[go: up one dir, main page]

TWI591854B - Light-emitting diode including porous transparent electrode - Google Patents

Light-emitting diode including porous transparent electrode Download PDF

Info

Publication number
TWI591854B
TWI591854B TW104131698A TW104131698A TWI591854B TW I591854 B TWI591854 B TW I591854B TW 104131698 A TW104131698 A TW 104131698A TW 104131698 A TW104131698 A TW 104131698A TW I591854 B TWI591854 B TW I591854B
Authority
TW
Taiwan
Prior art keywords
transparent electrode
electrode layer
layer
light emitting
emitting diode
Prior art date
Application number
TW104131698A
Other languages
Chinese (zh)
Other versions
TW201624767A (en
Inventor
申讚燮
Original Assignee
首爾偉傲世有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 首爾偉傲世有限公司 filed Critical 首爾偉傲世有限公司
Publication of TW201624767A publication Critical patent/TW201624767A/en
Application granted granted Critical
Publication of TWI591854B publication Critical patent/TWI591854B/en

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/83Electrodes
    • H10H20/832Electrodes characterised by their material
    • H10H20/833Transparent materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/83Electrodes
    • H10H20/831Electrodes characterised by their shape

Landscapes

  • Led Devices (AREA)

Description

包括多孔透明電極的發光二極體Light-emitting diode including porous transparent electrode

本發明涉及一種發光二極體,並且更具體地涉及一種包括多孔透明電極以提高光提取效率的發光二極體。 The present invention relates to a light emitting diode, and more particularly to a light emitting diode including a porous transparent electrode to improve light extraction efficiency.

通常,發光二極體是指基於如下原理將電流直接轉換成光的半導體器件:當向半導體p-n接面施加電壓時通過來自n區的電子與來自p區的電洞的複合來發光。由於具有多種優點,例如良好的能量轉換效率、使用壽命長並且光的方向性好、操作電壓低、無需預熱時間或無需複雜的驅動電路、以及良好的耐衝擊和耐震動,發光二極體作為能夠取代現有光源(例如白熾燈、螢光燈、汞燈等等)的下一代光源已經受到了關注。 In general, a light-emitting diode refers to a semiconductor device that directly converts a current into light based on the principle of emitting light by a combination of electrons from the n region and holes from the p region when a voltage is applied to the semiconductor p-n junction. Light-emitting diodes due to various advantages such as good energy conversion efficiency, long service life and good directionality of light, low operating voltage, no need for warm-up time or complex drive circuit, and good shock and vibration resistance As a next-generation light source capable of replacing an existing light source such as an incandescent lamp, a fluorescent lamp, a mercury lamp, or the like, attention has been paid.

發光二極體的照明效率通常取決於內部量子效率和光提取效率。具體來說,光提取效率是指釋放到發光二極體外部(即自由空間)的光子數與主動層發射的光子數之比,且儘管發光二極體的內部量子效率高,但是發光二極體的低光提取效率導致釋放到自由空間的光子數減少,從而導致在實踐中發光二極體作為光源的效率顯著降低。 The illumination efficiency of a light-emitting diode generally depends on internal quantum efficiency and light extraction efficiency. Specifically, the light extraction efficiency refers to the ratio of the number of photons released to the outside of the light-emitting diode (ie, free space) to the number of photons emitted by the active layer, and although the internal quantum efficiency of the light-emitting diode is high, the light-emitting diode The low light extraction efficiency of the volume results in a reduction in the number of photons released into the free space, resulting in a significant reduction in the efficiency of the light-emitting diode as a light source in practice.

在典型的發光二極體中,由於提供光傳輸至自由空間的路徑上的空氣(n空氣=1.0)、GaN類基底(nGaN=2.4)、藍寶石基底(nsapphire=1.77)以及ITO電極(nITO=1.9)之間的介面處折射率不同,因而會發生全內反射,困住大量光,從而導致光提取效率顯著降低。 In a typical light-emitting diode, air (n air = 1.0), GaN-based substrate (nGaN = 2.4), sapphire substrate (nsapphire = 1.77), and ITO electrode (nITO =) are provided on the path of light transmission to free space. 1.9) The refractive index at the interface between the two is different, so total internal reflection occurs, which traps a large amount of light, resulting in a significant decrease in light extraction efficiency.

例如,如圖1所示,從主動層2b發射的光L1、L2通過上部半導體層2c和透明電極3釋放到外部。在上部半導體層2c是由p型GaN製成,並且透明電極3是由銦錫氧化物(indium tin oxide,ITO)製成的情況下,由於折射率不同,光會在介面處發生折射。在這種情況下,當光穿過透明電極3與空氣之間的介面的折射角小於或等於臨界角時,光可以發射到外部,而當光(比如光L2)的折射角大於臨界角時,光就會困在介面內,而不是逃逸到外部。因此,由於全內反射,大量光困在發光二極體內,從而導致發光二極體的光提取效率顯著降低。 For example, as shown in FIG. 1, the light L1, L2 emitted from the active layer 2b is released to the outside through the upper semiconductor layer 2c and the transparent electrode 3. In the case where the upper semiconductor layer 2c is made of p-type GaN, and the transparent electrode 3 is made of indium tin oxide (ITO), light is refracted at the interface due to the difference in refractive index. In this case, when the angle of refraction of the light passing through the interface between the transparent electrode 3 and the air is less than or equal to the critical angle, the light may be emitted to the outside, and when the angle of refraction of the light (such as the light L2) is greater than the critical angle Light will be trapped inside the interface instead of escaping to the outside. Therefore, due to total internal reflection, a large amount of light is trapped in the light-emitting diode, resulting in a significant decrease in light extraction efficiency of the light-emitting diode.

為了有效減少全內反射,提高光提取效率,已經進行了各種努力,例如,蝕刻發光二極體以形成便於光釋放的結構,改變發光二極體的晶片結構,移除反射板,透明電極的表面圖案化等等。 In order to effectively reduce total internal reflection and improve light extraction efficiency, various efforts have been made, for example, etching a light emitting diode to form a structure that facilitates light release, changing a wafer structure of a light emitting diode, removing a reflective plate, and a transparent electrode. Surface patterning and more.

然而,透明電極層的表面圖案化通常是通過諸如電子束微影的製程來執行,而電子束微影難以用於形成大型發光二極體,並且增加了製程成本。此外,當透明電極層的表面經受諸如電子束微影的高能圖案化時,發光二極體的半導體層可能被高能損壞,從而導致發光二極體的可靠性降低。 However, the surface patterning of the transparent electrode layer is usually performed by a process such as electron beam lithography, and electron beam lithography is difficult to form for forming a large-sized light-emitting diode, and the process cost is increased. Further, when the surface of the transparent electrode layer is subjected to high-energy patterning such as electron beam lithography, the semiconductor layer of the light-emitting diode may be damaged by high energy, resulting in a decrease in reliability of the light-emitting diode.

示例性實施例提供一種可以有效減少光的全內反射以提高光提取效率的發光二極體。 The exemplary embodiment provides a light emitting diode that can effectively reduce total internal reflection of light to improve light extraction efficiency.

根據一個示例性實施例,發光二極體包括:發光結構,其包括第一導電型半導體層、設置在第一導電型半導體層上的主動層、以及設置在主動層上的第二導電型半導體層;第一透明電極層,其設置在發光結構上以覆蓋發光結構的一部分,並且具有在第一透明電極層中的多個氣隙;第二透明電極層,其設置在第一透明電極層上,並且具有形成在第二透明電極層中的多個氣隙,形成在第二透明電極層中的氣隙的數目或尺寸比形成在第一透明電極層中的氣隙的數目多或尺寸大;以及電極,其設置在對應於第一透明電極層的位置的第二透明電極層上,其中第一透明電極層具有比第二透明電極層高的比電阻。 According to an exemplary embodiment, a light emitting diode includes: a light emitting structure including a first conductive type semiconductor layer, an active layer disposed on the first conductive type semiconductor layer, and a second conductive type semiconductor disposed on the active layer a first transparent electrode layer disposed on the light emitting structure to cover a portion of the light emitting structure and having a plurality of air gaps in the first transparent electrode layer; and a second transparent electrode layer disposed on the first transparent electrode layer And having a plurality of air gaps formed in the second transparent electrode layer, the number or size of air gaps formed in the second transparent electrode layer being larger or larger than the number of air gaps formed in the first transparent electrode layer And an electrode disposed on the second transparent electrode layer corresponding to the position of the first transparent electrode layer, wherein the first transparent electrode layer has a higher specific resistance than the second transparent electrode layer.

所述第一透明電極層或所述第二透明電極層可由氧化鋅(ZnO)形成,並且所述發光二極體還可包括形成于所述發光結構和所述第一透明電極層之間的隧道接面層(tunnel junction layer)並且包括氧化鎳(NiO)、氧化鎵(Ga2O3)和氧化鎂(MgO)中的至少一種。所述電極可部分嵌入所述第二透明電極層中。 The first transparent electrode layer or the second transparent electrode layer may be formed of zinc oxide (ZnO), and the light emitting diode may further include a photodiode formed between the light emitting structure and the first transparent electrode layer A tunnel junction layer and includes at least one of nickel oxide (NiO), gallium oxide (Ga 2 O 3 ), and magnesium oxide (MgO). The electrode may be partially embedded in the second transparent electrode layer.

所述發光二極體還可包括第三透明電極層,所述第三透明電極層介於在所述第一透明電極層和所述第二透明電極層與所述發光結構之間,並且具有多個形成於第三透明電極層中的氣隙,其中所述第一透明電極層具有比所述第三透明電極層更高的比電阻。 The light emitting diode may further include a third transparent electrode layer interposed between the first transparent electrode layer and the second transparent electrode layer and the light emitting structure, and have a plurality of air gaps formed in the third transparent electrode layer, wherein the first transparent electrode layer has a higher specific resistance than the third transparent electrode layer.

所述第一透明電極層可在所述發光結構上以預定圖案形成,並且所述第一透明電極層的預定圖案可具有選自圓形、六邊形、正方形和三角形中的至少一種形狀。所述發光二極體還可包括從所述電極延伸的電極延伸部,其中所述第一透明電極層的圖案可對應於所述電極和所述電極延伸部的形狀。 The first transparent electrode layer may be formed in a predetermined pattern on the light emitting structure, and the predetermined pattern of the first transparent electrode layer may have at least one shape selected from the group consisting of a circle, a hexagon, a square, and a triangle. The light emitting diode may further include an electrode extension extending from the electrode, wherein a pattern of the first transparent electrode layer may correspond to a shape of the electrode and the electrode extension.

在所述第一透明電極層和所述第二透明電極層的每一者中,所述氣隙的數量或尺寸可從所述發光結構朝向所述電極逐漸增加。 In each of the first transparent electrode layer and the second transparent electrode layer, the number or size of the air gap may gradually increase from the light emitting structure toward the electrode.

根據示例性實施例,所述發光二極體包括具有氣隙的透明電極層,所述氣隙的數量和尺寸沿向上方向逐漸增加,從而使所述折射率沿所述透明電極層逐漸減小,從而提高所述發光二極體的光提取率。 According to an exemplary embodiment, the light emitting diode includes a transparent electrode layer having an air gap, the number and size of the air gap gradually increasing in an upward direction, thereby gradually decreasing the refractive index along the transparent electrode layer Thereby increasing the light extraction rate of the light-emitting diode.

此外,所述發光二極體包括電極,所述電極形成於所述透明電極層上或通過部分蝕刻所述透明電極層而形成的部分處,從而便於垂直電流擴展。 Further, the light emitting diode includes an electrode formed on the transparent electrode layer or at a portion formed by partially etching the transparent electrode layer, thereby facilitating vertical current spreading.

另外,電流阻擋層由與所述透明電極層相同的材料形成,同時調整其比電阻以通過防止從所述發光結構發出的光被所述電流阻擋層反射來減少光損失,並且形成於所述透明電極層上以允許更加有效地電流擴展。 Further, the current blocking layer is formed of the same material as the transparent electrode layer while adjusting its specific resistance to reduce light loss by preventing light emitted from the light emitting structure from being reflected by the current blocking layer, and is formed in the On the transparent electrode layer to allow for more efficient current spreading.

10‧‧‧基底 10‧‧‧Base

20‧‧‧發光結構 20‧‧‧Lighting structure

21‧‧‧第一導電型半導體層 21‧‧‧First Conductive Semiconductor Layer

23‧‧‧主動層 23‧‧‧Active layer

25‧‧‧第二導電型半導體層 25‧‧‧Second conductive semiconductor layer

30‧‧‧透明電極層 30‧‧‧Transparent electrode layer

31‧‧‧第一透明電極層 31‧‧‧First transparent electrode layer

33‧‧‧第二透明電極層 33‧‧‧Second transparent electrode layer

35‧‧‧第三透明電極層 35‧‧‧ third transparent electrode layer

41‧‧‧第一電極 41‧‧‧First electrode

43‧‧‧第二電極 43‧‧‧second electrode

43a‧‧‧電極延伸部 43a‧‧‧Electrode extension

G‧‧‧氣隙 G‧‧‧ air gap

圖1是典型的發光二極體的剖視圖。 1 is a cross-sectional view of a typical light emitting diode.

圖2是根據第一示例性實施例的發光二極體的剖視圖。 2 is a cross-sectional view of a light emitting diode according to a first exemplary embodiment.

圖3(a)至圖3(c)是根據所述第一示例性實施例的發光二極體的透明電極層和其變型的剖視圖。 3(a) to 3(c) are cross-sectional views of a transparent electrode layer of a light emitting diode according to the first exemplary embodiment and a modification thereof.

圖4(a)至圖4(c)是根據第二示例性實施例的發光二極體的透明電極層和其變型的剖視圖。 4(a) to 4(c) are cross-sectional views of a transparent electrode layer of a light-emitting diode and a modification thereof according to a second exemplary embodiment.

圖5(a)至圖5(d)是根據第三示例性實施例的發光二極體的透明電極層和其變型的剖視圖。 5(a) to 5(d) are cross-sectional views of a transparent electrode layer of a light-emitting diode and a modification thereof according to a third exemplary embodiment.

圖6是根據所述第三示例性實施例的發光二極體的第一透明電極層的一個實例的平面圖。 Fig. 6 is a plan view showing one example of a first transparent electrode layer of a light emitting diode according to the third exemplary embodiment.

下面將參照附圖來對示例性實施例進行詳細描述。 The exemplary embodiments will be described in detail below with reference to the drawings.

圖2是根據第一示例性實施例的發光二極體的剖視圖,並且圖3(a)是根據所述第一示例性實施例的發光二極體的透明電極層的放大的剖視圖。 2 is a cross-sectional view of a light emitting diode according to a first exemplary embodiment, and FIG. 3(a) is an enlarged cross-sectional view of a transparent electrode layer of the light emitting diode according to the first exemplary embodiment.

參照圖2,根據所述第一示例性實施例的發光二極體包括基底10、發光結構20、透明電極層30、第一電極41以及第二電極43。 Referring to FIG. 2, the light emitting diode according to the first exemplary embodiment includes a substrate 10, a light emitting structure 20, a transparent electrode layer 30, a first electrode 41, and a second electrode 43.

