TWI491655B - 難燃性發泡苯乙烯系樹脂組成物 - Google Patents
難燃性發泡苯乙烯系樹脂組成物 Download PDFInfo
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- TWI491655B TWI491655B TW099112727A TW99112727A TWI491655B TW I491655 B TWI491655 B TW I491655B TW 099112727 A TW099112727 A TW 099112727A TW 99112727 A TW99112727 A TW 99112727A TW I491655 B TWI491655 B TW I491655B
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- Prior art keywords
- bromine
- styrene
- group
- flame
- bis
- Prior art date
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- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims description 128
- 239000011342 resin composition Substances 0.000 title claims description 20
- 239000006260 foam Substances 0.000 title description 29
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 57
- 239000003063 flame retardant Substances 0.000 claims description 53
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 50
- 229920005989 resin Polymers 0.000 claims description 50
- 239000011347 resin Substances 0.000 claims description 50
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 49
- 229910052794 bromium Inorganic materials 0.000 claims description 49
- -1 2,3-dibromopropyl group Chemical group 0.000 claims description 33
- 150000002894 organic compounds Chemical class 0.000 claims description 27
- 239000004088 foaming agent Substances 0.000 claims description 19
- 238000005187 foaming Methods 0.000 claims description 17
- CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical compound BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 13
- XUMFBUWGVLTWTH-UHFFFAOYSA-N 1,2-dibromo-3-(2,3-dibromo-2-methylpropoxy)-2-methylpropane Chemical compound BrCC(Br)(C)COCC(C)(Br)CBr XUMFBUWGVLTWTH-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
- 241000208340 Araliaceae Species 0.000 claims description 6
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 6
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 claims description 6
- 235000003140 Panax quinquefolius Nutrition 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 235000008434 ginseng Nutrition 0.000 claims description 6
- 229940097275 indigo Drugs 0.000 claims description 6
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000002667 nucleating agent Substances 0.000 claims description 5
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 4
- 239000000454 talc Substances 0.000 claims description 4
- 229910052623 talc Inorganic materials 0.000 claims description 4
- YUAPUIKGYCAHGM-UHFFFAOYSA-N 1,2-dibromo-3-(2,3-dibromopropoxy)propane Chemical compound BrCC(Br)COCC(Br)CBr YUAPUIKGYCAHGM-UHFFFAOYSA-N 0.000 claims description 3
- 239000012760 heat stabilizer Substances 0.000 claims description 3
- 239000008188 pellet Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- OZHJEQVYCBTHJT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-methylbenzene Chemical compound CC1=C(Br)C(Br)=C(Br)C(Br)=C1Br OZHJEQVYCBTHJT-UHFFFAOYSA-N 0.000 claims description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 2
- CWZVMVIHYSYLSI-UHFFFAOYSA-N 1,3-dibromo-5-[3,5-dibromo-4-(2,3-dibromopropoxy)phenyl]sulfonyl-2-(2,3-dibromopropoxy)benzene Chemical compound C1=C(Br)C(OCC(Br)CBr)=C(Br)C=C1S(=O)(=O)C1=CC(Br)=C(OCC(Br)CBr)C(Br)=C1 CWZVMVIHYSYLSI-UHFFFAOYSA-N 0.000 claims description 2
- BSZXAFXFTLXUFV-UHFFFAOYSA-N 1-phenylethylbenzene Chemical class C=1C=CC=CC=1C(C)C1=CC=CC=C1 BSZXAFXFTLXUFV-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 239000005909 Kieselgur Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000010097 foam moulding Methods 0.000 claims description 2
- CAYGQBVSOZLICD-UHFFFAOYSA-N hexabromobenzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1Br CAYGQBVSOZLICD-UHFFFAOYSA-N 0.000 claims description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- FXXCUGLLZLHZFF-UHFFFAOYSA-N 1-(2,3-dibromopropyl)-1,3,5-triazinane-2,4,6-trione Chemical compound BrCC(Br)CN1C(=O)NC(=O)NC1=O FXXCUGLLZLHZFF-UHFFFAOYSA-N 0.000 claims 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 claims 1
- 239000012744 reinforcing agent Substances 0.000 claims 1
- 238000000034 method Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 239000004793 Polystyrene Substances 0.000 description 6
- 239000011324 bead Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 239000003017 thermal stabilizer Substances 0.000 description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 229910001868 water Inorganic materials 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 229920005990 polystyrene resin Polymers 0.000 description 4
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 3
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 3
- LXIZRZRTWSDLKK-UHFFFAOYSA-N 1,3-dibromo-5-[2-[3,5-dibromo-4-(2,3-dibromopropoxy)phenyl]propan-2-yl]-2-(2,3-dibromopropoxy)benzene Chemical compound C=1C(Br)=C(OCC(Br)CBr)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(OCC(Br)CBr)C(Br)=C1 LXIZRZRTWSDLKK-UHFFFAOYSA-N 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- YATIGPZCMOYEGE-UHFFFAOYSA-N 1,3,5-tribromo-2-[2-(2,4,6-tribromophenoxy)ethoxy]benzene Chemical compound BrC1=CC(Br)=CC(Br)=C1OCCOC1=C(Br)C=C(Br)C=C1Br YATIGPZCMOYEGE-UHFFFAOYSA-N 0.000 description 2
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 description 2
- ZVVFVKJZNVSANF-UHFFFAOYSA-N 6-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]hexyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCCCCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 ZVVFVKJZNVSANF-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
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- 239000004566 building material Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
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- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- FGHOOJSIEHYJFQ-UHFFFAOYSA-N (2,4-ditert-butylphenyl) dihydrogen phosphite Chemical compound CC(C)(C)C1=CC=C(OP(O)O)C(C(C)(C)C)=C1 FGHOOJSIEHYJFQ-UHFFFAOYSA-N 0.000 description 1
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- RGASRBUYZODJTG-UHFFFAOYSA-N 1,1-bis(2,4-ditert-butylphenyl)-2,2-bis(hydroxymethyl)propane-1,3-diol dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C RGASRBUYZODJTG-UHFFFAOYSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
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- VNQNXQYZMPJLQX-UHFFFAOYSA-N 1,3,5-tris[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CN2C(N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C(=O)N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C2=O)=O)=C1 VNQNXQYZMPJLQX-UHFFFAOYSA-N 0.000 description 1
- XYXJKPCGSGVSBO-UHFFFAOYSA-N 1,3,5-tris[(4-tert-butyl-3-hydroxy-2,6-dimethylphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C)=C1CN1C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C1=O XYXJKPCGSGVSBO-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- BKLOQHWBOAWCPY-UHFFFAOYSA-N 1-bromo-1-(1-bromo-2-methylpropoxy)-2-methylpropane Chemical compound BrC(C(C)C)OC(C(C)C)Br BKLOQHWBOAWCPY-UHFFFAOYSA-N 0.000 description 1
- BHNZEZWIUMJCGF-UHFFFAOYSA-N 1-chloro-1,1-difluoroethane Chemical compound CC(F)(F)Cl BHNZEZWIUMJCGF-UHFFFAOYSA-N 0.000 description 1
- BOUGCJDAQLKBQH-UHFFFAOYSA-N 1-chloro-1,2,2,2-tetrafluoroethane Chemical compound FC(Cl)C(F)(F)F BOUGCJDAQLKBQH-UHFFFAOYSA-N 0.000 description 1
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
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- ZMYIIHDQURVDRB-UHFFFAOYSA-N 1-phenylethenylbenzene Chemical group C=1C=CC=CC=1C(=C)C1=CC=CC=C1 ZMYIIHDQURVDRB-UHFFFAOYSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- BDFBPPCACYFGFA-UHFFFAOYSA-N 2,4,6-tris(2,4,6-tribromophenoxy)-1,3,5-triazine Chemical compound BrC1=CC(Br)=CC(Br)=C1OC1=NC(OC=2C(=CC(Br)=CC=2Br)Br)=NC(OC=2C(=CC(Br)=CC=2Br)Br)=N1 BDFBPPCACYFGFA-UHFFFAOYSA-N 0.000 description 1
- BIOCRZSYHQYVSG-UHFFFAOYSA-N 2-(4-ethenylphenyl)-n,n-diethylethanamine Chemical compound CCN(CC)CCC1=CC=C(C=C)C=C1 BIOCRZSYHQYVSG-UHFFFAOYSA-N 0.000 description 1
- TVWGHFVGFWIHFN-UHFFFAOYSA-N 2-hexadecan-2-yl-4,6-dimethylphenol Chemical compound CCCCCCCCCCCCCCC(C)C1=CC(C)=CC(C)=C1O TVWGHFVGFWIHFN-UHFFFAOYSA-N 0.000 description 1
- GAODDBNJCKQQDY-UHFFFAOYSA-N 2-methyl-4,6-bis(octylsulfanylmethyl)phenol Chemical compound CCCCCCCCSCC1=CC(C)=C(O)C(CSCCCCCCCC)=C1 GAODDBNJCKQQDY-UHFFFAOYSA-N 0.000 description 1
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- ODJQKYXPKWQWNK-UHFFFAOYSA-L 3-(2-carboxylatoethylsulfanyl)propanoate Chemical compound [O-]C(=O)CCSCCC([O-])=O ODJQKYXPKWQWNK-UHFFFAOYSA-L 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ADRNSOYXKABLGT-UHFFFAOYSA-N 8-methylnonyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCC(C)C)OC1=CC=CC=C1 ADRNSOYXKABLGT-UHFFFAOYSA-N 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- DVDQJIFXVBGUCC-UHFFFAOYSA-N C(C)(C)(C)C=1C=C(CCC(=O)NCCCCCCNC(CCC2=CC(=C(C(=C2)C(C)(C)C)O)C(C)(C)C)=O)C=C(C1O)C(C)(C)C.C(CCCCC)(NC(CCC1=CC(=C(C(=C1)C(C)(C)C)O)C(C)(C)C)=O)NC(CCC1=CC(=C(C(=C1)C(C)(C)C)O)C(C)(C)C)=O Chemical compound C(C)(C)(C)C=1C=C(CCC(=O)NCCCCCCNC(CCC2=CC(=C(C(=C2)C(C)(C)C)O)C(C)(C)C)=O)C=C(C1O)C(C)(C)C.C(CCCCC)(NC(CCC1=CC(=C(C(=C1)C(C)(C)C)O)C(C)(C)C)=O)NC(CCC1=CC(=C(C(=C1)C(C)(C)C)O)C(C)(C)C)=O DVDQJIFXVBGUCC-UHFFFAOYSA-N 0.000 description 1
- ZQVFGCXPTUPTEA-UHFFFAOYSA-L C(CCCCCCCCCCC)CCC(=S)[O-].[Sr+2].OCC(CO)(CO)CO.C(CCCCCCCCCCC)CCC(=S)[O-] Chemical compound C(CCCCCCCCCCC)CCC(=S)[O-].[Sr+2].OCC(CO)(CO)CO.C(CCCCCCCCCCC)CCC(=S)[O-] ZQVFGCXPTUPTEA-UHFFFAOYSA-L 0.000 description 1
- HOUXRZOATPBYFV-UHFFFAOYSA-N C(CCCCCCCCCCCCC)(=O)O.C(CCCCCCCCCCCCC)(=O)O.S(CCC(=O)O)CCC(=O)O Chemical compound C(CCCCCCCCCCCCC)(=O)O.C(CCCCCCCCCCCCC)(=O)O.S(CCC(=O)O)CCC(=O)O HOUXRZOATPBYFV-UHFFFAOYSA-N 0.000 description 1
- HIBWGGKDGCBPTA-UHFFFAOYSA-N C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 HIBWGGKDGCBPTA-UHFFFAOYSA-N 0.000 description 1
- TVPRQSIVOQNTQL-UHFFFAOYSA-N CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(COP(=O)OCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(COP(=O)OCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 TVPRQSIVOQNTQL-UHFFFAOYSA-N 0.000 description 1
- GLVVSTKAXONSQX-UHFFFAOYSA-N CCCCCCCCCCC1=C(C(=CC=C1)C2=C(C=CC(=C2)CCCCCCCCC)OP(O)O)CCCCCCCCCC Chemical compound CCCCCCCCCCC1=C(C(=CC=C1)C2=C(C=CC(=C2)CCCCCCCCC)OP(O)O)CCCCCCCCCC GLVVSTKAXONSQX-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- XWCDCDSDNJVCLO-UHFFFAOYSA-N Chlorofluoromethane Chemical compound FCCl XWCDCDSDNJVCLO-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- FDBMBOYIVUGUSL-UHFFFAOYSA-N OP(O)OP(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C Chemical compound OP(O)OP(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C FDBMBOYIVUGUSL-UHFFFAOYSA-N 0.000 description 1
- QAEPIAHUOVJOOM-UHFFFAOYSA-N OP(O)OP(O)O.C(CCCCCCCC)C1=C(C=CC=C1)C(O)(C(CO)(CO)CO)C1=C(C=CC=C1)CCCCCCCCC Chemical compound OP(O)OP(O)O.C(CCCCCCCC)C1=C(C=CC=C1)C(O)(C(CO)(CO)CO)C1=C(C=CC=C1)CCCCCCCCC QAEPIAHUOVJOOM-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- XPSGBCLYLJIYOB-UHFFFAOYSA-N bis(2,4-ditert-butylphenyl) hydrogen phosphite Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(O)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C XPSGBCLYLJIYOB-UHFFFAOYSA-N 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000003484 crystal nucleating agent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 125000005394 methallyl group Chemical group 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- MMSLOZQEMPDGPI-UHFFFAOYSA-N p-Mentha-1,3,5,8-tetraene Chemical compound CC(=C)C1=CC=C(C)C=C1 MMSLOZQEMPDGPI-UHFFFAOYSA-N 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920002098 polyfluorene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940078499 tricalcium phosphate Drugs 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 235000019731 tricalcium phosphate Nutrition 0.000 description 1
- MZHULIWXRDLGRR-UHFFFAOYSA-N tridecyl 3-(3-oxo-3-tridecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCC MZHULIWXRDLGRR-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000000326 ultraviolet stabilizing agent Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0019—Use of organic additives halogenated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/08—Organic materials containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/136—Phenols containing halogens
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
- C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
本發明係關於一種難燃性發泡苯乙烯系樹脂組成物及其發泡成形體。
苯乙烯系樹脂因為輕量，所以被使用於家電製品或建材等之隔熱用途、或填土工法等之土木用途等各種領域。
苯乙烯系樹脂因僅由碳與氫所構成，所以有著一旦起火就會冒出黑煙並劇烈燃燒的性質。因此，必須依用途而添加難燃劑使其難燃化。作為此種難燃劑，含溴化合物被廣為使用，在以少許添加量來賦予高難燃性的方面，如六溴環十二烷(HBCD)般全部的溴原子均鍵結於脂肪族碳的難燃劑雖然有效，但這些難燃劑的熱安定性低，會引起樹脂之劣化、對樹脂之著色、起因於產生溴化氫氣體之裝置腐蝕等問題。
另一方面，作為熱安定性優異的難燃劑，亦已知有四溴雙酚A-雙(2,3-二溴丙基醚)等，但這些難燃劑相較於HBCD等難燃劑時，因難燃化效果較低，所以必須大幅增加添加量。因此，不僅降低苯乙烯系樹脂發泡體的物性，也有著使苯乙烯系樹脂發泡體成本大幅上升的問題。
苯乙烯系樹脂發泡體，是經過加熱熔融、添加發泡劑、冷卻、及低壓條件下之壓出發泡的各步驟而製造。但是，
在使用如前述HBCD般熱安定性差的難燃劑的苯乙烯系樹脂發泡體中，則會發生苯乙烯系樹脂的分子量降低或著色等。於是，作為解決此問題的方法，而有了併用各種熱安定劑的報告(例如日本專利特開2006-316251號公報)，已能夠製造使用這些難燃劑的苯乙烯系樹脂發泡體。
可是，近年來由於環保意識的高漲，而謀求將使用過的苯乙烯系樹脂發泡體再度使用作為原料。在此種再生苯乙烯系樹脂發泡體的製造上，因為是將前次製造時已經經過加熱熔融步驟的苯乙烯系樹脂發泡體進而加熱熔融而使用，所以謀求著比目前更高的熱安定性，僅併用上述熱安定劑尚無法獲得充分的熱安定性。
於是，在日本專利特開2005-139356號公報中，記載著藉由使用四溴雙酚A-雙(2-甲基烯丙基醚)或四溴雙酚A-雙(2,3-二溴-2-甲基丙基醚)作為難燃劑，而得到回收性優異之苯乙烯系樹脂發泡體。然而，已知這些苯乙烯系樹脂發泡體的熱安定性並不充分。
[先前技術文獻]
(專利文獻)
專利文獻1：日本專利特開2006-316251號公報
專利文獻2：日本專利特開2005-139356號公報
本發明係鑑於上述課題而完成，其目的在於提供一種發泡苯乙烯系樹脂組成物，其難燃性、熱安定性優異，且適合於回收。
本發明提供一種難燃性發泡苯乙烯系樹脂組成物，係含有苯乙烯系樹脂、含溴難燃劑及發泡劑，其特徵在於：前述含溴難燃劑為下述的混合物：(a)具有2,3-二溴丙基的含溴有機化合物或全部的溴原子均鍵結於苯環且溴含量為60重量%以上的含溴有機化合物、及(b)具有2,3-二溴-2-烷基丙基的含溴有機化合物；並且，相對於每100重量份之苯乙烯系樹脂，含有0.5~10重量份之含溴難燃劑。
若根據本發明，藉由併用：具有2,3-二溴丙基的含溴有機化合物或全部的溴原子均鍵結於苯環且溴含量為60重量%以上的含溴有機化合物、及具有2,3-二溴-2-烷基丙基的含溴有機化合物來添加作為難燃劑，而可獲得一種發泡苯乙烯系樹脂組成物，其整體使用時會少於各自單獨使用時的添加量而仍具有高難燃性，且具有很高的熱安定性而能夠進行回收。
[實施發明的較佳形態]
本發明的苯乙烯系樹脂，例如是：苯乙烯的單獨聚合
物；苯乙烯與鄰甲基苯乙烯、間甲基苯乙烯、對甲基苯乙烯、2,4-二甲基苯乙烯、乙基苯乙烯、對第三丁基苯乙烯、α-甲基苯乙烯、α-甲基-對甲基苯乙烯、1,1-二苯基乙烯、對(N,N-二乙基胺基乙基)苯乙烯、對(N,N-二乙基胺基甲基)苯乙烯等之共聚物；進而是其混合物，其中以含有50重量%以上之苯乙烯單體為佳，較典型的是聚苯乙烯。
進而，亦可在上述苯乙烯系樹脂中調配橡膠狀聚合物。作為橡膠狀聚合物，例如可舉出：聚丁二烯、聚異戊二烯、苯乙烯-丁二烯共聚物、苯乙烯-異戊二烯共聚物、丙烯腈-丁二烯共聚物、苯乙烯-異丁烯-丁二烯系共聚物、丁二烯-(甲基)丙烯酸酯共聚物、苯乙烯-丁二烯嵌段共聚物、苯乙烯-異戊二烯嵌段共聚物、丁基橡膠、乙烯-α-烯烴系共聚物(乙烯-丙烯橡膠)、乙烯-α-烯烴-多烯共聚物(乙烯-丙烯-二烯橡膠)、聚矽氧橡膠、丙烯酸系橡膠、氫化二烯系橡膠(氫化苯乙烯-丁二烯嵌段共聚物、氫化丁二烯系聚合物等)等。這些橡膠狀聚合物可單獨或混合2種以上而使用。其使用量以在單體成分中為30重量%以下為佳，更佳為20重量%以下。
本發明之含溴難燃劑，是由下述的混合物所構成：(a)具有2,3-二溴丙基的含溴有機化合物或全部的溴原子均鍵結於苯環且溴含量為60重量%以上的含溴有機化合物、及(b)具有2,3-二溴-2-烷基丙基的含溴有機化合物。
具有2,3-二溴丙基的含溴化合物(a)，例如包含：四溴雙酚A-雙(2,3-二溴丙基醚)、四溴雙酚S-雙(2,3-二溴
丙基醚)、四溴雙酚F-雙(2,3-二溴丙基醚)、參(2,3-二溴丙基)異三聚氰酸酯、及參(2,3-二溴丙基)三聚氰酸酯。全部的溴原子均鍵結於苯環且溴含量為60重量%以上的含溴有機化合物，例如包含：四溴雙酚A、六溴苯、五溴甲苯、聚溴二苯基醚、聚溴二苯基乙烷、雙多溴苯氧基乙烷、參多溴苯氧基三(trispolybromophenoxy triazine)、聚溴苯基茚烷、聚丙烯酸五溴苄酯、伸乙基雙四溴鄰苯二甲醯亞胺。
具有2,3-二溴-2-烷基丙基的含溴有機化合物，例如可舉出：四溴雙酚A-雙(2,3-二溴-2-甲基丙基醚)、四溴雙酚S-雙(2,3-二溴-2-甲基丙基醚)、四溴雙酚F-雙(2,3-二溴-2-甲基丙基醚)。
該含溴有機化合物(a)與該含溴有機化合物(b)的調配比例，以重量為基準時以10/90~90/10為佳，較佳為20/80~80/20，更佳為30/70~80/20。藉由設在上述範圍內，而可賦予較高的熱安定性。
又，本發明的難燃性苯乙烯系樹脂發泡體組成物，以重量為基準時，是相對於每100重量份之苯乙烯系樹脂而含有0.5~10重量份之含溴難燃劑，以含有0.5~6重量份為佳。藉由設在上述範圍內，而可賦予較高的難燃性與熱安定性。
本發明的難燃性苯乙烯系樹脂發泡體組成物中，可進而調配熱安定劑。藉由調配熱安定劑，可進而提升熱安定性。作為此種熱安定劑，例如可舉出：亞磷酸化合物、硫
醚化合物、及受阻酚(hindered phenol)化合物等。
作為亞磷酸化合物，例如可舉出：參(2,4-二第三丁基苯基)亞磷酸酯、雙(2,4-二第三丁基苯基)季戊四醇二亞磷酸酯、亞磷酸雙[2,4-雙(1,1-二甲基乙基)-6-甲基苯基]乙基酯、肆(2,4-二第三丁基苯基)[1,1-聯苯]-4,4’-二基雙膦酸酯、雙(壬基苯基)季戊四醇二亞磷酸酯、雙硬脂基季戊四醇二亞磷酸酯、雙(2,6-二第三丁基-4-甲基苯基)季戊四醇二亞磷酸酯、2,2’-亞甲基雙(4,6-二第三丁基-1-苯氧基)(2-乙基己氧基)磷、四(十三基)-4,4’-亞丁基-雙(2-第三丁基-5-甲基苯基)二亞磷酸酯、六-十三基-1,1,3-參(3-第三丁基-6-甲基-4-氧基苯基)-3-甲基丙烷三亞磷酸酯、單(二壬基苯基)單-對壬基苯基亞磷酸酯、參(單壬基苯基)亞磷酸酯、四烷基(C=12~16)-4,4’-異亞丙基-(二苯)二亞磷酸酯、亞磷酸單或二苯基單或二烷基(或烷氧基烷基，C=8~13)酯、二苯基異癸基亞磷酸酯、亞磷酸三癸酯、亞磷酸三苯酯等。
作為硫醚化合物，例如可舉出：3,3’-硫代二丙酸二月桂酯、3,3’-硫代二丙酸二肉豆蔻酯、3,3’-硫代二丙酸二硬脂酯、季戊四醇肆(3-月桂基硫丙酸酯)、3,3’-硫代二丙酸二-十三酯、2-巰基苯并咪唑等。
作為受阻酚化合物，例如可舉出：1,6-己二醇-雙[3-(3,5-二第三丁基-4-羥苯基)丙酸酯]、三乙二醇-雙[3-(3-第三丁基-5-甲基-4-羥苯基)丙酸酯]、甘油三[3-(3,5-二第三丁基-4-羥苯基)-丙酸酯]、季戊四醇肆[3-(3,5-二第
三丁基-4-羥苯基)丙酸酯]、十八基-3-(3,5-二第三丁基-4-羥苯基)丙酸酯、硫代二乙基雙[3-(3,5-二第三丁基-4-羥苯基)丙酸酯]、N,N’-雙-(3-(3,5-二第三丁基-4-羥苯基)丙醯基)己二胺(N,N’-(1,6-Hexanediyl)bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionamide])、2,4-二甲基-6-(1-甲基十五基)苯酚、二乙基[[3,5-雙(1,1-二甲基乙基)-4-羥苯基]甲基]磷酸酯、雙[[3,5-雙(1,1-二甲基乙基)-4-羥苯基]甲基]磷酸二乙基酯鈣鹽(calcium diethyl bis[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]phosphonate)、3,3’,3”,5,5’,5”-六第三丁基-a,a’,a”-(均三甲苯-2,4,6-三基)三-對甲酚、4,6-雙(辛基硫甲基)鄰甲酚、伸乙基雙(氧化乙烯)雙[3-(5-第三丁基-4-羥基-間甲苯)丙酸酯]、六亞甲基雙[3-(3,5-二第三丁基-4-羥苯基)丙酸酯]、1,3,5-參(3,5-二第三丁基-4-羥苄基)-1,3,5-三-2,4,6(1H,3H,5H)-三酮(1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione)、1,3,5-參[(4-第三丁基-3-羥基-2,6-二甲苯基)甲基]-1,3,5-三-2,4,6(1H,3H,5H)-三酮(1,3,5-tris[(4-tert-butyl-3-hydroxy-2,6-xylyl)methyl]-1,3,5-triazine-2,4,6(1H,3H,5H)-trione)、2,6-二第三丁基-4-(4,6-雙(辛硫基)-1,3,5-三-2-基胺基)苯酚(2,6-di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazine-2-yl amino)phenol)等。
使用熱安定劑時的添加量，以相對於每100重量份之苯乙烯系樹脂為0.01~0.5重量份為佳。
又，本發明的難燃性苯乙烯系樹脂發泡體組成物中，可進而調配難燃助劑。藉由調配難燃助劑，可更加提高含溴難燃劑的難燃效果。作為此種難燃助劑，可舉出：三氧化銻、五氧化銻、硼酸鋅、水合氧化鋁、氧化鉬等。使用難燃助劑時的添加量，以相對於每100重量份之苯乙烯系樹脂為0.01~5重量份為佳。
溴系難燃劑的難燃效果，已知會因自由基產生劑或酞青(phthalocyanine)金屬錯合物而增強。作為此種自由基產生劑之例示，有：過氧化異丙苯(cumene peroxide)、氫過氧化異丙苯、過氧化二第三丁基、過氧化二第三己基、2,5-二甲基-2,5-二(第三丁基過氧化)己炔-3基(2,5-dimethyl-2,5-di(t-butylperoxy)hexyne-3)、過氧化二異丙苯、2,3-二甲基-2,3-二苯基丁烷等，酞青金屬錯合物之例示則有：酞青鐵、酞青錳、酞青鈷等。其中以過氧化二異丙苯、2,3-二甲基-2,3-二苯基丁烷、及酞青鐵為佳。其量以相對於每100重量份之苯乙烯系樹脂為0.01~0.5重量份為佳。
本發明的難燃性發泡苯乙烯系樹脂組成物，可藉由壓出發泡法或珠粒(beads)發泡法來形成發泡成形體。在壓出發泡法的情形中，是將溴系難燃劑及其他添加劑在壓出機內與苯乙烯系樹脂熔融混合，壓入發泡劑後，從壓出機的噴嘴壓出至空氣中，藉此而發泡成形。在珠粒發泡法的情形中，則是將藉懸浮聚合而得的苯乙烯系樹脂粒，在溴系難燃劑及除了發泡劑以外之其他添加劑的乳化分散液中加以含浸，接著將發泡劑壓入熱壓釜中而含浸，將水分離並將
所獲得的顆粒以100℃的水蒸氣使其預備發泡後，在成形模型內以高溫加壓水蒸氣使其加熱發泡，藉此而成形。
在此，作為發泡劑，例如可舉出：丙烷、丁烷、異丁烷、戊烷、環戊烷、己烷、環己烷、1-氯-1,1-二氟乙烷、單氯二氟甲烷、單氯-1,2,2,2-四氟乙烷、1,1-二氟乙烷、1,1,1,2-四氟乙烷、1,1,3,3,3-五氟丙烷、二氯甲烷、1,2-二氯乙烷、二甲基醚、二乙基醚、乙基甲基醚等揮發性有機發泡劑；水、氮氣、二氧化碳氣體等無機發泡劑；偶氮化合物等化學發泡劑等。這些發泡劑可單獨或併用2種以上而使用。發泡劑的調配量，因為可根據所需的發泡體之性能或成形方法而改變，所以並不加以限定，以相對於100重量份之聚苯乙烯系樹脂為0.01~0.5莫耳為佳，較佳為0.05~0.3莫耳。
又，製造本發明的難燃性苯乙烯系樹脂發泡成形體之際，除了添加發泡劑以外，亦可進而調配成核劑(nucleating agent)。作為此種成核劑，例如可舉出：滑石、膨土、高嶺土、雲母、二氧化矽、黏土、矽藻土等。使用成核劑時，使用量以相對於100重量份之聚苯乙烯系樹脂為0.01~20重量份為佳，較佳為0.1~10重量份。
本發明的難燃性發泡苯乙烯系樹脂組成物中，在無損於本發明之功效的範圍內，亦可併用：(a)及(b)以外的含溴有機化合物、磷酸酯、聚矽氧化合物、水合金屬化合物等。
又，本發明的難燃性發泡苯乙烯系樹脂組成物中，在
無損於本發明之功效的範圍內，亦可調配：光安定劑、紫外線吸收劑、紫外線安定劑、重金屬去活性劑、耐衝擊改良劑、著色劑、潤滑劑、抗滴落劑、結晶核劑、抗靜電劑、相容劑等習知的樹脂添加劑。
[實施例]
以下，就實施例及比較例而具體地說明本發明，但本發明並不限定於此。
實施例及比較例所使用的原料如同以下所示。
(A1)
GP-PS；PSJ聚苯乙烯G9305(PS日本株式會社製)
(A2)
苯乙烯系樹脂顆粒(藉由下述方法而製造)
於附設攪拌機的5L之熱壓釜中，填入2000g之離子交換水、4g之磷酸三鈣、0.5g之月桂基苯磺酸鈉後，一邊攪拌，一邊將作為觸媒而預先溶解的6g之過氧化苯甲醯(BPO)加入至2000g之苯乙烯單體中，以100℃懸浮聚合8小時。
濾出所得到的聚苯乙烯系樹脂顆粒，以蒸餾水清洗後加以乾燥，進而以篩來分級並篩選於0.3~1.0mm的粒徑範圍內，而獲得苯乙烯系樹脂顆粒(A2)。以GPC分析而得的重量平均分子量(Mw)，是290,000。
(a)-1
四溴雙酚A-雙(2,3-二溴丙基)醚；Pyroguard SR-720(第一工業製藥株式會社製)
(a)-2
四溴雙酚S-雙(2,3-二溴丙基)醚；NONNEN PR-2(丸菱油化工業株式會社製)
(a)-3
參(2,3-二溴丙基)異三聚氰酸酯；TAIC-6B(日本化成株式會社製)
(a)-4
2,4,6-參(2,4,6-三溴苯氧基)-1,3,5-三；Pyroguard SR-245(第一工業製藥株式會社製)
(a)-5
1,2-雙(2,4,6-三溴苯氧基)乙烷；FF-680(Chemtura Japan株式會社製)
(a)-6
四溴雙酚A；FR-1524(ICL-IP JAPAN株式會社製)
(a)-7
聚丙烯酸五溴苄酯；FR-1025(ICL-IP JAPAN株式會社製)
(b)-1
四溴雙酚A-雙(2,3-二溴-2-甲基丙基)醚；Pyroguard SR-130(第一工業製藥株式會社製)
參(2,4-二第三丁基苯基)亞磷酸酯與季戊四醇肆[3-(3,5-二第三丁基-4-羥苯基)丙酸酯]的混合物；IRGANOX B 225(汽巴精化股份有限公司製)
2,3-二甲基-2,3-二苯基丁烷；Nofmer BC-90(日油株式會社製)
異丁烷
Talc MS(日本Talc工業株式會社製)
己二酸二辛酯；DOA(大八化學公司製)
自65mm口徑直接連接至90mm口徑而成兩段式壓出機，對於其65mm口徑之壓出機，投入除了發泡劑以外之如表1及表2所述的原料，加熱至200℃並藉由熔融、塑化、混練而作成苯乙烯系樹脂組成物。接著，以其他管線將規定量的發泡劑壓入65mm之壓出機前端(與90mm口
徑之壓出機噴嘴的相反側)，在90mm口徑之壓出機中將樹脂溫度冷卻至120℃，從設於90mm口徑之壓出機前端且厚度方向為2.5mm、寬度方向為45mm之長方形剖面的模唇(die lip)向空氣中壓出，藉此獲得長方體狀的苯乙烯系樹脂的壓出發泡成形體。
在具備攪拌機的熱壓釜中，填入100重量份之蒸餾水、苯乙烯系樹脂顆粒與除了發泡劑以外之如表3所述的原料、規定量的熱安定劑及調配劑，在室溫下攪拌，使調配劑乳化分散後，投入100g之經分級的聚苯乙烯系樹脂顆粒，以溫度100℃持續攪拌5小時而使調配劑進行含浸。於其中壓入10g之發泡劑，以115℃進行8小時的發泡劑含浸。將水分離並將所獲得的聚苯乙烯系樹脂顆粒以100℃的蒸氣加熱使其預備發泡後，將發泡物置入成形模型內，藉由115℃之加壓蒸氣使其加熱融化而獲得立方體狀發泡成形體。
另外，發泡成形體的評價是藉由下述方法來進行。
藉由目視而如下述般評價發泡成形體的狀態。
○：無破裂、龜裂、孔洞等，可安定地獲得良好的發泡體。
×：會有氣體從模具噴出，無法安定地獲得發泡體。而且發泡體上有著破裂或龜裂、孔洞等。
依照JIS K-7201而測定氧指數。
○：氧指數為26以上
×：氧指數小於26
以GPC分析來測定發泡成形前之苯乙烯系樹脂與難燃性苯乙烯系樹脂發泡成形體的分子量，並計算聚苯乙烯系樹脂成形前後之重量平均分子量(Mw)的降低率(%)。
將藉由珠粒法發泡而成形的立方體，以切割機切片而作成板材，先以雙軸滾筒將板材壓縮，再以粉碎機加以粗碎。將已粗碎的回收樹脂投入Labo Plastomill磨機，以200℃加以混練，於5分鐘後取出並將已冷卻的樹脂進行GPC分析而求出重量平均分子量，計算分子量的降低率。
○：重量平均分子量的保持率為70%以上
×：重量平均分子量的保持率為小於70%
由表1及表3可明顯得知，實施例1~13的壓出發泡成形體，無論在成形性、難燃性、及熱安定性的任一項目中均為優異。
另一方面，如表2及表4所述之比較例1~5及比較例10~14般僅使用1種含溴有機化合物的壓出發泡成形體，則無法在難燃性、成形性、熱安定性的方面全部獲得滿足。又，如比較例6~9及比較例15~18般併用2種不具有2,3-二溴-2-烷基丙基構造的含溴有機化合物的情形中，亦同樣無法在難燃性、成形性、熱安定性的方面全部獲得滿足。
由表5可明顯得知，實施例14的珠粒法發泡成形體，無論在成形性、難燃性、及熱安定性的任一項目中均為優異。
另一方面，如比較例19及20般僅使用1種含溴有機化合物的珠粒法發泡成形體，則無法在難燃性、成形性、預設進行回收之熱安定性的方面全部獲得滿足。
[產業上之可利用性]
本發明的發泡苯乙烯系樹脂發泡體組成物，可獲得一種苯乙烯系樹脂發泡體，其即便難燃劑的添加量少仍具有高難燃性，且具有適合於回收之很高的熱安定性。因此，可利用於以家電製品或建材等之隔熱用途、或填土工法等之土木用途為首的各種領域。
Claims (12)
- 一種難燃性發泡苯乙烯系樹脂組成物，係含有苯乙烯系樹脂、含溴難燃劑及發泡劑之難燃性發泡苯乙烯系樹脂組成物，其特徵在於：前述含溴難燃劑為下述的混合物：(a)具有2,3-二溴丙基的含溴有機化合物或全部的溴原子均鍵結於苯環且溴含量為60重量%以上的含溴有機化合物、及(b)具有2,3-二溴-2-烷基丙基的含溴有機化合物；並且，相對於每100重量份之苯乙烯系樹脂，含有0.5~10重量份之含溴難燃劑。
- 如申請專利範圍第1項所述之難燃性發泡苯乙烯系樹脂組成物，其中：前述全部的溴原子均鍵結於苯環且溴含量為60重量%以上的含溴有機化合物，是選自由四溴雙酚A、六溴苯、五溴甲苯、聚溴二苯基醚、聚溴二苯基乙烷、雙多溴苯氧基乙烷、參多溴苯氧基三(trispolybromophenoxy triazine)、聚溴苯基茚烷、聚丙烯酸五溴苄酯、以及伸乙基雙四溴鄰苯二甲醯亞胺所構成之群組。
- 如申請專利範圍第1項所述之難燃性發泡苯乙烯系樹脂組成物，其中：前述具有2,3-二溴丙基的含溴有機化合物，是選自由四溴雙酚A-雙(2,3-二溴丙基醚)、四溴雙酚 S-雙(2,3-二溴丙基醚)、四溴雙酚F-雙(2,3-二溴丙基醚)、參(2,3-二溴丙基)異三聚氰酸酯、以及參(2,3-二溴丙基)三聚氰酸酯所構成之群組。
- 如申請專利範圍第1項所述之難燃性發泡苯乙烯系樹脂組成物，其中：前述具有2,3-二溴-2-烷基丙基的含溴有機化合物，是選自由四溴雙酚A-雙(2,3-二溴-2-甲基丙基醚)、四溴雙酚S-雙(2,3-二溴-2-甲基丙基醚)、以及四溴雙酚F-雙(2,3-二溴-2-甲基丙基醚)所構成之群組。
- 如申請專利範圍第2項所述之難燃性發泡苯乙烯系樹脂組成物，其中：前述具有2,3-二溴-2-烷基丙基的含溴有機化合物，是選自由四溴雙酚A-雙(2,3-二溴-2-甲基丙基醚)、四溴雙酚S-雙(2,3-二溴-2-甲基丙基醚)、以及四溴雙酚F-雙(2,3-二溴-2-甲基丙基醚)所構成之群組。
- 如申請專利範圍第3項所述之難燃性發泡苯乙烯系樹脂組成物，其中：前述具有2,3-二溴-2-烷基丙基的含溴有機化合物，是選自由四溴雙酚A-雙(2,3-二溴-2-甲基丙基醚)、四溴雙酚S-雙(2,3-二溴-2-甲基丙基醚)、以及四溴雙酚F-雙(2,3-二溴-2-甲基丙基醚)所構成之群組。
- 如申請專利範圍第1項所述之難燃性發泡苯乙烯系樹脂組成物，其中：前述含溴難燃劑中，相對於(b)具有2,3-二溴-2-烷基丙基的含溴有機化合物之(a)具有2,3-二 溴丙基的含溴有機化合物或全部的溴原子均鍵結於苯環且溴含量為60重量%以上的含溴有機化合物，其比例(a)/(b)以重量為基準時為90/10~10/90。
- 如申請專利範圍第1至7項中任一項所述之難燃性發泡苯乙烯系樹脂組成物，其中：進而含有熱安定劑，該熱安定劑是選自亞磷酸化合物、硫醚化合物及受阻酚化合物，且相對於每100重量份之苯乙烯系樹脂為0.01~0.5重量份。
- 如申請專利範圍第1至7項中任一項所述之難燃性發泡苯乙烯系樹脂組成物，其中：進而含有難燃增強劑，該難燃增強劑是選自由酞青金屬錯合物及自由基產生劑所組成之群組，且相對於每100重量份之苯乙烯系樹脂為0.01~0.5重量份。
- 如申請專利範圍第1至7項中任一項所述之難燃性發泡苯乙烯系樹脂組成物，其中：進而含有成核劑，該成核劑是選自由滑石、膨土、高嶺土、雲母、二氧化矽、黏土、矽藻土所構成之群組，且相對於每100重量份之苯乙烯系樹脂為0.01~20重量份。
- 一種發泡成形體，係將不包含發泡劑在內的如申請專利範圍第1至10項中任一項所述之難燃性發泡苯乙烯系樹 脂組成物，在壓出機中進行熔融，壓入發泡劑後，從壓出機的噴嘴壓出發泡至空氣中而獲得。
- 一種發泡成形體，係將如申請專利範圍第1至10項中任一項所述之難燃性發泡苯乙烯系樹脂組成物的顆粒以水蒸氣加熱，藉此使其預備發泡後，在成形模型內發泡成形而獲得。
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| US10358538B2 (en) | 2009-10-27 | 2019-07-23 | Sekisui Plastics Co., Ltd. | Foamable polystyrene resin particles and polystyrene resin prefoamed particles |
| WO2012057060A1 (ja) * | 2010-10-27 | 2012-05-03 | 株式会社カネカ | スチレン系樹脂押出発泡体及びその製造方法 |
| ITVI20110231A1 (it) * | 2011-08-09 | 2013-02-10 | Micaela Lorenzi | Nuova composizione ritardante di fiamma per polistirene |
| KR101368864B1 (ko) * | 2012-02-14 | 2014-02-27 | 이상수 | 난연성 실리콘조성물을 이용한 발포시트제조방법 |
| ITMI20121808A1 (it) | 2012-10-24 | 2014-04-25 | Versalis Spa | Composizioni polimeriche concentrate di polimeri e/o copolimeri vinilaromatici |
| JP6061742B2 (ja) * | 2013-03-15 | 2017-01-18 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡体の製造方法 |
| JP6551908B2 (ja) * | 2013-05-20 | 2019-07-31 | 第一工業製薬株式会社 | 難燃性発泡スチレン系樹脂組成物 |
| CN103450579B (zh) * | 2013-09-16 | 2016-05-04 | 内蒙古大学 | 以废弃聚氨酯泡沫、高岭土及废弃聚苯乙烯泡沫制备板材的方法 |
| EP3070118B1 (en) | 2013-11-14 | 2020-02-26 | Kaneka Corporation | Extruded styrenic resin foam and method for manufacturing same |
| JP2016056271A (ja) | 2014-09-09 | 2016-04-21 | カンナテクノロジー株式会社 | ゴム状ラテックスとメラミンシアヌレートを含有する発泡ポリスチレン系樹脂成形品及びその製造方法 |
| JP6306643B2 (ja) * | 2016-06-08 | 2018-04-04 | 株式会社カネカ | 発泡性スチレン系樹脂粒子とその製造方法、スチレン系樹脂発泡成形体 |
| IT201600071347A1 (it) | 2016-07-08 | 2018-01-08 | Versalis Spa | Composizioni espandibili contenenti polimeri vinil aromatici aventi proprietà autoestinguenti e migliorata processabilità |
| CN106633588B (zh) * | 2016-12-12 | 2019-03-08 | 盐城庆达新材料有限公司 | 一种电动汽车充电桩用电缆材料及其制备方法 |
| KR102119032B1 (ko) * | 2016-12-27 | 2020-06-04 | 롯데첨단소재(주) | 발포성 수지 조성물, 이를 이용한 발포체 및 제조방법 |
| KR101977818B1 (ko) * | 2018-05-11 | 2019-05-13 | 제일화학주식회사 | 압출 폴리스티렌 발포체용 난연 마스터 배치 조성물 및 이를 이용한 압출 폴리스티렌 발포체 |
| CN110872421A (zh) * | 2018-08-31 | 2020-03-10 | 第一工业制药株式会社 | 苯乙烯系树脂粒子及其的制造方法 |
| CN109705507B (zh) * | 2018-11-30 | 2020-11-17 | 金发科技股份有限公司 | 一种阻燃hips材料及其制备方法 |
| CN109705506B (zh) * | 2018-11-30 | 2020-11-17 | 金发科技股份有限公司 | 一种阻燃hips材料及其制备方法 |
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| KR101357378B1 (ko) | 2014-02-03 |
| TW201111425A (en) | 2011-04-01 |
| WO2010125894A1 (ja) | 2010-11-04 |
| CN102356123B (zh) | 2013-03-27 |
| EP2426165A1 (en) | 2012-03-07 |
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