1379158 九、發明說明 【發明所屬之技術領域】 本發明係關於用於修補用於透射和反射彩色液 器及彩色攝像裝置及濾色器缺點的修補方法。 【先前技術】 關於用於彩色液晶顯示器及彩色攝像裝置之濾 形成手段，已經廣泛地採用藉由施塗彩色的輻射敏 組成物，令其於輻射底下曝露並令其顯影而在基材 預定圖案的彩色層之微影法。然而，此技術會由於 質在以上的處理期間黏到遮罩或基材或由於施塗彩 敏感樹脂組成物時來自噴嘴的外來物質黏到彩色層 彩色層的曝露失效而引起無色或低色密度缺點等之 題，因而降低生產量。事實上連在防止以上問題發 度時也無法完全地消除以上的問題。因此，爲了改 量，必須修補有缺點的彩色層。 關於修補以上的缺點之手段，已有人根據缺點 而提出不同的方法。關於典型的實施例，JP-4 258025 (在此使用的「JP-Aj —詞表示「審查中的 許公開公報」）揭示藉由雷射束的應用而燒掉有缺 的彩色層並將修補液塡入所形成的洞孔並固化之方 而’若以供先前技藝的濾色器用之彩色輻射敏感樹 物用於修補液中’該修補液將可溼塗在洞孔周圍的 無法僅塡入洞孔而造成修補部分的性能可能會變得 晶顯不 色器的 感樹脂 上形成 外來物 色輻射 而造成 類的問 生的量 良生產 的類型 2002- 日本特 點之處 法。然 脂組成 部分且 不適當 -5- 1379158 或在溼塗洞孔周圍部分時可能發生新的問題。 【發明內容】 月的目的在於提供用於修補濾色器缺點的輻射敏 胃_ Β旨組L成物’該組成物可僅完全地溼塗到藉移除被塡入 洞I孔的濾色器缺點而形成的洞孔中並可利用修補部分與正 胃$分之間的小量色品差異而修補該缺點，以及修補濾色 器缺點的方法。 本發明的發明者對以上的問題已經對以上的問題進行 深入的硏究並發現鹼溶性樹脂成分對多官能基單體成分的 比例'溶劑的平均蒸氣壓及用於修補該缺點之輻射敏感樹 脂組成物的固含量與可修補性及修補後的性能緊密關聯。 基於此發現而完成本發明。 首先’根據本發明，可藉由包含（Α)顏料、（Β) 驗溶性樹脂、（C)多官能基單體或多官能基單體與單官 能基單體的組合、（D )光起始劑及（Ε )溶劑的輻射敏 感樹脂組成物而達到以上的目的，其中 以100重量份的成分（Β)爲基準，成分（C)的量 爲350至1，〇〇〇重量份，成分（Ε)在2(TC下的平均蒸氣 壓低於3.0 mmHg，且該組成物具有25至50重量％的固 含量並用於修補濾色器缺點。 在此使用的「輻射」一詞表示可見光輻射、紫外線輻 射、遠紫外線輻射、電子輻射及X-輻射。 其次’根據本發明，藉由濾色器缺點的修補方法達到 -6 - 印9158 以上的目的，該方法依序包含以下的步驟： (1) 移除濾色器缺點，將以上用於修補濾色器缺點 的轄射敏感樹脂組成物塡入所形成的洞孔中，並移除溶劑 » (2) 令塡充的部分在輻射下曝露；以及 (3) 在曝露之後加熱塡充的部分。 本發明將詳細地說明於下。 【實施方式】 供修補濾色器缺點用之輻射敏感樹脂組成物 -(A )顏料- 有機顏料、無機顏料、染料或天然著色物質已經充當 著色劑用於供濾色器用之彩色輻射敏感樹脂組成物中。除 此之外’就色彩特性與耐熱性來看，較佳爲顏料且特佳爲 有機顏料。以有機顏料充當供修補本發明的濾色器缺點用 之輻射敏感樹脂組成物中的顏料特別理想，因爲已經修補 缺點的部分（後文稱之爲「經修補部分」）須要與正常部 分相同的色彩特性與耐熱性。 以上的有機顏料之實施例包括根據色指數（CI :由 染工與上色師協會頒布）歸類成顔料組群的化合物，明確 地說具以下色指數（C. I.)數字的化合物： c.l. Pigment Yellow 12、C.I. Pigment Yellow 13、1379158 IX. Description of the Invention [Technical Field] The present invention relates to a repairing method for repairing the disadvantages of a color filter and a color image pickup device and a color filter for transmitting and reflecting. [Prior Art] Regarding the filter forming means for color liquid crystal displays and color image pickup devices, a predetermined pattern on a substrate has been widely used by applying a color radiant sensitive composition to be exposed to radiation and developed. The lithography of the colored layer. However, this technique may cause colorless or low color density defects due to adhesion of the foreign matter from the nozzle to the color layer of the colored layer due to the adhesion of the foreign matter to the nozzle during the above treatment or the application of the color sensitive resin composition. The problem, thus reducing production. In fact, even in the prevention of the above problems, the above problems cannot be completely eliminated. Therefore, in order to be modified, it is necessary to repair the defective color layer. Regarding the means for repairing the above disadvantages, different methods have been proposed based on the disadvantages. Regarding a typical embodiment, JP-4 258025 ("JP-Aj" as used herein means "the disclosure of the publication") discloses that the defective color layer is burned by the application of the laser beam and will be repaired. The liquid is poured into the formed hole and solidified, and if the color radiation sensitive tree for the color filter of the prior art is used in the repair liquid, the repair liquid can be wetly coated around the hole and cannot be broken into The performance of the repaired portion of the hole may become a type of quality production of the type II produced by the colorless sensitizer on the resin. However, new problems may occur when the fat component is not appropriate -5 - 1379158 or when the portion around the hole is wet coated. SUMMARY OF THE INVENTION The purpose of the month is to provide a radiation-sensitive stomach for repairing the defects of the color filter. The composition can be completely wet-coated only to remove the color filter that is inserted into the hole of the hole I. The hole formed by the disadvantage of the device can be repaired by utilizing a small amount of chromaticity difference between the repaired portion and the positive stomach, and a method of repairing the disadvantage of the color filter. The inventors of the present invention have intensively studied the above problems with the above problems and found that the ratio of the alkali-soluble resin component to the polyfunctional monomer component 'the average vapor pressure of the solvent and the radiation-sensitive resin for repairing the disadvantage The solids content of the composition is closely related to the repairability and post-repair performance. The present invention has been completed based on this finding. Firstly, according to the present invention, (D) light can be obtained by including (Α) pigment, (Β) test-soluble resin, (C) polyfunctional monomer or a combination of a polyfunctional monomer and a monofunctional monomer. The above object is achieved by a radiation-sensitive resin composition of a starting agent and a (Ε) solvent, wherein the component (C) is in an amount of 350 to 1, 〇〇〇 by weight, based on 100 parts by weight of the component (Β). (Ε) The average vapor pressure at 2 (TC is less than 3.0 mmHg, and the composition has a solid content of 25 to 50% by weight and is used to repair the color filter defects. The term "radiation" as used herein means visible radiation, Ultraviolet radiation, far ultraviolet radiation, electron radiation and X-radiation. Secondly, according to the present invention, the repair method of the defect of the color filter achieves the purpose of -6 - 9158 or more, and the method comprises the following steps in sequence: (1) Removing the disadvantages of the color filter, inserting the above-mentioned photosensitive resin composition for repairing the defects of the color filter into the formed hole, and removing the solvent » (2) exposing the charged portion to radiation; And (3) heating the charged portion after exposure. The invention will be described in detail below. [Embodiment] A radiation-sensitive resin composition for the purpose of repairing a color filter - (A) Pigment - an organic pigment, an inorganic pigment, a dye or a natural coloring matter has been used as a coloring agent for filtration In addition to the color characteristics and heat resistance, it is preferably a pigment and particularly preferably an organic pigment. The organic pigment acts as a color filter for repairing the color filter of the present invention. The pigment in the radiation-sensitive resin composition is particularly preferable because the portion where the defect has been repaired (hereinafter referred to as "the repaired portion") requires the same color characteristics and heat resistance as the normal portion. Examples of the above organic pigment include According to the color index (CI: issued by the Society of Dyestuffs and Colorists), a compound classified as a pigment group, specifically a compound having the following color index (CI) number: cl Pigment Yellow 12, CI Pigment Yellow 13,
C.I. Pigment Yellow 14 ' C.I. Pigment Yellow 17 ' C I 1379158C.I. Pigment Yellow 14 ' C.I. Pigment Yellow 17 ' C I 1379158
Pigment Yellow 20、 C.I. Pigment Yellow 2 4、 C.I. Pigment Yellow 3 1 ' C.I. Pigment Yellow 5 5 > C.I. Pigment Yellow 83 ' C.I. Pigment Yellow 93 、 C.I. Pigment Yellow 109、 C.I. Pigment Yellow 110、 C.I. Pigment Yellow 138、 C.I. Pigment Yellow 139、 C.I. Pigment Yellow 150、 C.I. Pigment Yellow 153、 C.I. Pigment Yellow 154、 C.I. Pigment Yellow 155' C.I. Pigment Yellow 166 ' C.I. Pigment Y e 11 ο 1 6 8 及 C.I. Pigment Yellow 2 11; C.I. Pigment Orange 36、C.I. Pigment Orange 43、 C.I. Pigment Orange 51 、c. I. Pigment Orange 61及 C.I. Pigment Orange 7 1 ； C.I. Pigment Red 9、 C.I. Pigment Red 97 ' C.I. Pigment Red 122 ' C.I. Pigment Red 123 ' C. I. Pigment Red 149 、C.I. Pigment Red 168 > C.I. Pigment Red 176、 C.I. Pigment Red 177 、C .I. Pigment Red 180、 C.I. Pigment Red 207 ' C.I. Pigment Red 208 、 C. I. Pigment Red 209 、C.I. Pigment Red 215' C.I. Pigment Red 224 、 C.I. Pi gm ent Red 242及 C.I. Pigment Red 254 ； C.I. Pigment Violet 19、C.I. Pigment Violet 23 及 C.I. Pigment Violet 29 ; C. I. Pigment Blue 15、C. I. Pigment Blue 60、C.I. Pigment Blue 15:3、C.I. Pigment Blue 15:4、C.I. Pigment Blue 15:6 ； -8- 1379158 C.I. Pigment Green 7 ' C.I. Pigment Green 36 ' C.I.Pigment Yellow 20, CI Pigment Yellow 2 4, CI Pigment Yellow 3 1 'CI Pigment Yellow 5 5 > CI Pigment Yellow 83 ' CI Pigment Yellow 93 , CI Pigment Yellow 109 , CI Pigment Yellow 110 , CI Pigment Yellow 138 , CI Pigment Yellow 139, CI Pigment Yellow 150, CI Pigment Yellow 153, CI Pigment Yellow 154, CI Pigment Yellow 155' CI Pigment Yellow 166 ' CI Pigment Y e 11 ο 1 6 8 and CI Pigment Yellow 2 11; CI Pigment Orange 36, CI Pigment Orange 43, CI Pigment Orange 51, c. I. Pigment Orange 61 and CI Pigment Orange 7 1 ; CI Pigment Red 9, CI Pigment Red 97 ' CI Pigment Red 122 ' CI Pigment Red 123 ' CI Pigment Red 149 , CI Pigment Red 168 > CI Pigment Red 176, CI Pigment Red 177, C.I. Pigment Red 180, CI Pigment Red 207 'CI Pigment Red 208, CI Pigment Red 209, CI Pigment Red 215' CI Pigment Red 224, CI Pi gm Ent Red 242 and CI Pigment Red 254 ; C .I. Pigment Violet 19, CI Pigment Violet 23 and CI Pigment Violet 29; CI Pigment Blue 15, CI Pigment Blue 60, CI Pigment Blue 15:3, CI Pigment Blue 15:4, CI Pigment Blue 15:6; -8 - 1379158 CI Pigment Green 7 ' CI Pigment Green 36 ' CI
Pigment Green 136 及 C.I. Pigment Green 210 ;以及 C.I. Pigment Brown 23 ^ C . I · P i g m e n t B r o wn 2 5。 這些有機顏料皆可單獨使用或組合二或多種使用。視 情況需要地，可與以下列舉的無機顔料組合使用。 在本發明中，該有機顏料可在使用之前藉由再結晶、 再沈澱、溶劑清洗、昇華 '真空加熱或它們的組合純化。 無機顏料的實施例包括氧化鈦、硫酸鋇、碳酸鈣、鋅 白、硫酸鉛、黃鉛、鋅黃、紅氧化鐵（紅氧化鐵（III) )、鎘紅、群青、普魯士藍'氧化鉻綠、鈷綠、琥珀、鈦 黑、合成鐵黑及碳黑。 這些無機顏料皆可單獨使用或組合二或多種使用》 再者，在本發明中，以上的顏料可視情況需要地與至 少一種染料或天然著色物質組合使用。 在本發明中’顏料粒子可在使用之前視情況需要地具 有由聚合物修飾的表面。用於修飾顏料粒子的表面之聚合 物爲，例如’ JP-A 8-2598"76揭示的聚合物，或市面上可 購得之用於分散顏料的聚合物或寡聚物。 在本發明中，較佳爲選用與已用於要修補的缺點部分 之顏料具相同色品與耐熱性的顏料，吾人企圖以相同比例 之用於缺點部分的顏料之相同類型顔料使用。 在本發明中，顏料可視情況需要地與分散劑組合使用 〇 分散劑爲陽離子型 '陰離子型、非離子型、兩性、砂 -9- 1379158 氧烷系或氟系界面活性劑。 界面活性劑的實施例包括聚氧乙烯月桂酸、聚氧I% 硬脂醚及聚氧乙烯油醚等聚氧乙烯烷基醚類；聚氧乙miE 辛基苯基醚及聚氧乙烯正壬基苯基醚等聚氧乙條丨完 酸類；聚乙二醇二月桂酸醋及聚乙二醇二硬脂酸酯等聚乙 二醇二酯類；山梨醇脂肪酸酯類；經脂肪酸改質的聚醋類 :經三級胺改質的聚胺酯類：以及聚乙烯亞胺。這些界面 活性劑可在市面上以（Shin-Etsu Chemical股份有限公司 的）KP、 （Kyoeisha Yushi Kagaku 股份有限公司的）Pigment Green 136 and C.I. Pigment Green 210; and C.I. Pigment Brown 23 ^ C . I · P i g m e n t B r o wn 2 5. These organic pigments may be used singly or in combination of two or more. It may be used in combination with the inorganic pigments listed below as occasion demands. In the present invention, the organic pigment may be purified by recrystallization, reprecipitation, solvent washing, sublimation 'vacuum heating or a combination thereof before use. Examples of inorganic pigments include titanium oxide, barium sulfate, calcium carbonate, zinc white, lead sulfate, yellow lead, zinc yellow, red iron oxide (red iron oxide (III)), cadmium red, ultramarine blue, Prussian blue 'chromia green , cobalt green, amber, titanium black, synthetic iron black and carbon black. These inorganic pigments may be used singly or in combination of two or more. Further, in the present invention, the above pigments may optionally be used in combination with at least one dye or natural coloring matter. In the present invention, the "pigment particles" may have a surface modified by a polymer as needed before use. The polymer used to modify the surface of the pigment particles is, for example, the polymer disclosed in 'JP-A 8-2598" 76, or a commercially available polymer or oligomer for dispersing pigments. In the present invention, it is preferred to use a pigment having the same color and heat resistance as the pigment which has been used for the defective portion to be repaired, and it is intended to use the same type of pigment for the pigment of the defective portion in the same ratio. In the present invention, the pigment may optionally be used in combination with a dispersing agent. The dispersing agent is a cationic 'anionic, nonionic, amphoteric, sand-9-1379158 oxyalkylene or fluorine-based surfactant. Examples of the surfactant include polyoxyethylene alkyl ethers such as polyoxyethylene lauric acid, polyoxygen I% stearyl ether, and polyoxyethylene oleyl ether; polyoxyethylene miE octyl phenyl ether and polyoxyethylene hydrazine Polyoxyethylene oxime acid such as phenyl ether; polyethylene glycol diester such as polyethylene glycol dilaurate and polyethylene glycol distearate; sorbitol fatty acid ester; modified by fatty acid Polyurethanes: Polyamines modified with tertiary amines: and polyethyleneimine. These interfacial activators are available in the market (Shin-Etsu Chemical Co., Ltd.) KP, (Kyoeisha Yushi Kagaku Co., Ltd.)