對於所述基底10,可以使用任何基底而不受限制,只要所述基底允許發光結構20在其上生長。在某些示例性實施例中,所述基底10可為藍寶石基底、SiC基底、尖晶石基底、Si基底或氮化鎵基底。在某些示例性實施例中,所述基底10可具有形成於其上表面上的預定圖案,類似於圖案化的藍寶石基底(patterned sapphire substrate,PPS)。儘管在圖2中未示出,所述發光二極體還可包括形成於所述基底10上的緩衝層以用作用於所述發光結構20的生長的核層,從而提高所述發光結構 20的每個半導體層的結晶度。 For the substrate 10, any substrate may be used without limitation as long as the substrate allows the light-emitting structure 20 to grow thereon. In certain exemplary embodiments, the substrate 10 can be a sapphire substrate, a SiC substrate, a spinel substrate, a Si substrate, or a gallium nitride substrate. In certain exemplary embodiments, the substrate 10 can have a predetermined pattern formed on its upper surface, similar to a patterned sapphire substrate (PPS). Although not shown in FIG. 2, the light emitting diode may further include a buffer layer formed on the substrate 10 to serve as a core layer for growth of the light emitting structure 20, thereby improving the light emitting structure The crystallinity of each of the semiconductor layers of 20.

所述發光結構20設置在所述基底10上,並且包括第一導電型半導體層21、主動層23和第二導電型半導體層25。所述第二導電型半導體層25設置在所述第一導電型半導體層21上並且所述主動層23可介於在所述第一導電型半導體層21和所述第二導電型半導體層25之間。 The light emitting structure 20 is disposed on the substrate 10 and includes a first conductive type semiconductor layer 21, an active layer 23, and a second conductive type semiconductor layer 25. The second conductive type semiconductor layer 25 is disposed on the first conductive type semiconductor layer 21 and the active layer 23 may be interposed between the first conductive type semiconductor layer 21 and the second conductive type semiconductor layer 25 between.

第一導電型半導體層21與第二導電型半導體層25中的每層均可以包括III-V類化合物半導體,例如,諸如(Al,Ga,In)N的氮化物類半導體。第一導電型半導體層21可以包括摻雜有諸如Si的n型摻雜劑的n型半導體層,並且第二導電型半導體層25可以包括摻雜有諸如Mg的p型摻雜劑的p型半導體層。顯然,用於第一導電型半導體層21和第二導電型半導體層25的這些摻雜劑還可以互換。 Each of the first conductive type semiconductor layer 21 and the second conductive type semiconductor layer 25 may include a III-V compound semiconductor, for example, a nitride-based semiconductor such as (Al, Ga, In) N. The first conductive type semiconductor layer 21 may include an n-type semiconductor layer doped with an n-type dopant such as Si, and the second conductive type semiconductor layer 25 may include a p-type doped with a p-type dopant such as Mg Semiconductor layer. It is apparent that these dopants for the first conductive type semiconductor layer 21 and the second conductive type semiconductor layer 25 are also interchangeable.

另外,第一導電型半導體層21和第二導電型半導體層25中的每層均可以由單層或多層構成。例如,第一導電型半導體層21和/或第二導電型半導體層25可以包括覆蓋層和接觸層,並且還可以包括超晶格層。 In addition, each of the first conductive type semiconductor layer 21 and the second conductive type semiconductor layer 25 may be composed of a single layer or a plurality of layers. For example, the first conductive type semiconductor layer 21 and/or the second conductive type semiconductor layer 25 may include a cover layer and a contact layer, and may further include a superlattice layer.

主動層23可以包括多量子阱(multi-quantum well,MQW)結構,並且可以調整構成多量子阱結構的元素以及其組分以允許多量子阱結構發出具有所需峰值波長的光。例如,主動層23的阱層可以是如InGaN的三元半導體層或如AlInGaN的四元半導體層,其中可以調整成分的組分比例以發出具有所需峰值波長的光。 The active layer 23 may include a multi-quantum well (MQW) structure, and the elements constituting the multiple quantum well structure and its components may be adjusted to allow the multiple quantum well structure to emit light having a desired peak wavelength. For example, the well layer of the active layer 23 may be a ternary semiconductor layer such as InGaN or a quaternary semiconductor layer such as AlInGaN, in which the composition ratio of the components may be adjusted to emit light having a desired peak wavelength.

第一導電型半導體層21、主動層23以及第二導電型半導體層25中的每層均可以通過如金屬有機化學氣相沈積(metal organic chemical vapor deposition,MOCVD)、分子束外延(molecular beam epitaxy,MBE)或氫化物氣相外延(hydride vapor phase epitaxy,HVPE)的技術來在生長基底上生長。第一導電型半導體層21可以通過微影和蝕刻製程進行圖案化,從而暴露其中一些區域。 Each of the first conductive type semiconductor layer 21, the active layer 23, and the second conductive type semiconductor layer 25 may be passed through, for example, metal organic chemical vapor deposition (metal organic chemical) Vapor deposition (MOCVD), molecular beam epitaxy (MBE) or hydride vapor phase epitaxy (HVPE) techniques are used to grow on growth substrates. The first conductive type semiconductor layer 21 may be patterned by a lithography and etching process to expose some of the regions.

透明電極層30設置在第二導電型半導體層25上。透明電極層30通過對傳送給發光二極體的電流進行分散來用於提高發光面積,並且在第一示例性實施例中,透明電極層30可以包括如ZnO的導電材料。 The transparent electrode layer 30 is disposed on the second conductive type semiconductor layer 25. The transparent electrode layer 30 is used to increase the light-emitting area by dispersing a current transmitted to the light-emitting diode, and in the first exemplary embodiment, the transparent electrode layer 30 may include a conductive material such as ZnO.

如圖2中所示,在第一示例性實施例中,透明電極層30包括多個氣隙G。如圖2中所示,在本示例性實施例中,形成在透明電極層30中的氣隙G充滿空氣,並且可以彼此分離或彼此連接。氣隙G可以具有圓形或六邊形橫截面。 As shown in FIG. 2, in the first exemplary embodiment, the transparent electrode layer 30 includes a plurality of air gaps G. As shown in FIG. 2, in the present exemplary embodiment, the air gaps G formed in the transparent electrode layer 30 are filled with air, and may be separated from each other or connected to each other. The air gap G may have a circular or hexagonal cross section.

如圖3(a)所示,在本示例性實施例中,氣隙G可以形成在透明電極層30中,使得氣隙G的數目或大小從透明電極層30下側至其上側(沿著從第二導電型半導體層25至第二電極43的方向)逐漸增加。以這種方式,氣隙G形成在透明電極層30中,同時調節氣隙G的密度,使得氣隙的數目或大小從透明電極層30的下側至其上側逐漸增加,從而提高發光二極體的光提取效率。 As shown in FIG. 3(a), in the present exemplary embodiment, an air gap G may be formed in the transparent electrode layer 30 such that the number or size of the air gap G is from the lower side of the transparent electrode layer 30 to the upper side thereof (along The direction from the second conductive type semiconductor layer 25 to the second electrode 43 is gradually increased. In this manner, the air gap G is formed in the transparent electrode layer 30 while adjusting the density of the air gap G such that the number or size of the air gap gradually increases from the lower side of the transparent electrode layer 30 to the upper side thereof, thereby improving the light emitting diode Light extraction efficiency of the body.

同樣,氣隙G形成在透明電極層30中,使得氣隙的數目或大小從透明電極層30的下側至其上側逐漸增加,從而使發光二極體的全內反射最小化。隨著在透明電極層30中的氣隙G的數目或大小增加,透明電極層30內部的折射率降低。 Also, the air gap G is formed in the transparent electrode layer 30 such that the number or size of the air gap gradually increases from the lower side of the transparent electrode layer 30 to the upper side thereof, thereby minimizing total internal reflection of the light emitting diode. As the number or size of the air gaps G in the transparent electrode layer 30 increases, the refractive index inside the transparent electrode layer 30 decreases.

