TWI575125B - Green energy-saving fiber, its preparation method and the fabric made of the fiber - Google Patents

Description

Green energy ring control fiber, its preparation method and fabric made of the fiber

The invention relates to a green energy environmental control fiber, a preparation method thereof and a fabric made of the fiber, and is applied to an organic environment control agricultural industry such as an agricultural plant green energy environmental control greenhouse and a plant green energy environmental control factory, or the like. Environmental control equipment in life such as health care green energy environmental control fabric, indoor air quality green energy environmental control fabric, fume green energy environmental control fabric, geotextile green energy environmental control fabric, defogging green energy control fabric, air clear green It can control environmentally-friendly fabrics and environmental pollution control green energy control fabrics. The use of green energy in the environment, such as solar energy, solar thermal energy, wind energy, hydropower, geothermal energy and other renewable energy sources, the various types of green energy radiation waves in the fiber material receiving environment produce free electron effects, and the interior of the fiber is composed of photoelectric materials. The thermoelectric material and the piezoelectric material have an effect on the natural energy of the green energy radiation wave and act on various kinds of catalyst materials in the fabric fiber, thereby effectively improving various functions of the catalyst material, so that the catalyst fiber and the product are green energy. It produces growth light, water and oxygen anion, far-infrared growth wave, prevention of pests and diseases, and sedimentation decomposition and cleansing of growth environment pollutants.

In response to the increase in food demand and the food crisis caused by the increase in population, humans have tried various farming methods such as genetic modification, chemical pesticides, chemical fertilizers, growth hormones, and microbial fertilizers to increase food production. In order to solve the problem of increasing food demand and the food crisis, the current farming methods are also accompanied by the use of a large number of pesticides, resulting in increasingly serious environmental pollution, and the harsh environment directly causes harm to human health, and in the future, with the climate Changes and new pests and diseases have increased, but crop yields have decreased. Under the vicious cycle of soil acidification, the food crisis has never been lifted. The increase in production and the demand for organic planting have created problems in the agricultural environment and the quality and quantity of crops that need to be solved and overcome. Good natural environment and resources are limited. In order to solve the problem of human food shortage and improve the safety and health of food for the sustainable development of agriculture, human beings should learn the natural circulation principle of the natural environment. We will continue to use the sustainable green energy to maximize the benefits of converting green energy, using material characteristics and natural interaction with green energy, and creating agricultural products with suitable organic environment control in a natural way. The vicious circle caused by farming methods to meet food demand and provide safe food for consumption.

In the prior art, a functional material such as a catalyst is added to the fabric to produce a deodorizing and antibacterial function by the action of the catalyst material. However, one of the conventional techniques is to apply a functional material on the surface of the fabric. Not only does the functional material fail to effectively increase its efficiency, but it does not exert its performance, and it will fall off after a period of use. The economic benefit of this technology. Not high. Other techniques, for example, in U.S. Patent No. 4,784,909, are to add copper to the fiber to have an antibacterial and deodorizing function. For example, in U.S. Patent No. 6,540,807, a thermoplastic plastic resin and an antibacterial agent are added to the fabric to have an antibacterial function. For example, in U.S. Patent No. 5,690,922, the fiber is added with a metal phosphate and a metal hydroxide to have a deodorizing function. However, in the prior art, the functional materials in the fiber can only achieve benefits in an effective space without effective stimulation. Furthermore, although some manufacturers have developed LED lights to emit light that is beneficial to the growth of blue light and red light plants for planting fruits and vegetables, the use of LED lights requires electricity and is expensive, and relatively high cost, not only produces Energy consumption problems, and the inability to control pests and diseases, must still rely on pesticides or biological control or additional installation of mesh isolation pests or nets Closed plastic sheds, glass greenhouses, etc., but still can not effectively achieve the effect of environmental control.

Therefore, in order to achieve effective environmentally-controlled agricultural production and energy-saving control, the inventors believe that it is necessary to make good use of green energy that exists in nature and is endless, and to convert green energy into a suitable crop growing environment. For example, using green energy, making good use of the sunlight in green energy, converting or increasing the sunlight into the light waves needed for plant growth, increasing the yield of organic net crops; receiving the fiber material through the crystal band effect in the fiber material. The effectiveness of the catalytic material in the fiber material after green energy energy not only converts the sunlight and increases the required light, but also reduces the humidity of the air, which is beneficial to plant growth and can prevent plant diseases and remove environmental pollutants. In addition, it can be combined with the use of natural plant essential oils to avoid the insect pests, and thus achieve the purpose of organic cultivation. The above is the concept and research engine of the present invention, and is also an agricultural green energy environmental control material that is worthy of active research and development, and a technology that can achieve true organic agricultural planting production and environmental pollution control, for current organic agricultural environmental control materials and food production energy. Loss and problems such as consumption can be improved.

