TWI237030B - Ion-sensitive, water-dispersible polymers, a method of making same and items using same - Google Patents

Abstract

The present invention is directed to ion-sensitive, water-dispersible polymers. The present invention is also directed to a method of making ion-sensitive, water-dispersible polymers and their applicability as binder compositions. The present invention is further directed to fiber-containing fabrics and webs comprising ion-sensitive, water-dispersible binder compositions and their applicability in water-dispersible personal care products.

Description

1237030 __ A7 Γ ----- 5. Description of the invention (1) I Aiming ^ A suitable invention is a concept applied to the decomposition of polymers by ion-induced water. The method invented by the crew is also applicable to the idea of decomposing polymers with ion-induced water and it is also applicable to adhesive compositions related to disposable items. This sun and moon is further applied to disposable items such as wipes containing an adhesive composition of ion-sensitive water-splitting polymers. BACKGROUND OF THE INVENTION Disposable problems have been contagious over the years, providing disposable spoons, diapers, diapers, wipes, incontinence clothing and sanitary napkins. Although there has been great progress in dealing with this problem, and the lack of its ten-point correlation has been unable to produce a saving adhesive fiber fabric, it can easily decompose or disintegrate in water, but still has sufficient strength for use. For example, U.S. Patent No. 2,241,373 and U.S. Patent No. 4,1 86,233 are disclosed. Without such a product, if not removed, the user's ability to scour the product would be greatly reduced. Furthermore, the ability of the product to disintegrate in the landfill is quite limited, as most of the product components, even if microbially degradable or photodegradable, are compressed or coagulated together by the plastic that has been lowered for a long period of time. Therefore, if the plastic disintegrates in water, the internal components can be reduced, resulting in plastic compression cracking or coagulation. Disposable products (such as diapers, sanitary napkins, and adult incontinence care products) can be flushed to the toilet. Often such articles contain a body-side pad, which must pass quickly through a fluid (such as urine or menses) so that the fluid can be absorbed by the absorbent core of the article. In general, the bodyside pad may be an adhesive fibrous fabric, which ideally has many characteristics' such as softness and flexibility. The fiber woven paper size of the body side cushion material is applicable to China National Standard (CNS) A4 (21Q X 297) ^ CWC-C \ mDOWS ^ rnms \ U5erhDesktop \ PK-001-0734.Doc December Η 1237030 A7 V. Description of the invention (2) Generally, most fibers are arranged and connected together by wetting or drying (air) at will to form an adhesive weave # with a composition of the admixture. Function. In any case, fibrous fabrics containing these compositions tend to be undispersed, and-generally, there are some problems in domestic sewer systems.-Threading Recently the adhesive composition has been developed to be more dispersible and more environmentally friendly than past adhesive compositions. The types of adhesive composition include polymeric materials with reverse dissolution. These adhesive compositions are insoluble in warm water, but soluble in cold water, such as in the toilet. Many polymers are known to show turbidity in water-soluble vehicles. Point or reverse dissolution characteristics. These polymers have been cited in several publications for various purposes, including (1) as evaporation retarders (Japanese Patent No. 62). No. 7162); (2) As a temperature-sensitive composition, it is beneficial as a temperature indicator due to the combination of bright color changes and consistent temperature changes (Japanese Patent No. 6192527), and (3) as a heat-sensitive material, which is specifically It is opaque at temperature and becomes transparent when cooled below a certain temperature (Japanese Patent No. 5 1003248 and Japanese Patent No. 81〇357〇3); (4) As a wound bandage, it has a good Absorptive features and can be easily removed (Japanese Patent No. 6233809); and (5) as a flushable personal care product (US Patent No. 5,509,913, issued by Richard S. Yeo on April 23, 1996 , And transferred to Kimberly-Clark International Co., Ltd.). Other interesting recent adhesives include ion-sensitive adhesives. Several US and European patents were transferred to Japan ’s Li-ion Co., Ltd., whose disclosures include acrylic and Alkyl or aryl acrylates. Ion-sensitive polymers. See U.S. Pat. Nos. 5,3 12,883, 5,3 17,063, and 5,384,189 at this paper size. China National Fresh (CNS) A4 Specification (21G X 297 Male #) ~ J _ _ ____ In the following, U.S. Patent Application Serial No. 09 / 223,999 discloses a modified anion-modified acrylic terpolymer with a continuous anion that improves dispersibility in harder water (ie, rises to 200 ppm Ca2 + and / or Mg2 +). In any case, when used When used as an adhesive for personal use, Lion Co., Ltd. described above can ionically polymer and sulfonated anions of common undefined uses to change acrylic terpolymers to increase the stiffness of the sheet, increase the stiffness of the sheet, and reduce the adhesive. Spray power and higher product costs. Another close-to-dispersive personal care product is U.S. Patent No. 5,281,306 which was disclosed by Ka 0 Limited of Tokyo, Japan. This patent discloses a water-washing sheet, that is, a wet wipe, which comprises treating a water-dispersible fiber with a water-soluble binder having several bases. This wash sheet is treated with a detergent containing 5% to 95% water-compatible base solvent and 95% to 5% water. The preferred organic solvent is glycerol. The washed flakes have wet strength and are not dispersed in an organic solvent cleaner, but are dispersed in water. Although many patents disclose various ionic and temperature-sensitive compositions of water-dispersible or flushable materials, dispersible products with softness, flexibility, three-dimensional and elasticity need to be stored; body fluids (including diarrhea) are cored at body temperature Suction and complete structure; and suitable fiber dispersion after toilet flushing, so the fiber has not become entangled with tree roots or bent in the dewatering pipe. In addition, it is known that ion-sensitive polymers (such as the common indefinite uses of Lion Co., Ltd. and Kimberly-Clark) have high viscosity at high mass force rates, which makes spray applications impossible or impossible. Furthermore, there is a need for flushable product technology that has water dispersible properties around the world (including soft and hard water regions). Furthermore, a water-dispersible adhesive that reduces the wettability of the product is needed so that it can be used for easy spraying and the same use, and penetrates into the product. The most top \ PK-00U734.Doc December 24, 2001 1237030 A7 B7 V. The invention said. Ming (there is a need for persistent water-dispersible, flushable wipes during storage, and to maintain the desired degree of wet strength during use , And thirst with a moist composition without organic solvents. Tang Zuo Nu >>, ", and there are black products that endanger safety and environmental concerns and fair prices, which cannot be achieved in the past. Isl 齐 Sr ior ^ ^ ti7_ 'Invention capture: The present invention is an ion-sensitive polymer formulation that has been developed to address the aforementioned issues regarding currently available ion-sensitive polymers and other polymers described in the literature. The ion-sensitive polymer of the present invention The formula has a "trigger property", so that the polymer is not dissolved in a wet composition containing ions of a specific type and concentration, such as a monovalent salt solution at a concentration of about 0% to 10%, but when water is used, Soluble when diluted, including divalent salt solutions (such as hard water up to 200 ppm (parts per million) and iron ions). Some different ion-sensitive polymer formulations (because Ionic cross-linking, so the dispersibility is lost in hard water), the polymer formulation of the present invention and / or money ions are less money. The flushable products with the polymer of the present invention remain dispersible in hard water Moreover, the ion-sensitive polymer formulation of the present invention may have the characteristics of improving the spraying ability or reducing the high shear viscosity, improving the wettability of the product, or reducing the stiffness and viscosity of the product. The polymer formulation of the present invention Used as an adhesive and structural component of air-laid and wet-laid nonwoven fabrics, such as body side flow, flow distribution material, fluid inhalation material flow) or sealing discs for various personal care ^ cover stock). The polymer formulation of the present invention is especially used as a binder material for sandy personal care products, especially for personal wipes. (Please read the precautions on the back before filling this page). n ϋ n ϋJ ^ T · --line-

