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TWI469272B - Method of manufacturing damascene structue for nand flash memory - Google Patents

Method of manufacturing damascene structue for nand flash memory Download PDF

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TWI469272B
TWI469272B TW101148798A TW101148798A TWI469272B TW I469272 B TWI469272 B TW I469272B TW 101148798 A TW101148798 A TW 101148798A TW 101148798 A TW101148798 A TW 101148798A TW I469272 B TWI469272 B TW I469272B
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layer
dielectric layer
opening
forming
flash memory
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TW101148798A
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TW201426912A (en
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Lu Ping Chiang
Hsiu Han Liao
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Winbond Electronics Corp
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Description

NAND快閃記憶體之鑲嵌結構的製造方法Method for manufacturing NAND flash memory mosaic structure

本發明是有關於一種非揮發性記憶體的製造方法,且特別是有關於一種NAND快閃記憶體之鑲嵌結構的製造方法。The present invention relates to a method of fabricating a non-volatile memory, and more particularly to a method of fabricating a damascene structure of a NAND flash memory.

隨著積體電路技術的進步及元件尺寸的縮小,為了克服愈來愈小的線寬以及防止對準失誤(mis-alignment),通常會採用自行對準製程(self-alignment process)的設計。With advances in integrated circuit technology and shrinking component sizes, in order to overcome ever-increasing line widths and prevent mis-alignment, a self-alignment process design is often employed.

以NAND快閃記憶體元件為例,為了確保電性連接,各位元線需要覆蓋介層窗,且介層窗必須覆蓋並垂直地對準相對應的接觸窗,因此通常需進行多道微影製程來形成上述結構,且需要高的解析度,從而容易增加對準失誤的風險。Taking NAND flash memory components as an example, in order to ensure electrical connection, each of the lines needs to cover the vias, and the vias must cover and vertically align with the corresponding contact windows, so multiple lithography is usually required. The process forms the above structure and requires high resolution, thereby easily increasing the risk of misalignment.

因此,亟需一種可簡化製程步驟及避免對準失誤問題之NAND快閃記憶體的內連線的製造方法。Therefore, there is a need for a method of fabricating an interconnect of a NAND flash memory that simplifies the process steps and avoids misalignment problems.

本發明提供一種NAND快閃記憶體之鑲嵌結構的製造方法,其可簡化製程步驟以及避免對準失誤。The invention provides a manufacturing method of a mosaic structure of a NAND flash memory, which can simplify the process steps and avoid misalignment.

本發明另提供一種NAND快閃記憶體之鑲嵌結構的製造方法,其以簡單步驟形成位元線,而同時降低週邊區中導線的電阻值。The present invention further provides a method of fabricating a damascene structure of a NAND flash memory, which forms a bit line in a simple step while reducing the resistance value of the wire in the peripheral region.

本發明提出一種NAND快閃記憶體之鑲嵌結構的製造方法。提供具有記憶胞陣列的基底,記憶胞陣列包括沿一方向配置的多個NAND串,且在此方向上,各NAND串包括多個字元線及位於多個字元線下方的多個浮置閘極,以及位在多個字元線之兩端的兩個選擇電晶體。在基底上形成覆蓋記憶胞陣列的第一介電層。在鄰近的NAND串之間形成接觸基板的至少一接觸窗插塞。在第一介電層及接觸窗插塞上依序形成終止層及第二介電層。在第二介電層上形成圖案化終止層,其具有對應接觸窗插塞的至少一第一開口並露出第二介電層。在圖案化終止層上及第一開口中形成第三介電層。在第三介電層上形成圖案化罩幕層,其具有對應第一開口的至少一第二開口,且此第二開口沿上述方向延伸並露出第三介電層。以圖案化罩幕層為罩幕,移除自第二開口露出的第三介電層而形成溝渠,並繼續移除自第一開口露出的第二介電層而形成介層窗並露出終止層。移除露出的終止層,使接觸窗插塞暴露出來。在溝渠及介層窗內形成與接觸窗插塞接觸的導體層。The invention provides a method for manufacturing a mosaic structure of a NAND flash memory. Providing a substrate having an array of memory cells, the memory cell array comprising a plurality of NAND strings arranged in one direction, and in this direction, each NAND string comprises a plurality of word lines and a plurality of floating spaces below the plurality of word lines A gate, and two select transistors positioned at opposite ends of the plurality of word lines. A first dielectric layer covering the array of memory cells is formed on the substrate. At least one contact plug that contacts the substrate is formed between adjacent NAND strings. A termination layer and a second dielectric layer are sequentially formed on the first dielectric layer and the contact plug. A patterned termination layer is formed on the second dielectric layer having at least one first opening corresponding to the contact plug and exposing the second dielectric layer. A third dielectric layer is formed on the patterned termination layer and in the first opening. A patterned mask layer is formed on the third dielectric layer, and has at least one second opening corresponding to the first opening, and the second opening extends in the above direction and exposes the third dielectric layer. Using the patterned mask layer as a mask, removing the third dielectric layer exposed from the second opening to form a trench, and continuing to remove the second dielectric layer exposed from the first opening to form a via window and exposing the termination Floor. The exposed termination layer is removed to expose the contact window plug. A conductor layer in contact with the contact plug is formed in the trench and the via.

本發明另提出一種NAND快閃記憶體之鑲嵌結構的製造方法。提供具有記憶胞陣列及週邊區的基底,且週邊區包括至少一電晶體,以及記憶胞陣列包括沿一方向配置的多個NAND串,而在此方向上,各NAND串包括多個字元線及位於多個字元線下方的多個浮置閘極,以及位在多個字元線之兩端的兩個選擇電晶體。在基底上形成覆蓋記憶胞陣列及週邊區之電晶體的第一介電層。在鄰近的 NAND串之間形成接觸基板的至少一第一接觸窗插塞。在第一介電層及第一接觸窗插塞上依序形成終止層及第二介電層。在第二介電層上形成圖案化終止層,其具有對應第一接觸窗插塞的至少一第一開口與位於週邊區的至少一第二開口,並露出第二介電層。在圖案化終止層上以及第一開口及第二開口中形成第三介電層。在第三介電層上形成圖案化罩幕層,其具有對應第一開口且沿上述方向延伸的至少一第三開口,以及對應第二開口的至少一第四開口,並露出第三介電層。以圖案化罩幕層為罩幕,移除自第三開口與第四開口露出的第三介電層而形成溝渠,並繼續移除自第一開口及第二開口露出的第二介電層而形成介層窗並露出終止層。移除露出的終止層,使第一接觸窗插塞及週邊區的第一介電層暴露出來。在溝渠與介層窗內形成與第一接觸窗插塞接觸的導體層。The invention further provides a method for manufacturing a damascene structure of a NAND flash memory. Providing a substrate having a memory cell array and a peripheral region, wherein the peripheral region includes at least one transistor, and the memory cell array includes a plurality of NAND strings arranged in one direction, and in this direction, each NAND string includes a plurality of word lines And a plurality of floating gates located below the plurality of word lines, and two selection transistors positioned at opposite ends of the plurality of word lines. A first dielectric layer covering the transistor of the memory cell array and the peripheral region is formed on the substrate. In the neighborhood At least one first contact window plug that contacts the substrate is formed between the NAND strings. A termination layer and a second dielectric layer are sequentially formed on the first dielectric layer and the first contact window plug. Forming a patterned termination layer on the second dielectric layer having at least one first opening corresponding to the first contact window plug and at least one second opening in the peripheral region, and exposing the second dielectric layer. A third dielectric layer is formed on the patterned termination layer and in the first opening and the second opening. Forming a patterned mask layer on the third dielectric layer, having at least one third opening corresponding to the first opening and extending in the above direction, and at least one fourth opening corresponding to the second opening, and exposing the third dielectric Floor. Forming the mask layer as a mask, removing the third dielectric layer exposed from the third opening and the fourth opening to form a trench, and continuing to remove the second dielectric layer exposed from the first opening and the second opening A via window is formed and the termination layer is exposed. The exposed termination layer is removed to expose the first contact plug and the first dielectric layer of the peripheral region. A conductor layer in contact with the first contact plug is formed in the trench and the via.

基於上述,本發明所提出之NAND快閃記憶體之鑲嵌結構的製造方法利用自行對準雙鑲嵌(self aligned daul damascene)製程,以形成位元線及與介層窗插塞,因而有效降低製程步驟複雜度以及避免對準失誤。另外,本發明所提出之NAND快閃記憶體之鑲嵌結構的製造方法可在基底上同時對記憶胞陣列及週邊區進行處理,因此有效地降低製程複雜度,並且可降低週邊區中導線的電阻值。Based on the above, the manufacturing method of the NAND flash memory mosaic structure proposed by the present invention utilizes a self aligned daul damascene process to form a bit line and a via plug, thereby effectively reducing the process. Step complexity and avoid alignment errors. In addition, the manufacturing method of the NAND flash memory mosaic structure of the present invention can simultaneously process the memory cell array and the peripheral region on the substrate, thereby effectively reducing the process complexity and reducing the resistance of the wires in the peripheral region. value.

為讓本發明之上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。The above described features and advantages of the present invention will be more apparent from the following description.

圖1到圖7C為依照本發明之第一實施例的NAND快閃記憶體的鑲嵌結構之製造流程圖。1 to 7C are flowcharts showing the manufacture of a damascene structure of a NAND flash memory in accordance with a first embodiment of the present invention.

首先,請參照圖1,提供其上具有記憶胞陣列102的基底100,基底100例如是矽基底。在B-B線方向上,記憶胞陣列102配置有多個NAND串104,各個NAND串104包括多個字元線106、位在字元線106下方的浮置閘極107,以及位在多個字元線106兩端的兩個選擇電晶體108,其中字元線106及浮置閘極107的材料例如是摻雜多晶矽。而字元線106與浮置閘極107之間更包括具有閘間介電層109,其材料例如是氧化矽/氮化矽/氧化矽。此外,在基底100與記憶胞陣列102之間更包括形成有閘極氧化層110,其材料例如是氧化矽,而其形成方法包括進行熱氧化法。另外,在圖1中的各個NAND串104雖然只繪示2個字元線106,但本發明並不限定於此。First, referring to Fig. 1, a substrate 100 having a memory cell array 102 thereon, such as a germanium substrate, is provided. In the BB line direction, the memory cell array 102 is configured with a plurality of NAND strings 104, each NAND string 104 including a plurality of word lines 106, floating gates 107 located below the word lines 106, and bits in multiple words. Two select transistors 108 are provided at both ends of the line 106, wherein the material of the word line 106 and the floating gate 107 is, for example, doped polysilicon. The word line 106 and the floating gate 107 further include an inter-gate dielectric layer 109, such as yttria/tantalum nitride/yttria. In addition, a gate oxide layer 110 is formed between the substrate 100 and the memory cell array 102, and the material thereof is, for example, ruthenium oxide, and the method for forming the method includes performing a thermal oxidation method. In addition, although only two word lines 106 are shown in each NAND string 104 in FIG. 1, the present invention is not limited to this.

接著,請參照圖2,在基底100上形成第一介電層112,以覆蓋記憶胞陣列102。第一介電層112的材料例如是氧化矽,而其形成方法包括進行化學氣相沈積製程。之後,在B-B線方向上之鄰近的兩個NAND串104之間形成接觸基底100的接觸窗插塞114。接觸窗插塞114的材料例如是金屬鎢,而其形成方法例如在第一介電層112及閘極氧化層110中形成暴露出部分基底100的接觸窗開口(未繪示),然後於接觸窗開口中填滿金屬材料,以形成接觸窗插塞114,但本發明並不以此為限。此外,在形成第一介 電層112之前還可選擇於選擇電晶體108的側壁上形成間隙壁111,其材料例如是氮化矽。在本實施例中,接觸窗插塞114例如是位元線接觸窗插塞,且當形成位元線接觸窗插塞的同時,還可形成NAND串104的源極線插塞(未繪示)。另外,在圖2中,雖然繪示基底100上具有5個接觸窗插塞114,但本發明並不限定於此。Next, referring to FIG. 2, a first dielectric layer 112 is formed on the substrate 100 to cover the memory cell array 102. The material of the first dielectric layer 112 is, for example, ruthenium oxide, and the method of forming the method includes performing a chemical vapor deposition process. Thereafter, a contact plug 114 contacting the substrate 100 is formed between adjacent two NAND strings 104 in the B-B line direction. The material of the contact window plug 114 is, for example, metal tungsten, and the forming method thereof forms, for example, a contact window opening (not shown) exposing a portion of the substrate 100 in the first dielectric layer 112 and the gate oxide layer 110, and then in contact. The window opening is filled with a metal material to form the contact plug 114, but the invention is not limited thereto. In addition, in the formation of the first The electrical layer 112 may also be selected to form a spacer 111 on the sidewall of the selective transistor 108, the material of which is, for example, tantalum nitride. In the present embodiment, the contact window plug 114 is, for example, a bit line contact window plug, and the source line plug of the NAND string 104 can also be formed while forming the bit line contact window plug (not shown) ). In addition, in FIG. 2, although the five contact window plugs 114 are shown in the base 100, this invention is not limited to this.

此外,雖然圖2中繪示的第一介電層112高於間隙壁111而覆蓋NAND串104,但本發明並不以此為限;換句話說,第一介電層112的頂面可與間隙壁111的頂面共平面,剛好填滿NAND串104之間的空隙。In addition, although the first dielectric layer 112 illustrated in FIG. 2 is higher than the spacer 111 to cover the NAND string 104, the present invention is not limited thereto; in other words, the top surface of the first dielectric layer 112 may be Coplanar with the top surface of the spacer 111, just filling the gap between the NAND strings 104.

之後,請參照圖3,在第一介電層112及接觸窗插塞114上依序形成終止層116及第二介電層118。終止層116的材料例如是氮化矽,而其形成方法包括進行化學氣相沈積製程。而第二介電層118例如是氧化矽層,其形成方法包括進行化學氣相沈積製程。Thereafter, referring to FIG. 3, the termination layer 116 and the second dielectric layer 118 are sequentially formed on the first dielectric layer 112 and the contact window plug 114. The material of the termination layer 116 is, for example, tantalum nitride, and the method of forming the method includes performing a chemical vapor deposition process. The second dielectric layer 118 is, for example, a ruthenium oxide layer, and the formation method thereof includes performing a chemical vapor deposition process.

然後,請參照圖4,在第二介電層118上形成圖案化終止層122,其具有對應接觸窗插塞114的至少一第一開口123,並暴露出對應第一開口123的部分第二介電層118。圖案化終止層122的材料例如是氮化矽,而其形成方法例如先在第二介電層118上全面性地沈積一層材料層,再進行微影蝕刻製程,以於此材料層中形成第一開口123。Then, referring to FIG. 4, a patterned termination layer 122 is formed on the second dielectric layer 118, and has at least one first opening 123 corresponding to the contact window plug 114, and exposes a portion corresponding to the first opening 123. Dielectric layer 118. The material of the patterned termination layer 122 is, for example, tantalum nitride, and the formation method thereof is, for example, firstly depositing a layer of material on the second dielectric layer 118, and then performing a photolithography process to form a layer in the material layer. An opening 123.

之後,請參照圖5A、圖5B及圖5C,其中圖5A為上視圖,圖5B為沿圖5A中之B-B線的剖面圖,而圖5C為沿圖5A中之C-C線的剖面圖。在圖案化終止層122上及 第一開口123中形成第三介電層124。第三介電層124例如是氧化矽層,其形成方法包括進行化學氣相沈積製程。接著,在第三介電層124上形成圖案化罩幕層126,其具有對應第一開口123的至少一第二開口125,且第二開口125呈溝槽狀並暴露出對應第二開口125的部分第三介電層124。圖案化罩幕層126的材料例如是光阻材料,且其第二開口125是以微影製程形成。在其他實施例中,圖案化罩幕層126亦可為硬罩幕(hard mask)。5A, 5B, and 5C, wherein FIG. 5A is a top view, FIG. 5B is a cross-sectional view taken along line B-B of FIG. 5A, and FIG. 5C is a cross-sectional view taken along line C-C of FIG. 5A. On the patterned termination layer 122 and A third dielectric layer 124 is formed in the first opening 123. The third dielectric layer 124 is, for example, a hafnium oxide layer, and the method of forming the same includes performing a chemical vapor deposition process. Next, a patterned mask layer 126 is formed on the third dielectric layer 124, and has at least one second opening 125 corresponding to the first opening 123, and the second opening 125 is groove-shaped and exposes the corresponding second opening 125. A portion of the third dielectric layer 124. The material of the patterned mask layer 126 is, for example, a photoresist material, and the second opening 125 is formed by a lithography process. In other embodiments, the patterned mask layer 126 can also be a hard mask.

然後,請參照圖6A及圖6B,其分別顯示圖5B以及圖5C的下一步驟的同一視角圖。在以圖案化罩幕層126為罩幕,移除自第二開口125露出的部分第三介電層124而形成溝渠127之後,繼續移除自第一開口123露出的部分第二介電層118而形成介層窗128並暴露出對應第一開口123的部分終止層116。部分第三介電層124及部分第二介電層118的移除方法例如乾蝕刻製程。Next, please refer to FIG. 6A and FIG. 6B, which respectively show the same perspective view of the next step of FIG. 5B and FIG. 5C. After the mask layer 126 is used as a mask to remove a portion of the third dielectric layer 124 exposed from the second opening 125 to form the trench 127, a portion of the second dielectric layer exposed from the first opening 123 is removed. A via window 128 is formed 118 and a portion of the termination layer 116 corresponding to the first opening 123 is exposed. A method of removing a portion of the third dielectric layer 124 and a portion of the second dielectric layer 118 is, for example, a dry etch process.

之後,請參照圖7A、圖7B及圖7C,其中圖7A為上視圖,圖7B為沿圖7A中之B-B線的剖面圖,而圖7C為沿圖7A中之C-C線的剖面圖。移除露出的部分終止層116,使接觸窗插塞114暴露出來,部分終止層116的移除方法包括進行乾蝕刻製程。接著,在溝渠127及介層窗128內形成導體層130,且導體層130與接觸窗插塞114相接觸,其中導體層130的材料例如是金屬鎢,而其形成方法包括進行化學氣相沈積製程。然後,可藉由化學機械研磨製程(CMP)將溝渠127之外的金屬鎢移除。此外,在形成導體層130之前,還 可先將圖案化罩幕層126移除,且移除方法包括進行乾式蝕刻製程。在本實施例中,沿B-B線方向延伸的導體層130是作為NAND快閃記憶體的位元線。7A, 7B, and 7C, wherein Fig. 7A is a top view, Fig. 7B is a cross-sectional view taken along line B-B of Fig. 7A, and Fig. 7C is a cross-sectional view taken along line C-C of Fig. 7A. The exposed portion of the termination layer 116 is removed to expose the contact plug 114, and the method of removing the portion of the termination layer 116 includes a dry etch process. Next, a conductor layer 130 is formed in the trench 127 and the via 128, and the conductor layer 130 is in contact with the contact plug 114. The material of the conductor layer 130 is, for example, metal tungsten, and the forming method includes performing chemical vapor deposition. Process. The tungsten metal outside the trench 127 can then be removed by a chemical mechanical polishing process (CMP). In addition, before forming the conductor layer 130, The patterned mask layer 126 can be removed first, and the removal method includes a dry etch process. In the present embodiment, the conductor layer 130 extending in the B-B line direction is a bit line as a NAND flash memory.

基於第一實施例可知,上述NAND快閃記憶體的製造方法於介電層中夾了一層圖案化終止層122,並利用介電層(如氧化矽)對終止層(如氮化矽)之高蝕刻選擇比,以一步驟蝕刻製程形成溝渠127及介層窗128,並一步驟完成金屬鎢的填入,因此為一自行對準雙鑲嵌製程,其有效地降低製程步驟複雜度,及避免對準失誤。According to the first embodiment, the method for fabricating the NAND flash memory has a patterned termination layer 122 sandwiched between the dielectric layers and a termination layer (such as tantalum nitride) by a dielectric layer (such as hafnium oxide). The high etching selectivity ratio forms the trench 127 and the via 128 in a one-step etching process, and completes the filling of the metal tungsten in one step, thereby being a self-aligned dual damascene process, which effectively reduces the complexity of the process steps and avoids Misalignment.

圖8A到圖8G為依照本發明之第二實施例的NAND快閃記憶體的鑲嵌結構之製造流程剖面圖。應注意,圖示僅作為解說之用,並非用以限定本發明。8A to 8G are cross-sectional views showing a manufacturing process of a damascene structure of a NAND flash memory in accordance with a second embodiment of the present invention. It should be noted that the illustrations are for illustrative purposes only and are not intended to limit the invention.

首先,請參照圖8A,提供基底200,基底200例如是矽基底,且其具有記憶胞陣列202及週邊區203,其中週邊區203包括至少一電晶體205,電晶體205由閘介電層205b及位於閘介電層205b上之閘極205a所構成。另外,在剖面方向上,記憶胞陣列202配置有多個NAND串204,各個NAND串204包括多個字元線206、位在字元線206下方的多個浮置閘極207,以及位在多個字元線206兩端的兩個選擇電晶體208,其中字元線206及浮置閘極207的材料例如是摻雜多晶矽,其可與週邊區203的閘極205a一起形成。而字元線206與浮置閘極207之間更包括具有閘間介電層209,其材料例如是氧化矽/氮化矽/氧化矽。此外,在基底200與記憶胞陣列202之間更包括形成有閘極 氧化層210,其材料例如是氧化矽,而其可與週邊區203的閘介電層205b一起藉由如熱氧化法之類的製程形成。另外,在圖8A中的各個NAND串204雖然只繪示2個字元線206,且週邊區203只繪示一個電晶體205,但本發明並不限定於此。First, referring to FIG. 8A, a substrate 200 is provided. The substrate 200 is, for example, a germanium substrate, and has a memory cell array 202 and a peripheral region 203. The peripheral region 203 includes at least one transistor 205, and the transistor 205 is composed of a gate dielectric layer 205b. And a gate 205a on the gate dielectric layer 205b. In addition, in the cross-sectional direction, the memory cell array 202 is configured with a plurality of NAND strings 204, each NAND string 204 including a plurality of word lines 206, a plurality of floating gates 207 located below the word lines 206, and Two select transistors 208 at both ends of the plurality of word lines 206, wherein the material of the word line 206 and the floating gate 207 are, for example, doped polysilicon, which may be formed together with the gate 205a of the peripheral region 203. The word line 206 and the floating gate 207 further include an inter-gate dielectric layer 209, such as yttria/tantalum nitride/yttria. In addition, a gate is formed between the substrate 200 and the memory cell array 202. The oxide layer 210, which is made of, for example, tantalum oxide, can be formed together with the gate dielectric layer 205b of the peripheral region 203 by a process such as thermal oxidation. In addition, although only two word lines 206 are shown in each NAND string 204 in FIG. 8A, and only one transistor 205 is shown in the peripheral area 203, the present invention is not limited thereto.

接著,請參照圖8B,在基底200上形成第一介電層212,以覆蓋記憶胞陣列202及週邊區203的電晶體205。第一介電層212的材料例如是氧化矽,而其形成方法包括進行化學氣相沈積製程。此外,在形成第一介電層212之前,可選擇於選擇電晶體208及電晶體205的側壁上形成間隙壁211,其材料例如是氮化矽。另外,雖然圖8B中繪示的第一介電層212高於間隙壁211而覆蓋NAND串204,但本發明並不以此為限;換句話說,第一介電層212的頂面可與間隙壁211的頂面共平面,剛好填滿住NAND串204之間的空隙。之後,在剖面方向上之鄰近的兩個NAND串204之間形成接觸基底200的第一接觸窗插塞214。第一接觸窗插塞214的材料例如是金屬鎢,而其形成方法例如在第一介電層212及閘極氧化層210中形成暴露出部分基底200的接觸窗開口(未繪示),然後於接觸窗開口中填滿金屬材料,以形成第一接觸窗插塞214,但本發明並不以此為限。在本實施例中,第一接觸窗插塞214例如是位元線接觸窗插塞,且當形成位元線接觸窗插塞的同時,還可形成NAND串204之源極線插塞(未繪示)。Next, referring to FIG. 8B, a first dielectric layer 212 is formed on the substrate 200 to cover the memory cell array 202 and the transistor 205 of the peripheral region 203. The material of the first dielectric layer 212 is, for example, tantalum oxide, and the method of forming the method includes performing a chemical vapor deposition process. In addition, before forming the first dielectric layer 212, a spacer 211 may be formed on the sidewalls of the selective transistor 208 and the transistor 205, and the material thereof is, for example, tantalum nitride. In addition, although the first dielectric layer 212 illustrated in FIG. 8B is higher than the spacer 211 to cover the NAND string 204, the present invention is not limited thereto; in other words, the top surface of the first dielectric layer 212 may be Coplanar with the top surface of the spacer 211 just fills the gap between the NAND strings 204. Thereafter, a first contact plug 214 that contacts the substrate 200 is formed between adjacent NAND strings 204 in the cross-sectional direction. The material of the first contact window plug 214 is, for example, metal tungsten, and the forming method thereof, for example, forms a contact window opening (not shown) exposing a portion of the substrate 200 in the first dielectric layer 212 and the gate oxide layer 210, and then The contact opening is filled with a metal material to form the first contact window plug 214, but the invention is not limited thereto. In the present embodiment, the first contact window plug 214 is, for example, a bit line contact window plug, and the source line plug of the NAND string 204 can also be formed while forming the bit line contact window plug (not Painted).

之後,請參照圖8C,在第一介電層212及第一接觸窗 插塞214上依序形成終止層216及第二介電層218。終止層216的材料例如是氮化矽,而其形成方法包括進行化學氣相沈積製程製程。而第二介電層218例如是氧化矽層,其形成方法包括進行化學氣相沈積製程。Thereafter, please refer to FIG. 8C, at the first dielectric layer 212 and the first contact window. A termination layer 216 and a second dielectric layer 218 are sequentially formed on the plug 214. The material of the termination layer 216 is, for example, tantalum nitride, and the method of forming the method includes performing a chemical vapor deposition process. The second dielectric layer 218 is, for example, a ruthenium oxide layer, and the formation method thereof includes performing a chemical vapor deposition process.

然後,請參照圖8D,在第二介電層218上形成圖案化終止層222,其具有對應第一接觸窗插塞214的至少一第一開口223及位於週邊區203的至少一第二開口231,並暴露出對應第一開口223及第二開口231的部分第二介電層218。圖案化終止層222的材料例如是氮化矽,而其形成方法例如先在第二介電層218上全面性地沈積一層材料層,再進行微影蝕刻製程,以於此材料層中形成第一開口223及第二開口231。之後,在圖案化終止層222上以及第一開口223及第二開口231中形成第三介電層224。第三介電層224例如是氧化矽層,其形成方法包括進行化學氣相沈積製程。另外,圖8D中的第二開口231雖然繪示在週邊區203的電晶體205上方,但本發明並不以此為限。Then, referring to FIG. 8D, a patterned termination layer 222 is formed on the second dielectric layer 218, and has at least one first opening 223 corresponding to the first contact window plug 214 and at least one second opening located in the peripheral region 203. 231, and a portion of the second dielectric layer 218 corresponding to the first opening 223 and the second opening 231 is exposed. The material of the patterned termination layer 222 is, for example, tantalum nitride, and the formation method thereof is, for example, firstly depositing a layer of material on the second dielectric layer 218, and then performing a photolithography process to form a layer in the material layer. An opening 223 and a second opening 231. Thereafter, a third dielectric layer 224 is formed on the patterned termination layer 222 and in the first opening 223 and the second opening 231. The third dielectric layer 224 is, for example, a hafnium oxide layer, and the method of forming the same includes performing a chemical vapor deposition process. In addition, although the second opening 231 in FIG. 8D is shown above the transistor 205 of the peripheral region 203, the invention is not limited thereto.

接著,請參照圖8E,在第三介電層224上形成圖案化罩幕層226,其在記憶胞陣列202上具有對應第一開口223且沿剖面方向延伸的至少一第三開口225,以及在週邊區203有對應第二開口231的至少一第四開口233,並暴露出部分第三介電層224。圖案化罩幕層226的材料例如是光阻材料,且其第三開口225及第四開口233是以微影製程形成,但本發明並不以此為限。在其他實施例中,圖案化罩幕層226亦可為硬罩幕。其中,圖8E中的虛線表示圖 案化罩幕層226在平行於剖面方向上的輪廓;且在貫穿頁面的方向上,圖案化罩幕層226內的第三開口225是間隔排列,如第一實施例中之圖5A及圖5C所示。Next, referring to FIG. 8E, a patterned mask layer 226 is formed on the third dielectric layer 224, and has at least one third opening 225 on the memory cell array 202 corresponding to the first opening 223 and extending in the cross-sectional direction, and At least one fourth opening 233 corresponding to the second opening 231 is formed in the peripheral region 203, and a portion of the third dielectric layer 224 is exposed. The material of the patterned mask layer 226 is, for example, a photoresist material, and the third opening 225 and the fourth opening 233 are formed by a lithography process, but the invention is not limited thereto. In other embodiments, the patterned mask layer 226 can also be a hard mask. Wherein, the dotted line in FIG. 8E represents a diagram The patterned mask layer 226 is contoured parallel to the cross-sectional direction; and in the direction through the page, the third openings 225 in the patterned mask layer 226 are spaced apart, as in FIG. 5A and FIG. 5C is shown.

然後,請參照圖8F,以圖案化罩幕層226為罩幕,移除自第三開口225及第四開口233露出的部分第三介電層224而在記憶胞陣列202上形成溝渠以及在週邊區203形成開口227,並繼續移除自第一開口223及第二開口231露出的部分第二介電層218而在記憶胞陣列202上形成介層窗228a以及在週邊區203形成介層窗228b,並暴露出部分終止層216。移除部分第三介電層224及部分第二介電層218的方法例如乾蝕刻製程。其中,圖8F之記憶胞陣列202中的溝渠平行於剖面方向,如第一實施例中之圖6B所示的溝渠127。Then, referring to FIG. 8F, the mask layer 226 is patterned as a mask to remove a portion of the third dielectric layer 224 exposed from the third opening 225 and the fourth opening 233 to form a trench on the memory cell array 202 and The peripheral region 203 forms an opening 227, and further removes a portion of the second dielectric layer 218 exposed from the first opening 223 and the second opening 231 to form a via 228a on the memory cell array 202 and a via in the peripheral region 203. Window 228b and exposes a portion of termination layer 216. A method of removing a portion of the third dielectric layer 224 and a portion of the second dielectric layer 218 is, for example, a dry etch process. The trench in the memory cell array 202 of FIG. 8F is parallel to the cross-sectional direction, such as the trench 127 shown in FIG. 6B in the first embodiment.

之後,請參照圖8G,移除露出的部分終止層216,使第一接觸窗插塞214暴露出來,此時週邊區203的第一介電層212也會暴露出來。部分終止層216的移除方法包括進行乾蝕刻製程。接著,在溝渠、開口227及介層窗228a-b內形成導體層230,且導體層230與第一接觸窗插塞214相接觸,其中導體層230的材料例如是金屬鎢,而其形成方法包括進行化學氣相沈積製程。然後,可藉由化學機械研磨製程將溝渠和開口227之外的金屬鎢移除。此外,在形成導體層230之前,還可先將圖案化罩幕層226移除,且移除方法包括進行乾式蝕刻製程。在本實施例中,記憶胞陣列202上沿剖面方向延伸的導體層230是作為NAND快閃記憶體的位元 線,而週邊區203的導體層230可作為內連線。Thereafter, referring to FIG. 8G, the exposed portion of the termination layer 216 is removed to expose the first contact window plug 214, and the first dielectric layer 212 of the peripheral region 203 is also exposed. The method of removing the portion of the termination layer 216 includes performing a dry etch process. Next, a conductor layer 230 is formed in the trench, the opening 227 and the via 228a-b, and the conductor layer 230 is in contact with the first contact plug 214, wherein the material of the conductor layer 230 is, for example, metal tungsten, and the forming method thereof Including the chemical vapor deposition process. The metal tungsten outside the trench and opening 227 can then be removed by a chemical mechanical polishing process. In addition, the patterned mask layer 226 may also be removed prior to forming the conductor layer 230, and the removal method includes performing a dry etching process. In this embodiment, the conductor layer 230 extending in the cross-sectional direction on the memory cell array 202 is a bit of the NAND flash memory. The wires, while the conductor layer 230 of the peripheral region 203 can serve as an interconnect.

同樣地,第二實施例是藉由自行對準雙鑲嵌製程形成位元線及與接觸窗插塞接觸的介層窗插塞,因而有效地降低製程複雜度,及避免對準失誤。另外,第二實施例因為NAND快閃記憶體的位元線和內連線是利用一致的步驟製作,所以不但不會增加製程複雜度,還能藉由增加內連線的深度,從而降低其阻值。Similarly, the second embodiment is to form a bit line and a via window plug in contact with the contact window plug by self-aligning the dual damascene process, thereby effectively reducing process complexity and avoiding alignment errors. In addition, in the second embodiment, since the bit lines and the interconnect lines of the NAND flash memory are fabricated by using a uniform step, not only the process complexity is not increased, but also the depth of the interconnect line is increased, thereby reducing the depth thereof. Resistance value.

圖9A到圖9F為依照本發明之第三實施例的NAND快閃記憶體的鑲嵌結構之製造流程剖面圖。其中,圖9A為接續圖8A之後所進行的步驟。此外,第三實施例和第二實施例中相同或相類似之構件可採用相同的材料或方法來進行,故於此不再贅述。9A to 9F are cross-sectional views showing a manufacturing process of a damascene structure of a NAND flash memory in accordance with a third embodiment of the present invention. Here, FIG. 9A is a step performed subsequent to FIG. 8A. In addition, the same or similar components in the third embodiment and the second embodiment may be carried out by the same material or method, and thus will not be described again.

首先,請參照圖9A,在剖面方向上之鄰近的兩個NAND串204之間形成接觸基底200的第一接觸窗插塞314,且同時在週邊區203中的電晶體205的至少一側形成接觸基底200的第二接觸窗插塞315。第一接觸窗插塞314及第二接觸窗插塞315的材料例如是金屬鎢,而其形成方法可參照上述各實施例。在本實施例中,第一接觸窗插塞314例如是位元線接觸窗插塞,且當形成位元線接觸窗插塞的同時,還可形成NAND串204之源極線插塞(未繪示);第二接觸窗插塞315則可連接至電晶體205之源/汲極(未繪示)。First, referring to FIG. 9A, a first contact plug 314 contacting the substrate 200 is formed between adjacent two NAND strings 204 in the cross-sectional direction, and simultaneously formed on at least one side of the transistor 205 in the peripheral region 203. The second contact window plug 315 of the substrate 200 is contacted. The material of the first contact window plug 314 and the second contact window plug 315 is, for example, metal tungsten, and the method of forming the same can be referred to the above embodiments. In the present embodiment, the first contact window plug 314 is, for example, a bit line contact window plug, and the source line plug of the NAND string 204 can also be formed while forming the bit line contact window plug (not The second contact window plug 315 can be connected to the source/drain of the transistor 205 (not shown).

接著,請參照圖9B,在第一介電層212、第一接觸窗插塞314及第二接觸窗插塞315上依序形成終止層316及 第二介電層318。終止層316的材料例如是氮化矽,而其形成方法可參照上述各實施例。而第二介電層318例如是氧化矽層,其形成方法亦可參照上述各實施例。Next, referring to FIG. 9B, a termination layer 316 is sequentially formed on the first dielectric layer 212, the first contact window plug 314, and the second contact window plug 315. The second dielectric layer 318. The material of the termination layer 316 is, for example, tantalum nitride, and the formation method thereof can be referred to the above embodiments. The second dielectric layer 318 is, for example, a ruthenium oxide layer, and the method of forming the same may be referred to the above embodiments.

然後,請參照圖9C,在第二介電層318上形成圖案化終止層322,其具有對應第一接觸窗插塞314的至少一第一開口323及對應週邊區203之第二接觸窗插塞315的至少一第五開口331,並暴露出對應第一開口323及第五開口331的部分第二介電層318。圖案化終止層322的材料例如是氮化矽,而其形成方法例如先在第二介電層318上全面性地沈積一層材料層,再進行微影蝕刻製程,以於此材料層中形成第一開口323及第五開口331。Then, referring to FIG. 9C, a patterned termination layer 322 is formed on the second dielectric layer 318, and has a second contact window corresponding to the first contact opening 323 of the first contact window plug 314 and the corresponding peripheral region 203. At least one fifth opening 331 of the plug 315 and a portion of the second dielectric layer 318 corresponding to the first opening 323 and the fifth opening 331 are exposed. The material of the patterned termination layer 322 is, for example, tantalum nitride, and the formation method thereof is, for example, firstly depositing a layer of material on the second dielectric layer 318, and then performing a photolithography process to form a layer in the material layer. An opening 323 and a fifth opening 331.

之後,在圖案化終止層322上以及第一開口323及第五開口331中形成第三介電層324。第三介電層324例如是氧化矽層,其形成方法可參照上述各實施例。Thereafter, a third dielectric layer 324 is formed on the patterned termination layer 322 and in the first opening 323 and the fifth opening 331. The third dielectric layer 324 is, for example, a ruthenium oxide layer, and the formation method thereof can be referred to the above embodiments.

接著,請參照圖9D,在第三介電層324上形成圖案化罩幕層326,其在記憶胞陣列202上具有對應第一開口323且沿剖面方向延伸的至少一第三開口325,以及在週邊區203有對應第五開口331的至少一第六開口333,並暴露出部分第三介電層324。圖案化罩幕層326的材料與形成方式可參照上述各實施例。其中,圖9D中的虛線表示圖案化罩幕層326在平行於剖面方向上的輪廓;且在貫穿頁面的方向上,與圖案化罩幕層326內的第三開口325間隔排列,如第一實施例中之圖5A及圖5C所示。另外,第六開口333不但可如圖9D所示是在貫穿頁面的方向上延伸, 也可依設計需要而改為沿剖面方向延伸。Next, referring to FIG. 9D, a patterned mask layer 326 is formed on the third dielectric layer 324, and has at least a third opening 325 on the memory cell array 202 corresponding to the first opening 323 and extending in the cross-sectional direction, and At least one sixth opening 333 corresponding to the fifth opening 331 is formed in the peripheral region 203, and a portion of the third dielectric layer 324 is exposed. The materials and formation of the patterned mask layer 326 can be referred to the above embodiments. The dashed line in FIG. 9D indicates the contour of the patterned mask layer 326 in a direction parallel to the cross-section; and is spaced apart from the third opening 325 in the patterned mask layer 326 in the direction through the page, such as the first 5A and 5C in the embodiment. In addition, the sixth opening 333 can extend not only in the direction of the page as shown in FIG. 9D. It can also be extended in the direction of the section according to the design requirements.

然後,請參照圖9E,以圖案化罩幕層326為罩幕,移除自第三開口325及第六開口333露出的部分第三介電層324而在記憶胞陣列202上形成溝渠以及在週邊區203形成開口327,並繼續移除自第一開口323及第五開口331露出的部分第二介電層318而在記憶胞陣列202上形成介層窗328a以及在週邊區203形成介層窗328b,並暴露出部分終止層316。移除部分第三介電層324及部分第二介電層318的方法例如乾蝕刻製程。其中,圖9E中之記憶胞陣列202中的溝渠平行於剖面方向,如第一實施例中之圖6B所示的溝渠127。Then, referring to FIG. 9E, a patterned mask layer 326 is used as a mask to remove a portion of the third dielectric layer 324 exposed from the third opening 325 and the sixth opening 333 to form a trench on the memory cell array 202 and The peripheral region 203 forms an opening 327, and further removes a portion of the second dielectric layer 318 exposed from the first opening 323 and the fifth opening 331, forming a via 328a on the memory cell array 202 and forming a via in the peripheral region 203. Window 328b and exposes a portion of termination layer 316. A method of removing a portion of the third dielectric layer 324 and a portion of the second dielectric layer 318 is, for example, a dry etch process. The trench in the memory cell array 202 in FIG. 9E is parallel to the cross-sectional direction, such as the trench 127 shown in FIG. 6B in the first embodiment.

之後,請參照圖9F,移除露出的部分終止層316,使第一接觸窗插塞314暴露出來,此時第二接觸窗插塞315也會暴露出來。部分終止層316的移除方法包括進行乾蝕刻製程。接著,在溝渠、開口327及介層窗328a-b內形成導體層330,且導體層330與第一接觸窗插塞314及第二接觸窗插塞315相接觸,導體層330的材料與形成方法可參照上述各實施例。此外,在形成導體層330之前,還可先將圖案化罩幕層326移除,且移除方法包括進行乾式蝕刻製程。在本實施例中,在記憶胞陣列202上沿剖面方向延伸的導體層330是作為NAND快閃記憶體的位元線,而週邊區203的導體層330可作為內連線。Thereafter, referring to FIG. 9F, the exposed portion of the termination layer 316 is removed, exposing the first contact window plug 314, and the second contact window plug 315 is also exposed. The method of removing the portion of the termination layer 316 includes performing a dry etch process. Next, a conductor layer 330 is formed in the trench, the opening 327 and the via 328a-b, and the conductor layer 330 is in contact with the first contact plug 314 and the second contact plug 315, and the material and formation of the conductor layer 330 The method can be referred to the above embodiments. In addition, the patterned mask layer 326 may also be removed prior to forming the conductor layer 330, and the removal method includes performing a dry etching process. In the present embodiment, the conductor layer 330 extending in the cross-sectional direction on the memory cell array 202 is a bit line as a NAND flash memory, and the conductor layer 330 of the peripheral region 203 can serve as an interconnect.

同樣地,第三實施例是藉由自行對準雙鑲嵌製程形成位元線及與接觸窗插塞接觸的介層窗插塞,因而有效地降 低製程複雜度,及避免對準失誤。另外,第三實施例因為NAND快閃記憶體的位元線和內連線是利用一致的步驟製作,所以不會增加製程複雜度,從而節省製程成本。Similarly, the third embodiment effectively forms a bit line and a via window plug in contact with the contact window plug by self-aligning the dual damascene process. Low process complexity and avoid alignment errors. In addition, in the third embodiment, since the bit lines and the interconnect lines of the NAND flash memory are fabricated using a uniform step, the process complexity is not increased, thereby saving process cost.

圖10A到圖10D為依照本發明之第四實施例的NAND快閃記憶體的鑲嵌結構之製造流程剖面圖。其中,圖10A為接續圖9B之後所進行的步驟。此外,第四實施例和第三實施例中相同或相類似之構件可採用相同的材料或方法來進行,故於此不再贅述。10A through 10D are cross-sectional views showing a manufacturing process of a damascene structure of a NAND flash memory in accordance with a fourth embodiment of the present invention. 10A is a step performed subsequent to FIG. 9B. In addition, the same or similar components in the fourth embodiment and the third embodiment may be carried out by the same materials or methods, and thus will not be described again.

首先,請參照圖10A,在第二介電層318上形成圖案化終止層422,其具有對應第一接觸窗插塞314的至少一第一開口423,並暴露出對應第一開口423的部分第二介電層318。之後,在圖案化終止層422上以及第一開口423中形成第三介電層424。First, referring to FIG. 10A, a patterned termination layer 422 is formed on the second dielectric layer 318, which has at least one first opening 423 corresponding to the first contact window plug 314, and exposes a portion corresponding to the first opening 423. The second dielectric layer 318. Thereafter, a third dielectric layer 424 is formed on the patterned termination layer 422 and in the first opening 423.

接著,請參照圖10B,在第三介電層424上形成圖案化罩幕層426,其在記憶胞陣列202上具有對應第一開口423且沿剖面方向延伸的至少一第三開口425,以及在週邊區203有對應第二接觸窗插塞315的至少一第七開口433,並暴露出部分第三介電層424。其中,圖10B中的虛線表示圖案化罩幕層426在平行於剖面方向上的輪廓;且在貫穿頁面的方向上,與圖案化罩幕層426內的第三開口425間隔排列,如第一實施例中之圖5A及圖5C所示。另外,第七開口433不但可如圖10B所示是在貫穿頁面的方向上延伸,也可依設計需要而改為沿剖面方向延伸。Next, referring to FIG. 10B, a patterned mask layer 426 is formed on the third dielectric layer 424, and has at least one third opening 425 on the memory cell array 202 corresponding to the first opening 423 and extending in the cross-sectional direction, and At the peripheral region 203, there is at least a seventh opening 433 corresponding to the second contact window plug 315, and a portion of the third dielectric layer 424 is exposed. The dashed line in FIG. 10B indicates the contour of the patterned mask layer 426 in a direction parallel to the cross-section; and is spaced apart from the third opening 425 in the patterned mask layer 426 in the direction through the page, such as the first 5A and 5C in the embodiment. In addition, the seventh opening 433 may extend not only in the direction of the page as shown in FIG. 10B but also in the cross-sectional direction as required by the design.

然後,請參照圖10C,以圖案化罩幕層426為罩幕, 移除自第三開口425及第七開口433露出的部分第三介電層424而在記憶胞陣列202上形成溝渠以及在週邊區203形成開口427,並繼續移除自第一開口423露出的部分第二介電層318而在記憶胞陣列202上形成介層窗428,並暴露出部分終止層316。其中,圖10C中之記憶胞陣列202中的溝渠平行於剖面方向,如第一實施例中之圖6B所示的溝渠127。Then, referring to FIG. 10C, the mask layer 426 is patterned as a mask. A portion of the third dielectric layer 424 exposed from the third opening 425 and the seventh opening 433 is removed to form a trench on the memory cell array 202 and an opening 427 is formed in the peripheral region 203, and the removal from the first opening 423 is continued. A portion of the second dielectric layer 318 forms a via 428 on the memory cell array 202 and exposes a portion of the termination layer 316. The trench in the memory cell array 202 in FIG. 10C is parallel to the cross-sectional direction, such as the trench 127 shown in FIG. 6B in the first embodiment.

之後,請參照圖10D,移除露出的部分終止層316,使第一接觸窗插塞314暴露出來,此時週邊區203的第二介電層318也會暴露出來。接著,在溝渠、開口427與介層窗428內形成導體層430,且導體層430與第一接觸窗插塞314相接觸。此外,在形成導體層430之前,還可先將圖案化罩幕層426移除。在本實施例中,在記憶胞陣列202上沿剖面方向延伸的導體層430是作為NAND快閃記憶體的位元線,而週邊區203的導體層430可作為內連線。Thereafter, referring to FIG. 10D, the exposed portion of the termination layer 316 is removed to expose the first contact window plug 314, and the second dielectric layer 318 of the peripheral region 203 is also exposed. Next, a conductor layer 430 is formed in the trench, opening 427 and via 428, and the conductor layer 430 is in contact with the first contact plug 314. In addition, the patterned mask layer 426 may also be removed prior to forming the conductor layer 430. In the present embodiment, the conductor layer 430 extending in the cross-sectional direction on the memory cell array 202 is a bit line as a NAND flash memory, and the conductor layer 430 of the peripheral region 203 can serve as an interconnect.

同樣地,第四實施例是藉由自行對準雙鑲嵌製程形成位元線及與接觸窗插塞接觸的介層窗插塞,因而有效地降低製程複雜度,及避免對準失誤。另外,第四實施例因為NAND快閃記憶體的位元線和內連線是利用一致的步驟製作,所以不會增加製程複雜度,從而節省製程成本。Similarly, the fourth embodiment is to form a bit line and a via plug in contact with the contact plug by self-aligning the dual damascene process, thereby effectively reducing process complexity and avoiding alignment errors. In addition, in the fourth embodiment, since the bit lines and the interconnect lines of the NAND flash memory are fabricated using a uniform step, the process complexity is not increased, thereby saving process cost.

此外,本發明的NAND快閃記憶體之鑲嵌結構的製造方法,針對週邊區的電路設計,根據需求而可選擇性地將第二實施例、第三實施例及第四實施例結合使用。Further, in the method of fabricating the damascene structure of the NAND flash memory of the present invention, the second embodiment, the third embodiment, and the fourth embodiment can be selectively used in combination with respect to the circuit design of the peripheral region.

綜上所述,上述實施例所提出之NAND快閃記憶體之 鑲嵌結構的製造方法採用自行對準雙鑲嵌製程,以一步驟形成溝渠及介層窗,從而形成位元線及與接觸窗插塞接觸的介層窗插塞,因此有效地降低製程步驟複雜度,及避免對準失誤。另外,上述實施例所提出之NAND快閃記憶體之鑲嵌結構的製造方法可利用一致的步驟製作出NAND快閃記憶體的位元線和內連線,從而降低製程步驟複雜度及製程成本,並可藉由增加週邊區之內連線的深度,而降低其阻值。In summary, the NAND flash memory proposed by the above embodiments The manufacturing method of the damascene structure adopts a self-aligned dual damascene process to form a trench and a via window in one step, thereby forming a bit line and a via window plug in contact with the contact window plug, thereby effectively reducing the complexity of the process step And avoid misalignment. In addition, the manufacturing method of the NAND flash memory mosaic structure proposed in the above embodiment can use the consistent steps to create the bit line and the interconnect line of the NAND flash memory, thereby reducing the complexity of the process steps and the process cost. The resistance can be lowered by increasing the depth of the wiring within the peripheral area.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,故本發明之保護範圍當視後附之申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the invention, and any one of ordinary skill in the art can make some modifications and refinements without departing from the spirit and scope of the invention. The scope of the invention is defined by the scope of the appended claims.

100、200‧‧‧基底100, 200‧‧‧ base

102、202‧‧‧記憶胞陣列102, 202‧‧‧ memory cell array

104、204‧‧‧NAND串104, 204‧‧‧NAND strings

106、206‧‧‧字元線106, 206‧‧ ‧ character line

107、207‧‧‧浮置閘極107, 207‧‧‧ Floating Gate

108、208‧‧‧選擇電晶體108, 208‧‧‧Selecting a crystal

109、209‧‧‧閘間介電層109, 209‧‧‧ Inter-gate dielectric layer

110、210‧‧‧閘極氧化層110, 210‧‧ ‧ gate oxide layer

111、211‧‧‧間隙壁111, 211‧‧ ‧ spacer

112、212‧‧‧第一介電層112, 212‧‧‧ first dielectric layer

114、214、314、315‧‧‧接觸窗插塞114, 214, 314, 315‧ ‧ contact window plug

116、216、316‧‧‧終止層116, 216, 316‧‧‧ termination layer

118、218、318‧‧‧第二介電層118, 218, 318‧‧‧ second dielectric layer

122、222、322、422‧‧‧圖案化終止層122, 222, 322, 422‧‧‧ patterned termination layer

123、125、223、225、231、233、227、323、325、331、333、327、423、425、433、427‧‧‧開口123, 125, 223, 225, 231, 233, 227, 323, 325, 331, 333, 327, 423, 425, 433, 427‧‧

124、224、324、424‧‧‧第三介電層124, 224, 324, 424‧‧‧ third dielectric layer

126、226、326、426‧‧‧圖案化罩幕層126, 226, 326, 426‧‧‧ patterned mask layer

127‧‧‧溝渠127‧‧‧ Ditch

128、228a、228b、328a、328b、428‧‧‧介層窗128, 228a, 228b, 328a, 328b, 428‧‧

130、230、330、430‧‧‧導體層130, 230, 330, 430‧‧‧ conductor layers

203‧‧‧週邊區203‧‧‧The surrounding area

205‧‧‧電晶體205‧‧‧Optoelectronics

205a‧‧‧閘極205a‧‧‧ gate

205b‧‧‧閘介電層205b‧‧‧gate dielectric layer

圖1到圖7C為依照本發明之第一實施例的NAND快閃記憶體的鑲嵌結構之製造流程圖。1 to 7C are flowcharts showing the manufacture of a damascene structure of a NAND flash memory in accordance with a first embodiment of the present invention.

圖8A到圖8G為依照本發明之第二實施例的NAND快閃記憶體的鑲嵌結構之製造流程剖面圖。8A to 8G are cross-sectional views showing a manufacturing process of a damascene structure of a NAND flash memory in accordance with a second embodiment of the present invention.

圖9A到圖9F為依照本發明之第三實施例的NAND快閃記憶體的鑲嵌結構之製造流程剖面圖。9A to 9F are cross-sectional views showing a manufacturing process of a damascene structure of a NAND flash memory in accordance with a third embodiment of the present invention.

圖10A到圖10D為依照本發明之第四實施例的NAND快閃記憶體的鑲嵌結構之製造流程剖面圖。10A through 10D are cross-sectional views showing a manufacturing process of a damascene structure of a NAND flash memory in accordance with a fourth embodiment of the present invention.

100‧‧‧基底100‧‧‧Base

106‧‧‧字元線106‧‧‧ character line

107‧‧‧浮置閘極107‧‧‧Floating gate

108‧‧‧選擇電晶體108‧‧‧Selecting a crystal

109‧‧‧閘間介電層109‧‧‧Interruptor dielectric layer

110‧‧‧閘極氧化層110‧‧‧ gate oxide layer

111‧‧‧間隙壁111‧‧‧ spacer

112‧‧‧第一介電層112‧‧‧First dielectric layer

114‧‧‧接觸窗插塞114‧‧‧Contact window plug

116‧‧‧終止層116‧‧‧End layer

118‧‧‧第二介電層118‧‧‧Second dielectric layer

122‧‧‧圖案化終止層122‧‧‧patterned termination layer

123‧‧‧開口123‧‧‧ openings

127‧‧‧溝渠127‧‧‧ Ditch

128‧‧‧介層窗128‧‧・Intermediate window

130‧‧‧導體層130‧‧‧Conductor layer

Claims (19)

一種NAND快閃記憶體之鑲嵌結構的製造方法,包括:提供一基底,具有一記憶胞陣列,該記憶胞陣列包括沿一方向配置的多個NAND串,其中在該方向上,各該NAND串包括多個字元線及位於該些字元線下方的多個浮置閘極,以及位在該些字元線之兩端的兩個選擇電晶體;於該基底上形成一第一介電層,該第一介電層覆蓋該記憶胞陣列;於鄰近的該些NAND串之間形成接觸該基板的至少一接觸窗插塞;於該第一介電層及該接觸窗插塞上形成一終止層;於該終止層上形成一第二介電層;於該第二介電層上形成一圖案化終止層,該圖案化終止層具有對應該接觸窗插塞的至少一第一開口並露出該第二介電層;於該圖案化終止層上及該第一開口中形成一第三介電層;於該第三介電層上形成一圖案化罩幕層,具有對應該第一開口的至少一第二開口,該第二開口沿該方向延伸並露出該第三介電層;以該圖案化罩幕層為罩幕,移除自該第二開口露出的該第三介電層而形成一溝渠,並繼續移除自該第一開口露出的該第二介電層而形成一介層窗並露出該終止層; 移除露出的該終止層,使該接觸窗插塞暴露出來;以及在該溝渠及該介層窗內形成一導體層,該導體層與該接觸窗插塞接觸。A method of fabricating a damascene flash memory mosaic structure, comprising: providing a substrate having a memory cell array, the memory cell array including a plurality of NAND strings arranged in a direction, wherein the NAND strings are in the direction a plurality of word lines and a plurality of floating gates under the word lines, and two selection transistors positioned at opposite ends of the word lines; forming a first dielectric layer on the substrate The first dielectric layer covers the memory cell array; at least one contact window plug is formed between the adjacent NAND strings to contact the substrate; and a first dielectric layer and the contact window plug are formed on the first dielectric layer Forming a second dielectric layer on the termination layer; forming a patterned termination layer on the second dielectric layer, the patterned termination layer having at least one first opening corresponding to the window plug and Exposing the second dielectric layer; forming a third dielectric layer on the patterned termination layer and the first opening; forming a patterned mask layer on the third dielectric layer, corresponding to the first At least one second opening of the opening, the second opening extending along the direction Stretching and exposing the third dielectric layer; using the patterned mask layer as a mask, removing the third dielectric layer exposed from the second opening to form a trench, and continuing to remove from the first opening Exposing the second dielectric layer to form a via and exposing the termination layer; Removing the exposed termination layer to expose the contact plug; and forming a conductor layer in the trench and the via, the conductor layer being in contact with the contact plug. 如申請專利範圍第1項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中該第一介電層、該第二介電層及該第三介電層包括氧化矽層。The method of fabricating a damascene structure of a NAND flash memory according to claim 1, wherein the first dielectric layer, the second dielectric layer, and the third dielectric layer comprise a ruthenium oxide layer. 如申請專利範圍第1項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中該終止層及該圖案化終止層的材料包括氮化矽。The manufacturing method of the damascene structure of the NAND flash memory according to claim 1, wherein the material of the termination layer and the patterned termination layer comprises tantalum nitride. 如申請專利範圍第1項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中形成該導體層之步驟包括填滿該介層窗而形成一介層窗插塞,並填滿該溝渠而形成一位元線。The method for fabricating a damascene flash memory in accordance with claim 1, wherein the step of forming the conductor layer comprises filling the via to form a via plug and filling the trench. Form a single line. 如申請專利範圍第1項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中形成該導體層之步驟前更包括移除該圖案化罩幕層。The manufacturing method of the damascene structure of the NAND flash memory according to claim 1, wherein the step of forming the conductor layer further comprises removing the patterned mask layer. 如申請專利範圍第1項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中在形成該第一介電層之前,更包括至少在各該選擇電晶體的側壁上形成一間隙壁。The manufacturing method of the damascene structure of the NAND flash memory according to claim 1, wherein before forming the first dielectric layer, further comprising forming a spacer on at least a sidewall of each of the selection transistors. 如申請專利範圍第6項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中該間隙壁包括氧化矽層。The manufacturing method of the damascene structure of the NAND flash memory according to claim 6, wherein the spacer comprises a ruthenium oxide layer. 一種NAND快閃記憶體之鑲嵌結構的製造方法,包括: 提供一基底,具有一記憶胞陣列及一週邊區,其中該週邊區包括至少一電晶體,該記憶胞陣列包括沿一方向配置的多個NAND串,而在該方向上,各該NAND串包括多個字元線及位於該些字元線下方的多個浮置閘極,以及位在該些字元線之兩端的兩個選擇電晶體;於該基底上形成一第一介電層,該第一介電層覆蓋該記憶胞陣列及該週邊區的該電晶體;於鄰近的該些NAND串之間形成接觸該基板的至少一第一接觸窗插塞;於該第一介電層及該第一接觸窗插塞上形成一終止層;於該終止層上形成一第二介電層;於該第二介電層上形成一圖案化終止層,該圖案化終止層具有對應該第一接觸窗插塞的至少一第一開口與位於該週邊區的至少一第二開口,並露出該第二介電層;於該圖案化終止層上以及該第一開口及該第二開口中形成一第三介電層;於該第三介電層上形成一圖案化罩幕層,其中具有對應該第一開口且沿該方向延伸的至少一第三開口,以及對應該第二開口的至少一第四開口,並露出該第三介電層;以該圖案化罩幕層為罩幕,移除自該第三開口與該第四開口露出的該第三介電層而形成一溝渠,並繼續移除自該第一開口及該第二開口露出的該第二介電層而形成一介層窗並露出該終止層; 移除露出的該終止層,使該第一接觸窗插塞暴露出來且暴露該週邊區的該第一介電層;以及在該溝渠與該介層窗內形成一導體層,該導體層與該第一接觸窗插塞接觸。A method for manufacturing a mosaic structure of a NAND flash memory, comprising: Providing a substrate having a memory cell array and a peripheral region, wherein the peripheral region includes at least one transistor, the memory cell array including a plurality of NAND strings arranged in one direction, and in the direction, each of the NAND strings includes a plurality of word lines and a plurality of floating gates under the word lines, and two selection transistors positioned at opposite ends of the word lines; forming a first dielectric layer on the substrate The first dielectric layer covers the memory cell array and the transistor of the peripheral region; forming at least one first contact window plug contacting the substrate between the adjacent NAND strings; and the first dielectric layer Forming a termination layer on the first contact window plug; forming a second dielectric layer on the termination layer; forming a patterned termination layer on the second dielectric layer, the patterned termination layer having corresponding At least one first opening of the first contact window plug and at least one second opening in the peripheral region, and exposing the second dielectric layer; on the patterned termination layer and the first opening and the second opening Forming a third dielectric layer; forming on the third dielectric layer a patterned mask layer having at least one third opening corresponding to the first opening and extending in the direction, and at least a fourth opening corresponding to the second opening, and exposing the third dielectric layer; The mask layer is a mask, the third dielectric layer exposed from the third opening and the fourth opening is removed to form a trench, and the removal of the first opening and the second opening is further removed. Forming a via window and exposing the termination layer; Removing the exposed termination layer, exposing the first contact window plug and exposing the first dielectric layer of the peripheral region; and forming a conductor layer in the trench and the via, the conductor layer The first contact window plug contacts. 如申請專利範圍第8項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中形成該圖案化終止層的步驟包括使該第二開口對應於該週邊區的該電晶體上。The method of fabricating a damascene structure of a NAND flash memory according to claim 8 wherein the step of forming the patterned stop layer comprises causing the second opening to correspond to the transistor of the peripheral region. 如申請專利範圍第8項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中形成該第一接觸窗插塞的步驟包括於該週邊區中的該電晶體的至少一側形成接觸該基板的至少一第二接觸窗插塞。The method of fabricating a damascene flash memory in accordance with claim 8 wherein the step of forming the first contact plug comprises forming contact with at least one side of the transistor in the peripheral region. At least one second contact window plug of the substrate. 如申請專利範圍第10項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中形成該圖案化終止層的步驟包括使該圖案化終止層在該週邊區中具有對應該第二接觸窗插塞的至少一第五開口。The method of fabricating a damascene structure of a NAND flash memory according to claim 10, wherein the step of forming the patterned termination layer comprises causing the patterned termination layer to have a second contact window in the peripheral region. At least one fifth opening of the plug. 如申請專利範圍第11項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中形成該圖案化罩幕層的步驟包括使該圖案化罩幕層在該週邊區中具有對應該第五開口的至少一第六開口。The method for manufacturing a damascene flash memory inlaid structure according to claim 11, wherein the step of forming the patterned mask layer comprises causing the patterned mask layer to have a fifth in the peripheral region. At least one sixth opening of the opening. 如申請專利範圍第10項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中形成該圖案化罩幕層的步驟包括使該圖案化罩幕層在該週邊區中具有對應該第二接觸窗插塞的至少一第七開口。The method of manufacturing a damascene flash memory inlaid structure according to claim 10, wherein the step of forming the patterned mask layer comprises causing the patterned mask layer to have a second portion in the peripheral region. Contacting at least a seventh opening of the window plug. 如申請專利範圍第13項所述之NAND快閃記憶 體之鑲嵌結構的製造方法,其中以該圖案化罩幕層為罩幕,移除自該第七開口露出的該第三介電層而形成一溝渠。NAND flash memory as described in claim 13 The manufacturing method of the mosaic structure of the body, wherein the patterned mask layer is used as a mask, and the third dielectric layer exposed from the seventh opening is removed to form a trench. 如申請專利範圍第8項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中該第一介電層、該第二介電層及該第三介電層包括氧化矽層。The method for fabricating a damascene structure of a NAND flash memory according to claim 8, wherein the first dielectric layer, the second dielectric layer, and the third dielectric layer comprise a ruthenium oxide layer. 如申請專利範圍第8項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中該終止層及該圖案化終止層的材料包括氮化矽。The manufacturing method of the damascene structure of the NAND flash memory according to claim 8, wherein the material of the termination layer and the patterned termination layer comprises tantalum nitride. 如申請專利範圍第8項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中形成該導體層之步驟前更包括移除該圖案化罩幕層。The manufacturing method of the damascene structure of the NAND flash memory according to claim 8, wherein the step of forming the conductor layer further comprises removing the patterned mask layer. 如申請專利範圍第8項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中在形成該第一介電層之前,更包括至少在各該選擇電晶體及該電晶體的側壁上形成一間隙壁。The method for fabricating a damascene structure of a NAND flash memory according to claim 8, wherein before forming the first dielectric layer, further comprising forming at least on each of the selected transistors and sidewalls of the transistor a gap wall. 如申請專利範圍第18項所述之NAND快閃記憶體之鑲嵌結構的製造方法,其中該間隙壁包括氧化矽層。The manufacturing method of the damascene structure of the NAND flash memory according to claim 18, wherein the spacer comprises a ruthenium oxide layer.
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