Poly fl ow、 （Tokem Products 股份有限公司的）f Top、 (D a i n i ρ ρ ο η I n k a n d C h e m i c a 1 s 有限公司的）μ e g a f a c、 (Sumitomo 3M 股份有限公司的）Florade、 （Asahi Glass 股份有限公司的）Asahi Guard 和 Surflon、（Byk Chemie Japan 股份有限公司的）Disperbyk 及（Zeneca 股 份有限公司的）Solsperse的註冊名稱購得。 這些界面活性劑皆可單獨使用或組合二或多種使用。 以1 00重量份的顏料爲基準，分散劑的量較佳爲5 〇 重量份或更少，更佳地3 0重量份或更少。 -(B)鹼溶性樹脂- 本發明的鹼溶性樹脂具有羧基或酚羥基等酸官能基， 可溶於鹼性水溶液且較佳地作爲顏料（A )的黏結劑。 本發明的鹼溶性樹脂較佳爲含羧基的樹脂，特佳爲含 至少一個羧基的乙烯基化不飽和單體（後文稱之爲「含羧 -10- 1379158 基的不飽和單體」）與另一種可共聚合的乙烯基化不飽和 單體（後文稱之爲「可共聚合的不飽和單體」）之共聚物 (後文稱之爲「含羧基的共聚物」）^ 含羧基的不飽和單體之實施例包括（甲基）丙烯酸' 巴豆酸、（X -氯丙烯酸及肉桂酸等不飽和單羧酸；順丁烯二 酸、順丁烯二酸酐、反丁烯二酸、衣康酸、衣康酸酐、檸 康酸 '棒康酸野及甲基延胡索酸（mesaconic acid)等不 飽和二羧酸及其酸酐；含三或多個羧基的不飽和多元羧酸 及其酸酐；單〔2-(甲基）丙烯醯氧基乙基〕丁二酸酯及 單〔2-(甲基）丙烯醯氧基乙基〕苯二甲酸酯等含二或多 羧基的多羧酸之單〔（甲基）丙烯醯氧基烷基〕酯類；以 及ω·羧基聚己內酯單（甲基）丙烯酸酯等末端含羧基及羥 基的聚合物之單（甲基）丙烯酸酯類。 在這些含羧基的不飽和單體當中，可在市面上以（ Toagosei Chemical Industry 股份有限公司的）Μ-5300 和 M-5400的註冊名稱購得單〔2-(甲基）丙烯醯氧基乙基 〕丁二酸酯及單〔2-(甲基）丙烯醯氧基乙基〕苯二甲酸 酯。 以上的含羧基的不飽和單體皆可單獨使用或組合二或 多種使用。 可共聚合的不飽和單體之實施例包括苯乙烯、（X-甲基 苯乙烯 '鄰-乙烯基甲苯、間·乙烯基甲苯、對-乙烯基甲 苯、對-氯苯乙烯、鄰-甲氧基苯乙烯、間-甲氧基苯乙稀 '對-甲氧基苯乙烯、鄰-乙烯基苯甲基甲基醚、間-乙稀 -11 - 1379158 基苯甲基甲基醚、對-乙烯基苯甲基甲基醚、鄰-乙烯基苯 甲基縮水甘油基醚、間-乙烯基苯甲基縮水甘油基醚及對-乙稀基苯甲基縮水甘油基酸等芳香族乙烧基化合物；節及 1-甲基節等節類；（甲基）丙烧酸甲醋、（甲基）丙烧酸 乙酯、（甲基）丙烯酸正丙酯、（甲基）丙烯酸異丙酯、 (甲基）丙烯酸正丁酯、（甲基）丙烯酸異丁酯、（甲基 )丙烯酸第二丁酯、（甲基）丙烯酸第三丁酯、（甲基） 丙烯酸2-羥乙酯' (甲基）丙烯酸2-羥丙酯、（甲基） 丙烯酸3-羥丙酯、（甲基）丙烯酸2-羥丁酯、（甲基） 丙烯酸3-羥丁酯、（甲基）丙烯酸4-羥丁酯、（甲基） 丙烯酸烯丙酯、（甲基）丙烯酸苯甲酯、（甲基）丙烯酸 環己酯、（甲基）丙烯酸苯酯、（甲基）丙烯酸2 -甲氧 基乙酯、（甲基）丙烯酸2-苯氧基乙酯、甲氧基二乙二 醇（甲基）丙烯酸酯、甲氧基三乙二醇（甲基）丙烯酸酯 、甲氧基丙二醇（甲基）丙烯酸酯、甲氧基二丙二醇（甲 基）丙烯酸酯、（甲基）丙烯酸異冰片酯、（甲基）丙烯 酸三環〔5.2.1.02.5〕癸-8-酯、（甲基）丙烯酸2-羥基·3-苯氧基丙酯及丙三醇（甲基）丙烯酸酯等不飽和羧酸酯類 ;(甲基）丙烯酸2-胺基乙酯' (甲基）丙烯酸2-二甲 基胺基乙酯、（甲基）丙烯酸2 -胺丙酯、（甲基）丙烯 酸2-二甲基胺基丙酯、（甲基）丙烯酸3-胺丙酯、（甲 基）丙烯酸3 -二甲基胺基丙酯等不飽和羧酸胺基烷酯類 :(甲基）丙烯酸縮水甘油酯等不飽和羧酸縮水甘油酯類 :醋酸乙烯酯、丙酸乙烯酯、丁酸乙烯酯及苯甲酸乙烯酯 -12- 1379158 等羧酸乙烯酯類；乙烯基甲基醚、乙烯基乙基酸及烯丙基 縮水甘油醚等不飽和醚類；（甲基）丙烯腈、α·氯丙烯腈 及亞乙基二氰等乙烯基氰化合物類；（甲基）丙烯醯胺、 α-氯丙烯醯胺及Ν-2-羥乙基（甲基）丙烯醯胺等不飽和 醯胺類；順丁烯二醯亞胺' Ν-苯基順丁烯二醯亞胺及Ν-環己基順丁烯二醯亞胺等不飽和醯亞胺類；1，3-丁二烯、 異戊二烯及氯丁二烯等脂肪族共軛二烯類；及聚苯乙烯、 聚（甲基）丙烯酸甲酯、聚（甲基）丙烯酸正丁酯及聚矽 氧烷等聚合物分子鏈末端含單（甲基）丙烯醯基的巨型單 體類。 這些可共聚合的不飽和單體皆可單獨使用或組合二或 多種使用。 本發明含羧基的共聚物較佳爲以下之物的共聚物（後 文稱之爲「含羧基的共聚物（Α1)」）：（Ο含羧基的 不飽和單體成分，其包含充當基本成分的（甲基）丙烯酸 及視情況需要地至少一種選自單〔2-(甲基）丙烯醯氧基 乙基〕丁二酸酯及ω-羧基聚己內酯單（甲基）丙烯酸酯的 化合物與（b)至少一種選自苯乙烯、（甲基）丙烯酸甲 酯' (甲基）丙烯酸2-羥乙酯、（甲基）丙烯酸烯丙酯 ' (甲基）丙烯酸苯甲酯、丙三醇單（甲基）丙烯酸酯、 Ν·苯基順丁烯二醯亞胺、聚苯乙烯巨型單體及聚甲基丙烯 酸甲酯巨型單體者。 含羧基的共聚物（Α1)的例示性實施例包括（甲基 )丙烯酸與（甲基）丙烯酸甲酯的共聚物、（甲基）丙烯 -13- 1379158 酸與（甲基）丙烯酸苯甲酯的共聚物、（甲基）丙烯酸、 (甲基）丙烯酸2_羥乙酯與（甲基）丙烯酸苯甲酯的共 聚物、（甲基）丙烯酸、（甲基）丙烯酸甲酯與聚苯乙烯 巨型單體的共聚物'(甲基）丙烯酸、（甲基）丙烯酸甲 酯與聚甲基丙烯酸甲酯巨型單體的共聚物、（甲基）丙烯 酸、（甲基）丙烯酸苯甲酯與聚甲基丙烯酸甲酯巨型單體 的共聚物、（甲基）丙烯酸、（甲基）丙烯酸2-羥乙酯 、（甲基）丙烯酸苯甲酯與聚苯乙烯巨型單體的共聚物、 (甲基）丙烯酸、（甲基）丙烯酸2 -羥乙酯、甲基丙烯 酸苯甲酯與（甲基）丙烯酸苯甲酯的共聚物、（甲基）丙 烯酸、苯乙烯、（甲基）丙烯酸苯甲酯與N-苯基順丁烯 二醯亞胺的共聚物、（甲基）丙烯酸、單〔2-(甲基）丙 烯醯氧基乙基〕丁二酸酯、苯乙烯、（甲基）丙烯酸苯甲 酯與N-苯基順丁烯二醯亞胺的共聚物、（甲基）丙烯酸 、單〔2-(甲基）丙烯醯氧基乙基〕丁二酸酯、苯乙烯、 (甲基）丙烯酸烯丙酯與N-苯基順丁烯二醯亞胺的共聚 物、（甲基）丙烯酸、苯乙烯、（甲基）丙烯酸苯甲酯、 丙三醇單（甲基）丙烯酸酯與N-苯基順丁烯二醯亞胺的 共聚物及（甲基）丙烯酸、ω -羧基聚己內酯單（甲基）丙 烯酸酯、苯乙烯、（甲基）丙烯酸苯甲酯、丙三醇單（甲 基）丙烯酸酯與Ν-苯基順丁烯二醯亞胺的共聚物。 本發明中，含羧基共聚物中的含羧基的不飽和單體含 量較佳爲5至50重量％，更佳爲1 〇至4〇重量。/。。若以上 的含量低於5重量％，製得的輻射敏感樹脂組成物之儲存 -14- 1379158 安定性可能會降低，又若含量高於50重量％， 樹脂組成物在聚合期間可能會膠化。 本發明中，以聚苯乙烯來看藉由凝膠滲透. GPC，沖提溶劑：四氫呋喃）測量鹼溶性樹脂成 平均分子量（後文稱之爲「Mw」）較佳爲 300.000 > 更佳地 5,000 至 1 00,000。 以聚苯乙烯來看藉由凝膠滲透層析法（GPC 劑：四氫呋喃）測量鹼溶性樹脂成分的數目平均 後文稱之爲「Μη」）較佳爲 3,000至 60,000 5.000 至 25,000 。 鹼溶性樹脂的Mw/Mn比較佳爲1至5，更佳 〇 本發明中，藉由使用具指定的Mw與Μη的 脂成分，顏料的分散性變高，因而可製得本發明 儲存安定性的組成物。 本發明中，鹼溶性樹脂皆可單獨使用或組合 使用。 本發明中的鹼溶性樹脂之用量以100重量份 Α)爲基準，較佳爲10至1，000重量份，更佳 5〇〇重量份。若鹼溶性樹脂的量小於10重量份 料不安定的分散性，在儲存時顔料可能會沈澱。 1，〇〇〇重量份，組成物的黏度可能會變得太高， 狀物可能難以自用於修補之設備或裝置的針狀部 輻射敏感 層析法（ 分的重量 3,000 至 ，沖提溶 分子量（ ，更佳地 地1至4 鹼溶性樹 之具優異 二或多種 的顔料（ 地 20至 ’由於顏 若量大於 因而該液 移除。 -15- 1379158 -(c)多官能基單體或多官能基單體與單官能基單體的組 合- 本發明的多官能基單體爲二或多個可聚合的不飽和鍵 之單體。 多官能基單體的實施例包括乙二醇及丙二醇等伸院二 醇的二（甲基）丙烯酸酯類；含二或多個伸乙氧基的聚乙 二醇及含二或多個伸丙氧基的聚丙二醇等聚伸烷二醇的二 (甲基）丙烯酸酯類；丙三醇、三羥甲基丙烷、季戊四醇 及二季戊四醇等含3或多個羥基的多羥醇及其二羧酸改質 的產物之聚（甲基）丙烯酸酯類；聚酯、環氧樹脂、胺基 甲酸酯樹脂、醇酸樹脂、矽氧烷樹脂及螺烷樹脂等寡聚合 (甲基）丙烯酸酯；兩個末端都含羥基的聚—丁二烧、 兩個末端都含羥基的聚異戊二烯及兩個末端都含羥基的聚 己內醋等分子鏈兩個末端都含羥基的聚合物之二（甲基） 丙烯酸酯類；及參〔2·(甲基）丙烯醯氧基乙基〕磷酸醋 〇 在這些多官能基單體當中，較佳爲含3或多個經基的 多羥醇及其二羧酸改質的產物之聚（甲基）丙烯酸醋類， 列舉如三羥甲基丙烷三（甲基）丙烯酸酯、季戊四醇三（ 甲基）丙烯酸酯、季戊四醇四（甲基）丙烯酸酯、二季戊 四醇五（甲基）丙烯酸醋及二季戊四醇六（甲基）丙烧酸 酯。特佳爲三羥甲基丙烷三（甲基）丙烯酸酯、季戊四醇 三（甲基）丙燃酸酯及二季戊四醇六（甲基）丙烯酸酯， 因爲它們在輻射底下曝露都會迅速地聚合並固化而變成非 -16- 1379158 流動性。 .* 以上官能基的單體皆可單獨使用或組合二或多種使用 • 〇 以100重量份的鹼溶性樹脂（B)爲基準，多官能基 單體的量較佳爲350至1，000重量份，更佳地350至700 重量份或更少。若多官能基單體的量少於3 5 0重量份，由 曝露產生的固化可能變得不適當且固化之後所需的部分可 φ 能因而變成流體。若量大於1,〇〇〇重量份，製得的組成物 之黏度變得太低，藉以在該組成物塡入該洞孔時，該組成 物可能幾乎不會附著到用於修補的設備或裝置的針狀部。 本發明中，可藉由含一個可聚合的不飽和鍵之單官能 基單體取代一部分的多官能基單體。 以上的單官能基單體實施例包括已列舉供以上含羧基 的共聚物用之含羧基的不飽和單體及可共聚合的不飽和單 體，N-(甲基）丙烯醯基嗎啉、N-乙烯基吡啶酮' N_乙烯 φ 基-ε·己內醯胺及可在市面上購得的（Toagosei Chemical Industry股份有限公司的）M-5300和M-5400。 這些單官能基單體皆可單獨使用或組合二或多種使用 〇 以多官能基單體及單官能基單體的總量爲基準，單官 能基單體的量較佳爲90重量％或更少，更佳地50重量％ 或更少。若單官能基單體的量大於90重量％，經修補部 分的強度及表面平滑度可能會變得不適當。 以1 0 0重量份的鹼溶性樹脂（B )爲基準，本發明中 -17- 1379158 多官能基單體及單官能基單體的總量爲3 5 0至1,000重量 份，較佳地350至700重量份。若以上的總量少於350重 量份，經修補部分的強度及表面平滑度可能會降低，又若 總量大於1，〇〇0重量份，製得的組成物之黏度變得太低， 藉以在該組成物塡入該洞孔時，該組成物可能幾乎不會附 著到用於修補的設備或裝置的針狀部。 • ( D )光起始劑· 本發明的光起始劑爲可透過於可見光輻射、紫外線輻 射' 遠紫外線輻射、電子輻射及X-輻射（後文稱之爲「 曝露」）等輻射底下曝露而形成可引發以上成分（C)的 聚合作用之自由基的化合物。 光起始劑的實施例包括乙醯酮系化合物、聯咪唑系化 合物、三嗪系化合物、苯偶姻系化合物、苯甲酮系化合物 、α -二酮系化合物、多核醌系化合物、咕噸酮系化合物及 重氮系化合物。 本發明中，以上的光起始劑皆可單獨使用或組合二或 多種使用。本發明的光起始劑較佳爲至少一種選自乙醯酮 系化合物、聯咪唑系化合物及三嗪系化合物者。 以重量份的成分（C)爲基準，本發明的光起始 劑量較佳爲0.01至80重量份，更佳地1至60重量份。 若光起始劑的量小於0 · 0 1重量份，經修補部分固化之後 可能由於曝露產生的不完全固化而變成流體。若量大於 80重量份，光自由基產生劑幾乎不會溶於組成物中，藉 -18- 1379158 以經修補部分充當濾色器的特性可能會受損° 在本發明之較佳光起始劑當中的乙酿酮系化合物實施 例包括2 -羥基-2-甲基-1-苯基丙酮-1、2 -甲基-1-( 4 -甲基 噻吩基）-2-(嗎啉基）丙酮-1、2 -苯甲基-2-二甲基胺基- 1- ( 4-嗎啉基苯基）丁酮-1、1-羥基環己基苯基酮及2,2-二甲氧基·1，2-二苯基乙酮-1。 在這些乙醯酮系化合物當中，特佳爲2-甲基-】-(4-甲基噻吩基）-2-(嗎啉基）丙酮-1及2-苯甲基-2-二甲基 胺基-1-(4 -嗎啉基苯基）丁酮-1。 以下的乙醯酮系化合物皆可單獨使用或組合二或多種 使用。 若以乙醯酮系化合物作爲本發明的光起始劑’以1 00 重量份的成分（C)爲基準，乙醯酮系化合物的量較佳爲 0.01至80重量份，更佳地1至60重量份，特佳地1至 3 〇重量份。若乙醯酮系化合物的量小於〇. 〇 1重量份，經 修補部分固化之後可能由於曝露產生的不完全固化而變成 流體。若量大於80重量份，乙醯酮系化合物幾乎不會溶 於組成物中，藉以經修補部分充當濾色器的特性可能會受 損。 聯咪唑系化合物的實施例包括2,2’-雙（2-氯苯基）-4,4’，5,5’-肆（4-乙氧羰基苯基）-1,2’-聯咪唑、2,2’·雙（ 2- 溴苯基）·4,4’，5,5’·肆（4-乙氧羰基苯基）聯咪唑 、2,2’-雙（2-氯苯基）-4,4’，5,5’-四苯基-1，2’-聯咪唑、 2,2’-雙（2,4-二氯苯基）-4,4’，5,5，-四苯基-1,2’-聯咪唑、 -19- 1379158 2,2’-雙（2,4,6-三氯苯基）-4,4’，5,5，-四苯基-1， 、2,2’-雙（2-溴苯基）-4,4’，5,5’-四苯基-1，2、 2,2’-雙（2,4-二溴苯基）-4,4’，5,5’-四苯基-1,2’· 2,2’-雙（2,4,6-三溴苯基）-4,4，，5,5，-四苯基-1， 〇 在這些聯咪唑系化合物當中，較佳爲2,2’. 苯基）-4,4’，5,5’-四苯基-1，2’-聯咪唑、2,2，-雙（ 苯基）-4,45,5,5’-四苯基-1，2’-聯咪唑及2,2’-雙 氯苯基）-4,4’，5,5’-四苯基-1，2’-聯咪唑，又特隹 雙（2,4-二氯苯基）-4,4’，5,5’-四苯基-1，2’-聯咪| 以上的聯咪唑系化合物在溶劑中具有優異的 但不會產生不溶的產物及沈澱物等外來物質，具 ，可利用小量能量曝露而完全地促成固化反應並 防止固化之後經修補部分的流動。 以上的聯咪唑系化合物皆可單獨使用或組合 使用。 若以聯咪唑系化合物作爲本發明的光起始劑 重量份的成分（C)爲基準，聯咪唑系化合物的 0.01至40重量份，更佳地1至30重量份，特 20重量份。若聯咪唑系化合物的量小於〇.〇1重 修補部分固化之後可能由於曝露產生的不完全固 流體。若量大於40重量份，聯咪唑系化合物幾 於組成物中且以經修補部分充當濾色器的特性可 2 ’ -聯咪唑 聯咪唑、 聯咪唑及 2’-聯咪唑 -雙（2-氯 :2,4-二氯 (2,4,6·三 I 爲 2,2，-坐。 溶解度， 商靈敏性 可有效地 二或多種 ，以 1 0 0 量較佳爲 佳地1至 量份，經 化而變成 乎不會溶 能會受損 -20- 1379158 -氫供體- 若以聯咪唑系化合物作爲本發明的光起始劑，較理想 的是與以下的氫供體組合使用以進一步改善靈敏度。在此 使用的「氫供體j 一詞表示可透過曝露提供氫原子給聯咪 唑系化合物形成的自由基之化合物。 本發明的氫供體較佳爲後文定義的硫醇系化合物或胺 系化合物。 以上的硫醇系化合物爲含充當母核的苯環或雜環，且 有1或多個，較佳地1至3個，更佳地1或2個直接地鍵 結到該分子的母核之硫醇基的化合物（後文稱之爲「硫醇 系氫供體」）。 以上的胺系化合物爲含充當母核的苯環或雜環，且有 1或多個，較佳地1至3個，更佳地1或2個直接地鍵結 到該分子的母核之胺基的化合物（後文稱之爲「胺系氫供 體」）。 氫供體可同時含硫醇基與胺基。 接下來將提供這些氫供體的詳細說明。 硫醇系氫供體的分子中可含至少一個苯環或雜環，或 它們二者。若其含有兩個或多個環，就可形成或可不形成 稠合環。 若該硫醇系氫供體含兩個或多個硫醇基，只要保持至 少一個自由的硫醇基，至少一個其他的硫醇基就可被院基 、芳烷基或芳基取代。再者，只要保持至少一個自由硫醇 -21 - 1379158 基，硫醇系氫供體就可具有兩個硫原子藉由伸烷基等二價 有機基團鍵結在一起的結構單元，或兩個硫原子呈二硫化 • 物的形態鍵結在一起的結構單元。 再者，硫醇系氫供體在硫醇基以外的位置可被羧基、 烷氧羰基、經取代的烷氧羰基、苯氧羰基、經取代的苯氧 羰基或腈基所取代。 此硫醇系氫供體的實施例包括2-硫醇基苯并噻唑、2_ φ 硫醇基苯并噚唑、2 -硫醇基苯并咪唑、2,5 -二硫醇基· 1，3,4-噻二唑及2-硫醇基-2,5-二甲基胺基吡啶。 在這些硫醇系氫供體當中，較佳爲2,5.二硫醇基_ 1,3,4-噻二唑及2_硫醇基-2,5_二甲基胺基吡啶，又特佳爲 2 -硫醇基-2，5 -二甲基胺基吡啶。 胺系氫供體的分子中可含至少一個苯環或雜環，或它 們二者。若其含有兩個或多個環，就可形成或可不形成调 合環。 φ 該胺系氫供體之至少一個胺基可被烷基或經取代的院 基取代。胺系氫供體在胺基以外的位置可被羧基、院氧鎖 基、經取代的烷氧羰基、苯氧羰基、經取代的苯氧端基或 睛基所取代。 以上之胺系氫供體的實施例包括4,4’-雙（二甲基胺 基）苯甲酮、4，4，-雙（二乙基胺基）苯甲酮、4·二乙基胺 基苯甲酮、4-二甲基胺基苯甲酮、乙基-4_二甲基胺基苯 甲酸醋、4-二甲基胺基苯甲酸酯及4_二甲基胺基苯甲腈。 在這些胺系氫供體當中，較佳爲4,4，-雙（二甲基胺 -22- 1379158 基）苯甲酮及4,4’-雙（二乙基胺基）苯甲酮，又特佳爲 4,4’-雙（二乙基胺基）苯甲酮。 若使用聯咪唑系化合物以外的光起始劑，胺系氫供體 就作爲敏化劑。 在本發明中，以上的氫供體皆可單獨使用或組合二或 多種使用。較佳爲使用至少一種硫醇系氫供體與至少一種 .胺系氨供體的組合以防止曝露固化而造成的流動。 硫醇系氫供體與胺系氫供體的組合之實施例包括2-硫醇基苯并噻唑與4,4’-雙（二甲基胺基）苯甲酮的組合 、2-硫醇基苯并噻唑與4,4’-雙（二乙基胺基）苯甲酮的 組合、2_硫醇基苯并Pf唑與4,4’-雙（二甲基胺基）苯甲 酮的組合，及2_硫醇基苯并Pf唑與4,4’-雙（二乙基胺基 )苯甲酮的組合。較佳爲2 -硫醇基苯并鳄唑與4,4’-雙（ 二甲基胺基）苯甲酮的組合及2·硫醇基苯并噚唑與4，4’-雙（二乙基胺基）苯甲酮的組合，又特佳爲2_硫醇基苯 并鸣唑與4,4’-雙（二甲基胺基）苯甲酮的組合。 在硫醇系氫供體與胺系氫供體的組合中硫醇系氫供體 對胺系氫供體的重量比較佳爲1:1至1:4，更佳爲1:1至 1:3° 若本發明中使用氫供體與聯咪唑系化合物組合，以成 分（C)的重量爲基準，氫供體的量較佳爲〇.〇1至4〇重 量份’更佳地1至3 0重量份，特佳地]至2 0重量份。若 氫供體的量小於0·01重量份，其改善靈敏度的效果可能 會降低。若量大於4 0重量份，氫供體可能幾乎不溶於組 -23- 1379158 成物中且以經修補部分充當濾色器的特性可能會受損。 . 以上三嗪系化合物的實施例包括2,4,6 -參（三氯甲基 • ) ·對稱-三嗪、2-甲基-4,6-雙（三氯甲基）-對稱-三嗪. 2-〔 2- ( 5 -甲基呋喃.2-基）乙烯基〕_4,6_雙（三氯甲基 )-對稱-三嗪、2-〔2-(呋喃-2-基）乙烯基〕-4,6-雙（三 氯甲基）·對稱-三嗪、2-〔 2-(4-二乙基胺基-2-甲基苯基 )乙烯基〕-4,6-雙（三氯甲基）-對稱-三嗪、2-〔 2-( φ 3，4·二甲氧基苯基）乙烯基〕-4,6 -雙（三氯甲基）.對稱· 三嗪、2-(4-甲氧基苯基）_4,6-雙（三氯甲基）_對稱-三 嗪、2-(4-乙氧基苯乙烯基）·4,6_雙（三氯甲基）—對稱_ 三嗪等含鹵甲基的化合物。 在以上的三嗪系化合物當中，較佳爲2-〔 2- ( 3,4-二 甲氧基苯基）乙烯基〕-4,6-雙（三氯甲基）-對稱-三嗪。 以上的三嗪系化合物皆可單獨使用或組合二或多種使 用。 • 若以三嗪系化合物作爲本發明的光起始劑，以1 00 m 量份的成分（C)爲基準，三嗪系化合物的量較佳爲〇〇】 至4〇重量份，更佳地1至30重量份，特佳地1至2〇重 量份。若三嗪系化合物的量小於〇 · 〇丨重量份，經修補部 分固化之後可能由於曝露產生的不完全固化而變成流體。 若量大於40重量份，三嗪系化合物可能幾乎不會溶於組 成物中且以經修補部分充當濾色器的特性可能會受損。 -添加物- -24- I3?9158 必要時可添加各種添加物到本發明 用之輻射敏感樹脂組成物。 以上的添加物包括藍色顏料衍生物 ’即，酞花青銅衍生物，等分散助劑； :聚乙烯醇、聚乙二醇單烷基醚或聚（ 等聚合物調合物：非離子型、陽離子型 性劑；乙烯基三甲氧基矽烷、乙烯基三 基參（2-甲氧基乙氧基）矽烷、Ν-(2-, -甲基·二甲氧基矽烷、Ν-(2-胺乙基）· 矽烷、3-胺丙基三乙氧基矽烷' 3-縮水 氧基矽烷、3-縮水甘油氧基丙基·甲基· (3,4-環氧基環己基）乙基三甲氧基矽 •二甲氧基矽烷、3-氯丙基三甲氧基矽院 基丙基三甲氧基矽烷或3-硫醇基丙基 著加速劑：2,2-硫代雙（4-甲基-6-第三 第三丁基酚等抗氧化劑；2- ( 3-第三了 苯基）-5-氯苯并三嗪或烷氧基苯甲酮 聚丙烯酸鈉等凝聚抑制劑；以及1,1’-* 甲腈）或2·苯基偶氮-4-甲氧基-2,4-二 基產生劑。 -(Ε )溶劑- 較佳地，本發明的溶劑將分散或溶 脂組成物的成分（A )到（D )及添加 供修補濾色器缺點 或黃色顏料衍生物 玻璃或礬土等塡料 氟烷基丙烯酸酯） 或陰離子型界面活 乙氧基矽烷、乙烯 按乙基）-3-胺丙基 3-胺丙基三甲氧基 甘油氧基丙基三甲 二甲氧基矽烷、2-院、3-氯丙基·甲基 :、3-甲基丙烯醯氧 三甲氧基矽烷等黏 丁基酚）或2,6-二 '基-5-甲基-2-羥基 等紫外線吸收劑； 厲氮雙（環己烷-1-甲基戊腈等熱自由 解構成輻射敏感樹 物，且不會與這些 -25- 1379158 起反應。 溶劑的實施例包括例如乙二醇單甲基酸、乙二醇單乙 基醚、乙二醇單正丙基醚 '乙二醇單正丁基酸、二乙二醇 單甲基醚、二乙二醇單乙基醚、二乙二醇單正丙基醚 '二 乙二醇單正丁基醚、三乙二醇單甲基醚、三乙二醇單乙基 醚、丙二醇單甲基醚、丙二醇單乙基醚、丙二醇單正丙基 醚、丙二醇單正丁基醚、二丙二醇單甲基醚、二丙二醇單 乙基醚、二丙二醇單正丙基醚、二丙二醇單正丁基酸、三 丙二醇單甲基醚及三丙二醇單乙基醚等（聚）伸院基二醇 單烷基醚類；例如乙二醇單甲基醚醋酸醋、乙二醇單乙基 醚醋酸酯、乙二醇單正丙基醚醋酸酯、乙二醇單正丁基酸 醋酸酯、二乙二醇單甲基醚醋酸酯、二乙二醇單乙基醚醋 酸酯、丙二醇單甲基醚醋酸酯及丙二醇單乙基醚醋酸酯等 (聚）伸烷基二醇單烷基醚醋酸酯類；例如二乙二醇二甲 基醚、二乙二醇甲基乙基醚、二乙二醇二乙基醚、四氫咲 喃、苯甲基乙基醚及二正己基醚等其他醚類；例如甲乙酮 、2 -庚酮、3·庚酮及環己酮等酮類；例如乳酸甲酯及乳酸 乙酯等乳酸烷酯類；例如2-羥基-2-甲基丙酸乙酯、3-甲 氧基丙酸甲酯、3 -甲氧基丙酸乙酯、3 -乙氧基丙酸甲酯、 3 -乙氧基丙酸乙酯、乙氧基醋酸乙酯、羥基醋酸乙酯、2-羥基-3-甲基丁酸甲酯 '醋酸3-甲氧基丁酯、3-甲基-3-甲 氧基丁基醋酸酯、3 -甲基-3·甲氧基丁基丙酸酯、醋酸乙 酯、醋酸正丙酯、醋酸異丙酯、醋酸正丁酯、醋酸異丁酯 、甲酸正戊酯、醋酸異戊酯、丙酸正丁酯、酪酸乙酯、酪 -26- 1379158 酸正丙酯、酩酸異丙酯、酪酸正丁酯、丙酮酸甲酯、丙酮 酸乙酯、丙酮酸正丙酯' 乙醯醋酸甲酯、乙醯醋酸乙酯' 2-氧丁酸乙酯、醋酸苯甲酯、苯甲酸乙酯、草酸二乙酯及 順丁烯二酸二乙酯等其他酯類；例如甲苯及二甲苯等芳香 族烴類；例如N -甲基吡啶酮、Ν,Ν -二甲基甲醯胺及n，N-二甲基乙醯胺等醯胺類；及丙酮基丙酮、異佛爾酮（ isophorone)、己酸乙酯、辛酸、1·辛醇、1-壬醇、苯甲 醇、二丙酮醇、3 -甲氧基-3 -甲基-1-丁醇、γ_ 丁內酯、碳 酸乙二酯、碳酸丙二酯、乙二醇單苯基醚醋酸酯及3 -甲 氧基-3-甲基-1 -丁醇。 這些溶劑皆可單獨使用或組合二或多種使用。 由本發明發明者進行的硏究發現若要塡入藉由移除有 缺點的部分而形成之洞孔的輻射敏感樹脂組成物乾得太快 ，就不適用於修補，因爲該組成物會在用於修補之設備或 裝置的針狀部達到要塡充的部分之前就先乾燥並固化。因 此，用於本發明供修補濾色器缺點用之輻射敏感樹脂組成 物的溶劑在20 °C時的平均蒸氣壓（後文簡單地稱之爲「 平均蒸氣壓」）必須低於3.0 mmHg。平均蒸氣壓較佳爲 0.1或更高且低於3.0 mmHg，更佳地1.0或更高且低於 3 · 0 m m H g。 