TWI415315B - Racetrack nonvolatile memory manufacturing method and structure thereof - Google Patents
Racetrack nonvolatile memory manufacturing method and structure thereof Download PDFInfo
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本發明是有關於一種軌道競賽式非揮發性記憶體,且特別是有關於一種軌道競賽式非揮發性記憶體的製造方法。The present invention relates to an orbital competitive non-volatile memory, and more particularly to a method of manufacturing an orbital non-volatile memory.
【先前技術】美國IBM實驗室的Stuart Parkin先生提出了一種軌道競賽式非揮發性記憶體理論,此理論是基於自旋電子學(Spintronics)技術,使非揮發性記憶體同時兼具半導體記憶體之高存取性能與強固的優點,以及一般硬碟之成本低與容量大的優點。[Prior Art] Mr. Stuart Parkin of IBM Labs in the United States proposed an orbital non-volatile memory theory based on spintronics technology, which enables non-volatile memory to simultaneously have semiconductor memory. The advantages of high access performance and robustness, as well as the low cost and large capacity of the general hard disk.
然而,Parkin先生所提出之軌道競賽式非揮發性記憶體,是一種長條狀的磁性記錄元;而且,此軌道競賽式非揮發性記憶體需要一個額外的穿隧磁阻感應器(Tunnel magnetoresistance sensor,TMR sensor),才能順利讀取訊號。However, Mr. Parkin's orbital non-volatile memory is a long strip of magnetic recording elements; moreover, this orbital non-volatile memory requires an additional tunneling magnetoresistive sensor (Tunnel magnetoresistance). Sensor, TMR sensor) to read the signal smoothly.
本發明之一技術態樣在於提供一種軌道競賽式非揮發性記憶體製造方法,以製造一軌道競賽式非揮發性記憶體。One aspect of the present invention provides a method for manufacturing a track-competitive non-volatile memory to manufacture a track-competitive non-volatile memory.
根據本發明之一技術態樣,提供一種軌道競賽式非揮發性記憶體製造方法,其包括下列步驟:利用一阻劑,以一微影技術在一自旋閥上定義一軌道競賽式記錄元。利用一舉離技術於軌道競賽式記錄元中央製作一訊號讀取端。利用舉離技術於軌道競賽式記錄元之一端製作一磁壁推動端。電性連接一第一奈秒級短脈衝電流源於磁壁推動端。電性連接一第一匹配電阻於軌道競賽式記錄元之另一端。製作一絕緣層於訊號讀取端與磁壁推動端之間。利用舉離技術於絕緣層上製作一寫入電極。電性連接一第二奈秒級短脈衝電流源於寫入電極之一端。以及,電性連接一第二匹配電阻於寫入電極之另一端。藉此,本方法可製造一軌道競賽式非揮發性記憶體。According to one aspect of the present invention, a method for manufacturing a track-competitive non-volatile memory is provided, which includes the steps of: defining a track-competitive recording element on a spin valve by a lithography technique using a resist . A signal reading end is produced in the center of the track-competitive recording element by using one technique. A magnetic wall push end is fabricated on one end of the orbital competition recording element by using the lifting technique. Electrically connected to a first nanosecond short pulse current source from the magnetic wall push end. A first matching resistor is electrically connected to the other end of the track-competitive recording element. An insulating layer is formed between the signal reading end and the magnetic wall pushing end. A write electrode is fabricated on the insulating layer using lift-off techniques. Electrically connecting a second nanosecond short pulse current source from one end of the write electrode. And electrically connecting a second matching resistor to the other end of the write electrode. Thereby, the method can manufacture a track-competitive non-volatile memory.
本發明之另一技術態樣在於提供一種軌道競賽式非揮發性記憶體結構,此結構之訊號讀取端僅需利用外加電極,即可實現之。Another technical aspect of the present invention is to provide a track-competitive non-volatile memory structure, and the signal reading end of the structure can be realized only by using an external electrode.
根據本發明之另一技術態樣,提供一種軌道競賽式非揮發性記憶體結構,其包括一基底、一自旋閥、一軌道競賽式記錄元、一訊號讀取端、一磁壁推動端、一第一奈秒級短脈衝電流源、一第一匹配電阻、一絕緣層、一寫入電極、一第二奈秒級短脈衝電流源,以及一第二匹配電阻。自旋閥位於基底上,自旋閥包括一釘扎子層及一自由子層,自由子層位於釘扎子層上,且釘扎子層接觸基底。軌道競賽式記錄元係利用一微影技術,定義自旋閥而產生。訊號讀取端係位於軌道競賽式記錄元中央,磁壁推動端係位於軌道競賽式記錄元之一端,第一奈秒級短脈衝電流源係電性連接於磁壁推動端,第一匹配電阻係電性連接於軌道競賽式記錄元之另一端。絕緣層係位於自旋閥上,且位於訊號讀取端與磁壁推動端之間;寫入電極係形成於絕緣層上。第二奈秒級短脈衝電流源係電性連接於寫入電極之一端,第二匹配電阻係電性連接於寫入電極之另一端。According to another aspect of the present invention, a track-competitive non-volatile memory structure includes a base, a spin valve, a track-competitive recording element, a signal reading end, and a magnetic wall pushing end. a first nanosecond short pulse current source, a first matching resistor, an insulating layer, a write electrode, a second nanosecond short pulse current source, and a second matching resistor. The spin valve is located on the substrate, the spin valve includes a pinned sublayer and a free sublayer, the free sublayer is on the pinning sublayer, and the pinned sublayer contacts the substrate. The orbital competition recording element is generated by using a lithography technique to define a spin valve. The signal reading end is located in the center of the orbital competition recording element, and the magnetic wall pushing end is located at one end of the orbital competition recording element, and the first nanosecond short pulse current source is electrically connected to the magnetic wall pushing end, and the first matching resistance is electrically connected. The sex is connected to the other end of the orbital competition record element. The insulating layer is located on the spin valve and is located between the signal reading end and the magnetic wall pushing end; the writing electrode is formed on the insulating layer. The second nanosecond short pulse current source is electrically connected to one end of the write electrode, and the second matching resistor is electrically connected to the other end of the write electrode.
藉此,本發明之軌道競賽式非揮發性記憶體結構,僅需外加電極於訊號讀取端,即可順利讀出訊號。換句話說,自旋閥可為一多層結構自旋閥(spin valve)或多層結構磁穿隧結(Magnetic Tunnel Junction,MTJ),來產生較大的磁阻。若自旋閥選用多層結構自旋閥,則訊號讀取端的外加電極,可為直接施加兩電極於自旋閥表面,訊號讀取端的左右兩側面。而若自旋閥選用多層結構磁穿隧結,則外加電極須一上一下,連接於多層結構磁穿隧結之表面及其底層。Therefore, the track-competitive non-volatile memory structure of the present invention can read the signal smoothly only by applying an electrode to the signal reading end. In other words, the spin valve can be a multi-layer spin valve or a multi-layer magnetic tunnel junction (MTJ) to generate a large magnetoresistance. If the spin valve adopts a multi-layer structure spin valve, the external electrode of the signal reading end can directly apply two electrodes on the surface of the spin valve and the left and right sides of the signal reading end. If the spin valve uses a multilayer structure magnetic tunneling junction, the applied electrode must be attached to the surface of the multilayer structure magnetic tunneling junction and its bottom layer.
請參照第1圖,其係為本發明一實施例之軌道競賽式非揮發性記憶體製造方法。本實施例包括下列步驟:首先,如步驟110所示,利用一阻劑,以一微影技術在一自旋閥上定義一軌道競賽式記錄元。此阻劑一般可用負光阻劑,則相對應的微影技術即為一光微影技術。但若為追求輕薄短小,此阻劑亦可選用負電子阻劑,且相應之微影技術為一電子束微影技術。接下來,如步驟120所示,利用一舉離(lift-off)技術於軌道競賽式記錄元中央製作一訊號讀取端。值得注意的是,此處係選用負電子阻劑與相應之舉離技術,方可於軌道競賽式記錄元實現訊號讀取端。換句話說,若採用光微影技術,則訊號讀取端極可能面積太大而無法正常工作。Please refer to FIG. 1 , which is a method for manufacturing a track-competitive non-volatile memory according to an embodiment of the present invention. This embodiment includes the following steps: First, as shown in step 110, a track-type recording element is defined on a spin valve by a lithography technique using a resist. The resist is generally a negative photoresist, and the corresponding lithography technology is a photolithography technique. However, in order to pursue lightness and shortness, the resist may also be a negative electron resistive, and the corresponding lithography technique is an electron beam lithography technique. Next, as shown in step 120, a signal reading end is created in the center of the track-competitive recording element using a lift-off technique. It is worth noting that the negative electron resist and the corresponding lift technology are used here to realize the signal reading end of the track-competition recording element. In other words, if optical lithography is used, the signal reading end is likely to be too large to work properly.
接下來,如步驟130所示,利用舉離技術於軌道競賽式記錄元之一端製作一磁壁推動端。然後,如步驟140所示,電性連接一第一奈秒級短脈衝電流源於磁壁推動端。接下來,如步驟150所示,電性連接一第一匹配電阻於軌道競賽式記錄元之另一端。此第一匹配電阻一般係選用50歐姆。然後,如步驟160所示,製作一絕緣層於訊號讀取端與磁壁推動端之間;並且,如步驟170所示,再利用舉離技術於絕緣層上製作一寫入電極。Next, as shown in step 130, a magnetic wall push end is fabricated on one end of the track-competitive recording element using the lift-off technique. Then, as shown in step 140, a first nanosecond short pulse current is electrically connected to the magnetic wall push end. Next, as shown in step 150, a first matching resistor is electrically connected to the other end of the track-competitive recording element. This first matching resistor is typically 50 ohms. Then, as shown in step 160, an insulating layer is formed between the signal reading end and the magnetic wall pushing end; and, as shown in step 170, a writing electrode is formed on the insulating layer by lift-off technique.
最後,如步驟180所示,電性連接一第二奈秒級短脈衝電流源於寫入電極之一端;以及,如步驟190所示,電性連接一第二匹配電阻於寫入電極之另一端。其中,第二匹配電阻一般亦選用50歐姆。Finally, as shown in step 180, a second nanosecond short pulse current is electrically connected to one end of the write electrode; and, as shown in step 190, a second matching resistor is electrically connected to the write electrode. One end. Among them, the second matching resistor is generally also 50 ohms.
值得注意的是,本實施例之軌道競賽式記錄元係建立於一自旋閥上,而此自旋閥可為一多層結構自旋閥(spin valve)或多層結構磁穿隧結(Magnetic Tunnel Junction,MTJ),來產生較大的磁阻。It should be noted that the orbital recording element of this embodiment is built on a spin valve, and the spin valve can be a multi-layer spin valve or a multi-layer magnetic tunneling junction (Magnetic). Tunnel Junction, MTJ), to generate a large magnetic reluctance.
本發明另於一實施例中,提出一種軌道競賽式非揮發性記憶體結構。其係以上述之軌道競賽式非揮發性記憶體製造方法所達成。各步驟及其相應之軌道競賽式非揮發性記憶體加工半成品結構,詳述如下:請參考第2A圖及第2B圖。本實施例首先選用一基底100,並於基底上鋪設一自旋閥200,由第2B圖所繪示之剖面圖可清楚知悉,自旋閥200包括一釘扎子層210及一自由子層220。In another embodiment of the present invention, an orbital non-volatile memory structure is proposed. This is achieved by the above-described orbital non-volatile memory manufacturing method. The steps and their corresponding orbital non-volatile memory processing semi-finished structures are detailed as follows: Please refer to Figures 2A and 2B. In this embodiment, a substrate 100 is first selected, and a spin valve 200 is laid on the substrate. As is clear from the cross-sectional view shown in FIG. 2B, the spin valve 200 includes a pinned sub-layer 210 and a free sub-layer. 220.
請參考第3A圖及第3B圖。本實施例鋪設一負阻劑層300於自旋閥200上。當然,本實施例亦可選用正阻劑,而僅需改動相應之光罩。Please refer to Figures 3A and 3B. In this embodiment, a negative resist layer 300 is laid on the spin valve 200. Of course, this embodiment can also use a positive resist, and only need to change the corresponding mask.
請參考第4A圖及第4B圖。本實施例以微影技術,在負阻劑層300上定義出需要的圖案,亦即蝕刻圖形310。Please refer to Figures 4A and 4B. In this embodiment, a desired pattern, that is, an etched pattern 310, is defined on the negative resist layer 300 by lithography.
請參考第5A圖及第5B圖。本實施例將不受蝕刻圖形310之光阻所保護的區域,予以蝕刻,即可定義出軌道競賽式記錄元400。Please refer to Figures 5A and 5B. In this embodiment, the region that is not protected by the photoresist of the etched pattern 310 is etched to define the track-competitive recording element 400.
請參考第6A圖及第6B圖。本實施例鋪設電子阻劑500於上述半成品上。此處選用電子阻劑500,是為了配合電子束微影技術,以加工適當大小之訊號讀取端。Please refer to Figures 6A and 6B. In this embodiment, an electronic resist 500 is laid on the above semi-finished product. The electronic resist 500 is selected here to cooperate with the electron beam lithography technology to process an appropriately sized signal reading end.
請參考第7A圖及第7B圖。本實施例以電子束微影技術及舉離技術,在電子阻劑500上產生訊號讀取區600、第一舉離區610及第二舉離區620。Please refer to Figures 7A and 7B. In the embodiment, the signal reading area 600, the first lifting area 610 and the second lifting area 620 are generated on the electronic resist 500 by electron beam lithography and lifting technology.
請參考第8A圖及第8B圖。本實施例在訊號讀取區600、第一舉離區610及第二舉離區620填入導電物質,再清除電子阻劑500。如此一來,即可形成訊號讀取端601、磁壁推動端611及電阻匹配端621。Please refer to Figures 8A and 8B. In this embodiment, the conductive material is filled in the signal reading area 600, the first lifting area 610, and the second lifting area 620, and then the electronic resist 500 is removed. In this way, the signal reading end 601, the magnetic wall pushing end 611 and the resistance matching end 621 can be formed.
請參考第9A圖及第9B圖。本實施例在訊號讀取端601與磁壁推動端611之間鋪設一絕緣層700,此絕緣層700可選用二氧化矽(SiO2 )絕緣層或其它高介電材料。Please refer to Figures 9A and 9B. In this embodiment, an insulating layer 700 is disposed between the signal reading end 601 and the magnetic wall pushing end 611. The insulating layer 700 may be made of a cerium oxide (SiO 2 ) insulating layer or other high dielectric material.
請參考第10A圖及第10B圖。本實施例在絕緣層700上鋪設一電極,即可作為寫入電極710。Please refer to Figures 10A and 10B. In this embodiment, an electrode is laid on the insulating layer 700, which can be used as the write electrode 710.
請參考第11A圖及第11B圖。本實施例在磁壁推動端611連接一第一奈秒級短脈衝電流源810,在電阻匹配端621連接一第一匹配電阻820,在寫入電極710之兩端分別連接一第二奈秒級短脈衝電流源830及一第二匹配電阻840。其中,第一匹配電阻820與第二匹配電阻840一般選用50歐姆。Please refer to Figures 11A and 11B. In this embodiment, a first nanosecond short pulse current source 810 is connected to the magnetic wall pushing end 611, a first matching resistor 820 is connected to the resistance matching end 621, and a second nanosecond level is respectively connected to the two ends of the writing electrode 710. A short pulse current source 830 and a second matching resistor 840. The first matching resistor 820 and the second matching resistor 840 are generally 50 ohms.
因此,本實施例之軌道競賽式非揮發性記憶體結構包括一基底100、一自旋閥200、一軌道競賽式記錄元400、一訊號讀取端601、一磁壁推動端611、一第一奈秒級短脈衝電流源810、一第一匹配電阻820、一絕緣層700、一寫入電極710、一第二奈秒級短脈衝電流源830,以及一第二匹配電阻840。自旋閥200位於基底100上,自旋閥200包括一釘扎子層210及一自由子層220,自由子層220位於釘扎子層210上,且釘扎子層210接觸基底100。軌道競賽式記錄元400係利用一微影技術,定義自旋閥200而產生。訊號讀取端601係位於軌道競賽式記錄元400中央,磁壁推動端611係位於軌道競賽式記錄元400之一端,第一奈秒級短脈衝電流源810係電性連接於磁壁推動端611,第一匹配電阻820係電性連接於軌道競賽式記錄元400之另一端。絕緣層700係位於自旋閥200上,且位於訊號讀取端601與磁壁推動端611之間;寫入電極710係形成於絕緣層700上。第二奈秒級短脈衝電流源830係電性連接於寫入電極710之一端,第二匹配電阻840係電性連接於寫入電極710之另一端。藉此,本發明之軌道競賽式非揮發性記憶體結構,僅需外加電極900於訊號讀取端601,即可順利讀出訊號。Therefore, the track-competitive non-volatile memory structure of the embodiment includes a substrate 100, a spin valve 200, a track-competitive recording element 400, a signal reading end 601, a magnetic wall pushing end 611, and a first The nanosecond short pulse current source 810, a first matching resistor 820, an insulating layer 700, a write electrode 710, a second nanosecond short pulse current source 830, and a second matching resistor 840. The spin valve 200 is located on the substrate 100. The spin valve 200 includes a pinning sub-layer 210 and a free sub-layer 220. The free sub-layer 220 is located on the pinning sub-layer 210, and the pinning sub-layer 210 contacts the substrate 100. The track-racing recording element 400 is produced by defining a spin valve 200 using a lithography technique. The signal reading end 601 is located at the center of the track-competitive recording element 400, and the magnetic wall pushing end 611 is located at one end of the orbital competition recording element 400. The first nanosecond short pulse current source 810 is electrically connected to the magnetic wall pushing end 611. The first matching resistor 820 is electrically connected to the other end of the track-competitive recording element 400. The insulating layer 700 is located on the spin valve 200 and is located between the signal reading end 601 and the magnetic wall pushing end 611; the writing electrode 710 is formed on the insulating layer 700. The second nanosecond short pulse current source 830 is electrically connected to one end of the write electrode 710, and the second matching resistor 840 is electrically connected to the other end of the write electrode 710. Therefore, the track-competitive non-volatile memory structure of the present invention only needs to add the electrode 900 to the signal reading end 601, so that the signal can be read smoothly.
值得注意的是,自旋閥200可為一多層結構自旋閥(spin valve)或多層結構磁穿隧結(Magnetic Tunnel Junction,MTJ),來產生較大的磁阻。若自旋閥200選用多層結構自旋閥,則訊號讀取端601的外加電極900,可為直接施加兩電極於自旋閥表面,訊號讀取端601的左右兩側面。而若自旋閥200選用多層結構磁穿隧結,則外加電極900須一上一下,連接於多層結構磁穿隧結之表面及其底層。It should be noted that the spin valve 200 can be a multi-layer spin valve or a multi-layer magnetic tunnel junction (MTJ) to generate a large magnetoresistance. If the spin valve 200 is a multi-layer structure spin valve, the external electrode 900 of the signal reading end 601 can directly apply two electrodes to the surface of the spin valve, and the left and right sides of the signal reading end 601. If the spin valve 200 selects a multilayer structure magnetic tunneling junction, the additional electrode 900 must be attached to the surface of the multilayer structure magnetic tunneling junction and its bottom layer.
雖然本發明已以實施方式揭露如上,然其並非用以限定本發明,任何熟習此技藝者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention, and the present invention can be modified and modified without departing from the spirit and scope of the present invention. The scope is subject to the definition of the scope of the patent application attached.
100...基底100. . . Base
110~190...步驟110~190. . . step
200...自旋閥200. . . Spin valve
210...釘扎子層210. . . Pinning sublayer
220...自由子層220. . . Free sublayer
300...負阻劑層300. . . Negative resist layer
310...蝕刻圖形310. . . Etched graphics
400...軌道競賽式記錄元400. . . Orbital competition record element
500...電子阻劑500. . . Electronic resist
600...訊號讀取區600. . . Signal reading area
601...訊號讀取端601. . . Signal reader
610...第一舉離區610. . . First lift
611...磁壁推動端611. . . Magnetic wall push end
620...第二舉離區620. . . Second lift
621...電阻匹配端621. . . Resistance matching end
700...絕緣層700. . . Insulation
710...寫入電極710. . . Write electrode
810...第一奈秒級短脈衝電流源810. . . First nanosecond short pulse current source
820...第一匹配電阻820. . . First matching resistor
840...第二匹配電阻840. . . Second matching resistor
830...第二奈秒級短脈衝電流源830. . . Second nanosecond short pulse current source
900...讀取電極900. . . Read electrode
第1圖係為本發明一實施例之軌道競賽式非揮發性記憶體製造方法的步驟流程圖。1 is a flow chart showing the steps of a method for manufacturing a track-competitive non-volatile memory according to an embodiment of the present invention.
第2A圖~第11B圖係為本發明一實施例之軌道競賽式非揮發性記憶體結構,加工過程之結構示意圖。2A to 11B are schematic views showing the structure of a track-competitive non-volatile memory structure according to an embodiment of the present invention.
110~190...步驟110~190. . . step
Claims (12)
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| TW98111551A TWI415315B (en) | 2009-04-07 | 2009-04-07 | Racetrack nonvolatile memory manufacturing method and structure thereof |
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| TW98111551A TWI415315B (en) | 2009-04-07 | 2009-04-07 | Racetrack nonvolatile memory manufacturing method and structure thereof |
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| TW201037872A TW201037872A (en) | 2010-10-16 |
| TWI415315B true TWI415315B (en) | 2013-11-11 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6795379B2 (en) * | 2001-01-09 | 2004-09-21 | Canon Kabushiki Kaisha | Magneto-optical medium utilizing domain wall displacement and process of reproduction |
| US20050141148A1 (en) * | 2003-12-02 | 2005-06-30 | Kabushiki Kaisha Toshiba | Magnetic memory |
| US7154773B2 (en) * | 2005-03-31 | 2006-12-26 | Infineon Technologies Ag | MRAM cell with domain wall switching and field select |
| EP1901305A2 (en) * | 2006-09-15 | 2008-03-19 | Samsung Electronics Co., Ltd | Memory device employing magnetic domain wall movement |
| US20090034321A1 (en) * | 2007-08-01 | 2009-02-05 | Honeywell International Inc. | Magnetoresistive Element with a Biasing Layer |
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- 2009-04-07 TW TW98111551A patent/TWI415315B/en not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6795379B2 (en) * | 2001-01-09 | 2004-09-21 | Canon Kabushiki Kaisha | Magneto-optical medium utilizing domain wall displacement and process of reproduction |
| US20050141148A1 (en) * | 2003-12-02 | 2005-06-30 | Kabushiki Kaisha Toshiba | Magnetic memory |
| US7154773B2 (en) * | 2005-03-31 | 2006-12-26 | Infineon Technologies Ag | MRAM cell with domain wall switching and field select |
| EP1901305A2 (en) * | 2006-09-15 | 2008-03-19 | Samsung Electronics Co., Ltd | Memory device employing magnetic domain wall movement |
| US20090034321A1 (en) * | 2007-08-01 | 2009-02-05 | Honeywell International Inc. | Magnetoresistive Element with a Biasing Layer |
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