TWI437371B - Illumination optical device, production method of an illumination optical device, adjusting method of an illumination optical device, exposure device and exposure method - Google Patents
Illumination optical device, production method of an illumination optical device, adjusting method of an illumination optical device, exposure device and exposure method Download PDFInfo
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Classifications
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3083—Birefringent or phase retarding elements
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
- G02B27/28—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 for polarising
- G02B27/286—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 for polarising for controlling or changing the state of polarisation, e.g. transforming one polarisation state into another
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/70—Microphotolithographic exposure; Apparatus therefor
- G03F7/70483—Information management; Active and passive control; Testing; Wafer monitoring, e.g. pattern monitoring
- G03F7/7055—Exposure light control in all parts of the microlithographic apparatus, e.g. pulse length control or light interruption
- G03F7/70566—Polarisation control
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- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
Description
本發明涉及一種照明光學裝置,其製造方法,曝光裝置及曝光方法。本發明特別是涉及以微影製程來製造半導體元件,攝影元件,液晶顯示元件,薄膜磁性頭等微型元件所用的曝光裝置。The invention relates to an illumination optical device, a manufacturing method thereof, an exposure device and an exposure method. More particularly, the present invention relates to an exposure apparatus for manufacturing a semiconductor element, a photographic element, a liquid crystal display element, a thin film magnetic head, and the like by a lithography process.
上述典型的曝光裝置中,由光源所射出的光束經由作為光學整合器用的弗利斯(Fries)目鏡而形成二次光源,其係作為多個光源所構成的實質之面光源。由二次光源(通常是照明光學裝置的照明瞳或其近旁所形成的照明瞳分佈)而來的光束經由配置在弗利斯目鏡後側焦點面的近旁之開口光圈而受到限制後入射到聚光透鏡。In the above-described typical exposure apparatus, the light beam emitted from the light source forms a secondary light source via a Fries eyepiece as an optical integrator, and serves as a substantial surface light source composed of a plurality of light sources. The light beam from the secondary light source (usually the illumination pupil of the illumination optics or the illumination pupil formed by the vicinity thereof) is restricted by the aperture aperture disposed near the rear focal plane of the Flis eyepiece, and then incident on the beam. Optical lens.
藉由聚光透鏡所聚光的光束重疊地照射在所定的圖樣(patterns)所形成的光罩上。透過光罩的圖樣後之光經由投影光學系統而成像在晶圓上。因此,光罩圖樣即投影曝光(轉印)在晶圓上。又,光罩上所形成的圖樣屬於高積體化者,其微細的圖樣正確地轉印至晶圓上時在晶圓上可得到均一的照度分佈而不可有缺口。The light beams condensed by the condensing lens are superimposed on the reticle formed by the predetermined patterns. The light passing through the pattern of the reticle is imaged on the wafer via the projection optical system. Therefore, the reticle pattern is projected (transferred) onto the wafer. Further, the pattern formed on the photomask is a highly integrated person, and when the fine pattern is correctly transferred onto the wafer, a uniform illuminance distribution can be obtained on the wafer without being nicked.
例如,在本案申請人所屬之專利第3246615號公報中揭示一種設定技術,其中為了實現任意方向的微細圖樣忠實地轉印時所需的適當的照明條件,則弗利斯目鏡的後側焦點面上須形成環狀的二次光源,通過該環狀的二次光源的光束成為一種以其周圍方向作為偏光方向的直線偏光狀 態(以下簡稱為周圍方向偏光狀態)。For example, a setting technique is disclosed in the patent No. 3246615 to which the present applicant belongs, in which the rear focus surface of the Flis eyepiece is used in order to realize appropriate lighting conditions required for faithful transfer of the fine pattern in an arbitrary direction. A ring-shaped secondary light source is formed, and the light beam passing through the annular secondary light source becomes a linearly polarized light having a circumferential direction as a polarization direction State (hereinafter referred to as the polarization state in the surrounding direction).
【專利文獻1】專利第3246615號公報Patent Document 1 Patent No. 3246615
不限於上述的周圍方向偏光狀態,使用特定的直線偏光狀態的光以進行特定的圖樣的投影曝光時,投影光學系統的解像度可有效地向上提高。又,一般而言,對應於光罩圖樣以使用特定的偏光狀態(以下包含非偏光狀態的廣泛概念)的光來進行投影曝光時,投影光學系統的解像度可有效地向上提高。It is not limited to the above-described peripheral direction polarization state, and when the specific linearly polarized light is used for projection exposure of a specific pattern, the resolution of the projection optical system can be effectively increased upward. Further, in general, when the projection exposure is performed in accordance with the reticle pattern using light of a specific polarization state (hereinafter, a broad concept including a non-polarization state), the resolution of the projection optical system can be effectively increased upward.
然而,即使以所期望的偏光狀態的光來對光罩(甚至晶圓)進行照明時,照明光路中若存在著使光的偏光狀態發生變化的光學元件,則不能以所期望的偏光狀態來成像,進而可能使成像性能惡化。特別是照明光路中所配置的透鏡或平行平面板之類的光透過構件中,由於內部偏斜所產生的複折射性而會使通過的光的偏光狀態發生變化。However, even if the photomask (or even the wafer) is illuminated with light in a desired polarization state, if there is an optical element that changes the polarization state of the light in the illumination optical path, the desired polarization state cannot be obtained. Imaging, which in turn may deteriorate imaging performance. In particular, in a light-transmitting member such as a lens or a parallel flat plate disposed in the illumination light path, the polarization state of the passing light changes due to the birefringence caused by the internal deflection.
本發明鑑於上述的問題以提供一種照明光學裝置,其可良好地抑制照明光路中之光的偏光狀態的變化,以所期望的偏光狀態的光來對被照射面進行照射。又,本發明的另一目的是提供一種曝光裝置和曝光方法,其使用所期望的偏光狀態的光來對被照射面進行照射用的照明光學裝置,以所期望的偏光狀態使微細圖樣忠實地成像在感光性基板上且進行一種良好的曝光。The present invention has been made in view of the above problems, and an illumination optical device capable of satisfactorily suppressing a change in a polarization state of light in an illumination light path and irradiating an illuminated surface with light in a desired polarization state. Further, another object of the present invention is to provide an exposure apparatus and an exposure method which use a desired polarized light to illuminate an illuminated surface to faithfully make a fine pattern in a desired polarization state. Imaging on a photosensitive substrate and performing a good exposure.
為了解決上述問題,本發明的第1形式中提供一種照 明光學裝置,其依據光源所提供的光來對被照射面進行照明且具備:一種偏光設定部,其配置在光源和被照射面之間的光路中,將到達被照射面之光的偏光狀態設定成所定的偏光狀態,其特徵為:該偏光設定部和被照射面之間的光路中所配置的多個光透過構件的每一個都是一種光學材料,此光學材料對於內部偏斜所造成的複折射量是5nm/cm以下。In order to solve the above problem, a photo is provided in the first form of the present invention. A bright optical device that illuminates an illuminated surface according to light provided by a light source and includes: a polarizing setting unit disposed in an optical path between the light source and the illuminated surface to achieve a polarized state of light reaching the illuminated surface A predetermined polarization state is set, wherein each of the plurality of light transmitting members disposed in the optical path between the polarized light setting portion and the illuminated surface is an optical material, and the optical material is caused by internal deflection The amount of birefringence is 5 nm/cm or less.
本發明的第2形式中提供一種照明光學裝置,其依據光源所供給的光來對被照射面進行照明且具備:一種偏光設定部,其配置在光源和被照射面之間的光路中,將到達被照射面之光的偏光狀態設定成所定的偏光狀態。According to a second aspect of the present invention, there is provided an illumination optical device that illuminates an illuminated surface in accordance with light supplied from a light source, and includes: a polarization setting unit disposed in an optical path between the light source and the illuminated surface; The polarization state of the light reaching the illuminated surface is set to a predetermined polarization state.
其特徵為:該偏光設定部和被照射面之間的光路中所配置的多個光透過構件分別定位在以光軸為中心的所要的旋轉角度位置中,以使各光透過構件中內部偏斜所造成的複折射的影響藉由相消而減低。The plurality of light-transmitting members disposed in the optical path between the polarized light setting portion and the illuminated surface are respectively positioned at a desired rotational angular position centering on the optical axis, so that the light-transmitting members are internally biased. The effect of the birefringence caused by the skew is reduced by cancellation.
本發明的第3形式中提供一種照明光學裝置,其依據光源所供給的光來對被照射面進行照明且具備:一偏光設定部,其配置在光源和被照射面之間的光路中,將到達被照射面之光的偏光狀態設定成所定的偏光狀態,以及一曲面鏡,其配置在偏光設定部和被照射面之間的光路中以使光路折曲,其特徵為:該曲面鏡的反射膜中形成一種對此反射膜以P偏光入射的光和對此反射膜以S偏光入射的光之間由 於反射而產生的相位差,此相位差就應入射至反射膜中的光線而言係在15度以內。According to a third aspect of the present invention, there is provided an illumination optical device that illuminates an illuminated surface in accordance with light supplied from a light source and includes: a polarization setting unit disposed in an optical path between the light source and the illuminated surface; a polarization state of the light reaching the illuminated surface is set to a predetermined polarization state, and a curved mirror disposed in the optical path between the polarization setting portion and the illuminated surface to bend the optical path, wherein the curved mirror is A light is formed in the reflective film between the light incident on the reflective film with P-polarized light and the light incident on the reflective film with S-polarized light The phase difference caused by the reflection is within 15 degrees of the light incident on the reflective film.
本發明的第4形式中供給一種照明光學裝置,其依據光源所供給的光來對被照射面進行照明且其特徵為具備:一偏光設定部,其配置在光源和被照射面之間的光路中,將被照射面上之光的偏光狀態設定成所定的偏光狀態,以及一光學系統,其配置在該偏光設定部和被照射面之間的光路中,以對複折射量進行管理。According to a fourth aspect of the present invention, there is provided an illumination optical device that illuminates an illuminated surface in accordance with light supplied from a light source and is characterized by: a polarization setting unit disposed between the light source and the illuminated surface The polarization state of the light on the illuminated surface is set to a predetermined polarization state, and an optical system is disposed in the optical path between the polarization setting portion and the illuminated surface to manage the amount of birefringence.
本發明的第5形式中供給一種照明光學裝置,其依據光源所供給的光來對被照射面進行照明且其特徵為具備:一偏光設定部,其配置在光源和被照射面之間的光路中,將被照射面上之光的偏光狀態設定成所定的偏光狀態,以及一光學系統,其配置在該偏光設定部和被照射面之間的光路中且保持著此到達被照射面之光的偏光狀態,使被照射面上之光的偏光狀態成為所定的偏光狀態。According to a fifth aspect of the present invention, there is provided an illumination optical device that illuminates an illuminated surface in accordance with light supplied from a light source and is characterized by: a polarization setting unit disposed between the light source and the illuminated surface The polarizing state of the light on the illuminated surface is set to a predetermined polarized state, and an optical system is disposed in the optical path between the polarized light setting portion and the illuminated surface and holds the light reaching the illuminated surface In the polarized state, the polarized state of the light on the illuminated surface is a predetermined polarized state.
本發明的第6形式中提供一種具備多個光透過構件之照明光學裝置的製造方法,其特徵為包含以下各過程:塊材(bulk material)準備過程,準備塊材以形成多個光學構件中的每一個,測定過程,測定已準備好的各塊材的複折射量,算出過程,收集由與構成該照明光學裝置的至少一部份的多個光透過構件有關的測定過程而來的各塊材的測定 資訊,選定可容許複折射的影響之構成該照明光學裝置的至少一部份的多個光透過構件的適當組合,以求出前述多個光透過構件的適當組合所造成的各光透過構件的設定位置,加工過程,對前述多個塊材加工以形成各光透過構件,以及組裝過程,依據上述算出過程的結果,使該加工過程中已加工的多個光透過構件組裝至所定的各別的設定位置中。According to a sixth aspect of the present invention, there is provided a method of manufacturing an illumination optical device including a plurality of light-transmitting members, comprising the following processes: a bulk material preparation process for preparing a bulk material to form a plurality of optical members. For each of the measurement processes, the amount of birefringence of each of the prepared blocks is measured, and the calculation process collects the respective measurement processes associated with the plurality of light-transmitting members constituting at least a portion of the illumination optical device. Bulk determination Information, selecting an appropriate combination of a plurality of light-transmitting members constituting at least a part of the illumination optical device, which can influence the influence of birefringence, to obtain respective light-transmitting members caused by appropriate combination of the plurality of light-transmitting members Setting a position, a processing process, processing the plurality of blocks to form each of the light-transmitting members, and assembling the process, and assembling the plurality of light-transmitting members processed in the process to the determined respective pieces according to the result of the calculation process In the set position.
本發明的第7形式中提供一種曝光裝置,其具備第1形式至第5形式的照明光學裝置或藉由第6形式的製造方法所製造的照明光學裝置,此曝光裝置的特徵為:使藉由照明光學裝置所照明的光罩的圖樣在感光性基板上曝光。According to a seventh aspect of the present invention, there is provided an exposure apparatus comprising: an illumination optical device of a first form to a fifth form; or an illumination optical device manufactured by the manufacturing method of the sixth form, wherein the exposure device is characterized by: The pattern of the reticle illuminated by the illumination optics is exposed on the photosensitive substrate.
本發明的第8形式中提供一種曝光方法,其使用第1至第5形式之照明光學裝置或藉由第6形式的製造方法所製造的照明光學裝置,此曝光方法的特徵為:使光罩的圖樣在感光性基板上曝光。According to an eighth aspect of the present invention, there is provided an exposure method using the illumination optical device of the first to fifth aspects or the illumination optical device manufactured by the manufacturing method of the sixth form, wherein the exposure method is characterized in that the photomask is provided The pattern is exposed on a photosensitive substrate.
本發明的第9形式中提供一種微型元件的製造方法,此製造方法的特徵為包含:曝光過程,使用第1至第5形式之照明光學裝置或藉由第6形式的製造方法所製造的照明光學裝置,以使光罩的圖樣在感光性基板上曝光;以及顯影過程,其使藉由曝光過程所曝光的感光性基板顯影。According to a ninth aspect of the present invention, there is provided a method of manufacturing a micro-component, comprising: an exposure process, using the illumination optical device of the first to fifth forms or the illumination manufactured by the manufacturing method of the sixth form; An optical device for exposing the pattern of the photomask to the photosensitive substrate; and a developing process for developing the photosensitive substrate exposed by the exposure process.
第7形式中,照明光學系統所具有的偏光設定部使被照射面的光的偏光狀態設定成所定的偏光狀態,此照明光 學系統的調整方法之特徵是包含以下各過程:取得過程,其取得與該偏光設定部和該被照射面之間的光路中應配置的光學系統的至少一部份有關的資訊,管理過程,其對該偏光設定部和被照射面之間的光路中所配置的光學系統的複折射量進行管理。In the seventh aspect, the polarization setting unit of the illumination optical system sets the polarization state of the light on the illuminated surface to a predetermined polarization state, and the illumination light The adjustment method of the learning system is characterized by the following processes: an acquisition process of obtaining information relating to at least a part of an optical system to be disposed in the optical path between the polarization setting unit and the illuminated surface, a management process, The birefringence amount of the optical system disposed in the optical path between the polarization setting unit and the illuminated surface is managed.
第8形式中,照明光學系統所具有的偏光設定部使被照射面的光的偏光狀態設定成所定的偏光狀態,此照明光學系統的調整方法之特徵是包含以下各過程:取得過程,其取得與該偏光設定部和該被照射面之間的光路中應配置的光學系統的至少一部份有關的資訊,維持過程,其維持著由該偏光設定部至被照射面為止之間的光路中之偏光特性,以經由光學系統使到達被照射面之光的偏光狀態成為所定的偏光狀態。In the eighth aspect, the polarization setting unit of the illumination optical system sets the polarization state of the light on the illumination surface to a predetermined polarization state, and the adjustment method of the illumination optical system includes the following processes: acquisition process, which is obtained. Information relating to at least a portion of the optical system to be disposed in the optical path between the polarized light setting portion and the illuminated surface, maintaining a process in which the optical path between the polarized light setting portion and the illuminated surface is maintained The polarization characteristic is such that the polarization state of the light reaching the illuminated surface is in a predetermined polarization state via the optical system.
本發明典型的形式中所遵從之照明光學裝置中,使到達被照射面之光的偏光狀態設定成所定的偏光狀態用的偏光設定部配置在光源與被照射面之間的光路中。然後,偏光設定部與被照射面之間的光路中所配置的各透光構件(透鏡,平行平面板等)是一種光學材料,此光學材料對於內部偏斜所造成的複折射量是5nm/cm以下。結果,各光透過構件中由內部偏斜所造成的複折射性受到抑制,進而使通過的光之由複折射性所引起的偏光狀態不會受到不良的影響。In the illumination optical device according to a typical aspect of the present invention, the polarization setting unit for setting the polarization state of the light reaching the illuminated surface to a predetermined polarization state is disposed in the optical path between the light source and the illuminated surface. Then, each of the light transmitting members (lenses, parallel plane plates, and the like) disposed in the optical path between the polarized light setting portion and the illuminated surface is an optical material, and the amount of birefringence caused by the optical material for internal deflection is 5 nm/ Below cm. As a result, the birefringence caused by the internal deflection in each of the light-transmitting members is suppressed, and the polarized state caused by the birefringence of the passing light is not adversely affected.
因此,本發明的照明光學裝置中,照明光路中之光的 偏光狀態的變化可良好地受到抑制,能以所期望的偏光狀態的光對被照射面進行照明。因此,本發明的曝光裝置和曝光方法中,可使用一種以所期望的偏光狀態的光對被照射面進行照明用的照明光學裝置,以所期望的偏光狀態使微細圖樣忠實地成像在感光性基板上且進行一種良好的曝光,進而可製造良好的微型元件。Therefore, in the illumination optical device of the present invention, the light in the illumination path is illuminated The change in the polarization state can be satisfactorily suppressed, and the illuminated surface can be illuminated with light in a desired polarization state. Therefore, in the exposure apparatus and the exposure method of the present invention, an illumination optical device for illuminating the illuminated surface with light in a desired polarization state can be used to faithfully image the fine pattern in the desired polarization state. A good exposure is made on the substrate to produce a good micro-component.
本發明的各實施形式以下將依據附圖來說明。圖1係本發明的實施形式所屬的曝光裝置的構成的概略圖。圖1中,沿著感光性基板中的晶圓W的法線方向來設定Z軸,晶圓W的面內將Y軸設定成與圖1的紙面相平行的方向,晶圓W的面內將X軸設定成與圖1的紙面成垂直的方向。Embodiments of the present invention will be described below with reference to the accompanying drawings. Fig. 1 is a schematic view showing the configuration of an exposure apparatus according to an embodiment of the present invention. In FIG. 1, the Z axis is set along the normal direction of the wafer W in the photosensitive substrate, and the Y axis is set in the plane parallel to the paper surface of FIG. 1 in the plane of the wafer W, and the wafer W is in the plane. The X axis is set to be perpendicular to the paper surface of Fig. 1.
參照圖1,本實施形式的曝光裝置具備一種供給該曝光光束(照明光)所用的光源1。例如,可使用一種供給193奈米波長的光所用的ArF準分子(excimer)雷射光源或一種供給248奈米波長的光所用的KrF準分子(excimer)雷射光源作為光源1。由光源1所射出的大略成平行的光束經由中繼透鏡系統2,偏光狀態切換部3(3a,3b)以及環照明用的繞射光學元件4而入射至無焦點透鏡5。又,偏光狀態切換部3的構成和作用容後再述, 中繼透鏡系統2之功能是使由光源1而來的大略成平行的光束變換成具有所定矩形狀斷面的大略成平行的光且將此光導引至偏光狀態切換部3。無焦點透鏡5是一種無 焦點光學系統,其使前側焦點位置和繞射光學元件4的位置設定成大約相一致且其後側焦點位置和圖中以斷線所示的所定面6的位置亦設定成大約相一致。Referring to Fig. 1, an exposure apparatus of this embodiment includes a light source 1 for supplying the exposure light beam (illumination light). For example, an ArF excimer laser light source for supplying light of 193 nm wavelength or a KrF excimer laser light source for supplying light of 248 nm wavelength can be used as the light source 1. The substantially parallel light beams emitted from the light source 1 are incident on the focusless lens 5 via the relay lens system 2, the polarization state switching sections 3 (3a, 3b), and the diffractive optical elements 4 for ring illumination. Further, the configuration and function of the polarization state switching unit 3 will be described later. The function of the relay lens system 2 is to convert the substantially parallel light beams from the light source 1 into substantially parallel light having a predetermined rectangular cross section and guide the light to the polarization state switching portion 3. The focusless lens 5 is a no The focus optical system sets the front focus position and the position of the diffractive optical element 4 to approximately coincide with each other and the position of the rear side focus position and the position of the fixed surface 6 indicated by the broken line in the figure are also set to approximately coincide.
另一方面,繞射光學元件4藉由段差之形成而構成且具有使入射光束繞射至所期望的角度之作用,此段差在基板上具有曝光光束(照明光)的波長大小的間距。具體而言,在具有矩形斷面之平行光束入射時,環照明用的繞射光學元件4具有一種使環狀的光強度分佈形成在其遠場(far field)(或Fraunhofer繞射區域)中的功能。On the other hand, the diffractive optical element 4 is constituted by the formation of a step and has an effect of diffracting the incident beam to a desired angle which has a pitch of a wavelength of the exposure beam (illumination light) on the substrate. Specifically, when a parallel light beam having a rectangular cross section is incident, the diffractive optical element 4 for ring illumination has a circular light intensity distribution formed in its far field (or Fraunhofer diffraction area). The function.
因此,作為光束變換元件的繞射光學元件4中所入射的大約平行的光束在無焦點透鏡5的瞳面上形成環狀的光強度分佈之後,以環狀的角度分佈而由無焦點透鏡5射出。又,無焦點透鏡5的前側透鏡群5a和後側透鏡群5b之間的光路中該瞳位置或其近旁處配置著偏光變換元件7和圓錐旋轉三稜鏡(axicon)系統8。偏光變換元件7和圓錐旋轉三稜鏡(axicon)系統8的構成和作用容後再述。Therefore, the approximately parallel light beams incident in the diffractive optical element 4 as the beam converting element form an annular light intensity distribution on the pupil surface of the non-focus lens 5, and are distributed in a ring shape by the angleless lens 5 Shoot out. Further, a polarization conversion element 7 and a conical rotation axicon system 8 are disposed in or near the optical path between the front lens group 5a and the rear lens group 5b of the non-focus lens 5. The configuration and function of the polarization conversion element 7 and the conical rotation axicon system 8 will be described later.
經由無焦點透鏡5之光束經由σ值可變的變焦透鏡9而入射至作為光學整合器用的微(micro)弗利斯(Fries)目鏡(或弗利斯目鏡)10中。微弗利斯目鏡10是由具有縱橫-且稠密配列的多個正折射率之微小透鏡所構成的光學元件。一般而言,微弗利斯目鏡例如是藉由在平行平面板上施加蝕刻處理以形成微小透鏡群來構成者。The light beam passing through the focusless lens 5 is incident into a micro Fries eyepiece (or Flis eyepiece) 10 as an optical integrator via a zoom lens 9 having a variable σ value. The micro-Fris eyepiece 10 is an optical element composed of a plurality of microlenses having a positive refractive index and a plurality of positive refractive indices. In general, the micro-Frisian eyepiece is constructed, for example, by applying an etching process on a parallel plane plate to form a microlens group.
此處,構成微弗利斯目鏡所用之各微小透鏡是較構成弗利斯目鏡所用的各透鏡元件還微小。又,微弗利斯目鏡 與互相隔絕之透鏡元件所構成的弗利斯目鏡並不相同,其中多個微小透鏡(微小折射面)並未互相隔絕而以一體方式形成。然而,就具有正折射率之透鏡元件以縱橫方式配置著此點而言,微弗利斯目鏡與弗利斯目鏡同樣都是波面分割型的光學整合器。Here, each of the minute lenses used to constitute the micro-Fris eyepiece is smaller than the lens elements used to constitute the Flis eyepiece. Again, the micro-Fris eyepiece The Flis eyepiece formed by the lens elements isolated from each other is not the same, and a plurality of minute lenses (microscopic refractive surfaces) are not integrally formed and are integrally formed. However, in the case where the lens element having a positive refractive index is disposed in a vertical and horizontal manner, the micro-Fris eyepiece and the Flis eyepiece are both wavefront-separated optical integrators.
所定面6的位置配置在變焦透鏡9的前側焦點位置的近旁,微弗利斯目鏡10的入射面配置在變焦透鏡9的後側焦點位置的近旁。換言之,變焦透鏡9實際上是以傅立葉(Fourier)變換的關係來對該所定面6和微弗利斯目鏡10的入射面進行配置,進而使無焦點透鏡5的瞳面和微弗利斯目鏡10的入射面配置成在光學上幾乎可共同作用。The position of the fixed surface 6 is disposed in the vicinity of the front focus position of the zoom lens 9, and the incident surface of the micro-Fris eyepiece 10 is disposed in the vicinity of the rear focus position of the zoom lens 9. In other words, the zoom lens 9 actually configures the incident surface 6 and the incident surface of the micro-Fris eyepiece 10 in a Fourier transform relationship, thereby making the face of the non-focus lens 5 and the micro-Fris eyepiece The entrance faces of 10 are configured to be optically nearly synergistic.
因此,微弗利斯目鏡10的入射面上與無焦點透鏡5的瞳面一樣例如會形成一種以光軸AX為中心的環狀的照射區。此環狀的照射區的全體形狀係與變焦透鏡9的焦點距離有關而作相似的變化,這以下將再描述。構成微弗利斯目鏡10之各微小透鏡具有一種與光罩M上應形成的照射區的形狀(進而是晶圓W上應形成的曝光區域的形狀)相似的矩形狀的斷面。Therefore, the incident surface of the micro-Fris eyepiece 10, like the pupil plane of the non-focus lens 5, forms, for example, an annular irradiation region centered on the optical axis AX. The overall shape of the annular irradiation zone is similarly changed in relation to the focal length of the zoom lens 9, which will be described later. Each of the minute lenses constituting the micro-Fris eyepiece 10 has a rectangular cross section similar to the shape of the irradiation region to be formed on the mask M (and thus the shape of the exposure region to be formed on the wafer W).
入射至微弗利斯目鏡10上的光束藉由多個微小透鏡而分割成二維空間,其後側焦點面或其近旁(進而是照明瞳面)處形成二次光源,其所具有的光強度分佈大約與由入射光束所形成的照射區相同,即,會形成一種以光軸AX為中心的環狀的實質的面光源所形成的二次光源。由微弗利斯目鏡10的後側焦點面或其近旁處形成的二次光源而來 的光束經由聚光器光學系統11之後重疊地對光罩遮板12進行照明。The light beam incident on the micro-Frisian eyepiece 10 is divided into a two-dimensional space by a plurality of minute lenses, and a secondary light source is formed at a rear side focal plane or a vicinity thereof (and thus an illumination pupil plane), and the light having the same The intensity distribution is approximately the same as the illumination area formed by the incident beam, i.e., a secondary source of light formed by an annular substantially planar source centered on the optical axis AX. From the rear side focal plane of the micro-Fris eyepiece 10 or a secondary light source formed at or near its vicinity The beam of light illuminates the reticle 12 in an overlapping manner after passing through the concentrator optical system 11.
因此,作為照明視野光圈用的光罩遮板12會形成一種與構成微弗利斯目鏡10用的各微小透鏡的形狀和焦點距離相對應的矩形狀的照射區。經由光罩遮板12的矩形狀的開口部(光透過部)的光束受到成像光學系統13的聚光作用之後,重疊地對所定的圖樣所形成的光罩M進行照明。即,成像光學系統13使光罩遮板12的矩形狀開口部的像形成在光罩M上。又,成像光學系統13的光路中配置著一對曲面鏡M1和M2。Therefore, as the reticle shutter 12 for illuminating the field of view aperture, a rectangular irradiation region corresponding to the shape and focal length of each of the minute lenses constituting the micro-Fris eyepiece 10 is formed. The light beam that has passed through the rectangular opening (light transmitting portion) of the reticle 12 is subjected to the condensing action of the imaging optical system 13, and then the reticle M formed by the predetermined pattern is superimposed and illuminated. That is, the imaging optical system 13 forms an image of the rectangular opening of the reticle 12 on the reticle M. Further, a pair of curved mirrors M1 and M2 are disposed in the optical path of the imaging optical system 13.
保持在光罩台MS上的光罩M的圖樣所透過的光束經由投影光學系統PL而在晶圓台WS上所保持的晶圓(感光性基板)W上形成光罩圖樣的像。於此,與投影光學系統PL的光軸AX直交的平面(XY平面)內一方面以二維空間的方式來驅動控制該晶圓台WS,進而以二維空間的方式來驅動控制該晶圓W,以進行整體曝光或掃描曝光,使晶圓W的各曝光區域中各光罩M的圖樣依序曝光。The light beam transmitted through the pattern of the mask M held on the mask stage MS forms an image of the mask pattern on the wafer (photosensitive substrate) W held on the wafer table WS via the projection optical system PL. Here, in a plane (XY plane) orthogonal to the optical axis AX of the projection optical system PL, the wafer table WS is driven and controlled in a two-dimensional space, and the wafer is driven and controlled in a two-dimensional space. W, in order to perform overall exposure or scanning exposure, sequentially exposing the patterns of the masks M in the respective exposure regions of the wafer W.
偏光狀態切換部3由光源側依序具備1/4波長板3a,1/2波長板3b。1/4波長板3a係以光軸AX為中心時對結晶光學軸以可自由旋轉的方式構成,使入射的橢圓偏光的光變換成直線偏光的光。又,1/2波長板3b係以光軸AX為中心時對結晶光學軸以可自由旋轉的方式構成,使入射的直線偏光的偏光面(偏光方向)變化。又,1/4波長板3a和1/2波長板3b的旋轉係藉由以控制部20而來的指令為 基準而動作之驅動部21來進行。The polarization state switching unit 3 is provided with a quarter-wavelength plate 3a and a half-wavelength plate 3b in this order from the light source side. The quarter-wavelength plate 3a is configured to be rotatable about the crystal optical axis around the optical axis AX, and converts the incident elliptically polarized light into linearly polarized light. Further, the half-wavelength plate 3b is configured to be rotatable about the crystal optical axis when the optical axis AX is centered, and to change the polarization plane (polarization direction) of the incident linearly polarized light. Further, the rotation of the 1⁄4 wavelength plate 3a and the 1⁄2 wavelength plate 3b is controlled by the control unit 20 as The drive unit 21 that operates based on the reference is performed.
使用KrF準分子(excimer)雷射光源或ArF準分子雷射光源作為光源1時,由此種光源所射出的光典型上具有95%以上的偏光度,1/4波長板3a上所入射者幾乎都是直線偏光的光。然而,光源1和偏光切換部3之間的光路中存在著作為裏面反射鏡的直角稜鏡時,入射的直線偏光的偏光面若與對著反射面之P偏光面或S偏光面不一致時,則藉由直角稜鏡上的全反射使直線偏光改變成橢圓偏光。When a KrF excimer laser light source or an ArF excimer laser light source is used as the light source 1, the light emitted from such a light source typically has a degree of polarization of 95% or more, and is incident on the quarter-wavelength plate 3a. Almost all linearly polarized light. However, when there is a right angle 著作 written as the inner mirror in the optical path between the light source 1 and the polarization switching unit 3, if the polarized surface of the incident linearly polarized light does not coincide with the P polarizing surface or the S polarizing surface facing the reflecting surface, Then, the linearly polarized light is changed into an elliptically polarized light by total reflection on the right angle 稜鏡.
例如,即使因為直角稜鏡上的全反射而使橢圓偏光的光入射至偏光狀態切換部3上,藉由1/4波長板3a的作用而變換後的直線偏光的光仍可入射至1/2波長板3b。以下為了作簡單的說明,圖1中Y方向中具有偏光方向(電場的方向)之直線偏光(以下稱為Y方向偏光)的光設定成入射至1/2波長板3b。For example, even if the elliptically polarized light is incident on the polarization state switching portion 3 due to the total reflection on the right angle, the linearly polarized light converted by the action of the quarter wave plate 3a can be incident on the light. 2 wave plate 3b. Hereinafter, for the sake of simple explanation, the light of the linearly polarized light (hereinafter referred to as the Y-direction polarized light) having the polarization direction (the direction of the electric field) in the Y direction in FIG. 1 is set to be incident on the 1/2 wavelength plate 3b.
此種情況下,對所入射的Z方向偏光的偏光面而言若將1/2波長板3b的結晶光學軸設定成0度或90度的角度時,則入射至1/2波長板3b上的Z方向偏光的光的偏光面未變化而使Z方向偏光保持原狀地通過,且以Z方向偏光狀態入射至繞射光學元件4。另一方面,對所入射的Z方向偏光的偏光面而言若將1/2波長板3b的結晶光學軸設定成45度的角度時,則入射至1/2波長板3b上的Z方向偏光的光的偏光面只變化90度而成為一種具有圖1之X方向中具有偏光方向(電場的方向)之直線偏光(以下稱為X方向偏光)的光,且以X方向偏光狀態入射至繞射光學元件4。In this case, when the crystal optical axis of the 1/2 wavelength plate 3b is set to an angle of 0 or 90 degrees with respect to the incident polarization surface of the Z-direction polarized light, it is incident on the 1/2 wavelength plate 3b. The polarizing surface of the light polarized in the Z direction does not change, the Z-direction polarized light passes through the original direction, and is incident on the diffractive optical element 4 in the Z-polarized state. On the other hand, when the crystal optical axis of the 1/2 wavelength plate 3b is set to an angle of 45 degrees with respect to the incident polarized surface of the Z-direction polarized light, the Z-direction polarized light incident on the 1/2 wavelength plate 3b is incident. The polarizing surface of the light changes only by 90 degrees to become a linearly polarized light having a polarization direction (a direction of an electric field) in the X direction of FIG. 1 (hereinafter referred to as X-direction polarized light), and is incident on the X-direction polarized state. The optical element 4 is injected.
一般而言,對所入射的Z方向偏光的偏光面而言藉由將1/2波長板3b的結晶光學軸設定成所要的角度時,則朝向繞射光學元件4的入射光的偏光狀態可設定成在任意方向中都可具有偏光方向的直線偏光狀態。又,偏光狀態切換部3藉由使1/2波長板3b由照明光路退避且將1/4波長板3a的結晶光學軸設定成對入射的橢圓偏光形成所要的角度,則可使圓偏光狀態或所期望的橢圓偏光狀態的光入射至繞射光學元件4。即,後述的偏光變換元件7在由光路退避的狀態下,藉由偏光狀態切換部3的作用,則可使光罩M或晶圓W照明用的光的偏光狀態設定成在任意方向中都可具有偏光方向的直線偏光狀態,圓偏光狀態或所期望的橢圓偏光狀態。In general, when the incident optical plane of the Z-direction polarized light is set to a desired angle by the crystal optical axis of the half-wavelength plate 3b, the polarized state of the incident light toward the diffractive optical element 4 can be It is set to a linearly polarized state which can have a polarization direction in any direction. Further, the polarization state switching unit 3 can make the circular polarization state by setting the 1⁄2 wavelength plate 3b to the illumination optical path and setting the crystal optical axis of the 1⁄4 wavelength plate 3a to a desired angle to the incident elliptically polarized light. Light of the desired elliptically polarized state is incident on the diffractive optical element 4. In other words, in the state where the polarization conversion element 7 to be described later is retracted by the optical path, the polarization state of the light for illuminating the mask M or the wafer W can be set to be in any direction by the action of the polarization state switching unit 3. It may have a linearly polarized state of a polarization direction, a circularly polarized state, or a desired elliptically polarized state.
其次,圓錐旋轉三稜鏡(axis cone)系統8由光源側依順序由第1稜鏡構件8a(其平面向著光源側且凹圓錐狀的折射面向著光罩側)和第2稜鏡構件8b(其平面向著光罩側且凸圓錐狀的折射面向著光源側)所構成。然後,第1稜鏡構件8a的凹圓錐狀的折射面和第2稜鏡構件8b的凸圓錐狀的折射面須以互補的方式而形成以便可互相接合。又,第1稜鏡構件8a和第2稜鏡構件8b中至少一個構件在構造上須可沿著光軸AX而移動。在構造上該第1稜鏡構件8a的凹圓錐狀的折射面和第2稜鏡構件8b的凸圓錐狀的折射面的間隔可改變。Next, the conical rotation of the axis cone system 8 is sequentially guided by the first side member 8a (the plane thereof toward the light source side and the concave conical refraction faces the mask side) and the second jaw member 8b. (The plane is oriented toward the mask side and the convex conical refraction faces the light source side). Then, the concave conical refractive surface of the first weir member 8a and the convex conical refractive surface of the second weir member 8b are formed in a complementary manner so as to be engageable with each other. Further, at least one of the first weir member 8a and the second weir member 8b is structurally movable along the optical axis AX. The interval between the concave conical refractive surface of the first meandering member 8a and the convex conical refractive surface of the second meandering member 8b can be changed in construction.
此處,第1稜鏡構件8a的凹圓錐狀的折射面和第2稜鏡構件8b的凸圓錐狀的折射面在互相接合的狀態時,圓 錐旋轉三稜鏡系統8在功能上是用作平行平面板,其對所形成的環狀的二次光源無影響。然而,若第1稜鏡構件8a的凹圓錐狀的折射面和第2稜鏡構件8b的凸圓錐狀的折射面互相離開,則一方面該環狀的二次光源的寬度(環狀的二次光源的外徑和內徑的差的1/2)保持一定,且另一方面環狀的二次光源的外徑(內徑)會變化。即,環狀的二次光源的環比(內徑/外徑)和大小(外徑)會變化。Here, when the concave conical refractive surface of the first meandering member 8a and the convex conical refractive surface of the second meandering member 8b are in a state of being joined to each other, the circle The cone rotating triaxial system 8 is functionally used as a parallel planar plate which has no effect on the formed annular secondary source. However, if the concave conical refractive surface of the first meandering member 8a and the convex conical refractive surface of the second meandering member 8b are separated from each other, the width of the annular secondary light source (ring 2) The difference between the outer diameter and the inner diameter of the secondary light source is kept constant, and on the other hand, the outer diameter (inner diameter) of the annular secondary light source changes. That is, the ring ratio (inner diameter/outer diameter) and size (outer diameter) of the annular secondary light source vary.
變焦透鏡9具有使環狀的二次光源的全體形狀以相似的方式擴大或縮小的功能。例如,變焦透鏡9的焦點距離藉由自最小值向所定的值擴大,則環狀的二次光源的全體形狀即以相似的方式擴大。換言之,藉由變焦透鏡9的作用,則環狀的二次光源的環比不會變化,其寬度和大小(外徑)同時會變化。因此,藉由圓錐旋轉三稜鏡系統8和變焦透鏡9的作用,則可控制環狀的二次光源的環比和大小(外徑)。The zoom lens 9 has a function of expanding or contracting the overall shape of the annular secondary light source in a similar manner. For example, when the focal length of the zoom lens 9 is expanded from a minimum value to a predetermined value, the overall shape of the annular secondary light source is expanded in a similar manner. In other words, by the action of the zoom lens 9, the ring-shaped secondary light source does not change in the ring ratio, and its width and size (outer diameter) change at the same time. Therefore, by the action of the conical rotating three-turn system 8 and the zoom lens 9, the ring ratio and size (outer diameter) of the annular secondary light source can be controlled.
又,若不使用環照明用的繞射光學元件4,則亦可在照明光路徑中設定4極照明用的繞射光學元件(未圖示)以進行4極照明。在具有矩形狀的斷面之平行光束入射時,4極照明用的繞射光學元件具有使4極狀的光強度分佈形成在其遠場中的功能。因此,經由4極照明用的繞射光學元件的光束在微弗利斯目鏡10的入射面上形成例如以光軸AX為中心的4個圓形狀的照射區所形成的4極狀的照射區。結果,在微弗利斯目鏡10的後側焦點面或其近旁會形成一與該入射面上所形成的照射區相同的4極狀的二次光 源。Further, if the diffractive optical element 4 for ring illumination is not used, a diffractive optical element (not shown) for 4-pole illumination can be set in the illumination light path to perform 4-pole illumination. When a parallel light beam having a rectangular cross section is incident, the diffractive optical element for 4-pole illumination has a function of forming a 4-pole light intensity distribution in its far field. Therefore, the light beam passing through the diffractive optical element for 4-pole illumination forms a 4-pole irradiation area formed by, for example, four circular irradiation regions centered on the optical axis AX on the incident surface of the micro-Fris eyepiece 10 . As a result, a quadrupole secondary light having the same illumination area as that formed on the incident surface is formed on or near the rear focal plane of the micro-Fris eyepiece 10. source.
又,若不使用環照明用的繞射光學元件4,則亦可在照明光路徑中設定圓形照明用的繞射光學元件(未圖示)以進行通常的圓形照明。在具有矩形狀的斷面之平行光束入射時,圓形照明用的繞射光學元件具有使圓形狀的光強度分佈形成在其遠場中的功能。因此,經由圓形照明用的繞射光學元件的光束在微弗利斯目鏡10的入射面上形成例如以光軸AX為中心的圓形狀的照射區。結果,在微弗利斯目鏡10的後側焦點面或其近旁會形成一與該入射面上所形成的照射區相同的圓形狀的二次光源。Further, if the diffractive optical element 4 for ring illumination is not used, a diffractive optical element (not shown) for circular illumination can be set in the illumination light path to perform normal circular illumination. When a parallel light beam having a rectangular cross section is incident, the diffractive optical element for circular illumination has a function of forming a circular light intensity distribution in its far field. Therefore, the light beam passing through the diffractive optical element for circular illumination forms a circular irradiation region centered on the optical axis AX on the incident surface of the micro-Frisian eyepiece 10, for example. As a result, a circular secondary light source having the same illumination area as that formed on the incident surface is formed at or near the rear focal plane of the micro-Fris eyepiece 10.
又,若不使用環照明用的繞射光學元件4,則亦可在照明光路中設定其它多極照明用的繞射光學元件(未圖示)以進行各種各樣的多極照明(2極照明,8極照明等)。同樣,若不用環照明用的繞射光學元件4,則亦可在照明光路中設定各種具有適當特性的繞射光學元件(未圖式),以進行各種各樣的變形照明。Further, if the diffractive optical element 4 for ring illumination is not used, a diffractive optical element (not shown) for other multi-pole illumination can be set in the illumination light path to perform various multi-pole illumination (2 poles). Lighting, 8-pole lighting, etc.). Similarly, if the diffractive optical element 4 for ring illumination is not used, various diffractive optical elements (not shown) having appropriate characteristics can be set in the illumination path to perform various types of anamorphic illumination.
圖2係圖1的偏光變換元件的構成的概略圖。圖3係就水晶的旋光性來作說明時的圖解。圖4係藉由偏光變換元件的作用而設定成周圍方向偏光狀態的環狀的二次光源的概略圖。本實施形式中所述的偏光變換元件7配置在無焦點透鏡5的瞳位置或其近旁,即,照明光學裝置(1至13)的瞳面或其近旁。因此,環照明時,具有以光軸AX為中心的近似環狀的斷面之光束會入射至偏光變換元件7上。Fig. 2 is a schematic view showing a configuration of a polarization conversion element of Fig. 1; Fig. 3 is a diagram for explaining the optical rotation of the crystal. 4 is a schematic view of a ring-shaped secondary light source that is set to a polarization state in a peripheral direction by the action of a polarization conversion element. The polarization conversion element 7 described in the present embodiment is disposed at or near the pupil position of the focusless lens 5, that is, the face of the illumination optical device (1 to 13) or its vicinity. Therefore, in the case of ring illumination, a light beam having a substantially annular cross section centered on the optical axis AX is incident on the polarization conversion element 7.
請參照圖2,偏光變換元件7整體上具有以光軸AX 為中心的環狀的有效區域,此環狀的有效區域是在以光軸AX為中心的圓周方向中由等分成8份的扇形形狀的基本元件所構成。在此8個基本元件中,挾著光軸AX而相面對的一對基本元件互相具有相同的特性。即,8個基本元件沿著光的透過方向(Y方向)之厚度(光軸方向的長度)以2個為一組而包含互相不同的4種類的基本元件7A~D。Referring to FIG. 2, the polarization conversion element 7 has an optical axis AX as a whole. As the center-shaped effective region, the annular effective region is constituted by a basic element which is equally divided into eight sectors in the circumferential direction centered on the optical axis AX. Among the eight basic elements, a pair of basic elements facing each other with the optical axis AX have the same characteristics. In other words, the thickness of the eight basic elements along the light transmission direction (Y direction) (the length in the optical axis direction) includes two types of basic elements 7A to D which are different from each other in two groups.
具體而言,第1基本元件7A的厚度最大,第4基本元件7D的厚度最小,第2基本元件7B的厚度設定成較第3基本元件7C的厚度還大。結果,偏光變換元件7的一面(例如,入射面)雖然是平面狀,但另一面(例如,射出面)則藉由各基本元件7A~D的厚度的不同而成為凹凸狀。 又,偏光變換元件7的二面(入射面和射出面)亦可同時形成凹凸狀。Specifically, the thickness of the first basic element 7A is the largest, the thickness of the fourth basic element 7D is the smallest, and the thickness of the second basic element 7B is set to be larger than the thickness of the third basic element 7C. As a result, one surface (for example, the incident surface) of the polarization conversion element 7 is planar, but the other surface (for example, the emission surface) is uneven by the thickness of each of the basic elements 7A to D. Further, the two faces (incident surface and exit surface) of the polarization conversion element 7 may be formed in a concavo-convex shape at the same time.
又,本實施形式中,各基本元件7A~D藉由具有旋光性的光學材料之類的水晶來構成,各基本元件7A~D的結晶光學軸設定成大致與光軸AX相一致。以下,請參閱圖3來對水晶的旋光性作簡單的說明。請參閱圖3,由厚度d的水晶所構成的平行平面板狀的光學構件100配置成使其結晶光學軸與光軸AX相一致。此時,藉由光學構件100的旋光性,使已入射的直線偏光的偏光方向在只對光軸AX旋轉θ角時的狀態下使直線偏光的光射出。Further, in the present embodiment, each of the basic elements 7A to 7D is constituted by a crystal having an optical material such as an optical property, and the crystal optical axes of the respective basic elements 7A to 7D are set to substantially coincide with the optical axis AX. Hereinafter, please refer to FIG. 3 for a brief description of the optical rotation of the crystal. Referring to FIG. 3, the parallel planar plate-shaped optical member 100 composed of crystals having a thickness d is disposed such that its crystal optical axis coincides with the optical axis AX. At this time, the linearly polarized light is emitted in a state where the polarization direction of the incident linearly polarized light is rotated by the angle θ by only the optical axis AX by the optical rotation of the optical member 100.
此時,由光學構件100的旋光性所造成的偏光方向的旋轉角(旋光角度)θ藉由光學構件100的厚度d和水晶的旋光能ρ而以下式(1)來表示。At this time, the rotation angle (rotation angle) θ of the polarization direction caused by the optical rotation of the optical member 100 is expressed by the following formula (1) by the thickness d of the optical member 100 and the optical rotation energy ρ of the crystal.
θ=d.ρ (1)θ=d. ρ (1)
一般而言,水晶的旋光能ρ具有波長相依性(依據所使用之光的波長,旋光能的值不相同的情況下之性質:旋光分散)。具體而言,使用光的波長變短時,則旋光能ρ有變大的傾向。依據「應用光學II」第167頁的記述,對波長是250.3奈米之光而言水晶的旋光能ρ是153.9度/mm。In general, the optical energy ρ of a crystal has a wavelength dependence (a property in the case where the values of the optical energy are different depending on the wavelength of light used: optical dispersion). Specifically, when the wavelength of the used light is shortened, the optical energy ρ tends to become large. According to the description on page 167 of "Applied Optics II", the optical energy ρ of the crystal is 153.9 degrees/mm for light having a wavelength of 250.3 nm.
本實施形式中,在Y方向中具有偏光方向的直線偏光的光入射時,第1基本元件7A設定成具有厚度dA,使Y方向對Z軸旋轉+180度之後的方向(即,Y方向)中具有偏光方向的直線偏光的光射出。因此,此時圖4所示的環狀的二次光源31中受到一對第1基本元件7A的旋光作用的光束所形成的一對圓弧狀區域31A中所通過的光束的偏光方向成為Y方向。In the present embodiment, when light having linearly polarized light having a polarization direction in the Y direction is incident, the first basic element 7A is set to have a thickness dA and a direction in which the Y direction is rotated by +180 degrees to the Z axis (that is, the Y direction). The linearly polarized light having a polarization direction is emitted. Therefore, at this time, the polarization direction of the light beam passing through the pair of arc-shaped regions 31A formed by the light beams that are subjected to the optical rotation of the pair of first basic elements 7A in the ring-shaped secondary light source 31 shown in FIG. 4 becomes Y. direction.
在Y方向中具有偏光方向的直線偏光的光入射時,第2基本元件7B設定成具有厚度dB,使Y方向對Z軸旋轉+135度之後的方向(即,Y方向對Z軸旋轉-45度之後的方向)中具有偏光方向的直線偏光的光射出。因此,此時圖4所示的環狀的二次光源31中受到一對第2基本元件7B的旋光作用的光束所形成的一對圓弧狀區域31B中所通過的光束的偏光方向成為Y方向對Z軸旋轉-45度之後的方向。When the linearly polarized light having the polarization direction in the Y direction is incident, the second basic element 7B is set to have a thickness dB and the Y direction is rotated by +135 degrees with respect to the Z axis (that is, the Y direction is rotated by the Z axis - 45 The linearly polarized light having the polarization direction in the direction after the degree is emitted. Therefore, at this time, the polarization direction of the light beam passing through the pair of arc-shaped regions 31B formed by the light flux of the pair of second basic elements 7B in the ring-shaped secondary light source 31 shown in FIG. 4 becomes Y. The direction is rotated by -45 degrees after the Z axis.
在Y方向中具有偏光方向的直線偏光的光入射時,第3基本元件7C設定成具有厚度dC,使Y方向對Z軸旋轉+90度之後的此一Y方向(即,X方向)中具有偏光方向的直線偏光的光射出。因此,此時圖4所示的環狀的二次光 源31中受到一對第3基本元件7C的旋光作用的光束所形成的一對圓弧狀區域31C中所通過的光束的偏光方向成為X方向。When the linearly polarized light having the polarization direction in the Y direction is incident, the third basic element 7C is set to have the thickness dC, and the Y direction is rotated in the Y direction (ie, the X direction) after the Z axis is rotated by +90 degrees. The linearly polarized light in the direction of polarization is emitted. Therefore, at this time, the circular secondary light shown in FIG. 4 The polarization direction of the light beam that passes through the pair of arc-shaped regions 31C formed by the light beams that are subjected to the optical rotation of the pair of third basic elements 7C in the source 31 is the X direction.
在Y方向中具有偏光方向的直線偏光的光入射時,第4基本元件7D設定成具有厚度dD,使Y方向對Z軸旋轉+45度之後的此一方向中具有偏光方向的直線偏光的光射出。因此,此時圖4所示的環狀的二次光源31中受到一對第4基本元件7D的旋光作用的光束所形成的一對圓弧狀區域31D中所通過的光束的偏光方向成為Y方向對Z軸旋轉+45度之後的方向。When the linearly polarized light having the polarization direction in the Y direction is incident, the fourth basic element 7D is set to have a thickness dD, and the linearly polarized light having the polarization direction in the one direction after the Y direction is rotated by +45 degrees to the Z axis. Shoot out. Therefore, at this time, the polarization direction of the light beam passing through the pair of arc-shaped regions 31D formed by the light flux of the pair of fourth basic elements 7D in the ring-shaped secondary light source 31 shown in FIG. 4 becomes Y. The direction is rotated by +45 degrees in the direction of the Z axis.
又,可將各別所形成的8個基本元件相組合以得到偏光變換元件7,或亦可藉由形成平行平面板狀的水晶基板上所要的凹凸形狀(段差)以得到偏光變換元件7。又,設有一種不具旋光性的圓形狀中央區域7E,其具有偏光變換元件7的有效區域的直徑方向的大小的1/3以上的大小,使偏光變換元件7未由光路退避以進行通常的圓形照明。此處,中央區域7E例如亦可由石英之類之未具有旋光性的光學材料所形成或亦可單純地是一種圓形狀的開口。然而,中央區域7E不是此偏光變換元件7中必要的元件。Further, the eight basic elements formed by the respective elements may be combined to obtain the polarization conversion element 7, or the polarization conversion element 7 may be obtained by forming a desired uneven shape (step) on the crystal substrate in a parallel plane plate shape. Further, a circular central region 7E having no optical rotation is provided, which has a size of 1/3 or more of the diameter direction of the effective region of the polarization conversion element 7, and the polarization conversion element 7 is not evacuated by the optical path to perform normal operation. Circular lighting. Here, the central region 7E may be formed, for example, of an optical material such as quartz which is not optically active or may simply be a circular opening. However, the central area 7E is not an essential element in this polarization conversion element 7.
圖5係圖1的偏光測定部的內部構成的概略圖。如圖5所示,本實施形式中,保持著晶圓W所用的晶圓台WS上設有一種偏光測定部(偏光狀態測定部)14,其對晶圓W上之照明光(曝光光束)的偏光狀態進行測定。偏光測定部14在晶圓W的曝光面的高度位置上具備一種能以二維空 間方式來決定位置的銷(pin)孔構件40。又,使用此偏光測定部14時,晶圓W由光路退避。Fig. 5 is a schematic view showing an internal configuration of a polarization measuring unit of Fig. 1; As shown in Fig. 5, in the present embodiment, a wafer measuring unit WS is provided with a polarization measuring unit (polarization state measuring unit) 14 for illuminating light (exposure beam) on the wafer W. The polarization state was measured. The polarization measuring unit 14 has a two-dimensional space at a height position of the exposure surface of the wafer W. The pin hole member 40 is positioned to determine the position. Moreover, when this polarization measuring part 14 is used, the wafer W is evacuated by the optical path.
通過銷(pin)孔構件40之銷孔40a的光經由準直透鏡(collimate lens)41而成為幾乎是平行的光,在反射鏡42上反射之後入射至中繼透鏡系統43。經由中繼透鏡系統後幾乎成平行的光束經由作為移相器用的λ/4板44和作為偏光器用的偏光束分光器45之後到達二維空間CCD46的檢出面46a。二維空間CCD46的輸出供給至控制部20。此處,λ/4板44以光軸作為中心而以可旋轉的方式構成,此λ/4板44中連接著以該光軸為中心的旋轉角度設定用的設定部47。The light passing through the pin hole 40a of the pin hole member 40 becomes almost parallel light via the collimating lens 41, is reflected by the mirror 42, and is incident on the relay lens system 43. The almost parallel light beam after passing through the relay lens system reaches the detection surface 46a of the two-dimensional space CCD 46 via the λ/4 plate 44 as a phase shifter and the polarization beam splitter 45 as a polarizer. The output of the two-dimensional space CCD 46 is supplied to the control unit 20. Here, the λ/4 plate 44 is rotatably formed around the optical axis, and the λ/4 plate 44 is connected to the setting portion 47 for setting the rotation angle around the optical axis.
因此,對晶圓W的照明光的偏光度不是0的情況下,經由設定部47藉由λ/4板44對光軸旋轉,使二維空間CCD46的檢出面46a中的光強度分佈發生變化。因此,偏光測定部14中使用該設定部47一方面使λ/4板44對光軸旋轉以檢出該檢出面46a中的光強度分佈的變化,且另一方面由此檢出結果藉由旋轉移相法可測得照明光的偏光狀態(偏光度;與光有關的Stokes參數S1 ,S2 ,S3 )。Therefore, when the degree of polarization of the illumination light of the wafer W is not 0, the optical axis is rotated by the λ/4 plate 44 via the setting unit 47, and the light intensity distribution in the detection surface 46a of the two-dimensional CCD 46 is generated. Variety. Therefore, the polarization measuring unit 14 uses the setting unit 47 to rotate the λ/4 plate 44 on the optical axis to detect a change in the light intensity distribution in the detection surface 46a, and on the other hand, the detection result is borrowed. The polarization state of the illumination light (polarization degree; Stokes parameters S 1 , S 2 , S 3 related to light) can be measured by the rotational phase shift method.
又,就旋轉移相法而言,例如,鶴田著,「光的鉛筆-光技術者用的應用光學」,株式會社新技術Communications等之中有詳細的記載。實際上,沿著晶圓面一方面以二維空間的方式使銷孔構件40(進而是銷孔40a)移動,且另一方面測定晶圓面內的多個位置中的照明光的偏光狀態。此時,偏光測定部14中由於對二維空間之檢出面46a中的光 強度分佈的變化進行檢出,則可依據該檢出分佈資訊來測定該照明光的瞳內中的偏光狀態的分佈。In addition, as for the rotational phase shifting method, for example, Tsuruta, "Applied Optics for Light Pencil-Light Technicians", New Technology Communications, etc. are described in detail. Actually, the pinhole member 40 (and thus the pin hole 40a) is moved in a two-dimensional space along the wafer surface, and on the other hand, the polarization state of the illumination light in a plurality of positions in the wafer surface is measured. . At this time, the light in the detection surface 46a of the two-dimensional space is detected by the polarization measuring unit 14. When the change in the intensity distribution is detected, the distribution of the polarization state in the ridge of the illumination light can be measured based on the detected distribution information.
因此,偏光測定部14中亦可使用λ/2板以取代λ/4板44來作為移相器。不管使用哪一種移相器,為了測定偏光狀態,(即,4個Stokes參數),則一方面須使移相器和偏光器(偏光束分光器45)的光軸旋轉的相對角度改變,另一方面使移相器或偏光器由光路退避時須在至少4種不同狀態中檢出該檢出面46a中之光強度分佈的變化。Therefore, a λ/2 plate can be used as the phase shifter instead of the λ/4 plate 44 in the polarization measuring unit 14. Regardless of which phase shifter is used, in order to determine the polarization state (ie, 4 Stokes parameters), on the one hand, the relative angles of the optical axes of the phase shifter and the polarizer (polar beam splitter 45) must be changed, and On the one hand, when the phase shifter or the polarizer is retracted from the optical path, the change in the light intensity distribution in the detection surface 46a must be detected in at least four different states.
又,本實施形式中雖然使作為移相器用的λ/4板44對光軸進行旋轉,但亦可使作為偏光器用的偏光束分光器45對光軸進行旋轉,亦可使移相器和偏光器的雙方都對光軸進行旋轉。又,亦可使作為移相器用的λ/4板44和作為偏光器用的偏光束分光器45中的一方或雙方由光路中脫離,以取代上述的動作或加入上述的動作中。Further, in the present embodiment, the λ/4 plate 44 as the phase shifter is rotated about the optical axis. However, the polarization beam splitter 45 as a polarizer may be rotated about the optical axis, and the phase shifter may be Both sides of the polarizer rotate the optical axis. Further, one or both of the λ/4 plate 44 for the phase shifter and the partial beam splitter 45 for the polarizer may be detached from the optical path instead of the above-described operation or the above-described operation.
又,偏光測定部14中亦可能藉由反射鏡42的偏光特性使光的偏光狀態改變。此時,由於反射鏡42的偏光特性須預先設定,則須藉由所需要的計算以依據對該反射鏡42的偏光特性的偏光狀態的影響來對偏光測定部14的測定結果進行補正,以便可正確地測定該照明光的偏光狀態。又,不限於反射鏡,即使透鏡等的其它光學構件造成偏光狀態的變化時亦可同樣地對測定結果進行補正,以正確地測定該照明光的偏光狀態。Further, in the polarization measuring unit 14, the polarization state of the light may be changed by the polarization characteristics of the mirror 42. At this time, since the polarization characteristic of the mirror 42 has to be set in advance, the measurement result of the polarization measuring unit 14 must be corrected in accordance with the influence of the polarization state of the polarization characteristic of the mirror 42 by a required calculation so that the measurement result can be corrected. The polarization state of the illumination light can be accurately measured. Further, the mirror is not limited to the mirror, and the measurement result can be corrected in the same manner even when other optical members such as lenses cause a change in the polarization state, so that the polarization state of the illumination light can be accurately measured.
因此,使用偏光測定部14來對晶圓W上之照明光的瞳內之偏光狀態(偏光度)進行測定,以判定此照明光在瞳 內是否成為適當的偏光狀態(例如,上述的周圍方向偏光狀態等)。然後,控制部20依據偏光測定部14的測定結果而在必要時可對偏光狀態切換部3(1/4波長板3a和1/2波長板3b)進行驅動,使朝向光罩M(進而是晶圓W)的照明光的偏光狀態調整成所期望的偏光狀態。Therefore, the polarization measuring unit 14 is used to measure the polarization state (polarization degree) of the illumination light on the wafer W to determine that the illumination light is in the 瞳 Whether or not it is in an appropriate polarization state (for example, the above-described peripheral direction polarization state, etc.). Then, the control unit 20 can drive the polarization state switching unit 3 (the quarter-wavelength plate 3a and the half-wavelength plate 3b) to the mask M as necessary, depending on the measurement result of the polarization measuring unit 14 (and further The polarization state of the illumination light of the wafer W) is adjusted to a desired polarization state.
本實施形式中,周圍方向偏光環照明(通過環狀的二次光源之光束設定成周圍方向偏光狀態時的變形照明)進行時,偏光狀態切換部3中的1/2波長板3b的結晶光學軸的光軸旋轉的角度位置須進行調整,此時藉由Y方向偏光入射至環照明用的繞射光學元件4中,使Y方向中具有偏光方向之直線偏光的光入射至偏光變換元件7。結果,微弗利斯目鏡10之後側焦點面或其近旁會形成環狀的二次光源(環狀的照明瞳分佈)31,如圖4所示,通過此環狀的二次光源31的光束設定成周圍方向偏光狀態。In the present embodiment, when the peripheral direction polarizing ring illumination (deformation illumination when the light beam of the annular secondary light source is set to the polarization state in the peripheral direction) is performed, the crystal optical of the 1⁄2 wavelength plate 3b in the polarization state switching unit 3 is performed. The angular position of the optical axis of the shaft must be adjusted. At this time, the polarized light in the Y direction is incident on the diffractive optical element 4 for ring illumination, and the linearly polarized light having the polarization direction in the Y direction is incident on the polarization conversion element 7. . As a result, an annular secondary light source (annular illumination 瞳 distribution) 31 is formed at or near the rear focal plane of the micro-Fris eyepiece 10, as shown in FIG. 4, the light beam passing through the annular secondary light source 31 Set to the polarization state in the surrounding direction.
在周圍方向偏光狀態時,構成環狀的二次光源31所用的圓弧狀區域31A~31D中所分別通過的光束成為一種直線偏光狀態,其所具有的偏光方向是與沿著各圓弧狀區域31A~31D的圓周方向的中心位置所在的光軸AX作為中心時的圓的切線方向大約一致。因此,本實施形式中,藉由偏光變換元件7的旋光作用,實質上不會發生光量損失下即可形成周圍方向偏光狀態的環狀的二次光源31。又,以周圍方向偏光狀態的環狀的照明瞳分佈為基準的周圍方向偏光環照明中,作為最後被照射面的晶圓W上所照射的光成為以S偏光為主成份的偏光狀態。In the polarization state in the peripheral direction, the light beams respectively passing through the arc-shaped regions 31A to 31D for forming the annular secondary light source 31 are in a linearly polarized state, and the polarization directions thereof are along the respective arc shapes. The tangential direction of the circle when the optical axis AX in the circumferential direction of the regions 31A to 31D is the center is approximately the same. Therefore, in the present embodiment, the annular secondary light source 31 in which the polarization in the peripheral direction is formed can be substantially eliminated without the loss of the amount of light by the optical rotation of the polarization conversion element 7. Further, in the peripheral direction polarizing ring illumination based on the distribution of the annular illumination pupil in the peripherally polarized state, the light irradiated on the wafer W as the last irradiated surface is in a polarized state mainly composed of S-polarized light.
此處,所謂S偏光是指一種直線偏光,其所具有的偏光方向對入射面是成垂直的方向(電場向量在與入射面成垂直的方向中振動時的偏光)。然而,所謂入射面係定義成光到達介質的邊界面(被照射面:晶圓W的表面)時,包含”該點所在的邊界面的法線與光的入射方向”的面。結果,周圍方向偏光環照明中,投影光學系統之光學性能(焦點深度等)可向上提高,晶圓(感光性基板)上可得到高對比的良好之光罩圖樣。Here, the S-polarized light refers to a linearly polarized light having a polarization direction that is perpendicular to the incident surface (polarization when the electric field vector vibrates in a direction perpendicular to the incident surface). However, the incident surface is defined as a surface where the light reaches the boundary surface of the medium (the surface to be irradiated: the surface of the wafer W), and includes the surface of the normal line of the boundary surface where the point is located and the incident direction of the light. As a result, in the peripheral direction polarizing ring illumination, the optical performance (focus depth, etc.) of the projection optical system can be improved upward, and a high contrast good reticle pattern can be obtained on the wafer (photosensitive substrate).
一般而言,上述方式不限於環照明,例如,亦可用於周圍方向偏光狀態的多極狀的照明瞳分佈為基準的照明。入射至晶圓W上的光成為以S偏光為主成份的偏光狀態,晶圓W上可得到高對比的良好的光罩圖樣之像。此時,可在照明光路中設定多極照明(2極照明,4極照明,8極照明等)用的繞射光學元件以取代環照明用的繞射光學元件4,且對偏光狀態切換部3中的1/2波長板3b的結晶光學軸的光軸旋轉的角度位置進行調整,使Y方向偏光入射至多極照明用的繞射光學元件上,則可使在Y方向中具有偏光方向的直線偏光的光入射至偏光變換元件7。In general, the above-described method is not limited to ring illumination, and for example, it can also be used for illumination in which a multi-pole illumination 瞳 distribution in a peripherally polarized state is used as a reference. The light incident on the wafer W is in a polarized state mainly composed of S-polarized light, and a high-contrast image of a good reticle pattern can be obtained on the wafer W. In this case, a diffractive optical element for multi-polar illumination (2-pole illumination, 4-pole illumination, 8-pole illumination, etc.) can be set in the illumination optical path instead of the diffractive optical element 4 for ring illumination, and the polarization state switching section The angular position of the optical axis rotation of the crystal optical axis of the 1⁄2 wavelength plate 3b in 3 is adjusted, and when the Y-direction polarized light is incident on the diffractive optical element for multipolar illumination, the polarization direction in the Y direction can be obtained. The linearly polarized light is incident on the polarization conversion element 7.
如上所述,依據光源1所供給的光,則本實施形式中照射至作為被照射面用的光罩M上所用之照明光學裝置(1~13)須配置在光源1和光罩M之間的光路中,且具備偏光狀態切換部3(3a,3b)和偏光變換元件7以作為偏光設定部,使到達光罩M上的光的偏光狀態被設定成所定的偏光狀態。然而,即使藉由偏光狀態切換部3和偏光變換元件 7的作用以所期望的偏光狀態的光對光罩M(進而是晶圓W)進行照明,若照明光路中存在著使光的偏光狀態發生變化的光學元件,則不能以所期望的偏光狀態來成像,進而可能使成像性能惡化。特別是照明光路中配置的光透過構件(透鏡或平行平面板)中由內部偏斜所造成的複折射性會使通過的光的偏光狀態發生變化。As described above, according to the light supplied from the light source 1, the illumination optical devices (1 to 13) used for the mask M for the illuminated surface in the present embodiment are disposed between the light source 1 and the mask M. In the optical path, the polarization state switching unit 3 (3a, 3b) and the polarization conversion element 7 are provided as the polarization setting unit, and the polarization state of the light reaching the mask M is set to a predetermined polarization state. However, even by the polarization state switching section 3 and the polarization conversion element The action of 7 illuminates the mask M (and further the wafer W) with light in a desired polarization state, and if there is an optical element that changes the polarization state of the light in the illumination path, the desired polarization state cannot be achieved. Imaging, which in turn may deteriorate imaging performance. In particular, the birefringence caused by the internal deflection in the light transmitting member (lens or parallel plane plate) disposed in the illumination light path changes the polarization state of the passing light.
以下,依據典型的設計例,例如就內部偏斜所造成之複折射的影響來驗證。首先,第1驗證例中,偏光狀態切換部3和光罩M之間的光路中所配置的全部之光透過構件(透鏡,平行平面板)中的任一個光透過構件設定成具有一種隨著”相對於光軸AX之旋轉對稱的二次分佈”而變化的複折射。更詳細而言,如圖6(a)所示,作為複折射分佈時,有效區域的中心(光軸AX)的複折射量是0nm/cm,有效區域的周邊之複折射量是10nm/cm,此種複折射分佈可想定成由有效區域的中心向周邊依據二次函數而單調地增加的一種分佈。此處,所謂複折射量是指:光透過構件內只透過1公分時P偏光和S偏光之間所發生的相位差。又由於相位差會與波長相關,為了使相位差有統一的表達方式,一般是會將一個波長視為360度的相位,因此相位差的單位,以波長正規化而將角度的單位相對於波長轉換成為無單位的nm/cm。又,此處之相位前移軸和遲相軸對光透過構件的中心而言是在放射方向或同心圓方向中,且複折射量可想定成由中心向周邊依據二次函數而單調地增加的一種分佈。Hereinafter, it is verified according to a typical design example, for example, the influence of the birefringence caused by the internal deflection. First, in the first verification example, any one of the light-transmitting members (lenses, parallel plane plates) disposed in the optical path between the polarization state switching unit 3 and the mask M is set to have a kind of Birefringence that varies with respect to the rotationally symmetric secondary distribution of the optical axis AX. More specifically, as shown in Fig. 6(a), as the birefringent distribution, the birefringence of the center of the effective region (optical axis AX) is 0 nm/cm, and the amount of birefringence of the periphery of the effective region is 10 nm/cm. Such a birefringence distribution can be thought of as a distribution that monotonically increases from the center of the effective region to the periphery according to a quadratic function. Here, the amount of birefringence refers to a phase difference occurring between P-polarized light and S-polarized light when only 1 cm is transmitted through the light-transmitting member. Since the phase difference is related to the wavelength, in order to make the phase difference have a unified expression, a wavelength is generally regarded as a phase of 360 degrees. Therefore, the unit of the phase difference is normalized by the wavelength and the unit of the angle is relative to the wavelength. Converted to a unitless nm/cm. Further, the phase advance axis and the slow phase axis here are in the radial direction or the concentric direction with respect to the center of the light transmitting member, and the amount of birefringence can be determined to monotonically increase from the center to the periphery according to the quadratic function. a distribution.
此時,依據上述的旋轉對稱之二次分佈而變化的複折射不管存在於哪一個光透過構件中,到達晶圓W上的曝光區域ER的中心CR(即,參閱該光軸AX:圖6(c))之光完全不受複折射的影響。然而,以曝光區域ER的中心CR以外的位置作為一例,依據上述旋轉對稱之二次分佈而變化的複折射到底存在於哪一個光透過構件中,則到達X方向中離曝光區域ER的中心CR最遠的周邊位置P1的光所受到的複折射的影響程度是不同的。At this time, the birefringence which changes according to the above-described secondary distribution of rotational symmetry reaches the center CR of the exposure region ER on the wafer W regardless of which light-transmitting member exists (ie, refer to the optical axis AX: FIG. 6 (c)) The light is completely unaffected by birefringence. However, as an example of a position other than the center CR of the exposure region ER, which of the light-transmitting members is present in accordance with the secondary distribution of the rotational symmetry, it reaches the center CR of the exposure region ER in the X direction. The degree of influence of the birefringence of the light at the farthest peripheral position P1 is different.
具體而言,到達曝光區域ER的周邊位置P1的光在偏光變換元件7的配置位置或其近旁的瞳位置中在X方向中具有偏光方向(圖6(b)中圓A和圓B所示),即,若著眼於瞳位置中Stokes參數S1 是1的光時,依據上述旋轉對稱之二次分佈而變化的複折射到底存在於哪一個光透過構件中,則到達曝光區域ER的周邊位置P1時的Stokes參數S1 的值的偏差已知是大約在0.91~1.0之間。Specifically, the light reaching the peripheral position P1 of the exposure region ER has a polarization direction in the X direction at the arrangement position of the polarization conversion element 7 or the 瞳 position in the vicinity thereof (indicated by the circle A and the circle B in FIG. 6( b )) When focusing on the light in which the Stokes parameter S 1 is 1 in the 瞳 position, which of the light-transmitting members is present in accordance with the secondary distribution of the rotational symmetry, the periphery of the exposure region ER is reached. The deviation of the value of the Stokes parameter S 1 at the position P1 is known to be approximately between 0.91 and 1.0.
另一方面,到達曝光區域ER的周邊位置P1的光之中,若著眼於偏光變換元件7的配置位置或其近旁的瞳位置中使X方向對Z軸旋轉-45度之後的方向中具有偏光方向的光(圖6(b)中圓C和D所示),即,若著眼於瞳位置中Stokes參數S2 是1的光時,依據上述旋轉對稱之二次分佈而變化的複折射到底存在於哪一個光透過構件中,則到達曝光區域ER的周邊位置P1時的Stokes參數S2 的值的偏差已知是大約在0.92~1.0之間。On the other hand, among the lights reaching the peripheral position P1 of the exposure region ER, focusing on the arrangement position of the polarization conversion element 7 or the vicinity of the pupil position, the X direction is rotated in the direction after the Z axis is rotated by -45 degrees. The direction of light (shown by circles C and D in Fig. 6(b)), that is, when focusing on the light in which the Stokes parameter S 2 is 1 in the 瞳 position, the complex refraction changes according to the secondary distribution of the above-described rotational symmetry In which of the light transmitting members is present, the deviation of the value of the Stokes parameter S 2 when reaching the peripheral position P1 of the exposure region ER is known to be approximately between 0.92 and 1.0.
其次,第2驗證例中,偏光狀態切換部3和光罩M之 間的光路中所配置的全部之光透過構件中的任一個光透過構件設定成具有一種隨著”沿著一方向而線形地變化之傾斜分佈”而變化的複折射。更詳細而言,如圖7(a)所示,作為複折射分佈時,有效區域之一周邊的複折射量是0nm/cm,有效區域的另一周邊之複折射量是10nm/cm,此種複折射分佈可想定成由沿著X方向的一周邊朝向另一周邊以依據一次函數而單調地增加的一種分佈。又,此處之相位前移軸和遲相軸可想定成與複折射量的傾斜方向成平行或垂直。Next, in the second verification example, the polarization state switching unit 3 and the mask M are The light-transmitting member of any one of the light-transmitting members disposed in the optical path therebetween is set to have a birefringence which changes as the "inclined distribution which changes linearly along one direction". More specifically, as shown in FIG. 7( a ), when the complex refractive index is distributed, the amount of birefringence around one of the effective regions is 0 nm/cm, and the amount of birefringence of the other periphery of the effective region is 10 nm/cm. The birefringence distribution can be thought of as a distribution that monotonically increases according to a linear function from one periphery along the X direction toward the other. Further, the phase advance axis and the slow phase axis here are desirably set to be parallel or perpendicular to the oblique direction of the birefringence amount.
此時,即使隨著上述已傾斜之一次分佈而變化的複折射存在於任意之光透過構件時,偏光變換元件7的配置位置或其近旁的瞳位置中在X方向中具有偏光方向的光(圖7(b)中圓A和圓B所示)或Y方向中具有偏光方向的光(圖7(b)中圓E和圓F所示),即,瞳位置中Stokes參數S1 是1的光,只限於到達晶圓W上的曝光區域ER的X軸上的區域或Y軸上的區域而完全不受複折射的影響。At this time, even if the birefringence which changes with the above-described tilted primary distribution exists in any of the light-transmitting members, the light having the polarization direction in the X direction among the arrangement positions of the polarization conversion elements 7 or the vicinity of the pupil position ( 7(b) in the circle A and the circle B) or the light having the polarization direction in the Y direction (indicated by the circle E and the circle F in Fig. 7(b)), that is, the Stokes parameter S 1 in the 瞳 position is 1 The light is limited to the area on the X-axis or the area on the Y-axis of the exposure area ER on the wafer W and is completely unaffected by the birefringence.
然而,依據上述傾斜之一次分佈而變化的複折射到底存在於哪一個光透過構件中,則偏光變換元件7的配置位置或其近旁的瞳位置中使X方向對Z軸旋轉-45度之後的方向中具有偏光方向的光(圖7(b)中圓C和D所示),即,瞳位置中Stokes參數S2 是1的光,在到達晶圓W上的曝光區域ER的中心CR(即,參閱該光軸AX:圖7(c))或到達X方向中離中心CR最遠的周邊位置P1時所受到的複折射的影響程度是不同的。However, in which light-transmitting member is present depending on the birefringence which changes according to the primary distribution of the above-described inclination, the arrangement position of the polarization conversion element 7 or the vicinity of the 瞳 position causes the X direction to be rotated by -45 degrees to the Z axis. Light having a polarization direction in the direction (shown by circles C and D in Fig. 7(b)), that is, light having a Stokes parameter S 2 of 1 in the 瞳 position, reaching the center CR of the exposure region ER on the wafer W ( That is, the degree of influence of the birefringence received when referring to the optical axis AX: FIG. 7(c)) or the peripheral position P1 farthest from the center CR in the X direction is different.
具體而言,瞳位置中Stokes參數S2 是1的光C到達曝光區域ER的中心CR時,依據上述傾斜之一次分佈而變化的複折射到底存在於哪一個光透過構件中,則Stokes參數S2 的值的偏差已知是大約在0.77~1.0之間。又,瞳位置中Stokes參數S2 是1的光D到達曝光區域ER的中心CR時,依據上述傾斜之一次分佈而變化的複折射到底存在於哪一個光透過構件中,則Stokes參數S2 的值的偏差已知是大約在0.65~1.0之間。Specifically, when the light C whose Stokes parameter S 2 is 1 in the 瞳 position reaches the center CR of the exposure region ER, which of the light-transmitting members is present in accordance with the primary distribution of the tilt, the Stokes parameter S The deviation of the value of 2 is known to be approximately between 0.77 and 1.0. Further, when the light D of the Stokes parameter S 2 in the 瞳 position reaches the center CR of the exposure region ER, which of the light-transmitting members is present depending on the primary distribution of the tilt first, the Stokes parameter S 2 The deviation of the values is known to be between approximately 0.65 and 1.0.
另一方面,瞳位置中Stokes參數S2 是1的光C到達曝光區域ER的周邊位置P1時,依據上述傾斜之一次分佈而變化的複折射到底存在於哪一個光透過構件中,則Stokes參數S2 的值的偏差已知是大約在0.83~1.0之間。On the other hand, when the light C whose Stokes parameter S 2 is 1 in the 瞳 position reaches the peripheral position P1 of the exposure region ER, which of the light-transmitting members is present depending on the primary distribution of the tilt, the Stokes parameter The deviation of the value of S 2 is known to be approximately between 0.83 and 1.0.
又,瞳位置中Stokes參數S2 是1的光D到達曝光區域ER的周邊位置P1時,依據上述傾斜之一次分佈而變化的複折射到底存在於哪一個光透過構件中,則Stokes參數S2 的值的偏差已知是大約在0.88~1.0之間。Further, when the light D of the Stokes parameter S 2 in the 瞳 position reaches the peripheral position P1 of the exposure region ER, which of the light-transmitting members is present depending on the primary distribution of the tilt distribution, the Stokes parameter S 2 The deviation of the value is known to be between approximately 0.88 and 1.0.
由上述2個驗證例的結果,偏光狀態切換部3和光罩M之間的光路中的光透過構件中,例如,若發生一種隨著內部偏斜所造成的旋轉對稱之二次分佈而變化的複折射,則該旋轉對稱之二次分佈的複折射對到達光罩M(進而晶圓W)之光的偏光狀態的影響已知是很大的。又,偏光狀態切換部3和光罩M之間的光路中的光透過構件中,若發生一種隨著內部偏斜所造成的傾斜之一次分佈而變化的複折射,則該傾斜之一次分佈的複折射對到達光罩M(進而晶圓 W)之光的偏光狀態的影響已知是很大的。As a result of the above-described two verification examples, in the light-transmitting member in the optical path between the polarization state switching portion 3 and the reticle M, for example, a secondary distribution of rotational symmetry due to internal deflection occurs. In the case of birefringence, the influence of the birefringence of the second distribution of the rotational symmetry on the polarization state of the light reaching the mask M (and hence the wafer W) is known to be large. Further, in the light transmitting member in the optical path between the polarization state switching portion 3 and the mask M, if a birefringence which changes with the primary distribution of the inclination due to the internal deflection occurs, the first distribution of the inclination is repeated. Refractive pair reaches the mask M (and thus the wafer The effect of the polarization state of the light of W) is known to be large.
因此,本實施形式中,作為第1手段時,偏光設定部(3,7)中的偏光狀態切換部3和光罩M之間的光路中所配置的各光透過構件以一種可使內部偏斜所造成的複折射量被抑制在5nm/cm以下的光學材料來形成。藉由此種構成,可使照明光路中之光的偏光狀態的變化受到良好的抑制,且能以所期望的偏光狀態的光來對光罩M進行照明,進而使微細圖樣以所期望的偏光狀態忠實地成像在晶圓W上,以進行良好的曝光。Therefore, in the present embodiment, as the first means, each of the light-transmitting members disposed in the optical path between the polarization state switching portion 3 and the mask M in the polarization setting portion (3, 7) can be internally skewed. The resulting amount of birefringence is formed by suppressing an optical material of 5 nm/cm or less. According to this configuration, the change in the polarization state of the light in the illumination light path can be satisfactorily suppressed, and the mask M can be illuminated with the light in a desired polarization state, and the fine pattern can be desired to be polarized. The state is faithfully imaged on wafer W for good exposure.
同樣,曝光裝置中若將由光源1至投影光學系統PL為止的部份考慮成照明光學裝置,則偏光設定部(3,7)中的偏光狀態切換部3和晶圓W之間的光路中所配置的各光透過構件以一種可使內部偏斜所造成的複折射量被抑制在5nm/cm以下的光學材料來形成。藉由此種構成,可使照明光路中之光的偏光狀態的變化受到良好的抑制,且能以所期望的偏光狀態的光來對晶圓W進行照明,進而使微細圖樣以所期望的偏光狀態忠實地成像在晶圓W上,以進行良好的曝光。Similarly, in the exposure apparatus, when the portion from the light source 1 to the projection optical system PL is considered as an illumination optical device, the optical path between the polarization state switching portion 3 and the wafer W in the polarization setting portion (3, 7) is used. Each of the disposed light-transmitting members is formed of an optical material whose amount of birefringence caused by internal deflection is suppressed to 5 nm/cm or less. According to this configuration, the change in the polarization state of the light in the illumination light path can be satisfactorily suppressed, and the wafer W can be illuminated with the light in a desired polarization state, and the fine pattern can be desired to be polarized. The state is faithfully imaged on wafer W for good exposure.
因此,依據上述的說明,雖然著眼於由內部偏斜所造成的複折射的影響,但光透過構件被保持時較大的應力由外部而發生作用,對應於外部應力所產生的複折射性而造成光透過構件中所通過的光的偏光狀態發生變化。因此,本實施形式的第2手段中,偏光設定部(3,7)中的偏光狀態切換部3和光罩M(或晶圓W)之間的光路中所配置的各 光透過構件仍保持著,使由外部應力所造成的複折射量被抑制在5nm/cm以下。藉由此種構成,可使照明光路中之偏光狀態的變化受到良好的抑制,且以所期望的偏光狀態的光來對光罩M(或晶圓W)進行照明,進而使微細圖樣以所期望的偏光狀態忠實地成像在晶圓W上,以進行良好的曝光。Therefore, according to the above description, while focusing on the influence of the birefringence caused by the internal deflection, a large stress acts when the light transmitting member is held by the outside, corresponding to the birefringence caused by the external stress. The polarization state of the light passing through the light transmitting member is changed. Therefore, in the second means of the present embodiment, each of the optical path between the polarization state switching unit 3 and the mask M (or the wafer W) in the polarization setting unit (3, 7) is disposed. The light transmitting member is maintained, so that the amount of birefringence caused by external stress is suppressed to 5 nm/cm or less. According to this configuration, the change in the polarization state in the illumination light path can be satisfactorily suppressed, and the mask M (or the wafer W) can be illuminated with the light in a desired polarization state, thereby making the fine pattern The desired polarization state is faithfully imaged on the wafer W for good exposure.
具體而言,先前技術中照明光路中所配置的光透過構件一般是藉由鏡筒內圓筒形狀的間隔環而以由二側來挾住的形態以保持著。此時,就原理而言,光透過構件沿著以光軸為中心的圓環狀的區域而連續地被支持著。然而,實際上由於間隔環的端面(與光透構件相接的面)的製造誤差等的影響,光透過構件沿著圓環狀的區域並未連續地被支持著,而是在沿著圓環狀區域的多個點區域(特別是無支持意圖之區域)上被支持著。Specifically, in the prior art, the light-transmitting member disposed in the illumination light path is generally held in a state of being caught by the two sides by a cylindrical ring-shaped spacer ring. At this time, in principle, the light transmitting member is continuously supported along an annular region centered on the optical axis. However, actually, due to the manufacturing error of the end surface of the spacer ring (the surface in contact with the light transmitting member), the light transmitting member is not continuously supported along the annular region, but is along the circle. A plurality of dot regions of the annular region (especially regions without support intent) are supported.
即,先前技術中,如圖8(a)所示,由外部作用在光透過構件50的一光學面側上的主力F1的位置與由外部作用在光透過構件50的另一光學面側上的主力F2的位置並不一致。結果,如圖8(b)中之等高線所示,對由外部而來的力F1和F2起反應,在光透構件50的有效區域50a的幾乎整個全體上持續地產生較大的應力分佈,這樣會對應於此種應力分佈而產生複折射性,使通過光透過構件50的光的偏光狀態發生變化。That is, in the prior art, as shown in Fig. 8(a), the position of the main force F1 acting externally on one optical surface side of the light transmitting member 50 and the other acting on the other optical surface side of the light transmitting member 50 by the outside The position of the main force F2 is not consistent. As a result, as shown by the contour lines in FIG. 8(b), the forces F1 and F2 from the outside react, and a large stress distribution is continuously generated over almost the entire entirety of the effective region 50a of the light transmitting member 50, This causes birefringence in response to such a stress distribution, and changes the polarization state of light passing through the light transmitting member 50.
對上述情況而言,本實施形式中如圖9(a)所示,光透過構件50的一光學面側以3個區域51a~51c來形成三點 式支持,且同時使光透過構件50的另一光學面側以大致上與此3個區域51a~51c相面對的3個區域52a~52c來形成三點式支持。此時,由外部作用在光透過構件50的一光學面側上的3個力F3的位置與由外部作用在光透過構件50的另一光學面側上的3個力F4的位置幾乎一致。In the above case, in the present embodiment, as shown in Fig. 9(a), one optical surface side of the light transmitting member 50 is formed into three points by three regions 51a to 51c. At the same time, the other optical surface side of the light transmitting member 50 is supported by three regions 52a to 52c substantially facing the three regions 51a to 51c to form a three-point support. At this time, the position of the three forces F3 acting on the optical surface side of the light transmitting member 50 from the outside almost coincides with the position of the three forces F4 acting on the other optical surface side of the light transmitting member 50 from the outside.
因此,如圖9(b)中之等高線所示,對由外部而來的力F3和F4起反應,以便只產生一種集中於光透過構件50的支持區域51a~51c(52a~52c)中的應力分佈,有效區域50a中實質上不會產生應力分佈。結果,本實施形式中大致上相面對的區域中以三點方式所支持著的光透過構件中由應力分佈所造成的複折射性幾乎不會發生,進而使通過之光的偏光狀態幾乎不會由於複折射性而發生變化。Therefore, as shown by the contour lines in Fig. 9(b), the forces F3 and F4 from the outside react to generate only one of the support regions 51a to 51c (52a to 52c) concentrated in the light transmitting member 50. The stress distribution does not substantially cause a stress distribution in the effective region 50a. As a result, the birefringence caused by the stress distribution in the light-transmitting member supported by the three-point method in the substantially facing region in the present embodiment hardly occurs, and the polarization state of the passing light is hardly caused. Will change due to birefringence.
圖10係本實施形式中由二側以三點支持著光透過構件所用的保持構件的構成之概略圖。本實施形式的保持構件具備:第1間隔環71,其所具有的3個支持部71a~71c以3個區域(與圖9的51a~51c相對應)來對該應保持的光透過構件60的一光學面側(圖10中上側)形成三點式支持;以及第2間隔環72,其所具有的3個支持部72a~72c以3個區域(與圖9的52a~52c相對應)來對該光透過構件60的另一光學面側(圖10中下側)形成三點式支持。Fig. 10 is a schematic view showing a configuration of a holding member for supporting a light-transmitting member at three points on both sides in the embodiment. The holding member of the present embodiment includes a first spacer ring 71, and the three supporting portions 71a to 71c included in the three supporting portions 71a to 71c correspond to the light transmitting member 60 to be held in three regions (corresponding to 51a to 51c in Fig. 9). One optical side (upper side in FIG. 10) forms a three-point support; and the second spacer ring 72 has three support portions 72a to 72c in three areas (corresponding to 52a to 52c of FIG. 9). The other optical surface side (lower side in FIG. 10) of the light transmitting member 60 forms a three-point support.
此處,第1間隔環71的3個支持部71a~71c大致上以等角度間隔而設置著,第2間隔環72的3個支持部72a~72c大致上亦以等角度間隔而設置著。又,第1間隔環71和第2間隔環72在位置上設定成大致上與支持部71a 和支持部72a相面對,進而使支持部71b和71c以及支持部72b和72c大致上亦分別地互相面對。因此,藉由保持構件(71,72)使大致上相面對的3個區域中該光透過構件60可由二側以三點方式來支持著。Here, the three support portions 71a to 71c of the first spacer ring 71 are provided substantially at equal angular intervals, and the three support portions 72a to 72c of the second spacer ring 72 are substantially also disposed at equal angular intervals. Further, the first spacer ring 71 and the second spacer ring 72 are positioned to substantially correspond to the support portion 71a. The support portion 72a faces the support portion 71b and 71c and the support portions 72b and 72c substantially face each other. Therefore, the light transmitting member 60 can be supported by the two sides in a three-point manner in the three regions facing substantially upward by the holding members (71, 72).
如上所述,本實施形式的照明光學裝置(1~15)中,光路中所配置的光透過構件中所要的光透過構件(一般而言至少1個光透過構件)在大致上相面對的3個區域上由二側以三點方式來支持著。此時,只產生一種集中在光透過構件的支持區域中的應力分佈,光透過構件的有效區域中實質上未產生應力分佈。結果,由應力所造成的複折射性幾乎不會發生,進而使通過之光的偏光狀態幾乎不會由於複折射性而發生變化。As described above, in the illumination optical device (1 to 15) of the present embodiment, the light-transmitting members (generally at least one light-transmitting member) required for the light-transmitting members disposed in the optical path face substantially face each other. The three areas are supported by two sides in three ways. At this time, only a stress distribution concentrated in the support region of the light transmitting member is generated, and substantially no stress distribution occurs in the effective region of the light transmitting member. As a result, the birefringence caused by the stress hardly occurs, and the polarized state of the passing light hardly changes due to the birefringence.
因此,本實施形式的照明光學裝置(1~15)中,光路中之光的偏光狀態的變化可良好地受到抑制,且能以所期望的偏光狀態或非偏光狀態之光來對該作為被照射面的光罩M(進而是晶圓W)進行照明。因此,本實施形式的曝光裝置中使用照明光學裝置(1~15),其以所期望的偏光狀態或非偏光狀態之光來對該作為被照射面的光罩M進行照明,且可依據光罩圖樣所對應之所期望的照明條件,使微細圖樣忠實地轉印至晶圓(感光性基板)W上。Therefore, in the illumination optical device (1 to 15) of the present embodiment, the change in the polarization state of the light in the optical path can be satisfactorily suppressed, and the light can be suppressed in a desired polarized state or a non-polarized state. The mask M (and thus the wafer W) on the illumination surface is illuminated. Therefore, in the exposure apparatus of the present embodiment, the illumination optical device (1 to 15) is used which illuminates the mask M as the illuminated surface with light in a desired polarization state or non-polarization state, and can be based on light. The fine pattern is faithfully transferred onto the wafer (photosensitive substrate) W by the desired illumination conditions corresponding to the mask pattern.
然而,上述的實施形式中,作為光學整合器用的微弗利斯目鏡11和作為被照射面用的光罩M之間的光路中所配置的光透過構件在徑向中容易大型化,由外部而來的力被接收時,所通過的光的偏光狀態容易由於複折射性而發 生變化。因此,光路中之光的偏光狀態的變化良好地受到抑制時,作為光學整合器用的微弗利斯目鏡11和作為被照射面用的光罩M之間的光路中所配置的光透過構件中,較佳是藉由保持構件以三點方式來支持著徑向中較大型的光透過構件。However, in the above-described embodiment, the light-transmitting member disposed in the optical path between the micro-Fris eyepiece 11 for the optical integrator and the mask M for the illuminated surface is easily enlarged in the radial direction, and is externally When the incoming force is received, the polarized state of the light that passes through is easily caused by the birefringence. Change. Therefore, when the change in the polarization state of the light in the optical path is satisfactorily suppressed, the light transmitting member disposed in the optical path between the micro-Fris eyepiece 11 for the optical integrator and the mask M for the illuminated surface is used. Preferably, the larger light transmissive member in the radial direction is supported by the holding member in a three-point manner.
又,上述的實施形式中如圖10所示,若藉由保持構件(72,73)以大致上相面對的3個區域由二側以三點方式來支持一種與光透過構件60相鄰接的光透過構件61時,光透過構件60之由保持構件(71,72)所造成的三點支持位置和光透過構件61之由保持構件(72,73)所造成的三點支持位置較佳是對光軸旋轉而在位置上形成偏差。藉由此種構成,則多個光透過構件的三點支持的影響可分散至光軸旋轉的角度方向中,進而使光路中之光的偏光狀態的變化受到良好的抑制。此點不限於相鄰接的光透過構件之間,一般之多個光透過構件亦同樣適用。Further, in the above-described embodiment, as shown in FIG. 10, if the holding members (72, 73) support the light transmitting member 60 adjacent to each other by three sides facing the three regions substantially in the three-point manner. When the light is transmitted through the member 61, the three-point support position of the light-transmitting member 60 by the holding members (71, 72) and the three-point support position of the light-transmitting member 61 by the holding members (72, 73) are preferred. It is a rotation of the optical axis to form a deviation in position. According to this configuration, the influence of the three-point support of the plurality of light transmitting members can be dispersed in the angular direction of the optical axis rotation, and the change in the polarization state of the light in the optical path can be satisfactorily suppressed. This point is not limited to the adjacent light-transmitting members, and a plurality of light-transmitting members are also generally applicable.
如上所述,在上述的實施例中,光路中之光的偏光狀態的變化受到良好的抑制,藉由保持構件來達成三點式支持的狀態中,光透過構件的有效區域中之複折射量可良好地保持在5nm/cm以下。又,如圖11和圖12所示,較佳是使用切口部(加工部)所形成的光透過構件63以取代光透過構件(60,61),此切口部(加工部)在光透過構件62的有效區域的全周圍部具有一種與光軸AX直交的面62a。因此,如圖10所示,藉由如光透過構件62所示的切口部(加工部)所形成的2個光透過構件以3點來支持著以取代光透 過構件(60,61),則可使保持時所造成的外部應力更進一層地受到抑制。As described above, in the above-described embodiment, the change in the polarization state of the light in the optical path is well suppressed, and in the state in which the three-point support is achieved by the holding member, the amount of birefringence in the effective region of the light transmitting member can be good. The ground is kept below 5 nm/cm. Further, as shown in FIGS. 11 and 12, it is preferable to use a light transmitting member 63 formed by a notched portion (processed portion) instead of the light transmitting member (60, 61), and the notched portion (processed portion) is in the light transmitting member. The entire circumference of the effective area of 62 has a face 62a that is orthogonal to the optical axis AX. Therefore, as shown in FIG. 10, the two light transmitting members formed by the notched portions (processed portions) as shown by the light transmitting member 62 are supported by three points instead of light. Through the members (60, 61), the external stress caused by the holding can be further suppressed.
又,由於保持時所造成的外部應力已下降,則支持部等的金屬構件所連接的光透過構件等的光學構件的支持部使”對光學構件的周邊部進行加工”之過程只限制在與光軸AX相垂直的平面部上。光學構件之至少一些片面屬於該平面部時亦可。In addition, since the external stress caused by the holding is lowered, the support portion of the optical member such as the light transmitting member to which the metal member such as the support portion is connected is limited to the process of "processing the peripheral portion of the optical member". The optical axis AX is perpendicular to the plane portion. It is also possible that at least some of the facets of the optical member belong to the plane portion.
又,光學構件中已加工的平面部中藉由支持構件而受到應力時,就徑向或旋轉方向中無偏差的支持形態而言,雖然以上是以3點式支持作為例子,但不限於此,在徑向或旋轉方向中若能使用無偏差的支持形態,則任一種支持形態都可使用。Further, in the case where the processed planar portion of the optical member is subjected to stress by the supporting member, the support form having no deviation in the radial direction or the rotational direction is an example of the three-point support, but is not limited thereto. Any support form can be used if an unbiased support form can be used in the radial or rotational direction.
又,進行上述的”支持”過程時,以偏斜計測機等來計測支持部近旁的光學構件的偏斜,依據已計測的偏斜,更佳是進行一種過程以對一種應壓鐵器的力矩或彈簧常數進行調整,使應力所產生的複折射量成為5nm以下(更佳是2nm以下)。Further, when the above-mentioned "support" process is performed, the deflection of the optical member near the support portion is measured by a skew measuring machine or the like, and depending on the measured deflection, it is more preferable to perform a process for the torque of a type of pressure-receiving device. Or the spring constant is adjusted so that the amount of birefringence generated by the stress becomes 5 nm or less (more preferably 2 nm or less).
又,如圖11和圖12所示,離該光透過構件62的有效區域3毫米以上的處所(周緣部)若形成一種具有與光軸AX直交的面62a之切口部時,則由光透過構件62保持時所造成的外部應力更進一步地確實減低。Further, as shown in FIG. 11 and FIG. 12, when a portion (peripheral portion) having a distance of 3 mm or more from the effective region of the light transmitting member 62 is formed as a notch portion having a surface 62a orthogonal to the optical axis AX, light is transmitted through The external stress caused by the retention of the member 62 is further reduced.
又,第1手段中,較佳是使用一種光學材料來形成各光透過構件,此光學材料對於內部偏斜所造成的複折射量是在2nm/cm以下。又,第2手段中,較佳是保持著各光 透過構件,使外部應力所造成的複折射量被抑制在2nm/cm以下。此時,照明光路中之光的偏光狀態的變化更可良好地受到抑制,進而使微細圖樣以所期望的偏光狀態忠實地成像在晶圓W上,以進行良好的曝光。而且,可藉由第1手段和第2手段以期待相乘的效果。Further, in the first means, it is preferable to form each of the light-transmitting members by using an optical material, and the amount of birefringence of the optical material with respect to the internal deflection is 2 nm/cm or less. Further, in the second means, it is preferable to hold each light The amount of birefringence caused by external stress is suppressed to 2 nm/cm or less through the member. At this time, the change in the polarization state of the light in the illumination light path can be satisfactorily suppressed, and the fine pattern can be faithfully imaged on the wafer W in a desired polarization state for good exposure. Further, the first means and the second means can be expected to multiply the effect.
又,在以上的說明中,雖然著眼於由內部偏斜或外部應力所造成的複折射的影響,但成像光學系統13的光路中所配置的一對曲面鏡M1和M2中,由於光線經由較廣的入射角度範圍而入射,則P偏光和S偏光之間會由於反射而產生相位差(P-S),進而使通過曲面M1和M2中的光的偏光狀態發生變化。因此,本實施形式中,第3手段中須分別形成曲面M1和M2,使對反射膜以P偏光入射的光和以S偏光入射的光之間由於反射所造成的相位差就入射至反射膜上的全部之光線而言成為在15度以內。Further, in the above description, although focusing on the influence of the birefringence caused by the internal deflection or the external stress, the pair of curved mirrors M1 and M2 disposed in the optical path of the imaging optical system 13 are When a wide incident angle range is incident, a phase difference (PS) is generated between the P-polarized light and the S-polarized light due to reflection, and the polarization state of the light passing through the curved surfaces M1 and M2 is changed. Therefore, in the third embodiment, the curved surfaces M1 and M2 are respectively formed in the third means, so that the phase difference caused by the reflection between the light incident on the reflective film by the P-polarized light and the light incident on the S-polarized light is incident on the reflective film. The total light is within 15 degrees.
藉由上述的構成,則包含各曲面M1和M2之照明光路中之光的偏光狀態可良好地受到抑制,以便以所期的偏光狀態來對光罩M(或晶圓W)進行照明,進而使微細圖樣以所期望的偏光狀態忠實地成像在晶圓W上,以進行良好的曝光。又,第3手段中,P偏光和S偏光之間由於反射所造成的相位差較佳是被抑制在10度以內。此時,各曲面M1和M2中的光的偏光狀態的變化更可受到良好的抑制,進而使微細圖樣以所期望的偏光狀態更忠實地成像在晶圓W上,以進行良好的曝光。According to the above configuration, the polarization state of the light in the illumination light path including the curved surfaces M1 and M2 can be satisfactorily suppressed, so that the mask M (or the wafer W) is illuminated in the desired polarization state, and further The fine pattern is faithfully imaged on the wafer W in a desired polarized state for good exposure. Further, in the third means, the phase difference due to reflection between the P-polarized light and the S-polarized light is preferably suppressed to within 10 degrees. At this time, the change in the polarization state of the light in each of the curved surfaces M1 and M2 can be more well suppressed, and the fine pattern can be more faithfully imaged on the wafer W in a desired polarized state for good exposure.
然而,例如,依據內部偏斜所造成的旋轉非對稱分佈 (典型情況下是傾斜分佈)而變化的複折射率若發生在多個光透過構件中,則藉由各光透過構件中之複折射率分佈的組合,一方面可使場內的偏光狀態(與晶圓W上的曝光區域ER內的各位置有關的瞳面內的偏光狀態)實質上成為不均一,且另一方面瞳面內的偏光狀態會由所期望的偏光狀態(例如,周圍方向偏光狀態)變化成實質上不同的狀態。若場內的偏光狀態實質上成為不均一(例如,與到達曝光區域ER的中心的光有關的瞳面內的偏光狀態和與到達此曝光區域ER的周邊的光有關的瞳面內的偏光狀態實質上不相同),則晶圓W上所形成的圖樣的線寬在曝光區域ER內的位置每次有偏差時,都可發生所謂場內線寬度差。However, for example, a rotationally asymmetric distribution due to internal skew (typically, oblique distribution) and if the changed complex refractive index occurs in a plurality of light-transmitting members, the polarization state in the field can be made on the one hand by the combination of the complex refractive index distributions in the respective light-transmitting members ( The polarization state in the pupil plane associated with each position in the exposure region ER on the wafer W is substantially non-uniform, and on the other hand, the polarization state in the pupil plane is caused by the desired polarization state (for example, the peripheral direction) The polarization state) changes to a substantially different state. If the polarization state in the field is substantially non-uniform (for example, a polarization state in the pupil plane related to light reaching the center of the exposure region ER and a polarization state in the pupil plane related to light reaching the periphery of the exposure region ER) Substantially different, a so-called in-field line width difference may occur every time the line width of the pattern formed on the wafer W is deviated in the position in the exposure area ER.
又,瞳面內的偏光狀態若由所期望的偏光狀態實質上變化成不同的狀態,例如,晶圓W上沿著縱方向成細長形延伸的圖樣和沿著橫方向成細長形延伸的圖樣之間線寬度有偏差時,則會發生所謂VH線寬度差。因此,本實施形式之第4手段中,各光透過構件分別定位在以光軸AX為中心的所要的旋轉角度位置處,以便使偏光設定部(3,7)中的偏光狀態切換部3和光罩M(或晶圓W)之間的光路中所配置的各光透過構件中由內部偏斜所造成的複折射的影響藉由相消而減低。Further, if the polarization state in the pupil plane is substantially changed to a different state from the desired polarization state, for example, a pattern extending on the wafer W in the longitudinal direction and a pattern extending in the lateral direction is elongated. When there is a deviation between the line widths, a so-called VH line width difference occurs. Therefore, in the fourth aspect of the present embodiment, each of the light transmitting members is positioned at a desired rotational angle position centering on the optical axis AX so as to cause the polarization state switching portion 3 and the light in the polarization setting portion (3, 7). The influence of the birefringence caused by the internal deflection in each of the light-transmitting members disposed in the optical path between the cover M (or the wafer W) is reduced by cancellation.
藉由上述的構成,則照明光路中之光的偏光狀態可良好地受到抑制,能以所期望的偏光狀態的光來對光罩M(或晶圓W)進行照明,進而使微細圖樣以所期望的偏光狀態忠實地成像在晶圓W上,以進行良好的曝光。更具體而言, 藉由上述的摩擦脫色(crocking)手段,則場內的偏光狀態可調整成大致上是均一的狀態,可使場內線寬度差的發生受到抑制,同時瞳面內的偏光狀態可調整成接近所期望的偏光狀態,使VH線寬度差的發生受到抑制。According to the above configuration, the polarization state of the light in the illumination light path can be satisfactorily suppressed, and the mask M (or the wafer W) can be illuminated with the light in a desired polarization state, and the fine pattern can be made The desired polarization state is faithfully imaged on the wafer W for good exposure. More specifically, By the above-described frictional crocking means, the polarization state in the field can be adjusted to be substantially uniform, and the occurrence of the difference in the line width of the field can be suppressed, and the polarization state in the face can be adjusted to be close to The desired polarization state suppresses the occurrence of the VH line width difference.
上述第1至第4手段亦可單獨地使用,2個以上的手段亦可適當地組合而加以使用。以下,就本實施形式所屬的照明光學裝置的製造方法來說明。圖13是本實施形式之照明光學裝置的製造方法的各步驟的流程圖。參閱圖13,本實施形式的製造方法中,例如可用來製造由石英之類的光學材料所構成的鑄塊(ingot)(S1)。具體而言,由石英所構成的鑄塊例如可用堆灰(soot)法或直接法而得到,其詳細情況可參照國際公開WO 00/41226號公報等。The first to fourth means described above may be used singly, and two or more means may be used in combination as appropriate. Hereinafter, a method of manufacturing the illumination optical device according to the embodiment will be described. Fig. 13 is a flow chart showing the steps of the method of manufacturing the illumination optical device of the embodiment. Referring to Fig. 13, in the manufacturing method of the present embodiment, for example, an ingot (S1) composed of an optical material such as quartz can be produced. Specifically, the ingot made of quartz can be obtained, for example, by a soot method or a direct method. For details, refer to International Publication WO 00/41226 and the like.
其次,將製造步驟S1所得到的鑄塊切斷(切出加工),且準備該照明裝置中的各光透過構件形成用的塊材(bulk material)(S2)。此處,所謂塊材之概念是:由鑄塊所切出的原來物件或包含一種在與相對應之光透過構件的大小和形狀相對應的情況下作某種程度之加工後的物件。具體而言,應形成的光透過構件是透鏡時,塊材的形狀較佳是作成薄圓柱形。圓柱形的塊材(即,碟片(disc)材)的口徑和厚度較佳是設定成與透鏡的有效外徑和光軸方向的厚度相一致。在準備步驟S2中,對藉由鑄塊所切出的塊材必要時相對應地進行退火(anneal)處理。Next, the ingot obtained in the manufacturing step S1 is cut (cut-out), and a bulk material for forming each of the light-transmitting members in the illumination device is prepared (S2). Here, the concept of the block material is that the original object cut out by the ingot or the object which has been processed to some extent in the case of corresponding to the size and shape of the corresponding light transmitting member. Specifically, when the light-transmitting member to be formed is a lens, the shape of the block is preferably made into a thin cylindrical shape. The diameter and thickness of the cylindrical block (i.e., the disc material) are preferably set to coincide with the effective outer diameter of the lens and the thickness in the optical axis direction. In the preparation step S2, the block cut by the ingot is subjected to an annealing treatment as necessary.
其次,對準備步驟S2中所得到的各塊材的複折射量進行測量(S3)。具體而言,在測定步驟S3中,對各塊材的 相位前移軸方向和複折射量(只透過單位距離時P偏光和S偏光之間由於內部偏斜所造成的相位差量)的分佈進行測定。又,就各塊材的相位前移軸方向和複折射量的測定而言,例如可參閱國際公開WO 00/41226號公報或WO 03/007045號公報。Next, the amount of birefringence of each of the blocks obtained in the preparation step S2 is measured (S3). Specifically, in the measuring step S3, for each block The distribution of the phase advance axis direction and the amount of birefringence (the amount of phase difference between the P-polarized light and the S-polarized light due to internal deflection when passing through the unit distance) was measured. Further, for the measurement of the phase advancement axis direction and the amount of birefringence of each block, for example, International Publication No. WO 00/41226 or WO 03/007045 can be referred to.
其次,對1個照明光學裝置構成用的光透過構件和塊材的組合(set)進行設定(S4)。具體而言,組合設定步驟S4中,初步選定此照明光學裝置構成時應該使用的塊材的組合(set),初步決定此種組合中的各塊材的光軸旋轉的旋轉角度位置。在組合設定步驟S4中,塊材的組合雖然有多種方式,但以下的說明只著眼於塊材的1種組合。Next, a combination of a light transmitting member and a block for constituting one illumination optical device is set (S4). Specifically, in the combination setting step S4, the combination of the blocks to be used in the configuration of the illumination optical device is initially selected, and the rotational angle position of the optical axis rotation of each of the blocks in the combination is initially determined. In the combination setting step S4, although there are various combinations of the blocks, the following description focuses only on one combination of the blocks.
因此,本實施形式的製造方法中,組合設定步驟S4中使用此初步所設定的塊材的組合時,藉由模擬來對照明光路中之光的偏光狀態的變化是否可被抑制在所期望的範圍內進行評價(S5)。具體而言,評價步驟S5中,例如可參照各透鏡(一般而言是光透過構件)的資料(曲率半徑,中心厚度,空氣間隔,折射率等),對曲面鏡(M1,M2)的反射膜的入射角之P-S相位差的設計值(或計測值),測定步驟S3中所得到的各塊材的測定結果(相位前移軸方位,複折射量的分佈),以算出照明光路中之光的偏光狀態的變化。Therefore, in the manufacturing method of the present embodiment, when the combination of the initially set blocks is used in the combination setting step S4, whether or not the change in the polarization state of the light in the illumination light path can be suppressed by the simulation is desired. Evaluation is performed within the range (S5). Specifically, in the evaluation step S5, for example, the reflection of the curved mirror (M1, M2) can be referred to the data (curvature radius, center thickness, air gap, refractive index, etc.) of each lens (generally a light transmitting member). The design value (or measurement value) of the PS phase difference of the incident angle of the film is measured in the measurement result (phase forward axis direction and birefringence amount) of each block obtained in step S3 to calculate the illumination light path. The change in the polarization state of light.
然而,在記述上述偏光狀態的方法中,可使用Stokes參數(S0 ,S1 ,S2 ,S3 )。此處,S0 定義成光的全強度(I0° +I90° )、S1 是橫偏光和縱偏光的強度差(I0° -I90° )、S2 是45度偏光和135度偏光的強度差(I45° -I135° )、S3 是右轉偏光和左轉偏光 之強度差(I右轉 -I左轉 )。又,亦可使用S0 已正規化成1之基準化Stokes參數(S1 ’,S2 ’,S3 ’)。此處,S1 ’=S1 /S0 、S2 ’=S2 /S0 、S3 ’=S3 /S0 。However, in the method of describing the above-described polarization state, Stokes parameters (S 0 , S 1 , S 2 , S 3 ) can be used. Here, S 0 is defined as the full intensity of light (I 0° + I 90° ), S 1 is the intensity difference between the transversely polarized light and the longitudinally polarized light (I 0° - I 90° ), S 2 is the 45-degree polarized light, and 135 The intensity difference of the degree of polarization (I 45° - I 135° ), and S 3 is the difference in intensity between right - handed polarization and left-handed polarization (I turn right - I turn left ). Further, a reference Stokes parameter (S 1 ', S 2 ', S 3 ') in which S 0 has been normalized to 1 may be used. Here, S 1 '=S 1 /S 0 , S 2 '=S 2 /S 0 , and S 3 '=S 3 /S 0 .
如圖14(a)所示,評價步驟S5中,光線入射至光學系統的入射瞳的矩形格子點上。此時,如圖14(b)所示,全部的入射光線是橫偏光時,其基準化Stokes參數(S1 ’,S2 ’,S3 ’)=(1,0,0)。評價步驟S5中藉由對偏光光線追蹤之測試,則可藉由光透過構件之內部偏斜所造成的複折射性的影響或曲面鏡(M1,M2)的反射膜的P-S相位差的影響來算出”是否有發生像朝著入射瞳的入射光的偏光狀態等那樣的變化”。As shown in Fig. 14 (a), in the evaluation step S5, the light is incident on the rectangular lattice point of the entrance pupil of the optical system. At this time, as shown in FIG. 14(b), when all incident light rays are transversely polarized light, the reference Stokes parameters (S 1 ', S 2 ', S 3 ') = (1, 0, 0). In the evaluation step S5, by the test of the tracking of the polarized light, the influence of the birefringence caused by the internal deflection of the light transmitting member or the influence of the PS phase difference of the reflecting film of the curved mirror (M1, M2) may be It is calculated whether or not there is a change such as a polarization state of incident light toward the entrance pupil.
因此,如圖14(c)所示,對應於入射瞳的矩形格子點以求出射出瞳的偏光圖。具體而言,就入射瞳的矩形格子點的各光線而言,由入射偏光狀態(S1 ’,S2 ’,S3 ’)=(1,0,0)來求出射出偏光狀態(S1 ”,S2 ”,S3 ”)。在評價步驟S5中,使入射橫偏光成份S1 ’=S(in)、射出橫偏光成份S1 ”=S(out),若S(out)/S(in)=S1 ”/S1 ’≧0.8,則照明光路中之光的偏光狀態的變化可評價為”被抑制在所期望的範圍內”。Therefore, as shown in FIG. 14(c), a rectangular grid point corresponding to the entrance pupil is obtained to obtain a polarization map of the emission pupil. Specifically, for each ray of a rectangular lattice point incident on the 瞳, the incident polarization state (S 1 ', S 2 ', S 3 ') = (1, 0, 0) is used to determine the emission polarization state (S 1 ", S 2 ", S 3 "). In the evaluation step S5, the incident transversely polarized light component S 1 '=S(in) is emitted, and the horizontally polarized light component S 1 ′′=S(out) is output, if S(out) /S(in)=S 1 ”/S 1 '≧0.8, the change in the polarization state of the light in the illumination light path can be evaluated as “suppressed within a desired range”.
又,如圖14(d)所示,縱偏光的光線入射至光學系統的入射瞳的矩形格子點上時的情況亦相同,此時若S(out)/S(in)=S1 ”/S1 ’≧0.8,則照明光路中之光的偏光狀態的變化可評價為”被抑制在所期望的範圍內”。又,如上所述,高數值孔徑的投影光學系統的成像性能向上提高時,可有效地使用周圍方向偏光狀態。此處,如圖15(a)所示, 評價步驟S5中入射瞳分割成4份,使全體成為周圍方向偏光狀態,偏光方向不同的光線亦可入射至每個瞳分割區域中。然而,圖15(a)中,為了說明時可更簡單,矩形格子點的一部份已省略。Further, as shown in Fig. 14 (d), the case where the light of the longitudinally polarized light is incident on the rectangular lattice point of the entrance pupil of the optical system is the same, and if S(out) / S(in) = S 1 "/ When S 1 '≧0.8, the change in the polarization state of the light in the illumination light path can be evaluated as "suppressed within the desired range." Further, as described above, the imaging performance of the high numerical aperture projection optical system is increased upward. In the evaluation step S5, the incident enthalpy is divided into four parts, and the whole direction is polarized in the peripheral direction, and light having a different polarization direction can also be incident on the photo-indicating state in the peripheral direction as shown in Fig. 15 (a). In each of the 瞳 divided regions, however, in Fig. 15(a), for the sake of explanation, a part of the rectangular lattice points has been omitted.
上述情況中,橫偏光的光線入射至瞳分割區域A和B中,縱偏光的光線入射至瞳分割區域C和D中。因此,入射光線的基準化Stokes參數(S1 ’,S2 ’,S3 ’)在區域A和B中成為(1,0,0),且在區域C和D中成為(-1,0,0)。然後,入射光線的偏光狀態完全維持在理想狀態中時,與區域A和B相對應的射出光線的基準化Stokes參數(S1 ”,S2 ”,S3 ”)成為(1,0,0),且與區域C和D相對應的射出光線的基準化Stokes參數(S1 ”,S2 ”,S3 ”)成為(-1,0,0)。因此,即使在此種情況下S(out)/S(in)=S1 ”/S1 ’≧0.8時,照明光路中之光的偏光狀態的變化仍可評價為”被抑制在所期望的範圍內”。In the above case, the light of the transversely polarized light is incident into the pupil division regions A and B, and the light of the longitudinal polarization light is incident into the pupil division regions C and D. Therefore, the reference Stokes parameter (S 1 ', S 2 ', S 3 ') of the incident ray becomes ( 1 , 0, 0) in the regions A and B, and becomes (-1, 0) in the regions C and D. , 0). Then, when the polarization state of the incident ray is completely maintained in the ideal state, the reference Stokes parameters (S 1 ", S 2 ′, S 3 ′′) of the emitted ray corresponding to the regions A and B become (1, 0, 0). And the reference Stokes parameters (S 1 ", S 2 ", S 3 ") of the emitted rays corresponding to the regions C and D become (-1, 0, 0). Therefore, even in this case, when S(out)/S(in)=S 1 ”/S 1 '≧0.8, the change in the polarization state of the light in the illumination light path can be evaluated as "suppressed at the desired Within the scope".
同樣,如圖15(b)所示,入射瞳分割成8份,使全體成為周圍方向偏光狀態,偏光方向不同的光線亦可入射至每個瞳分割區域中。然而,在圖15(b)中,為了說明時可更簡單,矩形格子點的一部份已省略。此時,入射光線的基準化Stokes參數(S1 ’,S2 ’,S3 ’)在瞳分割區域A和B中成為(1,0,0),在瞳分割區域C和D中成為(-1,0,0),在瞳分割區域E和F中成為(0,1,0),且在瞳分割區域G和H中成為(0,-1,0)。Similarly, as shown in FIG. 15(b), the incident 瞳 is divided into eight parts, and the entire light is in a peripherally polarized state, and light rays having different polarization directions may be incident on each of the 瞳 division regions. However, in Fig. 15(b), for the sake of simplicity, a part of the rectangular lattice points has been omitted. At this time, the reference Stokes parameters (S 1 ', S 2 ', S 3 ') of the incident ray become (1, 0, 0) in the 瞳 division regions A and B, and become (in the 瞳 division regions C and D) ( -1, 0, 0) is (0, 1, 0) in the 瞳 division regions E and F, and becomes (0, -1, 0) in the 瞳 division regions G and H.
然後,入射光線的偏光狀態完全維持在理想狀態中 時,與區域A和B相對應的射出光線的基準化Stokes參數(S1 ”,S2 ”,S3 ”)成為(1,0,0),與區域C和D相對應的射出光線的基準化Stokes參數(S1 ”,S2 ”,S3 ”)成為(-1,0,0),與區域E和F相對應的射出光線的基準化Stokes參數(S1 ”,S2 ”,S3 ”)成為(0,1,0),與區域G和H相對應的射出光線的基準化Stokes參數(S1 ”,S2 ”,S3 ”)成為(0,-1,0)。因此,在與區域A~D相對應時,S(out)/S(in)=S1 ”/S1 ’≧0.8,且在與區域E~H相對應時,S(out)/S(in)=S2 ”/S2 ’≧0.8時,則照明光路中之光的偏光狀態的變化可評價為”被抑制在所期望的範圍內”。Then, when the polarization state of the incident ray is completely maintained in the ideal state, the reference Stokes parameters (S 1 ", S 2 ′, S 3 ′′) of the emitted ray corresponding to the regions A and B become (1, 0, 0). ), the reference Stokes parameters (S 1 ", S 2 ", S 3 ") of the emitted rays corresponding to the regions C and D become (-1, 0, 0), and the emitted rays corresponding to the regions E and F The normalized Stokes parameters (S 1 ", S 2 ", S 3 ") become (0, 1, 0), the reference Stokes parameters (S 1 ", S 2 " of the emitted rays corresponding to the regions G and H" , S 3 ”) becomes (0, -1, 0). Therefore, when corresponding to the regions A to D, S(out)/S(in)=S 1 ”/S 1 '≧0.8, and when corresponding to the regions E to H, S(out)/S( When in)=S 2 ”/S 2 '≧0.8, the change in the polarization state of the light in the illumination light path can be evaluated as “suppressed within a desired range”.
又,在上述的說明中,在入射瞳的每個光線圖中決定偏光指標(評價指標)以顯示最佳化的基準。實際的照明光學裝置中,二次光源成為圓形狀,環形狀,4極狀等等,且在入射瞳面內保持著面積。因此,在評價步驟S5時各二次光源中其開口內所含的光線的偏光指標S(out)/S(in)的平均值在0.8以上時之值作為最佳化的基準。又,在上述的說明中,雖然是以照明區域內與1點有關的瞳內光線圖的偏光狀態來描述,但照明裝置的全體亦以偏光指標S(out)/S(in)的平均值在0.8以上時之值作為最佳化的基準。Further, in the above description, the polarization index (evaluation index) is determined in each ray diagram of the incident pupil to display the criterion for optimization. In an actual illumination optical device, the secondary light source has a circular shape, a ring shape, a quadrupole shape, and the like, and maintains an area in the incident pupil plane. Therefore, in the evaluation step S5, the value of the average value of the polarization index S(out)/S(in) of the light contained in the opening in each of the secondary light sources is 0.8 or more as a criterion for optimization. Further, in the above description, although the polarization state of the intra-orbital ray diagram related to one point in the illumination region is described, the illumination device has the average value of the polarization index S(out)/S(in). The value at or above 0.8 is used as a benchmark for optimization.
又,在評價步驟S5中,照明區域內與各點有關的偏光指標S(out)/S(in)的平均值的偏移大小在0.05以下時之值作為最佳化的基準。又,在評價步驟S5中,為了簡單之故,以光罩遮板12和光罩M之間的部份光學系統作為對象。此處,此部份光學系統具有曲面鏡(M1,M2)和會受內 部偏斜的影響的大直徑之透鏡。Further, in the evaluation step S5, the value of the shift value of the average value of the polarization index S(out)/S(in) relating to each point in the illumination region is 0.05 or less as a criterion for optimization. Further, in the evaluation step S5, for the sake of simplicity, a part of the optical system between the mask shutter 12 and the mask M is targeted. Here, this part of the optical system has a curved mirror (M1, M2) and will be affected by A large diameter lens that is affected by the deflection.
如上所述,評價步驟S5中上述組合設定步驟S4初期所選定的塊材的組合被加工成各光透過構件且在初期所決定的旋轉角度位置中分別決定各光透過構件的位置時,對”是否可滿足上述最佳化的基準”以及進而對”照明光路中之光的偏光狀態的變化是否被抑制在所期望的範圍內”進行評價。評價結果若是肯定時(圖13中YES時),則進入加工步驟S6以對各塊材進行加工而形成各光透過構件。As described above, in the evaluation step S5, when the combination of the blocks selected in the initial stage of the combination setting step S4 is processed into the respective light transmission members and the positions of the respective light transmission members are determined in the initial rotation angle positions, Whether or not the above-described optimization criterion can be satisfied and whether or not the change in the polarization state of the light in the illumination light path is suppressed within a desired range is evaluated. When the evaluation result is affirmative (YES in FIG. 13), the process proceeds to process step S6 to process each of the blocks to form each of the light-transmitting members.
另一方面,評價結果若是否定時(圖13中NG時),則須使任意的塊材(光透過構件)的旋轉角度位置變更(S7)。On the other hand, if the evaluation result is timed (in the case of NG in Fig. 13), the rotation angle position of an arbitrary block (light transmitting member) must be changed (S7).
即,在變更步驟S7中,須對場內的偏光狀態進行調整使大致上成為均一狀,且同時為了使瞳面內的偏光狀態調整成近似於所期望的偏光狀態,則此時適合使用上述之摩擦脫色(crocking)手段。然後,在上記任意的光透過構件變更後的旋轉角度位置中直接決定位置時,對照明光路中之光的偏光狀態的變化是否”被抑制在所期望的範圍內”進行評價。例如,此處藉由摩擦脫色手段所造成的各塊材(光透過構件)的基準軸(光軸旋轉)的旋轉角度位置的最佳化,以對”是否得到對內部偏斜所造成之複折射量應受適當地抑制之光學系統的光軸並不對稱之複折射分佈的最佳化”進行評價。That is, in the changing step S7, it is necessary to adjust the polarization state in the field to be substantially uniform, and at the same time, in order to adjust the polarization state in the pupil plane to approximate the desired polarization state, the above-mentioned The means of frictional crocking. Then, when the position is directly determined in the rotation angle position after the change of the arbitrary light transmission member, the change in the polarization state of the light in the illumination light path is suppressed to be within the desired range. For example, here, the rotation angle position of the reference axis (optical axis rotation) of each block (light transmission member) caused by the friction decoloring means is optimized to "whether or not the internal deflection is caused. The amount of refraction should be evaluated by the optimization of the optical axis of the optical system which is appropriately suppressed and the asymmetric birefringence distribution.
評價結果若是肯定時,則進入加工步驟S6,評價結果若是否定時,則重複上述之變更步驟S7和評價步驟S5直至得到肯定的評價結果時為止。在評價步驟S5中若得到 肯定的評價結果時,則如上所述在加工步驟S6中對各塊材進行加工以形成各光透過構件。經由加工步驟S6所形成的各光透過構件在評價步驟S5中分別設定在已最佳化之旋轉角度位置中以進行組構(S8)。If the evaluation result is affirmative, the process proceeds to the process step S6, and if the evaluation result is timed, the above-described change step S7 and evaluation step S5 are repeated until an affirmative evaluation result is obtained. If obtained in the evaluation step S5 In the case of a positive evaluation result, each of the blocks is processed in the processing step S6 as described above to form each of the light-transmitting members. Each of the light-transmitting members formed through the processing step S6 is set in the optimized rotation angle position in the evaluation step S5 to perform the configuration (S8).
又,在上述之本實施形式的製造方法中,若在評價步驟S5中不易得到肯定的評價結果,如圖13所示,則例如須將任意的塊材變更為另一種組合塊材(S9)。進而亦可變更塊材的組合。又,第2變更步驟S9中亦可使任意的塊材變更成滿足最佳化的基準時已給予之所期望的複折射分佈之塊材。以下,就給予所期望的複折射分佈時所用的手段來作簡單的說明。Further, in the manufacturing method of the present embodiment described above, if it is difficult to obtain an affirmative evaluation result in the evaluation step S5, as shown in Fig. 13, for example, an arbitrary block material must be changed to another type of composite block (S9). . Further, the combination of the blocks can be changed. Further, in the second changing step S9, an arbitrary block material may be changed to a block material having a desired birefringence distribution which is given when the optimization criterion is satisfied. Hereinafter, a means for giving a desired birefringence distribution will be briefly described.
例如,石英或已摻雜氟元素之石英(以下稱為”改質石英)之類的非結晶材料所形成的非結晶透過構件的情況下,其理想的狀態下不會發生複折射率。然而,石英或改質石英中混入雜質時或使高溫中形成的石英冷卻而產生溫度分佈時,會顯現出由內部應力所造成的複折射性。For example, in the case of an amorphous conductive member formed of quartz or an amorphous material such as quartz doped with fluorine (hereinafter referred to as "modified quartz"), the complex refractive index does not occur in an ideal state. When quartz or modified quartz is mixed with impurities or the quartz formed at a high temperature is cooled to generate a temperature distribution, birefringence due to internal stress is exhibited.
因此,藉由混入鑄塊中的雜質的量或種類,或藉由熱過程之調整,則可在石英或改質石英中發生所期望的複折射分佈。換言之,藉由製造時雜質、熱過程所造成的密度分佈此二者中至少一種進行調整,則可在非結晶透過構件中給予一種對光軸係旋轉對稱(或非旋轉對稱)之所期望的複折射分佈。Therefore, the desired birefringent distribution can occur in quartz or modified quartz by the amount or type of impurities mixed in the ingot, or by adjustment of the thermal process. In other words, by adjusting at least one of the impurity distribution and the density distribution caused by the thermal process, a desired rotational symmetry (or non-rotational symmetry) to the optical axis can be imparted in the amorphous transmission member. Complex refraction distribution.
又,舉例而言,OH,Cl,金屬雜質,可溶的氣體都可作為雜質,直接方法時,可考慮一種由混入量來支配的含 有數百pp以上的OH,其次是考慮一含有數十pp的Cl。這些雜質混入鑄塊中時由於會使材料的熱膨脹發生變化(例如,退火後冷卻時),則雜質已混入的部份的收縮部份會變大,會發生一種由收縮差所造成的內部應力而產生應力複折射。又,關於熱過程而言,無論依據上述直接法,VAD(vapor axial deposition)法,溶膠凝膠(sol-gel)法,電漿燒蝕(plasma burner)法等的製造方法中那一種都存在。Further, for example, OH, Cl, metal impurities, and soluble gases can be used as impurities. In the direct method, a content governed by the amount of mixing can be considered. There are hundreds of pp or more of OH, and secondly, consider a Cl containing tens of pp. When these impurities are mixed into the ingot, the thermal expansion of the material changes (for example, when it is cooled after annealing), the shrinkage portion of the portion where the impurities have been mixed becomes large, and an internal stress caused by the difference in shrinkage occurs. And stress birefringence occurs. Further, regarding the thermal process, regardless of the direct method described above, the VAD (vapor axial deposition) method, the sol-gel method, the plasma ablation method, and the like are all present in the manufacturing method. .
又,在上述之本實施形式的製造方法中,經過評價步驟S5之後,進行加工步驟S6,以對各塊材進行加工而形成各光透過構件。然而,不限於此方式,亦可在測定步驟S3之後首先進行評價步驟S5或亦可與評價步驟S5同時進行該加工步驟S6。Moreover, in the manufacturing method of the above-described embodiment, after the evaluation step S5, the processing step S6 is performed, and each of the blocks is processed to form each of the light-transmitting members. However, the present invention is not limited to this, and the evaluation step S5 may be performed first after the measurement step S3 or may be performed simultaneously with the evaluation step S5.
又,在上述之本實施形式的製造方法中,測定步驟S3之後亦可付加塊材挑選步驟,以挑選出複折射量被抑制成5nm/cm以下的塊材。此時,在評價步驟S5中容易得到肯定的評價結果。又,評價步驟S5中更容易得到肯定的評價結果時,則挑選步驟中較佳是挑選複折射量被抑制成2nm/cm以下的塊材。Further, in the above-described manufacturing method of the present embodiment, after the measurement step S3, a block picking step may be added to select a block in which the amount of birefringence is suppressed to 5 nm/cm or less. At this time, an affirmative evaluation result is easily obtained in the evaluation step S5. Further, when it is easier to obtain an affirmative evaluation result in the evaluation step S5, it is preferable to select a block in which the amount of birefringence is suppressed to 2 nm/cm or less.
如上所述,藉由已對第1至第4手段進行評價之第5手段所造成的實施形式顯示在圖16中。如圖16所示,在保持適當的內部應力所用的光學構件被選定的步驟S10中,藉由光學構件的計測,以選定複折射量被抑制成5nm/cm以下的塊材或透鏡等,以便對光學構件的內部偏斜所造成的複折射量進行管理。此處,在與圖15的第4手段 的步驟相對應下,圖16的步驟S10包含步驟S1,步驟S2和步驟S3。As described above, the embodiment resulting from the fifth means for evaluating the first to fourth means is shown in Fig. 16. As shown in FIG. 16, in the step S10 in which the optical member for holding appropriate internal stress is selected, the block or lens or the like which is selected to have a birefringence amount of 5 nm/cm or less is selected by measurement of the optical member so that The amount of birefringence caused by the internal deflection of the optical member is managed. Here, in the fourth means with FIG. Corresponding to the steps, step S10 of Fig. 16 includes step S1, step S2 and step S3.
又,步驟S10中,雖然主要是就光透過性的光學構件來說明,但偏光設定部(3,7)和被照射面(光罩等)之間的光路中所配置的光學系統含有反射構件時,不用說亦期望選定一種反射構件,使得對該反射構件的反射膜以P偏光入射的光和以S偏光入射的光之間由於反射所發生的相位差相對於入射至反射膜中的全部的光線而言成為在15度以內。Further, in step S10, although the optical member is mainly described as a light transmissive optical member, the optical system disposed in the optical path between the polarized light setting unit (3, 7) and the illuminated surface (such as a mask) contains a reflective member. It is needless to say that it is also desirable to select a reflection member such that a phase difference due to reflection between light incident on the reflection film of the reflection member and light incident on the S-polarized light is relative to all incident on the reflection film. The light is within 15 degrees.
又,為了使此裝置有更高的性能,不用說更期望選定一種由內部偏斜所造成的複折射量已被抑制在2nm/cm以下的光學構件。Further, in order to make the device have higher performance, it is needless to say that it is more desirable to select an optical member whose amount of birefringence caused by internal deflection has been suppressed to 2 nm/cm or less.
其次,在與圖15的第4手段的步驟相對應下,旋轉角度的位置之設定步驟S11包含步驟S4,步驟S5,步驟S7和步驟S9。例如,步驟S11中,藉由摩擦脫色(crocking)手段所造成的各光學構件(塊材、光透過構件)的基準軸(光軸旋轉)的旋轉角度位置的最佳化,則可對”是否得到對內部偏斜所造成之複折射量應受適當地抑制之光學系統的光軸並不對稱之複折射分佈的最佳化”進行評價。又,步驟S11中,偏光設定部(3,7)和被照射面(光罩等)之間的光路中所配置的光學系統含有反射構件時,則此光學系統含有步驟S10中已選定的反射構件的反射特性且對反射特性進行評價。Next, in response to the step of the fourth means of Fig. 15, the setting step S11 of the position of the rotation angle includes step S4, step S5, step S7 and step S9. For example, in step S11, by optimizing the rotational angle position of the reference axis (optical axis rotation) of each optical member (block, light transmitting member) caused by the frictional crocking means, it is possible to It was evaluated that the amount of birefringence caused by the internal deflection should be optimized by the optical axis of the optical system and the asymmetric birefringence distribution which are appropriately suppressed. Further, in step S11, when the optical system disposed in the optical path between the polarization setting unit (3, 7) and the illuminated surface (such as a mask) includes a reflection member, the optical system includes the reflection selected in step S10. The reflection characteristics of the members and the reflection characteristics were evaluated.
此處,步驟S11中未達成最佳化時,則回到步驟S10 中,再度選定一種保持著適當的內部偏斜分佈之光學構件。步驟S11中已達成最佳化時進行下一步驟S12。Here, when the optimization is not achieved in step S11, the process returns to step S10. Among them, an optical member that maintains an appropriate internal deflection distribution is again selected. When the optimization has been completed in step S11, the next step S12 is performed.
在光學系統(光學單元)的製造步驟S12中,在與圖15的第4手段的步驟相對應下,此製造步驟S12包含各光學構件的加工形成的步驟S6和各光學構件的組構步驟S8。此處,步驟S12中,在對經由各光學構件的加工形成的步驟之光學構件進行組構時,如圖9至圖12所示,其包含光學構件的保持或支持所需的步驟,使藉由外部所給予的偏斜(應力等)所產生的複折射量被抑制在5nm/cm以下。即,步驟S12中包含一種對由外部所給予的偏斜所造成的複折射量或複折射分佈進行管理之步驟,此種管理步驟包含上記之保持步驟。In the manufacturing step S12 of the optical system (optical unit), in accordance with the steps of the fourth means of FIG. 15, the manufacturing step S12 includes the step S6 of forming the respective optical members and the fabricating step S8 of the optical members. . Here, in step S12, when the optical member of the step formed by the processing of each optical member is assembled, as shown in FIGS. 9 to 12, it includes the steps required for holding or supporting the optical member, so as to borrow The amount of birefringence generated by the deflection (stress or the like) given from the outside is suppressed to 5 nm/cm or less. That is, step S12 includes a step of managing the amount of birefringence or birefringence distribution caused by the skew given by the outside, and this management step includes the above-described holding step.
又,步驟S12中,為了使此裝置有更高的性能,不用說更期望藉由保持一種光學構件,使由內部偏斜所產生的複折射量被抑制在2nm/cm。Further, in step S12, in order to make the apparatus have higher performance, it is needless to say that by maintaining an optical member, the amount of birefringence caused by internal deflection is suppressed to 2 nm/cm.
如上所述,若以一個觀點來描述圖16中所示的手段,則藉由偏光設定部(3,7)和被照射面(光罩等)之間的光路中所配置的光學系統的複折射量管理用之步驟,或藉由偏光設定部和被照射面之間的光路中複折射量已受到管理之光學系統配置時所提及的手段,由被照射面上進而由瞳面上都可得到良好的偏光狀態的照明分佈。As described above, if the means shown in Fig. 16 is described from one viewpoint, the complex of the optical system disposed in the optical path between the polarized light setting portion (3, 7) and the illuminated surface (photomask, etc.) The step of managing the amount of refraction, or the means mentioned in the optical system configuration in which the amount of birefringence in the optical path between the polarized light setting portion and the illuminated surface has been managed, from the illuminated surface to the top surface A good distribution of illumination in a polarized state can be obtained.
又,若以一個觀點來描述圖16中所示的手段,則藉由偏光設定部和被照射面之間的光路中所配置的光學系統,使入射至被照射面上的光之偏光狀態成為所定的偏光狀 態,由偏光設定部和被照射面為止之間的光路中之偏光特性被保持時所用的步驟中、或偏光設定部和被照射面之間的光路中被照射面上的光的偏光狀態成為所定的偏光狀態,藉由到達被照射面上的光的偏光狀態被保持時所用的光學系統配置時所提及的手段,則由被照射面上進而由瞳面上都可得到良好的偏光狀態的照明分佈。Moreover, when the means shown in FIG. 16 is described from one viewpoint, the optical state of the light incident on the illuminated surface is made by the optical system disposed in the optical path between the polarized light setting portion and the surface to be illuminated. Specified polarization The state in which the polarization characteristic in the optical path between the polarization setting unit and the illuminated surface is maintained, or the polarization state of the light on the illuminated surface in the optical path between the polarization setting unit and the illuminated surface becomes In the predetermined polarization state, the means mentioned in the arrangement of the optical system used when the polarization state of the light reaching the illuminated surface is maintained, a good polarization state can be obtained from the illuminated surface and the surface of the surface. The distribution of lighting.
在以上的二種觀點中,期望可得到偏光設定部和被照射面之間與光路中所配置的1種或1種以上之光學系統(包含光學系統全部)有關的資訊(例如,與複折射等有關的光學系統所容許的光學性能資訊且如圖13的步驟S3所示與構成光學系統所用的至少1個光學構件的複折射有關的測定等的資訊的至少1種資訊等)。In the above two aspects, it is desirable to obtain information relating to one or more optical systems (including all optical systems) disposed between the polarization setting unit and the illuminated surface (for example, and birefringence). The optical performance information permitted by the optical system is at least one type of information such as measurement relating to birefringence of at least one optical member used in the optical system, as shown in step S3 of FIG.
又,圖16中雖然依據由塊材所得到的複折射量的計測值以舉例方式來顯示光學構件管理的進行,但亦可對塊材來進行所定的加工以形成透鏡等的光學構件,依據已加工的光學構件的複折射量或複折射分佈來進行該步驟S10。此時,步驟S12內的光學構件的加工步驟已不需要而可進行各光學構件的組構步驟。Further, in FIG. 16, although the measurement of the optical component management is performed by way of example based on the measured value of the birefringence amount obtained by the bulk material, the block member may be subjected to predetermined processing to form an optical member such as a lens, depending on This step S10 is performed by the birefringence or birefringence distribution of the processed optical member. At this time, the processing steps of the optical members in the step S12 are not required, and the constituent steps of the respective optical members can be performed.
又,圖16中雖然以照明裝置或具備照明光學裝置之曝光裝置之製造例為主來說明,但就照明光學裝置定期的維護(修理、保持,點檢)時的情況而言,可挪用圖16來作說明。In addition, although the manufacturing example of the illuminating device or the exposure device provided with the illuminating optical device is mainly shown in FIG. 16, the case where the illuminating optical device is regularly maintained (repair, hold, check) can be used. 16 to illustrate.
首先,在維護時,在選定適當的切換用的光學構件或適當的切換用的光學單元的步驟S20中,首先預先獲得一 種與照明光學系統有關的偏光光學性能等的資訊(偏光測定部14的實計測值或照明光學系統的製造時的計測值等的資訊)、偏光測定部與被照射面之間的光路中與所配置的光學系統有關之複折射特性或偏光特性等的光學資訊(偏光測定部14的實測值或光學系統的製造時的計測值等的資訊)、或偏光測定部與被照射面之間的光路中與所配置的光學系統的至少1個光學構件有關的偏光光學性能的資訊(偏光測定部14的實測值或光學構件製造時的計測值等的資訊)的至少1種。然後,如上所記,依據與所得到的光學系統有關的資訊,以限定應切換之光學構件或光學單元,且選定一種可使由內部偏斜所造成的複折射量被抑制在5nm/cm以下之適當的切換用的光學構件或適當的切換用的光學單元。First, at the time of maintenance, in step S20 of selecting an appropriate optical member for switching or an optical unit for switching, first, one is obtained in advance. Information such as the polarization optical performance of the illumination optical system (information such as the measured value of the polarization measuring unit 14 or the measurement value at the time of manufacture of the illumination optical system), and the optical path between the polarization measuring unit and the illuminated surface Optical information such as the birefringence characteristic or the polarization characteristic of the optical system to be disposed (information such as the actual measurement value of the polarization measuring unit 14 or the measurement value at the time of manufacturing the optical system) or between the polarization measuring unit and the illuminated surface At least one of information on the optical properties of the optical path (the measured value of the polarization measuring unit 14 or the measured value at the time of manufacturing the optical member) relating to at least one optical member of the optical system to be disposed in the optical path. Then, as noted above, based on information relating to the resulting optical system, to define the optical member or optical unit to be switched, and to select one that can reduce the amount of birefringence caused by internal deflection to less than 5 nm/cm. An appropriate optical member for switching or an appropriate optical unit for switching.
其次,各光學構件加工之後,將各光學構件組構至照明光學系統內。在此種組構步驟中包含光學構件的保持或支持步驟,使由外部所施加的偏斜(應力)所產生的複折射量被抑制在5nm/cm以下。即,步驟S22中包含一種管理步驟,其對由外部所施加的偏斜所產生的複折射量或複折射分佈進行管理,此管理步驟包含上述之保持步驟。Next, after each optical member is processed, each optical member is assembled into an illumination optical system. The holding or supporting step of the optical member is included in such a constitutional step such that the amount of birefringence generated by the deflection (stress) applied from the outside is suppressed to 5 nm/cm or less. That is, step S22 includes a management step of managing the amount of birefringence or birefringence distribution generated by the deflection applied from the outside, and the management step includes the above-described holding step.
又,圖16的步驟S20中,雖然是依據由塊材所獲得之複折射量的計測值以顯示該光學構件的管理進行時之範例,但亦可對塊材進行所定的加工以形成透鏡等的光學構件,依據加工後的光學構件的複折射量或複折射分佈,以進行該步驟S20。此時,在光學系統的製造步驟(調整步 驟)S22內的光學構件的加工步驟已不需要之下即可進行各光學構件的組構步驟。Further, in the step S20 of FIG. 16, the measurement of the amount of the birefringence obtained by the block is used to show an example in which the management of the optical member is performed, but the block may be subjected to predetermined processing to form a lens or the like. The optical member is subjected to the step S20 according to the birefringence amount or the birefringence distribution of the processed optical member. At this time, in the manufacturing steps of the optical system (adjustment step) The processing steps of the optical members in S22 can be performed without the need for the construction steps of the optical members.
如上所示,若以一個觀點來描述圖16中所示的維護手段,則藉由偏光設定部(3,7)和被照射面(光罩等)之間的光路中所配置的光學系統的複折射量管理用之步驟,或藉由偏光設定部和被照射面之間的光路中複折射量已受到管理之光學系統配置時所提及的手段,由被照射面上進而由瞳面上都可得到良好的偏光狀態的照明分佈。As described above, if the maintenance means shown in Fig. 16 is described from one viewpoint, the optical system disposed in the optical path between the polarization setting portion (3, 7) and the illuminated surface (mask, etc.) The step of managing the birefringence amount, or the means mentioned in the optical system configuration in which the amount of birefringence in the optical path between the polarized light setting portion and the illuminated surface has been managed, from the illuminated surface to the upper surface A good distribution of illumination in a polarized state can be obtained.
又,若以一個觀點來描述圖16中所示的維護手段,則藉由偏光設定部和被照射面之間的光路中所配置的光學系統,使入射至被照射面上的光之偏光狀態成為所定的偏光狀態,由偏光設定部和被照射面為止之間的光路中之偏光特性被保持時所用的步驟中、或偏光設定部和被照射面之間的光路中被照射面上的光的偏光狀態成為所定的偏光狀態,藉由到達被照射面上的光的偏光狀態被保持時所用的光學系統配置時所提及的手段,則由被照射面上進而由瞳面上都可得到良好的偏光狀態的照明分佈。Further, when the maintenance means shown in Fig. 16 is described from one viewpoint, the polarization state of the light incident on the illuminated surface is made by the optical system disposed in the optical path between the polarization setting portion and the illuminated surface. In a predetermined polarization state, in the step used when the polarization characteristic in the optical path between the polarization setting unit and the illuminated surface is held, or in the light path on the illuminated surface between the polarization setting unit and the illuminated surface The polarized state is a predetermined polarized state, and the means mentioned in the arrangement of the optical system used when the polarized state of the light reaching the illuminated surface is maintained is obtained from the illuminated surface and the upper surface. Good distribution of illumination in a polarized state.
在以上的二種觀點中,期望可得到偏光設定部和被照射面之間與光路中所配置的1種或1種以上之光學系統(包含光學系統全部)有關的資訊(例如,如圖16的步驟S20所示,與複折射等有關的光學系統所涉及的光學性能的計測等的資訊,以及與構成光學系統所用的至少1個光學構件的複折射有關的測定等的資訊的至少1種資訊等)。In the above two aspects, it is desirable to obtain information relating to one or more optical systems (including all optical systems) disposed between the polarization setting unit and the illuminated surface (for example, as shown in FIG. 16 ). In the step S20, at least one of information such as measurement of optical performance in the optical system related to birefringence or the like, and information on measurement of birefringence of at least one optical member used in the optical system is displayed. Information, etc.).
又,圖16的維護手段中,為了使此裝置有更高的性 能,步驟S20中較佳是使用一種光學構件,使由內部偏斜所產生的複折射量被抑制在2nm/cm以下。又,在步驟S22中,不用說更期望藉由保持一種光學構件,使由外部偏斜所產生的複折射量被抑制在2nm/cm以下。Moreover, in the maintenance means of Fig. 16, in order to make the device more flexible Preferably, in step S20, an optical member is used so that the amount of birefringence generated by internal deflection is suppressed to 2 nm/cm or less. Further, in step S22, it is needless to say that it is more desirable to suppress the amount of birefringence caused by external deflection to be 2 nm/cm or less by holding an optical member.
又,圖16的步驟S10至步驟S12中雖然主要是以照明光學系統的製造方法的內容來說明,但就別的觀點而言,圖16的步驟S10至步驟S12亦可稱為曝光裝置的製造方法,照明光學系統的調整方法或曝光裝置的調整方法。Further, although steps S10 to S12 of FIG. 16 are mainly described as the contents of the manufacturing method of the illumination optical system, from another viewpoint, steps S10 to S12 of FIG. 16 may also be referred to as manufacture of an exposure apparatus. The method, the adjustment method of the illumination optical system, or the adjustment method of the exposure device.
又,圖16的步驟S20至步驟S22中雖然主要是以照明光學系統的調整方法的內容來說明,但就別的觀點而言,圖16的步驟S20至步驟S22亦可稱為曝光裝置的製造方法,照明光學系統的調整方法或曝光裝置的調整方法。Further, although steps S20 to S22 of FIG. 16 are mainly explained by the content of the adjustment method of the illumination optical system, from another viewpoint, steps S20 to S22 of FIG. 16 may also be referred to as manufacture of an exposure apparatus. The method, the adjustment method of the illumination optical system, or the adjustment method of the exposure device.
又,上述的實施形式中,圓錐旋轉三稜鏡(axicon)系統8之前(無焦點透鏡5的瞳或其近旁)配置著偏光變換元件7。然而,不限於此種方式,例如,成像光學系統13的瞳或其近旁或微弗利斯目鏡10之前或之後等亦可配置該偏光變換元件7。然而,成像光學系統13的光路中或微弗利斯目鏡10的前後若配置該偏光變換元件7,則偏光變換元件7所需要的有效直徑容易變大,則此時不能考慮到”在現狀下不易以高品質獲得大的水晶基板”。Further, in the above-described embodiment, the polarization conversion element 7 is disposed before the conical rotary axicon system 8 (with or without the focus of the focus lens 5). However, it is not limited to such a manner, for example, the polarization conversion element 7 may be disposed before or after the pupil of the imaging optical system 13 or its vicinity or the micro-Frisian eyepiece 10. However, if the polarization conversion element 7 is disposed in the optical path of the imaging optical system 13 or before and after the micro-Frisian eyepiece 10, the effective diameter required for the polarization conversion element 7 tends to become large, and at this time, it cannot be considered It is not easy to obtain a large crystal substrate with high quality."
又,上述的實施形式中,偏光變換元件7的至少一面(例如,射出面)形成凹凸狀,進而使偏光變換元件7在周圍方向中具有以離散方式(不連續)而變化的厚度分佈。然而,不限於此種形式,偏光變換元件7的至少一面(例如, 射出面)可形成曲面狀,使偏光變換元件7在周圍方向中具有以幾乎不連續之方式而變化之厚度分佈。Further, in the above-described embodiment, at least one surface (for example, the emitting surface) of the polarization conversion element 7 is formed in a concavo-convex shape, and the polarization conversion element 7 has a thickness distribution which varies in a discrete manner (discontinuously) in the peripheral direction. However, it is not limited to this form, at least one side of the polarization conversion element 7 (for example, The exit surface can be formed in a curved shape, and the polarization conversion element 7 has a thickness distribution that changes in a nearly discontinuous manner in the peripheral direction.
又,上述實施形式中,藉由環狀之有效區域分割成8份所對應的8個扇形狀的基本元件以構成此偏光變換元件7。然而,不限於此種形式,例如,藉由圓形狀之有效區域分割成8份所對應的8個扇形狀的基本元件,或藉由圓形狀或環狀的有效區域分割成4份所對應的4個扇形狀的基本元件,或藉由圓形狀或環狀的有效區域分割成16份所對應的16個扇形狀的基本元件等等亦可構成此偏光變換元件7。即,就偏光變換元件7的有效區域的形狀,有效區域的分割數(基本元件的分割數)等而言可有各種各樣的變形例。Further, in the above embodiment, the polarization conversion element 7 is constituted by dividing the effective area of the ring into eight basic elements of eight fan shapes corresponding thereto. However, the present invention is not limited to this form, for example, by dividing the effective area of the circular shape into 8 basic elements corresponding to 8 sectors, or by dividing the effective area of a circular shape or a ring into 4 parts. The basic element of the four fan shapes, or the basic element of 16 fan shapes corresponding to 16 parts by a circular or annular effective area, may also constitute the polarization conversion element 7. In other words, various modifications are possible in the shape of the effective region of the polarization conversion element 7, the number of divisions of the effective region (the number of divisions of the basic elements), and the like.
又,上述的實施形式中,使用水晶以形成各基本元件7A~7D(進而形成該偏光變換元件7)。然而,不限於此種形式,亦可使用其它具有旋光性的適當的光學材料來形成各基本元件。此時,較佳是使用一種對使用波長的光具有100度/mm以上的旋光能之光學材料。即,若使用旋光能小之光學材料,則為了得到偏光方向所要的旋轉角,所需要的厚度會過大,這會成為光量損失的原因,較佳是不考慮此種情況。Further, in the above-described embodiment, crystals are used to form the respective basic elements 7A to 7D (further, the polarization conversion element 7 is formed). However, it is not limited to this form, and other optical materials having optical rotation may be used to form the respective basic elements. At this time, it is preferred to use an optical material having an optical energy of 100 degrees/mm or more for light of a wavelength. That is, when an optical material having a small optical energy is used, in order to obtain a rotation angle required for the polarization direction, the required thickness is excessively large, which may cause a loss of light amount, and it is preferable not to consider such a case.
上述實施形式所屬的曝光裝置中,藉由照明光學裝置來對光罩(reticule)進行照明(照明步驟),使用投影光學系統使光罩上所形成的轉印(transfer)用的圖樣在感光性基板上曝光(曝光步驟),則可製成微型元件(半導體元件,攝像元 件,液晶顯示元件,薄膜磁性頭等)。以下,將使用上述實施形式的曝光裝置在作為感光性基板的晶圓等之上形成所定的電路圖樣,就得到一種作為微型元件用之半導體元件時的手段的一例而言,將參照圖17的流程圖來說明。In the exposure apparatus according to the above-described embodiment, the reticule is illuminated by the illumination optical device (illumination step), and the transfer pattern formed on the photomask is used for photosensitivity using the projection optical system. Exposure on the substrate (exposure step), can be made into micro-components (semiconductor components, camera elements) Pieces, liquid crystal display elements, thin film magnetic heads, etc.). In the following, an example in which a predetermined circuit pattern is formed on a wafer or the like as a photosensitive substrate by using the exposure apparatus of the above-described embodiment, and an example of a method for obtaining a semiconductor element for a micro device will be described with reference to FIG. Flow chart to illustrate.
首先,圖17的步驟301中,在1批(lot)晶圓上蒸鍍金屬膜。在下一個步驟302中,該1批晶圓上的金屬膜上塗佈光阻。然後,在步驟303中,使用上述實施形式中的曝光裝置,光罩上的圖樣的像經由其投影光學系統而依序曝光轉印至其1批晶圓上的各拍攝(shot)區域中。然後,在步驟304中,在此1批晶圓上的光阻進行顯影之後,在步驟305中此1批晶圓上藉由以光阻圖樣作為光罩以進行蝕刻,則與光罩上的圖樣相對應的電路圖樣形成在各晶圓上的各拍攝區域上。然後,藉由更上層的電路圖樣的形成以製成半導體元件等的裝置。依據上述半導體裝置的製造方法,可在生產量良好的情況下得到一種具有極微細的電路圖樣之半導體裝置。First, in step 301 of FIG. 17, a metal film is deposited on a single lot of wafers. In the next step 302, a photoresist is applied to the metal film on the batch of wafers. Then, in step 303, using the exposure apparatus of the above embodiment, the image of the pattern on the reticle is sequentially exposed and transferred to each shot area on one of the wafers via its projection optical system. Then, in step 304, after the photoresist on the batch of wafers is developed, in step 305, the wafer is etched by using the photoresist pattern as a mask, and then on the mask. A circuit pattern corresponding to the pattern is formed on each of the shot regions on each wafer. Then, a device of a semiconductor element or the like is formed by formation of a circuit pattern of a higher layer. According to the above method for manufacturing a semiconductor device, a semiconductor device having a very fine circuit pattern can be obtained with a good throughput.
又,上述實施形式之曝光裝置中,藉由板(玻璃基板)上形成所定的圖樣(電路圖樣、電極圖樣等),則亦可得到一種作為微型元件用的液晶顯示元件。以下,參照圖18的流程圖,以此時的手段的一例來說明。圖18中,在圖樣形成步驟401中,使用上述實施形式的曝光裝置使光罩的圖樣轉印曝光至感光性基板(塗佈光阻的玻璃基板等),以進行所謂光微影術步驟。藉由此種光微影術步驟,則在感光性基板上可形成一種含有多個電極等之所定的圖樣。然 後,已曝光的基板經過顯影步驟,蝕刻步驟,光阻剝離步驟等各步驟之後,基板上可形成所定的圖樣,以便向下一個濾色器形成步驟402進行。Further, in the exposure apparatus of the above-described embodiment, a predetermined pattern (circuit pattern, electrode pattern, or the like) is formed on a plate (glass substrate), and a liquid crystal display element as a micro device can be obtained. Hereinafter, an example of the means at this time will be described with reference to the flowchart of FIG. 18. In Fig. 18, in the pattern forming step 401, the pattern of the mask is transferred and exposed to a photosensitive substrate (a glass substrate coated with a photoresist, etc.) using the exposure apparatus of the above-described embodiment to perform a so-called photolithography step. By such a photolithography step, a predetermined pattern including a plurality of electrodes or the like can be formed on the photosensitive substrate. Of course Thereafter, after the exposed substrate is subjected to each of the steps of the developing step, the etching step, and the photoresist stripping step, a predetermined pattern can be formed on the substrate for the next color filter forming step 402.
其次,在濾色器形成步驟402中,與紅(R)、綠(G)、藍(B)相對應的3個點(dot)之組一方面由多個配列成矩陣狀,或形成一種濾色器,其中R、G、B的3個線條之濾波器組配置在多條水平掃描方向中。然後,在濾色器形成步驟402之後,進行單元(cell)組立步驟403。在單元(cell)組立步驟403中,使用具有由圖樣形成步驟401中所得到的所定圖樣之基板以及由濾色器形成步驟402所得到之濾色器等來對液晶面板(液晶單元)進行組裝。Next, in the color filter forming step 402, the groups of three dots corresponding to red (R), green (G), and blue (B) are arranged in a matrix or a kind on the one hand. A color filter in which filter banks of three lines of R, G, and B are arranged in a plurality of horizontal scanning directions. Then, after the color filter forming step 402, a cell assembly step 403 is performed. In the cell assembly step 403, the liquid crystal panel (liquid crystal cell) is assembled using the substrate having the predetermined pattern obtained in the pattern forming step 401 and the color filter obtained by the color filter forming step 402. .
在單元(cell)組裝步驟403中,例如,具有所定圖樣(其由圖樣形成步驟401中獲得)之基板和由濾色器形成步驟402中所得到的濾色器之間注入液晶,以製成液晶面板(液晶單元)。然後,在模組組立步驟404中,安裝各種可進行該已組立的液晶面板(液晶單元)的顯示動作所用之電路、背光模組等各構件以完成此液晶顯示元件。依據上述液晶顯示元件的製造方法,可在生產量良好的情況下得到一種具有極微細的電路圖樣之液晶顯示裝置。In a cell assembling step 403, for example, a liquid crystal having a predetermined pattern (which is obtained by the pattern forming step 401) and a color filter obtained by the color filter forming step 402 are injected to form a liquid crystal. Liquid crystal panel (liquid crystal cell). Then, in the module assembly step 404, various components such as a circuit for performing display operation of the assembled liquid crystal panel (liquid crystal cell) and a backlight module are mounted to complete the liquid crystal display element. According to the method for manufacturing a liquid crystal display device described above, a liquid crystal display device having a very fine circuit pattern can be obtained with a good throughput.
又,上述的實施形式中,雖然使用193奈米波長的ArF準分子(excimer)雷射光或248奈米波長的KrF準分子(excimer)雷射光作為曝光光源,但不限於此,亦可使用對本發明適用的其它適當的雷射光源,例如,可使用一種供給157奈米波長的雷射光所用的F2 雷射光源。又,上述的 實施形式中,雖然以具備照明光學裝置的曝光裝置為例來說明本發明,但明顯的是其它可對被照射面進行照明用的一般照明裝置亦可適用於本發明中。Further, in the above-described embodiment, although an ArF excimer laser light of 193 nm wavelength or KrF excimer laser light of 248 nm wavelength is used as the exposure light source, the present invention is not limited thereto, and may be used. Other suitable laser sources to which the invention is applicable, for example, an F 2 laser source for supplying laser light having a wavelength of 157 nm can be used. Further, in the above-described embodiment, the present invention has been described by taking an exposure apparatus including an illumination optical device as an example. However, it is apparent that other general illumination devices that can illuminate an illuminated surface can be applied to the present invention.
又,上述的實施形式中亦適合使用所謂液浸法,此時投影光學系統和感光性基板之間的光路中以折射率較1.1還大的介質(典型上是液體)來填滿。此時,投影光學系統和感光性基板之間的光路中以液體來填滿時所用的手段可採用國際公開編號WO 99/49504號公報中已揭示的局部地填滿液體的手段,或特開平6-124873號公報所揭示的已保持著曝光對象的基板所用的台(stage)被移動至液槽中時的手段,或特開平10-303114號公報中已揭示的台上形成所定深度的液體槽且基板須保持在槽中時所用的手段等。Further, in the above-described embodiment, the so-called liquid immersion method is also suitably employed, and in this case, the optical path between the projection optical system and the photosensitive substrate is filled with a medium (typically liquid) having a refractive index larger than 1.1. In this case, the means for filling the optical path between the projection optical system and the photosensitive substrate with a liquid may be a method of partially filling a liquid, or a special opening, as disclosed in International Publication No. WO 99/49504. In the case where the stage for holding the substrate to be exposed is moved to the liquid bath, the liquid having a predetermined depth is formed on the stage disclosed in Japanese Laid-Open Patent Publication No. Hei 10-303114. The means used for the groove and the substrate to be held in the groove, and the like.
較佳是使用一種只對曝光光束具有透過性且折射率高的液體,其對投影光學系統或基板表面上所塗佈的光阻具有安定性。例如,KrF準分子(excimer)雷射光或ArF準分子雷射光作為曝光光源時,可使用純水、脫離子水作為液體。又,使用F2 雷射光作為曝光光源時,例如亦可使用可透過F2 雷射光之氟系列油或過氟化聚乙烯(PFPE)等的氟元素的液體以作為液體。It is preferred to use a liquid which is only transparent to the exposure beam and has a high refractive index, which has stability to the photoresist applied to the projection optical system or the surface of the substrate. For example, when KrF excimer laser light or ArF excimer laser light is used as an exposure light source, pure water or deionized water can be used as the liquid. Further, when F 2 laser light is used as the exposure light source, for example, a liquid of a fluorine element such as a fluorine series oil or a perfluoropolyethylene (PFPE) which can transmit F 2 laser light can be used as the liquid.
雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明,任何熟習此技藝者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。While the present invention has been described in its preferred embodiments, the present invention is not intended to limit the invention, and the present invention may be modified and modified without departing from the spirit and scope of the invention. The scope of protection is subject to the definition of the scope of the patent application.
1‧‧‧光源1‧‧‧Light source
3‧‧‧偏光狀態切換部3‧‧‧Polarized state switching unit
3a‧‧‧1/4波長板3a‧‧1/4 wavelength plate
3b‧‧‧1/2波長板3b‧‧‧1/2 wavelength plate
4‧‧‧繞射光學元件(光束變換元件)4‧‧‧Diffractive optical elements (beam conversion elements)
5‧‧‧無焦點(afocal)透鏡5‧‧‧Focus-free lens
7‧‧‧偏光變換元件7‧‧‧Polarized light conversion elements
8‧‧‧圓錐8‧‧‧ cone
9‧‧‧變焦透鏡9‧‧‧Zoom lens
10‧‧‧微弗利斯目鏡10‧‧‧ micro-Fris eyepiece
11‧‧‧聚光器光學系統11‧‧‧Condenser optical system
12‧‧‧光罩遮板12‧‧‧Photomask
13‧‧‧成像光學系統13‧‧‧ imaging optical system
14‧‧‧偏光測定部14‧‧‧Polarization Measurement Department
20‧‧‧控制部20‧‧‧Control Department
21‧‧‧驅動部21‧‧‧ Drive Department
M‧‧‧光罩M‧‧‧Photo Mask
PL‧‧‧投影光學系統PL‧‧‧Projection Optical System
W‧‧‧晶圓W‧‧‧ wafer
M1、M2‧‧‧曲面鏡M1, M2‧‧‧ curved mirror
圖1係本發明的實施形式所屬的曝光裝置的構成的概略圖。Fig. 1 is a schematic view showing the configuration of an exposure apparatus according to an embodiment of the present invention.
圖2係圖1的偏光變換元件的構成的概略圖。Fig. 2 is a schematic view showing a configuration of a polarization conversion element of Fig. 1;
圖3係就水晶的旋光性來作說明時的圖解。Fig. 3 is a diagram for explaining the optical rotation of the crystal.
圖4係藉由偏光變換元件的作用而設定成周圍方向偏光狀態的環狀的二次光源的概略圖。4 is a schematic view of a ring-shaped secondary light source that is set to a polarization state in a peripheral direction by the action of a polarization conversion element.
圖5係圖1的偏光測定部的內部構成的概略圖。Fig. 5 is a schematic view showing an internal configuration of a polarization measuring unit of Fig. 1;
圖6係就與光軸有關的旋轉對稱之二次分佈中所遵從之複折射的影響來驗證的第2驗證例說明用的圖解。Fig. 6 is a diagram for explaining the second verification example verified by the influence of the birefringence in the secondary distribution of the rotational symmetry related to the optical axis.
圖7係就一方向中成線形變化的傾斜之一次分佈中所遵從之複折射的影響來驗證的第2驗證例說明用的圖解。Fig. 7 is a diagram for explaining the second verification example verified by the influence of the birefringence in the primary distribution of the inclination of the linear change in one direction.
圖8係先前技術中光透過構件中由外部所作用的力和光透過構件中所產生的應力分佈以模式方式所顯示的圖解。Fig. 8 is a view schematically showing a mode in which a force acting on the outside and a stress distribution generated in the light-transmitting member in the light-transmitting member in the prior art are exemplified.
圖9係本實施形式中光透過構件中由外部所作用的力和光透過構件中所產生的應力分佈以模式方式所顯示的圖解。Fig. 9 is a view schematically showing the force acting on the outside and the stress distribution generated in the light-transmitting member in the light-transmitting member in the present embodiment.
圖10係本實施形式中由二側以三點支持著光透過構件所用的保持構件的構成之概略圖。Fig. 10 is a schematic view showing a configuration of a holding member for supporting a light-transmitting member at three points on both sides in the embodiment.
圖11係光透過構件之有效區域外的全周圍部中具有與光軸直交的面62a之切口部(加工部)形成後的樣式被顯示時的斷面圖。Fig. 11 is a cross-sectional view showing a state in which a notched portion (processed portion) having a surface 62a orthogonal to the optical axis in the entire peripheral portion outside the effective region of the light transmitting member is formed.
圖12係光透過構件之有效區域外的全周圍部中具有與光軸直交的面62a之切口部(加工部)形成後的樣式被顯 示時的斜示圖。Fig. 12 shows a pattern in which a notched portion (processed portion) having a surface 62a orthogonal to the optical axis in the entire peripheral portion outside the effective region of the light transmitting member is formed. An oblique view of the time.
圖13係顯示本實施形式所屬的照明光學裝置的製造方法的各過程所用的流程圖。Fig. 13 is a flow chart showing the processes of the method of manufacturing the illumination optical device to which the embodiment is applied.
圖14係說明本實施形式的製造方法中之評價步驟所用的第1圖。Fig. 14 is a first view for explaining the evaluation procedure in the manufacturing method of the embodiment.
圖15係說明本實施形式的製造方法中之評價步驟所用的第2圖。Fig. 15 is a second view for explaining the evaluation procedure in the manufacturing method of the embodiment.
圖16係顯示本實施形式所屬的照明光學裝置的製造方法(調整方法)的各過程所用的流程圖。Fig. 16 is a flow chart showing the processes of the method (adjustment method) for manufacturing the illumination optical device according to the embodiment.
圖17係作為微型元件用的半導體裝置取得時的手段之流程圖。Fig. 17 is a flowchart showing means for obtaining a semiconductor device for a micro device.
圖18係作為微型元件用的液晶顯示裝置取得時的手段之流程圖。Fig. 18 is a flowchart showing means for obtaining a liquid crystal display device for a micro device.
1‧‧‧光源1‧‧‧Light source
3‧‧‧偏光狀態切換部3‧‧‧Polarized state switching unit
3a‧‧‧1/4波長板3a‧‧1/4 wavelength plate
3b‧‧‧1/2波長板3b‧‧‧1/2 wavelength plate
4‧‧‧繞射光學元件(光束變換元件)4‧‧‧Diffractive optical elements (beam conversion elements)
5‧‧‧無焦點(afocal)透鏡5‧‧‧Focus-free lens
7‧‧‧偏光變換元件7‧‧‧Polarized light conversion elements
8‧‧‧圓錐8‧‧‧ cone
9‧‧‧變焦透鏡9‧‧‧Zoom lens
10‧‧‧微弗利斯目鏡10‧‧‧ micro-Fris eyepiece
11‧‧‧聚光器光學系統11‧‧‧Condenser optical system
12‧‧‧光罩遮板12‧‧‧Photomask
13‧‧‧成像光學系統13‧‧‧ imaging optical system
14‧‧‧偏光測定部14‧‧‧Polarization Measurement Department
20‧‧‧控制部20‧‧‧Control Department
21‧‧‧驅動部21‧‧‧ Drive Department
M‧‧‧光罩M‧‧‧Photo Mask
PL‧‧‧投影光學系統PL‧‧‧Projection Optical System
W‧‧‧晶圓W‧‧‧ wafer
M1、M2‧‧‧曲面鏡M1, M2‧‧‧ curved mirror
Claims (60)
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|---|---|
| TW (1) | TWI437371B (en) |
| WO (1) | WO2006059549A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070019179A1 (en) | 2004-01-16 | 2007-01-25 | Damian Fiolka | Polarization-modulating optical element |
| CN101726863B (en) | 2004-01-16 | 2012-08-29 | 卡尔蔡司Smt有限责任公司 | Polarization-modulating optical element |
| US7324280B2 (en) | 2004-05-25 | 2008-01-29 | Asml Holding N.V. | Apparatus for providing a pattern of polarization |
| EP2009678A4 (en) | 2006-04-17 | 2011-04-06 | Nikon Corp | Illuminating optical apparatus, exposure apparatus and device manufacturing method |
| EP2040284A4 (en) * | 2006-07-12 | 2013-01-23 | Nikon Corp | Illuminating optical apparatus, exposure apparatus and device manufacturing method |
| JP2008070730A (en) * | 2006-09-15 | 2008-03-27 | Sony Corp | Mask blank selection method, birefringence index calculation method, lithography method, mask blank selection apparatus, birefringence index calculation apparatus and program thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19535392A1 (en) * | 1995-09-23 | 1997-03-27 | Zeiss Carl Fa | Radial polarization-rotating optical arrangement and microlithography projection exposure system with it |
| DE10010131A1 (en) * | 2000-03-03 | 2001-09-06 | Zeiss Carl | Microlithography projection exposure with tangential polarization involves using light with preferred direction of polarization oriented perpendicularly with respect to plane of incidence |
| US7301605B2 (en) * | 2000-03-03 | 2007-11-27 | Nikon Corporation | Projection exposure apparatus and method, catadioptric optical system and manufacturing method of devices |
| AU2001277758A1 (en) * | 2000-08-18 | 2002-03-04 | Nikon Corporation | Optical element holding device |
| JP2004179172A (en) * | 2002-06-26 | 2004-06-24 | Nikon Corp | Exposure apparatus, exposure method, and device manufacturing method |
-
2005
- 2005-11-25 WO PCT/JP2005/021693 patent/WO2006059549A1/en not_active Ceased
- 2005-12-02 TW TW094142415A patent/TWI437371B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TW200625024A (en) | 2006-07-16 |
| WO2006059549A1 (en) | 2006-06-08 |
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