TWI304635B - - Google Patents
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- TWI304635B TWI304635B TW91101584A TW91101584A TWI304635B TW I304635 B TWI304635 B TW I304635B TW 91101584 A TW91101584 A TW 91101584A TW 91101584 A TW91101584 A TW 91101584A TW I304635 B TWI304635 B TW I304635B
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- 239000010410 layer Substances 0.000 claims description 240
- 229910052751 metal Inorganic materials 0.000 claims description 98
- 239000002184 metal Substances 0.000 claims description 98
- 239000004065 semiconductor Substances 0.000 claims description 75
- 239000000758 substrate Substances 0.000 claims description 33
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 28
- 229920005591 polysilicon Polymers 0.000 claims description 28
- 238000009792 diffusion process Methods 0.000 claims description 25
- 238000004519 manufacturing process Methods 0.000 claims description 24
- 230000004888 barrier function Effects 0.000 claims description 19
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 16
- 229910052721 tungsten Inorganic materials 0.000 claims description 16
- 239000010937 tungsten Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 14
- 239000012790 adhesive layer Substances 0.000 claims description 11
- 239000002019 doping agent Substances 0.000 claims description 10
- 229910052732 germanium Inorganic materials 0.000 claims description 10
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 10
- 238000000151 deposition Methods 0.000 claims description 7
- 230000008021 deposition Effects 0.000 claims description 7
- 239000004744 fabric Substances 0.000 claims description 7
- 239000007943 implant Substances 0.000 claims description 7
- 238000000137 annealing Methods 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 238000001465 metallisation Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- 229910000577 Silicon-germanium Inorganic materials 0.000 claims description 2
- 229910001507 metal halide Inorganic materials 0.000 claims description 2
- 150000005309 metal halides Chemical class 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 239000013078 crystal Substances 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000010936 titanium Substances 0.000 description 9
- 238000010586 diagram Methods 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 238000005498 polishing Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910008310 Si—Ge Inorganic materials 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 238000002513 implantation Methods 0.000 description 2
- 238000001451 molecular beam epitaxy Methods 0.000 description 2
- 238000001289 rapid thermal chemical vapour deposition Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 230000005641 tunneling Effects 0.000 description 2
- 229910015900 BF3 Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 1
- 239000011195 cermet Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- SCCCLDWUZODEKG-UHFFFAOYSA-N germanide Chemical compound [GeH3-] SCCCLDWUZODEKG-UHFFFAOYSA-N 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000000038 ultrahigh vacuum chemical vapour deposition Methods 0.000 description 1
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- Electrodes Of Semiconductors (AREA)
Description
Ι3Ό4635 _案號91101584_年月日 修正 五、發明說明(1) 【發明說明】 發明背景 本發明有關於一種有金屬/半導體介面之半導體裝 置’特別有關於一種半導體裝置,其係使用一 SixGe1-x層 (0<χ<1 )而形成一低電阻、可調整之接觸。 在現代半導體製造技術中,傳統上是藉由形成歐姆接Ι Ό Ό Ό Ό Ό Ό 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 91 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 The x layer (0<χ<1) forms a low resistance, adjustable contact. In modern semiconductor manufacturing technology, traditionally by forming ohmic connections
觸(Ohmic contact)或擴散接觸(diffusion contact)而形 成MS (metal-semiconductor ;金屬-半導體)接觸的。前 者技術疋將推質佈植入MS介面層中,到達固體溶解限制 (solid solubility limit)以上之濃度(亦即, N(n,p)>102G cm_3)而形成一隧穿阻障(tunneling bar^r i er )。至於後者技術則是將掺質擴散入介面層,以降 低蕭基阻障高度(Schottky Barrier Height;別1〇。 矽是常用的半導體,其具有高的本質SBH (或Eg (energy gap)),Eg = l· 11 eV。因此,當使用矽時,在Ms 介面層上需要有相當高的摻雜濃度(通常是使用高能量佈 植來進行),以降低SBH,進而形成較佳的接觸。然而,高Contact with Ohmic contact or diffusion contact to form MS (metal-semiconductor; metal-semiconductor) contact. In the former technique, a push fabric is implanted into the MS interface layer to a concentration above the solid solubility limit (ie, N(n, p) > 102 G cm_3) to form a tunneling barrier (tunneling). Bar^ri er ). As for the latter technique, the dopant is diffused into the interface layer to reduce the height of the Schottky Barrier Height (Schottky Barrier Height; 矽 is a commonly used semiconductor with a high intrinsic SBH (or Eg (energy gap)), Eg = l· 11 eV. Therefore, when using germanium, a relatively high doping concentration (usually using high energy implants) is required on the Ms interface layer to lower the SBH and thus form a better contact. high
3ΪΪΪ尺致不需要的深接觸接面,這會使得裝置受到 紐通道效應(Sh〇rt channel effect; SCE)或擊穿 (punch-through)(漏電)。 發明之目的及概述 有鑑於此 種半導體裝置 面。 =發明之一目的為解決上述問題而提供一 其包括有低電阻接觸之金屬/半導體介The 3D ruler does not require a deep contact junction, which causes the device to be subjected to a Sh〇rt channel effect (SCE) or a punch-through (leakage). SUMMARY OF THE INVENTION The present invention is directed to such a semiconductor device. One of the objectives of the invention is to provide a metal/semiconductor dielectric comprising low resistance contacts in order to solve the above problems.
1304635 ------9Πηΐπ;ρ/[ 五、發明說明(2) 屬/半導、 . I面上形成一低電阻接觸,這可保護裝置使其 不受短通道效應且防止漏電。 本發明之又一目的為提供一種適用於CMOS裝置之低電 阻、可調整的接觸。 為達成上述目的,本發明之半導體裝置包括一半導體 一介電層,位於該半導體基板上,其具有曝露該半 =體基板之一接觸開口; 一 SixGei_x層,在該接觸開口内形 古,其中0<χ<1 ;以及一金屬插塞,位於該3、(;6卜X層上, 填入該接觸開口中。 本發明亦提供一種方法以在金屬/半導體介面上形成 二金屬接觸。首先,在一半導體基板上形成一介電層。在 η電層中形成一接觸開口,以曝露該半導體基板。在接觸 ,口中形成-SixGei_x層,# w<x<1。最後,將一金屬插 基填入該接觸開口之x層上。1304635 ------9Πηΐπ;ρ/[ V. INSTRUCTION DESCRIPTION (2) genus/semiconductor. A low-resistance contact is formed on the I surface, which protects the device from short-channel effects and prevents leakage. It is yet another object of the present invention to provide a low resistance, adjustable contact suitable for use in CMOS devices. To achieve the above object, a semiconductor device of the present invention includes a semiconductor-dielectric layer on the semiconductor substrate having a contact opening exposing the half-body substrate; a SixGei_x layer in which the contact opening is shaped, wherein 0<χ<1; and a metal plug on the 3, (X) X layer, filled in the contact opening. The invention also provides a method to form a two metal contact on the metal/semiconductor interface. Forming a dielectric layer on a semiconductor substrate. A contact opening is formed in the n-electrode layer to expose the semiconductor substrate. In the contact, a -SixGei_x layer is formed in the port, #w<x<1. Finally, a metal is inserted The base is filled in the x layer of the contact opening.
圖式之簡單說明 X 第la至le圖顯示依據本發明第一具體實施例,在金屬 /半導體介面上製造一金屬接觸之製造流程剖面圖。 ,、第2a至2d圖顯示依據本發明第二具體實施例,在金屬 /半導體介面上製造一金屬接觸之製造流程剖面圖,其中 有一可消耗複晶矽層選擇性地形成KSi_Ge層上。 第3a至3e圖顯示依據本發明第三具體實施例,在金屬 /半導體介面上製造一金屬接觸之製造流程剖面圖,其中 有一順應性可消耗複晶矽層形成。 第4a至4e圖顯示依據本發明第四具體實施例製造一BRIEF DESCRIPTION OF THE DRAWINGS X Figures la to le show cross-sectional views of a manufacturing process for fabricating a metal contact on a metal/semiconductor interface in accordance with a first embodiment of the present invention. 2a to 2d are cross-sectional views showing a manufacturing process for fabricating a metal contact on a metal/semiconductor interface in accordance with a second embodiment of the present invention, in which a consumable polysilicon layer is selectively formed on the KSi_Ge layer. Figures 3a through 3e show cross-sectional views of a fabrication process for fabricating a metal contact on a metal/semiconductor interface in accordance with a third embodiment of the present invention, wherein a compliant consumable polysilicon layer is formed. 4a to 4e are diagrams showing the manufacture of a fourth embodiment in accordance with the present invention
Ι3Ό4635 _;_案號91101584_年月曰 修正_ 五、發明說明(3) CMOS的製造流程剖面圖。 第5圖為依據本發明第五具體實施例之CMOS剖面圖。 第6圖為依據本發明第六具體實施例之CMOS剖面圖。 標號之說明 1 0〜半導體基板, 2 0〜介電層, 3 0〜接觸開口, 40 〜SixGe 卜x 層(0<χ<1), 5 0〜金屬層, 5 2〜黏著層, 5 4〜擴散阻障層, 90、92、94〜金屬矽化物層, 6 0〜擴散區, 7 0〜金屬插塞, 8 0、8 2〜可消耗複晶矽層; 1 0 0〜半導體基板, 120〜N井, 140〜P井, 2 2 0〜閘極氧化物, 240〜複晶矽層, 情 610、62 0〜源/汲極區, 2 0 0〜介電層, 3 0 0〜接觸開口, 400〜8^6卜乂層(0<又<1),Ι3Ό4635 _;_Case No. 91101584_年月曰 Correction _ V. Description of invention (3) Cross-section of the manufacturing process of CMOS. Figure 5 is a cross-sectional view of a CMOS according to a fifth embodiment of the present invention. Figure 6 is a cross-sectional view of a CMOS according to a sixth embodiment of the present invention. DESCRIPTION OF REFERENCE NUMERALS 1 0~ semiconductor substrate, 2 0~ dielectric layer, 3 0~ contact opening, 40~SixGe Bu x layer (0<χ<1), 5 0~metal layer, 5 2~adhesive layer, 5 4 ~ diffusion barrier layer, 90, 92, 94 ~ metal telluride layer, 60 0 ~ diffusion region, 7 0 ~ metal plug, 8 0, 8 2 ~ consumable polysilicon layer; 1 0 0 ~ semiconductor substrate, 120~N well, 140~P well, 2 2 0~ gate oxide, 240~polycrystalline layer, 610, 62 0~ source/drain region, 2 0 0~ dielectric layer, 3 0 0~ Contact opening, 400~8^6 divination layer (0<also <1),