在本示例性實施例中,通過混合奈米結構製備的溶膠-凝膠 (sol-gel)材料用於在透明電極層30中形成氣隙。此處,通過將奈米結構與ZnO混合形成溶膠-凝膠材料,該材料在第一示例性實施例中用作透明電極層30的原材料。此處,奈米結構可以是具有0.1um到3um的粒徑的奈米球。如在第一示例性實施例中,奈米結構的分佈可以根據透明電極層30的位置進行調整,以獲得氣隙G的所期望的數目或大小。然後,可以通過選擇性使用煆燒來去除奈米結構,以在透明電極層30中形成多個氣隙。 In the present exemplary embodiment, a sol-gel prepared by mixing a nanostructure A (sol-gel) material is used to form an air gap in the transparent electrode layer 30. Here, a sol-gel material is formed by mixing a nanostructure with ZnO, which is used as a raw material of the transparent electrode layer 30 in the first exemplary embodiment. Here, the nanostructure may be a nanosphere having a particle diameter of 0.1 um to 3 um. As in the first exemplary embodiment, the distribution of the nanostructures may be adjusted according to the position of the transparent electrode layer 30 to obtain a desired number or size of the air gaps G. Then, the nanostructure can be removed by selectively using helium to form a plurality of air gaps in the transparent electrode layer 30.

再次參照圖2,第二電極43形成在透明電極層30上,並且第一電極41設置在第一導電型半導體層21的暴露出的區域上。因此,第二電極43通過透明電極層30電連接至第二導電型半導體層25,並且第一電極41電連接至第一導電型半導體層21。 Referring again to FIG. 2, the second electrode 43 is formed on the transparent electrode layer 30, and the first electrode 41 is disposed on the exposed region of the first conductive type semiconductor layer 21. Therefore, the second electrode 43 is electrically connected to the second conductive type semiconductor layer 25 through the transparent electrode layer 30, and the first electrode 41 is electrically connected to the first conductive type semiconductor layer 21.

雖然已經參照橫向型發光二極體描述了第一示例性實施例,但是應當理解,本公開內容不限於此,並且其他實現方式是可能的。在另外的示例性實施例中,垂直發光二極體包括具有形成在其中的氣隙G的透明電極層30,以使全內反射最小化,從而提高光提取效率。 Although the first exemplary embodiment has been described with reference to a lateral type light emitting diode, it should be understood that the present disclosure is not limited thereto, and other implementations are possible. In a further exemplary embodiment, the vertical light emitting diode includes a transparent electrode layer 30 having an air gap G formed therein to minimize total internal reflection, thereby improving light extraction efficiency.

根據第一示例性實施例,發光二極體還可以包括在發光結構20與透明電極層30之間的隧道接面層(未示出)。在發光結構20上形成薄厚度的隧道接面層以改善透明電極層30與發光結構20之間的歐姆接觸,並且隧道接面層可以包含NiO、Ga2O3和MgO中的至少一者。 According to the first exemplary embodiment, the light emitting diode may further include a tunnel junction layer (not shown) between the light emitting structure 20 and the transparent electrode layer 30. A thin thickness tunnel junction layer is formed on the light emitting structure 20 to improve ohmic contact between the transparent electrode layer 30 and the light emitting structure 20, and the tunnel junction layer may include at least one of NiO, Ga 2 O 3 , and MgO.

圖3(b)是根據第一示例性實施例的發光二極體的透明電極層的一種變型的剖視圖。 Fig. 3 (b) is a cross-sectional view showing a modification of the transparent electrode layer of the light emitting diode according to the first exemplary embodiment.

如圖3(b)中所示,在第一示例性實施例的這種變型中,透 明電極層30包括第一透明電極層31和第二透明電極層33。第一透明電極層31可以設置在第二導電型半導體層25上,並且第二透明電極層33可以設置在第一透明電極層31上。在此,第二透明電極層33可以具有比第一透明電極層31更多數目或更大尺寸的氣隙G。因此,氣隙G的數目或尺寸沿向上方向逐漸增大。此外,根據需要,透明電極層可以包括第三透明電極層,第三透明電極層可以形成在第二透明電極層33上並且具有比第二透明電極層33更多數目或更大尺寸的氣隙G。 As shown in FIG. 3(b), in this modification of the first exemplary embodiment, The bright electrode layer 30 includes a first transparent electrode layer 31 and a second transparent electrode layer 33. The first transparent electrode layer 31 may be disposed on the second conductive type semiconductor layer 25, and the second transparent electrode layer 33 may be disposed on the first transparent electrode layer 31. Here, the second transparent electrode layer 33 may have an air gap G of a larger number or larger size than the first transparent electrode layer 31. Therefore, the number or size of the air gap G gradually increases in the upward direction. Further, the transparent electrode layer may include a third transparent electrode layer, which may be formed on the second transparent electrode layer 33 and have a larger or larger size than the second transparent electrode layer 33, as needed G.

在第一示例性實施例的這種變型中,第二電極43可以形成在第二透明電極層33上並且電連接至第二導電型半導體層25。 In this modification of the first exemplary embodiment, the second electrode 43 may be formed on the second transparent electrode layer 33 and electrically connected to the second conductive type semiconductor layer 25.

圖3(c)是根據第一示例性實施例的發光二極體的透明電極層的另一種變型的剖視圖。 Fig. 3 (c) is a cross-sectional view showing another modification of the transparent electrode layer of the light emitting diode according to the first exemplary embodiment.

如圖3(c)中所示,在第一示例性實施例的這種變型中,可以形成透明電極層30使得氣隙G的數目或尺寸從透明電極層的下側至上側(沿著從第二導電型半導體層25至第二電極43的方向)逐漸增大。另外,透明電極層30可以通過蝕刻被部分地去除,使得第二電極43部分地嵌入透明電極層30中。以這種方式,採用其中第二電極43設置在由部分地蝕刻形成的透明電極層30的經蝕刻的區域上的結構,電流路徑的長度可以沿垂直方向降低,從而提供了在電流擴展方面的優點。 As shown in FIG. 3(c), in this modification of the first exemplary embodiment, the transparent electrode layer 30 may be formed such that the number or size of the air gap G is from the lower side to the upper side of the transparent electrode layer (along the slave The direction from the second conductive type semiconductor layer 25 to the second electrode 43 is gradually increased. In addition, the transparent electrode layer 30 may be partially removed by etching such that the second electrode 43 is partially embedded in the transparent electrode layer 30. In this manner, with a structure in which the second electrode 43 is disposed on the etched region of the transparent electrode layer 30 formed by partial etching, the length of the current path can be lowered in the vertical direction, thereby providing a current expansion. advantage.

圖4(a)是根據第二示例性實施例的發光二極體的透明電極層的剖視圖。 4(a) is a cross-sectional view of a transparent electrode layer of a light emitting diode according to a second exemplary embodiment.

根據第二示例性實施例的發光二極體包括基底10、發光結構20、第一透明電極層31、第二透明電極層33、第一電極41和第二電極 43,並且將省略與第一示例性實施例中的特徵相同的特徵的描述。 The light emitting diode according to the second exemplary embodiment includes a substrate 10, a light emitting structure 20, a first transparent electrode layer 31, a second transparent electrode layer 33, a first electrode 41, and a second electrode 43. Description of the same features as those in the first exemplary embodiment will be omitted.

如圖4(a)中所示,第一透明電極層31設置在發光結構20的第二導電型半導體層25上。在此,第一透明電極層31可以僅形成在第二導電型半導體層25的一些區域上。此外,第二透明電極層33形成在第二導電型半導體層25上以覆蓋第一透明電極層31。 As shown in FIG. 4(a), the first transparent electrode layer 31 is disposed on the second conductive type semiconductor layer 25 of the light emitting structure 20. Here, the first transparent electrode layer 31 may be formed only on some regions of the second conductive type semiconductor layer 25. Further, a second transparent electrode layer 33 is formed on the second conductive type semiconductor layer 25 to cover the first transparent electrode layer 31.

在該示例性實施例中,第一透明電極層31具有比第二透明電極層33更高的比電阻,並且第一透明電極層31和第二透明電極層33中的每一個電極層包含ZnO,使得第一透明電極層31的ZnO具有比第二透明電極層33的ZnO更高的比電阻。第二電極43形成在第一透明電極層31上方的第二透明電極層33上。採用這種結構,第一透明電極層31用作第二示例性實施例中的電流阻擋層(current blocking layer,CBL)。 In the exemplary embodiment, the first transparent electrode layer 31 has a higher specific resistance than the second transparent electrode layer 33, and each of the first transparent electrode layer 31 and the second transparent electrode layer 33 contains ZnO The ZnO of the first transparent electrode layer 31 is made to have a higher specific resistance than the ZnO of the second transparent electrode layer 33. The second electrode 43 is formed on the second transparent electrode layer 33 above the first transparent electrode layer 31. With this configuration, the first transparent electrode layer 31 functions as a current blocking layer (CBL) in the second exemplary embodiment.

