TWI387111B - Dye - sensitized solar cell packaging method - Google Patents
Dye - sensitized solar cell packaging method Download PDFInfo
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- TWI387111B TWI387111B TW98118154A TW98118154A TWI387111B TW I387111 B TWI387111 B TW I387111B TW 98118154 A TW98118154 A TW 98118154A TW 98118154 A TW98118154 A TW 98118154A TW I387111 B TWI387111 B TW I387111B
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- solar cell
- dye
- sensitized solar
- working electrode
- encapsulating material
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Links
- 238000000034 method Methods 0.000 title claims description 20
- 238000004806 packaging method and process Methods 0.000 title claims description 14
- 239000000758 substrate Substances 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 238000007731 hot pressing Methods 0.000 claims description 15
- 238000002955 isolation Methods 0.000 claims description 12
- 239000003792 electrolyte Substances 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 2
- 239000011521 glass Substances 0.000 description 10
- 239000005022 packaging material Substances 0.000 description 7
- 238000007789 sealing Methods 0.000 description 5
- 239000005021 flexible packaging material Substances 0.000 description 4
- 238000012536 packaging technology Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
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- Photovoltaic Devices (AREA)
- Hybrid Cells (AREA)
Description
本發明是有關於一種電池之封裝方法,且特別是有關於一種染料敏化太陽能電池之封裝方法。The present invention relates to a method of packaging a battery, and more particularly to a method of packaging a dye-sensitized solar cell.
一般而言,染料敏化太陽能電池係由上導電玻璃基板與下導電玻璃基板所組成。上導電玻璃基板的作用主要是將奈米級尺寸的二氧化鈦(TiO2 )粒子經溶劑溶解後,均勻塗佈在上導電玻璃基板上,以形成一二氧化鈦層。經加熱處理後,可形成一微觀狀似海綿、具多孔及大比表面積的薄膜。此一具有多孔性的二氧化鈦薄膜經過適當染料敏化之後,即形成工作電極,為主要的光電轉換部件。然後,塗佈一例如白金的金屬觸媒層於下導電玻璃基板上,以作為一對應電極。最後,將上導電玻璃基板、下導電玻璃基板與一電解液如三明治方式組裝起來,並對二氧化鈦層進行照光即可驅動電子,形成一太陽能電池裝置。In general, a dye-sensitized solar cell is composed of an upper conductive glass substrate and a lower conductive glass substrate. The function of the upper conductive glass substrate is mainly to dissolve the nano-sized titanium dioxide (TiO 2 ) particles in a solvent and uniformly coat the upper conductive glass substrate to form a titanium dioxide layer. After heat treatment, a microscopic sponge-like film having a porous and large specific surface area can be formed. This porous titanium oxide film is sensitized by a suitable dye to form a working electrode, which is a main photoelectric conversion member. Then, a metal catalyst layer such as platinum is applied on the lower conductive glass substrate to serve as a corresponding electrode. Finally, the upper conductive glass substrate, the lower conductive glass substrate and an electrolyte are assembled as a sandwich, and the titanium dioxide layer is illuminated to drive the electrons to form a solar cell device.
上述製作過程中,上導電玻璃基板與下導電玻璃基板,一般使用ITO或FTO透明導電玻璃為基板,然而使用上述兩種基板將面臨價格昂貴、基板不具可撓性、大面積製作困難,串聯電阻過大等問題。此外,目前所使用的有機封裝材料經陽光長期曝曬後易造成劣化、毀損,且常用的封裝材料同樣具有不可彎曲之限制。這些都是目前染料敏化太陽能電池無法商業化的瓶頸。In the above manufacturing process, the upper conductive glass substrate and the lower conductive glass substrate generally use ITO or FTO transparent conductive glass as the substrate. However, the use of the above two substrates will be expensive, the substrate is not flexible, and the large-area fabrication is difficult. Too big and other issues. In addition, the organic packaging materials currently used are prone to deterioration and damage after long-term exposure to sunlight, and the commonly used packaging materials also have limitations of being inflexible. These are the bottlenecks that are currently not commercially viable for sensitized solar cells.
