1356517 九、發明說明： .【發明所屬之技術領域】 • 本發明涉及一種觸摸屏及使用該觸摸屏的顯示裝置， 尤其涉及一種基於奈米碳管的觸摸屏及使用該觸摸屏 不裝置。 【先前技術】 近年來，伴隨著移動電話與觸摸導航系統等各種電子 設備的高性能化和多樣化的發展’於液晶等顯示元件的前 #面安裝透光性的觸摸屏的電子設備逐步增加。這樣的電子 設備的利用者通過觸摸屏，一邊對位於觸摸屏背面的顯示 元件的顯示内容進行視覺確認，—邊利用手指或筆等方式 按壓觸摸屏來進行操作。由此，可以操作-電子設傷的各種 功能。 按照觸摸屏的工作原理和傳輸介質的不同，先前的觸 摸屏通常分爲四種類型，分別爲電阻式、電容感應式、紅 外線式及表面聲波式。其中電阻式觸摸屏的應用最爲廣泛 • (K. Noda, K. Tanimura, Electronics and Communications in1356517 IX. Description of the Invention: [Technical Field] The present invention relates to a touch screen and a display device using the same, and more particularly to a carbon nanotube-based touch screen and a touch screen using the same. [Prior Art] In recent years, with the development of various types of electronic devices such as mobile phones and touch navigation systems, the development of electronic devices having a translucent touch panel on the front side of display elements such as liquid crystals has been increasing. The user of such an electronic device visually confirms the display content of the display element located on the back surface of the touch panel through the touch panel, and presses the touch panel to operate by using a finger or a pen. Thereby, it is possible to operate various functions of electronic damage. According to the working principle of the touch screen and the transmission medium, the previous touch screens are generally divided into four types, namely resistive, capacitive sensing, infrared and surface acoustic waves. Among them, resistive touch screens are the most widely used. (K. Noda, K. Tanimura, Electronics and Communications in
Japan，Part 2, Vol. 84, No. 7, P40 (2001))。 先前的電阻式觸摸屏一般包括一上基板，該上基板的 下表面形成有一上透明導電層；一下基板，該下基板的上 表面形成有一下透明導電層；及多個點狀隔離物（Dot Spacer)設置於上透明導電層與下透明導電層之間。其中， 上基板通㊉爲具有一定柔軟度的薄膜或薄板，下基板通常 爲玻璃、石英、金剛石及塑料等製成的硬性基板，上透明 導電層與該下透明導電層通常採用具有導電特性的銦錫 6 1356517Japan, Part 2, Vol. 84, No. 7, P40 (2001)). The prior resistive touch screen generally comprises an upper substrate, the upper surface of which is formed with an upper transparent conductive layer; the lower substrate, the upper surface of which is formed with a transparent conductive layer; and a plurality of dot spacers (Dot Spacer ) is disposed between the upper transparent conductive layer and the lower transparent conductive layer. The upper substrate is a film or a thin plate having a certain degree of softness, and the lower substrate is usually a rigid substrate made of glass, quartz, diamond, plastic, etc., and the upper transparent conductive layer and the lower transparent conductive layer are generally made of conductive properties. Indium tin 6 1356517
Tin 0xide, IT0)^(Ts ιτο 時卜顯示11上，當使用手指或筆按壓上基板 栎，上基板發生扭曲，使得按壓處的上透明導電層 明導電層彼此接觸。通過外接的電子電:透 層依次施加電壓，觸摸屏控 j測里弟一導電層上的電壓變化與第二導電声 ===計算’將它轉換成觸點坐標。觸摸= 制益將數予化的觸點坐標傳遞給中央處理器。 根據觸點坐標發出相廡^ ^ 、处里〇口 啊出相應心令，啓動電子設備的各種功能切 換，並通過顯示器控制器控制顯示元件顯示。 然而，隨著顯示技術的日益發展，採用柔性 生 的柔性顯示設僙已蛵被贺^科衣仏 #鹿-哭産’如有柔性的機電致發 上設^二摸^1!"紙（e-paper)°於這些柔性顯示設備 其一 、/、爲一柔性觸摸屏。先前技術中觸摸屏的 變形的玻璃基板’並且，透明導電層通常採 用〇層。ΙΤ〇層作爲透明導電層具有機械和化學耐用性 ==彎折等缺點’故’上述觸摸屏只適合設置於不 :㈣的傳統顯示設備上’無法用於柔 的過程中，需要較法製備，於製備 ，、工衣;兄及加熱到2〇〇。(^〜3〇〇〇C， 故’使得m>層的製備成本較高。進一步地，⑽層於潮 濕的空氣申透明度會逐漸下义 曰、 摸屏及顯示裳置存在耐用性而導致先别的電阻式觸 雜較差等缺點難不够好’靈敏度低、線性及準 故’提供-種耐用性好’且靈敏度高、線性及準確性 7 1356517 强的觸摸屏及顯示裝置實為必要。 【發明内容】 一種觸摸屏，包括一第一電極板，該第 一第一基體及一第一導電厗，哕第電和板匕括 守电增这第一導電層設置於兮笛一 基體的下表面；及一第二電極板，該第二電極板電 極板間隔設置，該第二電極板包括一第二基體及 電層:該第二導電層設置於該第二基體的上表面；其^， 上述第一導電層和第二導電層均包括一夺 八 第一基體及第二基體由一柔性材料形成。s㈢，述 摸屏：f顯：裝置’包括：一觸摸屏及一顯示設備，該觸 該第一電極板包括-第-基體及 广：電層，該第一導電層設置於該第一基體的下表 f j一：極板，該第二電極板與第-電極板間隔設 置莫=二電極板包括一第二基體及一第二導電層，該第 電層設置於該第二基體的上表面，_示設備正對且 罪近上返觸摸屏的第二電極板設置；其中，上述第一導電 •層=導電層均包括一奈米碳管層，上述第一基體及第 一基體由一柔性材料形成。 麻本技術方案實施例提供的採用奈米碳管作爲透明導 電層的觸摸屏及顯示裝置具有以下優點：其一，奈米碳管 =的力學特性使得透明導電層具有很好的勒性和機 ^虽度/且耐彎折，故，可以相應的提高職屏的耐用 :，與柔性基體g己合，可以製備—柔性觸摸屏，從 柔性顯示裝置上；其二，由於奈米碳管於所述 •不只兔g層中均勻分佈’故，採用上述的奈米碳管層作 8 1356517 透明導電層，可使得透明導電層具有均句的阻值分佈，從 而提尚觸摸屏及使用該觸摸屏的顯示裝置的分辨率和精 確度。 【實施方式】 =下將結切圖詳細說明本技術方案提 顯示裝置。 』俱奸汉 請參閱圖1及圖2,本技術方案實施例提供一種觸摸 屏10,該觸摸屏1〇包括一第一電極板12 一;= 14及設置於第-電極板12與第二電極板14之=;= 明的點狀隔離物16。 <门的夕個透 ^第一電極板12包括一第一基體120，一第一導電# 122及兩個第一雷技导電曰 第一導電声” 9 該第一基體120爲平面結構，該 θ 與兩個第一電極124均設置於第__美# 120的下表面。兩佃笛^ J又直於第基體 第一導電岸122Γ 124分別沿第—方向設置於 二電極板包括第端並其與第一導電層則^ 個第二電極144。，第二基/ 140’ -第二導電層“2及兩 電層Χ42與兩個第：：：基體140爲平面結構’該第二導 表面。兩_^；； 料置於第：基體14〇的上 層142的兩端並蛊第分別沿第二方向設置於第二導電 垂直於第二方向^^ 電層142電連接。其中第一方向 正交設置。 Ρ兩個第一電極124與兩個第二電極144 其中，該第一其辦 等柔性材料形成。：120和第二基體140爲塑料或樹脂 所用的材料可^ ,，該第一基體120和第二基體14〇 爲4後酸酯（PC)、聚甲基丙烯酸曱酷 9 1356517 (PMMA)、聚對笨二甲酸乙二醇酯（ρΕτ)等聚酯材料，及聚 謎硬(PES)、纖維素酷、聚氯乙烯(pvc)、苯並環丁稀(β =二烯酸！脂等材料。該第-基體120和第二基體140的 :又爲1毫米〜丨厘米。本實施例中，該第一基體12〇與第 二基體、14G的材料均爲PET，厚度均爲2毫米。可以理解， 开乂成所述第—基體12G和第：基體14G的材料並不限於上 述列舉的材料，只要能使第一基體12〇和第二基體14〇起 丨支撑的作用’並具有一定柔性及較好的 發明保護的範圍内。 