在本發明中要將溶劑的平均蒸氣壓調整到小於3.0 mmHg的値，吾.人企求以至少一種選自乙二醇單正丁基醚 醋酸酯、二乙二醇甲基乙基醚、3-乙氧基丙酸乙酯、二乙 二醇甲基乙基酸、3-乙氧基丙酸乙酯、N-甲基吡啶酮、二 -27- 1379158 丙酮醇、3-甲氧基-3-甲基-1-丁醇及γ-丁內酯者，較佳地 至少一選自乙二醇單丁基醚醋酸酯、二乙二醇甲基乙基醚 及3 -乙氧基丙酸乙酯者作爲溶劑。這些溶劑對於顔料的 分散性並不具不良的影響。本發明中，以上任一種溶劑皆 可視情況需要地與另一種上列溶劑組合使用。 就組成物的流動性與安定性來看，本發明的溶劑量爲 可確保輻射敏感樹脂組成物的固含量較佳爲25至50重量 %，更佳爲25至35重量％的値而使經修補部分與正常部 分的色品差異降到最小。輻射敏感樹脂組成物的固含量爲 由（溶劑以外的成分總重量）/ (組成物總重量）χΙΟΟ 計算得到的値。 濾色器缺點的修補方法 濾色器由形成於基材上含紅 '綠和藍三原色像素陣列 的彩色層組成。因此，在此使用的「濾色器缺點」措辭表 示在含紅、綠和藍三原色像素陣列的彩色層中的缺點。 本發明的濾色器缺點之修補方法依序包含以下的步驟 (1 )移除濾色器缺點，將本發明用於修補濾色器缺 點的輻射敏感樹脂組成物（後文又稱之爲「液態樹脂組成 物」）塡入所形成的洞孔中，並移除溶劑； (2) 令塡充的部分在輻射下曝露；以及 (3) 在曝露之後加熱塡充的部分。 接下來爲每個步驟提供詳細說明。 -28- 1379158 在第一個步驟（〗）中，舉例來說，藉運用雷射束燒 掉而移除形成於基材上之含紅、綠和藍三原色像素陣列的 彩色層有缺點的部分。經移除的部分形成無彩色層的洞孔 且從而暴露出底下基材的表面。 之後，以液態樹脂組成物施加於設備或裝置之針狀部 而有薄細的針狀物被塡入所形成的洞孔中。此塡充操作可 進行數次直到在洞孔中塡入所需量的液態樹脂組成物爲止 。另一種將液態樹脂組成物塡入洞孔的手段係利用分配器 擠出或藉噴墨系統滴下。 接下來，預烘烤所塡充的液態樹脂組成物使溶劑蒸發 而在洞孔中形成不含溶劑的輻射敏感樹脂組成物（後文也 稱之爲「樹脂組成物」）層。 關於預烘烤條件，在70至11 0 °C下預烘烤樹脂組成 物1至5分鐘。 關於樹脂組成物層的厚度，經修補部分的厚度較佳地 與正常部分彩色層的厚度相同或幾乎相同，並可視需要重 複塡充及預烘烤。 藉由本發明之濾色器缺點修補方法所修補之濾色器的 基材係由玻璃、矽、聚碳酸酯、聚酯、芳香族聚醯胺、聚 醯胺-醯亞胺 '聚醯亞胺、聚醚硕、玻璃烯烴或其經氫化 的產物之開環聚合物。 必要時，基材可進行例如利用矽烷偶合劑、電漿處理 、離子電鍍、濺鍍、氣體蒸氣反應或真空沈積等適當的預 處理。 -29- 1379158 在接下的步驟（2 )中，洞孔中的樹脂組成物層係於 . 輻射底下曝露而聚合並固化。 • 用於曝露的輻射可爲可見光輻射、紫外線輻射、遠紫 外線輻射、電子輻射及X-輻射。輻射較佳地具有190至 450 nm的波長。 輻射量較佳爲約10至10,000 J/m2。 在以下的步驟（3)中，加熱（後文中稱之爲「後烘 φ 烤」）經曝露的塡充部分而完全地聚合並固化樹脂組成物 並完全地分解殘餘光起始劑（D )以形成缺點已經修補好 的彩色層。 關於後烘烤條件，在2 0 0至2 5 0 °C下後烘烤2 0至6 0 分鐘。 本發明中’若進行步驟（1)至（3) —個循環之後經 修補部分與正常部分之間的色品有差異，較佳地重複進行 該循環以儘可能消除它們之間的色品差異。 # 本發明中’若兩個或多個不同濾色器的色相，移除每 個色相中有缺點的部分並使用與經移除之有缺點的部分具 相同色相的液態樹脂組成物以供如以上說明之相同方法的 修補°若特定色相中有缺點的部分非常小，只要濾色器的 性能沒有問題，就可與相鄰不同色相中有缺點的部分同時 地修補。 ® »本發明’因爲在修補濾色器缺點時液態樹脂組成 物只會完全地溼塗於藉移除有缺點的部分形成的洞孔並完 全地聚合並固化’所以經修補部分與正常部分之間沒有或 -30- 1379158 有非常小的色品差異，藉以經修補部分具有與正常部分幾 乎相同的性能而不會引起有缺點的部分周圍部分的新問題 0 因此，可以供修補濾色器缺點用之輻射敏感樹脂組成 物及本發明.的濾色器缺點之修補方法應用於包括供電子業 界的彩色液晶顯示器用之濾色器的不同濾色器之修補。 實施例 以下的實施例係供用於進一步說明本發明的目的而不 得視爲限制。在合成實施例中「份J表示「重量份」。 合成實施例1 將1份2,2’-偶氮雙（2,4-二甲基戊腈）及200份丙二 醇單甲基醚醋酸酯塡入配備冷卻管及攪拌器的燒瓶，然後 將15份甲基丙烯酸、15份苯乙烯、30份甲基丙烯酸苯甲 酯、20份丙三醇單甲基丙烯酸酯、2〇份N_苯基順丁烯二 醯亞胺及2.5份充當鏈轉移劑的α-甲基苯乙烯二聚體塡入 燒瓶’燒瓶內部以氮氣取代，溫和地攪拌最後產生的溶液 ’並將反應溶液的溫度升到8(rc，藉著維持該溫度3小 時而使溶液聚合。之後，將溫度升到100〇c，添加〇 5份 2.2’-偶氮雙（2,4-二甲基戊腈），另外再進行聚合〗小時 而獲得共聚物溶液（固含量3 3 2重量％ )。將此共聚物溶 液標註爲共聚物溶液（bi)。製得的共聚物具有14, 〇〇〇 之 Mw 及 6,000 之 Μη。 -31 - 1379158 合成實施例2 將1份2,2’_偶氮雙（2,4-二甲基戊腈）及200份環己 酮塡入配備冷卻管及攪拌器的燒瓶，然後將]5份甲基丙 烯酸' 15份單（2-甲基丙烯醯氧基乙基）丁二酸酯、20 份苯乙烯、25份甲基丙烯酸苯甲酯、25份N-苯基順丁烯 二醯亞胺及2.5份充當鏈轉移劑的α-甲基苯乙烯二聚體塡 入燒瓶，燒瓶內部以氮氣取代，溫和地攪拌最後產生的溶 液，並將反應溶液的溫度升到8 0 °C，藉著維持該溫度3 小時而使溶液聚合。之後，將溫度升到10(TC，添加0.5 份2.2’-偶氮雙（2,4_二甲基戊腈），另外再進行聚合1小 時而獲得共聚物溶液（固含量3 2.9重量％ )。將此共聚物 溶液標註爲共聚物溶液（b2 )。製得的共聚物具有1 5,000 之 Mw 及 7,40〇 之 Μη。 合成實施例3 將1份2,2’·偶氮雙（2,4-二甲基戊腈）及200份丙二 醇單甲基醚醋酸酯塡入配備冷卻管及攪拌器的燒瓶，然後 將15份甲基丙烯酸、10份ω_羧基己內酯單（甲基）丙烯 酸酯、15份苯乙烯、30份甲基丙烯酸苯甲酯、15份丙三 醇單甲基丙烯酸酯、15份Ν-苯基順丁烯二醯亞胺及2.5 份充當鏈轉移劑的α_甲基苯乙烯二聚體塡入燒瓶，燒瓶內 部以氮氣取代，溫和地攪拌最後產生的溶液，並將反應溶 液的溫度升到80艽，藉著維持該溫度3小時而使溶液聚 -32- 1379158 合。之後’將溫度升到100°C，添加0.5份2.2，-偶氮雙（ 2,4 -二甲基戊腈），另外再進行聚合1小時而獲得共聚物 溶液（固含量33.0重量％)。將此共聚物溶液標註爲共聚 物溶液（b3)。製得的共聚物具有12, 〇〇〇之Mw及5,700 之Μ η。 實施例1Poly fl ow, (Tokem Products Co., Ltd.) f Top, (D aini ρ ρ ο η I nkand C hemica 1 s Ltd.) μ egafac, (Sumitomo 3M Co., Ltd.) Florade, (Asahi Glass shares limited The company's) Asahi Guard and Surflon, (Byk Chemie Japan Co., Ltd.) Disperbyk and (Zeneca Co., Ltd.) Solsperse registered the name. These surfactants may be used singly or in combination of two or more. The amount of the dispersant is preferably 5 Å by weight or less, more preferably 30 parts by weight or less, based on 100 parts by weight of the pigment. - (B) Alkali-Soluble Resin - The alkali-soluble resin of the present invention has an acid functional group such as a carboxyl group or a phenolic hydroxyl group, is soluble in an aqueous alkaline solution, and is preferably used as a binder of the pigment (A). The alkali-soluble resin of the present invention is preferably a carboxyl group-containing resin, particularly preferably a vinylated unsaturated monomer having at least one carboxyl group (hereinafter referred to as "carboxyl-10-1379158-based unsaturated monomer"). Copolymer with another copolymerizable vinylated unsaturated monomer (hereinafter referred to as "copolymerizable unsaturated monomer") (hereinafter referred to as "carboxyl-containing copolymer") Examples of the carboxyl group-unsaturated monomer include (meth)acrylic acid 'crotonic acid, (unsaturated monocarboxylic acid such as X-chloroacrylic acid and cinnamic acid; maleic acid, maleic anhydride, and antibutene) Unsaturated dicarboxylic acid and its anhydride such as acid, itaconic acid, itaconic anhydride, citraconic acid, and the mesaconic acid; unsaturated polycarboxylic acid containing three or more carboxyl groups and Anhydride; mono [2-(methyl) propylene oxiranyl ethyl] succinate and mono [2-(methyl) propylene methoxyethyl] phthalate, etc. Mono((meth)acryloxyalkyl]esters of carboxylic acids; and ω·carboxypolycaprolactone mono(meth)acrylates a mono(meth)acrylate of a polymer having a carboxyl group and a hydroxyl group at the end. Among these carboxyl group-containing unsaturated monomers, it is commercially available (Toagosei Chemical Industry Co., Ltd.) Μ-5300 and M-5400. The registered name of the product is [2-(methyl)propenyloxyethyl] succinate and mono [2-(methyl) propylene methoxyethyl] phthalate. The unsaturated monomers may be used singly or in combination of two or more. Examples of the copolymerizable unsaturated monomer include styrene, (X-methylstyrene 'o-vinyltoluene, m-vinyltoluene). , p-vinyl toluene, p-chlorostyrene, o-methoxystyrene, m-methoxystyrene 'p-methoxystyrene, o-vinylbenzyl methyl ether, between -ethyl -11 - 1379158 benzyl benzyl ether, p-vinyl benzyl methyl ether, o-vinyl benzyl glycidyl ether, m-vinyl benzyl glycidyl ether and An aromatic ethylenic compound such as p-ethylene benzyl glycidyl acid; a section and a 1-methyl ganglion; Methyl acetonate, ethyl (meth)propionate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate Ester, second butyl (meth)acrylate, tert-butyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate 2-hydroxypropyl (meth)acrylate, (meth)acrylic acid 3 -Hydroxypropyl ester, 2-hydroxybutyl (meth)acrylate, 3-hydroxybutyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, allyl (meth)acrylate, (methyl) Benzyl acrylate, cyclohexyl (meth) acrylate, phenyl (meth) acrylate, 2-methoxyethyl (meth) acrylate, 2-phenoxyethyl (meth) acrylate, A Oxydiethylene glycol (meth) acrylate, methoxy triethylene glycol (meth) acrylate, methoxy propylene glycol (meth) acrylate, methoxy dipropylene glycol (meth) acrylate, Isobornyl (meth)acrylate, tricyclo(meth)acrylate [5. 2. 1. 02. 5] anthracene-8-ester, 2-hydroxy-3-phenyloxypropyl (meth)acrylate, and unsaturated carboxylic acid esters such as glycerol (meth) acrylate; 2-amine (meth) acrylate Ethyl ethyl ester '2-dimethylaminoethyl (meth)acrylate, 2-aminopropyl (meth)acrylate, 2-dimethylaminopropyl (meth)acrylate, (meth)acrylic acid Aminoalkyl esters of unsaturated carboxylic acids such as 3-aminopropyl ester and 3-dimethylaminopropyl (meth)acrylate: unsaturated carboxylic acid glycidyl esters such as glycidyl (meth)acrylate: acetic acid Vinyl esters such as vinyl ester, vinyl propionate, vinyl butyrate and vinyl benzoate-12-1379158; unsaturated ethers such as vinyl methyl ether, vinyl ethyl acid and allyl glycidyl ether Vinyl cyanide compounds such as (meth)acrylonitrile, α·chloroacrylonitrile and ethylene dicyandiamide; (meth)acrylamide, α-chloropropenylamine and indole-2-hydroxyethyl ( Unsaturated guanamine such as methyl acrylamide; unsaturated quinone imine such as cis-phenyleneimine and fluorene-cyclohexylmethyleneimine Class; 1,3- Aliphatic conjugated dienes such as butadiene, isoprene and chloroprene; and polystyrene, poly(methyl) methacrylate, poly(methyl) methacrylate and polyoxyalkylene oxide A macromonomer containing a mono(meth)acrylonitrile group at the end of a polymer molecular chain. These copolymerizable unsaturated monomers may be used singly or in combination of two or more. The carboxyl group-containing copolymer of the present invention is preferably a copolymer of the following (hereinafter referred to as "carboxyl group-containing copolymer (?1)"): (a carboxyl group-containing unsaturated monomer component which contains as an essential component (meth)acrylic acid and optionally at least one selected from the group consisting of mono[2-(methyl)propenyloxyethyl]succinate and ω-carboxypolycaprolactone mono(meth)acrylate The compound and (b) at least one selected from the group consisting of styrene, methyl (meth) acrylate '2-hydroxyethyl (meth) acrylate, allyl (meth) acrylate ' methacrylate (meth) acrylate, C Triol mono(meth)acrylate, indole phenyl maleimide, polystyrene megamonomer, and polymethyl methacrylate megamonomer. Illustrative of carboxyl group-containing copolymer (Α1) Examples include a copolymer of (meth)acrylic acid and methyl (meth)acrylate, a copolymer of (meth)acryl-13-1379158 acid and benzyl (meth)acrylate, (meth)acrylic acid, Copolymer of 2-hydroxyethyl (meth)acrylate and benzyl (meth)acrylate, (methyl a copolymer of acrylic acid, methyl (meth) acrylate and polystyrene megamonomer '(meth)acrylic acid, methyl (meth) acrylate and polymethyl methacrylate megamonomer, (A Copolymer of acrylic acid, benzyl (meth) acrylate and polymethyl methacrylate mega monomer, (meth)acrylic acid, 2-hydroxyethyl (meth) acrylate, benzoyl (meth) acrylate a copolymer of an ester and a polystyrene megamonomer, a copolymer of (meth)acrylic acid, 2-hydroxyethyl (meth)acrylate, benzyl methacrylate and benzyl (meth)acrylate, (a) Acrylic acid, styrene, copolymer of benzyl (meth) acrylate and N-phenyl maleimide, (meth)acrylic acid, mono [2-(methyl) propylene oxy oxy group B Copolymer of succinic acid ester, styrene, benzyl (meth) acrylate and N-phenyl maleimide, (meth)acrylic acid, mono [2-(methyl) acrylonitrile Oxyethyl] succinate, styrene, allyl (meth) acrylate and N-phenylbutylene a copolymer of an amine, a copolymer of (meth)acrylic acid, styrene, benzyl (meth)acrylate, a glycerol mono(meth)acrylate and N-phenylmaleimide and ( Methyl)acrylic acid, ω-carboxypolycaprolactone mono(meth)acrylate, styrene, benzyl (meth)acrylate, glycerol mono(meth)acrylate and fluorene-phenyl-n-butylene The copolymer of diimine. In the present invention, the content of the carboxyl group-containing unsaturated monomer in the carboxyl group-containing copolymer is preferably from 5 to 50% by weight, more preferably from 1 to 4% by weight. The content of the radiation-sensitive resin composition prepared may be less than 5% by weight, and the stability may be lowered, and if the content is more than 50% by weight, the resin composition may be gelled during polymerization. In the case of polystyrene, it is penetrated by gel. GPC, solvent for extraction: tetrahydrofuran) The average molecular weight of the alkali-soluble resin (hereinafter referred to as "Mw") is preferably 300. 