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TWI452007B - Nano carbon tube membrane bearing structure and using method thereof - Google Patents

Nano carbon tube membrane bearing structure and using method thereof Download PDF

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TWI452007B
TWI452007B TW099137721A TW99137721A TWI452007B TW I452007 B TWI452007 B TW I452007B TW 099137721 A TW099137721 A TW 099137721A TW 99137721 A TW99137721 A TW 99137721A TW I452007 B TWI452007 B TW I452007B
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carbon nanotube
nanotube film
bearing
carbon
bearing structure
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TW099137721A
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TW201219294A (en
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Chen Feng
yu-quan Wang
Liang Liu
Li Qian
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Beijing Funate Innovation Tech
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奈米碳管膜承載結構及其使用方法 Nano carbon tube membrane bearing structure and using method thereof

本發明涉及一種奈米碳管膜承載結構及其使用方法。 The invention relates to a carbon nanotube membrane bearing structure and a method of using same.

奈米碳管係一種由石墨烯片卷成的中空管狀物,其具有優異的力學、熱學及電學性質。奈米碳管應用領域非常廣闊,例如,它可用於製作場效應電晶體、原子力顯微鏡針尖、場發射電子槍、奈米模板等等。惟,目前基本上都係在微觀尺度下應用奈米碳管,操作較困難。所以,將奈米碳管組裝成宏觀尺度的結構對於奈米碳管的宏觀應用具有重要意義。 The carbon nanotube is a hollow tube rolled from a graphene sheet, which has excellent mechanical, thermal and electrical properties. Nano carbon nanotubes are used in a wide range of applications, for example, in the production of field effect transistors, atomic force microscope tips, field emission electron guns, nano templates, and the like. However, at present, the application of carbon nanotubes at the microscopic scale is basically difficult. Therefore, the assembly of nano-carbon tubes into a macro-scale structure is of great significance for the macroscopic application of carbon nanotubes.

先前的奈米碳管宏觀結構主要有奈米碳管膜,惟,奈米碳管膜等奈米碳管宏觀結構的比表面積很大,宏觀上表現出很強的黏性,一旦接觸到其他物體便會黏住並且很難分開,所以給保存和轉移奈米碳管宏觀結構帶來較大的困難,從而大大限制了奈米碳管膜等奈米碳管結構在宏觀領域的進一步應用。 The macrostructure of the previous carbon nanotubes mainly consists of carbon nanotube membranes. However, the macrostructures of nanocarbon tubes such as carbon nanotube membranes have large specific surface area and macroscopically exhibit strong viscosity. Once exposed to other The objects will stick and be difficult to separate, so it will bring great difficulties in preserving and transferring the macrostructure of the carbon nanotubes, thus greatly limiting the further application of the carbon nanotube structure such as the carbon nanotube film in the macroscopic field.

有鑒於此,提供一種奈米碳管膜承載結構及其使用方法實為必要。 In view of this, it is necessary to provide a carbon nanotube film bearing structure and a method of using the same.

一種奈米碳管膜承載結構,該奈米碳管膜承載結構用於承載一奈米碳管膜狀結構,且該奈米碳管膜狀結構與該承載結構接觸後可完整地從該承載結構脫離,其中,該奈米碳管膜承載結構包括一本體,所述本體具有一表面,所述本體的表面具有一奈米碳管膜承載區域,該奈米碳管膜承載區域具有複數個凹陷結構,所述複數個凹陷結構的總凹陷面積大於等於所述奈米碳管膜承載區域面積的80%,從而使所述奈米碳管膜狀結構設置於所述奈米碳管膜承載區域時,所述奈米碳管膜狀結構與所述本體的有效接觸面積小於等於所述奈米碳管膜狀結構本身面積的20%。 A carbon nanotube film bearing structure for carrying a carbon nanotube film structure, and the carbon nanotube film structure can be completely intact from the bearing after contacting the bearing structure The structure is detached, wherein the carbon nanotube film bearing structure comprises a body, the body has a surface, the surface of the body has a carbon nanotube film bearing region, and the carbon nanotube film bearing region has a plurality of a recessed structure, wherein a total recessed area of the plurality of recessed structures is greater than or equal to 80% of an area of the carbon nanotube film bearing area, so that the carbon nanotube film structure is disposed on the carbon nanotube film bearing In the region, the effective contact area of the carbon nanotube film structure with the body is less than or equal to 20% of the area of the carbon nanotube film structure itself.

一種奈米碳管膜承載結構的使用方法,包括以下步驟:提供至少一奈米碳管膜承載結構,所述奈米碳管膜承載結構包括一本體,所述本體具有一表面,該表面具有一奈米碳管膜承載區域,該奈米碳管膜承載區域具有複數個凹陷結構,所述複數個凹陷結構的總凹陷面積大於等於所述奈米碳管膜承載區域的面積的80%;提供一奈米碳管膜狀結構;以及將所述奈米碳管膜狀結構直接設置於所述奈米碳管膜承載結構的奈米碳管膜承載區域,所述奈米碳管膜狀結構與所述奈米碳管膜承載結構的有效接觸面積小於等於所述奈米碳管膜狀結構本身面積的20%。 A method of using a carbon nanotube film carrying structure, comprising the steps of: providing at least one carbon nanotube film bearing structure, the carbon nanotube film bearing structure comprising a body, the body having a surface having a carbon nanotube film bearing region, the carbon nanotube film bearing region has a plurality of recessed structures, and a total recessed area of the plurality of recessed structures is greater than or equal to 80% of an area of the carbon nanotube film bearing region; Providing a carbon nanotube film structure; and placing the carbon nanotube film structure directly on the carbon nanotube film bearing region of the carbon nanotube film bearing structure, the carbon nanotube film The effective contact area of the structure with the carbon nanotube film support structure is less than or equal to 20% of the area of the carbon nanotube film structure itself.

相較先前技術,所述奈米碳管膜承載結構具有結構簡單等特點,該奈米碳管膜承載結構通過在一本體的表面設置複數個凹陷結構,使得將一奈米碳管膜狀結構設置於所述奈米碳管膜承載結構表面時,該奈米碳管膜狀結構的大部分結構通過所述凹陷結構懸空設置,從而大大地減少了所述奈米碳管膜狀結構與所述奈米碳管 膜承載結構的有效接觸面積,進而降低了所述奈米碳管膜狀結構與所述奈米碳管膜承載結構之間的凡得瓦力,最後實現奈米碳管膜狀結構的保存和轉移。 Compared with the prior art, the carbon nanotube film bearing structure has the characteristics of simple structure, and the carbon nanotube film bearing structure has a plurality of concave structures on the surface of a body, so that a carbon nanotube film structure is adopted. When disposed on the surface of the carbon nanotube film bearing structure, most of the structure of the carbon nanotube film structure is suspended by the concave structure, thereby greatly reducing the film structure and the structure of the carbon nanotube film. Carbon nanotube The effective contact area of the membrane-bearing structure further reduces the van der Waals force between the membrane structure of the carbon nanotube and the carbon nanotube membrane-bearing structure, and finally realizes the preservation of the membrane structure of the carbon nanotube Transfer.

所述奈米碳管膜承載結構的使用方法,通過將一奈米碳管膜直接承載於一奈米碳管膜承載結構的奈米碳管膜承載區域,從而實現奈米碳管膜狀結構的保存和轉移,該方法簡單易行。 The method for using the carbon nanotube film-bearing structure realizes a carbon nanotube film structure by directly carrying a carbon nanotube film on a carbon nanotube film bearing region of a carbon nanotube film bearing structure The method of saving and transferring is simple and easy.

100;200‧‧‧奈米碳管膜承載結構 100;200‧‧‧Nano carbon nanotube membrane bearing structure

110;210‧‧‧本體 110; 210‧‧‧ ontology

112;212‧‧‧表面 112; 212‧‧‧ surface

114;214‧‧‧奈米碳管膜承載區域 114;214‧‧‧Nano carbon nanotube film bearing area

116;216‧‧‧凹陷結構 116;216‧‧‧ recessed structure

120‧‧‧奈米碳管膜狀結構 120‧‧‧Nano carbon tube membrane structure

圖1 為本發明第一實施例所提供的奈米碳管膜承載結構的示意圖。 1 is a schematic view of a carbon nanotube film bearing structure provided by a first embodiment of the present invention.

圖2 為本發明第二實施例所提供的奈米碳管膜承載結構的示意圖。 2 is a schematic view of a carbon nanotube film bearing structure provided by a second embodiment of the present invention.

圖3 為應用本發明實施例提供的奈米碳管膜承載結構承載奈米碳管膜狀結構的流程圖。 FIG. 3 is a flow chart of a nano carbon tube film bearing structure for carrying a carbon nanotube film structure according to an embodiment of the present invention.

圖4 為應用本發明實施例提供的奈米碳管膜承載結構承載的奈米碳管拉膜的SEM照片。 4 is a SEM photograph of a carbon nanotube film carried by a carbon nanotube film carrying structure provided by an embodiment of the present invention.

圖5 為應用本發明實施例提供的奈米碳管膜承載結構承載的奈米碳管碾壓膜的SEM照片。 FIG. 5 is a SEM photograph of a carbon nanotube rolled film carried by a carbon nanotube film carrying structure provided by an embodiment of the present invention.

圖6 為應用本發明實施提供的奈米碳管膜承載結構承載的奈米碳管絮化膜的SEM照片。 Figure 6 is a SEM photograph of a carbon nanotube flocculation membrane supported by a carbon nanotube membrane support structure provided by the practice of the present invention.

圖7 為應用本發明實施例提供的奈米碳管膜承載結構承載一奈米碳管膜狀結構的示意圖。 FIG. 7 is a schematic view showing the application of a carbon nanotube film supporting structure according to an embodiment of the present invention to a film structure of a carbon nanotube.

下面將結合附圖及具體實施例,對本發明作進一步的詳細說明。 The invention will be further described in detail below with reference to the drawings and specific embodiments.

請參閱圖1,本發明第一實施例提供一種奈米碳管膜承載結構100,該奈米碳管膜承載結構100用於承載或保護一奈米碳管膜狀結構,且該奈米碳管膜狀結構與所述奈米碳管膜承載結構100接觸後可完整地從所述奈米碳管膜承載結構100剝離。該奈米碳管膜承載結構100包括:一本體110,其中,所述本體110具有一表面112,該表面112上設置有一奈米碳管膜承載區域114。該奈米碳管膜承載區域114用於承載一奈米碳管膜狀結構。該奈米碳管膜承載區域114具有複數個凹陷結構116。該複數個凹陷結構116的總凹陷面積大於等於所述奈米碳管膜承載區域114的面積的80%,從而使得將一奈米碳管膜狀結構設置於所述奈米碳管膜承載區域114時,該奈米碳管膜狀結構與所述本體110的有效接觸面積小於所述奈米碳管膜狀結構本身面積的20%,使該奈米碳管膜狀結構可以完整地從該本體110的表面112剝離。優選的,該複數個凹陷結構116的總凹陷面積大於等於所述奈米碳管膜承載區域114的面積的90%,從而使得將一奈米碳管膜狀結構設置於所述奈米碳管膜承載區域114時,該奈米碳管膜狀結構與所述本體110的有效接觸面積小於所述奈米碳管膜狀結構本身面積的10%。 Referring to FIG. 1 , a first embodiment of the present invention provides a carbon nanotube film bearing structure 100 for carrying or protecting a carbon nanotube film structure, and the nano carbon After the tubular film structure is in contact with the carbon nanotube film support structure 100, it can be completely peeled off from the carbon nanotube film bearing structure 100. The carbon nanotube film bearing structure 100 includes a body 110, wherein the body 110 has a surface 112 on which a carbon nanotube film bearing region 114 is disposed. The carbon nanotube film bearing region 114 is used to carry a carbon nanotube film structure. The carbon nanotube film bearing region 114 has a plurality of recessed structures 116. The total recessed area of the plurality of recessed structures 116 is greater than or equal to 80% of the area of the carbon nanotube film bearing area 114, so that a carbon nanotube film structure is disposed in the carbon nanotube film bearing area. At 114 o'clock, the effective contact area of the carbon nanotube film structure with the body 110 is less than 20% of the area of the carbon nanotube film structure itself, so that the carbon nanotube film structure can be completely from the The surface 112 of the body 110 is peeled off. Preferably, the total recessed area of the plurality of recessed structures 116 is greater than or equal to 90% of the area of the carbon nanotube film bearing region 114, so that a carbon nanotube film structure is disposed on the carbon nanotubes. When the film carries the region 114, the effective contact area of the carbon nanotube film structure with the body 110 is less than 10% of the area of the carbon nanotube film structure itself.

所述本體110為具有一定強度的薄片狀結構,其形狀、尺寸可依據實際需求設計。該本體110的材料可選自硬性或具有一定強度的柔性材料。具體地,該本體110的材料選自金屬、金屬氧化物、陶瓷、樹脂等材料。所述本體110的表面112可以為平面、曲面 或其他不規則面等。 The body 110 is a sheet-like structure having a certain strength, and its shape and size can be designed according to actual needs. The material of the body 110 can be selected from a flexible material having a strong or a certain strength. Specifically, the material of the body 110 is selected from the group consisting of metals, metal oxides, ceramics, resins, and the like. The surface 112 of the body 110 may be a flat surface or a curved surface Or other irregular faces.

所述奈米碳管膜承載區域114可以為本體110的整個表面112或者部分表面112。所述奈米碳管膜承載區域114包括複數個相互間隔設置的凹陷結構116。該凹陷結構116可以通過化學方法或物理方法形成於所述本體110的表面112。該複數個凹陷結構116可以為微孔、凹槽或微孔與凹槽的組合等結構。所述微孔可以為通孔或盲孔,該微孔的橫截面的形狀不限於圓型,亦可以為方形、矩形、橢圓形等其他規則或不規則的幾何形狀。所述凹槽可為長條形或其他形狀。優選地,所述本體110的表面112形成有複數個均勻分佈且間隔設置的微孔,該微孔的直徑可以為100微米~1毫米,相鄰的微孔之間的間距為10微米~100微米,該微孔的深度為1微米~1毫米。可以理解,所述微孔亦可以採用其他不同結構的組合。只需滿足所述微孔的直徑和間距的比值大於等於5:1,且所述微孔的間距小於等於100微米,使得所述複數個凹陷結構116的總凹陷面積大於等於所述奈米碳管膜承載區域114的面積的80%,從而使得將一奈米碳管膜狀結構設置於所述奈米碳管膜承載區域114時,該奈米碳管膜狀結構與所述奈米碳管膜承載區域114的有效接觸面積小於所述奈米碳管膜狀結構120本身面積的20%。優選的,所述微孔的直徑和間距的比值大於等於10:1,且所述微孔的間距小於等於100微米,使得所述複數個凹陷結構116的總凹陷面積大於等於所述奈米碳管膜承載區域114的面積的90%,從而使得將一奈米碳管膜狀結構設置於所述奈米碳管膜承載區域114時,該奈米碳管膜狀結構與所述奈米碳管膜承載區域114的有效接 觸面積小於所述奈米碳管膜狀結構120本身面積的10%。 The carbon nanotube film bearing region 114 may be the entire surface 112 or a portion of the surface 112 of the body 110. The carbon nanotube film bearing region 114 includes a plurality of recessed structures 116 that are spaced apart from one another. The recessed structure 116 can be formed on the surface 112 of the body 110 by chemical or physical methods. The plurality of recessed structures 116 may be micropores, grooves or a combination of micropores and grooves. The micropores may be through holes or blind holes, and the shape of the cross section of the micro holes is not limited to a circular shape, and may be other regular or irregular geometric shapes such as a square, a rectangle, an ellipse or the like. The groove may be elongated or otherwise shaped. Preferably, the surface 112 of the body 110 is formed with a plurality of uniformly distributed and spaced micropores, the micropores may have a diameter of 100 micrometers to 1 millimeter, and the spacing between adjacent microholes is 10 micrometers to 100 millimeters. In micrometers, the micropores have a depth of 1 micrometer to 1 millimeter. It can be understood that the micropores can also adopt a combination of other different structures. It is only required that the ratio of the diameter and the pitch of the micropores is greater than or equal to 5:1, and the pitch of the micropores is less than or equal to 100 micrometers, so that the total recessed area of the plurality of recessed structures 116 is greater than or equal to the nanocarbon. 80% of the area of the tubular membrane bearing region 114, such that when a carbon nanotube membrane structure is disposed in the carbon nanotube membrane bearing region 114, the carbon nanotube membrane structure and the nanocarbon The effective contact area of the tubular membrane bearing region 114 is less than 20% of the area of the carbon nanotube membrane structure 120 itself. Preferably, the ratio of the diameter and the pitch of the micropores is greater than or equal to 10:1, and the pitch of the micropores is less than or equal to 100 micrometers, such that the total recessed area of the plurality of recessed structures 116 is greater than or equal to the nanocarbon. 90% of the area of the tubular membrane bearing region 114, such that when a carbon nanotube membrane structure is disposed in the carbon nanotube membrane bearing region 114, the carbon nanotube membrane structure and the nanocarbon Effective connection of the membrane bearing area 114 The contact area is less than 10% of the area of the carbon nanotube film structure 120 itself.

本實施例中,所述本體110為一邊長為10cm的方形陽極氧化鋁薄片。該陽極氧化鋁薄片為通過陽極氧化法製備得到。該陽極氧化鋁薄片具有複數個均勻分佈的微孔,相鄰的微孔之間的距離約為50微米。所述微孔的直徑約為500微米。 In this embodiment, the body 110 is a square anodized aluminum foil having a side length of 10 cm. The anodized aluminum flakes were prepared by anodization. The anodized aluminum foil has a plurality of uniformly distributed micropores with a distance between adjacent micropores of about 50 microns. The micropores have a diameter of about 500 microns.

請參閱圖2,本發明第二實施例提供一種奈米碳管膜承載結構200,該奈米碳管膜承載結構200用於承載或保護一奈米碳管膜狀結構,且該奈米碳管膜狀結構與所述奈米碳管膜承載結構200接觸後可完整地從該奈米碳管膜承載結構200剝離。所述奈米碳管膜承載結構200包括:一本體210,其中,所述本體210具有一表面212,該表面212上設置有一奈米碳管膜承載區域214。該奈米碳管膜承載區域214用於承載一奈米碳管膜狀結構。該奈米碳管膜承載區域214具有複數個凹陷結構216。該複數個凹陷結構216的總凹陷面積大於等於所述奈米碳管膜承載區域214的面積的80%,從而使得將一奈米碳管膜狀結構設置於所述奈米碳管膜承載區域214時,該奈米碳管膜狀結構與所述本體210的有效接觸面積小於所述奈米碳管膜狀結構本身面積的20%,該奈米碳管膜狀結構可以完整地從該本體210的表面212剝離。優選的,該複數個凹陷結構216的總凹陷面積大於等於所述奈米碳管膜承載區域214的面積的90%,從而使得將一奈米碳管膜狀結構設置於所述奈米碳管膜承載區域214時,該奈米碳管膜狀結構與所述本體210的有效接觸面積小於所述奈米碳管膜狀結構本身面積的10%。 Referring to FIG. 2, a second embodiment of the present invention provides a carbon nanotube film bearing structure 200 for carrying or protecting a carbon nanotube film structure, and the nano carbon After the tubular membrane structure is in contact with the carbon nanotube membrane support structure 200, it can be completely peeled off from the carbon nanotube membrane support structure 200. The carbon nanotube film carrying structure 200 includes a body 210, wherein the body 210 has a surface 212 on which a carbon nanotube film bearing region 214 is disposed. The carbon nanotube film bearing region 214 is used to carry a carbon nanotube film structure. The carbon nanotube film bearing region 214 has a plurality of recessed structures 216. The total recessed area of the plurality of recessed structures 216 is greater than or equal to 80% of the area of the carbon nanotube film bearing region 214, so that a carbon nanotube film structure is disposed on the carbon nanotube film bearing region. At 214 hours, the effective contact area of the carbon nanotube film structure with the body 210 is less than 20% of the area of the carbon nanotube film structure itself, and the carbon nanotube film structure can be completely from the body The surface 212 of 210 is peeled off. Preferably, the total recessed area of the plurality of recessed structures 216 is greater than or equal to 90% of the area of the carbon nanotube film bearing region 214, so that a carbon nanotube film structure is disposed on the carbon nanotubes. In the membrane bearing region 214, the effective contact area of the carbon nanotube film structure with the body 210 is less than 10% of the area of the carbon nanotube film structure itself.

本實施例中,所述本體210為具有一定強度的陶瓷薄片。所述奈 米碳管膜承載區域214為所述陶瓷薄片的部分表面。所述奈米碳管膜承載區域214包括複數個凹槽216。該複數個凹槽216均勻分佈且相互平行間隔設置。該凹槽216可以通過化學方法或物理方法形成於所述本體210的表面212。該凹槽216的寬度可以為100微米~1毫米,相鄰的凹槽216之間的間距為10微米~100微米。所述凹槽216的深度為1微米~1毫米。可以理解,形成在所述本體210的表面212的複數個凹槽216亦可以採用其他不同結構的組合。只需滿足所述凹槽216的寬度和間距的比值大於等於5:1,且所述凹槽216的間距小於等於100微米,使得所述複數個凹槽216的總凹陷面積大於等於所述奈米碳管膜承載區域214的面積的80%,從而使得將一奈米碳管膜狀結構設置於所述奈米碳管膜承載區域214時,該奈米碳管膜狀結構與所述奈米碳管膜承載區域214的有效接觸面積小於所述奈米碳管膜狀結構本身面積的20%。優選的,所述凹槽的寬度和間距的比值大於等於10:1,且所述凹槽的間距小於等於100微米,使得所述複數個凹槽116的總凹陷面積大於等於所述奈米碳管膜承載區域214的面積的90%,從而使得將一奈米碳管膜狀結構設置於所述奈米碳管膜承載區域214時,該奈米碳管膜狀結構與所述奈米碳管膜承載區域214的有效接觸面積小於所述奈米碳管膜狀結構本身面積的10%。 In this embodiment, the body 210 is a ceramic sheet having a certain strength. The nai The carbon nanotube film bearing region 214 is a partial surface of the ceramic sheet. The carbon nanotube film bearing region 214 includes a plurality of grooves 216. The plurality of grooves 216 are evenly distributed and spaced apart from each other. The groove 216 can be formed on the surface 212 of the body 210 by chemical or physical means. The groove 216 may have a width of 100 micrometers to 1 millimeter and a spacing between adjacent grooves 216 of 10 micrometers to 100 micrometers. The groove 216 has a depth of 1 micrometer to 1 millimeter. It will be appreciated that a plurality of grooves 216 formed in the surface 212 of the body 210 may also be combined with other different configurations. It is only required that the ratio of the width and the pitch of the groove 216 is greater than or equal to 5:1, and the pitch of the groove 216 is less than or equal to 100 micrometers, so that the total concave area of the plurality of grooves 216 is greater than or equal to the The carbon nanotube film bearing region 214 has an area of 80%, such that when a carbon nanotube film structure is disposed in the carbon nanotube film bearing region 214, the carbon nanotube film structure and the nai The effective contact area of the carbon nanotube film bearing region 214 is less than 20% of the area of the carbon nanotube film structure itself. Preferably, the ratio of the width and the pitch of the groove is greater than or equal to 10:1, and the pitch of the groove is less than or equal to 100 micrometers, such that the total recessed area of the plurality of grooves 116 is greater than or equal to the nanocarbon. 90% of the area of the tubular membrane bearing region 214, such that when a carbon nanotube membrane structure is disposed in the carbon nanotube membrane bearing region 214, the carbon nanotube membrane structure and the nanocarbon The effective contact area of the tubular membrane bearing region 214 is less than 10% of the area of the carbon nanotube membrane structure itself.

請參閱圖3,本發明進一步提供一種所述奈米碳管膜承載結構100的使用方法,該方法主要包括以下步驟:(S101)提供至少一奈米碳管膜承載結構,所述奈米碳管膜承載結構包括一本體,所述本體具有一表面,該表面具有一奈米碳管膜承載區域,該奈米碳 管膜承載區域具有複數個凹陷結構,所述複數個凹陷結構的總凹陷面積大於等於所述奈米碳管膜承載區域面積的80%;(S102)提供一奈米碳管膜狀結構;以及(S103)將所述奈米碳管膜狀結構直接設置於所述奈米碳管膜承載結構的奈米碳管膜承載區域,所述奈米碳管膜狀結構與所述奈米碳管膜承載結構的有效接觸面積小於所述奈米碳管膜狀結構本身面積的20%。 Referring to FIG. 3, the present invention further provides a method for using the carbon nanotube film bearing structure 100. The method mainly includes the following steps: (S101) providing at least one carbon nanotube film bearing structure, the nano carbon The tubular membrane supporting structure comprises a body having a surface having a carbon nanotube membrane bearing region, the nanocarbon The tubular film bearing region has a plurality of concave structures, and the total concave area of the plurality of concave structures is greater than or equal to 80% of the area of the carbon nanotube film bearing region; (S102) providing a carbon nanotube film structure; (S103) directly placing the carbon nanotube film-like structure on a carbon nanotube film bearing region of the carbon nanotube film bearing structure, the carbon nanotube film structure and the carbon nanotube The effective contact area of the membrane-bearing structure is less than 20% of the area of the carbon nanotube membrane structure itself.

步驟S101,提供至少一奈米碳管膜承載結構,所述奈米碳管膜承載結構包括一本體,所述本體具有一表面,該表面具有一奈米碳管膜承載區域,該奈米碳管膜承載區域具有複數個凹陷結構,所述複數個凹陷結構的總凹陷面積大於等於所述奈米碳管膜承載區域的面積的80%。 Step S101, providing at least one carbon nanotube film bearing structure, the carbon nanotube film supporting structure comprising a body, the body having a surface having a carbon nanotube film bearing region, the nano carbon The tube film bearing region has a plurality of recessed structures, and the total recessed area of the plurality of recessed structures is greater than or equal to 80% of the area of the carbon nanotube film bearing region.

所述奈米碳管膜承載結構為本發明第一實施例所提供的奈米碳管膜承載結構100。可以理解,所述奈米碳管膜承載結構亦可以為本發明第二實施例所提供的奈米碳管膜承載結構200或其他結構。 The carbon nanotube film bearing structure is the carbon nanotube film bearing structure 100 provided by the first embodiment of the present invention. It can be understood that the carbon nanotube film bearing structure can also be the carbon nanotube film bearing structure 200 or other structure provided by the second embodiment of the present invention.

步驟S102,提供一奈米碳管膜狀結構。 Step S102, providing a carbon nanotube film structure.

提供一奈米碳管膜狀結構120,所述奈米碳管膜狀結構120包括至少一個奈米碳管膜。該奈米碳管膜可以係奈米碳管拉膜、奈米碳管絮化膜或奈米碳管碾壓膜等。 A carbon nanotube film structure 120 is provided, the carbon nanotube film structure 120 comprising at least one carbon nanotube film. The carbon nanotube film can be a carbon nanotube film, a carbon nanotube film or a carbon nanotube film.

請參見圖4,所述奈米碳管拉膜為從一奈米碳管陣列中直接拉取獲得的整體結構。該奈米碳管拉膜係由複數個奈米碳管組成的自支撐結構。所述自支撐結構係指該奈米碳管拉膜可無需基底支撐 ,自支撐存在。所述複數個奈米碳管基本沿同一方向擇優取向延伸。所述擇優取向係指在奈米碳管拉膜中大多數奈米碳管的整體延伸方向基本朝同一方向。而且,所述大多數奈米碳管的整體延伸方向基本平行於所述奈米碳管拉膜的表面。進一步地,所述奈米碳管拉膜中多數奈米碳管係通過凡得瓦力首尾相連並且基本沿同一方向延伸。所述奈米碳管拉膜及其製備方法請參見2007年2月12日申請的,2010年7月11日公告的,公告號為TW I327177的台灣發明專利申請公開說明書。 Referring to FIG. 4, the carbon nanotube film is a unitary structure obtained by directly pulling from a carbon nanotube array. The carbon nanotube film is a self-supporting structure composed of a plurality of carbon nanotubes. The self-supporting structure means that the carbon nanotube film can be supported without a substrate Self-support exists. The plurality of carbon nanotubes extend in a preferred orientation along substantially the same direction. The preferred orientation means that the overall extension direction of most of the carbon nanotubes in the carbon nanotube film is substantially in the same direction. Moreover, the overall direction of extension of the majority of the carbon nanotubes is substantially parallel to the surface of the carbon nanotube film. Further, most of the carbon nanotubes in the carbon nanotube film are connected end to end by van der Waals and extend substantially in the same direction. For the carbon nanotube film and the preparation method thereof, please refer to the Taiwan invention patent application publication specification of the TW I327177 filed on July 12, 2010, filed on July 11, 2010.

所述奈米碳管碾壓膜包括均勻分佈的奈米碳管,該奈米碳管無序,沿同一方向或不同方向擇優取向排列。請參見圖5,優選地,所述奈米碳管碾壓膜中的奈米碳管基本沿同一方向延伸且平行於該奈米碳管碾壓膜的表面。所述奈米碳管碾壓膜中的奈米碳管相互交疊。所述奈米碳管碾壓膜中奈米碳管之間通過凡得瓦力相互吸引,緊密結合,使得該奈米碳管碾壓膜具有很好的柔韌性,可以彎曲折疊成任意形狀而不破裂。所述奈米碳管碾壓膜及其製備方法請參見2009年1月1日公開的,公開號為TW200900348的台灣發明專利申請公開說明書。 The carbon nanotube rolled film comprises uniformly distributed carbon nanotubes which are disordered and arranged in a preferred orientation in the same direction or in different directions. Referring to FIG. 5, preferably, the carbon nanotubes in the carbon nanotube rolled film extend substantially in the same direction and are parallel to the surface of the carbon nanotube rolled film. The carbon nanotubes in the carbon nanotube rolled film overlap each other. The carbon nanotubes in the carbon nanotube film are attracted to each other by van der Waals force, and the carbon nanotubes have good flexibility and can be bent and folded into any shape. Does not break. The carbon nanotube rolled film and the preparation method thereof are described in the Taiwan Patent Application Publication No. TW200900348, which is published on Jan. 1, 2009.

請參見圖6,所述奈米碳管絮化膜包括相互纏繞的奈米碳管。該奈米碳管之間通過凡得瓦力相互吸引、纏繞,形成網路狀結構。所述奈米碳管絮化膜各向同性。所述奈米碳管絮化膜中的奈米碳管為均勻分佈,無規則排列。所述奈米碳管絮化膜及其製備方法請參見2008年11月16日公開的,公開號為TW200844041的台灣發明專利申請公開說明書。 Referring to FIG. 6, the carbon nanotube flocculation membrane comprises carbon nanotubes intertwined with each other. The carbon nanotubes are attracted and entangled by van der Waals forces to form a network structure. The carbon nanotube flocculation membrane is isotropic. The carbon nanotubes in the carbon nanotube flocculation membrane are uniformly distributed and arranged irregularly. The carbon nanotube flocculation film and the preparation method thereof are described in the Taiwan invention patent application publication No. TW200844041, which is published on Nov. 16, 2008.

本實施例中,所述奈米碳管膜狀結構120包為一奈米碳管拉膜,該奈米碳管拉膜為從一奈米碳管陣列中直接拉取獲得,其製備方法具體包括以下步驟: In this embodiment, the carbon nanotube film structure 120 is a carbon nanotube film, and the carbon nanotube film is directly drawn from a carbon nanotube array, and the preparation method thereof is specific. Includes the following steps:

首先,提供一形成於一生長基底的奈米碳管陣列,該陣列為超順排的奈米碳管陣列。 First, an array of carbon nanotubes formed on a growth substrate is provided, the array being a super-aligned array of carbon nanotubes.

所述超順排的奈米碳管陣列採用化學氣相沉積法製備,該超順排奈米碳管陣列的製備方法可參見台灣專利公告第TW I303239號。該超順排的奈米碳管陣列為複數個彼此平行且垂直於生長基底生長的奈米碳管形成的純奈米碳管陣列。通過控制生長條件,該超順排的奈米碳管陣列中基本不含有雜質,如無定型碳或殘留的催化劑金屬顆粒等,適於從中拉取奈米碳管膜。本發明實施例提供的奈米碳管陣列為多壁奈米碳管陣列。所述奈米碳管的直徑為0.5~50奈米,長度為50奈米~5毫米。本實施例中,奈米碳管的長度優選為100微米~900微米。 The super-aligned carbon nanotube array is prepared by chemical vapor deposition. The preparation method of the super-sequential carbon nanotube array can be referred to Taiwan Patent Publication No. TW I303239. The super-aligned carbon nanotube array is a plurality of pure carbon nanotube arrays formed of carbon nanotubes that are parallel to each other and perpendicular to the growth substrate. By controlling the growth conditions, the super-aligned carbon nanotube array contains substantially no impurities, such as amorphous carbon or residual catalyst metal particles, and is suitable for drawing a carbon nanotube film therefrom. The carbon nanotube array provided by the embodiment of the invention is a multi-walled carbon nanotube array. The carbon nanotubes have a diameter of 0.5 to 50 nm and a length of 50 nm to 5 mm. In this embodiment, the length of the carbon nanotubes is preferably from 100 micrometers to 900 micrometers.

其次,採用一拉伸工具從所述奈米碳管陣列中拉取奈米碳管獲得一奈米碳管膜,其具體包括以下步驟:(a)從所述超順排奈米碳管陣列中選定一個或具有一定寬度的複數個奈米碳管,本實施例優選為採用具有一定寬度的膠帶接觸奈米碳管陣列以選定一個或具有一定寬度的複數個奈米碳管;(b)以一定速度拉伸該選定的奈米碳管,從而形成首尾相連的複數個奈米碳管片段,進而形成一連續的奈米碳管拉膜。該拉取方向沿基本垂直於奈米碳管陣列的生長方向。 Next, a carbon nanotube film is obtained by pulling a carbon nanotube from the carbon nanotube array using a stretching tool, which specifically includes the following steps: (a) from the super-shoring carbon nanotube array Selecting one or a plurality of carbon nanotubes having a certain width, in this embodiment, preferably contacting the carbon nanotube array with a tape having a certain width to select one or a plurality of carbon nanotubes having a certain width; (b) The selected carbon nanotubes are drawn at a certain speed to form a plurality of carbon nanotube segments connected end to end, thereby forming a continuous carbon nanotube film. The pull direction is substantially perpendicular to the growth direction of the nanotube array.

在上述拉伸過程中,該複數個奈米碳管片段在拉力作用下沿拉伸方向逐漸剝離生長基底的同時,由於該複數個奈米碳管片段之間凡得瓦力的作用,該選定的複數個奈米碳管片段分別與其他奈米碳管片段首尾相連地連續地被拉出,從而形成一連續、均勻且具有一定寬度的奈米碳管拉膜。所述奈米碳管拉膜中的奈米碳管包括單壁奈米碳管、雙壁奈米碳管及多壁奈米碳管中的一種或多種。該奈米碳管拉膜具有較大的比表面積,故該奈米碳管拉膜宏觀上表現出較大的黏性。 In the above stretching process, the plurality of carbon nanotube segments are gradually peeled off the growth substrate in the stretching direction under the action of tension, and the selection is due to the effect of the vantage force between the plurality of carbon nanotube segments. A plurality of carbon nanotube segments are continuously drawn end-to-end with other carbon nanotube segments, thereby forming a continuous, uniform, and wide-width carbon nanotube film. The carbon nanotubes in the carbon nanotube film include one or more of a single-walled carbon nanotube, a double-walled carbon nanotube, and a multi-walled carbon nanotube. The carbon nanotube film has a large specific surface area, so the carbon nanotube film exhibits a large viscosity on a macroscopic view.

步驟S103,將所述奈米碳管膜狀結構直接設置於所述奈米碳管膜承載結構的奈米碳管膜承載區域,所述奈米碳管膜狀結構與所述奈米碳管膜承載結構的有效接觸面積小於所述奈米碳管膜狀結構本身面積的20%。 Step S103, the film structure of the carbon nanotubes is directly disposed on a carbon nanotube film bearing region of the carbon nanotube film bearing structure, the carbon nanotube film structure and the carbon nanotube The effective contact area of the membrane-bearing structure is less than 20% of the area of the carbon nanotube membrane structure itself.

請參照圖7,將所述奈米碳管膜狀結構120設置於所述奈米碳管膜承載結構100的奈米碳管膜承載區域114,該奈米碳管膜狀結構120在所述奈米碳管膜承載區域114中的複數個凹陷結構116處懸空設置。 Referring to FIG. 7, the carbon nanotube film structure 120 is disposed on the carbon nanotube film bearing region 114 of the carbon nanotube film supporting structure 100, and the carbon nanotube film structure 120 is A plurality of recessed structures 116 in the carbon nanotube film bearing region 114 are suspended.

可以理解,由於所述本體110的表面112具有複數個凹陷結構116,且該凹陷結構116的總凹陷面積大於等於所述奈米碳管膜承載區域114的面積的80%,因此,將所述奈米碳管膜狀結構120設置在所述奈米碳管膜承載區域114時,該奈米碳管膜狀結構120與所述本體110表面112的有效接觸面積小於所述奈米碳管膜狀結構120本身面積的20%,從而降低該奈米碳管膜狀結構120與該本體110的表面112之間的凡得瓦力,使該奈米碳管膜狀結構120與該 本體110的表面112之間的凡得瓦力小於所述奈米碳管膜狀結構120中複數個奈米碳管之間凡得瓦力。因此,將所述奈米碳管膜狀結構120設置於所述奈米碳管膜承載結構100時,由於所述奈米碳管膜狀結構120與所述本體110表面112之間的凡得瓦力小於所述奈米碳管膜狀結構120中複數個奈米碳管之間的凡得瓦力,從而使該奈米碳管膜狀結構120可以容易地從所述本體110的表面112剝離,而不至於破壞該奈米碳管膜狀結構120的形態和結構,從而實現了該奈米碳管膜狀結構120的保存和轉移。 It can be understood that, since the surface 112 of the body 110 has a plurality of recessed structures 116, and the total recessed area of the recessed structure 116 is greater than or equal to 80% of the area of the carbon nanotube film bearing region 114, the When the carbon nanotube film structure 120 is disposed in the carbon nanotube film bearing region 114, the effective contact area of the carbon nanotube film structure 120 with the surface 112 of the body 110 is smaller than the carbon nanotube film. 20% of the area of the structure 120 itself, thereby reducing the van der Waals force between the carbon nanotube film structure 120 and the surface 112 of the body 110, so that the carbon nanotube film structure 120 The van der Waals force between the surfaces 112 of the body 110 is less than the van der Waals force between the plurality of carbon nanotubes in the carbon nanotube film structure 120. Therefore, when the carbon nanotube film structure 120 is disposed on the carbon nanotube film bearing structure 100, due to the difference between the carbon nanotube film structure 120 and the surface 112 of the body 110 The tile force is less than the van der Waals force between the plurality of carbon nanotubes in the carbon nanotube film structure 120, so that the carbon nanotube film structure 120 can be easily removed from the surface 112 of the body 110. The morphology and structure of the carbon nanotube film structure 120 are peeled off without destroying, thereby realizing the preservation and transfer of the carbon nanotube film structure 120.

本實施例中,將一奈米碳管拉膜設置於所述陽極氧化鋁薄片的表面時,該奈米碳管拉膜的大部分結構懸空設置於所述陽極氧化鋁薄片表面的複數個微孔處,從而使所述奈米碳管拉膜與所述陽極氧化鋁薄片的有效接觸面積小於所述奈米碳管拉膜本身面積的10%,進而降低該奈米碳管拉膜與該陽極氧化鋁薄片的表面之間的凡得瓦力,使該奈米碳管拉膜與該陽極氧化鋁薄片的表面之間的凡得瓦力小於所述奈米碳管拉膜中複數個奈米碳管之間凡得瓦力。因此,將所述奈米碳管拉膜設置於所述陽極氧化鋁薄片的表面時,由於所述奈米碳管拉膜與所述陽極氧化鋁薄片的表面之間的凡得瓦力小於所述奈米碳管拉膜中複數個奈米碳管之間的凡得瓦力,從而使該奈米碳管拉膜可以容易地從所述陽極氧化鋁薄片的表面剝離,而不至於破壞該奈米碳管拉膜的形態和結構,從而實現了該奈米碳管拉膜的保存和轉移。 In this embodiment, when a carbon nanotube film is disposed on the surface of the anodized aluminum foil, most of the structure of the carbon nanotube film is suspended on the surface of the anodized aluminum foil. a hole so that an effective contact area of the carbon nanotube film and the anodized aluminum foil is less than 10% of an area of the carbon nanotube film itself, thereby reducing the carbon nanotube film and the a van der Waals force between the surfaces of the anodized aluminum foil, such that the van der Waals force between the carbon nanotube film and the surface of the anodized aluminum foil is smaller than the plurality of nanometers in the carbon nanotube film There is a wind power between the carbon tubes. Therefore, when the carbon nanotube film is disposed on the surface of the anodized aluminum foil, the van der Waals force between the carbon nanotube film and the surface of the anodized aluminum foil is smaller than Describe the van der Waals force between the plurality of carbon nanotubes in the carbon nanotube film, so that the carbon nanotube film can be easily peeled off from the surface of the anodized aluminum foil without destroying the The shape and structure of the carbon nanotube film are removed, thereby realizing the preservation and transfer of the carbon nanotube film.