丨本 該第一電極124與該第二電極144的材料爲金屬材料 2 :的：屬鍍層、導電塗層組成，或奈米碳管層組成。本 :中’該第-電極124與第二電極144爲導電的銀漿 θ可以理解，用於柔性觸摸屏上的上述電極應具有一定 的韌性和易彎折度。 進步地’該第二電極板14上表面外圍設置有一絕緣 θ 上述的第—電極板12設置於該絕緣層18上，且該 丨第板12的第—導電層122正對第二電極板14的第 一導電層142設置。上述多個點狀隔離物㈣ 極板14的第二導電声14? μ θ ^ ^ 、弟一電 曰 上’且該多個點狀隔離物16彼 此間隔設置。第—電極板12與第二電極板Μ之間的距離 爲=〇微米。該絕緣層18與點狀隔離物16均可採用絕 緣樹脂或其他絕緣材料製成，並且，該點狀隔 -透明材料製成。設置絕緣層18與點狀隔離物16可使 1 1:?=:與：二電極板12電絕緣。可以理解，當觸 摸屏10尺寸較小時’點狀隔離物16爲可選擇的結構，只 1356517 •.需確保第一電極板14與第二電極板12電絕緣即可。 • $外’該第一電極板12上表面可設置一透明保護膜 126。所述透明保護膜126可以通過點結劑直接點結於透明 導電層24上，也可採用熱壓法’與第一電極板壓合於— 起。該透明保護膜126可採用一層表面硬化處理、光滑防 刮的塑料層或樹脂層，該肖脂層彳由苯丙環丁稀（bcb)、 聚醋及丙烯酸樹脂等材料形成。本實施例中，形成該透明 保護膜126的材料爲聚對苯二甲酸乙二醇醋（ρΕτ)，用於 修保護第一電極板12,提高耐用性。該透明保護膜126經特 殊工藝處理後’可用以提供一些附加功能，如可以减少眩 光或降低反射。 該第一導電層122與第二導電層142.中均包括一奈米 碳管層，該奈米碳管層包括多個奈米碳管。進一步地X 述的奈米碳官層可以係單個奈米碳管薄膜或係多個平行無 間隙鋪設的奈米碳管薄膜。可以理解，由於上述的奈米碳 官層中的多個奈米碳管薄膜可以平行且無間隙的鋪設， 1 ’上述奈米碳管層的長度和寬度不限，可根據實際需要 製成具有任意長度和寬度的奈米碳管層。另外，上述奈米 碳管層中可進-步包括多個奈米碳管薄膜重叠設置，Ζ 上述奈米奴官層的厚度也不限，只要能够具有理想的透明 度，可根據實際需要製成具有任意厚度的奈米碳管層。 太上述奈米碳管層中的奈米碳管薄膜由有序的或無序的 奈米碳管組成，並且該奈米碳管薄膜具有均勻的厚度。具 體地，該奈米碳管層包括無序的奈米碳管薄膜或者有序的 奈米碳管薄膜。無序的奈求碳管薄膜中，奈米碳管爲無序 11 1356517 • » -或各向同性排列。該無序排列的奈米碳管相互纏繞，該各 .向同性排列的奈米碳管平行於奈米碳管薄膜的表面。有序 的奈米碳官薄膜中，奈米碳管爲沿同一方向擇優取向排列 或沿不同方向擇優取向。當奈米碳管層包括多層有序奈米 碳官薄膜時，該多層奈米碳管薄膜可以沿任意方向重叠設 置，故，於該奈米碳管層中，奈米碳管爲沿相同或不同方 向擇優取向排列。 本實施例中，所述奈米碳管層爲重叠設置的多層有序 _奈米碳管薄膜，每層奈米碳管薄膜中奈米碳管爲定向排 列。所述奈米碳管薄膜進一步包括多個奈米碳管束片段， 每個奈米碳管束片段具有大致相等的長度且每個奈米碳管 =片段由多個相互平行的奈米碳管束構成.，奈米碳管束片 段兩端通過凡德瓦爾力相互連接。具體的，第一導電層122 中的夕層奈米碳管薄膜均沿第一方向重叠設置，第二導電 層142中的多層奈米碳管薄膜均沿第二方向重叠設置。所 述奈米碳管薄膜的厚度爲〇.5奈米〜1〇〇微米，寬度爲〇 〇1 •厘米〜10厘米。所述奈米碳管包括單壁奈米碳管、雙壁奈 米碳管或多壁奈米碳管。所述單壁奈米碳管的直徑爲 奈米〜50奈米，雙壁奈米碳管的直徑爲i奈米〜5〇奈米， 多壁奈米碳管的直徑爲1.5奈米〜50奈米。 本實施例第一導電層122和第二導電層142中採用的 沿同一方向定向排列的有序奈米碳管薄膜的製備方法主 包括以下步驟： 步驟一：提供一奈米碳管陣列，優選地，該陣列爲 順排奈米碳管陣列。 12 1356517 • . I技術方案實施例提供的奈米碳管陣列爲單壁奈米碳 •管陣列、雙壁奈米碳管陣列或多壁奈米碳管陣列。本實施 例中’超順排奈米碳管陣列的製備方法採用化學氣相沈積 法，其具體步驟包括：⑴提供一平整基底，該基底可選 用p型或N型石夕基底，或選用形成有氧化層的石夕基底，本 實施例優選爲採用4英寸的石夕基底；（b)於基底表面均句 形成一催化劑層，該催化劑層材料可選用鐵（h )、鈷 (Co)、鎮（Ni)或其任意組合的合金之一；（c)將上述 _形成有催化劑層的基底於700〇c〜9〇(rc的空氣中退火約 30分鐘〜90分鐘；（d)將處理過的基底置於反應爐中，於 保護氣體環境下加熱到50(TC〜74(rc，然後通入碳源氣體 反應約5〜30分鐘，生長得到超順排奈米碳管陣列，其高 度爲200〜400微米。該超順排奈米碳管陣列爲多個彼此平 行且垂直於基底生長的奈米碳管形成的純奈米碳管陣列。 通過上述控制生長條件，該超順排奈米碳管陣列中基本不 含有雜質，如無定型碳或殘留的催化劑金屬顆粒等。該奈 _米叙管陣列中的奈米碳管彼此通過凡德瓦爾力緊密接觸形 成陣列。該奈米碳管陣列與上述基底面積基本相同。 本實施例中碳源氣可選用乙快、乙烯、甲烧等化學性 質較活潑的碳氫化合物’本實施例優選的碳源氣爲乙炔； 保護氣體爲氮氣或惰性氣體，本實施例優選的保護氣體爲 氬氣。 可以理解，本實施例提供的奈米碳管陣列不限於上述 製備方法。也可爲石墨電極恒流電弧放電沈積法、雷射蒸 發沈積法等。 13 1356517 步驟二：採用一拉伸工具從奈米碳管陣列中拉取獲得 一奈米奴官4膜。其具體包括以下步驟：（a)從上述奈米 石反官陣列中選定寬度的多個奈米碳管片斷，本實施例 優選爲採用具有寬度的膠帶接觸奈米碳管陣列以選定 一定寬度的多個奈米碳管片冑；（b)以-定速度沿基本垂 直於奈米碳管陣列生長方向拉伸該多個奈米碳管片斷，以 形成一連績的奈米碳管薄膜。 、於上述拉伸過程中’該多個奈米碳管片段於拉力作用 下拉伸方向逐漸脫離基底的同時，由於凡德瓦爾力作 用，該選定的多個奈米碳管片斷分別與其它奈米碳管片斷 首尾相連地連續地被拉出，踨而w ^ l 5 ^ ^ 被拉出’ k㈣成一奈米碳管薄膜。該 「卡厌專膜包括多個首尾相連且定向排列 =:::=奈米碳管的排列方向基本平行於奈 奈米：相職㈣取向排列的多個 腊hi 成的具有一$寬度的奈米碳管薄 1:不未碳管薄膜中奈米碳管的排列方向基本平行於太 米碳管薄膜比無序二的擇優取向的奈 呈有更约句的戸由 膜具有更好的均勻性，即 /、有更均勻的4度及具有更均勾的導電性 拉伸獲得奈米碳管薄膜 Π時該直接 應用。 4膜的方以早快速，適宜進行工業化 本實％例_，該奈米碳管薄膜的 太山》 所生長的基底的尺寸有關，兮太水山—又/、不未石厌官陣列 可根據實際需求製得。哕；二：：薄臈的長度不限’ 該不未反官缚膜的厚度爲0.5奈米 丄/ 二100微米。所述奈米碳f包括單壁奈米碳管、雙壁奈米碳 ::多壁奈米碳管。當該奈米碳管薄膜中的奈米碳管爲單 壁奈米碳管時，該單壁奈米碳管的直徑爲〇·5奈米〜 二Si米碳管薄膜中的奈米碳管爲雙壁奈米碳管時， 該又土不米碳管的直徑爲1〇奈米〜5〇 管薄膜中的奈米碳管爲多壁太不未石反 的直徑爲工.5奈米〜50奈米Γ卡“時，該多壁奈米碳管 與ΓΓΟ層的原料成本和製備方法相比較，由於本技術 I方案所提供的奈米碳管薄膜由一拉伸工具拉取而獲得，續 方法無需真空環境和加埶讲 ,,^ ^ 太丰η㈣ 熱私’故㈣上述的方法製備的 :，官薄膜用作第一導電層122及第二導電層M2，且 =!〇低^環保及節能的優點。⑨，本技術方案提供的觸 摸屏10的製備也具有成本低、環保及節能的優點。 可以理解’由於本實施例超順排奈米碳管陣列中的夺 ΐ碳：ΐίΓ淨，且由於奈米碳管本身的比表面積非常 大，故該不米碳管薄膜本身具有較强的粘性。&，該夺米 碳管薄膜作爲第-導電層122與第二導電層14直接 钻附於第一基體120或第二基體14〇上。 接 另外，可使用有機溶劑處理上述枯附於第一基體12〇 或第二基體140上的奈㈣管薄膜。具體地，可通過試管 將有機溶劑滴落於奈米碳管薄膜表面浸潤整個奈米碳管薄 膜。該有機溶劑爲揮發性有機溶劑，如乙醇、甲醇、丙酮、 院或氯仿’本實施例中採用乙醇。該奈米碳管薄膜 :有機溶劑浸潤處理後，於揮發性有機溶劑的表面張力的 作用下，該奈米碳管薄膜可牢固地貼附於基體表面，且表 15 1356517 » ♦ -面體積比减小，枯性降低，具有良好的機械强度及勒性。 Λ外’可選擇地，爲了减小由顯示設備産生的電磁干 擾，避免從觸摸屏10發出的信號産生錯誤，還可於 體140的下表面上設置-屏蔽層。該屏蔽層可由奈米碳^ 涛膜、導電聚合物薄膜等導電材料形成。本實施例中，所 蔽層包含-奈米碳管薄膜，該奈㈣㈣膜中的夺 列方式不限’可爲定向排列也可爲其它的排列 方式。本實施例中，該屏蔽層中的奈米碳管定向排列。該 奈米碳管薄膜作爲電接地點，起到屏蔽的作用，從而使^ 觸摸屏10能於無干擾的環境中工作。 請參閱圖4，本技術方案實施例還提供-使用上述觸 摸屏的顯示裝置咖，其包括上述觸摸屏1()及_= :20。該顯不設備20正對且靠近上述觸摸屏則第二 =板二4設置。該觸摸屏10可以與該顯示設備 預定距離設置，也可集成於該顯示設備20上。#該觸^ 與該=示設備20集成設置時，可通過枯結劑將該觸摸 #屏10附著到該顯示設備2〇上。 、 干二Si示:備20可以爲液晶顯示器、場發射顯 丁器電漿顯不器、電致發光顯示器 傳統r設備中的-種，另外== 電致發光顯示器等柔性顯示器有機 距離該顯示設備20與該觸模屏ι〇間隔-定 距離,又置時，可於該觸摸屏10的屏蔽層22遠離第二美 〇的表面上設置一鈍化層24,該鈍化層24可由苯^丁 16 1356517 ，BCB)、聚醋或丙烯酸樹脂等柔性材料形成。該鈍化層 24與顯示設備20的正面間隔一間隙％設置。該純化層μ 作爲介電層❹，且保護該顯示設備2()不致於由於外 大而損壞。 該顯示裝置細進-步包括—觸摸屏控制器％、一中 =理器40及一顯示設備控制器5〇。其中，該觸摸屏控 制态30、該中央處理哭4Π »兮5s - . 蛟埋°° 40及該顯不設備控制器50三者通 =電路相互連接，該觸摸屏控制器3()與該觸模屏2〇電連 接，該顯示設備控制器50連接該顯示設備2〇。該觸摸屏 ，制器30通過手指等觸摸物6〇觸模的圖標或菜單位置來 :位選擇::息輸入’並將該信息傳遞給中央處理器4〇。該 央處理器40通過該顯示器控制器％控制該顯示元件加 顯示。 使用時’第-電極板12之間與第二電極板Μ之間分 別施加5V㈣。使用者—邊視覺確認於觸摸屏ι〇下面設 置的顯示元件20的顯示，一邊通過觸摸物60如手指或筆 =觸摸屏1G第-電極板12進行操作。第—電極板Η 苐一基體120發生彎曲’使得按遷處70的第一導電声 H與第二電極板14的第二導電層142接觸形成導通 摸屏控制器30通過分別測量第—導電層122第—方向上的 電屋變化，第二導電層142第二方向上的電麼變化，並進 —精確计算將匕轉換成觸點坐標。