TWI546895B - Semiconductor structure and manufacturing method of the same - Google Patents
Semiconductor structure and manufacturing method of the same Download PDFInfo
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- TWI546895B TWI546895B TW104128181A TW104128181A TWI546895B TW I546895 B TWI546895 B TW I546895B TW 104128181 A TW104128181 A TW 104128181A TW 104128181 A TW104128181 A TW 104128181A TW I546895 B TWI546895 B TW I546895B
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- 239000004065 semiconductor Substances 0.000 title claims description 40
- 238000004519 manufacturing process Methods 0.000 title claims description 20
- 230000004888 barrier function Effects 0.000 claims description 37
- 238000005530 etching Methods 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 13
- 238000009413 insulation Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 description 42
- 239000004020 conductor Substances 0.000 description 11
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 10
- 229910052721 tungsten Inorganic materials 0.000 description 10
- 239000010937 tungsten Substances 0.000 description 10
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 9
- 239000011231 conductive filler Substances 0.000 description 9
- 125000006850 spacer group Chemical group 0.000 description 6
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 5
- 229920005591 polysilicon Polymers 0.000 description 5
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 239000003989 dielectric material Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 3
- 229910001936 tantalum oxide Inorganic materials 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 229910000449 hafnium oxide Inorganic materials 0.000 description 2
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 2
- 230000012447 hatching Effects 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 230000005055 memory storage Effects 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- LLHNYODRQOULLH-UHFFFAOYSA-N [Y].[Re] Chemical compound [Y].[Re] LLHNYODRQOULLH-UHFFFAOYSA-N 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- SEOYNUHKXVGWFU-UHFFFAOYSA-N mu-oxidobis(oxidonitrogen) Chemical compound O=NON=O SEOYNUHKXVGWFU-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
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- Semiconductor Memories (AREA)
Description
本揭露內容是有關於一種半導體結構及其製造方法,且特別是有關於一種具有蝕刻阻擋結構之半導體結構及其製造方法。The present disclosure relates to a semiconductor structure and a method of fabricating the same, and more particularly to a semiconductor structure having an etch barrier structure and a method of fabricating the same.
近年來半導體元件的結構不斷地改變,且元件的記憶體儲存容量也不斷增加。記憶裝置係使用於許多產品之中,例如MP3播放器、數位相機、電腦檔案等等之儲存元件中。隨著應用的增加,對於記憶裝置的需求也趨向較小的尺寸、較大的記憶容量。因應這種需求,係需要製造高元件密度及具有小尺寸的記憶裝置,也因此製程的難度係提升。In recent years, the structure of semiconductor elements has been constantly changing, and the memory storage capacity of the elements has also been increasing. Memory devices are used in many products, such as MP3 players, digital cameras, computer files, and the like. As applications increase, so does the demand for memory devices toward smaller sizes and larger memory capacities. In response to this demand, it is necessary to manufacture a memory device having a high component density and a small size, and thus the difficulty of the process is improved.
因此,設計者們無不致力於開發一種三維記憶裝置,不但具有許多堆疊平面而達到更高的記憶儲存容量,具有更微小的尺寸,同時具備簡化的製程及良好之穩定性。Therefore, designers are all committed to developing a three-dimensional memory device that not only has many stacked planes but also achieves higher memory storage capacity, has a smaller size, and has a simplified process and good stability.
本揭露內容係有關於一種半導體結構及其製造方法。實施例中,半導體結構中,垂直延伸區中的導電層形成於蝕刻阻擋結構上,使得垂直延伸的導電層可以獲得蝕刻阻擋結構所提供的良好的支撐,以提供堆疊結構和接觸插塞之間良好且穩定的電性接觸。The disclosure relates to a semiconductor structure and a method of fabricating the same. In an embodiment, in the semiconductor structure, the conductive layer in the vertical extension region is formed on the etch barrier structure such that the vertically extending conductive layer can obtain good support provided by the etch barrier structure to provide a structure between the stacked structure and the contact plug. Good and stable electrical contact.
根據本揭露內容之一實施例,係提出一種半導體結構。半導體結構包括一基板、一堆疊結構、一蝕刻阻擋結構(etching stop structure)、複數個記憶結構以及一第一填充切槽(filled slit groove)。基板具有一凹槽(trench)。堆疊結構具有一水平延伸區及一垂直延伸區,垂直延伸區沿凹槽之一側壁延伸,其中堆疊結構包括複數個導電層和複數個絕緣層,交錯設置(interlaced)堆疊於凹槽中。蝕刻阻擋結構形成於堆疊結構之垂直延伸區中。記憶結構垂直穿過堆疊結構之水平延伸區中的導電層和絕緣層。第一填充切槽形成於堆疊結構中,其中垂直延伸區中之導電層和絕緣層形成於蝕刻阻擋結構上且位於蝕刻阻擋結構和第一填充切槽之間。In accordance with an embodiment of the present disclosure, a semiconductor structure is proposed. The semiconductor structure includes a substrate, a stacked structure, an etching stop structure, a plurality of memory structures, and a first filled slit groove. The substrate has a trench. The stacked structure has a horizontal extension and a vertical extension, and the vertical extension extends along a sidewall of the recess, wherein the stacked structure comprises a plurality of conductive layers and a plurality of insulating layers, which are interlaced and stacked in the grooves. An etch barrier structure is formed in the vertical extension of the stacked structure. The memory structure passes vertically through the conductive and insulating layers in the horizontal extension of the stacked structure. A first fill sipe is formed in the stacked structure, wherein the conductive layer and the insulating layer in the vertical extension are formed on the etch stop structure and between the etch stop structure and the first fill nip.
根據本揭露內容之另一實施例,係提出一種半導體結構的製造方法。半導體結構的製造方法包括以下步驟。提供一基板,基板具有一凹槽;形成一堆疊結構,堆疊結構具有一水平延伸區及一垂直延伸區,垂直延伸區沿凹槽之一側壁延伸,其中堆疊結構包括複數個導電層和複數個絕緣層,交錯設置堆疊於凹槽中;形成一蝕刻阻擋結構於堆疊結構之垂直延伸區中;形成複數個記憶結構,垂直穿過堆疊結構之水平延伸區中的導電層和絕緣層;以及形成一第一填充切槽於堆疊結構中,其中垂直延伸區中之導電層和絕緣層形成於蝕刻阻擋結構上且位於蝕刻阻擋結構和第一填充切槽之間。In accordance with another embodiment of the present disclosure, a method of fabricating a semiconductor structure is presented. The method of fabricating a semiconductor structure includes the following steps. Providing a substrate having a recess; forming a stack structure having a horizontal extension and a vertical extension, the vertical extension extending along a sidewall of the recess, wherein the stack comprises a plurality of conductive layers and a plurality of An insulating layer, staggeredly stacked in the recess; forming an etch stop structure in the vertical extension of the stacked structure; forming a plurality of memory structures, vertically passing through the conductive layer and the insulating layer in the horizontal extension of the stacked structure; A first fill is scribed in the stacked structure, wherein the conductive layer and the insulating layer in the vertical extension are formed on the etch stop structure and between the etch stop structure and the first fill nip.
為了對本發明之上述及其他方面有更佳的瞭解,下文特舉較佳實施例,並配合所附圖式,作詳細說明如下:In order to better understand the above and other aspects of the present invention, the preferred embodiments are described below, and in conjunction with the drawings, the detailed description is as follows:
10、20‧‧‧半導體結構
100‧‧‧基板
100a‧‧‧上表面
100b‧‧‧底面
100s‧‧‧側壁
100t、6300‧‧‧凹槽
200、5200‧‧‧堆疊結構
210‧‧‧導電層
220‧‧‧絕緣層
230‧‧‧材料層
240‧‧‧空位
300‧‧‧蝕刻阻擋結構
300’‧‧‧蝕刻阻擋塊
310‧‧‧第一側壁
320‧‧‧第二側壁
330‧‧‧底表面
400‧‧‧介電結構
410‧‧‧第一填充切槽
420‧‧‧第二填充切槽
510、520‧‧‧接觸插塞
600‧‧‧氧化物間隔層
710‧‧‧頂蓋層
720‧‧‧硬遮罩層
730‧‧‧介電材料
800‧‧‧記憶結構
810‧‧‧記憶層
820‧‧‧通道層
830‧‧‧絕緣材料
910‧‧‧第一切槽
920‧‧‧第二切槽
2A-2A’、2B-2B’、2C-2C’、6A-6A’、6B-6B’、7A-7A’、7B-7B’、8A-8A’、8B-8B’、8C-8C’、9A-9A’、9B-9B’、10A-10A’、10B-10B’、10C-10C’、11A-11A’、11B-11B’、11C-11C’、12A-12A’、12B-12B’、13~13A‧‧‧剖面線
D1、D2‧‧‧距離
D3‧‧‧寬度
H‧‧‧水平延伸區
V‧‧‧垂直延伸區10, 20‧‧‧ semiconductor structure
100‧‧‧Substrate
100a‧‧‧ upper surface
100b‧‧‧ bottom
100s‧‧‧ side wall
100t, 6300‧‧‧ grooves
200, 5200‧‧‧ stacked structure
210‧‧‧ Conductive layer
220‧‧‧Insulation
230‧‧‧Material layer
240‧‧ ‧ vacancies
300‧‧‧etch barrier structure
300'‧‧‧etch block
310‧‧‧First side wall
320‧‧‧ second side wall
330‧‧‧ bottom surface
400‧‧‧Dielectric structure
410‧‧‧First fill grooving
420‧‧‧Second fill grooving
510, 520‧ ‧ contact plug
600‧‧‧Oxide spacer
710‧‧‧Top cover
720‧‧‧hard mask layer
730‧‧‧ dielectric materials
800‧‧‧ memory structure
810‧‧‧ memory layer
820‧‧‧channel layer
830‧‧‧Insulation materials
910‧‧‧first slot
920‧‧‧Second slot
2A-2A', 2B-2B', 2C-2C', 6A-6A', 6B-6B', 7A-7A', 7B-7B', 8A-8A', 8B-8B', 8C-8C', 9A-9A', 9B-9B', 10A-10A', 10B-10B', 10C-10C', 11A-11A', 11B-11B', 11C-11C', 12A-12A', 12B-12B', 13~13A‧‧‧ hatching
D1, D2‧‧‧ distance
D3‧‧‧Width
H‧‧‧ horizontal extension
V‧‧‧ vertical extension
第1圖繪示本揭露內容之一實施例之半導體結構之上視圖。
第1A圖繪示本揭露內容之另一實施例之半導體結構之上視圖。
第2A圖繪示沿第1圖之剖面線2A-2A’之剖面示意圖。
第2B圖繪示沿第1圖之剖面線2B-2B’之剖面示意圖。
第2C圖繪示沿第1圖之剖面線2C-2C’之剖面示意圖。
第3圖~第13A圖繪示依照本發明之一實施例之一種半導體結構之製造方法示意圖。
1 is a top view of a semiconductor structure in accordance with an embodiment of the present disclosure.
FIG. 1A is a top view of a semiconductor structure of another embodiment of the present disclosure.
Fig. 2A is a schematic cross-sectional view taken along line 2A-2A' of Fig. 1.
2B is a schematic cross-sectional view taken along line 2B-2B' of FIG. 1.
Fig. 2C is a schematic cross-sectional view taken along line 2C-2C' of Fig. 1.
3 to 13A are schematic views showing a method of fabricating a semiconductor structure in accordance with an embodiment of the present invention.
在此揭露內容之實施例中,係提出一種半導體結構及其製造方法。實施例中,半導體結構中,垂直延伸區中的導電層形成於蝕刻阻擋結構上,使得垂直延伸的導電層可以獲得蝕刻阻擋結構所提供的良好的支撐,以提供堆疊結構和接觸插塞之間良好且穩定的電性接觸。然而,實施例僅用以作為範例說明,並不會限縮本發明欲保護之範圍。此外,實施例中之圖式係省略部份要之元件,以清楚顯示本發明之技術特點。In the embodiments disclosed herein, a semiconductor structure and a method of fabricating the same are presented. In an embodiment, in the semiconductor structure, the conductive layer in the vertical extension region is formed on the etch barrier structure such that the vertically extending conductive layer can obtain good support provided by the etch barrier structure to provide a structure between the stacked structure and the contact plug. Good and stable electrical contact. However, the examples are for illustrative purposes only and are not intended to limit the scope of the invention. In addition, the drawings in the embodiments are omitted in order to clearly show the technical features of the present invention.
請參照第1、2A~2C圖,第1圖繪示本揭露內容之一實施例之半導體結構10之上視圖,第2A圖繪示沿第1圖之剖面線2A-2A’之剖面示意圖,第2B圖繪示沿第1圖之剖面線2B-2B’之剖面示意圖,第2C圖繪示沿第1圖之剖面線2C-2C’之剖面示意圖。實施例中,半導體結構10例如是三維記憶裝置的主要結構。Please refer to FIG. 1 , 2A to 2C , FIG. 1 is a top view of the semiconductor structure 10 according to an embodiment of the disclosure, and FIG. 2A is a cross-sectional view along the line 2A-2A′ of FIG. 1 . 2B is a cross-sectional view taken along line 2B-2B' of FIG. 1, and FIG. 2C is a cross-sectional view taken along line 2C-2C' of FIG. 1. In the embodiment, the semiconductor structure 10 is, for example, the main structure of a three-dimensional memory device.
如第1、2A~2C圖所示,半導體結構10包括一基板100、一堆疊結構200、複數個記憶結構800、一蝕刻阻擋結構(etching stop structure)300以及一第一填充切槽(filled slit groove)410。基板100具有一凹槽(trench)100t(請同時參照第3圖)。堆疊結構200具有一水平延伸區H及一垂直延伸區V,垂直延伸區V沿凹槽100t之一側壁100s延伸,堆疊結構200包括複數個導電層210和複數個絕緣層220,導電層210和絕緣層220交錯設置(interlaced)堆疊於凹槽100t中。記憶結構800垂直穿過堆疊結構200之水平延伸區H中的導電層210和絕緣層220。蝕刻阻擋結構300形成於堆疊結構200之垂直延伸區V中。第一填充切槽410形成於堆疊結構200中,垂直延伸區V中之導電層210和絕緣層220形成於蝕刻阻擋結構300上且位於蝕刻阻擋結構300和第一填充切槽410之間。As shown in FIGS. 1 and 2A-2C, the semiconductor structure 10 includes a substrate 100, a stacked structure 200, a plurality of memory structures 800, an etching stop structure 300, and a first filled trench. Groove) 410. The substrate 100 has a trench 100t (please refer to FIG. 3 at the same time). The stacked structure 200 has a horizontal extension H and a vertical extension V. The vertical extension V extends along one sidewall 100s of the recess 100t. The stacked structure 200 includes a plurality of conductive layers 210 and a plurality of insulating layers 220, and a conductive layer 210 and The insulating layers 220 are interlaced and stacked in the recess 100t. The memory structure 800 passes vertically through the conductive layer 210 and the insulating layer 220 in the horizontal extension H of the stacked structure 200. The etch stop structure 300 is formed in the vertical extension V of the stacked structure 200. The first filling grooving 410 is formed in the stacked structure 200, and the conductive layer 210 and the insulating layer 220 in the vertical extending region V are formed on the etch barrier structure 300 and between the etch barrier structure 300 and the first filling grooving 410.
