium tin oxide (ITO), hafnium oxide (HfOx), aluminum zinc oxide (AZO), aluminum oxide tin (ATO), gallium zinc oxide (GZO), Indium titanium oxide (ITiO), indium oxide molybdenum (IMO) or other transparent conductive material. For example, a transparent conductive layer (not shown) may be formed on the protective layer 170 by a sputtering process or other thin film deposition process, and the transparent electrode 180 may be formed by a photolithography process.
第4圖係顯示依照本發明又一實施方式之頂閘型的薄膜電晶體的剖面示意圖。本方法是於形成氧化物半導體層後再依序形成閘介電層與閘極。本製造方法依序包含下列步驟。首先,形成源極140a及汲極140b於一基材110上。形成圖形絕緣層150局部覆蓋源極140a及汲極140b,且暴露出一部分源極140a及一部分汲極140b。形成氧化物半導體層160接觸源極140a之該部分及汲極140b之該部分。形成閘介電層130覆蓋氧化物半導體層160與圖形絕緣層150。形成閘極120於閘介電層130上。形成保護層170覆蓋閘極120,其保護層170具有一接觸孔170'暴露出一部分的汲極140b。形成透明電極180於保護層170上以及接觸孔170'中。Fig. 4 is a schematic cross-sectional view showing a top gate type thin film transistor according to still another embodiment of the present invention. In the method, after forming the oxide semiconductor layer, the gate dielectric layer and the gate are sequentially formed. The manufacturing method sequentially includes the following steps. First, the source 140a and the drain 140b are formed on a substrate 110. The patterned insulating layer 150 partially covers the source 140a and the drain 140b, and exposes a portion of the source 140a and a portion of the drain 140b. The oxide semiconductor layer 160 is formed to contact the portion of the source 140a and the portion of the drain 140b. The gate dielectric layer 130 is formed to cover the oxide semiconductor layer 160 and the pattern insulating layer 150. Gate 120 is formed on gate dielectric layer 130. The protective layer 170 is formed to cover the gate 120, and the protective layer 170 has a contact hole 170' exposing a portion of the drain 140b. A transparent electrode 180 is formed on the protective layer 170 and in the contact hole 170'.
本發明之另一態樣提供一種薄膜電晶體,其包含源極140a及汲極140b、圖形絕緣層150、氧化物半導體層160、閘極120與閘介電層130,如第2B、3、4圖所示。薄膜電晶體可為第2B、3圖所例示之底閘型(即閘介電層130位於源極140a及汲極140b之下)薄膜電晶體或第4圖所例示之頂閘型(即閘介電層130位於源極140a及汲極140b之上)薄膜電晶體。Another aspect of the present invention provides a thin film transistor including a source 140a and a drain 140b, a pattern insulating layer 150, an oxide semiconductor layer 160, a gate 120, and a gate dielectric layer 130, such as 2B, 3, Figure 4 shows. The thin film transistor may be a bottom gate type exemplified in FIGS. 2B and 3 (ie, the gate dielectric layer 130 is located under the source 140a and the drain 140b) or a top gate type (ie, the gate illustrated in FIG. 4). The dielectric layer 130 is located above the source 140a and the drain 140b) a thin film transistor.
圖形絕緣層150局部覆蓋源極140a及汲極140b,其中圖形絕緣層150具有至少一開口150'露出一部分源極140a及一部分汲極140b,如第2B圖與第4圖所示。The pattern insulating layer 150 partially covers the source 140a and the drain 140b. The pattern insulating layer 150 has at least one opening 150' exposing a portion of the source 140a and a portion of the drain 140b, as shown in FIGS. 2B and 4.
在本實施方式中,開口150'大致對準閘極,如第2B圖與第4圖所示。開口的長度d大於源極140a及汲極140b之間距L。L即為通道長度(channel length)。In the present embodiment, the opening 150' is substantially aligned with the gate as shown in Figures 2B and 4. The length d of the opening is greater than the distance L between the source 140a and the drain 140b. L is the channel length.
在另一實施方式中,如第3圖所示,開口包含一第一開口150'a及一第二開口150'b分別露出源極140a之該部分及汲極140b之該部分。在此不限間距L與第一開口150'a之長度d1或第二開口150'b之長度d2之間的比例關係。In another embodiment, as shown in FIG. 3, the opening includes a first opening 150'a and a second opening 150'b exposing the portion of the source 140a and the portion of the drain 140b, respectively. Here, the proportional relationship between the distance L and the length d1 of the first opening 150'a or the length d2 of the second opening 150'b is defined.
如第2B、3、4圖所示,氧化物半導體層160覆蓋於圖形絕緣層150上,並接觸源極140a之該部分及汲極140b之該部分。如此一來,在進行退火製程時,源極140a及汲極140b被圖形絕緣層150及氧化物半導體層160所覆蓋而完全未露出,故可避免源極140a及汲極140b發生氧化。As shown in FIGS. 2B, 3, and 4, the oxide semiconductor layer 160 covers the pattern insulating layer 150 and contacts the portion of the source 140a and the portion of the drain 140b. As a result, when the annealing process is performed, the source electrode 140a and the drain electrode 140b are covered by the pattern insulating layer 150 and the oxide semiconductor layer 160, and are not exposed at all. Therefore, oxidation of the source electrode 140a and the drain electrode 140b can be avoided.
在一實施方式中,包含本發明實施方式之薄膜電晶體的基板可與對向基板(未繪示)及顯示介質層(未繪示)構成一顯示面板。顯示面板例如為非自發光顯示器(non-self-emissive display)或自發光顯示器(self-emissive display),但不限於此。In one embodiment, the substrate including the thin film transistor of the embodiment of the present invention may be combined with a counter substrate (not shown) and a display medium layer (not shown) to form a display panel. The display panel is, for example, a non-self-emissive display or a self-emissive display, but is not limited thereto.
綜上所述,本發明之實施方式藉由圖形絕緣層保護源極、汲極及同層的元件。如此一來,在進行退火製程時,源極、汲極及同層的元件因未直接暴露於高溫爐中,而可避免其發生氧化,進而影響阻抗及訊號傳輸,而能夠有效解決習知技術領域中所遭遇的問題。In summary, embodiments of the present invention protect source, drain, and peer components by a patterned insulating layer. In this way, when the annealing process is performed, the components of the source, the drain and the same layer are not directly exposed to the high temperature furnace, thereby avoiding oxidation, thereby affecting impedance and signal transmission, and effectively solving the conventional technology. Problems encountered in the field.
雖然本發明已以實施方式揭露如上,然其並非用以限定本發明,任何熟習此技藝者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention, and the present invention can be modified and modified without departing from the spirit and scope of the present invention. The scope is subject to the definition of the scope of the patent application attached.
10、20、30、40、50、60、70、80、90‧‧‧步驟10, 20, 30, 40, 50, 60, 70, 80, 90 ‧ ‧ steps
110‧‧‧基材110‧‧‧Substrate
120‧‧‧閘極120‧‧‧ gate
130‧‧‧閘介電層130‧‧‧gate dielectric layer
140a‧‧‧源極140a‧‧‧ source
140b‧‧‧汲極140b‧‧‧汲polar
150‧‧‧圖形絕緣層150‧‧‧graphic insulation
150'‧‧‧開口150'‧‧‧ openings
150'a‧‧‧第一開口150'a‧‧‧ first opening
150'b‧‧‧第二開口150'b‧‧‧ second opening
160‧‧‧氧化物半導體160‧‧‧Oxide semiconductor
170‧‧‧保護層170‧‧‧Protective layer
170'‧‧‧接觸孔170'‧‧‧Contact hole
180‧‧‧透明電極180‧‧‧Transparent electrode
d‧‧‧開口長度D‧‧‧ opening length
d1‧‧‧第一開口之長度D1‧‧‧ Length of the first opening
d2‧‧‧第二開口之長度D2‧‧‧ Length of the second opening
DL‧‧‧資料線DL‧‧‧ data line
L‧‧‧源極及汲極之間距L‧‧‧The distance between the source and the bungee
SL‧‧‧掃描線SL‧‧‧ scan line
為讓本發明之上述和其他目的、特徵、優點與實施例能更明顯易懂,所附圖式之說明如下:第1圖係顯示本發明一實施方式之薄膜電晶體基板之製造方法的流程圖。The above and other objects, features, advantages and embodiments of the present invention will become more apparent and understood. Figure.
第2A圖係顯示依照本發明一實施方式之薄膜電晶體基板的上視示意圖。2A is a top plan view showing a thin film transistor substrate in accordance with an embodiment of the present invention.
第2B圖係顯示沿第2A圖之2B-2B'線段的薄膜電晶體的剖面示意圖。Fig. 2B is a schematic cross-sectional view showing the thin film transistor along line 2B-2B' of Fig. 2A.
第3圖係顯示依照本發明另一實施方式之薄膜電晶體的剖面示意圖。Fig. 3 is a schematic cross-sectional view showing a thin film transistor according to another embodiment of the present invention.
第4圖係顯示依照本發明又一實施方式之薄膜電晶體的剖面示意圖。Fig. 4 is a schematic cross-sectional view showing a thin film transistor according to still another embodiment of the present invention.
110‧‧‧基材110‧‧‧Substrate
120‧‧‧閘極120‧‧‧ gate
130‧‧‧閘介電層130‧‧‧gate dielectric layer
140a‧‧‧源極140a‧‧‧ source
140b‧‧‧汲極140b‧‧‧汲polar
150‧‧‧圖形絕緣層150‧‧‧graphic insulation
150'‧‧‧開口150'‧‧‧ openings
160‧‧‧氧化物半導體160‧‧‧Oxide semiconductor
170‧‧‧保護層170‧‧‧Protective layer
170'‧‧‧接觸孔170'‧‧‧Contact hole
180‧‧‧透明電極180‧‧‧Transparent electrode
d‧‧‧開口長度D‧‧‧ opening length
L‧‧‧源極及汲極之間距L‧‧‧The distance between the source and the bungee
Claims (12)
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Citations (2)
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| US20100117076A1 (en) * | 2008-11-07 | 2010-05-13 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device and method for manufacturing the semiconductor device |
| US20110156117A1 (en) * | 2009-12-25 | 2011-06-30 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100117076A1 (en) * | 2008-11-07 | 2010-05-13 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device and method for manufacturing the semiconductor device |
| US20110156117A1 (en) * | 2009-12-25 | 2011-06-30 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device |
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