The first object of the present invention is to provide an environmental control fiber and a fabric thereof which use green energy to increase the growth of organic agricultural plants, and the special material properties of the fiber are controlled by the environment to increase the light wave required for plant growth and to transfer harmful light waves or increase Irradiating the light wave time, decomposing the moisture in the air to make the water molecules fine (water oxygen and anion), can absorb water more effectively, generate far infrared rays to provide plant growth light waves and remove environmental pollutants, thereby promoting sunlight and water in the environment. , air and soil increase the quality and quantity of organic plant production. The technical means is that the fiber is made of a polyolefin-based material, and the photoelectric material (light-storing long-lasting fluorescent phosphorescent material) including a photoelectric effect capable of generating electromagnetic radiation waves is internally mixed, and has a light conversion and light-storing function. A piezoelectric material capable of causing a piezoelectric effect in which a stress field and an electric field are coupled, a thermoelectric material capable of receiving external thermal radiation to generate far infrared rays, and a catalytic material capable of accelerating a chemical reaction rate. When the fiber receives the external green energy such as solar photovoltaic energy, the spectrum required for plant growth (400-700 nm wavelength light) is generated by the action of the photoelectric material (such as the long-lasting fluorescent phosphorescent material), which will be harmful to the plant. It is converted into 400-700 nm wavelength light required for plant growth, and the light storage energy source is used for plant growth at night to promote plant growth. When the fiber receives external green energy such as solar thermal energy or geothermal energy, an infrared energy wave having a growth wavelength of 4 to 14 um is generated in the environment by the action of the thermoelectric material. When the fiber receives the external green energy such as wind energy, the piezoelectric material generates piezoelectricity in the environment, and the hydrodynamic energy of the humidity in the air is decomposed to generate water and oxygen negative ions, so that the rain forest ecology is generated in the environment, and the plant is provided more effectively. Water absorption. The catalytic material generates resonance by photoelectric effect, thermoelectric effect and piezoelectric effect to amplify energy to activate the activity of free electrons, and stimulate the increase of the catalytic activity of the electron hole energy level activity in the material, thereby making the catalytic material more To effectively act to remove environmental contaminant materials.

A second object of the present invention is to provide a green energy ring control fiber and a fabric thereof having the function of removing biological contaminants. The technical means is that the green energy-controlled fiber inside the first object contains a catalytic material capable of removing biological pollutants in the environment. By the arrangement of the catalyst material, the green energy-controlled fiber and the fabric thereof have the functions of inhibiting biological pollution sources in the environment, thereby suppressing environmental pollution sources such as fungi, bacteria and viruses. Efficacy and purpose.

A third object of the present invention is to provide a green energy loop control fiber and a fabric thereof having the function of removing chemical pollutants from the environment. The technical means is that the green energy-controlled fiber inside the first object contains a catalytic material having the function of removing chemical pollutants, and has the environment of removing formaldehyde HCHO, total volatile organic compounds TVOCs, carbon monoxide CO, carbon dioxide CO ₂ , Oxygen O ₃ , acetic acid, acetaldehyde, ammonia, positive and negative ions (F ^- , Cl ^- , NO3 ^- , PO4 ^3- , SO4 ^2- , NH4 ⁺ ) and other chemical pollutants.

A fourth object of the present invention is to provide a green energy loop control fiber having a function of removing physical pollutants from the environment. The technical means is that the fiber inside the first object contains a catalytic material having a physical pollution source in a sedimentation environment, and has a physical activity source of air in a sedimentation environment to the ground, such as pollen, PM _2.5 , PM ₁₀ and the like.

A fifth object of the present invention is to provide a green energy ring-controlled fiber having fentanyl insect-repellent. The technical means is that the fiber of the first four items mentioned above contains a natural plant essential oil with anti-insect effect, and the material contains the effect of avoiding insects to achieve the effect of controlling insects, and can produce fentanyl for plant growth. .

A sixth object of the present invention is to provide a safe green energy ring-controlled fiber having a flame-resistant and conductive antistatic function. The technical means is that the fibers in the above five items increase the material containing the fireproof material and the conductive antistatic conductive function, so that the fiber has a safety function.

10‧‧‧Fiber

11‧‧ ‧ ribs

12‧‧‧ dent

20‧‧‧ fabric

30‧‧‧Photoelectric materials

31‧‧‧Piezoelectric materials

32‧‧‧ thermoelectric materials

33‧‧‧catalyst materials

BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic illustration of a first embodiment of the process of the present invention.

Figure 2 is a schematic illustration of a second embodiment of the process of the present invention.

Figure 3 is a schematic illustration of a third embodiment of the process of the present invention.

Fig. 4 is a schematic sectional view showing the structure of the fiber produced by the present invention.

Fig. 5 is a schematic view showing the fiber woven into an agricultural net made by the present invention and its use.