觸摸屏控制器將數 :化的觸點坐標傳遞給令央處理器4〇。中央處理器扣根 :觸點坐標發出相應指令，啓動電子設備的各種功能切 換，並通過顯示器控制器50控制顯示元件2〇顯示。 17 丄妁6517 本技術方案實施例提供的採用定向排列的奈米碳管作 -爲透明導電層的觸摸屏及顯示裝置具有以下優點：其一， 奈米碳管的優异的力學特性使得透明導電層具有很好的韌 生和機械强度’並且耐彎折，故，可以相應的提高觸摸屏 的耐用性，同時，與柔性基體配合，可以製備一柔性觸摸 屏從而適5用於柔性顯示裝置上。其二，由於奈米碳管 ^所述的奈米碳管層中均句分佈，故，採用上述的奈米碳 官層作透明導電層，可使得透明導電層具有均勻的阻值分 _佈’從而提高龍屏及❹該觸摸屏的顯示裝置的分辨率 和精確度。其二，由於本實施例所提供的奈米碳管薄膜由 。拉伸工具拉取而獲得，該方法無需真空環境和加熱過 程’故採用上述的方法製備的奈米碳管薄膜用作透明導電 層，具有成本低、環保及節能的優點。故，本技術方案提 供的，摸屏的製備也具有成本低、環保及節能的優點。 綜上所述，本發明確已符合發明專利之要件，遂依法 提出專利申請。惟’以上所述者僅為本發明之較佳實施例， 自不此以此限制本案之巾請專利範圍。舉凡習知本案技藝 ^人士援依本發明之精神所作之等效修飾或變化，皆應涵 盍於以下申請專利範圍内。 【圖式簡單說明】 圖1係本技術方案實施例觸摸屏的立體結構示意圖。 圖2係本技術方案實施例觸摸屏的側視結構示意圖。 圖3係本技術方案實施例觸摸屏沖奈米碳 描電鏡照片。 Φ 圖 4係本技術方案實施例顯示裝置的結構示意圖 18 1356517 .【主要元件符號說明】 , 觸摸屏 10 第一電極板 12 第二電極板 14 點狀隔離物 16 絕緣層 18 顯示裝置 100 第一基體 120 •第一導電層 122 第一電極 124 透明保護膜 126 第二基體 140 第二導電層 142 第二電極 144 顯示元件 20 φ屏蔽層 22 鈍化層 24 間隙 26 觸摸屏控制器 30 中央處理器 40 顯示器控制器 50 觸摸物 60 按壓處 70 19Tin 0xide, IT0)^(Ts ιτο When the display 11 is pressed, when the upper substrate is pressed with a finger or a pen, the upper substrate is twisted so that the upper transparent conductive layer of the pressing portion is in contact with each other. The external electronic electricity is: The transmissive layer sequentially applies a voltage, and the touch screen controls j to measure the voltage change on the conductive layer of the Lidi and the second conductive sound ===calculate 'converts it into contact coordinates. Touch = the benefit of the contact coordinate transfer To the central processing unit. According to the contact coordinates, the corresponding 心 ^ ^, the 〇 mouth ah out the corresponding order, start the various functions of the electronic device to switch, and control the display component display through the display controller. However, with the display technology Increasingly, the use of flexible and flexible display design has been smashed by He ^ 仏 仏 仏 鹿 鹿 鹿 哭 哭 哭 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如One of these flexible display devices is a flexible touch screen. In the prior art, the deformed glass substrate of the touch screen 'and the transparent conductive layer usually adopts a germanium layer. The germanium layer has a mechanical and chemical durability as a transparent conductive layer == bend Folding and other shortcomings 'so' the above touch screen is only suitable for setting on the traditional display device that does not: (4) 'can not be used in the soft process, need to be prepared by the method, in preparation, work clothes; brother and heated to 2 〇〇. ^~3〇〇〇C, so the 'm> layer is more expensive to produce. Further, the (10) layer in the humid air will gradually reduce the transparency, touch screen and display the durability of the skirt and lead to the first The disadvantages such as poor resistance and poor contact are not good enough. 'The sensitivity is low, linear and accurate. 'Provides good durability' and high sensitivity, linearity and accuracy. 7 1356517 Strong touch screen and display device are necessary. a touch screen comprising a first electrode plate, the first first substrate and a first conductive cymbal, and the first electrical layer and the slab of the first conductive layer are disposed on a lower surface of the base of the whistle; a second electrode plate, the second electrode plate electrode plates are spaced apart, the second electrode plate includes a second substrate and an electric layer: the second conductive layer is disposed on the upper surface of the second substrate; a conductive layer and a second conductive layer Each includes a first base body and a second base body formed of a flexible material. s (3), the touch screen: f display: the device 'includes: a touch screen and a display device, the touch of the first electrode plate includes a - the first base And an electric layer, the first conductive layer is disposed on the lower surface of the first substrate fj: a plate, the second electrode plate is spaced apart from the first electrode plate; the second electrode plate comprises a second substrate and a a second conductive layer, the first electrical layer is disposed on the upper surface of the second substrate, and the device is disposed opposite to the second electrode plate of the touch screen; wherein the first conductive layer=conductive layer includes The first base body and the first base body are formed of a flexible material. The touch screen and the display device using the carbon nanotubes as the transparent conductive layer provided by the embodiments of the present invention have the following advantages: The mechanical properties of the carbon nanotubes make the transparent conductive layer have good character and mechanical strength and resistance to bending. Therefore, the durability of the job screen can be improved accordingly: it can be prepared with the flexible substrate - Flexible touch screen, from flexible display On the device; secondly, because the carbon nanotubes are evenly distributed in the g layer of the rabbit, the above-mentioned carbon nanotube layer is used as the transparent conductive layer of 8 1356517, so that the transparent conductive layer has a uniform resistance. The value distribution provides a resolution and accuracy of the touch screen and the display device using the touch screen. [Embodiment] = The junction device will be described in detail with reference to the technical solution. Referring to FIG. 1 and FIG. 2, the embodiment of the present invention provides a touch screen 10, which includes a first electrode plate 12; = 14 and is disposed on the first electrode plate 12 and the second electrode plate. 14 == = clear dot spacer 16 . <The first electrode 120 of the door includes a first substrate 120, a first conductive #122 and two first conductive conductive first conductive sounds. 9 The first substrate 120 is a planar structure The θ and the two first electrodes 124 are both disposed on the lower surface of the __美# 120. The two sputums are further disposed on the second electrode plate along the first direction of the first conductive bank 122 Γ 124, respectively. The first end and the first conductive layer are second electrodes 144. The second base / 140' - the second conductive layer "2 and the two electrical layers Χ 42 and the two::: base 140 are planar structures" Second guiding surface. The two materials are placed at the two ends of the upper layer 142 of the base 14 蛊 and are electrically connected to the second conductive layer 142 in the second direction perpendicular to the second direction. The first direction is orthogonally set. The two first electrodes 124 and the two second electrodes 144 are formed of a flexible material such as the first one. The 120 and the second substrate 140 are made of a plastic or a resin, and the first substrate 120 and the second substrate 14 are 4 post-esters (PC), polymethacrylic acid 9 9 1356517 (PMMA), Polyester to polyethylene glycol (ρΕτ) and other polyester materials, and polyester hard (PES), cellulose cool, polyvinyl chloride (pvc), benzocyclobutene (β = dicarboxylic acid! The material of the first base body 120 and the second base body 140 is 1 mm to 丨 cm. In the embodiment, the first base body 12 〇 and the second base body and 14G are made of PET and have a thickness of 2 mm. It is to be understood that the materials of the first base 12G and the base 14G are not limited to the above-exemplified materials, as long as the first base 12 and the second base 14 can be used to support the support and have Within the scope of certain flexibility and better invention protection, the first electrode 124 and the second electrode 144 are made of a metal material 2: a coating layer, a conductive coating composition, or a carbon nanotube layer. This: the first electrode 124 and the second electrode 144 are electrically conductive silver paste θ can be understood, used on the flexible touch screen The electrode should have a certain degree of toughness and easy to bend. Progressively, the outer surface of the second electrode plate 14 is provided with an insulation θ. The first electrode plate 12 is disposed on the insulating layer 18, and the first plate 12 is disposed. The first conductive layer 122 is disposed opposite to the first conductive layer 142 of the second electrode plate 14. The plurality of dot spacers (four) of the second conductive sound of the plate 14 are 14? μ θ ^ ^, and the first one is on the electric And the plurality of dot spacers 16 are spaced apart from each other. The distance between the first electrode plate 12 and the second electrode plate 为 is 〇μm. The insulating layer 18 and the dot spacer 16 may be made of insulating resin or the like. The insulating material is made of, and is made of, a dot-like transparent material. The insulating layer 18 and the dot spacer 16 are provided to electrically insulate 1:1:: from the two electrode plates 12. It can be understood that when the touch screen 10 is used When the size is small, the dot-like spacer 16 is an optional structure, only 1356517. • It is necessary to