在其中第一透明電極層31和第二透明電極層33兩者均包含相同的材料即ZnO,並且第一透明電極層31具有比第二透明電極層33高的比電阻的結構中,電流可以沿著第二電極43的垂直方向通過電流阻擋層流動,從而實現了更有效的電流擴展。 In a structure in which both the first transparent electrode layer 31 and the second transparent electrode layer 33 comprise the same material, that is, ZnO, and the first transparent electrode layer 31 has a higher specific resistance than the second transparent electrode layer 33, the current may be The current blocking layer flows along the vertical direction of the second electrode 43, thereby achieving more efficient current spreading.

此外,如在第一示例性實施例中,氣隙G可以在第二透明電極層33中形成,使得氣隙G的數目或尺寸從第二透明電極層的下側至其上側(沿著從第二導電類型半導體層25至第二電極43的方向)逐漸增大。 Further, as in the first exemplary embodiment, the air gap G may be formed in the second transparent electrode layer 33 such that the number or size of the air gap G is from the lower side of the second transparent electrode layer to the upper side thereof (along the slave The direction from the second conductive type semiconductor layer 25 to the second electrode 43 is gradually increased.

根據第二示例性實施例的發光二極體還可以包括在發光結構20與第一透明電極層31和第二透明電極層33之間的隧道接面層(未示出)。在發光結構20上形成薄厚度的隧道接面層以改善第一透明電極層 31和第二透明電極層33與發光結構20之間的歐姆接觸,並且隧道接面層可以包含NiO、Ga2O3和MgO中的至少之一。 The light emitting diode according to the second exemplary embodiment may further include a tunnel junction layer (not shown) between the light emitting structure 20 and the first transparent electrode layer 31 and the second transparent electrode layer 33. A thin junction tunnel junction layer is formed on the light emitting structure 20 to improve ohmic contact between the first transparent electrode layer 31 and the second transparent electrode layer 33 and the light emitting structure 20, and the tunnel junction layer may include NiO, Ga 2 O At least one of 3 and MgO.

圖4(b)是根據第二示例性實施例的發光二極體的透明電極層的一種變型的剖視圖。 4(b) is a cross-sectional view showing a modification of the transparent electrode layer of the light emitting diode according to the second exemplary embodiment.

如圖4(b)中所示,在第二示例性實施例的這種變型中,透明電極層30包括第一透明電極層31、第二透明電極層33和第三透明電極層35。 As shown in FIG. 4(b), in this modification of the second exemplary embodiment, the transparent electrode layer 30 includes a first transparent electrode layer 31, a second transparent electrode layer 33, and a third transparent electrode layer 35.

第三透明電極層35設置在發光結構20的第二導電型半導體層25上,並且第一透明電極層31形成在第三透明電極層35的一些區域上。第二透明電極層33形成在第三透明電極層35上以覆蓋第一透明電極層31。因此,第二透明電極層33與第三透明電極層35中未形成有第一透明電極層31的區域接觸。 The third transparent electrode layer 35 is disposed on the second conductive type semiconductor layer 25 of the light emitting structure 20, and the first transparent electrode layer 31 is formed on some regions of the third transparent electrode layer 35. The second transparent electrode layer 33 is formed on the third transparent electrode layer 35 to cover the first transparent electrode layer 31. Therefore, the second transparent electrode layer 33 is in contact with a region of the third transparent electrode layer 35 where the first transparent electrode layer 31 is not formed.

第二透明電極層33具有比第三透明電極層35更多數目或更大尺寸的氣隙G。此外,第一透明電極層31形成為具有比第二透明電極層33和第三透明電極層35高的比電阻。在第二示例性實施例的這種變型中,由於第一透明電極層31、第二透明電極層33以及第三透明電極層35包含ZnO,因此第一透明電極層31用作電流阻擋層。即,第二電極43形成在第一透明電極層31上方的第二透明電極層33上。 The second transparent electrode layer 33 has a larger number or larger size of the air gap G than the third transparent electrode layer 35. Further, the first transparent electrode layer 31 is formed to have a higher specific resistance than the second transparent electrode layer 33 and the third transparent electrode layer 35. In this modification of the second exemplary embodiment, since the first transparent electrode layer 31, the second transparent electrode layer 33, and the third transparent electrode layer 35 contain ZnO, the first transparent electrode layer 31 functions as a current blocking layer. That is, the second electrode 43 is formed on the second transparent electrode layer 33 above the first transparent electrode layer 31.

隧道接面層(未示出)可以介於第三透明電極層35與發光結構20之間。 A tunnel junction layer (not shown) may be interposed between the third transparent electrode layer 35 and the light emitting structure 20.

圖4(c)是根據第二示例性實施例的發光二極體的透明電極層的另一種變型的剖視圖。 4(c) is a cross-sectional view showing another modification of the transparent electrode layer of the light emitting diode according to the second exemplary embodiment.

如圖4(c)中所示,第二透明電極層33通過蝕刻被部分地去除以暴露出第一透明電極層31的一部分,並且第二電極43形成在第一透明電極層31的所暴露出的區域上。在該結構中,第二電極43與第一透明電極層31直接接觸。如上所述,由於第一透明電極層31包含ZnO,因此電流可以沿著垂直方向流過第一透明電極層31。由於電流可以沿第二電極43的垂直方向流動,因此沿著水準方向的電流擴展變得更加有效。 As shown in FIG. 4(c), the second transparent electrode layer 33 is partially removed by etching to expose a portion of the first transparent electrode layer 31, and the second electrode 43 is exposed at the first transparent electrode layer 31. Out of the area. In this configuration, the second electrode 43 is in direct contact with the first transparent electrode layer 31. As described above, since the first transparent electrode layer 31 contains ZnO, current can flow through the first transparent electrode layer 31 in the vertical direction. Since current can flow in the vertical direction of the second electrode 43, current spreading in the level direction becomes more effective.

圖5(a)是根據第三示例性實施例的發光二極體的透明電極層的剖視圖。 Fig. 5(a) is a cross-sectional view of a transparent electrode layer of a light emitting diode according to a third exemplary embodiment.

如圖5(a)中所示,根據第三示例性實施例的發光二極體的透明電極層30包括第一透明電極層31和第二透明電極層33。另外,第一透明電極層31以預定圖案形成在發光結構20的第二導電型半導體層25上。第一透明電極層31形成在第二導電型半導體層25的一些區域上,或者形成在其整個區域上。 As shown in FIG. 5(a), the transparent electrode layer 30 of the light emitting diode according to the third exemplary embodiment includes a first transparent electrode layer 31 and a second transparent electrode layer 33. In addition, the first transparent electrode layer 31 is formed on the second conductive type semiconductor layer 25 of the light emitting structure 20 in a predetermined pattern. The first transparent electrode layer 31 is formed on some regions of the second conductive type semiconductor layer 25 or formed over the entire region thereof.

在該示例性實施例中,第一透明電極層31可以以具有選自圓形、六邊形、四邊形和三角形形狀中的至少一種形狀的圖案形成在第二導電型半導體層25上。此外,第一透明電極層31的圖案可以根據需要以各種方式改變。下面將描述第一透明電極層31的圖案的變型。 In the exemplary embodiment, the first transparent electrode layer 31 may be formed on the second conductive type semiconductor layer 25 in a pattern having at least one shape selected from the group consisting of a circular shape, a hexagonal shape, a quadrangular shape, and a triangular shape. Further, the pattern of the first transparent electrode layer 31 can be changed in various ways as needed. A modification of the pattern of the first transparent electrode layer 31 will be described below.