000 > Better 5,000 to 00,000. The average number of alkali-soluble resin components measured by gel permeation chromatography (GPC agent: tetrahydrofuran) in terms of polystyrene is hereinafter referred to as "Μη"), preferably 3,000 to 60,000. 000 to 25,000. The Mw/Mn of the alkali-soluble resin is preferably from 1 to 5, more preferably, in the present invention, by using a fat component having a specified Mw and Μη, the dispersibility of the pigment becomes high, and thus the storage stability of the present invention can be obtained. Composition. In the present invention, the alkali-soluble resins may be used singly or in combination. The amount of the alkali-soluble resin in the present invention is preferably from 10 to 1,000 parts by weight, more preferably 5 parts by weight, based on 100 parts by weight of hydrazine. If the amount of the alkali-soluble resin is less than 10 parts by weight of the unstable dispersion, the pigment may precipitate upon storage. 1, the weight of the component, the viscosity of the composition may become too high, the shape may be difficult to self-repair equipment or device for needle-shaped radiation-sensitive chromatography (weight of 3,000 to, eluted molecular weight (More preferably, 1 to 4 alkali-soluble trees have excellent two or more pigments (ground 20 to 'because the amount of pigment is larger than this liquid is removed. -15- 1379158 - (c) polyfunctional monomer or polyfunctional Combination of a base monomer and a monofunctional monomer - The polyfunctional monomer of the present invention is a monomer of two or more polymerizable unsaturated bonds. Examples of the polyfunctional monomer include ethylene glycol and propylene glycol. a di(meth) acrylate of a diol; a polyethylene glycol containing two or more ethoxylated groups; and a polyalkylene glycol such as a polypropylene glycol having two or more propoxy propylene groups. Methyl acrylates; poly(meth) acrylates of polyhydric alcohols containing 3 or more hydroxyl groups, such as glycerol, trimethylolpropane, pentaerythritol and dipentaerythritol, and their dicarboxylic acid modified products ; polyester, epoxy resin, urethane resin, alkyd resin, decane Oligomerized (meth) acrylates such as resins and spiro resins; poly-butadienes containing hydroxyl groups at both ends, polyisoprene having hydroxyl groups at both ends, and poly-caps containing hydroxyl groups at both ends a bis(meth) acrylate of a polymer having hydroxyl groups at both ends of a molecular chain such as vinegar; and ginseng [2·(meth) propylene methoxyethyl] citrate in these polyfunctional monomers Among them, poly(meth)acrylic acid vinegar containing 3 or more transbasic polyhydric alcohols and products modified therefrom, such as trimethylolpropane tri(meth)acrylate, is preferred. Pentaerythritol tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, dipentaerythritol penta(meth)acrylate vinegar and dipentaerythritol hexa(methyl)propionate. Particularly preferred is trimethylolpropane tri Methyl) acrylate, pentaerythritol tris(meth)propionate and dipentaerythritol hexa(meth) acrylate, because they are rapidly polymerized and cured under irradiation to become non-16-1379158 fluidity. * The above functional group monomers may be used singly or in combination of two or more. 〇 The amount of the polyfunctional monomer is preferably from 350 to 1,000 parts by weight based on 100 parts by weight of the alkali-soluble resin (B). More preferably, it is 350 to 700 parts by weight or less. If the amount of the polyfunctional monomer is less than 350 parts by weight, the curing by exposure may become inappropriate and the portion required after curing may become a fluid. If the amount is more than 1, 〇〇〇 by weight, the viscosity of the resulting composition becomes too low, so that when the composition breaks into the hole, the composition may hardly adhere to the equipment for repair or The needle portion of the device. In the present invention, a part of the polyfunctional monomer can be substituted by a monofunctional monomer having a polymerizable unsaturated bond. The above monofunctional monomer examples include a carboxyl group-containing unsaturated monomer and a copolymerizable unsaturated monomer for the above carboxyl group-containing copolymer, N-(methyl)propenylmorpholine, N-vinylpyridone 'N_Ethylene φ-based-caprolactam and commercially available (Toagosei Chemical Industry Co., Ltd.) M-5300 and M-5400. These monofunctional monomers may be used singly or in combination of two or more. The amount of the monofunctional monomer is preferably 90% by weight or more based on the total amount of the polyfunctional monomer and the monofunctional monomer. Less, more preferably 50% by weight or less. If the amount of the monofunctional monomer is more than 90% by weight, the strength and surface smoothness of the repaired portion may become inappropriate. The total amount of the -17-1379158 polyfunctional monomer and the monofunctional monomer in the present invention is from 350 to 1,000 parts by weight, preferably 350, based on 100 parts by weight of the alkali-soluble resin (B). Up to 700 parts by weight. If the total amount is less than 350 parts by weight, the strength and surface smoothness of the repaired portion may be lowered, and if the total amount is more than 1, 重量0 parts by weight, the viscosity of the obtained composition becomes too low, thereby When the composition breaks into the hole, the composition may hardly adhere to the needle portion of the device or device for repair. • (D) Photoinitiator · The photoinitiator of the present invention is radiantly exposed to visible radiation, ultraviolet radiation 'far ultraviolet radiation, electron radiation, and X-ray (hereinafter referred to as "exposure"). Further, a compound which forms a radical which can initiate polymerization of the above component (C) is formed. Examples of the photoinitiator include an acetone-based compound, a biimidazole-based compound, a triazine-based compound, a benzoin-based compound, an benzophenone-based compound, an α-diketone-based compound, a polynuclear lanthanide compound, and a xanthene A ketone compound and a diazo compound. In the present invention, the above photoinitiators may be used singly or in combination of two or more. The photoinitiator of the present invention is preferably at least one selected from the group consisting of an acetone compound, a biimidazole compound, and a triazine compound. The light-initiating dose of the present invention is preferably 0. by weight of the component (C). 01 to 80 parts by weight, more preferably 1 to 60 parts by weight. If the amount of the photoinitiator is less than 0.1 part by weight, the partially cured portion may become a fluid due to incomplete curing due to exposure. If the amount is more than 80 parts by weight, the photoradical generator is hardly soluble in the composition, and the characteristics of the repaired portion acting as a color filter may be impaired by -18-1379158. Examples of the ethyl ketone-based compound among the agents include 2-hydroxy-2-methyl-1-phenylacetone-1,2-methyl-1-(4-methylthienyl)-2-(morpholinyl) Acetone-1,2-benzyl-2-dimethylamino-1-(4-morpholinylphenyl)butanone-1, 1-hydroxycyclohexyl phenyl ketone and 2,2-dimethyl Oxy-1,2-diphenylethanone-1. Among these acetone compounds, 2-methyl-]-(4-methylthienyl)-2-(morpholinyl)acetone-1 and 2-benzyl-2-dimethyl group are particularly preferred. Amino-1-(4-morpholinylphenyl)butanone-1. The acetone compounds below may be used singly or in combination of two or more. When the acetone compound is used as the photoinitiator of the present invention, the amount of the acetone compound is preferably 0 based on 100 parts by weight of the component (C). 01 to 80 parts by weight, more preferably 1 to 60 parts by weight, particularly preferably 1 to 3 parts by weight. If the amount of the acetone compound is less than 〇. 〇 1 part by weight, after partial curing by the repair, may become a fluid due to incomplete curing due to exposure. If the amount is more than 80 parts by weight, the acetone compound is hardly dissolved in the composition, whereby the characteristics of the repaired portion serving as a color filter may be impaired. Examples of biimidazole-based compounds include 2,2'-bis(2-chlorophenyl)-4,4',5,5'-indole (4-ethoxycarbonylphenyl)-1,2'-biimidazole , 2,2'·bis(2-bromophenyl)·4,4′,5,5′·肆(4-ethoxycarbonylphenyl)biimidazole, 2,2′-bis(2-chlorophenyl) -4,4',5,5'-tetraphenyl-1,2'-biimidazole, 2,2'-bis(2,4-dichlorophenyl)-4,4',5,5, -tetraphenyl-1,2'-biimidazole, -19- 1379158 2,2'-bis(2,4,6-trichlorophenyl)-4,4',5,5,-tetraphenyl- 1,2,2'-bis(2-bromophenyl)-4,4',5,5'-tetraphenyl-1,2,2,2'-bis(2,4-dibromophenyl) )-4,4',5,5'-tetraphenyl-1,2'. 2,2'-bis(2,4,6-tribromophenyl)-4,4,5,5,- Tetraphenyl-1, hydrazine among these biimidazole compounds, preferably 2, 2'. Phenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole, 2,2,-bis(phenyl)-4,45,5,5'-tetraphenyl- 1,2'-biimidazole and 2,2'-dichlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole, and especially bis(2,4- Dichlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-bimethicone | The above biimidazole-based compound has excellent but no insoluble products and precipitates in a solvent A foreign substance, such as a small amount of energy exposure, can completely contribute to the curing reaction and prevent the flow of the repaired portion after curing. The above biimidazole compounds may be used singly or in combination. When the biimidazole compound is used as the photoinitiator of the present invention in parts by weight based on the component (C), the biimidazole compound is 0. 01 to 40 parts by weight, more preferably 1 to 30 parts by weight, particularly 20 parts by weight. If the amount of the biimidazole compound is less than 〇. 〇1 Heavy Repair of incomplete solids that may result from exposure after partial cure. If the amount is more than 40 parts by weight, the biimidazole compound is several components in the composition and can be used as a color filter with the repaired portion. 