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TWI304092B
TWI304092B TW94131936A TW94131936A TWI304092B TW I304092 B TWI304092 B TW I304092B TW 94131936 A TW94131936 A TW 94131936A TW 94131936 A TW94131936 A TW 94131936A TW I304092 B TWI304092 B TW I304092B
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Taiwan
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weight
parts
surfactant
hydrocarbon
alcohol
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TW94131936A
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Chinese (zh)
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TW200712195A (en
Inventor
Mao Sheng Lee
Jian-Ming Zhao
Yan-Zhi Wu
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New Modern Co Ltd
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1304092 九、發明說明: 【發明所屬之技術領域】 本發明係有關-種車用燃料,更具體的說,本發 - 一種車用醇烴燃料組合物。 系百關 . 【先前技術】 曱醇氧分子含量高達50% (汽車氧分子含量為〇) 度52米/秒(M/S)(汽油38M/S),甲醇燃燒熱值只有 半,甲醇與碳氫化合物(烴)燃料混合後,在汽虹中雜 於燃燒速賴’發動機汽缸平均纽壓力比使用汽油提g,因 此使用相同的量,汽車跑的路程與使用汽油相同。 曱极煤、天然氣生麵產品,丨· 5〜L 8爾可製i嘴甲 成本比汽油低的多’價格只有9〇號汽油概左右。輕炉 (丁烧、戊烧、己烧混合煙)是石化煉薇副產品,因辛烧 快,故不能直接作為車用汽油使用。如何將::石 S;;質烴組合’使她 【發明内容】 本,明需姨㈣顯_《侧—轉麟烴燃料組 口物^^服現有技術存在的缺陷。滿足有關領域發展的需要。 本發明的技術構思是這樣的: 本發明設想將無水f喊無水乙醇、迪(了烧、戍烧、 - ,以提高燃料的燃燒熱值和抗爆性能,又可節 期Γ很有^也可降低尾氣污染的排放,在石油資源緊張時 一本發明的相醇烴燃料組合物,組合的重量份: 輕經(丁燒、戊烧、己烧混合烴)100重量份 甲醇或乙醇 3-30重量份 1304092 助溶劑 3-15重量份 陽離子氟碳表面活性劑 0· 004〜0· 04重量份 其中的輕烴(丁烷、戊烷、己烷混合烴)是石化煉廠的副 產拔頭油’ 180#溶劑油,C5組分等產品,例如天然氣凝析油 分離出來的戊烷餾分; 其中的助;谷劑選自甲基第三丁基醚(jjjdhyl krf — ether’ MTBE)、甲基弟二戊基醚(methy 1 tertamyi fflethyl ether)、第三丁基醇(tert—butyi alc〇h〇1、TBA)或異丁醇 (iso-butanol)甲苯、二甲苯等中的一種; MTBE、TAME、TBA是優良的汽油抗爆劑、異丁醇是助溶劑 亦可改善汽油的蒸發性能。曱苯、二甲苯既是助溶劑,也是辛 烷值,燃燒熱值改進劑。 其中的無水曱醇必須採用99· 5重量%以上的無水甲醇,其 產如來源於煤炭或天然氣,經脫除水份處理,無水曱醇為人類 期待之未來能源之一。 無水甲醇或無水乙醇相對於100重量份的輕烴(丁烧、戍 - 烧、己烧混合烴)’添加量為3_30重量份,其添加量系依據所 - 使用_烴的辛雌(_)而定。例如輕煙的辛錄⑽) 是84 ’無水曱醇的辛烧值⑽N)是13〇 ;無水曱醇使用15重 量份添加助溶劑MTBE 5重量份與丁烷,輕烴(丁烷、戊烷、 己烧混合煙)80重量份,可以得到曱醇輕烴燃料的辛烧值(_ 1304092 為90,-般適合發動機壓縮比為9 〇:ι以下汽車使用,替代 90號汽油。 再者甲醇2〇重里份,混合輕烴π重量份 ,混合MTBE 5 重里伤’其辛烧值為93單位,適合發動機壓縮比為9· 3:1以 下汽車使用’替代93號汽油。無水甲醇25重量份,添加助溶 劑MTBE 5重量份,混合輕烴7〇重量份,其辛烧值為邪單位, 適合發動機壓縮比為9. 5:1汽車使用,替代95號汽油。無水 情重量份30 ’添加助溶劑5重量份,混合輕_重量份, 其辛烧值在97 ’適合發動缝縮比9. 5:卜㈣發動機使用, 替代97號南標準汽油。 由於無水甲醇或無水乙醇與輕煙(丁烧、戊烧、己燒混合 烴)在常溫下均能互溶,在互溶後容易分層,特別是當氣溫低 於15C4 ’互溶性差’針對這項缺點,可以使用氣碳表面活 性劑、該劑具有既親水又親油的特性,擴散性極強,且均勻的 附著在f醇與石炭氫化合物(烴、芳烴)分子的界面,並在金屬 與橡聲表面形成-層較薄的膜,有較強的防腐餘、防錄和抗磨 效果;必要時使用助溶劑來解決此項問題。而無水曱醇或無水 乙醇與!總在氣溫15°C以上時,互溶性較好,因此需減少助 溶劑添加量。相對於100重量份的輕烴(丁院、戊烧、己烧混 合烴)’助溶劑使用0-25重量份亦可,當溫度較高時,不必添 加助溶劑即可達成目的。 1304092 其中的氟碳表面活性劑為氟烷基胺鹽或季銨鹽陽離子氟 碳表面活性劑,選自式(1)、(2)或(3)中的一種或其混合 物·· (1) 含氟烷基胺季銨鹽陽離子氟碳表面活性劑: (CFa) 2CF (CF2) 6CH2CH (OH) CH2N+ (CHs) 3Γ (2) 全氟烷基醯胺季銨鹽陽離子氟碳表面活性劑: C7F15CONH (CH2) sN+ (CH3) 3Γ (3) 氟烧基胺鹽陽離子氟碳表面活性劑: (F (CF2) sCH (OH) CH2] 2NCH2CH2NH2 · H2SO4 相對於100重量份的輕烴(丁烷、戊烷、己烷混合烴), 氟碳表面活性劑的添加量為〇 〇〇4至〇 〇4重量份,較佳為 0· 006重量份。在本發明中,(丨)氟烷基胺季銨鹽陽離子氟碳 表面活性劑、(2)全氟烷基醯胺季銨陽離子氟碳表面活性劑、 (3)氟烧基胺鹽型%離子敦碳表面活性劑,可以擇一使用或混 合使用。 上海地區的氟碳表面活性劑商品「馬π力威(MARAVILLA)」 可使用於本發明,其系上海文景精細化工有限公司出品,1〇〇 重I伤的丁烧、戊烧、己烧混合的輕烴,馬叻威(MARAVILLA) 之添加量為〇· 004至0· 04重量份,較佳為〇· 〇〇β重量份。 