形成第二透明電極層33以覆蓋具有形成在其上的圖案的第一透明電極層31。因此,形成第二透明電極層33以覆蓋第一透明電極層31,同時第二透明電極層33與第二導電型半導體層25的一部分接觸。第二電極43形成在第二透明電極層33上。在其中第一透明電極層31 形成在第二導電型半導體層25的整體區域上的結構中,第一透明電極層31可以形成在第二透明電極層33上的任何位置處。相反地,在其中第一透明電極層31形成在第二導電型半導體層25的一些區域上的結構中,第二電極43可以形成在第一透明電極層31上方的第二透明電極層33上。 The second transparent electrode layer 33 is formed to cover the first transparent electrode layer 31 having the pattern formed thereon. Therefore, the second transparent electrode layer 33 is formed to cover the first transparent electrode layer 31 while the second transparent electrode layer 33 is in contact with a portion of the second conductive type semiconductor layer 25. The second electrode 43 is formed on the second transparent electrode layer 33. In which the first transparent electrode layer 31 In the structure formed on the entire region of the second conductive type semiconductor layer 25, the first transparent electrode layer 31 may be formed at any position on the second transparent electrode layer 33. Conversely, in the structure in which the first transparent electrode layer 31 is formed on some regions of the second conductive type semiconductor layer 25, the second electrode 43 may be formed on the second transparent electrode layer 33 above the first transparent electrode layer 31. .

採用這種結構,第一透明電極層31用作電流阻擋層(CBL)。為此,第一透明電極層31包含ZnO,第一透明電極層31的比電阻高於第二透明電極層33的比電阻。因此,電流可以容易地通過由ZnO形成並且具有預定圖案的第一透明電極層31,從而能夠方便電流擴展。 With this configuration, the first transparent electrode layer 31 functions as a current blocking layer (CBL). To this end, the first transparent electrode layer 31 contains ZnO, and the specific resistance of the first transparent electrode layer 31 is higher than the specific resistance of the second transparent electrode layer 33. Therefore, the current can easily pass through the first transparent electrode layer 31 formed of ZnO and having a predetermined pattern, so that current spreading can be facilitated.

此外,氣隙G可以在第二透明電極層33中形成,使得氣隙G的數目或尺寸從第二透明電極層的下側至其上側(沿著從第二導電型半導體層25至第二電極43的方向)逐漸增大。 Further, an air gap G may be formed in the second transparent electrode layer 33 such that the number or size of the air gap G is from the lower side of the second transparent electrode layer to the upper side thereof (along from the second conductive type semiconductor layer 25 to the second The direction of the electrode 43 is gradually increased.

根據第二示例性實施例的發光二極體還可以包括發光結構20與第一透明電極層31和第二透明電極層33之間的隧道接面層(未示出)。在發光結構20上形成薄厚度的隧道接面層以改善第一透明電極層31和第二透明電極層33與發光結構20之間的歐姆接觸,並且隧道接面層可以包含NiO、Ga2O3和MgO中的至少一者。 The light emitting diode according to the second exemplary embodiment may further include a tunnel junction layer (not shown) between the light emitting structure 20 and the first transparent electrode layer 31 and the second transparent electrode layer 33. A thin junction tunnel junction layer is formed on the light emitting structure 20 to improve ohmic contact between the first transparent electrode layer 31 and the second transparent electrode layer 33 and the light emitting structure 20, and the tunnel junction layer may include NiO, Ga 2 O At least one of 3 and MgO.

圖5(b)是根據第三示例性實施例的發光二極體的透明電極層的一種變型的剖視圖。 Fig. 5 (b) is a cross-sectional view showing a modification of the transparent electrode layer of the light emitting diode according to the third exemplary embodiment.

如圖5(b)中所示,在第三示例性實施例的這種變型中,透明電極層30包括第一透明電極層31和第二透明電極層33。第二透明電極層33通過蝕刻被部分地去除以暴露出具有預定圖案的第一透明電極 層31的一部分,並且第二電極43形成在第一透明電極層31的所暴露出的區域上。在該結構中,第二電極43可以與第一透明電極層31的部分暴露出的區域接觸。 As shown in FIG. 5(b), in this modification of the third exemplary embodiment, the transparent electrode layer 30 includes a first transparent electrode layer 31 and a second transparent electrode layer 33. The second transparent electrode layer 33 is partially removed by etching to expose the first transparent electrode having a predetermined pattern A portion of the layer 31, and the second electrode 43 is formed on the exposed region of the first transparent electrode layer 31. In this configuration, the second electrode 43 may be in contact with a portion of the first transparent electrode layer 31 exposed.

此外,氣隙G可以在第二透明電極層33中形成,使得氣隙G的數目或尺寸從第二透明電極層的下側至其上側(沿著從第二導電型半導體層25至第二電極43的方向)逐漸增大。 Further, an air gap G may be formed in the second transparent electrode layer 33 such that the number or size of the air gap G is from the lower side of the second transparent electrode layer to the upper side thereof (along from the second conductive type semiconductor layer 25 to the second The direction of the electrode 43 is gradually increased.

圖5(c)是根據第三示例性實施例的發光二極體的透明電極層的另一種變型的剖視圖。 Fig. 5 (c) is a cross-sectional view showing another modification of the transparent electrode layer of the light emitting diode according to the third exemplary embodiment.

如圖5(c)中所示,在第三示例性實施例的這種變型中,透明電極層30包括第一透明電極層31、第二透明電極層33和第三透明電極層35。 As shown in FIG. 5(c), in this modification of the third exemplary embodiment, the transparent electrode layer 30 includes a first transparent electrode layer 31, a second transparent electrode layer 33, and a third transparent electrode layer 35.

第三透明電極層35設置在發光結構20的第二導電型半導體層25上,並且第一透明電極層31以預定圖案形成在第三透明電極層35上。在第三示例性實施例的這種變型中,第一透明電極層31形成在第三透明電極層35的一些區域上,或者形成在第三透明電極層35的整個區域上。第二透明電極層33形成在第三透明電極層35上以覆蓋第一透明電極層31。因此,第二透明電極層33與第三透明電極層35中未形成有第一透明電極層31的區域接觸。 The third transparent electrode layer 35 is disposed on the second conductive type semiconductor layer 25 of the light emitting structure 20, and the first transparent electrode layer 31 is formed on the third transparent electrode layer 35 in a predetermined pattern. In this modification of the third exemplary embodiment, the first transparent electrode layer 31 is formed on some regions of the third transparent electrode layer 35 or on the entire region of the third transparent electrode layer 35. The second transparent electrode layer 33 is formed on the third transparent electrode layer 35 to cover the first transparent electrode layer 31. Therefore, the second transparent electrode layer 33 is in contact with a region of the third transparent electrode layer 35 where the first transparent electrode layer 31 is not formed.

在第三示例性實施例的這種變型中,第一透明電極層31可以以選自圓形、六邊形、四邊形和三角形形狀中的至少一種形狀形成在第三透明電極層35上。此外,第一透明電極層31的圖案可以根據需要以各種方式改變。 In this modification of the third exemplary embodiment, the first transparent electrode layer 31 may be formed on the third transparent electrode layer 35 in at least one shape selected from the group consisting of a circular shape, a hexagonal shape, a quadrangular shape, and a triangular shape. Further, the pattern of the first transparent electrode layer 31 can be changed in various ways as needed.

第二電極43形成在第二透明電極層33上。在其中第一透明電極層31形成在第二導電型半導體層25的整個區域上的結構中,第一透明電極層31可形成在第二透明電極層33上的任何位置處。相反,在其中第一透明電極層31形成在第二導電型半導體層25的一些區域上的結構中,第二電極43可形成在第一透明電極層31上方的第二透明電極層33上。 The second electrode 43 is formed on the second transparent electrode layer 33. In the structure in which the first transparent electrode layer 31 is formed over the entire region of the second conductive type semiconductor layer 25, the first transparent electrode layer 31 may be formed at any position on the second transparent electrode layer 33. In contrast, in the structure in which the first transparent electrode layer 31 is formed on some regions of the second conductive type semiconductor layer 25, the second electrode 43 may be formed on the second transparent electrode layer 33 above the first transparent electrode layer 31.

