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TWI569987B - A method of forming a layer on a composite surface - Google Patents

A method of forming a layer on a composite surface Download PDF

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Publication number
TWI569987B
TWI569987B TW100136935A TW100136935A TWI569987B TW I569987 B TWI569987 B TW I569987B TW 100136935 A TW100136935 A TW 100136935A TW 100136935 A TW100136935 A TW 100136935A TW I569987 B TWI569987 B TW I569987B
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Taiwan
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layer
forming
composite material
substrate
material according
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TW100136935A
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Chinese (zh)
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TW201315617A (en
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Sheng-Chong Li
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Sheng-Chong Li
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Priority to TW100136935A priority Critical patent/TWI569987B/en
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Publication of TWI569987B publication Critical patent/TWI569987B/en

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Description

複合材料表面形成圖層之方法Method of forming a layer on a composite surface

本發明係與一種複合材料之製造方法有關,特別是指一種於複合材料表面形成圖層之方法。The present invention relates to a method of manufacturing a composite material, and more particularly to a method of forming a layer on the surface of a composite material.

按,複合材料因為具有質輕、機械強度高以及耐腐蝕等特性,因此被廣泛的應用在各種產業製品,如造船、球拍、筆電外殼、手機外殼及自行車架等,且為了提升該複合材料之美觀性,通常該複合材料的表面更會利用噴塗的方式成型有一圖層,並於該圖層之外側再噴塗一層透明漆以保護該圖層不受破壞。According to the characteristics of light weight, high mechanical strength and corrosion resistance, composite materials are widely used in various industrial products, such as shipbuilding, racket, notebook case, mobile phone case and bicycle frame, etc., and in order to enhance the composite material. The appearance of the composite material is usually formed by spraying a layer, and a layer of transparent paint is sprayed on the outside of the layer to protect the layer from damage.

惟,因為該複合材料係由一編織纖維布灌注樹脂所構成,所以該複合材料之表面會因纖維束互相交疊而佈滿編織孔,導致該複合材料在噴塗該圖層之前,必須先經過補土整平以及底色塗裝等步驟,才能有效的將該圖層噴塗於該複合材料上,同時為了讓該透明漆之表面較為光滑,該透明漆還必須使用研磨劑進行表面打磨拋光,使得該複合材料之整體製程不僅費時費力,且非常耗能與不環保,故,如何研發一種不用經過補土整平、底色塗裝及打磨拋光,即可直接於該複合材料表面形成該圖層之方法,實有必要。However, since the composite material is composed of a woven fiber cloth impregnated resin, the surface of the composite material is covered with the woven holes due to the overlapping of the fiber bundles, so that the composite material must be replenished before spraying the layer. The method of soil leveling and background color painting can effectively spray the layer on the composite material, and in order to make the surface of the transparent paint smoother, the transparent paint must also be surface-polished with an abrasive, so that The overall process of composite materials is not only time-consuming and labor-intensive, but also very energy-intensive and environmentally friendly. Therefore, how to develop a method for directly forming the layer on the surface of the composite material without refining, bottoming, polishing and polishing It is necessary.

本發明之目的係在提供一種不用經過補土整平、底色塗裝及打磨拋光,即可直接於複合材料表面形成圖層之方法。SUMMARY OF THE INVENTION It is an object of the present invention to provide a method for forming a layer directly on the surface of a composite material without the need for soil leveling, undercoating, and polishing.

為連上述目的,本發明所提供之複合材料表面形成圖層之方法,其係包含有成型圖層步驟、成型表層步驟以及完成成品步驟,其中,該成型圖層步驟係將一預定圖案成型於一基材,使該基材上形成有一圖層;而該成型表層步驟則是將一聚氨基甲酸酯設置於該基材之外側,且至少覆蓋該圖層,以在該基材上形成一透明表層;最後該完成成品步驟則是將該基材結合於一複合材料上,使該複合材料表面會形成有該圖層。In order to achieve the above object, a method for forming a layer on a surface of a composite material provided by the present invention comprises a step of forming a layer, a step of forming a surface layer, and a step of completing a finished product, wherein the step of forming the layer forms a predetermined pattern on a substrate. Forming a layer on the substrate; and the step of forming the surface layer comprises disposing a polyurethane on the outer side of the substrate and covering at least the layer to form a transparent surface layer on the substrate; The finished product step is to bond the substrate to a composite material such that the layer is formed on the surface of the composite.

本發明所提供之複合材料表面形成圖層之方法,透過上述成型圖層步驟、成型表層步驟以及完成成品步驟,使用者只要先將該圖層成型於該基材,再將該透明表層覆蓋於該基材,之後再將該基材與該複合材料互相結合,便可於該複合材料表面形成有該圖層,藉此,不僅可有效改善習知複合材料製程需要進行補土整平與底色塗裝才能有效噴塗圖層之缺點,且因為該透明表層係由聚氨基甲酸酯所構成,而能夠填補該基材上凹凸不平處並形成一光滑平整之表面,所以使用者亦不需要對該透明表層進行打磨拋光,從而使本發明與習知製程相較能夠達到縮短製程與節能減碳之效果。The method for forming a layer on the surface of the composite material provided by the present invention, through the step of forming the layer, the step of forming the surface layer, and the step of completing the finished product, the user only needs to form the layer on the substrate, and then cover the substrate with the transparent surface layer. Then, the substrate and the composite material are combined with each other to form the layer on the surface of the composite material, thereby not only effectively improving the conventional composite material process, but also requiring soil leveling and background color coating. The disadvantage of effective spraying of the layer, and because the transparent surface layer is composed of polyurethane, and can fill the unevenness on the substrate and form a smooth and flat surface, the user does not need to perform the transparent surface layer. Grinding and polishing, so that the present invention can achieve the effect of shortening the process and saving energy and reducing carbon compared with the conventional process.

請同時參閱第一圖、第二圖以及第三圖所示,係為本發明之較佳實施例之流程圖、立體圖以及剖視圖,其係揭露有一種複合材料表面形成圖層之方法,該方法主要係包含有下列步驟:成型圖層步驟:將一預定圖案成型於一基材10,使該基材10上形成有一圖層20,其中,該預定圖案係採用熱昇華轉印或UV印刷之其中一種方式直接成型於該基材10上,且該基材10係選自不織布、彈性布、PE膜、PET膜及橡膠膜之其中一種。Please refer to the first, second and third figures, which are flowcharts, perspective views and cross-sectional views of a preferred embodiment of the invention, which disclose a method for forming a layer on a composite surface, the method mainly The method comprises the steps of: forming a layer: forming a predetermined pattern on a substrate 10 such that a layer 20 is formed on the substrate 10, wherein the predetermined pattern is one of sublimation transfer or UV printing. The substrate 10 is directly molded on the substrate 10, and the substrate 10 is selected from the group consisting of a nonwoven fabric, an elastic cloth, a PE film, a PET film, and a rubber film.

成型表層步驟:將一含有NCO之異氰酸鹽聚合物與一含有OH之羥化合物混合成一液態之聚氨基甲酸酯,並將該聚氨基甲酸酯灌注於該基材10上,且至少覆蓋該圖層20,以在該基材10上形成一透明表層30,於本實施例中,該聚氨基甲酸酯係選自熱塑性聚氨基甲酸酯(TPU)及反應型熱固性聚氨基甲酸酯(R-TPU)之其中一種,且該透明表層30係覆蓋整個基材10。Forming the surface layer step: mixing an NCO-containing isocyanate polymer with an OH-containing hydroxy compound into a liquid polyurethane, and pouring the polyurethane onto the substrate 10, and at least The layer 20 is covered to form a transparent surface layer 30 on the substrate 10. In this embodiment, the polyurethane is selected from the group consisting of thermoplastic polyurethane (TPU) and reactive thermosetting polyurethane. One of the esters (R-TPU), and the transparent skin 30 covers the entire substrate 10.

完成成品步驟:將該基材10結合於一複合材料40上,使該複合材料40表面會形成有該圖層20,其中,該基材10係採用熱壓成型之方式結合於該複合材料40上,且該複合材料40係係由一編織纖維布灌注樹脂所構成,該編織纖維布係選自玻璃纖維布、碳纖維布及硼纖維布之其中一種。Finishing the finished product step: bonding the substrate 10 to a composite material 40, such that the layer 20 is formed on the surface of the composite material 40, wherein the substrate 10 is bonded to the composite material 40 by thermoforming. And the composite material 40 is composed of a woven fiber cloth impregnated resin selected from one of a glass fiber cloth, a carbon fiber cloth and a boron fiber cloth.