實施例中,垂直延伸區V中的導電層210和絕緣層220形成於蝕刻阻擋結構300上且位於蝕刻阻擋結構300和第一填充切槽410之間,使得沿Z方向垂直延伸的導電層210可以獲得蝕刻阻擋結構300所提供的良好的支撐,導電層210不會變形或垮掉,以提供堆疊結構200和接觸插塞之間良好且穩定的電性接觸。In an embodiment, the conductive layer 210 and the insulating layer 220 in the vertical extension V are formed on the etch barrier structure 300 and between the etch barrier structure 300 and the first fill scribe 410 such that the conductive layer 210 extends vertically in the Z direction. Good support provided by the etch stop structure 300 can be obtained without the conductive layer 210 being deformed or bounced to provide good and stable electrical contact between the stacked structure 200 and the contact plug.
實施例中,第1、2A~2C圖所示,半導體結構10更可選擇性地包括一氧化物間隔層(oxide spacer)600。氧化物間隔層600位於堆疊結構200和凹槽100t的側壁100s之間,且位於蝕刻阻擋結構300之一第一側壁310和凹槽100t的側壁100s之間。In the embodiment, as shown in FIGS. 1A and 2A-2C, the semiconductor structure 10 more selectively includes an oxide spacer 600. The oxide spacer layer 600 is located between the stacked structure 200 and the sidewall 100s of the recess 100t and is located between the first sidewall 310 of one of the etch barrier structures 300 and the sidewall 100s of the recess 100t.
另一實施例中,半導體結構10可不包括氧化物間隔層(未繪示於圖中),而蝕刻阻擋結構300的第一側壁310鄰接凹槽100t的側壁100s。換言之,蝕刻阻擋結構300可延伸至並接觸凹槽100t的側壁100s。In another embodiment, the semiconductor structure 10 may not include an oxide spacer layer (not shown), and the first sidewall 310 of the etch barrier structure 300 abuts the sidewall 100s of the recess 100t. In other words, the etch stop structure 300 can extend to and contact the sidewall 100s of the recess 100t.
實施例中,第1、2B~2C圖所示,蝕刻阻擋結構300之一第二側壁320可位於堆疊結構200之水平延伸區H中。In the embodiment, as shown in FIGS. 1B and 2B-2C, one of the second sidewalls 320 of the etch barrier structure 300 may be located in the horizontal extension H of the stacked structure 200.
實施例中,第1、2B~2C圖所示,蝕刻阻擋結構300之一底表面330可直接接觸凹槽100t之一底面100b。In the embodiment, as shown in the first, second, and second embodiments, the bottom surface 330 of the etch barrier structure 300 can directly contact one of the bottom surfaces 100b of the recess 100t.
換言之,蝕刻阻擋結構300可覆蓋堆疊結構200的垂直延伸區V沿X-Z方向的剖面,位於蝕刻阻擋結構300沿Y方向兩側的導電層210藉由蝕刻阻擋結構300而分隔開來。In other words, the etch stop structure 300 may cover a cross section of the vertical extension V of the stacked structure 200 in the X-Z direction, and the conductive layers 210 on both sides of the etch barrier structure 300 in the Y direction are separated by the etch barrier structure 300.
實施例中,如第1圖所示,蝕刻阻擋結構300和第一填充切槽410之間相隔的距離D1例如係20~200奈米(nm)。實施例中,記憶結構800的剖面寬度例如是5~100奈米。In the embodiment, as shown in FIG. 1, the distance D1 between the etching stopper structure 300 and the first filling slit 410 is, for example, 20 to 200 nanometers (nm). In the embodiment, the cross-sectional width of the memory structure 800 is, for example, 5 to 100 nm.
實施例中,如第2A~2C圖所示,半導體結構10更可包括一介電結構400和複數個接觸插塞510/520。介電結構400位於基板100和堆疊結構200上。接觸插塞510/520形成於介電結構400之中,其中每一個接觸插塞510/520分別電性連接至堆疊結構200之垂直延伸區V中的每一個對應的導電層210。In an embodiment, as shown in FIGS. 2A-2C, the semiconductor structure 10 further includes a dielectric structure 400 and a plurality of contact plugs 510/520. The dielectric structure 400 is located on the substrate 100 and the stacked structure 200. Contact plugs 510 / 520 are formed in the dielectric structure 400 , wherein each of the contact plugs 510 / 520 is electrically connected to each of the corresponding conductive layers 210 of the vertical extensions V of the stacked structure 200, respectively.
實施例中,如第1圖所示,半導體結構10更可包括一第二填充切槽420。第二填充切槽420形成於堆疊結構200中,蝕刻阻擋結構300位於第一填充切槽410和第二填充切槽420之間。實施例中,蝕刻阻擋結構300和第二填充切槽420之間相隔的距離D2例如係20~200奈米。In an embodiment, as shown in FIG. 1 , the semiconductor structure 10 further includes a second filling slot 420 . A second fill sipe 420 is formed in the stack structure 200 between the first fill nip 410 and the second fill nip 420. In the embodiment, the distance D2 between the etching stopper structure 300 and the second filling slot 420 is, for example, 20 to 200 nm.
一實施例中,第一填充切槽410和第二填充切槽420可分別包括一絕緣層和一導電填充物,其中絕緣層形成於一切槽的表面上,導電填充物形成於此絕緣層上並填充此切槽。實施例中,絕緣層例如是氧化矽層,導電填充物例如是氮化鈦(TiN)及鎢,其中氮化鈦層形成於絕緣層上,而鎢形成於氮化鈦層上並填充此切槽。另一實施例中,第一填充切槽410和第二填充切槽420可分別包括一絕緣填充物。實施例中,第一填充切槽410和第二填充切槽420之間的距離例如是約1000微米。In one embodiment, the first filling slot 410 and the second filling slot 420 may respectively include an insulating layer and a conductive filler, wherein the insulating layer is formed on the surface of all the slots, and the conductive filler is formed on the insulating layer. And fill this slot. In an embodiment, the insulating layer is, for example, a tantalum oxide layer, and the conductive filler is, for example, titanium nitride (TiN) and tungsten, wherein a titanium nitride layer is formed on the insulating layer, and tungsten is formed on the titanium nitride layer and fills the cut. groove. In another embodiment, the first filling slot 410 and the second filling slot 420 can each include an insulating filler. In an embodiment, the distance between the first fill slot 410 and the second fill slot 420 is, for example, about 1000 microns.
實施例中,堆疊結構200的垂直延伸區V中之導電層210和絕緣層220更位於蝕刻阻擋結構300和第二填充切槽420之間。In an embodiment, the conductive layer 210 and the insulating layer 220 in the vertical extension V of the stacked structure 200 are further located between the etch stop structure 300 and the second fill scribe 420.