ensure that the first electrode plate 14 is electrically insulated from the second electrode plate 12. • The outer surface of the first electrode plate 12 A transparent protective film 126 may be disposed. The transparent protective film 126 may be directly pointed by a bonding agent On the transparent conductive layer 24, the first electrode plate may be pressed together by a hot pressing method. The transparent protective film 126 may be a surface hardened, smooth scratch-resistant plastic layer or a resin layer. The layer is formed of a material such as styrene-butadiene (bcb), a polyester, or an acrylic resin. In the present embodiment, the transparent protective film 126 is formed of polyethylene terephthalate (ρΕτ) for The first electrode plate 12 is protected to improve durability. The transparent protective film 126 is specially treated to provide additional functions such as reducing glare or reducing reflection. The first conductive layer 122 and the second conductive layer 142. respectively comprise a carbon nanotube layer, and the carbon nanotube layer comprises a plurality of carbon nanotubes. Further, the nanocarbon layer of X can be a single carbon nanotube film or a plurality of carbon nanotube films laid in parallel without gaps. It can be understood that since the plurality of carbon nanotube films in the above-mentioned nano carbon layer can be laid in parallel and without gaps, the length and width of the above-mentioned carbon nanotube layer are not limited, and can be made according to actual needs. A layer of carbon nanotubes of any length and width. In addition, the above-mentioned carbon nanotube layer may further comprise a plurality of carbon nanotube film overlapping arrangements, and the thickness of the above-mentioned nano slave layer is not limited, as long as it has the desired transparency, it can be made according to actual needs. A carbon nanotube layer of any thickness. The carbon nanotube film in the above-mentioned carbon nanotube layer is composed of ordered or disordered carbon nanotubes, and the carbon nanotube film has a uniform thickness. Specifically, the carbon nanotube layer comprises a disordered carbon nanotube film or an ordered carbon nanotube film. In the disordered carbon nanotube film, the carbon nanotubes are disordered 11 1356517 • » - or isotropically arranged. The disordered array of carbon nanotubes are intertwined, and the isotropically arranged carbon nanotubes are parallel to the surface of the carbon nanotube film. In an ordered nanocarbon film, the carbon nanotubes are oriented in the same direction or in different directions. When the carbon nanotube layer comprises a multi-layered ordered carbon carbon film, the multi-layered carbon nanotube film can be overlapped in any direction, so in the carbon nanotube layer, the carbon nanotubes are along the same or Different orientations are preferred. In this embodiment, the carbon nanotube layer is a multi-layered ordered carbon nanotube film which is arranged in an overlapping manner, and the carbon nanotubes in each layer of the carbon nanotube film are oriented. The carbon nanotube film further comprises a plurality of carbon nanotube bundle segments, each of the carbon nanotube bundle segments having substantially equal lengths and each of the carbon nanotubes = segments being composed of a plurality of mutually parallel carbon nanotube bundles. The carbon nanotube bundle segments are connected to each other by Van der Waals force. Specifically, the solar nanotube films in the first conductive layer 122 are overlapped in the first direction, and the plurality of carbon nanotube films in the second conductive layer 142 are overlapped in the second direction. The carbon nanotube film has a thickness of 〇. 5 nm to 1 〇〇 micrometer and a width of 〇 • 1 • cm to 10 cm. The carbon nanotubes include single-walled carbon nanotubes, double-walled carbon nanotubes or multi-walled carbon nanotubes. The diameter of the single-walled carbon nanotube is nanometer to 50 nanometer, the diameter of the double-walled carbon nanotube is i nanometer to 5 nanometer nanometer, and the diameter of the multi-walled carbon nanotube is 1.5 nanometer to 50 nanometer Nano. The method for preparing the ordered carbon nanotube film arranged in the same direction in the first conductive layer 122 and the second conductive layer 142 of the present embodiment mainly comprises the following steps: Step 1: providing a carbon nanotube array, preferably Ground, the array is a tandem carbon nanotube array. 