本發明之車用醇烴燃料之配制方法,包括有下列步驟: 將氟碳表面活性劑、助溶劑例如ΜΤΒΕ、TAME、ΤΒΑ或甲 1304092 句二Γ 擇—使用’加入無柯醇或無水乙醇均 、=::用再與這當用量的輕_、戊貌、已合烴) 而成車用醇烴燃料。 本發明產品為-種高熱值高辛紐_),成本低、盈腐 純磨_汽車清潔替代燃料。使用時尾氣污染的排放降 低,疋一種尚效、節能,對環境友好的汽車替代新能源。此種 繼源符合世界保護地球魏的铸預定書的要求又符合目 別世界此源的多疋化’其利用石化煤油場利用價值較低的副產 原料,利用本專利加以處理後,即可成為汽車使用並可以節省 .汽車燃料費用的支出’是―有利於地球魏人類絲生存空 間,更是一項利國利民的新發明。 【實施方式】 所作之Γ細方法’應用原理,作用與功效,則請參下列 所作之§兄明,即可得到完全的了解。 _ 實施例1 C1)輕烴(丁烷、戊烷、己烷混合烴) 70重量份 (2)無水曱醇 15重量份 (3)曱笨(或二甲苯) 10重量份 (4)甲基第三丁基醚([BE) 5重量份 (5XCF3)2CF(CF2)6CH 2CH (0H)CH2N+(CH3)3r 0. 006重量份 以上組分(2)無水曱醇、(3)MTBE和(4)氟碳表面活性劑混 合均勻,再加入組分(1)輕烴(丁烷、戊烷、己烷混合烴)共同 1304092 期&成辛烧值(麵)為93個單位的車用雜烴燃料產品。 ★在本__财巾,組分⑸為含氟絲鱗銨鹽型陽 • 離作碳絲·劑,其他可以改用為全魏細胺季銨陽離 2NCH2CH2NH2 · Η$〇4。組分(4)MTBE 可以使用異丁 醇、TAB 或 TAME 替代的。 實施例2 (1)輕烴(丁烷、戊烷、己烷混合烴) 50重量份 (2)無水甲醇 25重量份 (3)曱苯 20重量份 ⑷甲基第三丁基ϋ(ΜΤΒΕ) 5重量份 ⑸ C7Fi5CONHC3H6lf(CH3 )3 Γ 0. 008重量份 在本貫加例配方的操作方式如同前述第1實施配方,將組 分(1)、(2)、(3)、(4)、(5)共同調配成辛烷值(R0N)為93個 單位的車用醇烴燃料產品,再本實施利的配方中,組成為一種 全氟烧基胺季銨陽離子氟碳表面活性劑,其還可以政用含氟 烷基安季銨基型陽離子氟碳表面活性劑(參照前述第丨實施例 配方的組分(5)),或者,改用氟烷基胺鹽陽離子氟碳表面活性 子氣碳表面活性劑,例如他C0_H2M+(CH3)3r ;或者氟烧 基胺鹽型陽離子I碳表面活性〜例如(F(㈤頌⑽既)1304092 IX. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a vehicle fuel, and more particularly to a vehicle alcohol fuel fuel composition. Department of Baiguan. [Prior Art] sterol oxygen molecular content up to 50% (automotive oxygen molecular content is 〇) degree 52 m / s (M / S) (gasoline 38M / S), methanol combustion heat value is only half, methanol and After the hydrocarbon (hydrocarbon) fuel is mixed, the average engine pressure in the steam engine is higher than that of the engine cylinder. Therefore, the same amount is used, and the car runs the same distance as the gasoline. Bungee coal, natural gas noodle products, 丨·5~L 8 er can be made into a mouthpiece. The cost is much lower than that of gasoline. The price is only about 9 汽油. The light furnace (dibutyl, pentyl, and burned) is a by-product of petrochemical refining. Because it burns quickly, it cannot be used directly as motor gasoline. How to:: Stone S;; Hydrocarbon combination 'to make her 【Inventive content】 Ben, Ming needs 姨 (four) _ _ side-to-the-carbon hydrocarbon fuel group ^ ^ service defects in the existing technology. Meet the needs of the development of related fields. The technical idea of the present invention is as follows: The present invention contemplates that anhydrous f is called anhydrous ethanol, di (burning, simmering, - to improve the combustion heat value and antiknock performance of the fuel, and it is also possible to save the festival) The exhaust gas pollution can be reduced, and the petroleum alcohol fuel composition of the invention is in the case of a shortage of petroleum resources, and the combined parts by weight: light by weight (butadiene, pentane, and calcined mixed hydrocarbon) 100 parts by weight of methanol or ethanol 3- 30 parts by weight 1304092 cosolvent 3-15 parts by weight of cationic fluorocarbon surfactant 0· 004~0·04 parts by weight of light hydrocarbons (butane, pentane, hexane mixed hydrocarbon) is a by-product of petrochemical refinery Head oil '180# solvent oil, C5 component and other products, such as pentane fraction separated by natural gas condensate; the help; the granule is selected from methyl tert-butyl ether (jjjdhyl krf - ether ' MTBE), One of methim 1 tertamyi fflethyl ether, tert-butyl alcohol (tert-butyi alc〇h〇1, TBA) or isobutanol toluene, xylene, and the like; MTBE, TAME, TBA are excellent gasoline antiknock agents, isobutanol is a cosolvent or a solvent Evaporation performance of good gasoline. Benzene and xylene are both cosolvents and octane number, combustion calorific value improver. The anhydrous decyl alcohol must be more than 99.5% by weight of anhydrous methanol, which is derived from coal or Natural gas, treated with water removal, anhydrous decyl alcohol is one of the future energy sources expected by humans. Addition of anhydrous methanol or absolute ethanol relative to 100 parts by weight of light hydrocarbons (butadiene, strontium-fired, hexane-fired mixed hydrocarbons) 3 to 30 parts by weight, the amount of addition is determined according to the use of - hydrocarbons of the female (_). For example, the light smoke of Xin Lu (10)) is 84 'anhydrosterol octane (10) N) is 13 〇; anhydrous 曱The alcohol can be obtained by using 15 parts by weight of a cosolvent MTBE in an amount of 5 parts by weight with butane, 80 parts by weight of a light hydrocarbon (butane, pentane, and hexahydrate mixed tobacco) to obtain a smoldering value of the sterol light hydrocarbon fuel (_1304092 is 90). , generally suitable for engine compression ratio of 9 〇: ι below the car, replacing the No. 90 gasoline. In addition, methanol 2 〇 heavy parts, mixed light hydrocarbon π parts by weight, mixed MTBE 5 heavy injury 'its smoldering value is 93 units, Suitable for engine compression ratio of 9·3:1 or less Generation of gasoline No. 93. 25 parts by weight of anhydrous methanol, adding 5 parts by weight of the cosolvent MTBE, mixing 7 parts by weight of light hydrocarbons, the smoldering value is an evil unit, suitable for the engine compression ratio of 9. 5:1 for car use, instead of 95 No. of gasoline. No water content of 30 'Addition of cosolvent 5 parts by weight, mixed light _ parts by weight, its smoldering value at 97 'suitable to start sewing ratio 9.5: Bu (four) engine use, instead of 97 South Standard gasoline. Since anhydrous methanol or anhydrous ethanol and light smoke (butadiene, pentane, and burned hydrocarbons) are mutually soluble at room temperature, they are easily stratified after mutual dissolution, especially when the temperature is lower than 15C4 'poor miscibility'. A carbonaceous surfactant can be used, which has both hydrophilic and lipophilic properties, is highly diffusible, and uniformly adheres to the interface between the f-alcohol and the charcoal (hydrocarbon, aromatic) molecules, and is in the metal and rubber. Acoustic surface formation - a thinner film with strong anti-corrosion, anti-recording and anti-wear effects; if necessary, use a solvent to solve this problem. The anhydrous decyl alcohol or anhydrous ethanol and the total temperature of 15 ° C or more, the mutual solubility is better, so it is necessary to reduce the amount of co-solvent added. It is also possible to use 0 to 25 parts by weight with respect to 100 parts by weight of light hydrocarbon (butyl, pentane, and hexane), and when the temperature is high, it is not necessary to add a co-solvent to achieve the object. 1304092 wherein the fluorocarbon surfactant is a fluoroalkylamine salt or a quaternary ammonium salt cationic fluorocarbon surfactant selected from one of the formulas (1), (2) or (3) or a mixture thereof (1) Fluorinated Alkylamine Quaternary Ammonium Cationic Fluorocarbon Surfactant: (CFa) 2CF (CF2) 6CH2CH (OH) CH2N+ (CHs) 3Γ (2) Perfluoroalkylguanamine Quaternary Ammonium Cationic Fluorocarbon Surfactant: C7F15CONH (CH2) sN+ (CH3) 3Γ (3) Fluoroalkylamine salt cationic fluorocarbon surfactant: (F (CF2) sCH (OH) CH2] 2NCH2CH2NH2 · H2SO4 relative to 100 parts by weight of light hydrocarbons (butane, The fluorocarbon surfactant is added in an amount of from 〇〇〇4 to 4 parts by weight, preferably 0. 006 parts by weight. In the present invention, (丨) fluoroalkylamine Quaternary ammonium salt cationic fluorocarbon surfactant, (2) perfluoroalkyl decylamine quaternary ammonium cationic fluorocarbon surfactant, (3) fluoroalkylamine salt type % ion Dun carbon surfactant, may be used alternatively or Mixed use. Shanghai fluorocarbon surfactant product "MARAVILLA" can be used in the present invention, which is based on Shanghai Wenjing Fine Chemicals Co., Ltd. Limited to the company, 1 〇〇 heavy I injured Ding, E-burn, and burned light hydrocarbons, MARAVILLA added 〇· 004 to 0. 04 parts by weight, preferably 〇· 〇 〇β parts by weight. The method for preparing an alcoholic hydrocarbon fuel for vehicles according to the present invention comprises the following steps: using a fluorocarbon surfactant, a co-solvent such as hydrazine, TAME, hydrazine or a 1304092 - the use of 'additional ke Alcohol or absolute ethanol, =:: used in this amount of light _, pentad, and hydrocarbons to form a vehicle alcohol fuel. The product of the invention is a kind of high calorific value high Xinxin_), the cost is low, the surplus rot is pure grinding _ car cleaning alternative fuel. When used, emissions from tail gas pollution are reduced, and a new, energy-efficient, environmentally friendly car replaces new energy sources. This kind of successor is in line with the requirements of the world's protection of the earth's casting book, and it is in line with the world's source of this multi-chemicalization. It uses the low-cost by-products of the petrochemical kerosene field and can be treated with this patent. The use of automobiles can save money. The expenditure on fuel costs of automobiles is a new invention for the benefit of the country and the people. [Embodiment] The application method, function and effect of the detailed method are as follows. Please refer to the following § brothers to get a complete understanding. _ Example 1 C1) Light hydrocarbon (butane, pentane, hexane mixed hydrocarbon) 70 parts by weight (2) anhydrous decyl alcohol 15 parts by weight (3) hydrazine (or xylene) 10 parts by weight (4) methyl Third butyl ether ([BE) 5 parts by weight (5XCF3) 2CF(CF2)6CH 2CH (0H)CH2N+(CH3)3r 0. 006 parts by weight of the above components (2) anhydrous decyl alcohol, (3) MTBE and ( 4) The fluorocarbon surfactant is uniformly mixed, and then the component (1) light hydrocarbon (butane, pentane, hexane mixed hydrocarbon) is commonly used in the 1304092 & Hydrocarbon fuel products. ★ In this __ 财, the component (5) is a fluorine-containing silk-salt ammonium cation. • It is used as a carbon wire agent. Others can be used as a whole-milamine quaternary ammonium cation 2NCH2CH2NH2 · Η$〇4. Component (4) MTBE can be replaced with isobutanol, TAB or TAME. Example 2 (1) Light hydrocarbon (butane, pentane, hexane mixed hydrocarbon) 50 parts by weight (2) anhydrous methanol 25 parts by weight (3) toluene 20 parts by weight (4) methyl tert-butyl fluorene (ΜΤΒΕ) 5 parts by weight (5) C7Fi5CONHC3H6lf(CH3)3 Γ 0. 008 parts by weight in the conventional addition formula is operated in the same manner as in the first embodiment, and components (1), (2), (3), (4), (5) Co-allocated into a vehicle alcoholic hydrocarbon fuel product having an octane number (R0N) of 93 units, and in the formulation of the present embodiment, the composition is a perfluoroalkylamine quaternary ammonium cationic fluorocarbon surfactant, It is also possible to use a fluorine-containing alkyl amido ammonium-based cationic fluorocarbon surfactant (refer to the component (5) of the foregoing first embodiment formula), or to use a fluoroalkylamine salt cationic fluorocarbon surface active gas. Carbon surfactant, for example, he C0_H2M+(CH3)3r; or fluoroalkylamine salt type cation I carbon surface activity~ for example (F((5)颂(10) both)

劑,例如[F(CF2)8CH(0H)CH2] «ί£ΜΗ2 · Κ〇4·組分⑷MTBE 可以使用異丁醇、TBA或TAME替代的。 1304092 實施例3 45重量份 30重量份 20重量份 5重量份 〇· 006重量份 (1) 輕烴(丁烷、戊烷、己烷混合烴) (2) 無水曱醇 (3) 甲苯 (4) 甲基第三丁基醚(MTBE) ⑸馬叻威(MARAVILLA) 依前述第1實施例配方的操作方式,將組分(1)、(2)、 (3)、(4)、(5)共同調配成辛烷值(R〇N)為97個單位的車用醇 經燃料產品’是巾社海文景精細缸械公q出品的一種氣 碳表面活性劑商品。 在第3實關配方中的組分⑷甲基第三丁基驗(mtbe)可 改用甲基第三戊基醚(TAME)、TBA或異丁醇,它們可以擇一使 用者混使用。 實施例4 -------- --;__. 57重量份 20重量份 20重量份 3重量份 0.006重量份 (1) 輕烴(丁烷、戊烷、己烷混合烴) (2) 無水甲醇 (3) 二甲苯 (4) 異丁醇 ⑸(CF3)2CF(CF2)6CH2CH(OH)CM+(CH3)3r 以上組分(2)無水甲醇和(3)氟碳表面活性劑混合均勻,再 加入組分(1)輕烴(丁烷、戊烷、己烷混合烴)共同調配成辛烷 11 1304092 值(丽)為95個單位的車用醇輕烴燃料產品。 在本:r齡m配料,組分⑸為含氣絲胺季銨鹽型陽 離子氟縣面活_,其也可赠用為全基醯胺季錢鹽型 陽離子氟碳表面活性劑,例如.⑺騰㈤鐵⑽厂;或者^ 氟烧基胺鹽陽離子氟碳表面活性劑,例如 {F(CF2)8CH(0H)CH2}2NCH2CMH2 ·膽4。 由上可知,本發明的車用醇輕烴燃料,確實提供一種改善 傳統燃料油的方法,本發明的車用醇輕烴燃料產品與傳統低辛 烷值(R0N)低熱值燃料油作比較,其優點如下: (1) 本發明是利用煉油廠副產品輕烴或天然氣凝析油分離 出來的戊烷餾分作能源綜合利用,以節省能源,使用曱 苯或二甲苯提高辛烷值和燃燒熱值。使用曱基第三丁基 醚(MTBE)、曱基第三戊基醚(tame)、TBA、异丁醇等助 溶劑,有助於環境污染之改良。 (2) 本發明所配置的高辛烷值(R〇N)車用醇烴燃料,其燃料 可達到完全而節省燃料’并可改善發動機的工作特性, - 使尾氣的排放降最低’且可減少喷油嘴、燃燒室的積碳 „ 發生,以延長機械的壽命。 (3) 本發明車用醇烴燃料辛烷值(ron)可達到90〜97,由於 使用較多量的無水曱醇,甲醇氧分子含量高達50%,熱 效率比汽油高12%以上,在高壓縮比發動機上使用,發 12 1304092 動機動力性、加速性可比使用相同型號的汽油提高 10%,燃燒成本可比使用相同標號的汽油下降20%左右, CO、破烴化合物(以HC表示)、Nox排放比使用相同標 號的Ά油下降90%以上,是一種高效、節能、對環境友 好的汽車替代新能源。 ^精神時’均應在本發_範_。為 1304092 【圖式簡單說明】 【主要元件符號說明】Agents such as [F(CF2)8CH(0H)CH2] «ί£ΜΗ2 · Κ〇4·Components (4) MTBE can be replaced with isobutanol, TBA or TAME. 1304092 Example 3 45 parts by weight 30 parts by weight 20 parts by weight 5 parts by weight 〇·006 parts by weight (1) Light hydrocarbon (butane, pentane, hexane mixed hydrocarbon) (2) Anhydrous decyl alcohol (3) Toluene (4) ) methyl tert-butyl ether (MTBE) (5) MARAVILLA According to the operation of the formulation of the first embodiment, the components (1), (2), (3), (4), (5) The fuel alcohol product, which is a unit of 97 units of octane number (R〇N), is a kind of carbonaceous surfactant product produced by the company. The component (4) methyl butyl group (mtbe) in the third embodiment can be changed to methyl tertiary amyl ether (TAME), TBA or isobutanol, which can be used by a single user. Example 4 -------- --__. 57 parts by weight 20 parts by weight 20 parts by weight 3 parts by weight 0.006 parts by weight (1) Light hydrocarbon (butane, pentane, hexane mixed hydrocarbon) (2 Anhydrous methanol (3) xylene (4) isobutanol (5) (CF3) 2CF (CF2) 6CH2CH (OH) CM + (CH3) 3r above components (2) anhydrous methanol and (3) fluorocarbon surfactant mixed evenly Then, the component (1) light hydrocarbon (butane, pentane, hexane mixed hydrocarbon) is co-formulated into an octane 11 1304092 (Li) 95 unit vehicle alcohol light hydrocarbon fuel product. In the present: r age m ingredients, component (5) is a gas-containing amine quaternary ammonium salt type cationic fluoride county surface _, which can also be given as a full-based guanamine quaternary salt type cationic fluorocarbon surfactant, for example. (7) Teng (5) iron (10) plant; or ^ fluoroalkylamine salt cationic fluorocarbon surfactant, such as {F(CF2)8CH(0H)CH2}2NCH2CMH2 ·4. As can be seen from the above, the vehicle alcohol light hydrocarbon fuel of the present invention does provide a method for improving the conventional fuel oil. The vehicle alcohol light hydrocarbon fuel product of the present invention is compared with a conventional low octane (R0N) low calorific value fuel oil. The advantages are as follows: (1) The invention utilizes a pentane fraction separated by light hydrocarbon or natural gas condensate as a by-product of a refinery as a comprehensive energy utilization to save energy, and uses benzene or xylene to increase octane number and combustion heat value. . The use of a solvent such as mercapto tert-butyl ether (MTBE), decyl tertiary amyl ether (tame), TBA, isobutanol, etc., contributes to the improvement of environmental pollution. (2) The high octane (R〇N) vehicle alcohol fuel fuel configured by the present invention can achieve complete fuel economy and improve engine operating characteristics, and minimize exhaust gas emissions. Reduce the carbon deposit of the injector and the combustion chamber to occur to prolong the life of the machine. (3) The octane number (ron) of the alcoholic hydrocarbon fuel of the invention can reach 90 to 97, due to the use of a large amount of anhydrous decyl alcohol, The molecular content of methanol oxygen is up to 50%, the thermal efficiency is more than 12% higher than that of gasoline. It is used on high compression ratio engines. The power of 12 1304092 is 10% higher than that of gasoline with the same model. The burning cost can be compared with the same number. Gasoline is reduced by about 20%, CO, hydrocarbon-blocking compounds (expressed as HC), and Nox emissions are more than 90% lower than those using the same label. It is an efficient, energy-saving and environmentally friendly alternative to new energy sources. All should be in this hair _ Fan _. Is 1304092 [Simple diagram description] [Main component symbol description]

Claims (1)

1304092 、申請專利範園: 恤合物,其特徵在純分姆份如下 U工(丁貌、戊院、己烧混合煙)1〇〇重量份 下 無水甲醇或無水乙醇 q加去/ 助溶劑 3 30重1份 P15重量份 陽離子氟碳表面活_ 0.004-0. 04重量份 2. ,,求項!所述的車用醇烴燃料組合物 中輕烴(丁烷、戊烷、 八符徵在於’其 3. 根據請求項丨"合⑷是石化煉_副產品。 中助溶劑選自甲基第三丁基峻 j徵f於,其 醇或異丁醇中的一種。 甲土第一戊基醚、弟三丁基 麵燃料組合物,其特徵在於,其 ·5重量%以上的無水甲醇。 . 碳表面活性劑,f自丨f f^鹽或季_陽離子氟 (1)含惫e其尬采式〇)、(2)、(3)中的一種或其混合物: rrr、凡土胺季銨鹽陽離子氟碳表面活性劑·· il(CF2) 6〇Η£Η (〇H) CM+(CH3) t 晴季銨鹽陽離子氟碳表面活性劑: ,侧(CH2) I ㈣ 3Γ ⑶氟烧基賴陽離子氣·面活性劑: fi㈣α㈣CH2〕规細週2 ·細4。 於明d二C述的車用醇烴燃料組合物’其特徵 表面活性劑姐、_合烴),氣破 15 1304092 十一、圖式: 無 161304092, Patent application garden: T-shirt, characterized by pure fractions of the following U (Ding Miao, Wuyuan, hexased mixed tobacco) 1 〇〇 part by weight of anhydrous methanol or absolute ethanol q plus / help solvent 3 30 weights 1 part P15 parts by weight of cationic fluorocarbon surface activity _ 0.004-0. 04 parts by weight 2. ,, seeking! The light hydrocarbon (butane, pentane, octagonal sign in the vehicle alcohol-based hydrocarbon fuel composition is 'the 3. According to the request item 合" (4) is a petrochemical refining_by-product. The medium cosolvent is selected from the group consisting of methyl The tributyl sulphate is one of an alcohol or an isobutanol. The methane first amyl ether and the tributyl butyl fuel composition are characterized in that they are 5% by weight or more of anhydrous methanol. a surfactant, f from 丨 ^ salt or quaternary cation fluoride (1) containing 惫 e 尬 尬 尬 、 、 、 、 、 、 、 、 、 、 、 、 、 、 r r r r r r r r r r r r r r r r r r r r Cationic fluorocarbon surfactant ·· il(CF2) 6〇Η£Η (〇H) CM+(CH3) t Quaternary ammonium salt cationic fluorocarbon surfactant: , side (CH2) I (4) 3Γ (3) Fluorocarbon Cationic gas / surfactant: fi (tetra) α (tetra) CH 2 ] fine week 2 · fine 4. The vehicle alcoholic hydrocarbon fuel composition described in Yuming D2 is characterized by a surfactant surfactant, a hydrocarbon, and a gas break. 15 1304092 XI. Fig.: None 16
TW094131936A 2005-09-15 2005-09-15 Alcoholic hydrocarbon fuel composition for automobiles TW200712195A (en)

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