2 '-imidazolidine, biimidazole and 2'-biimidazole-bis(2-chloro : 2,4-dichloro (2,4,6·three I is 2,2,-sit. Solubility, commercial sensitivity can be effectively two or more, preferably 1 to 0, preferably 1 to the amount If it is converted to become insoluble, it will be damaged. -20-1379158 - Hydrogen donor - If a biimidazole compound is used as the photoinitiator of the present invention, it is preferred to use it in combination with the following hydrogen donor. Further, the sensitivity is further improved. The term "hydrogen donor j" as used herein means a compound which can provide a radical formed by a hydrogen atom to a biimidazole compound by exposure. The hydrogen donor of the present invention is preferably a thiol system defined later. A compound or an amine compound. The above thiol compound is a benzene ring or a hetero ring which serves as a mother nucleus, and has 1 or more, preferably 1 to 3, more preferably 1 or 2 directly bonded. a thiol-based compound to the mother nucleus of the molecule (hereinafter referred to as "thiol-based hydrogen donor"). The compound is a compound containing a benzene ring or a heterocyclic ring serving as a mother nucleus, and having 1 or more, preferably 1 to 3, more preferably 1 or 2 amine groups directly bonded to the mother nucleus of the molecule (hereinafter referred to as "amine-based hydrogen donor"). The hydrogen donor may contain both a thiol group and an amine group. A detailed description of these hydrogen donors will be provided below. The thiol-based hydrogen donor may be in the molecule. Containing at least one benzene ring or heterocyclic ring, or both. If it contains two or more rings, it may or may not form a fused ring. If the thiol-based hydrogen donor contains two or more thiols a base, as long as at least one free thiol group is maintained, at least one other thiol group may be substituted by a deutero group, an aralkyl group or an aryl group. Further, as long as at least one free thiol-21 - 1379158 group is maintained, sulfur The alcohol-based hydrogen donor may have a structural unit in which two sulfur atoms are bonded together by a divalent organic group such as an alkyl group, or a structural unit in which two sulfur atoms are bonded together in the form of a disulfide. Further, the thiol-based hydrogen donor may be substituted by a carboxyl group, an alkoxycarbonyl group or a position other than the thiol group. An alkoxycarbonyl group, a phenoxycarbonyl group, a substituted phenoxycarbonyl group or a nitrile group. Examples of the thiol-based hydrogen donor include 2-thiol benzothiazole, 2 φ thiol benzoxazole, 2-thiolbenzimidazole, 2,5-dithiol-1,3,4-thiadiazole and 2-thiol-2,5-dimethylaminopyridine. Among these thiol systems Among the hydrogen donors, it is preferably 2, 5. Dithiol group 1,1,4-thiadiazole and 2-thiol-2,5-dimethylaminopyridine, and particularly preferably 2-thiol-2,5-dimethylamine Pyridine. The amine-based hydrogen donor may contain at least one benzene ring or heterocyclic ring in the molecule, or both. If it contains two or more rings, a blending ring may or may not be formed. φ At least one amine group of the amine-based hydrogen donor may be substituted with an alkyl group or a substituted substituent. The amine-based hydrogen donor may be substituted at a position other than the amine group by a carboxyl group, an alkoxy group, a substituted alkoxycarbonyl group, a phenoxycarbonyl group, a substituted phenoxy group or an eye group. Examples of the above amine-based hydrogen donor include 4,4'-bis(dimethylamino)benzophenone, 4,4,-bis(diethylamino)benzophenone, 4·diethyl Aminobenzophenone, 4-dimethylaminobenzophenone, ethyl-4-dimethylaminobenzoic acid vinegar, 4-dimethylaminobenzoic acid ester, and 4-dimethylamino group Benzoonitrile. Among these amine-based hydrogen donors, preferred are 4,4,-bis(dimethylamine-22- 1379158-yl)benzophenone and 4,4'-bis(diethylamino)benzophenone. Further preferred is 4,4'-bis(diethylamino)benzophenone. When a photoinitiator other than a biimidazole compound is used, an amine hydrogen donor is used as a sensitizer. In the present invention, the above hydrogen donors may be used singly or in combination of two or more. It is preferred to use at least one thiol hydrogen donor and at least one. A combination of amine-based ammonia donors to prevent flow caused by exposure to solidification. Examples of the combination of a thiol-based hydrogen donor and an amine-based hydrogen donor include a combination of 2-thiol benzothiazole with 4,4'-bis(dimethylamino)benzophenone, 2-thiol Combination of benzothiazole with 4,4'-bis(diethylamino)benzophenone, 2-thiol benzo Pfazole and 4,4'-bis(dimethylamino)benzophenone Combination of 2, thiol benzo Pfazole with 4,4'-bis(diethylamino)benzophenone. Preferably, the combination of 2-thiol benzo- oxazole and 4,4'-bis(dimethylamino)benzophenone and 2·thiol benzoxazole and 4,4′-double (two The combination of ethylamino)benzophenone is particularly preferably a combination of 2-thiol benzoxazole and 4,4'-bis(dimethylamino)benzophenone. The weight of the thiol-based hydrogen donor to the amine-based hydrogen donor in the combination of the thiol-based hydrogen donor and the amine-based hydrogen donor is preferably from 1:1 to 1:4, more preferably from 1:1 to 1: 3° If a hydrogen donor and a biimidazole compound are used in combination in the present invention, the amount of the hydrogen donor is preferably 〇 based on the weight of the component (C). From 1 to 4 parts by weight, more preferably from 1 to 30 parts by weight, particularly preferably from 20 parts by weight. If the amount of the hydrogen donor is less than 0.101 parts by weight, the effect of improving the sensitivity may be lowered. If the amount is more than 40 parts by weight, the hydrogen donor may be almost insoluble in the group -23- 1379158 and the characteristics of the repaired portion acting as a color filter may be impaired. . Examples of the above triazine-based compound include 2,4,6-paraxyl (trichloromethyl)-symmetric-triazine, 2-methyl-4,6-bis(trichloromethyl)-symmetric-triazine . 2-[2-(5-methylfuran. 2-yl)vinyl]_4,6-bis(trichloromethyl)-symmetric-triazine, 2-[2-(furan-2-yl)vinyl]-4,6-bis(trichloromethyl) )-symmetric-triazine, 2-[2-(4-diethylamino-2-methylphenyl)vinyl]-4,6-bis(trichloromethyl)-symmetric-triazine, 2 -[ 2-( φ 3,4·Dimethoxyphenyl)vinyl]-4,6-bis(trichloromethyl). Symmetry · Triazine, 2-(4-methoxyphenyl)_4,6-bis(trichloromethyl)_symmetric-triazine, 2-(4-ethoxystyryl)·4,6_ A compound containing a halogen methyl group such as bis(trichloromethyl)-symmetric _triazine. Among the above triazine-based compounds, 2-[2-(3,4-dimethoxyphenyl)ethenyl]-4,6-bis(trichloromethyl)-symmetric-triazine is preferred. The above triazine-based compounds may be used singly or in combination of two or more. • When a triazine-based compound is used as the photoinitiator of the present invention, the amount of the triazine-based compound is preferably from 4 to 4 parts by weight based on 100 parts by weight of the component (C). 1 to 30 parts by weight, particularly preferably 1 to 2 parts by weight. If the amount of the triazine-based compound is less than 〇·〇丨 by weight, the cured portion may become a fluid due to incomplete curing due to exposure after curing. If the amount is more than 40 parts by weight, the triazine-based compound may hardly dissolve in the composition and may be impaired in the characteristics of the repaired portion serving as a color filter. - Additive - -24- I3? 9158 Various additives may be added as necessary to the radiation-sensitive resin composition for use in the present invention. The above additives include a blue pigment derivative 'i.e., a phthalocyanine derivative, and the like, a dispersing aid; a polyvinyl alcohol, a polyethylene glycol monoalkyl ether or a poly (such as a polymer blend: nonionic, Cationic agent; vinyl trimethoxy decane, vinyl trisyl (2-methoxyethoxy) decane, Ν-(2-, -methyldimethoxy decane, Ν-(2- Aminoethyl)·decane, 3-aminopropyltriethoxydecane' 3-ketaloxydecane, 3-glycidoxypropylmethyl group (3,4-epoxycyclohexyl)ethyl Trimethoxy 矽•dimethoxydecane, 3-chloropropyltrimethoxyindole propyltrimethoxydecane or 3-thiolpropyl accelerator: 2,2-thiobis(4- An antioxidant such as methyl-6-third third butyl phenol; a coagulation inhibitor such as 2-(3-triphenyl)-5-chlorobenzotriazine or alkoxybenzophenone sodium polyacrylate; And 1,1'-*carbonitrile) or 2·phenylazo-4-methoxy-2,4-diyl generator. -(Ε) solvent - preferably, the solvent of the present invention will be dispersed or The components (A) to (D) of the fat-soluble composition and the disadvantages of adding a color filter for repair or Yellow pigment derivative glass or alumina such as fluoroalkyl acrylate) or anionic interface active ethoxy decane, ethylene ethyl)-3-aminopropyl 3-aminopropyltrimethoxy glyceryl propyl Trimethyldimethoxydecane, 2-yard, 3-chloropropyl·methyl:, 3-methylpropenyloxytrimethoxydecane, etc. or 2,6-di'yl-5- Ultraviolet absorber such as methyl-2-hydroxy; nitro-bis(cyclohexane-1-methylvaleronitrile) is a free radical solution that forms a radiation-sensitive tree and does not react with these -25-1379158. Examples include, for example, ethylene glycol monomethyl acid, ethylene glycol monoethyl ether, ethylene glycol mono-n-propyl ether 'ethylene glycol mono-n-butyl acid, diethylene glycol monomethyl ether, diethylene glycol Monoethyl ether, diethylene glycol mono-n-propyl ether 'diethylene glycol mono-n-butyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol Monoethyl ether, propylene glycol mono-n-propyl ether, propylene glycol mono-n-butyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol mono-n-propyl ether, dipropylene glycol single positive a polyalkylene ether such as ethylene glycol monomethyl ether acetate vinegar or ethylene glycol monoethyl ether acetate; Ester, ethylene glycol mono-n-propyl ether acetate, ethylene glycol mono-n-butyl acid acetate, diethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, propylene glycol monomethyl Ethyl acetate and propylene glycol monoethyl ether acetate (poly) alkyl glycol monoalkyl ether acetate; for example, diethylene glycol dimethyl ether, diethylene glycol methyl ethyl ether, diethyl Other ethers such as diol diethyl ether, tetrahydrofuran, benzyl ethyl ether and di-n-hexyl ether; for example, ketones such as methyl ethyl ketone, 2-heptanone, 3 · heptanone, and cyclohexanone; for example, lactic acid An alkyl lactate such as methyl ester or ethyl lactate; for example, ethyl 2-hydroxy-2-methylpropionate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, 3-ethoxy Methyl propyl propionate, ethyl 3-ethoxypropionate, ethyl ethoxyacetate, ethyl hydroxyacetate, methyl 2-hydroxy-3-methylbutyrate, 3-methoxybutyl acetate, 3-methyl-3-methoxybutyl Acetate, 3-methyl-3.methoxybutylpropionate, ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, n-amyl formate, acetic acid Amyl ester, n-butyl propionate, ethyl butyrate, stearyl -26-1379158 n-propyl acrylate, isopropyl citrate, n-butyl butyrate, methyl pyruvate, ethyl pyruvate, n-propyl pyruvate Other esters such as ethyl acetate, ethyl acetate, ethyl 2-acetoxybutyrate, benzyl acetate, ethyl benzoate, diethyl oxalate and diethyl maleate; for example, toluene And aromatic hydrocarbons such as xylene; for example, N-methylpyridone, hydrazine, hydrazine-dimethylformamide, and guanamine such as n,N-dimethylacetamide; and acetone-acetone, iso-fossil Isophorone, ethyl hexanoate, octanoic acid, 1-octyl alcohol, 1-nonanol, benzyl alcohol, diacetone alcohol, 3-methoxy-3-methyl-1-butanol, γ-butyrolactone Ethylene carbonate, propylene carbonate, ethylene glycol monophenyl ether acetate and 3-methoxy-3-methyl-1-butanol. These solvents may be used singly or in combination of two or more. As a result of investigations by the inventors of the present invention, it has been found that if the radiation-sensitive resin composition which is formed by the hole formed by removing the defective portion is dried too fast, it is not suitable for repair because the composition is in use. Dry and cure the needle portion of the repaired device or device before it reaches the portion to be filled. Therefore, the average vapor pressure (hereinafter simply referred to as "average vapor pressure") of the solvent used for the radiation-sensitive resin composition for the purpose of repairing the color filter of the present invention must be less than 3. 0 mmHg. The average vapor pressure is preferably 0. 1 or higher and lower than 3. 0 mmHg, more preferably 1. 0 or higher and lower than 3 · 0 m m H g. In the present invention, the average vapor pressure of the solvent is adjusted to less than 3. 0 mmHg 値, my. At least one selected from the group consisting of ethylene glycol mono-n-butyl ether acetate, diethylene glycol methyl ethyl ether, 3-ethoxypropionic acid ethyl ester, diethylene glycol methyl ethyl acid, 3- Ethyl ethoxypropionate, N-methylpyridone, di-27-1379158 acetol, 3-methoxy-3-methyl-1-butanol and γ-butyrolactone, preferably at least A solvent selected from the group consisting of ethylene glycol monobutyl ether acetate, diethylene glycol methyl ethyl ether and ethyl 3-ethoxypropionate is used. These solvents do not adversely affect the dispersibility of the pigment. In the present invention, any of the above solvents may be used in combination with another solvent listed as needed. The solvent amount of the present invention is such that the solid content of the radiation-sensitive resin composition is preferably from 25 to 50% by weight, more preferably from 25 to 35% by weight, based on the fluidity and stability of the composition. The chromaticity difference between the repaired part and the normal part is minimized. The solid content of the radiation-sensitive resin composition is 値 calculated from (total weight of components other than solvent) / (total weight of composition) χΙΟΟ. Patching method for color filter defects The color filter is composed of a color layer formed on a substrate containing a red-green and blue primary color pixel array. Therefore, the term "color filter defect" as used herein refers to a disadvantage in a color layer containing three primary color pixel arrays of red, green and blue. The method for repairing the defects of the color filter of the present invention sequentially comprises the following steps (1) removing the defects of the color filter, and the present invention is applied to a radiation-sensitive resin composition for repairing the defects of the color filter (hereinafter referred to as " The liquid resin composition ") breaks into the formed holes and removes the solvent; (2) exposes the filled portion to radiation; and (3) heats the filled portion after exposure. Next, provide a detailed description of each step. -28- 1379158 In the first step (), for example, by using a laser beam to burn off the defective portion of the color layer of the red, green and blue primary color pixel array formed on the substrate . The removed portion forms a hole in the achromatic layer and thereby exposes the surface of the underlying substrate. Thereafter, a liquid resin composition is applied to the needle portion of the apparatus or device, and a thin needle is inserted into the formed hole. This charging operation can be carried out several times until the required amount of the liquid resin composition is poured into the holes. Another means of breaking the liquid resin composition into the hole is by means of a dispenser or by an ink jet system. Next, the solvent-filled liquid resin composition is prebaked to evaporate the solvent to form a solvent-free radiation-sensitive resin composition (hereinafter also referred to as "resin composition") layer in the pores. Regarding the prebaking conditions, the resin composition was prebaked at 70 to 110 ° C for 1 to 5 minutes. Regarding the thickness of the resin composition layer, the thickness of the repaired portion is preferably the same as or nearly the same as the thickness of the normal portion colored layer, and may be repeatedly filled and pre-baked as needed. The substrate of the color filter repaired by the color filter defect repairing method of the present invention is made of glass, ruthenium, polycarbonate, polyester, aromatic polyamine, polyamidamine-imine. A ring-opening polymer of a polyether, a glass olefin or a hydrogenated product thereof. If necessary, the substrate can be subjected to appropriate pretreatment such as decane coupling agent, plasma treatment, ion plating, sputtering, gas vapor reaction or vacuum deposition. -29- 1379158 In the next step (2), the resin composition layer in the hole is tied to . It is polymerized and cured by exposure to radiation. • Radiation for exposure can be visible radiation, ultraviolet radiation, far ultraviolet radiation, electron radiation, and X-radiation. The radiation preferably has a wavelength of from 190 to 450 nm. The amount of radiation is preferably from about 10 to 10,000 J/m2. In the following step (3), heating (hereinafter referred to as "post-bake φ baking") completely polymerizes and cures the resin composition through the exposed entangled portion and completely decomposes the residual photoinitiator (D) To form a color layer that has been repaired by a defect. For post-baking conditions, post-baking at 20 to 250 ° C for 20 to 60 minutes. In the present invention, if the chromaticity between the repaired portion and the normal portion is different after performing the steps (1) to (3), it is preferable to repeat the cycle to eliminate the chromaticity difference between them as much as possible. . In the present invention, if the hue of two or more different color filters is used, the defective portion of each hue is removed and a liquid resin composition having the same hue as the removed defective portion is used. The repair of the same method as described above. If the defective portion of the specific hue is very small, as long as the performance of the color filter is not problematic, it can be repaired simultaneously with the defective portion of the adjacent different hue. ®»The present invention' because the liquid resin composition is only completely wet-coated on the hole formed by removing the defective portion and completely polymerized and solidified when repairing the defect of the color filter, so the repaired portion and the normal portion are There is no or -30- 1379158 there is a very small chromaticity difference, so that the repaired part has almost the same performance as the normal part without causing a new problem of the defective part. Therefore, it is possible to repair the color filter defects. Radiation-sensitive resin composition and the invention. The method of repairing the color filter defects is applied to the repair of different color filters including color filters for color liquid crystal displays for the electronics industry. EXAMPLES The following examples are intended to further illustrate the objectives of the invention and are not to be considered as limiting. In the synthesis example, "part J represents "parts by weight". Synthesis Example 1 1 part of 2,2'-azobis(2,4-dimethylvaleronitrile) and 200 parts of propylene glycol monomethyl ether acetate were poured into a flask equipped with a cooling tube and a stirrer, and then 15 a portion of methacrylic acid, 15 parts of styrene, 30 parts of benzyl methacrylate, 20 parts of glycerol monomethacrylate, 2 parts of N-phenyl maleimide and 2. 5 parts of α-methylstyrene dimer serving as a chain transfer agent were poured into the flask 'the inside of the flask was replaced with nitrogen, the resulting solution was gently stirred' and the temperature of the reaction solution was raised to 8 (rc, by maintaining The solution was polymerized at a temperature of 3 hours. Thereafter, the temperature was raised to 100 〇c, and 5 parts of hydrazine was added. 2'-Azobis(2,4-dimethylvaleronitrile) was further subjected to polymerization for a period of time to obtain a copolymer solution (solid content: 332 wt%). This copolymer solution was labeled as a copolymer solution (bi). The resulting copolymer had a Mw of 14, 〇〇〇 and a Μ of 6,000. -31 - 1379158 Synthesis Example 2 1 part of 2,2'-azobis(2,4-dimethylvaleronitrile) and 200 parts of cyclohexanone were poured into a flask equipped with a cooling tube and a stirrer, and then] 5 parts of methacrylic acid '15 parts of mono(2-methylpropenyloxyethyl) succinate, 20 parts of styrene, 25 parts of benzyl methacrylate, 25 parts of N-phenyl-butylene醯imine and 2. 5 parts of α-methylstyrene dimer serving as a chain transfer agent were poured into the flask, the inside of the flask was replaced with nitrogen, the resulting solution was gently stirred, and the temperature of the reaction solution was raised to 80 ° C by maintaining This temperature was allowed to polymerize for 3 hours. After that, raise the temperature to 10 (TC, add 0. 5 copies 2. 2'-Azobis(2,4-dimethylvaleronitrile), and further polymerization was carried out for 1 hour to obtain a copolymer solution (solid content 3 2. 9% by weight). This copolymer solution was labeled as a copolymer solution (b2). The resulting copolymer had a Mw of 15,000 and a Μη of 7,40〇. Synthesis Example 3 1 part of 2,2'-azobis(2,4-dimethylvaleronitrile) and 200 parts of propylene glycol monomethyl ether acetate were poured into a flask equipped with a cooling tube and a stirrer, and then 15 Methyl methacrylate, 10 parts of ω-carboxycaprolactone mono (meth) acrylate, 15 parts of styrene, 30 parts of benzyl methacrylate, 15 parts of glycerol monomethacrylate, 15 parts of bismuth - Phenyl maleimide and 2. 5 parts of α-methylstyrene dimer serving as a chain transfer agent were poured into the flask, the inside of the flask was replaced with nitrogen, the resulting solution was gently stirred, and the temperature of the reaction solution was raised to 80 Torr by maintaining the temperature. The solution was poly-32- 1379158 for 3 hours. After that, the temperature is raised to 100 ° C, and 0 is added. 5 copies 2. 2,-azobis(2,4-dimethylvaleronitrile), and further polymerization for 1 hour to obtain a copolymer solution (solid content 33. 0% by weight). This copolymer solution was labeled as a copolymer solution (b3). The resulting copolymer had a Mw of 12, 〇〇〇 and a Μ η of 5,700. Example 1
<正常部分及洞孔之形成> 將90重里份充當顔料（Α，）之C.I. Pigment Red 254 與 C.I_ Pigment Yellow 139 的混合物（重量比 82/18)、 20重量份（就固含量來看8重量份）充當分散劑的 Disperbyk-2000 (固含量：40.0重量°/。，溶劑：重量比i:i 之甲氧基丙醇醋酸與2_ 丁氧基乙醇的混合溶劑）、210.8 重量份（就固含量來看70重量份）充當鹼溶性樹脂（B’ )的共聚物溶液（bl)(固含量：33.2重量％)、80重量 份充當多官能基單體（C’）的二季四醇六丙烯酸酯、30 重量份充當光起始劑（D’）的2-苯甲基-2-二甲基胺基-1-(4·嗎琳基苯基）丁酮-1及859.2重量份充當溶劑（E’） 之3 -乙氧基丙酸乙酯與丙二醇單甲基醚醋酸酯（重量比 34.9/65.1 )的混合溶劑混合在一起而製備液態樹脂組成物 (CFR1)。 利用旋塗機將此液態樹脂組成物（CFR1 )施塗於含 表面上形成用於防止鈉離子洗提的5丨02膜之鹼石灰玻璃 基材（150 mm xl50 mm)的表面並在 80 °C下加熱的加熱 -33-<Formation of normal portion and pores> A mixture of CI Pigment Red 254 and C.I_ Pigment Yellow 139 (weight ratio 82/18), 20 parts by weight as a pigment (Α,), 20 parts by weight (on solid content) 8 parts by weight) Disperbyk-2000 (solid content: 40.0 wt%, solvent: weight ratio i: i of a mixed solvent of methoxypropanol acetic acid and 2-butoxyethanol) serving as a dispersant, 210.8 parts by weight The fraction (70 parts by weight in terms of solid content) serves as a copolymer solution (b1) of the alkali-soluble resin (B') (solid content: 33.2% by weight), and 80 parts by weight of the second season serving as the polyfunctional monomer (C') Tetraol hexaacrylate, 30 parts by weight of 2-benzyl-2-dimethylamino-1-(4·berlinylphenyl)butanone-1 as a photoinitiator (D') and 859.2 A liquid resin composition (CFR1) was prepared by mixing together a mixed solvent of ethyl 3-ethoxypropionate serving as a solvent (E') and propylene glycol monomethyl ether acetate (weight ratio 34.9/65.1). The liquid resin composition (CFR1) was applied to the surface of the soda-lime glass substrate (150 mm x 150 mm) on the surface containing a 5 丨 02 film for preventing sodium ion elution using a spin coater at 80 °. Heating under C-33-
1379158 板上預烘烤2分鐘而使溶劑蒸發並形成： 之後，令此基材暴露於100 mJ/cm2的紫 22〇°C下加熱的乾淨烘箱中後烘烤30分鐘 厚正常紅色層。 之後，藉（NTN股份有限公司的） 加雷射束而燒掉紅色層以於基材中心形成 <缺點修補性之評估〉 將1〇〇重量份充當顏料（A )之（：.1· 與 C.I. Pigment Yellow 139 的混合物（I 25重量份（就固含量來看1〇重量份 Disperbyk-200 0、60.2重量份（就固含量 )充當鹼溶性樹脂（B )的共聚物溶液（ 3 3 · 2重量％ )、丨3 0重量份充當多官能差 季四醇六丙烯酸酯、20重量份充當光起好 甲基-2-二甲基胺基-1- (4-嗎啉基苯基） 重量份充當溶劑（E)之3 -乙氧基丙酸乙 基醚醋酸酯及二乙二醇單正丁基醚醒 59·0/9.4/3K6)的混合溶劑混合在一起而 成物（RR1)。 以100重量份之成分（B )來看，此 (RR1)具有650重量份的成分（C)、 含量及1.4 mm Hg的平均蒸氣壓。 之後，將此液態樹脂組成物（CFR1 2·0 μηι·厚塗膜。 外線輻射下並在 【而形成1 .6 μηι - 雷射修補裝置施 9 0 μηι方孔。 Pigment Red 2 5 4 S 量比 82/18 )、 )充當分散劑的 來看20重量份 bl )(固含量： I單體（c)的二 5劑（D )的2-苯 丁酮-1 及 759.8 酯、丙二醇單甲 ^酸酯（重量比 製備液態樹脂組 ，液態樹脂組成物 2 5 · 6重量％的固 )施於以上雷射 -34- 1379158 修補裝置的針狀部而塡入洞孔中心4次 暴露於100 nU/cm2的紫外線輻射下並在 淨烘箱中後烘烤30分鐘而形成與洞孔 色相的1.6 μηι-厚紅色層》 若利用 Ohtsuka Electronic股份有 2000顏色分析儀測量經修補部分與正： 們爲（0.641，0.344，23.5)及（ 0.640， 此，經修補部分與正常部分之間的色品 因此，實施例1的液態樹脂組成物在實 題》 比較實施例1 <正常部分及洞孔之形成> 以實施例1之相同方法製得具正常 材。 <缺點修補性之評估> 將100重量份充當顏料（a)之C.I 與 C . I. P i gment Y el 1 〇 w 1 3 9 的混合物 < 25重量份（就固含量來看10重量七 Disperbyk-2000、60.2 重量份（就固含 )充當鹼溶性樹脂（b )的共聚物溶液 3 3 · 2重量。/。）、〗3 〇重量份充當多官能| 四醇六丙烯酸酯、20重量份充當光起好 。然後令塡充部分 22〇°C下加熱的乾 內正常部分具相同 1 艮公司的MCPD-常部分的色品，它 0.344， 23.6)。由 有非常小的差異。 際運用中並沒有問 紅色層及洞孔的基 .Pigment Red 254 :重量比8 2 /1 8 )、 })充當分散劑的 量來看2 0重量份 (b 1 )(固含量： S單體（c)的二季 1劑（d )的2 ·苯甲 -35- 1379158 基-2-二甲基胺基-1·(4-嗎啉基苯基）丁酮-i及25 9.8重 量份充當溶劑（e)之3 -乙氧基丙酸乙酯、丙二醇單甲基 醚醋酸酯及二乙二醇單正丁基醚醋酸酯（重量比 57· 8/11.2/31』）的混合溶劑混合在一起而製備液態樹脂 組成物（r r 1 )。 以1 〇〇重量份之成分（b )來看，此液態樹脂組成物 (rrl)具有65 0重量份的成分（c) 、17.6重量％的固含 量及1.4 mmHg的平均蒸氣壓。 以實施例1之相同方法修補洞孔，但是使用樹脂組成 物（rr 1 )。若測量經修補部分與正常部分的色品，它們 爲（0.641，0.3 44, 23.5 )及(0.632, 0.344, 24.4 )。由此 ’經修補部分與正常部分之間的色品具有比實施例1更大 的差異。因此，比較實施例1的液態樹脂組成物在修補性 方面較差。 比較實施例2 <正常部分及洞孔之形成> 以實施例1之相同方法製得具正常紅色層及洞孔的基 材。 <缺點修補性之評估> 以實施例1之相同方法修補洞孔，但是使用供形成實 施例I用的組色層之樹脂組成物（CFR 1 )。 以1 00重量份之鹼溶性樹脂來看，此液態樹脂組成物 -36- 1379158 (CFR1)具有】14重量份的多官能基單體含量、21.6重 量％的固含量及2.6 mmHg的平均蒸氣壓。 因爲液態樹脂組成物（CFR1)具有高乾燥速度，所 以在針狀部到達要塡充的部分之前就已經乾燥並固化。因 此，不適合用於修補。 實施例2 <正常部分及洞孔之形成> 將90重量份充當顏料（A’）之C.I. Pigment Green 36 與 C.I· Pigment Yellow 150 的混合物（重量比 60/40) 、25重量份（就固含量來看11.5重量份）充當分散劑的 Disperbyk-200 1 (固含量：46.0重量％，溶劑：重量比 2:2:1之甲氧基丙醇醋酸、2-丁氧基乙醇及甲氧基丙醇的 混合溶劑）、1 8 0.7重量份（就固含量來看60重量份）充 當鹼溶性樹脂（B’）的共聚物溶液（bl )(固含量：33.2 重量％)、90重量份充當多官能基單體（C’）的二季四醇 六丙烯酸酯、35重量份充當光起始劑（D’）的2-苯甲基-2-二甲基胺基-1-(4-嗎啉基苯基）丁酮及679.3重量份 充當溶劑（E，）之醋酸3 -甲氧丁酯與丙二醇單甲基醚醋酸 酯（重量比58.9/41」）的混合溶劑混合在一起而製備液 態樹脂組成物（CFG1 )。 以實施例1之相同方法形成】·6 ^^厚正常綠色層及 基材中心的9 0 μ m方孔，但是使用液態樹脂組成物（ CFG 1 )。 -37- 1379158 <缺點修補性之評估> 將90重里份充呈顔料（a)之〇丄pigment 〇reen 36 與 C.I. Pigment Yellow ι50 的混合物（重量比 6〇/4〇)、 25重量份（就固含量來看11.5重量份）充當分散劑的 Disperbyk-2 00 1、76.0重量份（就固含量來看25重量份 )充當鹼溶性樹脂（B)的共聚物溶液（b2)(固含量： 32.9重量°/〇) 、125重量份充當多官能基單體（C)的二 季四醇六丙烯酸酯、20重量份充當光起始劑（D)的2-苯 甲基-2-二甲基胺基-1-( 4 -嗎啉基苯基）丁酮-1及649.0 重量份充當溶劑（E)之醋酸3 -甲氧基丁酯、環己酮及二 乙二醇單正丁基醚醋酸酯（重量比60.4/7.2/32.4 )的混合 溶劑混合在一起而製備液態樹脂組成物（RG 1 )。 以1 00重量份之成分（B )來看，此液態樹脂組成物 (RG1)具有500重量份的成分（C) 、27.6重量％的固 含量及2.2 mmHg的平均蒸氣壓。 若以實施例1之相同方法修補洞孔，但是使用液態樹 脂組成物（RG 1 )並測量經修補部分與正常部分的色品’ 它們爲（ 0.293，0.560, 60_7)及（ 0.294，0.558，61.2) ° 由此，經修補部分與正常部分之間的色品有非常小的差異 。因此，實施例2的液態樹脂組成物在實際運用中並沒有 問題。 比較實施例3 -38- 1379158 <正常部分及洞孔之形成> ^ 以實施例2之相同方法製得具正常綠色層及洞孔的基 * 材。 <缺點修補性之評估> 將90重量份充當顔料（3)之C_I. Pigment Green 36 與 C.I. Pigment Yellow 150 的混合物（重量比 60/40 )、 φ 25重量份（就固含量來看H.5重量份）充當分散劑的 Disperbyk-2 00 1、76.0重量份（就固含量來看25重量份 )充當鹼溶性樹脂（b)的共聚物溶液（b2)(固含量： 32.9重量％)、125重量份充當多官能基單體（c)的二季 四醇六丙烯酸酯、20重量份充當光起始劑（d)的2-苯甲 基-2-二甲基胺基-1-(4-嗎啉基苯基）丁酮-]及649.0重 量份充當溶劑（e)之醋酸3 -甲氧基丁酯及環己酮（重量 比8 6 · 3 /1 3 · 7 )的混合溶劑混合在一起而製備液態樹脂組 擊 成物（r g 1 )。 以1 00重量份之成分（b )來看，此液態樹脂組成物 (rgl)具有500重量份的成分（c) 、27.6重量％的固含 量及3.1 mmHg的平均蒸氣壓。 以實施例1之相同方法修補涧孔，但是使用液態樹脂 組成物（rg 1 )。然而’因爲液態樹脂組成物（rg丨）具有 高乾燥速度’所以在針狀部到達要塡充的部分之前就已經 乾燥並固化。因此，不適合用於修補。 -39- 1379158 實施例 <正常部分及洞孔之形成> 將90重量份充當顏料/ ··、.1379158 The plate was prebaked for 2 minutes to evaporate and form the solvent: Thereafter, the substrate was exposed to a clean oven heated at 50 °C/cm2 of violet at 22 ° C and baked for 30 minutes with a thick normal red layer. After that, the red layer was burned by the addition of a laser beam (of NTN Co., Ltd.) to form a center of the substrate. <Evaluation of the defect repairability> 1 part by weight was used as the pigment (A) (:.1· Mixture with CI Pigment Yellow 139 (I 25 parts by weight (in terms of solid content, 1 part by weight of Disperbyk-200 0, 60.2 parts by weight (in terms of solid content) acts as a copolymer solution of the alkali-soluble resin (B) (3 3 · 2% by weight), 30 parts by weight of 丨 serves as a polyfunctional quarter tetraol hexaacrylate, and 20 parts by weight serves as a light-good methyl-2-dimethylamino-1-(4-morpholinylphenyl) group. A mixture of 3 - ethoxypropionic acid ethyl ether acetate and diethylene glycol mono-n-butyl ether awake 59·0/9.4/3K6 as a solvent (E) is mixed together (RR1) In terms of 100 parts by weight of the component (B), this (RR1) has 650 parts by weight of the component (C), the content, and an average vapor pressure of 1.4 mm Hg. Thereafter, the liquid resin composition (CFR1 2 · 0 μηι·thick film. Outside the line radiation and in the formation of 1. 6 μηι - laser repair device application 90 μηη square hole. Pigment Red 2 5 4 S Ratio of 82/18), as a dispersing agent, 20 parts by weight of bl) (solid content: I monomer (c) of two 5 doses (D) of 2-benzophenone-1 and 759.8 ester, propylene glycol monomethyl Acid ester (weight ratio of liquid resin group, liquid resin composition 2 5 · 6 wt% solid) applied to the needle portion of the above laser-34-1379158 repair device and into the center of the hole 4 times exposed to 100 nU/cm2 under UV irradiation and post-baking in a net oven for 30 minutes to form a 1.6 μηι-thick red layer with a hue of holes. If using Ohtsuka Electronic, there is a 2000 color analyzer to measure the repaired parts and positive: (0.641, 0.344, 23.5) and (0.640, the chromaticity between the repaired portion and the normal portion. Therefore, the liquid resin composition of Example 1 is in fact) Comparative Example 1 <Normal portion and hole Formation > A normal material was obtained in the same manner as in Example 1. <Evaluation of defective repairability> 100 parts by weight of CI serving as pigment (a) and C.I. P i gment Y el 1 〇w 1 Mixture of 3 9 < 25 parts by weight (for solid content, 10 weights seven Disperbyk-2000, 60. 2 parts by weight (as solid) a copolymer solution serving as the alkali-soluble resin (b) 3 3 · 2 by weight. ), 3 parts by weight as a polyfunctional | tetraol hexaacrylate, 20 parts by weight as a light. Then, the normal portion of the dry portion which is heated at 22 ° C is supplied with the same color of the MCPD-normal portion of the company, which is 0.344, 23.6). There are very small differences. In the application, the red layer and the hole are not asked. Pigment Red 254: weight ratio 8 2 /1 8 ), }) as the amount of dispersant, 20 parts by weight (b 1 ) (solid content: S single Two seasons of the body (c), one dose (d) of 2 · benzyl-35- 1379158-based 2-dimethylamino-1(4-morpholinylphenyl)butanone-i and 25 9.8 parts by weight a mixed solvent of 3-ethoxypropionic acid ethyl ester, propylene glycol monomethyl ether acetate, and diethylene glycol mono-n-butyl ether acetate (weight ratio 57·8/11.2/31) as solvent (e) The liquid resin composition (rr 1 ) was prepared by mixing together. The liquid resin composition (rrl) had 65 parts by weight of the component (c) and 17.6% by weight in terms of 1 part by weight of the component (b). The solid content and the average vapor pressure of 1.4 mmHg. The holes were repaired in the same manner as in Example 1, except that the resin composition (rr 1 ) was used. If the chromaticities of the repaired portion and the normal portion were measured, they were (0.641, 0.3). 