12 1356517 • I Technical Solution Examples The carbon nanotube arrays provided are single-walled nano carbon tube arrays, double-walled carbon nanotube arrays or multi-walled carbon nanotube arrays. In the present embodiment, the method for preparing a super-sequential carbon nanotube array adopts a chemical vapor deposition method, and the specific steps thereof include: (1) providing a flat substrate, the substrate may be selected from a p-type or an N-type base, or may be formed. In the present embodiment, a 4 inch stone base is used; (b) a catalyst layer is formed on the surface of the substrate, and the catalyst layer material may be iron (h) or cobalt (Co). One of the alloys of the town (Ni) or any combination thereof; (c) the above-mentioned substrate formed with the catalyst layer is annealed in air of 700 〇c to 9 Torr (rc for about 30 minutes to 90 minutes; (d) will be treated The substrate is placed in a reaction furnace and heated to 50 (TC~74 (rc) in a protective gas atmosphere, and then reacted with a carbon source gas for about 5 to 30 minutes to grow to obtain a super-aligned carbon nanotube array. The ultra-sequential carbon nanotube array is a plurality of pure carbon nanotube arrays formed by a plurality of carbon nanotubes that are parallel to each other and perpendicular to the substrate. The super-shun nai is controlled by the above controlled growth conditions. The carbon nanotube array contains substantially no impurities, such as amorphous carbon or Retaining catalyst metal particles, etc. The carbon nanotubes in the nanometer tube array are in close contact with each other by van der Waals force to form an array. The carbon nanotube array is substantially the same area as the above substrate. The gas may be selected from the chemically active hydrocarbons such as B-speed, ethylene, and methane. The preferred carbon source gas in this embodiment is acetylene; the shielding gas is nitrogen or an inert gas, and the preferred shielding gas in this embodiment is argon. It can be understood that the carbon nanotube array provided in this embodiment is not limited to the above preparation method, and may also be a graphite electrode constant current arc discharge deposition method, a laser evaporation deposition method, etc. 13 1356517 Step 2: using a stretching tool from Nana A nanotube array 4 is obtained by drawing in a carbon nanotube array, which specifically comprises the following steps: (a) selecting a plurality of carbon nanotube segments of a width from the nanometer squash array, the embodiment is preferably Contacting the carbon nanotube array with a tape having a width to select a plurality of carbon nanotube sheets of a certain width; (b) stretching at a constant speed along a direction perpendicular to the growth direction of the carbon nanotube array a plurality of carbon nanotube segments to form a continuous carbon nanotube film. In the above stretching process, the plurality of carbon nanotube segments are gradually pulled away from the substrate under tensile force, By Deval force, the selected plurality of carbon nanotube segments are continuously pulled out end to end with other carbon nanotube segments, and w ^ l 5 ^ ^ is pulled out 'k (four) into a carbon nanotube The film has a plurality of end-to-end and aligned orientations::::=The arrangement of the carbon nanotubes is substantially parallel to the distribution of the nanometers: the plurality of waxes arranged in the orientation (four) orientation has a width of The carbon nanotubes are thin 1: the arrangement direction of the carbon nanotubes in the non-carbon tube film is substantially parallel to the carbon nanotube film, and the preferred orientation of the carbon nanotube film is more than the order of the two. The uniformity, that is, / has a more uniform 4 degrees and has a more uniform conductive stretch to obtain a carbon nanotube film 该 when the direct application. The film of 4 is fast and suitable for industrialization. The size of the substrate is _, the size of the substrate grown by the nano-tube film of the nano-tube is related to the size of the substrate, and it is not too According to actual needs.