採用這種結構,第一透明電極層31用作電流阻擋層(CBL)。為此,第一透明電極層31包含ZnO,ZnO的比電阻高於第二透明電極層33的比電阻。相應地,電流可容易地通過由ZnO形成並且具有預定圖案的第一透明電極層31,從而實現容易的電流擴展。 With this configuration, the first transparent electrode layer 31 functions as a current blocking layer (CBL). To this end, the first transparent electrode layer 31 contains ZnO, and the specific resistance of ZnO is higher than the specific resistance of the second transparent electrode layer 33. Accordingly, current can easily pass through the first transparent electrode layer 31 formed of ZnO and having a predetermined pattern, thereby achieving easy current spreading.

在該變型中,第二透明電極層33具有比第三透明電極層35更多數目或更大尺寸的氣隙G。 In this modification, the second transparent electrode layer 33 has a larger or larger size air gap G than the third transparent electrode layer 35.

圖5(d)是根據第三示例性實施例的發光二極體的透明電極層的另一變型的剖視圖。 Fig. 5 (d) is a cross-sectional view showing another modification of the transparent electrode layer of the light emitting diode according to the third exemplary embodiment.

如圖5(d)中所示,在第三示例性實施例的這種變型中,透明電極層30包括第一透明電極層31、第二透明電極層33和第三透明電極層35。 As shown in FIG. 5(d), in this modification of the third exemplary embodiment, the transparent electrode layer 30 includes a first transparent electrode layer 31, a second transparent electrode layer 33, and a third transparent electrode layer 35.

第三透明電極層35設置在發光結構20的第二導電型半導體層25上,並且第一透明電極層31以預定圖案形成在第三透明電極層35上。在第三實施例的這種變型中,第一透明電極層31形成在第三透明電極層35的一些區域上或者第三透明電極層35的整個區域上。第二透明電極層33形成在第三透明電極層35上以覆蓋第一透明電極層31。相應 地,第二透明電極層33接觸第三透明電極層35的其中未形成第一透明電極層31的區域。 The third transparent electrode layer 35 is disposed on the second conductive type semiconductor layer 25 of the light emitting structure 20, and the first transparent electrode layer 31 is formed on the third transparent electrode layer 35 in a predetermined pattern. In this modification of the third embodiment, the first transparent electrode layer 31 is formed on some regions of the third transparent electrode layer 35 or the entire region of the third transparent electrode layer 35. The second transparent electrode layer 33 is formed on the third transparent electrode layer 35 to cover the first transparent electrode layer 31. corresponding The second transparent electrode layer 33 contacts a region of the third transparent electrode layer 35 in which the first transparent electrode layer 31 is not formed.

在第三示例性實施例的這種變型中,第二透明電極層33通過蝕刻予以部分去除以便暴露第一透明電極層31的一部分。在這種結構中,第二電極43可形成在第一透明電極層31的暴露區域上並且接觸第一透明電極層31的暴露區域。 In this modification of the third exemplary embodiment, the second transparent electrode layer 33 is partially removed by etching to expose a portion of the first transparent electrode layer 31. In this configuration, the second electrode 43 may be formed on the exposed region of the first transparent electrode layer 31 and contact the exposed region of the first transparent electrode layer 31.

第一透明電極層31的圖案與根據上述第三示例性實施例的第一透明電極層31的圖案相同,並且第二透明電極層33和第三透明電極層35與第三示例性實施例的其他變型的第二透明電極層33和第三透明電極層35相同。另外,隧道接面層(未示出)可以介於第三透明電極層35與發光結構20之間。 The pattern of the first transparent electrode layer 31 is the same as that of the first transparent electrode layer 31 according to the above-described third exemplary embodiment, and the second transparent electrode layer 33 and the third transparent electrode layer 35 are the same as those of the third exemplary embodiment. The other second transparent electrode layer 33 and the third transparent electrode layer 35 are the same. In addition, a tunnel junction layer (not shown) may be interposed between the third transparent electrode layer 35 and the light emitting structure 20.

圖6是在第三示例性實施例中具有預定圖案的第一透明電極層31的一個示例的平面圖。 FIG. 6 is a plan view of one example of the first transparent electrode layer 31 having a predetermined pattern in the third exemplary embodiment.

如上所述,第一透明電極層31的圖案可以具有從圓形、六邊形、四邊形和三角形形狀當中選擇的至少一種形狀,並且可以沿著第二電極43和電極延伸部43a形成,如圖6所示。 As described above, the pattern of the first transparent electrode layer 31 may have at least one shape selected from the group consisting of a circular shape, a hexagonal shape, a quadrangular shape, and a triangular shape, and may be formed along the second electrode 43 and the electrode extension portion 43a, as shown in the drawing. 6 is shown.

參考圖6,電極延伸部43a從第二電極43延伸以分散在第二電極43處聚集的電流。第二電極43和電極延伸部43a形成在第二透明電極層33上。採用其中第二電極43和電極延伸部43a形成在第二透明電極層33上的結構,第一透明電極層31可以以與第二電極43和電極延伸部43a相同的圖案形成。 Referring to FIG. 6, the electrode extension portion 43a extends from the second electrode 43 to disperse the current accumulated at the second electrode 43. The second electrode 43 and the electrode extension portion 43a are formed on the second transparent electrode layer 33. With the structure in which the second electrode 43 and the electrode extension portion 43a are formed on the second transparent electrode layer 33, the first transparent electrode layer 31 may be formed in the same pattern as the second electrode 43 and the electrode extension portion 43a.

即,第一透明電極層31以與第二電極43和電極延伸部43a的 大小和形狀相同的形式形成,並且沿著第二電極43和電極延伸部43a設置在第二透明電極層33下方。相應地,第一透明電極層31允許來自第二電極43和電極延伸部43a的電流容易地從中通過,從而能使水準方向上的電流擴展更容易。 That is, the first transparent electrode layer 31 is in contact with the second electrode 43 and the electrode extension portion 43a. The same size and shape are formed, and are disposed under the second transparent electrode layer 33 along the second electrode 43 and the electrode extension 43a. Accordingly, the first transparent electrode layer 31 allows the current from the second electrode 43 and the electrode extension portion 43a to easily pass therethrough, thereby making it easier to spread the current in the horizontal direction.

儘管結合圖式公開一些示例性實施例,但應理解,這些實施例和隨附圖式僅是為說明而提供並且不應理解為限制本發明的技術。根據以下隨附發明申請專利範圍,本發明的技術的範圍應當解釋為涵蓋從隨附發明申請專利範圍及其等同內容導出的所有變型或變化。 While the invention has been described in connection with the embodiments the embodiments The scope of the technology of the present invention should be construed as covering all modifications or variations derived from the scope of the appended claims and the equivalents thereof.

10‧‧‧基底 10‧‧‧Base

20‧‧‧發光結構 20‧‧‧Lighting structure

21‧‧‧第一導電型半導體層 21‧‧‧First Conductive Semiconductor Layer

23‧‧‧主動層 23‧‧‧Active layer

25‧‧‧第二導電型半導體層 25‧‧‧Second conductive semiconductor layer

30‧‧‧透明電極層 30‧‧‧Transparent electrode layer

41‧‧‧第一電極 41‧‧‧First electrode

43‧‧‧第二電極 43‧‧‧second electrode

G‧‧‧氣隙 G‧‧‧ air gap

Claims (10)

一種發光二極體,包括: 發光結構,其包括第一導電型半導體層,設置在所述第一導電型半導體層上的主動層,以及設置在所述主動層上的第二導電型半導體層; 第一透明電極層,其設置在所述發光結構上以覆蓋所述發光結構的一部分並且具有在所述第一透明電極層中的多個氣隙; 第二透明電極層,其設置在所述第一透明電極層上並且具有形成在所述第二透明電極層中的多個氣隙,形成在所述第二透明電極層中的所述氣隙的數目或者尺寸比形成在所述第一透明電極層中的所述氣隙的數目多或者尺寸大;以及 電極,其設置在對應於所述第一透明電極層的位置的所述第二透明電極層上, 其中所述第一透明電極層具有高於所述第二透明電極層的比電阻。A light emitting diode comprising: a light emitting structure comprising a first conductive type semiconductor layer, an active layer disposed on the first conductive type semiconductor layer, and a second conductive type semiconductor layer disposed on the active layer a first transparent electrode layer disposed on the light emitting structure to cover a portion of the light emitting structure and having a plurality of air gaps in the first transparent electrode layer; a second transparent electrode layer disposed at the On the first transparent electrode layer and having a plurality of air gaps formed in the second transparent electrode layer, the number or size ratio of the air gaps formed in the second transparent electrode layer is formed in the first a plurality of or a large number of the air gaps in a transparent electrode layer; and an electrode disposed on the second transparent electrode layer at a position corresponding to the first transparent electrode layer, wherein the first transparent The electrode layer has a specific resistance higher than that of the second transparent electrode layer. 如申請專利範圍第1項所述的發光二極體,其中所述第一透明電極層或所述第二透明電極層包含ZnO。The light-emitting diode according to claim 1, wherein the first transparent electrode layer or the second transparent electrode layer comprises ZnO. 如申請專利範圍第1項所述的發光二極體,還包括: 隧道接面層,其形成在所述發光結構與所述第一透明電極層之間並且包含NiO、Ga2 O3 和MgO中的至少一種。The light emitting diode according to claim 1, further comprising: a tunnel junction layer formed between the light emitting structure and the first transparent electrode layer and containing NiO, Ga 2 O 3 and MgO At least one of them. 如申請專利範圍第1項所述的發光二極體,其中所述電極部分嵌入所述第二透明電極層中。The light-emitting diode according to claim 1, wherein the electrode portion is embedded in the second transparent electrode layer. 如申請專利範圍第1項所述的發光二極體,還包括: 第三透明電極層,其介於所述第一透明電極層和所述第二透明電極層與所述發光結構之間,並且具有多個氣隙。The light emitting diode according to claim 1, further comprising: a third transparent electrode layer interposed between the first transparent electrode layer and the second transparent electrode layer and the light emitting structure, And has a plurality of air gaps. 如申請專利範圍第5項所述的發光二極體,其中所述第一透明電極層具有高於所述第三透明電極層的比電阻。The light-emitting diode according to claim 5, wherein the first transparent electrode layer has a specific resistance higher than that of the third transparent electrode layer. 如申請專利範圍第1項所述的發光二極體,其中所述第一透明電極層以預定圖案形成在所述發光結構上。The light emitting diode according to claim 1, wherein the first transparent electrode layer is formed on the light emitting structure in a predetermined pattern. 如申請專利範圍第7項所述的發光二極體,其中所述第一透明電極層的所述預定圖案具有選自圓形、六邊形、四邊形和三角形形狀中的至少一種形狀。The light-emitting diode according to claim 7, wherein the predetermined pattern of the first transparent electrode layer has at least one shape selected from the group consisting of a circle, a hexagon, a quadrangle, and a triangle. 如申請專利範圍第7項所述的發光二極體,還包括: 電極延伸部,其從所述電極延伸, 其中所述第一透明電極層的所述圖案對應於所述電極和所述電極延伸部的形狀。The light emitting diode according to claim 7, further comprising: an electrode extension extending from the electrode, wherein the pattern of the first transparent electrode layer corresponds to the electrode and the electrode The shape of the extension. 如申請專利範圍第1項所述的發光二極體,其中,在所述第一透明電極層和所述第二透明電極層中的每一者中,所述氣隙的數目或尺寸從所述發光結構朝向所述電極逐漸增加。The light emitting diode according to claim 1, wherein in each of the first transparent electrode layer and the second transparent electrode layer, the number or size of the air gap is from The light emitting structure gradually increases toward the electrode.
TW104131698A 2014-09-29 2015-09-25 Light-emitting diode including porous transparent electrode TWI591854B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020140130104A KR102264678B1 (en) 2014-09-29 2014-09-29 Light emitting diode comprising porous transparent electrode

Publications (2)

Publication Number Publication Date
TW201624767A TW201624767A (en) 2016-07-01
TWI591854B true TWI591854B (en) 2017-07-11

Family

ID=55630901

Family Applications (1)

Application Number Title Priority Date Filing Date
TW104131698A TWI591854B (en) 2014-09-29 2015-09-25 Light-emitting diode including porous transparent electrode

Country Status (3)

Country Link
KR (1) KR102264678B1 (en)
TW (1) TWI591854B (en)
WO (1) WO2016052929A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11142845B2 (en) * 2018-12-20 2021-10-12 Industrial Technology Research Institute Composite structure and dispersion
US11342484B2 (en) * 2020-05-11 2022-05-24 Silanna UV Technologies Pte Ltd Metal oxide semiconductor-based light emitting device
WO2023084274A1 (en) 2021-11-10 2023-05-19 Silanna UV Technologies Pte Ltd Epitaxial oxide materials, structures, and devices
JP2024544925A (en) 2021-11-10 2024-12-05 シランナ・ユー・ブイ・テクノロジーズ・プライベート・リミテッド Epitaxial oxide materials, structures, and devices

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101014339B1 (en) * 2008-01-10 2011-02-15 고려대학교 산학협력단 Nitride light emitting device having improved luminous efficiency and manufacturing method thereof
KR101004310B1 (en) * 2008-07-25 2010-12-28 고려대학교 산학협력단 Light emitting device with improved light extraction efficiency and manufacturing method thereof
KR101826032B1 (en) * 2011-03-24 2018-02-06 엘지디스플레이 주식회사 Light emitting diode chip and method for fabricating the same
JP6077201B2 (en) 2011-08-11 2017-02-08 昭和電工株式会社 Light emitting diode and manufacturing method thereof
KR102091831B1 (en) * 2013-01-08 2020-03-20 서울반도체 주식회사 Light emitting diode and fabricating method of the same

Also Published As

Publication number Publication date
WO2016052929A1 (en) 2016-04-07
TW201624767A (en) 2016-07-01
KR20160037497A (en) 2016-04-06
KR102264678B1 (en) 2021-06-15

Similar Documents

Publication Publication Date Title
KR101125395B1 (en) Light emitting device and fabrication method thereof
KR101007136B1 (en) Light emitting device, light emitting device package and manufacturing method
KR101712049B1 (en) Light emitting device
EP2242120A1 (en) White light emitting device
KR101034085B1 (en) Light emitting device and manufacturing method
TWI437737B (en) Light-emitting diode structure and manufacturing method thereof
KR102376468B1 (en) Red light emitting device and lighting system
KR101081129B1 (en) Light emitting device and fabrication method thereof
KR20150097322A (en) Nano-sturucture semiconductor light emitting device
TWI591854B (en) Light-emitting diode including porous transparent electrode
KR20130066308A (en) Light emitting device
JP5989318B2 (en) Semiconductor light emitting device and manufacturing method thereof
US20140138729A1 (en) High efficiency light emitting diode
KR102200027B1 (en) Light emitting device and lighting system
KR101166132B1 (en) Light Emitting Diode with the secrificial materials and Its manufacturing method
KR102053415B1 (en) Light emitting device and light emitting device package
US20180287013A1 (en) Light emitting device
KR20110083290A (en) Semiconductor light emitting device and manufacturing method thereof
KR20140036396A (en) Light emitting diode comprising porous transparent electrode and method of fabricating the same
TWI887590B (en) Light-emitting device
KR101134840B1 (en) Light Emitting Device and Method of Manufacturing Thereof
KR100756842B1 (en) Light-emitting diode having light extraction columns and method of manufacturing same
KR102175329B1 (en) Light emitting device and lighting system having the same
KR102303497B1 (en) Light emitting device and method for fabricating the same, and light emitting device package
KR102302855B1 (en) Light emitting device, and lighting system

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees