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TWI472002B - Mems apparatus - Google Patents

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TWI472002B
TWI472002B TW102100781A TW102100781A TWI472002B TW I472002 B TWI472002 B TW I472002B TW 102100781 A TW102100781 A TW 102100781A TW 102100781 A TW102100781 A TW 102100781A TW I472002 B TWI472002 B TW I472002B
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electrodes
oxide layer
region
layer
substrate
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TW102100781A
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TW201428921A (en
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Mao Chen Liu
Wen Chieh Chou
Po Wei Lu
Shu Yi Weng
Chun Chieh Wang
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Priority to TW102100781A priority Critical patent/TWI472002B/en
Priority to US14/151,622 priority patent/US20140190260A1/en
Priority to CN201410009937.5A priority patent/CN103910323B/en
Publication of TW201428921A publication Critical patent/TW201428921A/en
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Publication of TWI472002B publication Critical patent/TWI472002B/en

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Description

微機電裝置 Microelectromechanical device

本揭露係關於一種微機電裝置,特別是一種透過氧化層或是氧化層包覆連接層的方式以做為質量塊的微機電裝置。 The present disclosure relates to a microelectromechanical device, particularly a microelectromechanical device that is used as a mass block by coating a connecting layer through an oxide layer or an oxide layer.

在半導體製程中,大多數的元件製作皆自金屬層與氧化層的連續製程而來,其中金屬層多由物理性方式所沉積形成,故金屬層通常具有張應力,而氧化層多由化學性方式所沉積形成,故氧化層通常具有壓應力。微機電(MEMS)元件為一種常見且使用金屬層與氧化層相互堆疊形成的半導體元件,所以MEMS元件的殘留應力是一個具有壓應力與張應力所組合而成的等效應力值。以半導體製程製作的MEMS元件其最大的優點為整合特殊用途積體電路(ASIC)與MEMS於同一平面,省去了複雜的封裝方式,但最大的難題即為MEMS結構的殘留應力。 In the semiconductor process, most of the fabrication of the components comes from the continuous process of the metal layer and the oxide layer. The metal layer is mostly formed by physical deposition, so the metal layer usually has tensile stress, and the oxide layer is mostly chemical. The deposition is formed by the way, so the oxide layer usually has compressive stress. A microelectromechanical (MEMS) device is a common semiconductor element formed by stacking a metal layer and an oxide layer, so the residual stress of the MEMS element is an equivalent stress value combined with compressive stress and tensile stress. The biggest advantage of MEMS components fabricated in semiconductor manufacturing is the integration of special-purpose integrated circuits (ASICs) and MEMS in the same plane, eliminating the need for complex packaging, but the biggest problem is the residual stress of MEMS structures.

常見的XY軸加速度計即為MEMS元件的應用,因為金屬層具有張應力(結構呈上彎曲),而氧化層具有壓應力(結構呈下彎曲),其中氧化層是透過化學方式產生鍵結再由鍵結產生薄膜,此氧化層的沉積溫度高且鍵結與鍵結間的力量造成氧化層的殘留應力大於金屬的殘留應力,故殘留應力以氧化層為主並使MEMS結構呈下彎曲。此時,雖可使用快速退火(RTA)系統以進行殘留應力的釋放,然而尚有複合材料的熱膨脹係數必須進行考量,例如金屬鋁的熱膨脹係數是23ppm/℃,而氧化層的熱膨脹係數是0.5 ppm/℃,兩種不同材料的堆疊造成熱膨脹係數約有46倍的差距。如此一來,當MEMS結構受到溫度的變化時,除了本身的殘留應力之外,仍必須再考量兩種不同材料堆疊時的熱膨脹現象。 The common XY-axis accelerometer is the application of MEMS components because the metal layer has tensile stress (the structure is curved upwards), and the oxide layer has compressive stress (the structure is bent downward), wherein the oxide layer is chemically bonded. The film is formed by the bond, the deposition temperature of the oxide layer is high, and the force between the bond and the bond causes the residual stress of the oxide layer to be greater than the residual stress of the metal, so the residual stress is dominated by the oxide layer and the MEMS structure is bent downward. At this time, although a rapid annealing (RTA) system can be used for the release of residual stress, the thermal expansion coefficient of the composite material must be considered. For example, the thermal expansion coefficient of the metal aluminum is 23 ppm/° C., and the thermal expansion coefficient of the oxide layer is 0.5. At ppm/°C, the stacking of two different materials results in a 46-fold difference in thermal expansion coefficient. As a result, when the MEMS structure is subjected to temperature changes, in addition to its own residual stress, it is necessary to consider the thermal expansion phenomenon when two different materials are stacked.

一般而言,目前各種已用於習知技術中之MEMS元件結構的材料大多具有高膨脹係數,其造成MEMS元件結構在受到溫度的變化時而呈現翹曲的現象。 In general, most of the materials currently used in the MEMS element structure of the prior art have a high expansion coefficient, which causes the MEMS element structure to exhibit warpage when subjected to temperature changes.

本揭露提供一種微機電裝置,係透過氧化層或是氧化層包覆連接層的方式以做為質量塊的結構,可使結構本身運動不受到溫度變化的影響,進而達成高穩定性之功效。 The present disclosure provides a microelectromechanical device, which is a structure of a mass block by coating a connecting layer through an oxide layer or an oxide layer, so that the structure itself can be moved without being affected by temperature changes, thereby achieving high stability.

根據本揭露之一實施例的一種微機電裝置,其包括一基板、一氧化層、及多個懸臂。基板包含多個第一電極、多個第二電極、一第一區、一第二區、及一蝕刻區。多個第一電極位於第一區,多個第二電極位於第二區,蝕刻區位於基板的中央,且第一區與第二區彼此相對。氧化層設置於蝕刻區的中央,此氧化層包含多個第三電極、多個第四電極、一第一側邊、及一第二側邊,多個第三電極位於第一側邊,多個第四電極位於第二側邊,且第一側邊與第二側邊彼此相對。多個懸臂分別設置於基板的周圍與氧化層的周圍之間,且多個懸臂用以支撐氧化層。其中多個第一電極與多個第三電極彼此交叉相對,多個第二電極與多個第四電極彼此交叉相對。 A microelectromechanical device according to an embodiment of the present disclosure includes a substrate, an oxide layer, and a plurality of cantilevers. The substrate includes a plurality of first electrodes, a plurality of second electrodes, a first region, a second region, and an etched region. The plurality of first electrodes are located in the first region, the plurality of second electrodes are located in the second region, the etching region is located at the center of the substrate, and the first region and the second region are opposite to each other. An oxide layer is disposed at a center of the etched region, the oxide layer includes a plurality of third electrodes, a plurality of fourth electrodes, a first side, and a second side, and the plurality of third electrodes are located on the first side, The fourth electrodes are located on the second side, and the first side and the second side are opposite to each other. A plurality of cantilevers are respectively disposed between the periphery of the substrate and the periphery of the oxide layer, and a plurality of cantilevers are used to support the oxide layer. The plurality of first electrodes and the plurality of third electrodes intersect each other, and the plurality of second electrodes and the plurality of fourth electrodes cross each other.

以上之關於本揭露內容之說明及以下之實施方式之說明係用 以示範與解釋本揭露之精神與原理,並且提供本揭露之專利申請範圍更進一步之解釋。 The above description of the disclosure and the following description of the embodiments are used The spirit and principles of the present disclosure are illustrated and explained, and a further explanation of the scope of the patent application of the present disclosure is provided.

以下在實施方式中詳細敘述本揭露之詳細特徵以及優點,其內容足以使任何熟習相關技藝者了解本揭露之技術內容並據以實施,且根據本說明書所揭露之內容、申請專利範圍及圖式,任何熟習相關技藝者可輕易地理解本揭露相關之目的及優點。以下之實施例係進一步詳細說明本揭露之觀點,但非以任何觀點限制本揭露之範疇。 The detailed features and advantages of the present disclosure are described in detail in the following detailed description of the embodiments of the present disclosure, which are The objects and advantages associated with the present disclosure can be readily understood by those skilled in the art. The following examples are intended to further illustrate the present disclosure, but are not intended to limit the scope of the disclosure.

請參照『第1圖』,係為根據本揭露之一實施例之一種微機電裝置100,其包括一基板110、一氧化層120、及多個懸臂130。基板110包含多個第一電極111、多個第二電極112、一第一區113、一第二區114、及一蝕刻區115。多個第一電極111位於第一區113,多個第二電極112位於第二區114,蝕刻區115位於基板110的中央,且第一區113與第二區114彼此相對。在部份實施例中,基板110的材料可為矽,但不以此為限,而第一電極111與第二電極112的數目可為八個,亦不以此為限。 Referring to FIG. 1 , a microelectromechanical device 100 according to an embodiment of the present disclosure includes a substrate 110 , an oxide layer 120 , and a plurality of cantilevers 130 . The substrate 110 includes a plurality of first electrodes 111, a plurality of second electrodes 112, a first region 113, a second region 114, and an etched region 115. The plurality of first electrodes 111 are located in the first region 113, the plurality of second electrodes 112 are located in the second region 114, the etching region 115 is located at the center of the substrate 110, and the first region 113 and the second region 114 are opposed to each other. In some embodiments, the material of the substrate 110 may be 矽, but not limited thereto, and the number of the first electrode 111 and the second electrode 112 may be eight, and is not limited thereto.

如『第1圖』所示,氧化層120設置於蝕刻區115的中央,此氧化層120包含多個第三電極121、多個第四電極122、一第一側邊123、及一第二側邊124,多個第三電極121位於第一側邊123,多個第四電極122位於第二側邊124,且第一側邊123與第二側邊124彼此相對。在部份實施例中,氧化層120可為二氧化 矽且氧化層120的熱膨脹係數可為0.5ppm/℃,但不以此為限,而第三電極121與第四電極122的數目可為八個,亦不以此為限。此外,氧化層120更包括一連接層(未繪示於圖中),在部份實施例中,此連接層的材料可為鎢且連接層的熱膨脹係數可為4ppm/℃,但不以此為限。 As shown in FIG. 1 , the oxide layer 120 is disposed at the center of the etched region 115 . The oxide layer 120 includes a plurality of third electrodes 121 , a plurality of fourth electrodes 122 , a first side 123 , and a second layer . The side edges 124, the plurality of third electrodes 121 are located on the first side 123, and the plurality of fourth electrodes 122 are located on the second side 124, and the first side 123 and the second side 124 are opposite to each other. In some embodiments, the oxide layer 120 can be oxidized. The thermal expansion coefficient of the oxide layer 120 may be 0.5 ppm/° C., but not limited thereto, and the number of the third electrode 121 and the fourth electrode 122 may be eight or not. In addition, the oxide layer 120 further includes a connecting layer (not shown). In some embodiments, the connecting layer may be made of tungsten and the connecting layer may have a thermal expansion coefficient of 4 ppm/° C. Limited.

如『第1圖』所示,多個懸臂130分別設置於基板110的周圍與氧化層120的周圍之間,且多個懸臂130用以支撐氧化層120。在部份實施例中,此懸臂130的數量可為二、四、或是六個,但不以此為限,而懸臂130的材料可為金屬。其中多個第一電極111與多個第三電極121彼此交叉相對,多個第二電極112與多個第四電極122彼此交叉相對。 As shown in FIG. 1 , a plurality of cantilevers 130 are respectively disposed between the periphery of the substrate 110 and the periphery of the oxide layer 120 , and a plurality of cantilevers 130 are used to support the oxide layer 120 . In some embodiments, the number of the cantilever 130 can be two, four, or six, but not limited thereto, and the material of the cantilever 130 can be metal. The plurality of first electrodes 111 and the plurality of third electrodes 121 cross each other, and the plurality of second electrodes 112 and the plurality of fourth electrodes 122 cross each other.

在本實施例中,此微機電裝置100作為一加速度計,而氧化層120作為一質量塊。此微機電裝置100的運作上主要是當外在環境變化時,將驅使氧化層120接收到一加速度,進而帶動多個第三電極121與多個第四電極122接收到此加速度。由於多個第一電極111與多個第三電極121彼此交叉相對,因此多個第一電極111與多個第三電極121彼此之間具有重疊的耦合面積,將形成耦合電容的效應。利用此氧化層120在接收加速度之前與接收加速度之後的差異,可偵測多個第一電極111與多個第三電極121之間的前後耦合電容的差值。同理,多個第二電極112與多個第四電極122彼此之間亦形成耦合電容的效應,亦可偵測多個第二電極112與多個第四電極122之間的前後耦合電容的差值,以作 為加速度計的偵測。 In the present embodiment, the MEMS device 100 acts as an accelerometer and the oxide layer 120 acts as a mass. The operation of the MEMS device 100 is mainly to drive the oxide layer 120 to receive an acceleration when the external environment changes, thereby driving the plurality of third electrodes 121 and the plurality of fourth electrodes 122 to receive the acceleration. Since the plurality of first electrodes 111 and the plurality of third electrodes 121 cross each other, the plurality of first electrodes 111 and the plurality of third electrodes 121 have overlapping coupling regions with each other, and an effect of coupling capacitance is formed. The difference between the front and rear coupling capacitances between the plurality of first electrodes 111 and the plurality of third electrodes 121 can be detected by using the difference between the oxide layer 120 and the received acceleration before receiving the acceleration. Similarly, the plurality of second electrodes 112 and the plurality of fourth electrodes 122 also form a coupling capacitance effect between each other, and can also detect the front-back coupling capacitance between the plurality of second electrodes 112 and the plurality of fourth electrodes 122. Difference For the detection of accelerometers.

在本實施例中,此微機電裝置100是以氧化層120作為質量塊的結構,此氧化層120可為二氧化矽且氧化層120的熱膨脹係數可為0.5ppm/℃。此外,亦可以氧化層120包覆連接層的方式作為質量塊的結構,此連接層的材料可為鎢且連接層的熱膨脹係數可為4ppm/℃。前述質量塊的結構相較於習知以鋁的材料作為質量塊的結構而言,因鋁的熱膨脹係數為23ppm/℃,而氧化層120與連接層的熱膨脹係數分別為0.5ppm/℃與4ppm/℃,故以氧化層120或是氧化層120包覆連接層的方式所製成的質量塊,將可避免例如翹曲之不穩定的現象而導致無法作為加速度計偵測的應用。 In the present embodiment, the microelectromechanical device 100 is a structure in which the oxide layer 120 is used as a mass. The oxide layer 120 may be ceria and the thermal expansion coefficient of the oxide layer 120 may be 0.5 ppm/° C. In addition, the oxide layer 120 may be coated as a mass of the connecting layer. The material of the connecting layer may be tungsten and the connecting layer may have a thermal expansion coefficient of 4 ppm/° C. The structure of the foregoing mass is compared with the conventional structure of aluminum as a mass, since the coefficient of thermal expansion of aluminum is 23 ppm/° C., and the coefficients of thermal expansion of the oxide layer 120 and the connecting layer are 0.5 ppm/° C. and 4 ppm, respectively. /°C, the mass produced by coating the connection layer with the oxide layer 120 or the oxide layer 120 can avoid the instability of the warp, for example, and can not be used as an accelerometer detection application.

請參照『第2A圖』至『第2E圖』所繪示係為『第1圖』之一種微機電裝置100的製造流程示意圖,如『第2A圖』所示,首先,於基板210上利用薄膜沉積的方式成長氧化層220,在本實施例中,基板210的材料為矽,而氧化層220為二氧化矽且氧化層220的熱膨脹係數為0.5ppm/℃。另一方面,亦可於基板210上成長氧化層220與連接層(未繪示於圖中),亦即氧化層220包覆連接層的結構,在本實施例中,此連接層的材料為鎢且連接層的熱膨脹係數為4ppm/℃。 Please refer to the schematic diagram of the manufacturing process of a microelectromechanical device 100, which is shown in FIG. 2A and FIG. 2E, as shown in FIG. 2A. First, the substrate 210 is utilized. In the present embodiment, the material of the substrate 210 is germanium, and the oxide layer 220 is germanium dioxide and the thermal expansion coefficient of the oxide layer 220 is 0.5 ppm/° C. On the other hand, the oxide layer 220 and the connection layer (not shown) may be grown on the substrate 210, that is, the structure in which the oxide layer 220 covers the connection layer. In this embodiment, the material of the connection layer is Tungsten and the tie layer have a coefficient of thermal expansion of 4 ppm/°C.

接著,如『第2B圖』所示,先將光阻230塗佈於前述的氧化層220之上方,透過光罩再經由曝光與顯影之微影製程將定義出硬遮罩(Hard Mask),此硬遮罩所遮蔽的區域即為欲保留且不被破 壞的區域。接著,如『第2C圖』所示,使用乾式蝕刻(Dry Etching)以移除未被光阻230覆蓋之氧化層220,而被光阻230覆蓋之氧化層220將保留。在本實施例中,乾式蝕刻可透過反應式離子蝕刻(RIE)或是感應式耦合電漿(ICP)蝕刻等方式,但不以此為限,以達成非等向性之蝕刻。接著,如『第2D圖』所示,利用被光阻230覆蓋之氧化層220做為遮罩,繼續使用前述的乾式蝕刻移除氧化層220下方的基板210,使氧化層220的結構懸浮並形成蝕刻區240。最後,如『第2E圖』所示,利用前述的乾式蝕刻移除位於氧化層220上方的光阻230(如第2D圖所示),此時,即可完成『第1圖』之微機電裝置100的製程。 Next, as shown in FIG. 2B, the photoresist 230 is first applied over the oxide layer 220, and a hard mask is defined through the photomask and the lithography process of exposure and development. The area covered by this hard mask is intended to be retained and not broken. Bad area. Next, as shown in FIG. 2C, dry etching is used to remove the oxide layer 220 not covered by the photoresist 230, and the oxide layer 220 covered by the photoresist 230 is retained. In this embodiment, the dry etching may be performed by reactive ion etching (RIE) or inductively coupled plasma (ICP) etching, but not limited thereto to achieve anisotropic etching. Next, as shown in FIG. 2D, the oxide layer 220 covered by the photoresist 230 is used as a mask, and the substrate 210 under the oxide layer 220 is removed by using the dry etching described above to suspend the structure of the oxide layer 220. An etched region 240 is formed. Finally, as shown in FIG. 2E, the photoresist 230 located above the oxide layer 220 is removed by the dry etching described above (as shown in FIG. 2D), and at this time, the MEMS of "Fig. 1" can be completed. Process of device 100.

綜上所述,相較於習知技術,由於此微機電裝置係透過氧化層或是氧化層包覆連接層的方式以做為質量塊的結構,可使結構本身運動不受到溫度變化的影響,進而達成高穩定性之功效。 In summary, compared with the prior art, since the MEMS device is coated with a connecting layer through an oxide layer or an oxide layer as a mass structure, the structure itself can be moved without being affected by temperature changes. To achieve high stability.

雖然本揭露以前述之實施例揭露如上,然其並非用以限定本揭露。在不脫離本揭露之精神和範圍內,所為之更動與潤飾,均屬本揭露之專利保護範圍。關於本揭露所界定之保護範圍請參考所附之申請專利範圍。 Although the disclosure is disclosed above in the foregoing embodiments, it is not intended to limit the disclosure. All changes and refinements are beyond the scope of this disclosure. Please refer to the attached patent application for the scope of protection defined by this disclosure.

100‧‧‧微機電裝置 100‧‧‧Micro-electromechanical devices

110、210‧‧‧基板 110, 210‧‧‧ substrate

111‧‧‧第一電極 111‧‧‧First electrode

112‧‧‧第二電極 112‧‧‧second electrode

113‧‧‧第一區 113‧‧‧First District

114‧‧‧第二區 114‧‧‧Second District

115、240‧‧‧蝕刻區 115, 240‧‧ ‧ etched area

120、220‧‧‧氧化層 120, 220‧‧‧ oxide layer

121‧‧‧第三電極 121‧‧‧ third electrode

122‧‧‧第四電極 122‧‧‧fourth electrode

123‧‧‧第一側邊 123‧‧‧First side

124‧‧‧第二側邊 124‧‧‧Second side

130‧‧‧懸臂 130‧‧‧cantilever

230‧‧‧光阻 230‧‧‧Light resistance

第1圖係為根據本揭露之一實施例之一種微機電裝置。 1 is a microelectromechanical device in accordance with an embodiment of the present disclosure.