實施例中,垂直延伸區V中的導電層210和絕緣層220形成於蝕刻阻擋結構300上並直接接觸蝕刻阻擋結構300,因此即使導電層210和絕緣層220沿Z方向垂直延伸且沿X方向具有很小的厚度,仍可以獲得蝕刻阻擋結構300所提供的良好的支撐,導電層210不會變形或垮掉,以提供堆疊結構200和接觸插塞510/520之間良好且穩定的電性接觸,進而提高半導體結構10的穩定性。In the embodiment, the conductive layer 210 and the insulating layer 220 in the vertical extension region V are formed on the etch barrier structure 300 and directly contact the etch barrier structure 300, so even if the conductive layer 210 and the insulating layer 220 extend vertically in the Z direction and along the X direction With a very small thickness, good support provided by the etch stop structure 300 can still be obtained, and the conductive layer 210 is not deformed or bounced to provide good and stable electrical properties between the stacked structure 200 and the contact plugs 510/520. Contact, thereby improving the stability of the semiconductor structure 10.
實施例中,堆疊結構200的水平延伸區H中的導電層210可包括多晶矽、鎢、或前述兩者之組合,堆疊結構200的垂直延伸區V中的導電層210可包括鎢。垂直延伸區V中的導電層210電性連接至接觸插塞510/520,而鎢的阻值小於多晶矽的阻值,如此一來,垂直延伸區V中的導電層210包括鎢可以大幅降低堆疊結構的電性接觸端(pickup region)的阻值。In an embodiment, the conductive layer 210 in the horizontal extension H of the stacked structure 200 may include polysilicon, tungsten, or a combination of the two, and the conductive layer 210 in the vertical extension V of the stacked structure 200 may include tungsten. The conductive layer 210 in the vertical extension V is electrically connected to the contact plugs 510/520, and the resistance of the tungsten is less than the resistance of the polysilicon, so that the conductive layer 210 in the vertical extension V includes tungsten to greatly reduce the stacking. The resistance of the electrical pickup region of the structure.
實施例中,半導體結構例如是一三維記憶裝置的主要結構,導電層210例如是字元線。In an embodiment, the semiconductor structure is, for example, the main structure of a three-dimensional memory device, and the conductive layer 210 is, for example, a word line.
第1A圖繪示本揭露內容之另一實施例之半導體結構20之上視圖。本實施例中與前述實施例相同或相似之元件係沿用同樣或相似的元件標號,且相同或相似元件之相關說明請參考前述,在此不再贅述。FIG. 1A is a top view of a semiconductor structure 20 of another embodiment of the present disclosure. The same or similar components as those of the above-mentioned embodiments are denoted by the same or similar components, and the related descriptions of the same or similar components are referred to the foregoing, and are not described herein again.
如第1A圖所示,實施例中,蝕刻阻擋結構300可包括複數個蝕刻阻擋塊(etching stop block)300’。此些蝕刻阻擋塊300’中,最靠近第一填充切槽410的一個蝕刻阻擋塊300’和第一填充切槽410之間相隔的距離D1例如係20~200奈米,最靠近第二填充切槽420的一個蝕刻阻擋塊300’和第二填充切槽420之間相隔的距離D2例如係20~200奈米。As shown in FIG. 1A, in an embodiment, the etch stop structure 300 can include a plurality of etch stop blocks 300'. In the etch stop block 300', the distance D1 between the etch stop block 300' closest to the first fill grooving 410 and the first fill grooving 410 is, for example, 20 to 200 nm, closest to the second fill. The distance D2 between the etch stop block 300' of the grooving 420 and the second fill grooving 420 is, for example, 20 to 200 nm.
第3圖~第12A圖繪示依照本發明之一實施例之一種半導體結構之製造方法示意圖。3 to 12A are schematic views showing a method of fabricating a semiconductor structure in accordance with an embodiment of the present invention.
如第3圖所示,提供具有凹槽100t的基板100。實施例中,例如進行一蝕刻製程以形成凹槽100t於基板100中。實施例中,可選擇性地形成氧化物間隔層600在凹槽100t的側壁100s上。As shown in FIG. 3, a substrate 100 having a groove 100t is provided. In an embodiment, for example, an etching process is performed to form the recess 100t in the substrate 100. In an embodiment, the oxide spacer layer 600 can be selectively formed on the sidewall 100s of the recess 100t.
如第4~5圖所示,形成堆疊結構於凹槽100t中。實施例中,形成堆疊結構於凹槽100t中的製造方法例如包括以下步驟。As shown in FIGS. 4 to 5, a stacked structure is formed in the recess 100t. In the embodiment, the manufacturing method of forming the stacked structure in the recess 100t includes, for example, the following steps.
如第4圖所示,可形成複數個材料層230和複數個絕緣層220,材料層230和絕緣層220交錯設置堆疊於凹槽100t中和基板100上。實施例中,材料層230可以是導電材料層或是犧牲層。導電材料層例如包括多晶矽,犧牲層例如包括氮化矽(SiN)、氮氧化矽(SiON)、氮碳化矽(SiCN)或上述之任意組合。本實施例中,絕緣層220係為氧化矽,而材料層230例如是犧牲層,其材質係為氮化矽。As shown in FIG. 4, a plurality of material layers 230 and a plurality of insulating layers 220 may be formed, and the material layer 230 and the insulating layer 220 are alternately stacked in the recess 100t and on the substrate 100. In an embodiment, the material layer 230 may be a conductive material layer or a sacrificial layer. The conductive material layer includes, for example, polycrystalline germanium, and the sacrificial layer includes, for example, tantalum nitride (SiN), cerium oxynitride (SiON), lanthanum oxynitride (SiCN), or any combination thereof. In this embodiment, the insulating layer 220 is tantalum oxide, and the material layer 230 is, for example, a sacrificial layer, and the material thereof is tantalum nitride.
如第5圖所示,平坦化材料層230和絕緣層220,使得材料層230和絕緣層220與基板100之上表面100a共表面,接著形成介電材料730於材料層230和絕緣層220上,並形成頂蓋層(cap layer)710以及硬遮罩層720於平坦化的材料層230、絕緣層220及基板100之上表面100a上。實施例中,頂蓋層710例如是氧化矽層,硬遮罩層720例如是氮化矽層。至此,形成如第5圖所示的堆疊結構5200,堆疊結構5200具有水平延伸區H及垂直延伸區V,垂直延伸區V沿凹槽100t之側壁100s延伸,材料層230和絕緣層220交錯設置堆疊於凹槽100t中。於後續步驟中將材料層230置換為導電材料後,則形成堆疊結構200。As shown in FIG. 5, the material layer 230 and the insulating layer 220 are planarized such that the material layer 230 and the insulating layer 220 are coplanar with the upper surface 100a of the substrate 100, and then a dielectric material 730 is formed on the material layer 230 and the insulating layer 220. And forming a cap layer 710 and a hard mask layer 720 on the planarized material layer 230, the insulating layer 220, and the upper surface 100a of the substrate 100. In an embodiment, the cap layer 710 is, for example, a hafnium oxide layer, and the hard mask layer 720 is, for example, a tantalum nitride layer. So far, the stacked structure 5200 is formed as shown in FIG. 5, the stacked structure 5200 has a horizontal extension H and a vertical extension V, and the vertical extension V extends along the sidewall 100s of the groove 100t, and the material layer 230 and the insulation layer 220 are alternately arranged. Stacked in the groove 100t. After the material layer 230 is replaced with a conductive material in a subsequent step, the stacked structure 200 is formed.