有鑑於此,本發明提供一種太陽能電池之封裝方法,用以封裝一種可撓性的染料敏化太陽能電池。In view of this, the present invention provides a solar cell packaging method for packaging a flexible dye-sensitized solar cell.
本發明提出一種染料敏化太陽能電池之封裝方法,包括:提供一工作電極、一相對電極以及一隔離層;組合該工作電極、該相對電極與該隔離層,並使該隔離層配置於該工作電極與該相對電極之間;提供一軟性封裝材料,該軟性封裝材料進行第一次熱壓處理後,形成一容納空間;將該組合過之該工作電極、該相對電極與該隔離層配置於該容納空間;填充一電解液至該容納空間內並排出多於之氣體;以及進行第二次熱壓處理密封該容納空間。The present invention provides a method for packaging a dye-sensitized solar cell, comprising: providing a working electrode, an opposite electrode, and an isolation layer; combining the working electrode, the opposite electrode and the isolation layer, and disposing the isolation layer in the work Between the electrode and the opposite electrode; providing a soft encapsulating material, after the first hot pressing treatment, forming a receiving space; the combined working electrode, the opposite electrode and the isolating layer are disposed The accommodating space; filling an electrolyte into the accommodating space and discharging more gas; and performing a second hot pressing treatment to seal the accommodating space.
在本發明一實施例中,其中所述的熱壓處理係透過一封口機執行之。In an embodiment of the invention, the hot pressing process is performed through a mouth machine.
在本發明一實施例中,其中所述的軟性封裝材料為一透明膠膜。In an embodiment of the invention, the soft encapsulating material is a transparent adhesive film.
在本發明一實施例中,其中所述的軟性封裝材料為一可抗有機溶液侵蝕之材料。In an embodiment of the invention, the soft encapsulating material is a material resistant to attack by an organic solution.
在本發明一實施例中,其中所述的工作電極包括至少一基材及一二氧化鈦薄膜,該二氧化鈦薄膜配置於該基材上。In an embodiment of the invention, the working electrode comprises at least one substrate and a titanium dioxide film, and the titanium dioxide film is disposed on the substrate.
綜上所述,使用軟性封裝材料可以提供一可撓性的殼體,因此可提供一種可撓性之染料敏化太陽能電池。此外,透過封口機的熱壓處理,可提供一種低成本的太陽能電池封裝技術。In summary, the use of a flexible encapsulating material provides a flexible housing, thereby providing a flexible dye-sensitized solar cell. In addition, through the hot pressing process of the sealing machine, a low-cost solar cell packaging technology can be provided.
為讓本發明之上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式,作詳細說明如下。The above described features and advantages of the present invention will be more apparent from the following description.
圖1是本發明染料敏化太陽能電池的封裝方法流程圖,圖2是本發明染料敏化太陽能電池的組合示意圖。請分別參閱圖1及圖2,染料敏化太陽能電池100包括一工作電極110、一相對電極120、一隔離層130、一電解液(圖未示)以及一殼體140。BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a flow chart showing a method of packaging a dye-sensitized solar cell of the present invention, and Fig. 2 is a schematic view showing the combination of a dye-sensitized solar cell of the present invention. Referring to FIG. 1 and FIG. 2 respectively, the dye-sensitized solar cell 100 includes a working electrode 110, an opposite electrode 120, an isolation layer 130, an electrolyte (not shown), and a casing 140.