44, 23.5) and (0.632, 0.344, 24.4). Thus, the chromaticity between the repaired portion and the normal portion has a larger difference than that of the embodiment 1. Therefore, the comparative example 1 is The resin composition was inferior in repairability. Comparative Example 2 <Formation of normal portion and pores> A substrate having a normal red layer and a hole was obtained in the same manner as in Example 1. < Evaluation> The hole was repaired in the same manner as in Example 1, except that the resin composition (CFR 1 ) for forming the color layer for Example I was used. This liquid state was observed in terms of 100 parts by weight of the alkali-soluble resin. Resin composition -36-1379158 (CFR1) has a polyfunctional monomer content of 14 parts by weight, a solid content of 21.6% by weight, and an average vapor pressure of 2.6 mmHg. Since the liquid resin composition (CFR1) has a high drying speed, Therefore, the needle portion is dried and solidified before reaching the portion to be filled. Therefore, it is not suitable for repair. Example 2 <Formation of normal portion and hole> 90 parts by weight of the pigment (A') Mixture of CI Pigment Green 36 with CI· Pigment Yellow 150 (weight ratio 60/40), 25 parts by weight (11.5 parts by weight in terms of solid content) Disperbyk-200 1 (solid content: 46.0% by weight, solvent) :weight a ratio of 2:2:1 of methoxypropanol acetic acid, a mixed solvent of 2-butoxyethanol and methoxypropanol), 1 0.7 0.7 parts by weight (60 parts by weight in terms of solid content) as an alkali-soluble resin (B') copolymer solution (b1) (solid content: 33.2% by weight), 90 parts by weight of diquaternol hexaacrylate serving as the polyfunctional monomer (C'), and 35 parts by weight as a photoinitiator ( D') of 2-benzyl-2-dimethylamino-1-(4-morpholinylphenyl)butanone and 679.3 parts by weight of 3-methoxybutyl acetate serving as solvent (E,) A mixed solvent of propylene glycol monomethyl ether acetate (weight ratio 58.9/41") was mixed to prepare a liquid resin composition (CFG1). In the same manner as in Example 1, a normal green layer and a 90 μm square hole at the center of the substrate were formed, but a liquid resin composition (CFG 1 ) was used. -37- 1379158 <Evaluation of defects repairability> Mixture of 90 parts of pigment (a), Pigment 〇reen 36 and CI Pigment Yellow ι50 (weight ratio 6〇/4〇), 25 parts by weight (11.5 parts by weight in terms of solid content) Disperbyk-2 00 1 , 76.0 parts by weight (25 parts by weight in terms of solid content) serving as a dispersing agent as a copolymer solution (b2) of an alkali-soluble resin (B) (solid content) : 32.9 wt/〇), 125 parts by weight of diquaternal hexaol hexaacrylate serving as the polyfunctional monomer (C), and 20 parts by weight of 2-benzyl-2-di dimethyl hydride serving as photoinitiator (D) Amino-1-(4-morpholinylphenyl)butanone-1 and 649.0 parts by weight of 3-methoxybutyl acetate, cyclohexanone and diethylene glycol mono-n-butylate serving as solvent (E) A liquid resin composition (RG 1 ) was prepared by mixing together a mixed solvent of ether acetate (weight ratio: 60.4 / 7.2 / 32.4). The liquid resin composition (RG1) had a component (C) of 500 parts by weight, a solid content of 27.6% by weight, and an average vapor pressure of 2.2 mmHg in terms of 100 parts by weight of the component (B). If the holes were repaired in the same manner as in Example 1, but the liquid resin composition (RG 1 ) was used and the chromaticities of the repaired portion and the normal portion were measured, they were (0.293, 0.560, 60_7) and (0.294, 0.558, 61.2). ° ° Thus, there is a very small difference in the chromaticity between the repaired portion and the normal portion. Therefore, the liquid resin composition of Example 2 has no problem in practical use. Comparative Example 3 - 38 - 1379158 <Formation of normal portion and pores > ^ A base material having a normal green layer and pores was obtained in the same manner as in Example 2. <Evaluation of defective repairability> 90 parts by weight of C_I. Pigment Green 36 serving as pigment (3) and CI Pigment Yellow 150 (weight ratio 60/40), φ 25 parts by weight (in terms of solid content, H) .5 parts by weight) Disperbyk-2 00 as a dispersing agent, 76.0 parts by weight (25 parts by weight in terms of solid content) as a copolymer solution (b2) of an alkali-soluble resin (b) (solid content: 32.9% by weight) 125 parts by weight of diquaternal hexaol hexaacrylate serving as the polyfunctional monomer (c), 20 parts by weight of 2-benzyl-2-dimethylamino-1-(1) serving as photoinitiator (d) 4-morpholinylphenyl)butanone-] and 649.0 parts by weight of a mixed solvent of 3-methoxybutyl acetate and cyclohexanone (weight ratio 8 6 ·3 /1 3 · 7 ) serving as solvent (e) The liquid resin group composition (rg 1 ) was prepared by mixing together. The liquid resin composition (rgl) had a component (c) of 500 parts by weight, a solid content of 27.6% by weight, and an average vapor pressure of 3.1 mmHg in terms of 100 parts by weight of the component (b). The pupil was repaired in the same manner as in Example 1 except that a liquid resin composition (rg 1 ) was used. However, since the liquid resin composition (rg丨) has a high drying speed, it has dried and solidified before the needle portion reaches the portion to be filled. Therefore, it is not suitable for repair. -39- 1379158 EXAMPLES <Formation of normal portion and pores> 90 parts by weight are used as pigments/··,.
將 90 15:6 與 C.I. Pigment Vi〇iet '25重量份（就固含量來看| Disperbyk-2001 ' 180.7 重量份 )充當鹼溶性樹脂（B，）的共聚物溶液（w)(固含量： φ 33.2重量％)、90重量份充當多官能基單體（厂）的二季 四醇六丙烯酸酯、20重量份充當光起始劑（D，）的2_苯 甲基-2-二甲基胺基-1-(4-嗎啉基苯基）丁酮及8 79 3 重量份充當溶劑（E’）之醋酸3_乙氧基丙酸乙酯與丙二醇 單甲基醚醋酸酯（重量比68.2/31.8)的混合溶劑混合在 —起而製備液態樹脂組成物（CFB1 )。 以實施例1之相同方法形成1.6 μπι_厚正常綠色層及 基材中心的90 μπι方孔，但是使用液態樹脂組成物（ • CFB1) » <缺點修補性之評估> 將80重量份充當顔料（a)之C_I. Pigment Blue 15:6 與 C.I. Pigment Violet 23 的混合物（重量比 95/5) 、20重量份（就固含量來看9.2重量份）充當分散劑的 Disperbyk-200 1、90_9重量份（就固含量來看30重量份 )充當鹼溶性樹脂（B)的共聚物溶液（b3)(固含量： 33.0重量％) 、120重量份充當多官能基單體（c)的二 -40- 1379158 季四醇六丙烯酸酯、20重量份充當光起始劑（D)的2-苯 甲基·2_二甲基胺基-1-(4-嗎啉基苯基）丁酮-1及639.1 重量份充當溶劑（E)之3 -乙氧基丙酸乙酯、丙二醇單甲 基醚醋酸酯及二乙二醇單正丁基醚醋酸酯（重量比 2 1 ·9Μ 5.2/3 2.9 )的混合溶劑混合在一起而製備液態樹脂 組成物（RB1 ) «> 以1 〇〇重量份之成分（Β )來看，此液態樹脂組成物 (RB1)具有400重量份的成分（C) 、26.7重量％的固 含量及2.3 mm Hg的平均蒸氣壓。 若以實施例1之相同方法修補洞孔，但是使用液態樹 脂組成物（RB 1 )並測量經修補部分與正常部分的色品， 它們爲（0.136，0.107，12.4)及（ 0.136, 0.108，12.6)。 由此’經修補部分與正常部分之間的色品有非常小的差異 。因此’實施例3的液態樹脂組成物在實際運用中並沒有 問題。 比較實施例4 <正常部分及洞孔之形成> 以實施例3之相同方法製得具正常藍色層及洞孔的基 材。 <缺點修補性之評估> 將80重量份充當顔料之ci pigment B丨ue 15:6 與 C.l· Pigment Vi〇iet 23 的混合物（重量比 95/5) 、2〇 -41 - 1379158 重量份（就固含量來看9.2重量份）充當分散劑的 • Disperbyk-2001、227.3重量份（就固含量來看75重量份 / )充當鹼溶性樹脂（b)的共聚物溶液（b3)(固含量： 33.0重量％) 、75重量份充當多官能基單體（c)的二季 四醇六丙烯酸酯'20重量份充當光起始劑（d)的2苯甲 基-2-二甲基胺基-1-(4-嗎啉基苯基）丁酮-丨及547 7重 量份充當溶劑（e)之3 -乙氧基丙酸乙酯、肉二醇單甲基 φ 醚醋酸酯及二乙二醇單正丁基醚醋酸醋（重量比 25.6/36.1/38.3)的混合溶劑混合在一起而製備液態樹脂 組成物（rbl )。 以1 0 0重量份之成分（b )來看’此液態樹脂組成物 (rbl)具有100重量份的成分（c) 、26·7重量％的固含 量及2.3 mmHg的平均蒸氣壓。 以實施例1之相同方法修補洞孔，但是使用液態樹脂 組成物（rb 1 )。然而，因爲成分（e )蒸發之後液態樹脂 φ 組成物（rb 1 )並未完全固化，所以固化之後仍有流動性 。因此，不適合用於修補。 -42-90 15:6 and CI Pigment Vi〇iet '25 parts by weight (in terms of solid content | Disperbyk-2001 '180.7 parts by weight) as a copolymer solution (w) of alkali-soluble resin (B,) (solid content: φ 33.2% by weight), 90 parts by weight of diquaternal hexaol hexaacrylate serving as a polyfunctional monomer (factory), 20 parts by weight of 2-benzyl-2-dimethylamine serving as a photoinitiator (D,) 1-(4-morpholinylphenyl)butanone and 8 79 3 parts by weight of ethyl 3-acetoxypropionate and propylene glycol monomethyl ether acetate serving as solvent (E') (weight ratio 68.2) /31.8) The mixed solvent is mixed to prepare a liquid resin composition (CFB1). A 1.6 μm thick normal green layer and a 90 μπι square hole at the center of the substrate were formed in the same manner as in Example 1, except that a liquid resin composition (• CFB1) was used » <Evaluation of defective repairability> 80 parts by weight was used Pigment Blue 15:6 Mixture with CI Pigment Violet 23 (weight ratio 95/5), 20 parts by weight (9.2 parts by weight in terms of solid content) Disperbyk-200 1, 90_9 acting as a dispersing agent Parts by weight (30 parts by weight in terms of solid content) as a copolymer solution (b3) of an alkali-soluble resin (B) (solid content: 33.0% by weight), and 120 parts by weight of two as a polyfunctional monomer (c) 40- 1379158 quaternary alcohol hexaacrylate, 20 parts by weight of 2-benzyl-2,2-dimethylamino-1-(4-morpholinylphenyl)butanone as photoinitiator (D) 1 and 6391 parts by weight of 3-ethoxypropionic acid ethyl ester, propylene glycol monomethyl ether acetate and diethylene glycol mono-n-butyl ether acetate serving as solvent (E) (weight ratio 2 1 ·9Μ 5.2/3) 2.9) The mixed solvent is mixed to prepare a liquid resin composition (RB1) «> In terms of 1 part by weight of the component (Β), this liquid Component (C) a resin composition (the RB1) with 400 parts by weight, a solids content of 26.7 wt% and average 2.3 mm Hg vapor pressure. If the holes were repaired in the same manner as in Example 1, but the liquid resin composition (RB 1 ) was used and the chromaticities of the repaired portion and the normal portion were measured, they were (0.136, 0.107, 12.4) and (0.136, 0.108, 12.6). ). Thus there is a very small difference in the chromaticity between the repaired portion and the normal portion. Therefore, the liquid resin composition of Example 3 has no problem in practical use. Comparative Example 4 <Formation of normal portion and pores> A substrate having a normal blue layer and pores was obtained in the same manner as in Example 3. <Evaluation of defective repairability> 80 parts by weight of a mixture of ci pigment B丨ue 15:6 serving as a pigment and Cl· Pigment Vi〇iet 23 (weight ratio 95/5), 2〇-41 - 1379158 parts by weight (9.2 parts by weight in terms of solid content) Disperbyk-2001, 227.3 parts by weight (75 parts by weight in terms of solid content / ) as a copolymer solution (b3) of alkali-soluble resin (b) (solid content) : 33.0% by weight), 75 parts by weight of diquaternal hexa hexaacrylate serving as the polyfunctional monomer (c) 20 parts by weight of 2-benzyl-2-dimethylamino group serving as photoinitiator (d) 1-(4-morpholinylphenyl)butanone-indole and 547 7 parts by weight of ethyl 3-ethoxypropionate serving as solvent (e), glycerol monomethyl φ ether acetate and diethyl A liquid resin composition (rbl) was prepared by mixing together a mixed solvent of diol mono-n-butyl ether acetate vinegar (weight ratio 25.6/36.1/38.3). The liquid resin composition (rbl) has 100 parts by weight of the component (c), a solid content of 26.7 % by weight, and an average vapor pressure of 2.3 mmHg in terms of 100 parts by weight of the component (b). The hole was repaired in the same manner as in Example 1, except that the liquid resin composition (rb 1 ) was used. However, since the liquid resin φ composition (rb 1 ) is not completely cured after the evaporation of the component (e), there is still fluidity after curing. Therefore, it is not suitable for repair. -42-