TWI557191B - 在室內建築產品中使用醛類清除劑 - Google Patents
在室內建築產品中使用醛類清除劑 Download PDFInfo
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- TWI557191B TWI557191B TW101125583A TW101125583A TWI557191B TW I557191 B TWI557191 B TW I557191B TW 101125583 A TW101125583 A TW 101125583A TW 101125583 A TW101125583 A TW 101125583A TW I557191 B TWI557191 B TW I557191B
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- building product
- interior building
- ammonium
- melamine formaldehyde
- polyvinyl alcohol
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- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 title claims description 35
- 238000000576 coating method Methods 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 19
- 229920000877 Melamine resin Polymers 0.000 claims description 18
- 238000009472 formulation Methods 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 17
- 239000002516 radical scavenger Substances 0.000 claims description 17
- 239000004254 Ammonium phosphate Substances 0.000 claims description 16
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 16
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 16
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 12
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 7
- XNXNAUABWPNMLY-UHFFFAOYSA-N O1CCOCC1.C(CCCCC(=O)O)(=O)O Chemical compound O1CCOCC1.C(CCCCC(=O)O)(=O)O XNXNAUABWPNMLY-UHFFFAOYSA-N 0.000 claims description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 3
- ZRSKSQHEOZFGLJ-UHFFFAOYSA-N ammonium adipate Chemical compound [NH4+].[NH4+].[O-]C(=O)CCCCC([O-])=O ZRSKSQHEOZFGLJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000019293 ammonium adipate Nutrition 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 229940001584 sodium metabisulfite Drugs 0.000 claims description 3
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 3
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 239000002518 antifoaming agent Substances 0.000 claims description 2
- -1 propiamine Chemical compound 0.000 claims description 2
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 claims description 2
- 229910000342 sodium bisulfate Inorganic materials 0.000 claims description 2
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 2
- 229940010556 ammonium phosphate Drugs 0.000 claims 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 3
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 claims 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 229940116349 dibasic ammonium phosphate Drugs 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims 1