本發明的染料敏化太陽能電池100之封裝方法,其步驟包括:首先,提供一工作電極110、一相對電極120以及一隔離層130(步驟S100)。之後,組合工作電極110、相對電極120與隔離層130,並使隔離層130配置於工作電極110與相對電極120之間(步驟S200),其配置關係圖可參閱圖2,將隔離層130配置於工作電極110與相對電極120之間,可用於避免相對電極120與工作電極110碰觸而產生短路之現象。The method for packaging the dye-sensitized solar cell 100 of the present invention includes the steps of: first providing a working electrode 110, an opposite electrode 120, and an isolation layer 130 (step S100). Thereafter, the working electrode 110, the opposite electrode 120 and the isolation layer 130 are combined, and the isolation layer 130 is disposed between the working electrode 110 and the opposite electrode 120 (step S200). The arrangement diagram can be referred to FIG. Between the working electrode 110 and the opposite electrode 120, it can be used to avoid the phenomenon that the opposite electrode 120 and the working electrode 110 are in contact with each other to cause a short circuit.
其中,須特別說明的是染料敏化太陽能電池100的工作電極110可包括至少一基材及一二氧化鈦薄膜,二氧化鈦薄膜配置於基材上,其中基板可為一透明導電基板或一不透明導電基板,由於二氧化鈦薄膜配置於基板上,因此工作電極110可利用二氧化鈦薄膜來吸收太陽光,進行光電轉換,近而將光能轉換為電能。It should be noted that the working electrode 110 of the dye-sensitized solar cell 100 may include at least one substrate and a titanium dioxide film disposed on the substrate, wherein the substrate may be a transparent conductive substrate or an opaque conductive substrate. Since the titanium dioxide film is disposed on the substrate, the working electrode 110 can absorb the sunlight by using the titanium dioxide film, perform photoelectric conversion, and convert the light energy into electric energy.
之後,提供一軟性封裝材料,軟性封裝材料進行第一次熱壓處理後,形成一容納空間(步驟S300)。也就是說,在此步驟中,主要是透過一軟性封裝材料,在軟性封裝材料的三周圍先進行熱壓處理後形成一容納空間,而這個容納空間可用於容納染料敏化太陽能電池100的工作電極110、相對電極120、隔離層130以及電解液,而這個軟性封裝材料就可以組成染料敏化太陽能電池100的殼體140。Thereafter, a soft encapsulating material is provided, and the soft encapsulating material is subjected to the first hot pressing treatment to form a receiving space (step S300). That is to say, in this step, a accommodating space is formed by first performing hot pressing treatment on the periphery of the flexible packaging material through a flexible packaging material, and the accommodating space can be used for accommodating the work of the dye sensitized solar cell 100. The electrode 110, the opposite electrode 120, the isolation layer 130, and the electrolyte, and this flexible packaging material can constitute the housing 140 of the dye-sensitized solar cell 100.
這裡所述的軟性封裝材料可為一透明膠膜或一可抗有機溶液侵蝕之材料,如:塑膠,而熱壓處理可透過一封口機執行之,舉例來說,當軟性封裝材料為一塑膠時,利用封口機可以將塑膠進行熱壓處理,進而將塑膠的三周圍軟化密合起來。The soft encapsulating material described herein may be a transparent film or a material resistant to organic solution etching, such as plastic, and the hot pressing process may be performed through a mouth machine, for example, when the soft packaging material is a plastic. At the time, the plastic can be heat-pressed by a sealing machine to soften and close the three surrounding parts of the plastic.
之後,將步驟S200組合過之工作電極110、相對電極120與隔離層130配置於容納空間(步驟S400),並填充一電解液至該容納空間內並排出多於之氣體(步驟S500);以及進行第二次熱壓處理密封該容納空間(步驟S600)。Thereafter, the working electrode 110, the opposite electrode 120, and the isolation layer 130 combined in step S200 are disposed in the accommodating space (step S400), and an electrolyte is filled into the accommodating space and more gas is discharged (step S500); A second hot pressing process is performed to seal the accommodation space (step S600).
同樣的,這裡所指的第二次熱壓處理係透過一封口機執行,因軟性封裝材料為一塑膠,而利用封口機可以將塑膠所含有的最後開口處進行熱壓處理,最後將染料敏化太陽能電池100於軟性封裝材料密封起來。Similarly, the second hot pressing process referred to here is performed through a port machine. Because the soft packaging material is a plastic, the final opening of the plastic can be hot pressed by a sealing machine, and finally the dye is sensitive. The solar cell 100 is sealed in a flexible packaging material.
另外,如同一般的電池一樣,工作電極110與相對電極120可透過電解液電性導通,這裡,本發明的染料敏化太陽能電池100的電解液可為一含碘溶液,用以使工作電極與相對電極彼此電性導通。In addition, as in the case of a general battery, the working electrode 110 and the opposite electrode 120 can be electrically conducted through the electrolyte. Here, the electrolyte of the dye-sensitized solar cell 100 of the present invention can be an iodine-containing solution for the working electrode and The opposite electrodes are electrically connected to each other.
需特別說明的是,本發明與習知技術差異在於封裝體的材質以及封裝技術,如習知技藝所述,目前所使用的有機封裝材料大多經陽光長期曝曬後,易造成劣化、毀損,且具有不可彎曲之限制。而本發明則是提出一種完全不同於習知的封裝方法,此封裝方法係採用一種軟性封裝材料,透過封口機的熱壓處理,可將軟性封裝材料加以密封。It should be noted that the difference between the present invention and the prior art is the material of the package and the packaging technology. As described in the prior art, most of the organic packaging materials used in the present invention are easily deteriorated and damaged after being exposed to sunlight for a long time. Has an unbendable limit. However, the present invention proposes a packaging method which is completely different from the conventional one. The packaging method uses a soft packaging material, and the soft packaging material can be sealed by hot pressing treatment of the sealing machine.
如此,這樣的軟性封裝材料可以提供一可撓性的殼體140,因此可提供一種可撓性之染料敏化太陽能電池100。此外,透過封口機的熱壓處理,可提供一種低成本的太陽能電池封裝技術。As such, such a flexible encapsulating material can provide a flexible housing 140, thus providing a flexible dye-sensitized solar cell 100. In addition, through the hot pressing process of the sealing machine, a low-cost solar cell packaging technology can be provided.
雖然本發明以前述實施例揭露如上,然其並非用以限定本發明,任何熟習相像技藝者,在不脫離本發明之精神和範圍內,所作更動與潤飾之等效替換,仍為本發明之專利保護範圍內。While the present invention has been described above in the foregoing embodiments, it is not intended to limit the invention, and the equivalents of the modifications and retouchings are still in the present invention without departing from the spirit and scope of the invention. Within the scope of patent protection.
100...染料敏化太陽能電池100. . . Dye sensitized solar cell
110...工作電極110. . . Working electrode
120...相對電極120. . . Relative electrode
130...隔離層130. . . Isolation layer
140...殼體140. . . case
圖1是本發明染料敏化太陽能電池的封裝方法流程圖;及1 is a flow chart of a packaging method of a dye-sensitized solar cell of the present invention;
圖2是本發明染料敏化太陽能電池的組合示意圖。2 is a schematic view showing the combination of the dye-sensitized solar cell of the present invention.
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| TW98118154A TWI387111B (en) | 2009-06-02 | 2009-06-02 | Dye - sensitized solar cell packaging method |
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| TW98118154A TWI387111B (en) | 2009-06-02 | 2009-06-02 | Dye - sensitized solar cell packaging method |
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| TWI387111B true TWI387111B (en) | 2013-02-21 |
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| TWI684298B (en) * | 2018-10-02 | 2020-02-01 | 臺灣塑膠工業股份有限公司 | Hot-pressing method for aligning electrodes of dye-sensitized cell |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1197072A (en) * | 1997-07-23 | 1999-04-09 | Sanyo Electric Co Ltd | Sealed nonaqueous electrlyte battery using laminate facing body |
| JP2007280906A (en) * | 2006-04-12 | 2007-10-25 | Sony Corp | Functional device and manufacturing method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1197072A (en) * | 1997-07-23 | 1999-04-09 | Sanyo Electric Co Ltd | Sealed nonaqueous electrlyte battery using laminate facing body |
| JP2007280906A (en) * | 2006-04-12 | 2007-10-25 | Sony Corp | Functional device and manufacturing method thereof |
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