[go: up one dir, main page]

TWI315311B - Transition metal complexes, catalyst compositions containing the same, and olefin polymerization using the catalyst compositions - Google Patents

Transition metal complexes, catalyst compositions containing the same, and olefin polymerization using the catalyst compositions

Info

Publication number
TWI315311B
TWI315311B TW095124772A TW95124772A TWI315311B TW I315311 B TWI315311 B TW I315311B TW 095124772 A TW095124772 A TW 095124772A TW 95124772 A TW95124772 A TW 95124772A TW I315311 B TWI315311 B TW I315311B
Authority
TW
Taiwan
Prior art keywords
catalyst compositions
transition metal
same
metal complexes
olefin polymerization
Prior art date
Application number
TW095124772A
Other languages
English (en)
Other versions
TW200702335A (en
Inventor
Choong Hoon Lee
Eunjung Lee
Seungwhan Jung
Jong Joo Ha
Beomdoo Seo
Bun Yeoul Lee
Ui Gab Joung
Dae June Joe
Original Assignee
Lg Chemical Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lg Chemical Ltd filed Critical Lg Chemical Ltd
Publication of TW200702335A publication Critical patent/TW200702335A/zh
Application granted granted Critical
Publication of TWI315311B publication Critical patent/TWI315311B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
TW095124772A 2005-07-08 2006-07-07 Transition metal complexes, catalyst compositions containing the same, and olefin polymerization using the catalyst compositions TWI315311B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020050061820A KR100789241B1 (ko) 2005-07-08 2005-07-08 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합

Publications (2)

Publication Number Publication Date
TW200702335A TW200702335A (en) 2007-01-16
TWI315311B true TWI315311B (en) 2009-10-01

Family

ID=37619085

Family Applications (1)

Application Number Title Priority Date Filing Date
TW095124772A TWI315311B (en) 2005-07-08 2006-07-07 Transition metal complexes, catalyst compositions containing the same, and olefin polymerization using the catalyst compositions

Country Status (7)

Country Link
US (2) US7538239B2 (zh)
JP (1) JP5043007B2 (zh)
KR (1) KR100789241B1 (zh)
CN (1) CN101223195B (zh)
DE (1) DE112006001798B4 (zh)
TW (1) TWI315311B (zh)
WO (1) WO2007007992A1 (zh)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1966223B1 (en) 2005-12-30 2013-08-14 LG Chem. Ltd. Catalyst composition comprising group 4 transition metal complexes and method for preparing polyolefins using the same
KR100843603B1 (ko) 2005-12-31 2008-07-03 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
KR100874032B1 (ko) 2006-02-01 2008-12-17 주식회사 엘지화학 전이 금속 화합물을 포함하는 촉매 조성물 및 이를 이용한올레핀 중합
KR100874027B1 (ko) 2006-02-15 2008-12-17 주식회사 엘지화학 이핵 전이금속 화합물을 포함하는 촉매 조성물을 이용한올레핀의 중합 공정
KR100820542B1 (ko) 2006-03-24 2008-04-08 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
KR100853433B1 (ko) 2006-03-31 2008-08-21 주식회사 엘지화학 전이금속 화합물을 포함하는 촉매 조성물 및 이를 이용하는올레핀 중합체의 제조 방법
KR100964501B1 (ko) * 2006-09-20 2010-06-21 주식회사 엘지화학 이중 조성 분포를 가지는 에틸렌과 α-올레핀의 엘라스토머공중합체
EP2084210A1 (en) * 2006-11-22 2009-08-05 Gwangju Institute of Science and Technology Sulfonated poly(arylene ether) containing crosslinkable moity at end group, method of manufacturing the same, and polymer electrolyte membrane using the sulfonated poly(arylene ether) and the method
KR101011497B1 (ko) * 2007-01-29 2011-01-31 주식회사 엘지화학 초저밀도 폴리올레핀 공중합체의 제조 방법
KR101384450B1 (ko) 2010-04-12 2014-04-25 롯데케미칼 주식회사 티오펜-축합고리 사이클로펜타디에닐 리간드를 포함하는 전이금속 화합물을 사용한 올레핀-디엔 공중합체의 제조방법
WO2011129592A2 (ko) 2010-04-12 2011-10-20 호남석유화학 주식회사 올레핀 중합용 담지 촉매 및 이를 사용한 폴리올레핀의 제조방법
KR100986301B1 (ko) 2010-04-12 2010-10-07 아주대학교산학협력단 테트라하이드로퀴놀린 유도체로부터 유래한 티오펜-축합고리 싸이클로펜타디에닐 4족 금속 화합물 및 이를 이용한 올레핀 중합
ES2596719T3 (es) 2010-04-12 2017-01-11 Lotte Chemical Corporation Procedimiento de preparación de un copolímero de olefin-dieno usando un compuesto de metal de transición que incluye un ligando de ciclopentadienilo de anillo condensado con tiofeno
KR101384401B1 (ko) 2010-04-12 2014-04-25 롯데케미칼 주식회사 올레핀 중합용 담지 촉매 및 이를 사용한 폴리올레핀의 제조방법
US8084385B1 (en) * 2010-06-09 2011-12-27 Equistar Chemicals, L.P. Catalysts for olefin polymerization
CN105263969B (zh) * 2013-04-11 2017-04-05 埃克森美孚化学专利公司 使用茂金属聚合催化剂制备聚烯烃及共聚物的方法
KR101711788B1 (ko) * 2016-03-09 2017-03-14 한화케미칼 주식회사 혼성 촉매 조성물, 이의 제조방법, 및 이를 이용하여 제조된 폴리올레핀
KR102363032B1 (ko) 2018-03-21 2022-02-16 주식회사 엘지화학 전이금속 복합체의 제조 방법

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US6448355B1 (en) * 1991-10-15 2002-09-10 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
WO1997008179A1 (en) * 1995-08-31 1997-03-06 Sumitomo Chemical Company, Limited Transition metal complexes, catalyst for olefin polymerization, and process for producing olefin polymers
DE19624581C2 (de) 1996-06-20 1999-02-04 Targor Gmbh Übergangsmetallverbindung und ein Verfahren zu ihrer Herstellung, sowie ihre Verwendung
US5856258A (en) 1996-10-15 1999-01-05 Northwestern University Phenolate constrained geometry polymerization catalyst and method for preparing
AUPO903897A0 (en) 1997-09-08 1997-10-02 Commonwealth Scientific And Industrial Research Organisation Organic boronic acid derivatives
JP4309534B2 (ja) 1999-11-30 2009-08-05 独立行政法人科学技術振興機構 シクロペンタジエン誘導体の合成方法
CN1444592A (zh) * 2000-05-31 2003-09-24 巴塞尔聚烯烃股份有限公司 制备过渡金属化合物的方法及其用于烯烃聚合的用途
SG99905A1 (en) * 2000-06-21 2003-11-27 Sumitomo Chemical Co Transition metal compound, catalyst for addition polymerization, and process for producing addition polymer
WO2003024983A1 (en) 2001-09-14 2003-03-27 Sumitomo Chemical Company, Limited Transition metal complex, catalyst for olefin polymerization, and process for producing olefin polymer with the same
JP2003221396A (ja) * 2002-01-29 2003-08-05 Sumitomo Chem Co Ltd 遷移金属錯体および重合用触媒
KR100601089B1 (ko) 2003-09-19 2006-07-14 주식회사 엘지화학 메탈로센 촉매의 제조 방법

Also Published As

Publication number Publication date
KR20070006466A (ko) 2007-01-11
DE112006001798B4 (de) 2015-07-02
CN101223195A (zh) 2008-07-16
JP5043007B2 (ja) 2012-10-10
TW200702335A (en) 2007-01-16
DE112006001798T5 (de) 2008-05-08
WO2007007992A1 (en) 2007-01-18
US20090209712A1 (en) 2009-08-20
JP2009500403A (ja) 2009-01-08
CN101223195B (zh) 2011-10-26
KR100789241B1 (ko) 2008-01-02
US8129488B2 (en) 2012-03-06
US20070010637A1 (en) 2007-01-11
US7538239B2 (en) 2009-05-26

Similar Documents

Publication Publication Date Title
TWI347323B (en) Transition metal complex, catalyst composition including the same and olefin polymer using catalyst composition
TWI315311B (en) Transition metal complexes, catalyst compositions containing the same, and olefin polymerization using the catalyst compositions
ZA200809778B (en) Metallocene complex and polymerization catalyst composition containing the same
SG142667A1 (en) Highly dispersed metal catalysts
ZA200701613B (en) Hydrocracking catalyst composition
GB0400166D0 (en) Catalyst
ZA200709856B (en) Fluorene derivatives,compositions containing said derivatives and the use thereof
IL191137A0 (en) Polycation-polyanion complexes, compositions and methods of use thereof
EP1854538A4 (en) CATALYTIC COMPOSITION
GB0306308D0 (en) Polymerisation catalysts
GB0415879D0 (en) Polymerisation catalyst
MX253299B (es) Catalizador de oxido de etileno.
PL1947123T3 (pl) Składnik katalityczny do polimeryzacji etylenu, jego wytwarzanie i katalizator zawierający go
ZA200707570B (en) Catalyst composition
GB0425443D0 (en) Supported polymerisation catalysts
GB0424422D0 (en) Polymerisation catalysts
GB0300821D0 (en) Polymerisation catalysts
PT1682587T (pt) Componente de catalisador sólido melhorado
EP1675879A4 (en) ETHYLENE POLYMERIZATION USING BIS-IMINO PYRIDINYL METAL CATALYST COMPOUNDS
GB2442363B (en) Catalyst
ZA200803627B (en) Polymers incorporating 1,3 and 1,4 cyclohexnedimethanol
GB0506496D0 (en) Compound, composition and use
GB2444005B (en) Compound, composition and use
GB0403984D0 (en) Transition metal complexes and their uses as catalysts
GB0410260D0 (en) Transition metal complexes and their uses as catalysts

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees