TWI342811B - Method for laser scribing a brittle substrate and a brittle substrate - Google Patents
Method for laser scribing a brittle substrate and a brittle substrate Download PDFInfo
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- TWI342811B TWI342811B TW97110077A TW97110077A TWI342811B TW I342811 B TWI342811 B TW I342811B TW 97110077 A TW97110077 A TW 97110077A TW 97110077 A TW97110077 A TW 97110077A TW I342811 B TWI342811 B TW I342811B
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- 239000000758 substrate Substances 0.000 title claims description 78
- 238000000034 method Methods 0.000 title claims description 29
- 238000005520 cutting process Methods 0.000 claims description 97
- 238000003698 laser cutting Methods 0.000 claims description 23
- 239000011521 glass Substances 0.000 claims description 13
- 239000000919 ceramic Substances 0.000 claims description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052755 nonmetal Inorganic materials 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 2
- 239000012809 cooling fluid Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000033001 locomotion Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
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- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
- Processing Of Stones Or Stones Resemblance Materials (AREA)
Description
1342811 100年03月14日修正替换頁 六、發明說明: 【發明所屬之技術領域】 [0001] 本發明涉及切割與分離技術,尤其是一種雷射切割非金 屬或脆性基板之方法以及由該方法製得之脆性基板。 【先前技術】 [0002] [0003] 參見圖1,雷射切割脆性基板之方法一般以配合脆性基板 強烈吸收特性之雷射,如二氧化碳(C02)雷射光束20來加 熱玻璃基板10之表面,再以冷卻流體30加以局部冷卻,1342811 Correction and replacement page on March 14, 100. Description of the invention: [Technical field of the invention] [0001] The present invention relates to cutting and separating techniques, and more particularly to a method of laser cutting a non-metallic or brittle substrate and by the method A brittle substrate made. [Prior Art] [0002] Referring to FIG. 1, a method of laser-cutting a brittle substrate generally heats a surface of a glass substrate 10 with a laser having a strong absorption characteristic of a brittle substrate, such as a carbon dioxide (C02) laser beam 20. Partial cooling with cooling fluid 30,
進而於玻璃基板10之表面因急劇變化之溫度差產生熱應 • ·.· 力’使具有初始裂紋( i^i:友辦ί.、c絲雄之玻璃基板1 〇 4 · ·· I· · . . ' 之邊緣產生裂紋’並向雷(如圖1中 箭頭所示)成長成盲裂紋(b 進而可於 玻璃板件10之表面形成沿割線。 然而,於切割起始位置常會因玻璃基;^之邊緣強度較 低(例如,初始裂紋11之影^響射嶼成),使彳导初始裂紋11 會沿玻璃基板1 〇之厚度方cutting)並沿 雷射光束20之移動方向成睪;以致於在切割線 之起始端會形成一對應圖1中之全斷區12之全斷線。 [0004]請一併參見圖2,其為先於玻璃基板1 〇上沿a 1方向依序形 成第一方向切割線A10、All、A12、A13,再沿A2方向形 成第二方向切割線A20之一狀態示意圖。從圖2中可得知 ’當依序地沿單一方向(亦即第一方向A1)進行初始裂紋 及雷射切割時,第一方向切割線A10、A11、A12、A13之 起始端之初始裂紋全斷且具有沿A1方向之成長距離差異( 如圖2中第一方向切割線A1〇、A11、ai2、A13之實線部 097110077 表單編號· A0101 第4頁/共15頁 1003085051-0 13,42811 . ___ 100年03月14日梭正替換頁 分),使得鄰近第一方向切割線A10、A11、A12、A132 起始端之第二方向切割線A20無法跨越第一方向切割線( 例如A10)之全斷線而導致切割失效(如圖2中箭頭F1所指 部分),或者沿偏離A2方向之其他方向形成裂紋成長(如 ' 圖2中箭頭F2所指部分)而影響切割精度;進而導致玻璃 基板之切割良率不佳。 [0005] 有鑒於此,提供一種具有較高切割良率之雷射切割脆性 基板之方法以及採用該種方法製得之脆性基板實為必要Further, heat is generated on the surface of the glass substrate 10 due to a sharp temperature difference. The force is made to have an initial crack (i^i: a friend's glass substrate 1 〇4 · ·· I· ' . . 'The edge of the crack is generated ' and grows into a blind crack (as indicated by the arrow in Fig. 1) to form a blind crack (b and thus can form a secant line on the surface of the glass sheet member 10. However, the cutting start position is often due to the glass. The edge of the ^; has a low edge strength (for example, the shadow of the initial crack 11), so that the initial crack 11 will be cut along the thickness of the glass substrate 1 and along the moving direction of the laser beam 20睪; so that a full disconnection corresponding to the full-break region 12 in FIG. 1 is formed at the beginning of the dicing line. [0004] Please refer to FIG. 2 together, which is preceded by the a1 direction on the glass substrate 1 Forming a first direction cutting line A10, All, A12, A13, and forming a state of the second direction cutting line A20 along the A2 direction. It can be seen from FIG. 2 'when sequentially in a single direction (ie, First direction A1) When initial cracking and laser cutting are performed, the start of the first direction cutting lines A10, A11, A12, A13 The initial crack is completely broken and has a difference in growth distance along the A1 direction (the solid line portion 097110077 of the first direction cutting line A1〇, A11, ai2, A13 in the first direction in Fig. 2) Form number·A0101 Page 4/15 pages 1003085051- 0 13,42811 . ___ On March 14, 100, the shuttle is replacing the page), so that the second direction cutting line A20 adjacent to the starting end of the first direction cutting lines A10, A11, A12, A132 cannot cross the first direction cutting line ( For example, the full disconnection of A10) causes the cutting failure (as indicated by the arrow F1 in Fig. 2), or the crack growth in other directions deviating from the A2 direction (such as the portion indicated by the arrow F2 in Fig. 2) affecting the cutting precision. Further, the cutting yield of the glass substrate is poor. [0005] In view of the above, it is necessary to provide a laser cutting brittle substrate having a high cutting yield and a brittle substrate obtained by the method.
【發明内容】 [0006] 下面將以實施例說明一種雷敲切割脆性墓&之方法以及 由該種方法製得之一種脆性基板。 [0007] 一種雷射切割脆性基板之方法,其包括步驟: [0008] 提供一脆性基板;SUMMARY OF THE INVENTION [0006] Hereinafter, a method of lightning-cutting a brittle tomb & and a brittle substrate obtained by the method will be described by way of examples. [0007] A method of laser cutting a brittle substrate, comprising the steps of: [0008] providing a brittle substrate;
[0009] 利用一雷射切割製程於脆性基板之鄰近其一邊緣之位置 形成一沿一第一方向延伸之第;了切割線; [0010] 於脆性基板上之鄰近第一切割線之起始端之位置形成一 起始於該邊緣且跨過第一切割線之初始裂紋,初始裂紋 沿一不同於第一方向之第二方向延伸;以及 [0011] 利用一雷射切割製程於脆性基板上沿著初始裂紋形成一 沿第二方向延伸之第二切割線,該初始裂紋與該第二切 割線不重合且該第二切割線接著該初始裂紋而延伸。 [0012] 以及,一種脆性基板,其上形成有一第一切割線以及一 097110077 表單編號A0101 第5頁/共15頁 1003085051-0 1342811 [0013] [0014] [0015] [0016] 097110077 100年03月14日核正替换頁 第二切割線,第一切割線鄰近脆性基板之一邊緣,該脆 性基板之臨近該第一切割線之起始端之位置形成起始該 邊緣且跨過該第一切割線之初始裂紋,該第二切割線接 著該初始裂紋而延伸。 相對於先前技術,上述之雷射切割脆性基板之方法經由 採用於形成一第一切割線後於鄰近第一切割線之起始端 之位置形成一第二切割線之切割製程,可有效避免後續 形成之沿第一方向延伸及/或第二方向延伸之切割線(a ) 因無法跨越另一方向上之切割線之起始端而導致之切割 失效,或者(b)偏離獱资:無,從而可達 成較高之切割良率。 【實施方式】[0009] forming a cutting edge in a first direction at a position adjacent to an edge of the brittle substrate by a laser cutting process; cutting line; [0010] adjacent to the beginning end of the first cutting line on the brittle substrate a position forming an initial crack originating at the edge and crossing the first cutting line, the initial crack extending in a second direction different from the first direction; and [0011] utilizing a laser cutting process on the brittle substrate The initial crack forms a second cutting line extending in the second direction, the initial crack does not coincide with the second cutting line and the second cutting line extends along the initial crack. And a fragile substrate on which a first cutting line and a 097110077 are formed. Form No. A0101 Page 5 / Total 15 Page 1003085051-0 1342811 [0014] [0015] [0016] 097110077 100 years 03 On the 14th of the month, the second cutting line of the replacement page is replaced, the first cutting line is adjacent to one edge of the brittle substrate, and the position of the brittle substrate adjacent to the starting end of the first cutting line forms the starting edge and spans the first cutting An initial crack of the line, the second cut line extending followed by the initial crack. Compared with the prior art, the above method for laser-cutting a brittle substrate can effectively avoid subsequent formation by forming a cutting process of forming a second cutting line at a position adjacent to the beginning end of the first cutting line after forming a first cutting line. The cutting line extending in the first direction and/or extending in the second direction (a) fails due to the inability to cross the starting end of the cutting line in the other direction, or (b) deviates from the capital: none, thereby achieving Higher cutting yield. [Embodiment]
下面將結合附圖對本發明實施例作進一多'之詳細說明。 iS 參見圖3至圖5,本發明實施例提供之雷’射切割脆性基板 之方法,其包括以下步驟 如圖3所示,提供一個脆性分用雷射切割製程 於脆性基板1〇〇之鄰近脆性基^kr〇4之一邊緣ιοί之位置 形成一條第一切割線110,第一切割線110沿A1方向延伸 。其中,脆性基板100通常為陶瓷基板、玻璃基板、石英 基板、玻璃矽晶圓或發光二極體晶圓等非金屬基板。脆 性基板100可為一方形板件(如圖3所示),或依實際需求 而定之其他形狀工件,例如圓形件。雷射切割製程可大 致包括步驟:(a)利用一雷射光束加熱脆性基板100,並 使雷射光束與脆性基板100產生一沿A1方向之相對運動; 以及(b)向脆性基板100施加(例如喷射)一冷卻流體(例 表單編號A0101 第6頁/共15頁 1003085051-0The detailed description of the embodiments of the present invention will be described below with reference to the accompanying drawings. iS Referring to FIG. 3 to FIG. 5, a method for laser cutting a brittle substrate according to an embodiment of the present invention includes the following steps, as shown in FIG. 3, providing a brittle fractional laser cutting process adjacent to a brittle substrate. A position of one edge ιοί of the brittle base ^kr〇4 forms a first cutting line 110, and the first cutting line 110 extends in the A1 direction. The brittle substrate 100 is usually a non-metal substrate such as a ceramic substrate, a glass substrate, a quartz substrate, a glass germanium wafer, or a light-emitting diode wafer. The brittle substrate 100 can be a square plate (as shown in Figure 3), or other shaped workpieces, such as circular members, as desired. The laser cutting process can generally include the steps of: (a) heating the brittle substrate 100 with a laser beam, and causing the laser beam to generate a relative movement in the A1 direction with the brittle substrate 100; and (b) applying to the brittle substrate 100 ( For example, jetting) a cooling fluid (example form number A0101 page 6 / total 15 pages 1003085051-0
13,42811 100年03月14日梭正替換頁 如’氣液混合物)以局部冷卻加熱之跪性基板1〇〇,以於 脆性基板110上形成一條第一切割線11〇。進一步的,於 雷射光束加熱脆性基板1〇〇之前,還可於第一切割線11〇 之起始端11卜利用鑽石刀、刀輪或雷射刻劃等形成一個 初始裂紋(initial crack)(亦即圖3中第—切割線11〇 之實線部分之左側部分),該初始裂紋於雷射光束及冷卻 流體之作用下成長為全斷線(亦即,圖3中之第一切割線 110之實線部分)。 • [0017]如圖4所示,於脆性基板10〇上之鄰近第一切割線110之起 始端111之位置形成一個初始裂紋122 ;初始裂紋122起 始於邊緣101且跨過第一切封赢11〇。初始裂紋丨Μ與余 一切割線110之起始端11丨相^,其沿干同於A1方向之A2 方向延伸。A1方向與A2方向相交,例如垂直相交。初始 裂紋12 2可經由鎮石刀、刀輪或雷射刻劃形成。 [0018]如圖5所示,利用雷射切割製程殄脆性基板1〇〇上沿著初 始裂紋1 2 2形成一條沿A 2方向延伸之第二切割線12 〇,進 而可製得一如圖5所示之其上形成有第一切割線η 〇及與 其相交之第二切割線120之脆性基板1〇〇。第一切割線 110與第二切割線12〇位於脆性基板】00之同一表面。其 中,雷射切割製程可大致包括步驟··(3)利用一個雷射光 束加熱脆性基板1〇〇,並使雷射光束與脆性基板1〇〇產生 —沿Α2方向之相對運動;以及(b)向脆性基板1〇〇施加( 例如喷射)一冷卻流體(例如,氣液混合物)以局部冷卻加 熱之脆性基板100,以於脆性基板100上形成一條第二切 割線120。第二切割線120之起始端12〗與第—切割線11() 097110077 表草編Sfe A0101 第7頁/共15頁 1003085051-0 ___I_, 100年03月14日按正替换頁 之起始端111相交,初始裂紋122沿A2方向成長為一全斷 線(亦即圖5中之第二切割線1 2 0之實線部分)。 [0019] 需要指明的是,本實施例中之第二切割線120可為沿A2方 向延伸之第一條切割線(如圖5所示),亦可為沿A2方向延 伸之最後一條切割線;另外,第一切割線11 0亦可為沿A2 方向延伸,相應地,第二切割線12 0為沿A1方向延伸。 [0020] 此外,對於圖5所示脆性基板100之後續切割處理,可先 沿A1方向再沿A 2方向進行切割以於脆性基板1 0 0上再形成 [0021] 多條相交之切割線,亦可先沿向再沿A1方向進行切13,42811 On March 14, 100, the shuttle replacement page, such as the 'gas-liquid mixture,' partially cooled the heated substrate 1 to form a first cutting line 11〇 on the brittle substrate 110. Further, before the laser beam heats the brittle substrate 1 , an initial crack may be formed at the beginning end 11 of the first cutting line 11 by using a diamond knife, a cutter wheel or a laser scribing or the like ( That is, the left side portion of the solid line portion of the first cutting line 11〇 in FIG. 3, the initial crack grows into a full disconnection under the action of the laser beam and the cooling fluid (that is, the first cutting line in FIG. 3) The solid line of 110). [0017] As shown in FIG. 4, an initial crack 122 is formed on the brittle substrate 10 at a position adjacent to the starting end 111 of the first cutting line 110; the initial crack 122 starts at the edge 101 and spans the first slit Win 11 baht. The initial crack 丨Μ is intersected with the starting end 11 of the remaining cutting line 110, which extends in the A2 direction which is the same as the A1 direction. The A1 direction intersects the A2 direction, for example, perpendicularly intersects. The initial crack 12 2 can be formed by a town knife, a cutter wheel or a laser scoring. [0018] As shown in FIG. 5, a second cutting line 12 延伸 extending along the A 2 direction is formed along the initial crack 1 2 2 by using a laser cutting process, and a second cutting line 12 延伸 extending along the A 2 direction is formed. A fragile substrate 1 形成 having a first dicing line η 〇 and a second dicing line 120 intersecting therewith is formed thereon. The first cutting line 110 and the second cutting line 12 are located on the same surface of the brittle substrate 00. Wherein, the laser cutting process can generally include the steps of (3) heating the brittle substrate 1 利用 with a laser beam, and causing the laser beam and the brittle substrate 1 〇〇 to generate relative motion in the Α 2 direction; and (b) A cooling fluid (eg, a gas-liquid mixture) is applied (eg, sprayed) to the brittle substrate 1 to locally cool the heated brittle substrate 100 to form a second cutting line 120 on the brittle substrate 100. The beginning end 12 of the second cutting line 120 and the first cutting line 11 () 097110077 table grass Sfe A0101 page 7 / 15 pages 1003085051-0 ___I_, intersected at the beginning 111 of the replacement page 111 on March 14, 100 The initial crack 122 grows in the A2 direction to a full break (ie, the solid line portion of the second cut line 1 20 in FIG. 5). [0019] It should be noted that the second cutting line 120 in this embodiment may be a first cutting line extending in the A2 direction (as shown in FIG. 5), or may be the last cutting line extending in the A2 direction. In addition, the first cutting line 110 may also extend in the A2 direction, and correspondingly, the second cutting line 120 extends in the A1 direction. [0020] In addition, for the subsequent cutting process of the brittle substrate 100 shown in FIG. 5, the cutting may be further performed along the A2 direction in the A1 direction to form [0021] multiple intersecting cutting lines on the brittle substrate 100. You can also cut along the A1 direction first.
综上該,本發明實施例提 ,其經由採用於形成一條 割;緩而言之,後續之切割In summary, the embodiment of the present invention provides that it is used to form a cut; in a nutshell, subsequent cutting
'不作限定。 板之方法 t鄰近第一切 割線11 0之起始端111之位置形成一條切割線120之 切割製程,可有效避免後續形成之沿ΑΪ'方向延伸及/或A2'No limit. The method of the plate t forms a cutting process of the cutting line 120 adjacent to the starting end 111 of the first cutting line 110, which can effectively avoid the subsequent formation along the ΑΪ' direction and/or A2
方向延伸之切割線(1)因 上之切割線之 起始端而導致之切割失效預定方向而影響 切割精度,從而可達到較秦率。 [0022] 綜上所述,本發明確已符合發明專利之要件,遂依法提 出專利申請。惟,以上所述者僅為本發明之較佳實施方 式,自不能以此限制本案之申請專利範圍。舉凡熟悉本 案技藝之人士援依本發明之精神所作之等效修飾或變化 ,皆應涵蓋於以下申請專利範圍内。 【圖式簡單說明】 [0023] 圖1係利用雷射切割製程切割脆性基板之一局部剖示圖。 097110077 表單編號A0101 第8頁/共15頁 1003085051-0 1342811 100年03月14日梭正替換頁 [0024] 圖2係先前技術中利用雷射切割製程所切割之脆性基板之 一切割效果示意圖。 [0025] 圖3示出本發明實施例提供之利用雷射切割製程於脆性基 板之鄰近其一邊緣之位置形成有一條沿第一方向延伸之 第一切割線。 [0026] 圖4示出於圖3所示脆性基板之第一切割線之起始端形成 有一個起始於該邊緣且跨過第一切割線之初始裂紋。The cutting line extending in the direction (1) affects the cutting precision due to the cutting direction of the cutting end due to the cutting end of the cutting line, thereby achieving a higher Qin ratio. [0022] In summary, the present invention has indeed met the requirements of the invention patent, and the patent application is filed according to law. However, the above description is only a preferred embodiment of the present invention, and it is not possible to limit the scope of the patent application of the present invention. Equivalent modifications or variations made by persons skilled in the art in light of the spirit of the invention are intended to be included within the scope of the following claims. BRIEF DESCRIPTION OF THE DRAWINGS [0023] FIG. 1 is a partial cross-sectional view showing a brittle substrate cut by a laser cutting process. 097110077 Form No. A0101 Page 8 of 15 1003085051-0 1342811 March 14th, 2014 Shuttle Replacement Page [0024] FIG. 2 is a schematic view showing a cutting effect of a brittle substrate cut by a laser cutting process in the prior art. 3 shows a first cutting line extending along a first direction at a position adjacent to an edge of the brittle substrate by a laser cutting process according to an embodiment of the present invention. 4 shows that an initial crack originating from the edge and crossing the first cutting line is formed at the beginning of the first cutting line of the brittle substrate shown in FIG.
[0027] 圖5示出於圖4所示脆性基板上沿著初始裂紋形成有一條 沿第二方向延伸之第二切割線。 【主要元件符號說明】 [0028] 玻璃基板:10 [0029] 雷射光束:2 0 [0030] 冷卻流體:30 [0031] 初始裂紋:11、122[0027] FIG. 5 shows that a second cutting line extending in the second direction is formed along the initial crack on the brittle substrate shown in FIG. 4. [Main component symbol description] [0028] Glass substrate: 10 [0029] Laser beam: 2 0 [0030] Cooling fluid: 30 [0031] Initial crack: 11, 122
[0032] 全斷區:12 [0033] 盲裂紋:1 4 [0034] 邊緣:101 [0035] 第一切割線:11 0 [0036] 起始端:111、121 [0037] 第二切割線:1 2 0 [0038] 第一方向切割線:A1 0、A11、A1 2、A1 3 097110077 表單編號A0101 第9頁/共15頁 1003085051-0 1342811 ,_* 100年03月14日修正替換π [0039] 第二方向切割線:Α20 097110077 表單編號Α0101[0032] Full-break zone: 12 [0033] Blind crack: 1 4 [0034] Edge: 101 [0035] First cutting line: 11 0 [0036] Starting end: 111, 121 [0037] Second cutting line: 1 2 0 [0038] First direction cutting line: A1 0, A11, A1 2, A1 3 097110077 Form number A0101 Page 9 / Total 15 pages 1003085051-0 1342811 , _* Correction of replacement of π [0039] ] Second direction cutting line: Α20 097110077 Form number Α0101
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| Publication number | Priority date | Publication date | Assignee | Title |
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| TWI677394B (en) * | 2013-11-19 | 2019-11-21 | 美商柔芬新拿科技公司 | Method of closed form release for brittle materials using burst ultrafast laser pulses |
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| US8946590B2 (en) * | 2009-11-30 | 2015-02-03 | Corning Incorporated | Methods for laser scribing and separating glass substrates |
| US20180015569A1 (en) * | 2016-07-18 | 2018-01-18 | Nanya Technology Corporation | Chip and method of manufacturing chips |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| TWI677394B (en) * | 2013-11-19 | 2019-11-21 | 美商柔芬新拿科技公司 | Method of closed form release for brittle materials using burst ultrafast laser pulses |
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