如第6~7B圖所示,形成蝕刻阻擋結構300於堆疊結構5200之垂直延伸區V中。形成蝕刻阻擋結構300的製造方法例如包括以下步驟。As shown in FIGS. 6-7B, an etch stop structure 300 is formed in the vertical extension V of the stacked structure 5200. The manufacturing method of forming the etching stopper structure 300 includes, for example, the following steps.
第6A圖繪示沿第6圖之剖面線6A-6A’之剖面示意圖,第6B圖繪示沿第6圖之剖面線6B-6B’之剖面示意圖。如第6~6B圖所示,形成一凹槽6300於堆疊結構5200之垂直延伸區V中。實施例中,例如以一蝕刻製程形成凹槽6300,此蝕刻製程對於材料層230和絕緣層220不具有選擇比。Fig. 6A is a cross-sectional view taken along line 6A-6A' of Fig. 6, and Fig. 6B is a cross-sectional view taken along line 6B-6B' of Fig. 6. As shown in FIGS. 6-6B, a recess 6300 is formed in the vertical extension V of the stacked structure 5200. In an embodiment, the recess 6300 is formed, for example, by an etching process that does not have a selection ratio for the material layer 230 and the insulating layer 220.
如第6和6B圖所示,實施例中,凹槽6300的一端可延伸至氧化物間隔層600,而凹槽6300的另一端可延伸至水平延伸區H中。另一實施例中,凹槽6300的一端甚至可以延伸至暴露出凹槽100t的側壁100s(未繪示於圖中)。再者,實施例中,凹槽6300的底部可暴露出凹槽100t之底面100b。As shown in Figures 6 and 6B, in an embodiment, one end of the recess 6300 can extend to the oxide spacer layer 600, and the other end of the recess 6300 can extend into the horizontal extension H. In another embodiment, one end of the recess 6300 may even extend to the side wall 100s (not shown) that exposes the recess 100t. Moreover, in the embodiment, the bottom of the recess 6300 may expose the bottom surface 100b of the recess 100t.
第7A圖繪示沿第7圖之剖面線7A-7A’之剖面示意圖,第7B圖繪示沿第7圖之剖面線7B-7B’之剖面示意圖。如第7~7B圖所示,填入蝕刻阻擋材料於凹槽6300中以形成蝕刻阻擋結構300。填入蝕刻阻擋材料後,更可進行一化學機械研磨製程以平坦化蝕刻阻擋結構300的表面。Fig. 7A is a cross-sectional view taken along line 7A-7A' of Fig. 7, and Fig. 7B is a cross-sectional view taken along line 7B-7B' of Fig. 7. As shown in FIGS. 7-7B, an etch stop material is filled in the recess 6300 to form an etch stop structure 300. After filling the etch stop material, a CMP process can be performed to planarize the surface of the etch stop structure 300.
第8A圖繪示沿第8圖之剖面線8A-8A’之剖面示意圖,第8B圖繪示沿第8圖之剖面線8B-8B’之剖面示意圖,第8C圖繪示沿第8圖之剖面線8C-8C’之剖面示意圖。如第8~8C圖所示,形成記憶結構800。於此步驟中,此些記憶結構800垂直穿過堆疊結構5200的水平延伸區H中的材料層230和絕緣層220。於後續步驟中將材料層230置換為導電材料後,則此些記憶結構800垂直穿過堆疊結構200的水平延伸區H中的導電層210和絕緣層220。8A is a cross-sectional view taken along line 8A-8A' of FIG. 8, FIG. 8B is a cross-sectional view taken along line 8B-8B' of FIG. 8, and FIG. 8C is a view along line 8. A schematic cross-sectional view of section line 8C-8C'. As shown in Figs. 8-8C, a memory structure 800 is formed. In this step, the memory structures 800 pass vertically through the material layer 230 and the insulating layer 220 in the horizontal extension H of the stacked structure 5200. After the material layer 230 is replaced with a conductive material in a subsequent step, the memory structures 800 are vertically passed through the conductive layer 210 and the insulating layer 220 in the horizontal extension H of the stacked structure 200.
如第8~8C圖所示,形成記憶結構800的製造方法例如包括以下步驟。先以蝕刻製程形成複數個貫穿開口(through opening),此些貫穿開口垂直穿過堆疊結構5200的水平延伸區H中的材料層230和絕緣層220,且此蝕刻製程對於材料層230和絕緣層220不具有選擇比。接著形成記憶層810於貫穿開口的側壁上,接著形成通道層820於記憶層810上,再填入絕緣材料830於貫穿開口中的通道層820上。實施例中,如第8C圖所示,貫穿開口垂直向下延伸至基板100中。另一實施例中,貫穿開口亦可垂直向下延伸並停止於基板100的表面(未繪示於圖中)。As shown in FIGS. 8 to 8C, the method of manufacturing the memory structure 800 includes, for example, the following steps. First, a plurality of through openings are formed by an etching process, and the through openings vertically pass through the material layer 230 and the insulating layer 220 in the horizontal extension H of the stacked structure 5200, and the etching process is performed on the material layer 230 and the insulating layer. 220 does not have a selection ratio. A memory layer 810 is then formed over the sidewalls of the through opening, and then a channel layer 820 is formed over the memory layer 810, and an insulating material 830 is then filled over the channel layer 820 in the through opening. In the embodiment, as shown in FIG. 8C, the through opening extends vertically downward into the substrate 100. In another embodiment, the through opening may also extend vertically downward and stop on the surface of the substrate 100 (not shown).
實施例中,記憶層810例如是氧化矽-氮化矽-氧化矽(oxide-nitride-oxide,ONO)之複合層、氧化矽-氮化矽-氧化矽-氮化矽-氧化矽(oxide-nitride-oxide-nitride-oxide,ONONO)之複合層或氧化矽-氮化矽-氧化矽-氮化矽-氧化矽-氮化矽-氧化矽(oxide-nitride-oxide-nitride-oxide-nitride-oxide,ONONONO)之複合層,但不以此為限。通道層820例如是無摻雜的多晶矽。絕緣材料830例如是氧化矽、氮化矽、或其他適合的介電材料。In an embodiment, the memory layer 810 is, for example, a composite layer of oxide-nitride-oxide (ONO), yttrium-rhenium nitride-ytterbium oxide-yttria-yttrium oxide-oxide (oxide- Nitride-oxide-nitride-oxide, ONONO) composite layer or yttrium oxide-yttria-yttria-yttria-oxide-nitride-oxide-nitride- Oxide, ONONONO) composite layer, but not limited to this. Channel layer 820 is, for example, an undoped polysilicon. Insulating material 830 is, for example, tantalum oxide, tantalum nitride, or other suitable dielectric material.
一實施例中,記憶結構800可以全部形成於水平延伸區H中(未繪示於圖中)。一實施例中,如第8C圖所示,一些記憶結構800可以形成於蝕刻阻擋結構300中。In one embodiment, the memory structure 800 can all be formed in the horizontal extension H (not shown). In one embodiment, as shown in FIG. 8C, some memory structures 800 may be formed in the etch stop structure 300.
如第9~12B圖所示,形成第一填充切槽410於堆疊結構200中,其中垂直延伸區V中之導電層210和絕緣層220位於蝕刻阻擋結構300和第一填充切槽410之間。實施例中,如第9~12B圖所示,更可形成第二填充切槽420於堆疊結構200中,其中蝕刻阻擋結構300位於第一填充切槽410和第二填充切槽420之間。形成第一填充切槽410、第二填充切槽420和堆疊結構200之導電層210的製造方法例如包括以下步驟。As shown in FIGS. 9-12B, a first fill trench 410 is formed in the stacked structure 200, wherein the conductive layer 210 and the insulating layer 220 in the vertical extension V are located between the etch stop structure 300 and the first fill trench 410. . In the embodiment, as shown in FIGS. 9-12B, a second filling slot 420 may be formed in the stack structure 200, wherein the etch barrier structure 300 is located between the first filling slot 410 and the second filling slot 420. The manufacturing method of forming the first filling slit 410, the second filling slit 420, and the conductive layer 210 of the stacked structure 200 includes, for example, the following steps.