- 238000005728 strengthening Methods 0.000 claims 1
- 239000012855 volatile organic compound Substances 0.000 description 19
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 239000000126 substance Substances 0.000 description 9
- 238000009434 installation Methods 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ZQOMKIOQTCAGCM-UHFFFAOYSA-L [Na+].[Na+].OS(O)(=O)=O.[O-]S([O-])(=O)=O Chemical compound [Na+].[Na+].OS(O)(=O)=O.[O-]S([O-])(=O)=O ZQOMKIOQTCAGCM-UHFFFAOYSA-L 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C09D161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/33—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by chemical fixing the harmful substance, e.g. by chelation or complexation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Toxicology (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Paints Or Removers (AREA)
- Finishing Walls (AREA)
- Building Environments (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
Description
本發明總體上涉及施用於室內建築產品上(例如天花板貼磚)的塗層，其中這種塗層包括一種醛類清除劑，該醛類清除劑擁有束縛任何醛類的能力，包括可能會易於從基礎室內建築產品本身和/或該塗層散發出來的甲醛和/或其他揮發性有機化合物。
很多室內建築產品如天花板貼磚、纖維面板、石膏牆板以及其他不同類型的牆板，例如在安裝之後，會展現出一種向周圍環境散發醛類(包括甲醛、蒸汽和/或其他類型的揮發性有機化合物(“VOC”))的趨勢。該等醛類和其他VOC的來源可能存在於基礎室內建築產品本身或者施加在其上的覆蓋物、塗層和其他附屬物中。
由於該等醛類和其他VOC會對人和動物的健康、同時也對暴露在這種散發物中的人和動物的整體舒適感產生有害影響，該等醛類與其他VOC的釋放是不被希望的，並且應努力避免將其排放到周圍環境中。就這一點而言，從室內建築產品散發出來的甲醛和某些其他VOC已經被分類為致癌劑。
因此，存在一種需要來控制來自該等室內建築產品的醛類(包括甲醛)和其他VOC的散發。達到這個目的的方法之一涉及將室內建築產品與一物質相結合，這種物質將
束縛該等醛類和其他VOC，並且防止它們從該室內建築產品釋放到周圍環境中。這種物質可以在以下任何一種情況下結合到該室內建築產品中：比如在生產該室內建築產品時，在其安裝時或者在其安裝後。
在確定任何一種特定的物質對於束縛醛類和其他VOC的目的是否適用的一考慮因素可以是，由於該物質束縛一種醛類或者另一種VOC而形成的複合物對該室內建築產品的影響。即是說，這種複合物不應對室內建築產品的物理或化學性能、亦或是其審美價值產生負面影響。
在此所使用的，表述“醛類清除劑”意在指代用於束縛醛類和其他VOC的目的的任何物質，無論是例如藉由共價化學鍵合、離子相互作用、醛類和/或其他VOC對基底的改進的結合(醛類和/或其他VOC存在於該基底中)、相轉變、氫鍵合或其他方法。
根據一方面，本發明係關於施用在室內建築產品表面的一塗層，該塗層包括一樹脂配製物，這種樹脂配製物的特徵在於當其與一種醛類清除劑共同作為一塗層施加到這個室內建築產品上時，它能夠對該室內建築產品進行強化。
根據本發明的另一方面，這種醛類清除劑選自下組，該組由以下各項組成：四亞乙基五胺；丙醯胺；己內醯胺；氫氧化銨；硫酸氫鈉；焦亞硫酸鈉；一代磷酸銨；二代磷酸銨；一代磷酸銨和二代磷酸銨的一組合；一代磷酸銨、
二代磷酸銨和亞硫酸鹽的一組合；聚乙烯醇；己二酸二醯肼；以及聚乙烯醇和己二酸二醯肼的一組合。
在本發明的另一方面中，該樹脂配製物包括一種三聚氰胺甲醛樹脂，並且該醛類清除劑包括單獨的聚乙烯醇和己二酸二醯肼或者它們的組合。
在本發明另外的一方面，這種三聚氰胺甲醛樹脂配製物按重量計包括：約10%至20%的三聚氰胺甲醛樹脂；約20%至60%的碳酸鈣填充物以及約0%至10%的粘土填充物；約20%至80%的水；氯化銨和/或鎂催化劑；以及可以抑制在該樹脂配製物中形成泡沫的足量的消泡劑。在這個另外方面的一具體實施方式中，這種三聚氰胺甲醛樹脂配製物按重量計包括：約10%至20%的三聚氰胺甲醛樹脂；約35%的碳酸鈣填充物和約5%的粘土填充物；以及約40%的水。
在本發明的再另一方面中，施加該塗層的室內建築產品可以包括天花板貼磚。
結合了本發明一或多個方面的實施例在以下進行描述。該等實例並不意在限制本發明。因此，例如在某些情況下，參考一方面或一實施方式來描述的本發明的一或多個實例可用於其它多個方面和實施方式中。此外，在此使用的某些術語僅為方便而不應認為其限制了本發明。
本發明可應用到多種室內建築產品中，該等室內建築產品包括例如天花板貼磚、纖維面板和石膏牆板以及其他種類的牆板，以及施加到該等室內建築產品的至少一個表面上的塗層。在本發明的一具體應用中，這種塗層被施加到一天花板貼磚的背面，即該天花板貼磚未暴露的一面。在本發明的一實施方式中，該等塗層包括一樹脂配製物，該樹脂配製物的特徵在於當其與一醛類清除劑共同作為一塗層施加到這個室內建築產品上時，它能夠對該室內建築產品進行強化。例如，可以藉由使用噴塗技術或者保有該等塗層的輥來將塗層施加於該天花板貼磚的表面上，並且可以在例如貼磚生產過程完成時、天花板貼磚安裝時或天花板貼磚安裝後施加。
在本發明的一實施方式中，該樹脂配製物包括一種三聚氰胺甲醛樹脂，例如像該樹脂的一種丁基化的形式，它可以在正丁醇和二甲苯中溶解，並且然後與醇酸樹脂、環氧樹脂、丙烯酸樹脂和聚酯樹脂交聯。這種三聚氰胺甲醛樹脂在天花板貼磚上形成了一堅硬的覆蓋物，並且例如在該天花板貼磚從開放格柵結構(典型地安裝在內部結構的頂板上)懸垂時，為該天花板貼磚提供了用以維持其完好所需的的強度。
在本發明的一具體的方面中，這種三聚氰胺甲醛樹脂可以包含在一種三聚氰胺甲醛樹脂配製物中，該配製物屬於本發明的塗層，按重量計包括：約10%至20%的三聚氰胺甲醛樹脂；約20%至60%的碳酸鈣填充物以及約0%至
10%的粘土填充物；約20%至80%的水；足量的氯化銨和/或氯化鎂催化劑；以及可以抑制泡沫在該樹脂配製物中形成的足量的消泡劑。在本發明一具體方面的實施方式中，這種三聚氰胺甲醛樹脂可以包含在一種三聚氰胺樹甲醛脂配製物中，該三聚氰胺甲醛樹脂配製物按重量計包括：約10%至20%的三聚氰胺甲醛樹脂；約35%的碳酸鈣填充物和約5%的粘土填充物；以及約40%的水。
除了該樹脂配製物之外，本發明的塗層還包括一種醛類清除劑。這種醛類清除劑的主要功能係束縛天花板貼磚自身和/或施加到天花板貼磚上的塗層中可能散發出的任何醛類和其他VOC，並且防止該等醛類和其他VOC從已經安裝好的天花板貼磚中散發到周圍環境裡。例如共價化學鍵合、離子相互作用、醛類和/或其他VOC對天花板貼磚(該等醛類和/或其他VOC存在其中)的改進的結合、相轉變、氫鍵合或其他方法都可以導致對任何醛類和其他VOC進行束縛。當一甲醛樹脂配製物被用於塗層中時，典型地會出現醛類從該配製物中散發的現象。然而，易於散發的醛類和其他VOC可能來自於進入天花板貼磚製造過程的任何組分。包括該醛類清除劑的塗層可以在天花板貼磚製造時、安裝時、或者安裝後施加到該天花板貼磚上。
根據本發明的一方面，這種醛類清除劑可以包括選自下組中的一清除劑，該組由以下各項組成：四亞乙基五胺；丙醯胺；己內醯胺；氫氧化銨；硫酸氫鈉；焦亞硫酸鈉；一代磷酸銨；二代磷酸銨；一代磷酸銨和二代磷酸銨的一
組合；一代磷酸銨、二代磷酸銨和亞硫酸鹽的一組合；聚乙烯醇；己二酸二醯肼；以及聚乙烯醇和己二酸二醯肼的一組合。在本發明的一具體實施方式中，該醛類清除劑可以包括：聚乙烯醇，如具有化學文摘服務社登記號(“CAS號”)25213-24-5的Celvol® 205S或Celvol® 203S；己二酸二醯肼；以及聚乙烯醇和己二酸二醯肼的一組合，其中該聚乙烯醇具有化學文摘服務社登記號(“CAS號”)25213-24-5的Celvol® 205S或Celvol® 203S。
儘管本發明已參考其某些實施方式如上地進行了詳述和展示，在此應該理解的是本發明並非因此受限。此外，在閱讀並理解本說明書、包括附圖的基礎上，對熟習該項技術者而言，在此描述的本發明的該等方面將產生多種修改和改變。本發明意在涵蓋並包括對包含在以下申請專利範圍中的、所說明的實施方式進行的任何以及所有的此類修改和改變。
Claims (8)
- 一種室內建築產品，包括至少二個外部表面(exterior surface)以及一塗層(coating)施加至該至少二個外部表面之至少一者上，該塗層包含：一樹脂配製物(resin formulation)，其特徵在於當其作為一塗層施加到該建築產品時，其能夠對該室內建築產品進行強化，以及包含一三聚氰胺甲醛樹脂配製物；以及一醛類清除劑(aldehyde scavenger)，選自以下群組：四亞乙基五胺(tetraethylene pentamine)、丙醯胺、己內醯胺、氫氧化銨、硫酸氫鈉、焦亞硫酸鈉(sodium metabisulfite)、一代磷酸銨(ammonium primary phosphate)、二代磷酸銨(ammonium secondary phosphate)、一代磷酸銨和二代磷酸銨的一組合；一代磷酸銨、二代磷酸銨和亞硫酸鹽(sulfite)的一組合；聚乙烯醇、己二酸二醯肼(adipic dihydrazide)、以及聚乙烯醇和己二酸二醯肼的一組合。
- 如請求項1之室內建築產品，其中該醛類清除劑包含聚乙烯醇。
- 如請求項1之室內建築產品，其中該醛類清除劑包含己二酸二醯肼。
- 如請求項1之室內建築產品，其中該三聚氰胺甲醛樹脂配製物按重量計包含：約10%至20%的三聚氰胺甲醛樹脂； 約20%至60%的碳酸鈣填充物以及約0%至10%的粘土填充物；約20%至80%的水；一選自以下群組之催化劑：氯化銨、氯化鎂、及氯化銨和氯化鎂的一組合；以及可以抑制在該樹脂配製物中形成泡沫的足量的消泡劑。
- 如請求項4之室內建築產品，其中該三聚氰胺甲醛樹脂配製物按重量計包括：約10%至20%的三聚氰胺甲醛樹脂；約35%的碳酸鈣填充物和約5%的粘土填充物；以及約40%的水。
- 如請求項5之室內建築產品，其中該醛類清除劑包含聚乙烯醇。
- 如請求項6之室內建築產品，其中該室內建築產品包含天花板貼磚(ceiling tile)。