The green energy ring-controlled fiber developed by the invention generates energy conduction capability when the fiber receives external green energy, generates photoelectricity by photoelectric material, generates piezoelectricity by piezoelectric material and generates thermoelectric material (far infrared material). The wave-wave resonance activates the excitation material by the energy-increasing excitation, which increases the energy catalysis of the electron-cavity energy level, can effectively improve the pollutant efficiency in the catalytic catalyst environment, and generate light of 400-700 nm wavelength (such as wavelength 4~) The 14 μm far infrared ray and the decomposition of moisture (humidity) in the air produce water oxygen anions. Therefore, the fiber-woven fabric 20 of the present invention has a resonance friction-increasing effect and can produce an environmental control function, and the fabric 20 can be used as an organic agricultural green energy-controlled fabric or a plant grating green energy-controlled fabric to assist in cultivating plants. Please refer to Figure 5 for cooperation. The fabric made of the fiber of the invention can be further applied to the health care green energy environment control fabric, the indoor air quality green energy environment control fabric (such as the air conditioner green energy ring control network), the soot equipment green energy environment control fabric (such as removing the oil smoke green energy) Environmental control network), geophysical green-green environmental control fabrics (such as geophysical planting nets planted under the soil and planted on the soil), defogging green energy-controlled fabrics (such as washing tower defogging green energy ring control network) ), air clean green energy ring control fabric (such as air cleaner green energy ring control network), screen window green energy ring control fabric (such as screen window ventilation green energy ring control network) and environmental pollution control green energy environmental control fabric (such as washing The equipment removes industrial equipment such as TVOCS, positive and negative ions). The basic feature of the technology is that the fibers of the present invention are made of a polyolefine (such as polypropylene and polyethylene, and hydrocarbons are selected to reduce environmentally harmful materials), photovoltaic materials, piezoelectric materials, thermoelectric materials, and touches. The medium material is processed into a processing material by twin-screw air-cooling granulation, melt-kneading, and the processed material is made into a fiber by a melt-spinning processing technique. The fabric woven into the fiber receives natural energy such as external sunlight, air flow, heat energy, fiber vibration friction, air humidity, etc., and photoelectricity of the photoelectric material, piezoelectric effect of the piezoelectric material, and thermoelectric effect of the thermoelectric material ( Far infrared ray). The thermoelectric effect, the piezoelectric effect, the photocatalytic effect, the redox effect, the free electron effect, the catalytic effect and the slow release effect act on the catalytic material to increase the natural energy, so that the catalytic material can fully exert its performance. The weight ratio of each material can be adjusted according to the needs of the user. The main concept of the invention is to integrate the photoelectric material, the piezoelectric material, the thermoelectric material and the catalytic material into the fiber, so that the fiber touches the natural energy. The media material can produce radiation-increasing effects. First, the environment generates infrared rays with a wavelength range of 4 to 14 um and decomposes moisture (humidity) in the air to generate water and oxygen anions. Secondly, the light effect is increased to increase plant growth and limit the wavelength of sunlight at wavelengths of 400-700 nm and increase the nighttime brightness of long afterglow. The third is to reduce the plant diseases caused by the suppression of biological pollution sources such as total bacteria and mold in the air. Fourth achieve the removal of chemicals in the air pollution (e.g. air vaporous contaminants _{HCHO, TVOCs, O 3, CO} , CO 2, SO X, NO X, C X H Y, HCL, CS 2, CFC S, C m H _n X _{x ,} etc.) to reduce chemical pollution, or to achieve the function of sedimentation physical pollution such as airborne particulate pollen, PM _2.5 , PM ₁₀ and other suspended particles. The fifth achieves the effect of avoiding insects and protects plants from pest damage and infectious diseases. Sixth, it achieves safe green energy-controlled fiber with flameproof, antistatic and conductive functions. The green energy environmental control fiber green energy ring control fiber of the invention has excellent effect, and can be used for weaving the fabric to be applied to the agricultural green energy environmental control greenhouse room, the plant grating green energy ring control fabric, etc. and can be applied to All kinds of environmental green energy environmental control fabric equipment such as health care green energy environmental control fabric, indoor air quality green energy environmental control fabric, fume green energy control fabric, defogging green energy control fabric, geotextile green energy environmental control fabric Air clean green energy-controlled fabrics, screens green energy-controlled fabrics and environmental pollution control green energy environmental control fabrics, etc., for agricultural, industrial, fishing, animal husbandry and the people's livelihood.

The invention produces a green energy ring-controlled fiber, and the photoelectric effect of the photoelectric material used is that electromagnetic radiation wave (such as ultraviolet light) is irradiated to the material, and photon absorption excites the free electron effect, mainly for accumulating long-lasting fluorescent phosphorescent material to generate photoelectric The material has a light conversion light storage function; basically Zn ₂ SiO ₄ , CaSiO ₃ , SiO ₂ , TiO _{2 ,} (SrBaMg) ₃ Si ₂ O ₇ , CaWO ₄ , MgWO ₄ , LiAl ⁵ O ⁸ : Mn ⁴⁺ , CaAl ₂ O ₄ :Eu ²⁺ , Dy ³⁺ , CaAl ₁₂ O ₁₉ :Mn ⁴⁺ , SrAl ₂ O ₄ :Eu ²⁺ , Dy ³⁺ , Sr ₄ Al ₁₄ O ₂₅ :Eu ²⁺ , Dy ³⁺ , SrAl ₁₂ O ₁₉ :Eu ²⁺ , Dy ³⁺ , BaMg ₂ Al ₁₆ O ₂₇ , CeMgAl ₁₁ O ₁₉ , MgAl ₂ O ₄ , GdAlO ₃ , Y ₂ O ₃ , YVO ₄ , SrB ₄ O ₇ F, MgGa ₂ O ₄ , MgGa ₂ O ₄ , BeO, MgO, Al ₂ O ₃ , MgAl ₂ O ₄ , GeO ₂ SnO ₂ ZnO, Sc ₂ O ₃ , La ₂ O ₃ , Sm ₂ O ₃ , Gd ₂ O ₃ , Dy ₂ O ₃ , ZrO ₂ , CdS and WO _3, etc.

The invention produces a green energy ring-controlled fiber, and the piezoelectric effect of the piezoelectric material used is due to a special arrangement between atoms in the crystal lattice, and a coupling effect between the stress field and the electric field. Piezoelectric materials are basically quartz, cadmium sulfide, zinc oxide, aluminum nitride, ferroelectric crystal, barium titanate crystal, lithium niobate, barium strontium citrate, barium strontium silicate crystal, potassium dihydrogen phosphate, ammonium dihydrogen phosphate , lead hydrogen phosphate, lead strontium phosphate crystal, barium titanate crystal, barium titanate ceramic, lead zirconate titanate PZT and the like.