第9A圖繪示沿第9圖之剖面線9A-9A’之剖面示意圖,第9B圖繪示沿第9圖之剖面線9B-9B’之剖面示意圖。如第9~9B圖所示,形成一第一切槽910和一第二切槽920於堆疊結構5200中,第一切槽910和第二切槽920穿過堆疊結構5200的垂直延伸區V和水平延伸區H中的材料層230和絕緣層220。實施例中,例如是以一蝕刻製程形成第一切槽910和第二切槽920,且此蝕刻製程對於材料層230和絕緣層220不具有選擇比。Fig. 9A is a cross-sectional view taken along line 9A-9A' of Fig. 9, and Fig. 9B is a cross-sectional view taken along line 9B-9B' of Fig. 9. As shown in FIGS. 9-9B, a first slot 910 and a second slot 920 are formed in the stack structure 5200. The first slot 910 and the second slot 920 pass through the vertical extension of the stack structure 5200. And a material layer 230 and an insulating layer 220 in the horizontal extension H. In the embodiment, the first slit 910 and the second slit 920 are formed, for example, by an etching process, and the etching process does not have a selection ratio for the material layer 230 and the insulating layer 220.
第10A圖繪示沿第10圖之剖面線10A-10A’之剖面示意圖,第10B圖繪示沿第10圖之剖面線10B-10B’之剖面示意圖,第10C圖繪示沿第10圖之剖面線10C-10C’之剖面示意圖。如第10~10C圖所示,移除垂直延伸區V中的材料層230。10A is a cross-sectional view taken along line 10A-10A' of FIG. 10, FIG. 10B is a cross-sectional view taken along line 10B-10B' of FIG. 10, and FIG. 10C is a view along line 10 A schematic cross-sectional view of section line 10C-10C'. As shown in FIGS. 10-10C, the material layer 230 in the vertical extension V is removed.
如第10~10C圖所示,本實施例中,材料層230例如是犧牲層,以磷酸(H 3PO 4)溶液作為蝕刻液,磷酸溶液通過第一切槽910和第二切槽920而將垂直延伸區V和水平延伸區H中的材料層230移除而形成空位240。同時,蝕刻液亦可以將硬遮罩層720一併移除。 As shown in FIGS. 10-10C, in the present embodiment, the material layer 230 is, for example, a sacrificial layer, and a phosphoric acid (H 3 PO 4 ) solution is used as an etching solution, and the phosphoric acid solution passes through the first slit 910 and the second slit 920. The material layer 230 in the vertical extension V and the horizontal extension H is removed to form a vacancy 240. At the same time, the etching solution can also remove the hard mask layer 720.
如第10~10C圖所示,由於水平延伸區H沿Y方向的寬度D3可以很長,例如是約1000微米(μm),因此需經由蝕刻液的過蝕刻(over etching),而能夠將水平延伸區H中位於第一切槽910和第二切槽920之間的所有材料層230(犧牲層)均移除。此步驟中,由於垂直的記憶結構800穿過水平延伸區H,一層一層被空位240間隔開來的絕緣層220可以經由垂直的記憶結構800而得到支撐,經由第一切槽910和第二切槽920導入蝕刻液進行過蝕刻而可以把所有材料層230都蝕刻掉,而被空位240間隔開來的絕緣層220卻可以經由多個垂直的記憶結構800支撐住而不會垮掉。As shown in FIGS. 10 to 10C, since the width D3 of the horizontal extension H in the Y direction can be long, for example, about 1000 micrometers (μm), it is necessary to pass the etching of the etching liquid to enable the level. All of the material layers 230 (sacrificial layers) in the extension H located between the first slit 910 and the second slit 920 are removed. In this step, since the vertical memory structure 800 passes through the horizontal extension H, the insulating layer 220 layered by the vacancies 240 may be supported via the vertical memory structure 800, via the first slot 910 and the second slice. The trench 920 is etched into the etchant to etch away all of the material layers 230, while the insulating layer 220, which is spaced apart by the vacancies 240, can be supported via a plurality of vertical memory structures 800 without collapse.
如第10~10C圖所示,相較於水平延伸區H沿Y方向的寬度D3,垂直延伸區V中的蝕刻阻擋結構300和第一切槽910以及第二切槽920之間的距離D1和D2相對而言短得多,例如約20~200奈米。相較於沒有設置蝕刻阻擋結構300的情況,當垂直延伸區V中垂直延伸的材料層230被移除,則剩下被空位240間隔開來的垂直延伸的絕緣層220很容易變形或垮掉。根據本揭露內容之實施例,由於距離D1和D2相對而言較短,因此經由蝕刻液的過蝕刻可以輕易地完全移除垂直延伸區V中的材料層230並且停止於蝕刻阻擋結構300;再者,間隔開來的絕緣層220垂直延伸且形成於蝕刻阻擋結構300上,也就是說,絕緣層220直接接觸蝕刻阻擋結構300,因此絕緣層220可以獲得蝕刻阻擋結構300所提供的良好的支撐,不會變形或垮掉,進而穩定住製程中的整個結構體。As shown in FIGS. 10-10C, the distance D1 between the etch stop structure 300 in the vertical extension V and the first slot 910 and the second slot 920 is compared to the width D3 of the horizontal extension H in the Y direction. It is much shorter than D2, for example, about 20~200 nm. Compared to the case where the etch stop structure 300 is not provided, when the material layer 230 vertically extending in the vertical extension V is removed, the vertically extending insulating layer 220 separated by the vacancies 240 is easily deformed or collapsed. . According to an embodiment of the present disclosure, since the distances D1 and D2 are relatively short, the material layer 230 in the vertical extension V can be easily completely removed by over-etching of the etching solution and stopped at the etching stopper structure 300; The spaced apart insulating layer 220 extends vertically and is formed on the etch barrier structure 300, that is, the insulating layer 220 directly contacts the etch barrier structure 300, so the insulating layer 220 can obtain good support provided by the etch stop structure 300. , will not deform or collapse, and thus stabilize the entire structure in the process.
另一實施例中,材料層230例如是導電材料層,例如包括多晶矽,則亦可以調整蝕刻液的過蝕刻程度,僅完全移除垂直延伸區V中的材料層230並且停止於蝕刻阻擋結構300,而僅部分移除水平延伸區H中鄰接第一切槽910以及第二切槽920的部分材料層230(未繪示於圖中)。如此一來,垂直延伸區V的絕緣層220仍然可以獲得蝕刻阻擋結構300所提供的良好的支撐,不會變形或垮掉,而可以穩定住製程中的整個結構體。In another embodiment, the material layer 230 is, for example, a layer of conductive material, for example, including polysilicon, and the degree of overetching of the etchant can also be adjusted to completely remove the material layer 230 in the vertical extension V and stop at the etch stop structure 300. Only a portion of the material layer 230 (not shown) adjacent to the first slot 910 and the second slot 920 in the horizontal extension H is partially removed. As a result, the insulating layer 220 of the vertical extension region V can still obtain good support provided by the etch barrier structure 300 without being deformed or smashed, and can stabilize the entire structure in the process.
第11A圖繪示沿第11圖之剖面線11A-11A’之剖面示意圖,第11B圖繪示沿第11圖之剖面線11B-11B’之剖面示意圖,第11C圖繪示沿第11圖之剖面線11C-11C’之剖面示意圖。如第11~11C圖所示,形成導電層210。11A is a cross-sectional view taken along line 11A-11A' of FIG. 11, FIG. 11B is a cross-sectional view taken along line 11B-11B' of FIG. 11, and FIG. 11C is a view along line 11 A schematic cross-sectional view of section line 11C-11C'. As shown in FIGS. 11 to 11C, the conductive layer 210 is formed.
本實施例中,例如將導電材料通過第一切槽910和第二切槽920填入垂直延伸區V和水平延伸區H中的材料層230移除後的空位240,以形成導電層210。In this embodiment, for example, the conductive material is filled into the vacancies 240 of the material layer 230 in the vertical extension region V and the horizontal extension region H through the first slit 910 and the second slit 920 to form the conductive layer 210.
如第11~11C圖所示,通過第一切槽910和第二切槽920導入導電材料至空位240中。例如,以沈積製程先形成一層高介電常數材料層於空位240中的記憶結構800的外壁、及空位240的內壁上,高介電常數材料層例如可包括氧化鋁(AlO x)或氧化鉿(HfO 2)。接著,形成導電填充物於此高介電常數材料層上並填充空位240。實施例中,導電填充物例如包括氮化鈦及鎢,其中氮化鈦層形成於高介電常數材料層上,而鎢形成於氮化鈦層上並填充空位240。 As shown in FIGS. 11 to 11C, the conductive material is introduced into the vacancies 240 through the first slit 910 and the second slit 920. For example, the deposition process is first formed on an outer wall layer of a high dielectric constant material layer 240 in the configuration space memory 800, and the inner wall of the space 240, the high dielectric constant material layer may comprise, for example, aluminum oxide (AlO x) or oxidation铪 (HfO 2 ). Next, a conductive fill is formed on the high dielectric constant material layer and fills the vacancies 240. In an embodiment, the conductive filler includes, for example, titanium nitride and tungsten, wherein a titanium nitride layer is formed on the high dielectric constant material layer, and tungsten is formed on the titanium nitride layer and fills the vacancy 240.
接著,將一蝕刻液通過第一切槽910和第二切槽920,將從空位240突出至第一切槽910和第二切槽920內的導電填充物移除,而使得填充於不同空位240中的各個導電填充物部分彼此斷開而電性絕緣,而形成導電層210。至此,形成堆疊結構200。Next, an etchant is passed through the first slit 910 and the second slit 920 to remove the conductive filler protruding from the vacancy 240 into the first slit 910 and the second slit 920, so as to be filled in different vacancies. Each of the conductive filler portions in 240 is electrically disconnected from each other to form a conductive layer 210. So far, the stacked structure 200 is formed.
另一實施例中,材料層230例如是導電材料層,例如包括多晶矽,則水平延伸區H中的材料層230並不全部移除,而將導電材料通過第一切槽910和第二切槽920填入垂直延伸區V中的材料層230移除後的形成的空位240。如此一來,填入垂直延伸區V中的空位240的導電材料以及水平延伸區H中的材料層230(導電材料層)形成導電層210。In another embodiment, the material layer 230 is, for example, a conductive material layer, for example, including polysilicon, and the material layer 230 in the horizontal extension H is not completely removed, and the conductive material is passed through the first slit 910 and the second slit. 920 fills in the formed vacancies 240 after the material layer 230 in the vertical extension V is removed. As a result, the conductive material filled in the vacancy 240 in the vertical extension V and the material layer 230 (conductive material layer) in the horizontal extension H form the conductive layer 210.
第12A圖繪示沿第12圖之剖面線12A-12A’之剖面示意圖,第12B圖繪示沿第12圖之剖面線12B-12B’之剖面示意圖。如第12~12B圖所示,形成第一填充切槽410和第二填充切槽420。Fig. 12A is a cross-sectional view taken along line 12A-12A' of Fig. 12, and Fig. 12B is a cross-sectional view taken along line 12B-12B' of Fig. 12. As shown in FIGS. 12 to 12B, a first filling slit 410 and a second filling slit 420 are formed.
一實施例中,例如以沈積製程先形成絕緣層於切槽的表面上,接著形成導電填充物於此絕緣層上並填充切槽。絕緣層可包括二氧化矽(SiO2)、氮化矽(SiN)或低介電常數材料。導電填充物例如包括氮化鈦及鎢,其中氮化鈦層形成於絕緣層上,而鎢形成於氮化鈦層上並填充切槽。In one embodiment, an insulating layer is first formed on the surface of the dicing trench by a deposition process, and then a conductive filler is formed on the insulating layer and filled with the dicing. The insulating layer may include hafnium oxide (SiO2), tantalum nitride (SiN), or a low dielectric constant material. The conductive filler includes, for example, titanium nitride and tungsten, wherein a titanium nitride layer is formed on the insulating layer, and tungsten is formed on the titanium nitride layer and fills the slit.
另一實施例中,例如填入一絕緣填充物於第一切槽910和第二切槽920中以形成第一填充切槽410和第二填充切槽420。In another embodiment, for example, an insulating filler is filled in the first slit 910 and the second slit 920 to form a first filling slit 410 and a second filling slit 420.
實施例中,填入導電填充物或絕緣填充物於第一切槽910和第二切槽920中之後,可進行一化學機械研磨製程以平坦化第一填充切槽410和第二填充切槽420的上表面。In an embodiment, after filling the conductive filler or the insulating filler in the first slit 910 and the second slit 920, a chemical mechanical polishing process may be performed to planarize the first filling slit 410 and the second filling slit. The upper surface of 420.
第13A圖繪示沿第13圖之剖面線13A-13A’之剖面示意圖。如第13~13A圖所示,形成介電結構400於基板100和堆疊結構200上。Fig. 13A is a schematic cross-sectional view along section line 13A-13A' of Fig. 13. As shown in FIGS. 13-13A, a dielectric structure 400 is formed on the substrate 100 and the stacked structure 200.
請參照第1、2A~2C圖,形成接觸插塞510/520於介電結構400之中,其中各個接觸插塞510/520分別電性連接至堆疊結構200之垂直延伸區V中的各個導電層210。舉例而言,位於鄰近第一填充切槽410的接觸插塞510電性連接至奇數條的導電層210,而位於鄰近第二填充切槽420的接觸插塞520電性連接至偶數條的導電層210。如此一來,相較於將所有接觸插塞配置於同一側且同一排的設計,根據本揭露內容之實施例,接觸插塞510/520交錯電性連接至間隔的導電層210可以增大X方向的接觸插塞的節距,降低製程可以產生的錯位誤差。Referring to FIGS. 1 and 2A-2C, a contact plug 510/520 is formed in the dielectric structure 400, wherein each of the contact plugs 510/520 is electrically connected to each of the vertical extensions V of the stacked structure 200. Layer 210. For example, the contact plug 510 located adjacent to the first filling slot 410 is electrically connected to the odd-numbered conductive layer 210, and the contact plug 520 located adjacent to the second filling slot 420 is electrically connected to the even-numbered conductive strips. Layer 210. In this way, according to the embodiment of the present disclosure, the contact plugs 510 / 520 are electrically connected to the spaced conductive layers 210 to increase X, compared to the design in which all the contact plugs are disposed on the same side and in the same row. The pitch of the contact plugs in the direction reduces the misalignment error that can be generated by the process.
依照本發明之另一實施例之半導體結構之製造方法中,請參照第1A圖和第6~7B圖,可形成複數個凹槽6300於堆疊結構5200之垂直延伸區V中,再填入蝕刻阻擋材料於多個凹槽6300中以形成多個蝕刻阻擋結構300’,而形成如第1A圖所示的半導體結構20。In the method of fabricating a semiconductor structure according to another embodiment of the present invention, referring to FIG. 1A and FIGS. 6-7B, a plurality of recesses 6300 may be formed in the vertical extension V of the stacked structure 5200, and then etched. The barrier material is formed in the plurality of recesses 6300 to form a plurality of etch stop structures 300' to form the semiconductor structure 20 as shown in FIG. 1A.
綜上所述,雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明。本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定者為準。In conclusion, the present invention has been disclosed in the above preferred embodiments, and is not intended to limit the present invention. A person skilled in the art can make various changes and modifications without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.
10‧‧‧半導體結構 10‧‧‧Semiconductor structure
300‧‧‧蝕刻阻擋結構 300‧‧‧etch barrier structure
310‧‧‧第一側壁 310‧‧‧First side wall
410‧‧‧第一填充切槽 410‧‧‧First fill grooving
420‧‧‧第二填充切槽 420‧‧‧Second fill grooving
510、520‧‧‧接觸插塞 510, 520‧ ‧ contact plug
800‧‧‧記憶結構 800‧‧‧ memory structure
2A-2A’、2B-2B’、2C-2C’‧‧‧剖面線 2A-2A’, 2B-2B’, 2C-2C’‧‧‧ hatching
D1、D2‧‧‧距離 D1, D2‧‧‧ distance
H‧‧‧水平延伸區 H‧‧‧ horizontal extension
V‧‧‧垂直延伸區 V‧‧‧ vertical extension
Claims (10)
一基板,具有一凹槽(trench);
一堆疊結構,具有一水平延伸區及一垂直延伸區,該垂直延伸區沿該凹槽之一側壁延伸,其中該堆疊結構包括複數個導電層和複數個絕緣層,交錯設置(interlaced)堆疊於該凹槽中;
一蝕刻阻擋結構(etching stop structure),形成於該堆疊結構之該垂直延伸區中;
複數個記憶結構,垂直穿過該堆疊結構之該水平延伸區中的該些導電層和該些絕緣層;以及
一第一填充切槽(filled slit groove),形成於該堆疊結構中,其中該垂直延伸區中之該些導電層和該些絕緣層形成於該蝕刻阻擋結構上且位於該蝕刻阻擋結構和該第一填充切槽之間。
A semiconductor structure comprising:
a substrate having a trench;
a stacked structure having a horizontal extension and a vertical extension extending along a sidewall of the recess, wherein the stacked structure comprises a plurality of conductive layers and a plurality of insulating layers, interlaced on the stack In the groove;
An etching stop structure formed in the vertical extension of the stacked structure;
a plurality of memory structures vertically passing through the conductive layers and the insulating layers in the horizontal extension of the stacked structure; and a first filled slit groove formed in the stacked structure, wherein the memory structure The conductive layers and the insulating layers in the vertical extension are formed on the etch stop structure and between the etch stop structure and the first fill sipe.
The semiconductor structure of claim 1, wherein a first sidewall of the etch barrier structure abuts the sidewall of the recess, and a second sidewall of the etch barrier is located in the horizontal extension of the stack And a bottom surface of the etch barrier structure directly contacts a bottom surface of the recess.
The semiconductor structure of claim 1, wherein the etch barrier structure and the first fill nip are separated by 20 to 200 nanometers (nm).
一第二填充切槽,形成於該堆疊結構中,其中該蝕刻阻擋結構位於該第一填充切槽和該第二填充切槽之間,該垂直延伸區中之該些導電層和該些絕緣層更位於該蝕刻阻擋結構和該第二填充切槽之間。
For example, the semiconductor structure described in claim 1 of the patent scope further includes:
a second filling slot formed in the stack structure, wherein the etch barrier structure is between the first fill trench and the second fill trench, the conductive layers and the insulation in the vertical extension The layer is further between the etch stop structure and the second fill nip.
複數個蝕刻阻擋塊(etching stop block),該些蝕刻阻擋塊中最靠近該第二填充切槽者和該第二填充切槽係相隔20~200奈米。
The semiconductor structure of claim 4, wherein the etch barrier structure comprises:
A plurality of etching stop blocks, wherein the second of the etch stop blocks is closest to the second filling grooving and the second filling grooving system is separated by 20 to 200 nm.
提供一基板,該基板具有一凹槽;
形成一堆疊結構,該堆疊結構具有一水平延伸區及一垂直延伸區,該垂直延伸區沿該凹槽之一側壁延伸,其中該堆疊結構包括複數個導電層和複數個絕緣層,交錯設置(interlaced)堆疊於該凹槽中;
形成一蝕刻阻擋結構於該堆疊結構之該垂直延伸區中;
形成複數個記憶結構,垂直穿過該堆疊結構之該水平延伸區中的該些導電層和該些絕緣層;以及
形成一第一填充切槽於該堆疊結構中,其中該垂直延伸區中之該些導電層和該些絕緣層形成於該蝕刻阻擋結構上且位於該蝕刻阻擋結構和該第一填充切槽之間。
A method of fabricating a semiconductor structure, comprising:
Providing a substrate having a groove;
Forming a stack structure having a horizontal extension region and a vertical extension region extending along a sidewall of the recess, wherein the stack structure comprises a plurality of conductive layers and a plurality of insulating layers, staggered ( Interlaced) stacked in the groove;
Forming an etch stop structure in the vertical extension of the stacked structure;
Forming a plurality of memory structures vertically passing through the conductive layers and the insulating layers in the horizontal extension of the stacked structure; and forming a first filling slit in the stacked structure, wherein the vertical extending region The conductive layers and the insulating layers are formed on the etch stop structure and between the etch stop structure and the first fill dicing.
The method of fabricating a semiconductor structure according to claim 6, wherein a first sidewall of the etch barrier structure abuts the sidewall of the recess, and a second sidewall of the etch barrier is at the level of the stack structure In the extension region, one of the bottom surfaces of the etch barrier structure directly contacts a bottom surface of the recess.
The method of fabricating a semiconductor structure according to claim 6, wherein the etch barrier structure and the first filling grooving system are separated by 20 to 200 nm.
形成一第二填充切槽於該堆疊結構中,其中該蝕刻阻擋結構位於該第一填充切槽和該第二填充切槽之間,該垂直延伸區中之該些導電層和該些絕緣層更位於該蝕刻阻擋結構和該第二填充切槽之間。
The method for manufacturing a semiconductor structure as described in claim 6 further includes:
Forming a second filling slot in the stack structure, wherein the etch barrier structure is between the first filling slot and the second filling slot, the conductive layer and the insulating layer in the vertical extension More between the etch stop structure and the second fill grooving.
形成複數個蝕刻阻擋塊,該些蝕刻阻擋塊中最靠近該第二填充切槽者和該第二填充切槽係相隔20~200奈米。
The method of fabricating a semiconductor structure according to claim 9, wherein the forming the etch barrier structure comprises:
A plurality of etch stop blocks are formed, and the second of the etch stop blocks closest to the second fill sipe and the second fill sipe are separated by 20 to 200 nm.
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