- 如請求項5之室內建築產品，其中該醛類清除劑包含聚乙烯醇和己二酸二醯肼之一組合。
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| US9802866B2 (en) | 2005-06-09 | 2017-10-31 | United States Gypsum Company | Light weight gypsum board |
| AU2013221770B2 (en) | 2012-02-17 | 2016-06-09 | United States Gypsum Company | Gypsum products with high efficiency heat sink additives |
| US9540810B2 (en) | 2012-10-23 | 2017-01-10 | United States Gypsum Company | Pregelatinized starch with mid-range viscosity, and product, slurry and methods related thereto |
| US9828441B2 (en) | 2012-10-23 | 2017-11-28 | United States Gypsum Company | Method of preparing pregelatinized, partially hydrolyzed starch and related methods and products |
| US10399899B2 (en) | 2012-10-23 | 2019-09-03 | United States Gypsum Company | Pregelatinized starch with mid-range viscosity, and product, slurry and methods related thereto |
| RU2645518C2 (ru) | 2013-09-30 | 2018-02-21 | Сёртнтид Корпорейшн | Грязеотталкивающие и обеспечивающие удаление лос покрытия и применение указанных покрытий |
| US8974925B1 (en) | 2013-10-15 | 2015-03-10 | United States Gypsum Company | Gypsum board |
| US9764307B2 (en) | 2015-12-15 | 2017-09-19 | Awi Licensing Llc | VOC and odor reducing building panels |
| GB2565331B (en) * | 2017-08-10 | 2019-08-14 | Kingspan Holdings Irl Ltd | Phenolic foam and method of manufacture thereof |
| MX2020008240A (es) * | 2018-02-09 | 2020-11-06 | Pressing Dev L L C | Productos laminados manchables, composiciones y metodos de manufactura. |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101530624A (zh) * | 2009-03-10 | 2009-09-16 | 江沛芸 | 一种具有除味功能的甲醛清除剂 |
| US20100037399A1 (en) * | 2008-08-12 | 2010-02-18 | Hoefler Joseph M | Aldehyde reduction in aqueous coating and leather finishing compositions |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3655431A (en) * | 1969-06-02 | 1972-04-11 | American Cyanamid Co | Ceiling tile carrying anti-sag coating |
| US3996177A (en) * | 1975-02-18 | 1976-12-07 | The B. F. Goodrich Company | Stable acrylic ester latex coating compositions |
| US4443354A (en) | 1982-03-26 | 1984-04-17 | Minnesota Minning And Manufacturing Company | Sorbent material for reducing formaldehyde emission |
| US5594061A (en) * | 1992-09-14 | 1997-01-14 | Gencorp Inc. | Aqueous coating for vinyl chloride polymer substrate |
| CA2207883A1 (en) | 1996-09-27 | 1998-03-27 | Michael T. Philbin | Water resistant alkaline corrugating adhesive composition |