The invention produces a green energy ring-controlled fiber, and the thermoelectric material used is a far-infrared material that receives external thermal radiation to generate far-infrared rays having a wavelength of 4-14 μm on the spectrum, and the wavelength is greater than the wavelength of visible light, and is a kind of strong heat effect. Thermal induction" can. The thermoelectric material composition is substantially Al ₂ O ₃ , ZrO ₂ , MgO, TiO ₂ , SiO ₂ , ZrC, SiC, B ₄ C, TaC, TiB ₂ , ZrB ₂ , CrB ₂ , TiSi ₂ , MoSi ₂ , WSi ₂ , Si ₃ N ₄ , TiN, Fe ₂ O, high temperature bamboo charcoal, preparation of charcoal, medical stone, Guiyang stone, volcanic rock, jade.

The invention produces a green energy ring-controlled fiber, and the catalyst material used is a catalyst, which can accelerate the chemical reaction rate by providing another reaction energy with lower activation energy, and the quality, composition and chemical properties of itself participate in the chemical A substance that remains unchanged before and after the reaction. The catalytic material components are mainly catalytic metals such as gold, platinum, palladium, rhodium, silver, iron, copper, titanium, nickel, tungsten, zinc, manganese, lanthanum, cerium, lanthanum, cerium, lanthanum, molybdenum, chromium, cerium,铈, 鐠, 钕, 鉕, carbon nanotubes, etc. and oxidizing metal catalysts such as cerium oxide, zinc oxide, cerium oxide, titanium oxide, aluminum oxide, iron oxide, palladium oxide, magnesium oxide, zirconium oxide, nickel oxide, oxidation Tin, manganese oxide, chromium oxide, cerium oxide, cerium oxide, cerium oxide, and the like.

The invention produces green energy ring control fiber, and the natural plant essential oil used is tea tree oil, bitter oil, lemon oil, wintergreen oil, eucalyptus oil, clove oil, peppermint oil, eucalyptus oil, citronella oil, pheasant pepper oil, Sage oil, eucalyptus oil, rose oil, jasmine oil, geranium oil, rose geranium oil, ylang-ylang oil, mastic oil, hoarfrost oil, rosemary oil, permanent flower oil, thyme oil, pine oil, cedar oil , Juniper oil, sandalwood oil, basil oil, lime oil, orange oil, orange oil, bitter orange oil, bitter orange leaf oil, neroli oil, foreign citrus oil, pheasant pepper oil, myrrh oil, cattle Knee grass oil, white layer oil, ginger oil, etc.

The invention discloses a green energy ring-controlling fiber, and the fire-retardant fireproofing materials used are antimony trioxide, magnesium hydroxide, red phosphorus, molybdenum compound, zinc borate, zinc stannate, decabromodiphenyl ether, octabromoether, organic antimony. , carbon black and so on.

The invention produces green energy ring control fibers, and the conductive antistatic materials used are polyethers, quaternary ammonium salts, sulfonates, betaines, conductive carbon black, carbon fibers, metal fibers, nickel-plated metal carbon fibers, and nanometers. Carbon tube.

The basic characteristics of the green energy ring-control fiber green energy ring-controlled fiber of the invention: using polyolefine (Polyolefine), photoelectric material, piezoelectric material, thermoelectric material and catalytic material, depending on the ratio of each material and the structural strength requirement A rubber elastic material (such as Ethylene-Propylene-Diene Monomer (EPDM)) is added, and the materials are melted and kneaded together to form a polyolefin functional material, and then the granular polyene functionality is added. The material is melt-spun and made into fibers having a Danny number of 50 to 50000 den. Wherein, the first polyolefin may be polypropylene (melt flow rate (MFR) ranging from 0.1 to 50 g/10 min, or the first polyolefin may be polyethylene (melt flow rate (Melt flow) The rate, MFR) ranges from 0.1 to 50 g/10 min. The characteristics of the photoelectric material are light storage (3000-0.32 mcd/m ² ) particle size distribution: 10 to 0.1 μm; the characteristics of the piezoelectric material are: piezoelectric coefficient (10 ^{- 12} C/N) 0.1~1000, particle size distribution: 10~0.1μm. The characteristics of thermoelectric materials are: the emissivity of far infrared rays in the wavelength range of 4~14um is 0.85~0.99%, the particle size distribution is 10~0.1μm, three Ethylene propylene acrylate (EPDM) (with Mooney viscosity (ML1+4, 125 ° C) 20-70). As shown in FIG. 4, in a preferred embodiment, at least two ribs 11 are integrally formed on the surface of the fiber 10. The length of the rib 11 extends along the axial direction of the fiber, and the top of the rib 11 extends in a curve when viewed from a cross section of the fiber. In the example of FIG. 4, there is a concave 12 between the two ribs 11 when The fiber receives external sunlight, and the interaction of the photovoltaic material 30, the piezoelectric material 31, the thermoelectric material 32, and the catalytic material 33 in the fiber converts sunlight into color light required for plant growth, via The curvature of the ridges 11 is scattered and irradiated to the plants to promote plant growth.

Referring to FIG. 1 together, the basic feature of the method for producing the green energy-controlled fiber of the present invention to achieve the above first to fourth objects is mainly to prepare 70% to 95% by weight of the poly-thick material such as poly. Propylene fragments or polyethylene chips (Melt flow rate (MFR) ranging from 0.1 to 50 g/10 min) (the following corresponding experimental examples of the present invention have a melt flow rate of 5 g/10 min and account for 70% or 80%) % by weight of polypropylene as an example), 1% to 10% by weight of optoelectronic material (the following experimental examples of the present invention are 10% by weight of photoelectric material, particle size distribution: 0.3 μm, for example ), 1% to 5% by weight of piezoelectric material (the following experimental examples of the present invention are 2% by weight of piezoelectric material, particle size distribution: 1 μm, for example), 1% to 5% by weight The thermoelectric material (the following experimental examples of the present invention are 2% by weight of the thermoelectric material, the particle size distribution: 1 μm, for example) and 1% to 5% by weight of the catalyst material (the following experiments of the present invention) For example, the catalyst material accounts for 3% by weight, and the particle size distribution: 0.3 μm, for example, Depending on fiber ductility, strength and hardness, it is necessary to choose whether to add rubber elastic material (such as Ethylene-Propylene-Diene Monomer (EPDM) 1% to 5% by weight (the following experimental examples of the present invention are EPDM) Taking 3% by weight (Mooney viscosity 60) as an example). The above materials are mixed and granulated by air-cooled twin-screw mixing. When the medium polypropylene is used as the substrate, the granulation temperature is increased from 160 ° C to 250 ° C; when the polyethylene is used as the substrate, the granulation temperature is 260 ° C to 350 ° C. Further, a plurality of granular base materials (the average particle diameter of the granular base material is less than 2-10 mm) are prepared, and the plurality of granular base materials are passed through a single screw extruder to spin, cool, and thermally extend the processed material. Heated and shaped into fibers. Among them, when polypropylene is used as the substrate, the spinning temperature is increased from 160 ° C to 250 ° C; when polyethylene is used as the substrate, the spinning temperature is 260 ° C to 350 ° C. The subsequent cooling temperature is -20 to 50 ° C, the draw ratio is 3 to 8 times, the hot water extension temperature is 80 to 120 ° C, and the take-up speed is 40 to 180 rpm. In the specific operation example of the present invention, polypropylene is used as a substrate, and the granulation processing temperature is 180 ° C / 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C, and the fiber spinning temperature is 200 ° C / 210 ° C / 220 °C/230°C/240°C/250°C, cooling temperature 25°C, hot water extension temperature 100°C, draw ratio 6 times, coiling speed 120 rpm. The melt-spinning is to heat and melt the processed material, and the molten material is extruded from the spinning hole into the cooling water, cooled in the cooling water, and taken up at a constant speed, and then hot-rolled at a multiple speed of hot water to take up the coil. At this stage, the melted material of the processed material is solidified to form fibers, and the fibers are wound. In the melt spinning process, the spinnable polymer obtained in the polymerization step is extruded from the pores of the spinneret at a temperature higher than the melting point, cooled and refined into a filamentous solid, and simultaneously wound.

Please refer to FIG. 2, the basic characteristics of the method for producing the green energy ring control fiber of the present invention to achieve the green energy control fiber containing the insect-repellent effect of the fifth item, mainly preparing 65% to 94% by weight. Percentage of polyene-based materials (the experimental examples corresponding to the following examples of the present invention are based on a melt flow rate of 5 g/10 min and accounting for 80% by weight of polypropylene), and secondly, a photovoltaic material is prepared in an amount of 1 to 5% by weight. Percentage, piezoelectric material 1~5% weight percentage, thermoelectric material 1~5% weight percentage, catalyst material 1~5% weight percentage and apparent fiber ductility, strength and hardness need to choose whether to add rubber elastic material 1~5% The weight percentage accounts for 5% to 25% by weight (in the experimental example of the present invention, the photoelectric material accounts for 2% by weight, and the particle size distribution: 0.3μm; piezoelectric material accounts for 2% by weight, particle size distribution: 1μm; thermoelectric material accounts for 2% by weight, particle size distribution: 1μm; catalytic material accounts for 3% by weight, particle size distribution: 0.3μm, rubber elasticity Materials (such as Ethylene-Propylene-Diene Monomer (EPDM) accounted for 3% by weight (the Mooney viscosity of 60). Photoelectric materials, piezoelectric materials, thermoelectric materials, catalytic materials and EPDM accounted for 12 % by weight, for the purpose of illustration), natural plant essential oil 1~10% (the following tests in the present invention are based on 8% by weight of natural plant essential oils as an example).

Please refer to FIG. 3, the basic characteristics of the method for manufacturing the safe green energy ring control fiber to achieve the foregoing sixth object (safe green energy ring control fiber with flameproof and conductive antistatic function), mainly preparing 55%. ~92% by weight of the polyolefin material (the experimental examples corresponding to the following examples of the present invention are based on a melt flow rate of 5 g/10 min and 70% by weight of polypropylene). Secondly, prepare 1~5% by weight of photoelectric material, 1~5% by weight of piezoelectric material, 1~5% by weight of thermoelectric material, 1~5% by weight of catalyst material, and consider fiber ductility, strength and hardness. It is necessary to select whether to add rubber elastic material 1 to 5% by weight of 5% to 25% by weight (in the experimental example of the present invention, 2% by weight of the photoelectric material, particle size distribution: 0.3 μm; piezoelectric material 2%) Weight percentage, particle size distribution: 1 μm; thermoelectric material 2% by weight, particle size distribution: 1 μm; catalytic material accounted for 3% by weight, particle size distribution: 0.3 μm, rubber elastic material (such as ethylene propylene diene monomer (Ethylene) -Propylene-Diene Monomer, EPDM) accounts for 3% by weight (its Mooney viscosity is 60). Photoelectric materials, piezoelectric materials, thermoelectric materials, catalytic materials and rubber elastic materials (EPDM) account for 12% by weight. Make a description) and prepare natural plant essential oils 1 to 5% by weight (the following test in the present invention is based on 3% by weight of natural plant essential oils as an example). Prepare fireproof materials 1 to 10% by weight, particle size distribution :10~0.1μm (below the present invention) The corresponding experimental examples are in case 10% by weight of the fire material is used as an example). The conductive antistatic material is prepared in an amount of 1 to 5% by weight, and the particle size distribution thereof is 10 to 0.1 μm (the experimental examples corresponding to the following items of the present invention are exemplified by a conductive antistatic material of 5% by weight).

In the first experimental example of the present invention, 80% by weight of polypropylene (melt flow rate 5 g/10 min) and 10% by weight of photovoltaic material (Sr ₄ Al ₁₄ O ₂₅ :Eu ²⁺ , Dy ³⁺ ) powder are taken ( 2 μg of piezoelectric material (barium titanate ceramic) powder (particle size 1 μm), 2% by weight of thermoelectric material (containing alumina Al ₂ O ₃ 35.92%, magnesium oxide MgO 33.86%) Iron oxide Fe ₂ O 16.10%, titanium dioxide TiO ₂ 12.26% and cerium oxide SiO2 2.86% oxide) powder (particle size 1 μm), 3% by weight of catalyst material (gold 30% / titanium oxide 30% / Zinc oxide 40%) powder (particle size 0.3 μm), and EPDM accounted for 3% by weight (its Mooney viscosity 60). The above materials were granulated by twin-screw air-cooling granulation (granulation temperature: 180 ° C / 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C) to make a plurality of granular base materials as a kneading material (average The particle size is about 5mm), and the processing material of the granular base material is 200°C/210°C/220°C/230°C/240°C/250°C at a single screw mixing temperature, and then the melt processed material is subjected to spinning and cooling. The fibers were formed by ° C, hot stretching at 100 ° C, and winding at 120 rpm. The test results of the present invention are as follows.

For the tensile strength and tear strength test results of Experimental Example 1, please refer to Table 1: As the photoelectric material, piezoelectric material, thermoelectric material, catalytic material and EPDM content are more, the tensile strength will gradually decrease. However, the required strength is still maintained. Therefore, the photoelectric material, the piezoelectric material, the thermoelectric material, the catalytic material and the EPDM added by the present invention account for 20-30% of the total weight (the example of Table 1 adds 20% for explanation) . The light storage effect (Sr ₄ Al ₁₄ O ₂₅ :Eu ²⁺ , Dy ³⁺ blue-green light 488 nm) has a benefit of 956 minutes. The wavelength of 400~520nm increased the development of plant roots and stems, and absorbed the most chlorophyll and carotenoids, and had the greatest impact on photosynthesis. The 610-720 nm wavelength promotes photosynthesis and plant growth rate (CaAl ₁₂ O ₁₉ : Mn ^{4 +} red light 656 nm).

For the far-infrared emissivity test results of Experimental Example 1, please refer to Table 2: In the far-infrared emissivity test, the average emissivity of the far-infrared rays at 50 °C of 3-15 μm is 0.968. The average emissivity of far-infrared rays of 3-15 μm is 0.918 at 5 °C.

The results of the far infrared ray experiment of Experimental Example 1 are shown in Table 3; the far-infrared human physiological experiment of the fiber woven fabric of the present invention; the temperature was raised by 2.9 ° C after 30 minutes on the health care fabric.

The results of the negative ion experiment of Experimental Example 1 are shown in Table 4: the fiber woven fabric of the present invention was tested; under dynamic friction, 2858 negative ions (pieces/cc) in the air were added.

For the test results of the washing fastness test in the first example, please refer to Table 5: Washing fastness test, the good fastness is maintained before and after the test, and the amount of negative ions is not reduced by washing. less.

For the test results of the total volatile organic matter removal in the air in Experimental Example 1, please refer to Table 6.

See Table 7 for the results of Indoor Air Quality (Contaminant Removal Test) in Experimental Example 1. See Table 7-1 for test instruments.

For the test efficiency results of positive and negative ion contaminant removal in the air in Experimental Example 1, please refer to Table 8.

The antibacterial test results of Experimental Example 1 were 99.9% inhibition rate (R%), as shown in Table 9.

The anti-mildew test results of Experimental Example 1 (0: no mold), please refer to Table 10.

In the second experimental example of the present invention, 80% by weight of polypropylene (melt flow rate: 5 g/10 min) and 2% by weight of photovoltaic material (Sr ₄ Al ₁₄ O ₂₅ :Eu ²⁺ , Dy ³⁺ ) powder are taken ( 2 μg of piezoelectric material (barium titanate ceramic) powder (average particle size 1 μm), 2% by weight of thermoelectric material (containing alumina Al ₂ O ₃ 35.92%, magnesium oxide MgO) 33.86%, iron oxide Fe ₂ O 16.10%, titanium dioxide TiO ₂ 12.26% and cerium oxide SiO ₂ 2.86% by weight oxides) powder (average particle size 1 μm), 3% by weight of catalyst material (gold 30%) / titanium oxide 30% / zinc oxide 40% by weight) powder (average particle size 0.3 μm), EPDM accounted for 3% by weight (Mooney viscosity 60) and 8% by weight of plant essential oil material (eucalyptus 20%, 30% of lemon and 50% of tea tree oil), all of the above materials are cooled and granulated by twin-screw mixing air (granulation temperature is 180 ° C / 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C) to make a plurality of A particulate base material (having an average particle diameter of about 5 mm) is used as a processing material. The processed material is then melted by single screw (mixing temperature is 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C / 250 ° C) to form a melt processed material, and then the melt processed material is subjected to spinning, cooling at 25 ° C, 100 The fiber was thermally expanded and wound at 120 rpm to form a fiber.