為供進一步瞭解本發明構造特徵、運用技術手段及所預期達成之功效,茲將本發明使用方式加以敘述,相信當可由此而對本發明有更深入且具體之瞭解,如下所述:請繼續參閱第一圖、第二圖以及第三圖所示,透過上述步驟,使用者只要先將該圖層20利用熱昇華轉印或是UV印刷之方式直接成型於該基材10,再將該透明表層30覆蓋於該基材10,最後再將該基材10與該複合材料40一起進行熱壓成型,便可於該複合材料40表面形成有該圖層20,藉此,不僅可有效改善習知複合材料製程需要進行補土整平與底色塗裝才能有效噴塗圖層之缺點,且因為該透明表層30係由聚氨基甲酸酯所構成,而能夠填補該基材10上凹凸不平處並形成一光滑平整之表面,所以使用者亦不需要對該透明表層30進行表面打磨拋光,從而使本發明與習知製程相較能夠達到縮短製程與節能減碳之效果。For a further understanding of the structural features of the present invention, the application of the technical means, and the intended effect, the manner of use of the present invention will be described. It is believed that the present invention may be further understood and understood as follows: As shown in the first, second and third figures, the user can directly form the layer 20 on the substrate 10 by means of sublimation transfer or UV printing, and then the transparent surface layer. 30 covers the substrate 10, and finally the substrate 10 is hot-pressed together with the composite material 40, so that the layer 20 can be formed on the surface of the composite material 40, thereby not only effectively improving the conventional composite The material process requires the disadvantages of the soil leveling and the base color coating to effectively spray the layer, and because the transparent surface layer 30 is composed of polyurethane, it can fill the unevenness on the substrate 10 and form a Smooth and flat surface, so the user does not need to polish and polish the transparent surface layer 30, so that the invention can shorten the process and save energy and reduce carbon compared with the conventional process. fruit.

請再參閱第四圖、第五圖以及第六圖所示,係為本發明之另一較佳實施例之流程圖、立體圖以及剖視圖,該複合材料表面形成圖層之方法與前述較佳實施例不同之處係在於,於該完成成品步驟之前更進一步包含有一成型保護層步驟,該成型保護層步驟係在該透明表層30之外側貼附有一保護膜50,該保護膜50係選自PE膜及耐高溫離型膜之其中一種,可供在該基材10與該複合材料40熱壓成型完成後,再由該透明表層30上撕離,而能保護該透明表層30於熱壓成型之過程中不受到汙染。Referring to FIG. 4, FIG. 5 and FIG. 6 again, it is a flow chart, a perspective view and a cross-sectional view of another preferred embodiment of the present invention. The method for forming a layer on the surface of the composite material and the foregoing preferred embodiment The difference is that, before the step of completing the finished product, the method further comprises a step of forming a protective layer on the outer side of the transparent surface layer 30, the protective film 50 is selected from the PE film. And one of the high temperature resistant release film can be used to protect the transparent surface layer 30 from hot press forming after the substrate 10 and the composite material 40 are hot pressed and then peeled off from the transparent surface layer 30. No pollution during the process.

值得一提的是,由於該透明表層30係由聚氨基甲酸酯所構成,而具有耐高溫之特性,因此當該基材10與該複合材料40一起進行熱壓成型時,不論是應用於如第二圖所示之平板熱壓製程,或是應用於如第五圖所示之管狀內壓膨脹製程,該透明表層30皆可確保該圖層20不會受到破壞。It is worth mentioning that, since the transparent surface layer 30 is composed of polyurethane and has high temperature resistance, when the substrate 10 is subjected to hot press forming together with the composite material 40, it is applied to The transparent surface layer 30 ensures that the layer 20 is not damaged, as in the flat hot stamping process shown in FIG. 2 or in the tubular internal pressure expansion process as shown in FIG.