| JP4213365B2 (ja) | 2000-10-10 | 2009-01-21 | 吉野石膏株式会社 | 石膏ボード、石膏ボードの製造方法、建築物の内装構造、及び建築物の内装構造の改修方法 |
| US6906132B2 (en) * | 2001-09-04 | 2005-06-14 | Awi Licensing Company | Low formaldehyde emission coatings and binders from formaldehyde-based resins |
| EP1863619A1 (en) * | 2005-04-01 | 2007-12-12 | Akzo Nobel Coatings International BV | Method of reducing the emission of aldehyde from wood based products |
| US7989367B2 (en) * | 2006-06-30 | 2011-08-02 | Georgia-Pacific Chemicals Llc | Reducing formaldehyde emissions from fiberglass insulation |
| US8173219B2 (en) | 2006-06-09 | 2012-05-08 | Georgia-Pacific Chemicals Llc | Porous fiberglass materials having reduced formaldehyde emissions |
| US20070287018A1 (en) | 2006-06-09 | 2007-12-13 | Georgia-Pacific Resins, Inc. | Fibrous mats having reduced formaldehyde emissions |
| JP3999250B1 (ja) * | 2006-09-28 | 2007-10-31 | ニチハ株式会社 | アルデヒドを捕捉分解する繊維板 |
| JP5236882B2 (ja) * | 2007-02-02 | 2013-07-17 | ニチハ株式会社 | 機能性建築板 |
| DK3069778T3 (en) | 2008-07-18 | 2018-05-07 | Awi Licensing Llc | COMPOSITION TO REMOVE ALDEHYDE FROM AIR |
| GB2462619A (en) * | 2008-08-13 | 2010-02-17 | Dynea Austria Gmbh | Two-component adhesive system |
-
2012
- 2012-06-07 US US13/490,595 patent/US20130023612A1/en not_active Abandoned
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100037399A1 (en) * | 2008-08-12 | 2010-02-18 | Hoefler Joseph M | Aldehyde reduction in aqueous coating and leather finishing compositions |
| CN101530624A (zh) * | 2009-03-10 | 2009-09-16 | 江沛芸 | 一种具有除味功能的甲醛清除剂 |
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| CN103687917B (zh) | 2018-02-06 |
| TW201305286A (zh) | 2013-02-01 |
| WO2013012828A1 (en) | 2013-01-24 |
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| BR112014001284A2 (pt) | 2017-04-18 |
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| CA2841821C (en) | 2018-02-27 |
| EP2734592B1 (en) | 2022-09-07 |
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| US20130023612A1 (en) | 2013-01-24 |
| RU2014103706A (ru) | 2015-08-27 |
| CO6880058A2 (es) | 2014-02-28 |
| EP2734592A1 (en) | 2014-05-28 |
| CN103687917A (zh) | 2014-03-26 |
| BR112014001284B1 (pt) | 2021-05-04 |
| KR20140048961A (ko) | 2014-04-24 |
| AU2012284164B2 (en) | 2016-04-28 |
| US9334410B2 (en) | 2016-05-10 |
| PL2734592T3 (pl) | 2022-12-05 |
| UA115036C2 (uk) | 2017-09-11 |
| MY166178A (en) | 2018-06-07 |
| KR101832145B1 (ko) | 2018-02-26 |
| AR087190A1 (es) | 2014-02-26 |
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