哕; 2:: The length of the thin 不限 is not limited. The thickness of the non-reverse eclipse is 0.5 nm 二 / two 100 microns. The nanocarbon f includes a single-walled carbon nanotube, a double-walled nanocarbon :: a multi-walled carbon nanotube. When the carbon nanotube in the carbon nanotube film is a single-walled carbon nanotube, the diameter of the single-walled carbon nanotube is 奈·5 nm~ the carbon nanotube in the two-Si carbon nanotube film When it is a double-walled carbon nanotube, the diameter of the carbon nanotube is 1 〇 nanometer ~ 5 〇 tube in the film of the carbon nanotube is multi-walled too un-stone-reverse diameter of the work. 5 nm ~50nm Leica "When the multi-walled carbon nanotubes are compared with the raw material cost and preparation method of the tantalum layer, the carbon nanotube film provided by the solution of the present technology is obtained by pulling a stretching tool The continuation method does not require a vacuum environment and twisting, ^ ^ Taifeng η (4) hot private "4" prepared by the above method: the official film is used as the first conductive layer 122 and the second conductive layer M2, and =! The advantages of environmental protection and energy saving. 9. The preparation of the touch screen 10 provided by the technical solution also has the advantages of low cost, environmental protection and energy saving. It can be understood that 'the carbon in the super-sequential carbon nanotube array of the present embodiment is: ΐίΓ, and because the specific surface area of the carbon nanotube itself is very large, the carbon nanotube film itself has a strong viscosity. The carbon nanotube film is directly attached to the first substrate 120 or the second substrate 14 as the first conductive layer 122 and the second conductive layer 14. Alternatively, the organic solvent may be used to treat the above-mentioned dryness. a film of the naphthalene film on the substrate 12〇 or the second substrate 140. Specifically, the organic solvent is dripped on the surface of the carbon nanotube film by a test tube to infiltrate the entire carbon nanotube film. The organic solvent is a volatile organic solvent. For example, ethanol, methanol, acetone, hospital or chloroform is used in the present embodiment. The carbon nanotube film: after infiltration by an organic solvent, under the action of surface tension of a volatile organic solvent, the carbon nanotube film It can be firmly attached to the surface of the substrate, and Table 15 1356517 » ♦ - The surface volume ratio is reduced, the dryness is reduced, and the mechanical strength and the characterization are good. ΛExternally, in order to reduce the output generated by the display device The electromagnetic interference prevents the signal emitted from the touch screen 10 from generating an error, and a shielding layer may be disposed on the lower surface of the body 140. The shielding layer may be formed of a conductive material such as a nano carbon film or a conductive polymer film. In the embodiment, the mask layer comprises a film of a carbon nanotube, and the manner of entanglement in the film of the nano (four) (four) is not limited to being an alignment or other arrangement. In this embodiment, the layer in the shielding layer The carbon nanotubes are aligned, and the carbon nanotube film acts as an electrical grounding point to shield the touch screen 10 in a non-interfering environment. Referring to FIG. 4, the embodiment of the present invention further provides - The display device using the above touch screen includes the above-mentioned touch screen 1() and _=: 20. The display device 20 is directly opposite to the touch screen and then the second=board 2 is set. The touch screen 10 can be reserved with the display device. The distance setting can also be integrated on the display device 20. When the touch device is integrated with the display device 20, the touch screen 10 can be attached to the display device 2 by a dry agent. , dry two Si show: preparation 20 can be liquid crystal display, field emission display plasma display, electro-luminescence display traditional r equipment, and == electroluminescent display and other flexible display organic distance display The device 20 is spaced apart from the touch screen by a distance, and a passivation layer 24 is disposed on the surface of the shield layer 22 of the touch screen 10 away from the second surface. The passivation layer 24 can be made of benzene. 1356517, BCB), a flexible material such as polyester or acrylic resin. The passivation layer 24 is spaced from the front side of the display device 20 by a gap %. The purification layer μ serves as a dielectric layer and protects the display device 2 from damage due to externalities. The display device includes a touch screen controller %, a medium controller 40 and a display device controller 5A. The touch screen controller 30 and the touch panel controller 3 ( The screen 2 is electrically connected, and the display device controller 50 is connected to the display device 2〇. The touch screen controller 30 uses a finger or the like to touch the icon or menu position of the touch panel: bit selection: input and transmit the information to the central processing unit 4〇. The central processor 40 controls the display element plus display by the display controller %. In use, 5 V (four) is applied between the first electrode plates 12 and the second electrode plate 分, respectively. The user-side visually recognizes the display of the display element 20 disposed under the touch screen, while operating through the touch object 60 such as a finger or a pen = touch screen 1G first-electrode plate 12. The first electrode 120 is bent so that the first conductive sound H of the migration portion 70 is in contact with the second conductive layer 142 of the second electrode plate 14 to form the conduction screen controller 30 by measuring the first conductive layer separately. 122 changes in the first direction of the electric house, the second conductive layer 142 in the second direction of the change in electrical, and - accurate calculations to convert 匕 into contact coordinates. The touch screen controller passes the number of the contact coordinates to the command processor 4〇. The central processing unit buckles the contact coordinates to issue corresponding commands, activate various functions of the electronic device, and control the display unit 2 to display through the display controller 50. 17 丄妁 6517 The touch screen and the display device using the aligned carbon nanotubes as the transparent conductive layer provided by the embodiments of the present technical solution have the following advantages: First, the excellent mechanical properties of the carbon nanotubes make the transparent conductive The layer has good toughness and mechanical strength' and is resistant to bending, so that the durability of the touch screen can be correspondingly improved, and at the same time, in cooperation with the flexible substrate, a flexible touch screen can be prepared to be used for the flexible display device. Secondly, due to the uniform distribution of the carbon nanotube layer in the carbon nanotubes, the above-mentioned nano-carbon layer is used as the transparent conductive layer, so that the transparent conductive layer has a uniform resistance value. 'This improves the resolution and accuracy of the display and display of the touch screen. Second, the carbon nanotube film provided by the present embodiment is composed of. The drawing tool is obtained by drawing, and the method does not require a vacuum environment and a heating process. Therefore, the carbon nanotube film prepared by the above method is used as a transparent conductive layer, which has the advantages of low cost, environmental protection and energy saving. Therefore, the preparation of the touch screen provided by the technical solution also has the advantages of low cost, environmental protection and energy saving. In summary, the present invention has indeed met the requirements of the invention patent, and has filed a patent application according to law. However, the above description is only a preferred embodiment of the present invention, and the scope of the patent application of the present invention is not limited thereto. Equivalent modifications or variations made by those skilled in the art in light of the spirit of the present invention are intended to be within the scope of the following claims. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic perspective view of a touch screen of an embodiment of the present technical solution. FIG. 2 is a schematic side view showing the structure of a touch screen according to an embodiment of the present technical solution. FIG. 3 is a photograph of a touch screen nano carbon SEM image of an embodiment of the present technical solution. Fig. 4 is a schematic structural view of a display device according to an embodiment of the present invention. 18 1356517. [Description of main component symbols], touch panel 10 first electrode plate 12 second electrode plate 14 dot spacer 16 insulating layer 18 display device 100 first substrate 120 • First conductive layer 122 First electrode 124 Transparent protective film 126 Second substrate 140 Second conductive layer 142 Second electrode 144 Display element 20 φ Shield layer 22 Passivation layer 24 Clearance 26 Touch screen controller 30 Central processing unit 40 Display control 50 touch object 60 press 70 19