可以理解,當所述奈米碳管膜狀結構包括複數個奈米碳管膜時,該複數個奈米碳管膜可以層疊設置或並排設置於所述奈米碳管膜 承載區域。具體地,將所述奈米碳管膜設置於所述奈米碳管膜承載區域後,可以進一步將另一奈米碳管膜覆蓋至先前的奈米碳管膜表面,如此反復多次,在該奈米碳管膜承載區域上鋪設複數個奈米碳管膜。此外,當所述奈米碳管膜承載區域具有較大的面積時,將所述奈米碳管膜沿一個方向設置於所述奈米碳管膜承載區域後,還可以將另一奈米碳管膜並排設置於所述奈米碳管膜承載區域沒有鋪設奈米碳管膜的區域。可以理解,該步驟為可選步驟。 It can be understood that when the carbon nanotube film structure comprises a plurality of carbon nanotube films, the plurality of carbon nanotube films may be stacked or arranged side by side on the carbon nanotube film. Carrying area. Specifically, after the carbon nanotube film is disposed on the carbon nanotube film bearing region, another carbon nanotube film may be further covered to the surface of the previous carbon nanotube film, and thus repeated, A plurality of carbon nanotube films are laid on the carbon nanotube film bearing region. In addition, when the carbon nanotube film bearing region has a large area, after the carbon nanotube film is disposed in one direction on the carbon nanotube film bearing region, another nanometer can be further The carbon tube membranes are arranged side by side in a region where the carbon nanotube film bearing region is not laid with a carbon nanotube film. It can be understood that this step is an optional step.

此外,將所述奈米碳管膜狀結構直接設置於所述奈米碳管膜承載結構的奈米碳管膜承載區域後,可以進一步將另一奈米碳管膜承載結構覆蓋在所述奈米碳管膜狀結構的表面,並使所述另一奈米碳管膜承載結構中的奈米碳管膜承載區域與所述奈米碳管膜狀結構相接觸,形成一兩邊為奈米碳管膜承載結構,中間為奈米碳管膜的夾心結構。在所述夾心結構中,所述奈米碳管膜狀結構挾持於兩個奈米碳管膜承載結構的中間,使奈米碳管膜狀結構位於兩個奈米碳管膜承載結構具有凸起結構的表面之間,並分別與兩個奈米碳管膜承載結構具有凸起結構的表面接觸,使所述奈米碳管膜狀結構可以更牢固地被固定,從而使該奈米碳管膜狀結構可以更為容易的保存和轉移。此外,該夾心結構還可以使所述奈米碳管膜狀結構不受到破壞,以及具有防塵等作用。 In addition, after the carbon nanotube film structure is directly disposed on the carbon nanotube film bearing region of the carbon nanotube film bearing structure, another carbon nanotube film bearing structure may be further covered in the a surface of the carbon nanotube film structure, and contacting the carbon nanotube film bearing region in the other carbon nanotube film bearing structure with the carbon nanotube film structure to form a two sides The carbon nanotube film bearing structure is in the middle of the sandwich structure of the carbon nanotube film. In the sandwich structure, the carbon nanotube film structure is held in the middle of two carbon nanotube film bearing structures, so that the carbon nanotube film structure is located on two carbon nanotube film bearing structures having convexity Between the surfaces of the structure, and respectively contact with the surface of the two carbon nanotube film bearing structures having a convex structure, so that the carbon nanotube film structure can be more firmly fixed, thereby making the nano carbon The tubular membrane structure can be more easily preserved and transferred. In addition, the sandwich structure can also protect the carbon nanotube film structure from damage and have dustproof effects.

本發明實施例提供的奈米碳管膜承載結構具有結構簡單、成本較低等特點。該奈米碳管膜承載結構通過在一本體的表面設置複數個凹陷結構,使得將一奈米碳管膜狀結構設置於所述奈米碳管膜 承載結構表面時,該奈米碳管膜狀結構的大部分結構通過所述凹陷結構懸空設置,從而大大地減少了所述奈米碳管膜狀結構與所述奈米碳管膜承載結構的有效接觸面積,進而降低了所述奈米碳管膜狀結構與所述奈米碳管膜承載結構之間的凡得瓦力,最後實現奈米碳管膜狀結構的保存和轉移。 The carbon nanotube film bearing structure provided by the embodiment of the invention has the characteristics of simple structure and low cost. The carbon nanotube film bearing structure is provided with a plurality of concave structures on a surface of a body such that a carbon nanotube film structure is disposed on the carbon nanotube film When the surface of the structure is carried, most of the structure of the carbon nanotube film structure is suspended by the concave structure, thereby greatly reducing the film structure of the carbon nanotube film and the bearing structure of the carbon nanotube film. The effective contact area further reduces the van der Waals force between the carbon nanotube film structure and the carbon nanotube film bearing structure, and finally realizes the preservation and transfer of the carbon nanotube film structure.

本發明實施例所述奈米碳管膜承載結構的使用方法,通過將一奈米碳管膜狀結構直接承載於一奈米碳管膜承載結構的奈米碳管膜承載區域,從而實現奈米碳管膜狀結構的保存和轉移,該方法簡單易行。此外,將另一奈米碳管膜承載結構覆蓋在所述承載於一奈米碳管膜承載結構中的奈米碳管膜狀結構的表面,形成一兩側為奈米碳管膜承載結構中間為奈米碳管膜狀結構的夾心結構。所述奈米碳管膜狀結構挾持於兩個奈米碳管膜承載結構的中間,使該奈米碳管膜狀結構更牢固地被固定。此外,該夾心結構還可以使所述奈米碳管膜狀結構不受到外界作用力的破壞,還具有防塵等作用。 The method for using the carbon nanotube film bearing structure in the embodiment of the present invention realizes the naphthalene film bearing structure by directly carrying a film structure of a carbon nanotube film on a carbon nanotube film bearing region of a carbon nanotube film bearing structure The preservation and transfer of the membrane structure of the carbon tube is simple and easy. In addition, another carbon nanotube film bearing structure is covered on the surface of the carbon nanotube film-like structure carried in the carbon nanotube film bearing structure to form a carbon nanotube film bearing structure on both sides. In the middle is a sandwich structure of a carbon nanotube film structure. The film structure of the carbon nanotubes is held in the middle of the two carbon nanotube film-bearing structures, so that the film structure of the carbon nanotubes is more firmly fixed. In addition, the sandwich structure can also prevent the film structure of the carbon nanotube from being damaged by external forces, and also has the function of dustproofing.

綜上所述,本發明確已符合發明專利之要件,遂依法提出專利申請。惟,以上所述者僅為本發明之較佳實施例,自不能以此限制本案之申請專利範圍。舉凡習知本案技藝之人士援依本發明之精神所作之等效修飾或變化,皆應涵蓋於以下申請專利範圍內。 In summary, the present invention has indeed met the requirements of the invention patent, and has filed a patent application according to law. However, the above description is only a preferred embodiment of the present invention, and it is not possible to limit the scope of the patent application of the present invention. Equivalent modifications or variations made by those skilled in the art in light of the spirit of the invention are intended to be included within the scope of the following claims.

100‧‧‧奈米碳管膜承載結構 100‧‧‧Nano carbon nanotube membrane bearing structure

110‧‧‧本體 110‧‧‧ body

112‧‧‧表面 112‧‧‧ surface

114‧‧‧奈米碳管膜承載區域 114‧‧‧Nano carbon nanotube film bearing area

116‧‧‧凹陷結構 116‧‧‧ recessed structure

Claims (10)

一種奈米碳管膜承載結構的使用方法,其包括以下步驟:提供至少一奈米碳管膜承載結構,所述奈米碳管膜承載結構包括一本體,所述本體具有一表面,該表面具有一奈米碳管膜承載區域,該奈米碳管膜承載區域具有複數個凹陷結構,所述複數個凹陷結構的總凹陷面積大於等於所述奈米碳管膜承載區域的面積的80%;提供一奈米碳管膜狀結構;以及將所述奈米碳管膜狀結構直接設置於所述奈米碳管膜承載結構的奈米碳管膜承載區域,所述奈米碳管膜狀結構與所述奈米碳管膜承載結構的有效接觸面積小於等於所述奈米碳管膜狀結構本身面積的20%。 A method of using a carbon nanotube film carrying structure, comprising the steps of: providing at least one carbon nanotube film bearing structure, the carbon nanotube film bearing structure comprising a body, the body having a surface, the surface Having a carbon nanotube film bearing region, the carbon nanotube film bearing region has a plurality of recessed structures, and the total recessed area of the plurality of recessed structures is greater than or equal to 80% of the area of the carbon nanotube film bearing region Providing a carbon nanotube film structure; and placing the carbon nanotube film structure directly on the carbon nanotube film bearing region of the carbon nanotube film bearing structure, the carbon nanotube film The effective contact area of the structure with the carbon nanotube film bearing structure is less than or equal to 20% of the area of the carbon nanotube film structure itself. 如請求項1所述的奈米碳管膜承載結構的使用方法,其中,所述奈米碳管膜狀結構在所述複數個凹陷結構處懸空設置。 The method of using the carbon nanotube film-bearing structure according to claim 1, wherein the carbon nanotube film structure is suspended at the plurality of recess structures. 如請求項1所述的奈米碳管膜承載結構的使用方法,其中,所述奈米碳管膜狀結構包括至少一奈米碳管膜,該奈米碳管膜包括複數個奈米碳管,所述複數個奈米碳管通過凡得瓦力首尾相連並且沿同一方向擇優取向延伸。 The method for using a carbon nanotube film-bearing structure according to claim 1, wherein the carbon nanotube film structure comprises at least one carbon nanotube film, and the carbon nanotube film comprises a plurality of nano carbons In the tube, the plurality of carbon nanotubes are connected end to end by van der Waals force and extend in a preferred orientation in the same direction. 如請求項3所述的奈米碳管膜承載結構的使用方法,其中,所述奈米碳管膜為由複數個奈米碳管組成的一自支撐結構。 The method for using a carbon nanotube membrane supporting structure according to claim 3, wherein the carbon nanotube membrane is a self-supporting structure composed of a plurality of carbon nanotubes. 如請求項3所述的奈米碳管膜承載結構的使用方法,其中,所述奈米碳管膜為從一奈米碳管陣列中拉取獲得的一整體結構。 The method of using the carbon nanotube film-bearing structure according to claim 3, wherein the carbon nanotube film is a unitary structure obtained by pulling from a carbon nanotube array. 如請求項1所述的奈米碳管膜承載結構的使用方法,其中,將所述奈米碳管膜狀結構直接設置於所述奈米碳管膜承載結構的奈米 碳管膜承載區域後,進一步包括:將另一奈米碳管膜承載結構覆蓋於所述奈米碳管膜狀結構表面,使奈米碳管膜狀結構位於兩個奈米碳管膜承載結構具有凹陷結構的表面之間。 The method for using a carbon nanotube film-bearing structure according to claim 1, wherein the carbon nanotube film-like structure is directly disposed on the nano-carbon nanotube film-bearing structure of the nanometer. After the carbon nanotube film bearing region, the method further comprises: covering another carbon nanotube film bearing structure on the surface of the carbon nanotube film structure, so that the carbon nanotube film structure is located on the two carbon nanotube film bearing The structure has a surface between the recessed structures. 如請求項1所述的奈米碳管膜承載結構的使用方法,其中,所述複數個凹陷結構為複數個相互平行且間隔設置的微孔,該微孔的直徑和間距的比值大於等於5:1,且該微孔的間距小於等於100微米。 The method for using a carbon nanotube film-bearing structure according to claim 1, wherein the plurality of recessed structures are a plurality of micropores arranged in parallel and spaced apart from each other, and the ratio of the diameter to the pitch of the micropores is greater than or equal to 5 :1, and the pitch of the micropores is less than or equal to 100 μm. 如請求項7所述的奈米碳管膜承載結構的使用方法,其中,該微孔的直徑為100微米至1毫米,相鄰的微孔之間的間距為10微米至100微米。 The method of using the carbon nanotube film-bearing structure according to claim 7, wherein the micropores have a diameter of from 100 μm to 1 mm, and a spacing between adjacent micropores is from 10 μm to 100 μm. 如請求項1所述的奈米碳管膜承載結構的使用方法,其中,所述複數個凹陷結構為複數個均勻分佈且間隔設置的長條狀凹槽,該凹槽的寬度和間距的比值大於等於5:1,且該凹槽的間距小於等於100微米。 The method for using a carbon nanotube film bearing structure according to claim 1, wherein the plurality of recessed structures are a plurality of evenly spaced and spaced apart elongated grooves, and the ratio of the width to the pitch of the grooves It is greater than or equal to 5:1, and the pitch of the grooves is less than or equal to 100 micrometers. 如請求項9所述的奈米碳管膜承載結構的使用方法,其中,該凹槽的寬度為100微米至1毫米,相鄰的凹槽之間的間距為10微米至100微米。 The method of using the carbon nanotube film-bearing structure according to claim 9, wherein the groove has a width of 100 μm to 1 mm, and a spacing between adjacent grooves is 10 μm to 100 μm.
TW099137721A 2010-11-03 2010-11-03 Nano carbon tube membrane bearing structure and using method thereof TWI452007B (en)

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