第2A圖至第2E圖所繪示係為第1圖之一種微機電裝置的製造流程示意圖。 2A to 2E are schematic views showing a manufacturing process of a microelectromechanical device according to Fig. 1.

100‧‧‧微機電裝置 100‧‧‧Micro-electromechanical devices

110‧‧‧基板 110‧‧‧Substrate

111‧‧‧第一電極 111‧‧‧First electrode

112‧‧‧第二電極 112‧‧‧second electrode

113‧‧‧第一區 113‧‧‧First District

114‧‧‧第二區 114‧‧‧Second District

115‧‧‧蝕刻區 115‧‧‧etched area

120‧‧‧氧化層 120‧‧‧Oxide layer

121‧‧‧第三電極 121‧‧‧ third electrode

122‧‧‧第四電極 122‧‧‧fourth electrode

123‧‧‧第一側邊 123‧‧‧First side

124‧‧‧第二側邊 124‧‧‧Second side

130‧‧‧懸臂 130‧‧‧cantilever

Claims (6)

一種微機電裝置,其包括:一基板,包含多個第一電極、多個第二電極、一第一區、一第二區、及一蝕刻區,該些第一電極位於該第一區,該些第二電極位於該第二區,該蝕刻區位於該基板的中央,該第一區與該第二區彼此相對;一氧化層,設置於該蝕刻區的中央,該氧化層包含一連接層,該連接層包覆於該氧化層中,該連接層的材料為鎢,該氧化層包含多個第三電極、多個第四電極、一第一側邊、及一第二側邊,該些第三電極位於該第一側邊,該些第四電極位於該第二側邊,該第一側邊與該第二側邊彼此相對;以及多個懸臂,分別設置於該基板的周圍與該氧化層的周圍之間,該些懸臂用以支撐該氧化層;其中該些第一電極與該些第三電極彼此交叉相對,該些第二電極與該些第四電極彼此交叉相對。 A microelectromechanical device includes: a substrate including a plurality of first electrodes, a plurality of second electrodes, a first region, a second region, and an etched region, wherein the first electrodes are located in the first region The second electrodes are located in the second region, the etching region is located at a center of the substrate, the first region and the second region are opposite to each other; an oxide layer is disposed at a center of the etching region, and the oxide layer includes a connection a layer, the connection layer is coated in the oxide layer, the connection layer is made of tungsten, and the oxide layer comprises a plurality of third electrodes, a plurality of fourth electrodes, a first side, and a second side. The third electrodes are located on the first side, the fourth electrodes are located on the second side, the first side and the second side are opposite to each other, and a plurality of cantilevers are respectively disposed around the substrate The cantilever is configured to support the oxide layer, and the first electrodes and the third electrodes are opposite to each other, and the second electrodes and the fourth electrodes are opposite to each other. 如請求項1所述之微機電裝置,其中該基板的材料為矽。 The MEMS device of claim 1, wherein the material of the substrate is ruthenium. 如請求項1所述之微機電裝置,其中該氧化層為二氧化矽。 The MEMS device of claim 1, wherein the oxide layer is cerium oxide. 如請求項3所述之微機電裝置,其中該氧化層的熱膨脹係數為0.5ppm/℃。 The microelectromechanical device of claim 3, wherein the oxide layer has a coefficient of thermal expansion of 0.5 ppm/° C. 如請求項5所述之微機電裝置,其中該連接層的熱膨脹係數為4ppm/℃。 The microelectromechanical device of claim 5, wherein the connecting layer has a coefficient of thermal expansion of 4 ppm/° C. 如請求項1所述之微機電裝置,其中該些懸臂的材料為金屬。 The MEMS device of claim 1, wherein the materials of the cantilevers are metal.
TW102100781A 2013-01-09 2013-01-09 Mems apparatus TWI472002B (en)

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