0593-6873TWFl;90030;Cathy.ptc 第6頁 1304635 修正 案號 91101584 五、發明說明(4) 5 0 0〜金屬層, 5 2 0〜黏著層, 540〜擴散阻障層, 320、340〜光阻層, 920、940、960〜金屬矽化物層, 630、640〜擴散區, 700〜金屬插塞, 8 0 0、8 2 0〜可消耗複晶石夕層。 發明之詳細敘述0593-6873TWFl;90030;Cathy.ptc Page 6 1304635 Amendment No. 91101584 V. Invention description (4) 5 0 0~ metal layer, 5 2 0~ adhesive layer, 540~ diffusion barrier layer, 320, 340~ light Resistive layer, 920, 940, 960~ metal telluride layer, 630, 640~ diffusion region, 700~ metal plug, 8000, 8 2 0~ consumable polycrystalline stone layer. Detailed description of the invention
Six(^-X2 能帶隙(band gap)範圍為0.67 (x = 〇)至 1.11 eV (x = l)之間。也就是說,sixGeix (0<x<1)之能册 隙能量較純砍為低。 本發明之主要特徵為,在金屬/半導體介面上之一接 觸開口中形成一低能帶隙能量之半導體物質一層 (0<χ<1)。較低的能帶隙能量會降低金屬—半導體X(M^)X^費 米位階(Fermi level),進而降低…介面的SM。較低的、 SBH會降低接觸電阻,於是,適度的摻雜可在金屬/半導體 介面形成良好的接觸。這可以保護裝置不受到短通路效 且不致漏電。 > 〜 首先,第la至le圖顯示依據本發明第一具體實施例, 在金屬/半導體介面上製造一金屬接觸之製造流程圖。 在第la圖中,在一半導體基板10上形成一介電層2〇。 在介電層20中形成一接觸開口3〇,以曝露出半導體基板 10。然後,在接觸開口30中形成一SixGei_x層40 。The six (^-X2 band gap) range is from 0.67 (x = 〇) to 1.11 eV (x = l). That is, the energy of the sixthGeix (0<x<1) is purer. The main feature of the present invention is that a layer of semiconductor material having a low energy band gap energy is formed in one of the contact openings of the metal/semiconductor interface (0<χ<1). Lower band gap energy reduces the metal. —Semiconductor X(M^)X^ Fermi level, which in turn reduces the SM of the interface. Lower, SBH reduces the contact resistance, so moderate doping can form good contact on the metal/semiconductor interface. This protects the device from short path effects and does not leak. > ~ First, the first to elth figures show a manufacturing flow diagram for fabricating a metal contact on a metal/semiconductor interface in accordance with a first embodiment of the present invention. In the first drawing, a dielectric layer 2 is formed on a semiconductor substrate 10. A contact opening 3 is formed in the dielectric layer 20 to expose the semiconductor substrate 10. Then, a SixGei_x layer is formed in the contact opening 30. 40.
1304635 ___ _案號 91101584__年月日_修正_ 五、發明說明(5) 此SixGe^x層40可以各種方法形成,例如MBE (molecular beam epitaxy ;分子束磊晶法),UHV-CVD (ultra-high vacuum chemical vapor deposition ;超高 真空化學氣相沈積法),RT-CVD (rapid thermal CVD ;快 速熱CVD),以及LRP-CVD (limited reaction processing CVD ’限制反應製程cvd)。例如,S LGeh層40可在相當低 溫範圍下(<8〇〇。C)以選擇性磊晶成長法而形成。 3込〇61_5(層40最好是一富矽(以^(:〇11一1^(:^)之3]^(^1 層’其性質與純矽較為相近。這會減少產生差排 (dislocation)的機會。例如,χ最好是在〇· 5<χ<〇· 95的範 圍内。 一以前的報導中指出,比臨界(critical)厚度薄的SiGe 薄層(與其化學計量數和沈積條件有關), ,製程,也不會在石夕基板内產生差排。因此吏=;= 疋lxGei-x層40的厚度應該被控制在小於臨界厚产,以將 其維持在有應變(strained)的狀態下,不致因矽^以以之 間的晶格不相配(lattic mismatch)而引起 排,否則接合面會有漏電。 丞板内之差1304635 ___ _ Case No. 91101584__年月日日_Amendment_ V. DESCRIPTION OF THE INVENTION (5) The SixGe^x layer 40 can be formed by various methods, such as MBE (molecular beam epitaxy), UHV-CVD (ultra) -high vacuum chemical vapor deposition), RT-CVD (rapid thermal CVD), and LRP-CVD (limited reaction processing CVD 'restriction reaction process cvd). For example, the S LGeh layer 40 can be formed by a selective epitaxial growth method at a relatively low temperature range (<8〇〇.C). 3込〇61_5 (layer 40 is preferably a rich 矽 (^^(:〇11一1^(:^)3]^(^1 layer' is similar in nature to pure 。. This will reduce the difference ( The opportunity of dislocation. For example, χ is preferably in the range of 〇·5<χ<〇· 95. A previous report pointed out that a thin layer of SiGe thinner than the critical thickness (with its stoichiometry and deposition) Conditions related), , process, will not produce a difference row in the Shixi substrate. Therefore 吏 =; = 疋 lxGei-x layer 40 thickness should be controlled to be less than critical thickness to maintain it in strain (strained In the state of the state, it is not caused by the lattice mismatch between the two, otherwise there will be leakage on the joint surface.
此SixGei_x層40最好是一有應變的Si G 在半導基板10内的差排。此Si Γρ關/广不會引起 式笙層40之厚度最好是大於 或專於5 nm,且小於或等於3〇 nm。 接著,在第圖中,在SixGeix層4〇上 5〇。例如,此金屬層可由一 #篓 战至屬層 構成,i,ς · r 钻耆層52和一擴散阻障層54所 冓成/、係在SlxGei_x層40上和接觸開口 3〇之側邊上形成。The SixGei_x layer 40 is preferably a differential row of strained Si G within the semiconductor substrate 10. This Si Γρoff/wide does not cause the thickness of the germanium layer 40 to be preferably greater than or exclusively for 5 nm and less than or equal to 3 〇 nm. Next, in the figure, on the SixGeix layer 4〇5〇. For example, the metal layer may be composed of a 篓 至 warfare layer, i, ς r 耆 耆 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 Formed on.
1304635 案號 91101584 曰 修正 五、發明說明(6) 此黏著層52可為鈦(Ti)層,其對於介電層20有良好黏著 性。擴散阻障層54可為一TiN層,用以保護半導體矽基板 10不會在後鈦沈積製程(post tungsten deposition P r o c e s s )中受到氟的攻擊。或者,此黏著/擴散阻障層亦 可為W/WN層。 接著,在第1 c圖中,將一摻質佈植入金屬層5 〇和 SixGei_x層40内。此佈植可在低能量(1〇〇 eV至1〇 KeV)和低 劑量(1E14原子/cm2至1E15原子/cm2)之下進行,或者可 在高能量(20 KeV至80 KeV)和低劑量(5E14至3E15原子 /cm2)之下進行。或者,此佈植可以離子混合法進行。亦 即,首先,進行低能量(1〇〇 eV至丨〇 KeV)和高劑量(1E15 至1E16原子/cm2)的佈植,然後,進行高能量(2〇 Kev至 8 0 KeV)和低劑量(5E1 3至5E14原子/cm2)的佈植。此低能 里 '南劑置佈植可以PLAD (plasma doping ;電漿摻雜)或 ΡΙΠ (plasma ion immersion implantation ;電漿離子 沈浸佈植)來進行。此高能量、低劑量佈植可以傳統束—線 HI (beam-line ion implantation)來進行。 接著’在第Id圖中,進行退火以將金屬層50轉變為金 屬石夕化物層90 ’ 且以SADS (salicide as a doping source ;以金屬矽化物作為摻雜源)的方式將摻質擴散入 半導體基板10内,以形成一擴散區6〇。由圖中可看出,一 4为的S ix Ge1-X層4 0被消耗,而形成金屬矽化物層9 〇。於 是’ SixGei_x層40變薄,對於SixGei χ層4〇的SM有負面影 響。因此’可形成一較厚的SixGei x層4〇,例如,大於3〇1304635 Case No. 91101584 修正 Amendment 5. Invention Description (6) The adhesive layer 52 may be a titanium (Ti) layer which has good adhesion to the dielectric layer 20. The diffusion barrier layer 54 can be a TiN layer to protect the semiconductor germanium substrate 10 from attack by fluorine in the post tungsten deposition process (post tungsten deposition P r o c e s s ). Alternatively, the adhesion/diffusion barrier layer can also be a W/WN layer. Next, in Figure 1c, a dopant cloth is implanted into the metal layer 5 and the SixGei_x layer 40. This implant can be performed at low energy (1〇〇eV to 1〇KeV) and low dose (1E14 atoms/cm2 to 1E15 atoms/cm2), or at high energy (20 KeV to 80 KeV) and low dose. It is carried out under (5E14 to 3E15 atoms/cm2). Alternatively, the planting can be carried out by ion mixing. That is, first, low-energy (1〇〇eV to 丨〇KeV) and high-dose (1E15 to 1E16 atoms/cm2) are implanted, and then high energy (2〇Kev to 80 keV) and low dose are performed. (5E1 3 to 5E14 atoms/cm2). This low-energy 'Southern planting can be carried out by PLAD (plasma doping; plasma doping) or ion (plasma ion immersion implantation). This high-energy, low-dose implant can be performed by conventional beam-line ion implantation (HI). Then, in the first Id diagram, annealing is performed to convert the metal layer 50 into the metallization layer 90' and the dopant is diffused into the SADS (salicide as a doping source) Inside the semiconductor substrate 10, a diffusion region 6A is formed. As can be seen from the figure, the Si ix Ge1-X layer 40 of a 4 is consumed to form a metal telluride layer 9 〇. Thus, the SixGei_x layer 40 is thinner and has a negative impact on the SM of the SixGei layer. Therefore, a thicker SixGei x layer 4 〇 can be formed, for example, greater than 3 〇
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nm以補彳貝在矽化製程中所消耗的部分。於是,仍然可以 遠下^夠厚的SixGei X層4〇,而可維持低SBII。 最後’在第1e圖中,將一金屬插塞70填入接觸開口 30 2之金屬層50上。例如,以選擇性鎢沈積法形成一鎢層。 ;、、、'後,進行化學機械研磨法(CMp)以使鎢層平坦化,且除 去在介電層20上之金屬層5〇。 、第2a至2d圖顯示依據本發明第二具體實施例,在一金 屬/半胃導體介面上製造一金屬接觸之製造流程圖。和第一 具體貫施例不同的是,此具體實施例選擇性地在si —Ge層Nm is used to supplement the part consumed by the mussel in the purification process. Thus, it is still possible to go down to the thick enough SixGei X layer to maintain the low SBII. Finally, in Figure 1e, a metal plug 70 is filled into the metal layer 50 of the contact opening 30 2 . For example, a tungsten layer is formed by selective tungsten deposition. After that, the chemical mechanical polishing method (CMp) is performed to planarize the tungsten layer, and the metal layer 5 on the dielectric layer 20 is removed. Figures 2a through 2d show a manufacturing flow diagram for fabricating a metal contact on a metal/semi-gastric conductor interface in accordance with a second embodiment of the present invention. Unlike the first specific embodiment, this embodiment is selectively in the si-Ge layer.
上形成一可消耗的複晶矽層。標號和第丨a至丨e圖相同者代 表相同的元件。 在第2a圖中,在一半導體基板1〇上形成一介電層2〇。 在介電層20中形成一接觸開口3〇,以曝露出半導體基板 1 0。然後,在接觸開口 30中形成一siGeh層40 (0<χ<1)。 然後’僅在SixGei-x層40上形成一可消耗複晶矽層go。 接著’在第2b圖中,在可消耗複晶矽層8〇上形成一金 屬層5 0。例如,此金屬層可由一黏著層5 2和一擴散阻障層 5 4所構成’其係在可消耗複晶石夕層8 〇上和接觸開口 3 〇之側 邊上形成。此黏者層52可為欽(Ti)層,而擴散阻障層54可 為一 T i N層。接著,將一摻質佈植入金屬層$ 〇,可消耗複《, 晶矽層80,和SixGe^層40中。佈植條件可和第一具體實施 例中所述者相同。 接著,在第2c圖中,進行退火以將金屬層50轉變為金 屬石夕化物層92,且以SADS的方式將摻質擴散入半導體基板A consumable layer of polycrystalline germanium is formed thereon. The same reference numerals as in the drawings 丨a to 丨e denote the same elements. In Fig. 2a, a dielectric layer 2 is formed on a semiconductor substrate 1A. A contact opening 3 is formed in the dielectric layer 20 to expose the semiconductor substrate 10. Then, a siGeh layer 40 (0<χ<1) is formed in the contact opening 30. Then, a consumable polysilicon layer go is formed only on the SixGei-x layer 40. Next, in Fig. 2b, a metal layer 50 is formed on the consumable polysilicon layer 8A. For example, the metal layer may be formed by an adhesive layer 52 and a diffusion barrier layer 504 which are formed on the side of the consumable polycrystalline layer 8 and on the side of the contact opening 3 . The adhesive layer 52 can be a Ti (Ti) layer, and the diffusion barrier layer 54 can be a TiN layer. Next, a doped cloth is implanted into the metal layer $ 〇, which can be used in the composite layer, the germanium layer 80, and the SixGe layer 40. The planting conditions can be the same as those described in the first embodiment. Next, in FIG. 2c, annealing is performed to convert the metal layer 50 into the metal-lithium layer 92, and the dopant is diffused into the semiconductor substrate in the form of SADS.
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1 〇内,以形成一擴散區60。由圖中可看出,一部分可消耗 複晶矽層80被消耗,而形成金屬矽化物層”。於是,在矽 化步驟中,是可消耗複晶矽層8〇而非SixGe“層4〇被消耗。 廷可維持SixGei_x層40的完整性,不會使變薄, 因而可維持低SBH。為了使得可消耗複晶矽層8〇在矽化步 驟中被消耗,而不會消耗,可消耗複晶矽層8〇 必須夠厚’其厚度是好是10 _至5〇 nm之間。1 inside the crucible to form a diffusion zone 60. As can be seen from the figure, a portion of the consumable polysilicon layer 80 is consumed to form a metal germanide layer. Thus, in the deuteration step, the polycrystalline germanium layer 8 is consumed instead of the SixGe layer 4 Consumption. Ting can maintain the integrity of the SixGei_x layer 40 without thinning, thus maintaining a low SBH. In order for the consumable polysilicon layer 8 to be consumed in the deuteration step without being consumed, the depleted polylayer layer 8 must be thick enough that its thickness is preferably between 10 _ and 5 〇 nm.
隶後’在第2d圖中,將一金屬插塞填入接觸開口3〇 内之金屬層5 0上。例如,以選擇性鎢沈積法形成一鎢層。 然後’進行化學機械研磨法(CMp)以使鎢層平坦化,且除 去在介電層20上之金屬層5〇。 第3a至3e圖顯示依據本發明第三具體實施例在一金屬 /半導體介面上製造一金屬接觸的製造流程圖。和第一具 體實施例不同的是,此具體實施例係在SixGei x層上形成一 順應性可消耗複晶石夕層。標號和第1 a至1 e圖相同者代表相 同的元件。 在第3a圖中,在一半導體基板10上形成一介電層20。 在介電層20中形成一接觸開口3〇,以曝露出半導體基板 10。然後,在接觸開口 30中形成一SixGe^層40 (0<χ<1)。 然後,在SixGe^層40上和接觸開口 30之側邊上順應性地形 成一可消耗複晶矽層8 2。In the second drawing, a metal plug is filled in the metal layer 50 in the contact opening 3A. For example, a tungsten layer is formed by selective tungsten deposition. Then, a chemical mechanical polishing method (CMp) is performed to planarize the tungsten layer, and the metal layer 5 on the dielectric layer 20 is removed. Figures 3a through 3e show a manufacturing flow diagram for fabricating a metal contact on a metal/semiconductor interface in accordance with a third embodiment of the present invention. In contrast to the first specific embodiment, this embodiment forms a compliant consumable polycrystalline layer on the SixGei x layer. The same reference numerals as in Figures 1 a to 1 e represent the same components. In Fig. 3a, a dielectric layer 20 is formed on a semiconductor substrate 10. A contact opening 3 is formed in the dielectric layer 20 to expose the semiconductor substrate 10. Then, a SixGe layer 40 (0<χ<1) is formed in the contact opening 30. Then, a consumable polysilicon layer 8 2 is conformally formed on the side of the SixGe layer 40 and the side of the contact opening 30.
接著,在第3b圖中,在可消耗複晶矽層82上形成一金 屬層5 0。例如,此金屬層可為一擴散阻障層,例如T i N 層。Next, in Fig. 3b, a metal layer 50 is formed on the consumable polysilicon layer 82. For example, the metal layer can be a diffusion barrier layer, such as a TiN layer.
1304635 ΛΜ 91101584 年 月 曰 五、發明說明(9) 曰曰 接著’在第3c圖中,將一摻質佈植入金屬層5〇,複 石夕層82,和SixGei_x層40中。佈植條件可和第一具體實施例 中所述者相同。 接者’在弟3d圖中’進行退火以將金屬層5〇轉變為金 屬矽化物層94,且以SADS的方式將摻質擴散入半導體基 板10内,以形成一擴散區60。由圖中可看出,一部分可消 耗複晶矽層82被消耗,而形成金屬矽化物層94。於是,在 石夕化步驟中,是可消耗複晶矽層82而非被消 耗。這可維持SixGe^層40的完整性,不會使SixGei_x層40變 薄’因而可維持低SBH。為了使得可消耗複晶矽層82在矽 化步驟中被消耗,而不會消耗SixGei_x層4〇,可消耗複晶矽 層82必須夠厚,其厚度是好是10 nm至50 nm之間。 最後’在第3e圖中,將一金屬插塞70填入接觸開口 30 内之金屬層5 0上。例如,以選擇性鎢沈積法形成一鎢層。 然後’進行化學機械研磨法(CMP)以使鎢層平坦化,且除 去在介電層20上之金屬層5〇。 在此具體實施例中,可消耗複晶矽層82為順應性地形 成’亦即,其係形成於SixGei_x層40上和接觸開口 30之側邊 上。由於複晶矽層對於介電層2 〇而言是一良好的黏著層, 因此可省去鈦層或其他對於ILd (inter layer dielectric)之黏著層,如此可節省製造成本。 本發明之金屬接觸可很容易地與CM〇s裝置整合在一 起。第4a至4e圖顯示依據本發明第四具體實施例製造CMOS 之製造流程。在第4a圖中,藉由在每個井區域選擇性植入1304635 ΛΜ 91101584 月 、 发明 发明 发明 、 、 、 、 、 、 、 、 、 、 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 曰曰 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 The planting conditions can be the same as those described in the first embodiment. The picker is annealed in the 3D view to convert the metal layer 5 turns into the metal telluride layer 94, and the dopant is diffused into the semiconductor substrate 10 in a SADS manner to form a diffusion region 60. As can be seen, a portion of the consumable polysilicon layer 82 is consumed to form a metal halide layer 94. Thus, in the Shi Xihua step, the polycrystalline germanium layer 82 is consumed rather than being consumed. This maintains the integrity of the SixGe(R) layer 40 without thinning the SixGei_x layer 40' thus maintaining a low SBH. In order to cause the consumable polysilicon layer 82 to be consumed in the deuteration step without consuming the SixGei_x layer 4, the consumable polysilicon layer 82 must be thick enough to have a thickness between 10 nm and 50 nm. Finally, in Fig. 3e, a metal plug 70 is filled into the metal layer 50 in the contact opening 30. For example, a tungsten layer is formed by selective tungsten deposition. Then, a chemical mechanical polishing (CMP) is performed to planarize the tungsten layer, and the metal layer 5 on the dielectric layer 20 is removed. In this embodiment, the consumable polysilicon layer 82 is conformally formed, i.e., it is formed on the SixGei_x layer 40 and on the side of the contact opening 30. Since the polysilicon layer is a good adhesion layer for the dielectric layer 2, the titanium layer or other adhesion layer for the ILd (inter layer dielectric) can be omitted, which can save manufacturing costs. The metal contacts of the present invention can be easily integrated with the CM〇s apparatus. Figures 4a through 4e show a manufacturing process for fabricating a CMOS in accordance with a fourth embodiment of the present invention. In Figure 4a, by selective implantation in each well region
0593-6873TWF1;90030;Cathy.ptc 第12頁 1304635 __案號 91101584_年月 曰__ 五、發明說明(10) 適當的摻質,而在一半導體基板100中形成分離的N井120 和P井1 40。然後,形成淺溝槽隔離區(STI),以隔離主動 元件區’場效電晶體(F E T )係設於主動元件區内。然後, 成長一熱氧化物,以形成一閘極氧化物2 2 0。然後,形成 一複晶石夕層2 4 0 ’以構成N通道和P通道J? e T s的閘極構造。 然後’分別在N井1 2 0内形成源/汲極區6 1 〇,在p井1 4 〇内形 成源/汲極區62 0。 接著’在半導體基板1 0 0上形成—1电滑z u u ▽ # 句 層2 0 0内形成連接源/汲極區610和620之接觸開口 3 〇 q,以 曝露出半導體基板1 00。然後,在接觸開口 300内形成一 8込〇6卜叉層 40 0 ( 0<χ<1) 〇 接著,在S ix G 層4 0 0上形成一金屬層$ 〇 〇。例如,此 金屬層可由一黏著層5 2 0和一擴散阻障層5 4 〇所構成,其係 在SixGe^x層400上和接觸開口 30 0之側邊上形成。此黏著層 520可為鈦(Ti)層,其對於介電層2〇〇有良好黏著性 <。擴I 阻障層540可為一TlN層,用以保護半導體石夕基板ι〇〇不會 在後鈦沈積製程中受到I的攻擊。或者,此黏 障層亦可為W/WN層。 〃 接著,在第4b圖中,形成一光阻層32〇以 區。然後使半導體基板1〇〇進行佈植,亦即,將p % (如硼或氟化硼)佈植入N井120區中的" 層40〇中。 "·中的金屬層500和SixGei_x 接者,在弟4c圖中,形成一光M 、> 區。然後使半導體基板100進行佈植,曰 Ί蔽N井1 (如砷或磷)佈植入P井140區中的全屬声^ :型摻質 -----和“πΑ-χ 層 4〇〇0593-6873TWF1; 90030; Cathy.ptc Page 12 1304635 __ Case No. 91101584_年月曰__ V. Description of Invention (10) Proper doping, and forming a separate N well 120 in a semiconductor substrate 100 and P well 1 40. Then, a shallow trench isolation region (STI) is formed to isolate the active device region 'field effect transistor (F E T ) from the active device region. Then, a thermal oxide is grown to form a gate oxide 2 2 0. Then, a polycrystalline layer 2 4 0 ' is formed to constitute a gate structure of the N channel and the P channel J? e T s . Then, the source/drain region 6 1 形成 is formed in the N well 1 2 0, and the source/drain region 62 0 is formed in the p well 14 4 分别. Next, a contact opening 3 〇 q connecting the source/drain regions 610 and 620 is formed on the semiconductor substrate 100 to form a contact opening 3 〇 q of the source/drain regions 610 and 620 to expose the semiconductor substrate 100. Then, an 8 込〇 6 yoke layer 40 0 is formed in the contact opening 300 ( 0< χ < 1) 〇 Next, a metal layer $ 〇 形成 is formed on the S ix G layer 400. For example, the metal layer may be formed of an adhesive layer 520 and a diffusion barrier layer 5 4 , formed on the SixGe^x layer 400 and on the side of the contact opening 30 0 . The adhesive layer 520 may be a titanium (Ti) layer which has good adhesion to the dielectric layer 2 &. The expanded barrier layer 540 can be a T1N layer to protect the semiconductor substrate from attack by I during the post-titanium deposition process. Alternatively, the barrier layer can also be a W/WN layer. 〃 Next, in Figure 4b, a photoresist layer 32 is formed. The semiconductor substrate 1 is then implanted, i.e., a p% (e.g., boron or boron fluoride) cloth is implanted into the "layer 40" in the N-well 120 region. The metal layer 500 and the SixGei_x connector in "·, in the figure 4c, form a light M, > region. Then, the semiconductor substrate 100 is implanted, and the N-well 1 (such as arsenic or phosphorous) cloth is implanted into the P-well 140 region of the entire sound-mode type dopant---- and "πΑ-χ layer 4 〇〇
0593.6873TWFl;90030;Cathy.pt0593.6873TWFl;90030;Cathy.pt
第13頁Page 13
1304635 案號 91101584 曰 修」 五、發明說明(Π) 中 〇 接著,在第4d圖中,進行退火以將金屬層5〇〇轉變為 金屬石夕化物層9 2 0,且以S A D S的方式將掺質擴散入半導體 基板100内,以在N井120内之源/沒極區βίο内形成一擴散 區630,以及在P井140内之源/汲極區620内形成一擴散區 640 ° 最後’在第4 e圖中,將一金屬插塞7 〇 〇填入接觸開口 3 0 0内之金屬層5 0 0上。例如,以選擇性鎢沈積法形成一鎢 層。然後,進行化學機械研磨法(CMP )以使鎢層平坦化, Φ 且除去在介電層200上之金屬層5 0 0。 弟5圖顯不依據本發明弟五具體貫施例之c μ 〇 s音ιΐ面 圖。此CMOS構造和第四具體實施例大致相同,但此具體實 施例多了一層,在Si-Ge層400和金屬層500之間多長了一 層選擇性 者代表相 圖之CMOS 至2d圖。 耗,以形 可消耗複 SixGei—x 層 SBH ° 現在 之CMOS咅丨J 但此具體 間多形成 的可消耗複晶石夕層8 0 0。標號和第4 a至4 e圖相同 同的元件。製造第5圖之CMOS的步驟和製造第4e 的步驟類似,因此在此不多贅言。請亦參考第2a 如上所述,一部分之可消耗複晶矽層8 〇 〇被消 成金屬石夕化物層9 4 0。於是,在石夕化步驟中,是 晶石夕層8 0 0而非S ix G 層4 0 0被消耗。這可維持 4 0 0的完整性,而不會使其變薄,因而可維持低 參考第6圖,其顯示依據本發明第六具體實施例 面圖。此CMOS構造和第四具體實施例大致相同, 實施例多了一層,在Si-Ge層400和金屬層500之 了順應性的可消耗複晶矽層820。標號和第4a至1304635 Case No. 91101584 曰修” V. INSTRUCTION DESCRIPTION (Π) 〇 Next, in Figure 4d, annealing is performed to convert the metal layer 5〇〇 into a metal lithium layer 9 2 0, and in the form of SADS The dopant diffuses into the semiconductor substrate 100 to form a diffusion region 630 in the source/nothing region βίο in the N well 120, and a diffusion region 640° in the source/drain region 620 in the P well 140. In Fig. 4e, a metal plug 7 is filled into the metal layer 500 in the contact opening 300. For example, a tungsten layer is formed by selective tungsten deposition. Then, a chemical mechanical polishing (CMP) is performed to planarize the tungsten layer, Φ and remove the metal layer 500 on the dielectric layer 200. The figure 5 is not based on the c μ 〇 s sound ΐ plan of the specific embodiment of the present invention. This CMOS construction is substantially the same as the fourth embodiment, but this embodiment has one more layer, and a layer of selectivity between the Si-Ge layer 400 and the metal layer 500 is represented by a CMOS to 2d diagram representing the phase diagram. Consumption, shape, consumption, complex, SixGei-x layer, SBH °, now CMOS咅丨J, but this is more than a consumable polycrystalline stone layer 800. The numbers are the same as those of Figures 4a through 4e. The steps of manufacturing the CMOS of Fig. 5 are similar to the steps of manufacturing the 4e, and therefore there is no mention here. Please also refer to Section 2a. As described above, a portion of the consumable polysilicon layer 8 〇 is destroyed by the metallurgical layer 940. Thus, in the Shi Xihua step, the spar layer 800 is used instead of the S ix G layer 400. This maintains the integrity of the 400 without thinning and thus maintains a low reference Fig. 6, which shows a sixth embodiment of the present invention. This CMOS construction is substantially the same as the fourth embodiment, and the embodiment has an additional layer of a consumable compensable polysilicon layer 820 in the Si-Ge layer 400 and the metal layer 500. Label and 4a to
0593-6873曹l;90030;Cathy.ptc 第14頁 修正一 1304635 五、發明說明(12) 4e圖相同者代表相同的元件。製造第6圖之CM0S^^步驟和 製造第4e圖之CMOS的步驟類似,因此在此不多資吕。请亦 參考第3a至3e圖。如上所述,一部分之邛消耗複晶石夕層 820被消耗,以形成金屬矽化物層9 60。於是,在石夕化步驟 中,是可消耗複晶矽層820而非SixGe^層4 0 0被消耗。這可 維持SixGei_x層40 0的完整性,而不會使其變薄,因而可維0593-6873 曹l;90030;Cathy.ptc Page 14 Amendment 1304635 V. Description of Invention (12) The same figure in Figure 4e represents the same component. The steps of manufacturing the CM0S^^ of Fig. 6 are similar to the steps of manufacturing the CMOS of Fig. 4e, and therefore there is no need for more. Please also refer to Figures 3a to 3e. As described above, a portion of the ruthenium-consuming cermet layer 820 is consumed to form a metal ruthenide layer 960. Thus, in the Shi Xihua step, the consumable polysilicon layer 820 is consumed instead of the SixGe layer 40. This maintains the integrity of the SixGei_x layer 40 0 without thinning it, thus enabling dimensionality
持低SBH。再者,在此具體實施例中,可消耗複晶矽層820 是順應性地形成的,亦即,其係形成於S ixGe^層4 0 0上和 接觸開口 3 0 0之側邊上。由於複晶矽層對於介電層2 〇 〇而言 是良好的黏著層,因此可省去鈦層或對於ILD之其他黏著 層。這可節省製造成本。 雖然本發明已以較佳實施例揭露如上,然其並非用以 :制本發明,任何熟習此項技藝者,纟不脫離:發日 砷和範圍内,當可做更動與潤飾,因此本發明二 當以後附之申請專利範圍所界定者為準。 ”叹巳圍Hold low SBH. Moreover, in this embodiment, the consumable polysilicon layer 820 is formed conformally, that is, it is formed on the side of the S ixGe^ layer 400 and the contact opening 300. Since the polysilicon layer is a good adhesion layer for the dielectric layer 2, the titanium layer or other adhesion layer for the ILD can be omitted. This saves manufacturing costs. Although the present invention has been disclosed in the above preferred embodiments, it is not intended to be used in the practice of the present invention, and the skilled artisan will not depart from the arsenic and the scope of the invention, and may be modified and retouched, thus the present invention. 2. The date defined in the attached patent application shall prevail. "Sighing
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| TWI564995B (en) * | 2014-07-01 | 2017-01-01 | 台灣積體電路製造股份有限公司 | Semiconductor device and method of forming contact structure |
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| TWI564995B (en) * | 2014-07-01 | 2017-01-01 | 台灣積體電路製造股份有限公司 | Semiconductor device and method of forming contact structure |
| US9620601B2 (en) | 2014-07-01 | 2017-04-11 | Taiwan Semiconductor Manufacturing Company, Ltd. | Contact structures and methods of forming the same |
| US9859390B2 (en) | 2014-07-01 | 2018-01-02 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method for silicide formation |
| US10263088B2 (en) | 2014-07-01 | 2019-04-16 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method for silicide formation |
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