茲,再將本發明之特徵及其可達成之預期功效陳述如下:本發明之複合材料表面形成圖層之方法,透過成型圖層步驟、成型表層步驟以及完成成品步驟,使用者只要先將該圖層成型於該基材,再將該透明表層覆蓋於該基材,之後再將該基材與該複合材料互相結合,便可於該複合材料表面形成有該圖層,藉此,不僅可有效改善習知複合材料製程需要進行補土整平與底色塗裝才能有效噴塗圖層之缺點,且因為該透明表層係由聚氨基甲酸酯所構成,而能夠填補該基材上凹凸不平處並形成一光滑平整之表面,所以使用者亦不需要對該透明表層進行打磨拋光,從而使本發明與習知製程相較能夠達到縮短製程與節能減碳之效果。Further, the features of the present invention and the achievable expected efficacy thereof are as follows: the method for forming a layer on the surface of the composite material of the present invention, through the step of forming a layer, the step of forming a surface layer, and the step of completing the finished product, the user only needs to form the layer first. And coating the transparent surface layer on the substrate, and then bonding the substrate and the composite material to form the layer on the surface of the composite material, thereby not only effectively improving the conventional structure. The composite material process requires the advantages of soil leveling and undercoating to effectively spray the layer, and because the transparent surface layer is composed of polyurethane, it can fill the unevenness on the substrate and form a smooth The surface is flat, so the user does not need to polish and polish the transparent surface layer, so that the invention can achieve the effects of shortening the process and saving energy and reducing carbon compared with the conventional process.

綜上所述,本發明在同類產品中實有其極佳之進步實用性,同時遍查國內外關於此類結構之技術資料,文獻中亦未發現有相同的構造存在在先,是以,本發明實已具備發明專利要件,爰依法提出申請。In summary, the present invention has excellent advancement and practicability in similar products, and at the same time, the technical materials of such structures are frequently investigated at home and abroad, and the same structure is not found in the literature. The invention already has the invention patent requirements, and the application is filed according to law.

惟,以上所述者,僅係本發明之一較佳可行實施例而已,故舉凡應用本發明說明書及申請專利範圍所為之等效結構變化,理應包含在本發明之專利範圍內。However, the above-mentioned ones are merely preferred embodiments of the present invention, and the equivalent structural changes of the present invention and the scope of the claims are intended to be included in the scope of the present invention.

10...基材10. . . Substrate

20...圖層20. . . Layer

30...透明表層30. . . Transparent surface

40...複合材料40. . . Composite material

50...保護膜50. . . Protective film

第一圖係本發明之較佳實施例之流程圖。The first figure is a flow chart of a preferred embodiment of the present invention.

第二圖係本發明之較佳實施例之立體圖。The second drawing is a perspective view of a preferred embodiment of the present invention.

第三圖係本發明之較佳實施例之剖視圖。The third drawing is a cross-sectional view of a preferred embodiment of the invention.

第四圖係本發明之另一較佳實施例之流程圖。The fourth figure is a flow chart of another preferred embodiment of the present invention.

第五圖係本發明之另一較佳實施例之立體圖。Figure 5 is a perspective view of another preferred embodiment of the present invention.

第六圖係本發明之另一較佳實施例之剖視圖。Figure 6 is a cross-sectional view of another preferred embodiment of the present invention.

10...基材10. . . Substrate

20...圖層20. . . Layer

30...透明表層30. . . Transparent surface

40...複合材料40. . . Composite material

Claims (10)

一種複合材料表面形成圖層之方法,其係包含有下列步驟:成型圖層步驟:將一預定圖案成型於一基材,使該基材上形成有一圖層;成型表層步驟:將一含有NCO之異氰酸鹽聚合物與一含有OH之羥化合物混合成一液態之聚氨基甲酸酯,並將該聚氨基甲酸酯設置於該基材之外側,且至少覆蓋該圖層,以在該基材上形成一透明表層;完成成品步驟:將形成有該圖層之該基材結合於一複合材料上,該複合材料係由一編織纖維布灌注樹脂所構成,使該複合材料表面會形成有該圖層。 A method for forming a layer on a surface of a composite material, comprising the steps of: forming a layer: forming a predetermined pattern on a substrate to form a layer on the substrate; and forming a surface layer: a step of: forming an isocyanate containing NCO The acid salt polymer is mixed with an OH-containing hydroxy compound to form a liquid polyurethane, and the polyurethane is disposed on the outer side of the substrate, and at least covers the layer to form on the substrate. a transparent skin layer; a finished product step: bonding the substrate on which the layer is formed to a composite material, the composite material being composed of a woven fiber cloth impregnated resin, such that the layer is formed on the surface of the composite material. 依據申請專利範圍第1項所述之一種複合材料表面形成圖層之方法,其中,於該完成成品步驟之前更進一步包含有一成型保護層步驟,該成型保護層步驟係在該透明表層之外側貼附有一保護膜。 A method of forming a layer on a surface of a composite material according to claim 1, wherein the step of completing the finished product further comprises a step of forming a protective layer attached to the outer side of the transparent surface layer. There is a protective film. 依據申請專利範圍第2項所述之一種複合材料表面形成圖層之方法,其中,該保護膜係選自PE膜及耐高溫離型膜之其中一種。 A method for forming a layer on a surface of a composite material according to claim 2, wherein the protective film is selected from the group consisting of a PE film and a high temperature resistant release film. 依據申請專利範圍第1項所述之一種複合材料表面形成圖層之方法,其中,該透明表層係覆蓋整個基材。 A method of forming a layer on a surface of a composite material according to claim 1, wherein the transparent surface layer covers the entire substrate. 依據申請專利範圍第1項所述之一種複合材料表面形成圖層之方法,其中,該複合材料係由一編織纖維布灌注樹脂所構成。 A method of forming a layer on a surface of a composite material according to claim 1, wherein the composite material is composed of a woven fiber cloth impregnated resin. 依據申請專利範圍第5項所述之一種複合材料表面形成圖層之方法,其中,該編織纖維布係選自玻璃纖維布、碳纖維布及硼纖維布之其中一種。 A method of forming a layer on a surface of a composite material according to claim 5, wherein the woven fabric is selected from the group consisting of a glass fiber cloth, a carbon fiber cloth, and a boron fiber cloth. 依據申請專利範圍第1項所述之一種複合材料表面形成圖層之方法,其中,該基材係選自不織布、彈性布、PE膜、PET膜及橡膠膜之其中一種。 A method of forming a layer on a surface of a composite material according to claim 1, wherein the substrate is selected from the group consisting of a nonwoven fabric, an elastic cloth, a PE film, a PET film, and a rubber film. 依據申請專利範圍第1項所述之一種複合材料表面形成圖層之方法,其中,該預定圖案係採用熱昇華轉印或UV印刷之其中一種方式直接成型於該基材上。 A method of forming a layer on a surface of a composite material according to claim 1, wherein the predetermined pattern is directly formed on the substrate by one of sublimation transfer or UV printing. 依據申請專利範圍第1項所述之一種複合材料表面形成圖層之方法,其中,該基材係採用熱壓成型之方式結合於該複合材料上。 A method of forming a layer on a surface of a composite material according to claim 1, wherein the substrate is bonded to the composite by thermoforming. 依據申請專利範圍第1項所述之一種複合材料表面形成圖層之方法,其中,該聚氨基甲酸酯係選自熱塑性聚氨基甲酸酯(TPU)及反應型熱固性聚氨基甲酸酯(R-TPU)之其中一種。A method for forming a layer on a surface of a composite material according to claim 1, wherein the polyurethane is selected from the group consisting of thermoplastic polyurethane (TPU) and reactive thermosetting polyurethane (R). -TPU).
TW100136935A 2011-10-12 2011-10-12 A method of forming a layer on a composite surface TWI569987B (en)

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CN1676319A (en) * 2004-03-31 2005-10-05 大日本印刷株式会社 decorative flakes
CN101905548A (en) * 2009-06-03 2010-12-08 约翰斯曼维尔欧洲有限公司 The printing of nonwoven and their purposes in composite

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1676319A (en) * 2004-03-31 2005-10-05 大日本印刷株式会社 decorative flakes
CN101905548A (en) * 2009-06-03 2010-12-08 约翰斯曼维尔欧洲有限公司 The printing of nonwoven and their purposes in composite

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