For the physical properties of the fabric of Experimental Example 2, please refer to Table 11:

In the second experiment example, the repellent test result repellent rate (90.3%), please refer to Table 12:

The test results of the essential oil component-gas chromatography mass spectrometer (GC/MS) of Experimental Example 2 are shown in Table 13. The tested product is placed in a 1 cubic meter sealed test box, and the tested product is turned on for 1 hour. The essential oil components of this product are shown in Table 13. Test method: connected by gas chromatography mass spectrometry (GC/MS).

For the results of the analysis of the amount of pollutants removed in the air in Experimental Example 2, please refer to Table 14 for the test in a 1 m ³ closed space; the removal of contaminants per minute in a 1 m ² sample at 6.5 CMM.

In the third experimental example of the present invention, 70% by weight of polypropylene (melt flow rate: 5 g/10 min) and 2% by weight of photovoltaic material (Sr ₄ Al ₁₄ O ₂₅ :Eu ²⁺ , Dy ³⁺ ) powder were taken ( 2 μg of piezoelectric material (barium titanate ceramic) powder (average particle size 1 μm), 2% by weight of thermoelectric material (containing alumina Al ₂ O ₃ 35.92%, magnesium oxide MgO) 33.86%, iron oxide Fe ₂ O 16.10%, titanium dioxide TiO ₂ 12.26% and cerium oxide SiO ₂ 2.86% oxide), 3% by weight of catalyst material (gold 30% / titanium oxide 30% / zinc oxide 40 %) powder (average particle size 0.3 μm), EPDM 3% by weight (Mooney viscosity 60), 3% by weight of plant essential oil material (eucalyptus 20%, lemon 30% and tea tree essential oil 50% by weight) 10% by weight of fireproof material (magnesium hydroxide 90% and antimony trioxide 10% by weight, particle size 0.5 μm) and 5% by weight of conductive antistatic material (conductive carbon black, particle size 0.2 μm), All the above materials are granulated by twin-screw air-cooling granulation (granulation temperature: 180 ° C / 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C) to produce a plurality of granular base materials ( Average particle diameter of about 5mm) as the work material. The processed material is then melted by single screw (mixing temperature is 200 ° C / 210 ° C / 220 ° C / 230 ° C / 240 ° C / 250 ° C) to form a melt processed material, and then the melt processed material is subjected to spinning, cooling at 25 ° C, 100 The fiber was thermally expanded and wound at 120 rpm to form a fiber.

Test Example 3 toxic gas content test results: in line with the regulations. For toxic gas content, please refer to Table 15: The Toxic Gas value in this report refers to the toxic gas content produced by the combustion test for 4 minutes. ABD0031 (2005) ISSUE: F requirements: Detection tube measurement HF <100, HCL < 150, HCN < 150, SO ₂ <100, XO ₂ <100, CO <1000.

Experimental Example 3 Horizontal Burning Test Results Test Results: Compliance. Please refer to Table 16. FAR 25.853(b) (Amdt. 25-116, 2004) & Appendix F Par I(a)(1)(ii). Flame Time: ≦15Sec; Drip Flame Time: ≦5Sec; Burn Length: ≦8in (203.2mm).

Experimental Example 3 Vertical Burning Test Results Test Results: Compliance. Please refer to Table 17. FAR 25.853 appendix Appendix F Amdt. 25-111. Te(10)=te(11.5)-te(1.5).

Test sample smoke concentration test results: in accordance with the regulations. Please refer to Table 18: D _m is the maximum value of the measured smoke concentration within 4 minutes of the test time of the test sample. ABD0031 (2005) Issue: F specification requires that, under flaming or flameless test conditions, the maximum smoke concentration within 4 minutes of the test time should not exceed the specifications listed in Table 19.

Conductive antistatic test results of Experimental Example 3: R = 5.8 x 10 ⁵ Ω, see Table 20.

The above is only one of the possible embodiments of the present invention, and is not intended to limit the scope of the patents of the present invention, and the equivalent implementations of other changes according to the contents, features and spirits of the following claims are It should be included in the scope of the patent of the present invention. The invention is specifically defined in the structural features of the request item, is not found in the same kind of articles, and has practicality and progress, has met the requirements for the creation of patents, and has filed an application according to law, and requests the bureau to approve the patent according to law to maintain the present. The legal rights of the applicant.

10‧‧‧Fiber

20‧‧‧ fabric

Claims (10)

The invention discloses a method for preparing a green energy ring-controlled fiber, which is a polyene material which comprises 50% to 94% by weight as a substrate, and 1% to 10% by weight of a photoelectric material capable of generating a photoelectric effect of electromagnetic radiation waves, 1% to 5% by weight of a piezoelectric material capable of causing a piezoelectric effect in which a stress field and an electric field are coupled, and 1% to 5% by weight of a thermoelectric material capable of receiving external thermal radiation to generate far infrared rays, 1% to 5% by weight of the elastomer material and 1% to 5% by weight of the catalyst material which can accelerate the chemical reaction rate is a formula material, and the formula material is mixed to have a granulation temperature of 160 ° C~ The air-cooled granulation technique at 350 ° C melt-kneading to form a plurality of granular base materials, and then the plurality of granular base materials are made into fibers by a melt spinning technique. The method of claim 1, wherein the polyolefin material has a melt flow rate ranging from 0.1 to 50 g/10 min. The method according to claim 1, wherein the formula further comprises 1 to 10% by weight of a natural plant essential oil having an anti-insect effect; the polyene material has a melt flow rate ranging from 0.1 to 50 g/10 min. The method according to claim 1, wherein the formula further comprises 1 to 5% by weight of a natural plant essential oil having an anti-insect effect, and 1 to 10% by weight of the fireproof material and 1 to 5 % by weight of conductive antistatic material. The method of claim 4, wherein the fireproofing material is selected from the group consisting of magnesium hydroxide, antimony trioxide, red phosphorus, molybdenum compound, zinc borate, zinc stannate, decabromodiphenyl ether, octabromo ether, organic At least one of tantalum and carbon black; the conductive antistatic material is selected from the group consisting of conductive carbon black, polyether, quaternary ammonium salt, sulfonate, betaine, carbon fiber, metal fiber, nickel-plated metal carbon fiber and nano carbon At least one of the tubes. The method of any one of claims 1 to 5, wherein the polyolefin material is one selected from the group consisting of polypropylene and polyethylene; and the photovoltaic material is selected from the group consisting of (SrBaMg) ₃ Si ₂ O ₇ and LiAl ⁵ O ⁸ : Mn ⁴⁺ , CaAl ₂ O ₄ :Eu ²⁺ , Dy ³⁺ , CaAl ₁₂ O ₁₉ :Mn ⁴⁺ , SrAl ₂ O ₄ :Eu ²⁺ , Dy ³⁺ , Sr ₄ Al ₁₄ O ₂₅ :Eu ^{1 +} , Dy ³⁺ , SrAl ₁₂ O ₁₉ :Eu ²⁺ , Dy ³⁺ , BaMg ₂ Al ₁₆ O ₂₇ , CeMgAl ₁₁ O ₁₉ , MgAl ₂ O ₄ , GdAlO ₃ , SrB ₄ O ₇ F, MgGa ₂ O ₄ , At least one of the piezoelectric materials is selected from the group consisting of quartz, cadmium sulfide, zinc oxide, aluminum nitride, ferroelectric crystal, barium titanate crystal, lithium niobate, barium strontium citrate, barium strontium citrate crystal, lead strontium phosphate crystal At least one of barium titanate crystal, barium titanate ceramic and lead zirconate titanate; the thermoelectric material is selected from the group consisting of Al ₂ O ₃ , ZrO ₂ , MgO, TiO ₂ , SiO ₂ , ZrC, SiC, B ₄ C, TaC At least one of TiB ₂ , ZrB ₂ , CrB ₂ , TiSi ₂ , MoSi ₂ , WSi ₂ , Si ₃ N ₄ , Fe ₂ O, high temperature bamboo charcoal, prepared charcoal, medical stone, Guiyang stone, volcanic rock and jade; The material is selected from the group consisting of gold, platinum, palladium, rhodium, and silver. Iron, copper, titanium, nickel, tungsten, zinc, manganese, lanthanum, cerium, lanthanum, iron, lanthanum, molybdenum, chromium, lanthanum, cerium, lanthanum, cerium, lanthanum, carbon nanotubes, cerium oxide, zinc oxide, oxidation At least one of cerium, titanium oxide, aluminum oxide, iron oxide, palladium oxide, magnesium oxide, zirconium oxide, nickel oxide, tin oxide, manganese oxide, chromium oxide, cerium oxide, cerium oxide and cerium oxide. A green energy-controlled fiber according to the method of claim 1, wherein the fiber is based on the polyolefin material, and the photoelectric material, the piezoelectric material, and the ceramic material are mixed therein. a thermoelectric material, the elastomer material, and the catalyst material; when the fiber receives external energy, the photoelectric effect is generated by the photoelectric material, the piezoelectric material generates a piezoelectric effect, and the thermoelectric material generates a wave radiation resonance energy The radiation is activated to activate the catalyst material to enhance the performance of the catalyst material. The fiber according to claim 7, wherein the fiber has a Danny number of 50 to 50000 den. The fiber of claim 7, wherein the fiber surface is integrally formed with at least two ribs extending along an axial direction of the fiber and viewed from a cross section of the fiber, the ridge top Extends in a curve. A fabric made of green energy-controlled fiber, which is a fabric made of the green energy-controlled fiber according to claim 7, which comprises a plurality of mutually woven fibers extending in the warp direction and a plurality of strips The fiber extending in the weft direction, the fabric is selected from the group consisting of an agricultural plant green energy environmental control greenhouse and a plant green energy environmental control factory, a plant grating green energy environmental control fabric, or the like, or applied to various environmental control in life. Equipment such as health care green energy environmental control fabrics, indoor air quality green energy environmental control fabrics, fume green energy control fabrics, geophysical green energy environmental control fabrics, defogging green energy environmental control fabrics, air clean green energy control fabrics One of the green energy environmental control fabrics for environmental pollution prevention.