This paper size is applicable to the national standard (CNS) A4 specification 〇01237030 A7 ----——_ B7 V. Description of the invention (ό) I-" "-such as cleaning or disposing of the skin, removing makeup, removing nail polish, Medical care and cleaning for hard surface cleaning, car maintenance, including cleaning agent, disinfectant Xinsi. During storage and use, 'the flushable product maintains intact or wet strength' and when the salt concentration drops below a critical level, it breaks apart or disperses after being placed in the toilet. Suitable substrates for the treatment include tissue (such as continuous or non-creped tissue), coforms, hydroentangled fabrics, airlaid mats, fluff pulp, nonwoven fabrics, and composites thereof. The method of manufacturing non-continuous tissue and cast three-dimensional tissue fabrics used in the present invention can be found in the general holding "Resilient Webs and Disp〇sable Wet Elastic Fabrics and Disposable Articles Made of It

Chiu et al., U.S. Patent No. 5,429,686, issued July 7, 2005; U.S. Patent No. 5) 99, ^ 2, issued by sJSudall and SA Engel on March 21, 1995; by Wdndt et al. U.S. Patent No. 5,672,248, issued on September 30, 1997; U.S. Patent No. 5'607,551, issued by Farrington et al. On March 4, 1997, which is fully incorporated herein by reference. The tissue structure formed by the above patent is particularly useful for providing good cleaning of wet wipes. Providing coarseness grades on other substrates also promotes good cleaning, and can also be embossed, cast, wet, and completely air-dried on coarse and fine fabrics. The airlaid material can be formed by measuring the airflow containing fibers and other arbitrary materials in a dry state, and moving the iron wire horizontally to form a net. For example, a suitable system and device for an airlaid mixture of fibers and thermoplastic materials is disclosed in US Patent No. 4,157,724 (Perssoon), which is issued on this paper (please read the precautions on the back before filling this page ) Order · Line · 1237030 Δ7 __B7_________ 5. Description of the invention (7) (Please read the notes on the back before filling this page) Published on June 12, 1979, and reissued in the United States Patent on December 25, 1984 No. 31,775; U.S. Patent No. 4,278,1 13 (? 6 ^ 3〇11) issued on July 14, 1981; U.S. Patent No. 4,264,2 8 9 (Day), issued on April 28, 1981 · U.S. Patent No. 4,352,649 (Jacobsen et al.), Issued on October 5, 1982; U.S. Patent No. 4,3 53,687 (Hosier, et al.), Issued in 1982 October 12, said, U.S. Patent No. 4,494,278 (Kroyer et al.), Issued on January 22, 1985; U.S. Patent No. 4,627,806 (Johnson), issued in 1% 6 years 12 March 9; U.S. Patent No. 4,650,409 (Nistri et al.), Issued March 1987 17th; and U.S. Patent No. 4,724,980 (Farley), which was issued on February 16, 1988, and U.S. Patent No. 4,640,810 (Laursen, et al.), Which was issued on February 3, 1987. The invention also discloses how to make a water-dispersible non-woven fabric, including a sealing disc (pad), a suction (surge) material, and a wet wipe. Persistent in fluids, using the unique polymer formulation described above as a binder. As a result, due to suitable ion sensing, the non-woven fabric is flushable and water dispersible, which can cause disregard of the rigidity of toilet water in the United States and the world. The dispersible article of the present invention may also have properties which improve the flexibility and flexibility. Such products also have reduced viscosity. In the case of Erbeita, the polymer formulation of the treated article has the ability to improve the spraying ability of the product, which improves the polymer distribution on the product and penetrates into the product, reducing costs. The present invention further discloses a wet wipe with improved wet composition. The hair 1237030 A7

: TCac_feLr P I It shows that the wipes using polymer formula can be stored for a long time, and have the ideal wet strength during use, and wetting or cleaning agent with less organic solvent. These characteristics and advantages of the present invention will become more apparent after reviewing the following detailed description of the disclosed embodiments, the accompanying drawings and the scope of patent application. Brief description of the figure The first figure is a bar chart of the wet strength data describing the three adhesive formulations as a function of ionic environment and soaking time. The second figure shows the wet tensile strength that can be changed in time when the fabric containing 68 gsm of cork airlaid fabric and ion-sensitive adhesive is immersed in a solution containing calcium ions (recorded by CDWT, exceeding 2.54 cm per immersion). Time range in grams) chart. The third figure is a comparison group of two data taken from the second figure of a Lion SSB-3b product (referred to as code 3300) with a continuous salt sensing adhesive mixed with Dur-O-Set (R) RB polymer at a 75/25 ratio. . Detailed description of several examples: In order to effectively use ion-inductive formula, it is suitable for use in flushable or water-dispersible personal care products. The formula is ideal for (1) function; that is, to maintain the wet strength under controlled conditions and to decompose quickly. Or in soft or hard water, such as toilets and sinks in the world; (2) safe (non-toxic); and (3) more economical. In addition to the foregoing, 'when used as a non-woven substrate (such as a wet tissue adhesive) composition, there are ion-sensitive formulations, (4) disposal in accordance with commercial principles; that is, relatively fast application in large-scale principles, such as spraying Where the binder is required to make up in high shear

(Please read the precautions on the back before filling this page)-丨 Binding: -Line- This paper size is applicable to IP standard S) A4 size (210 x 297 public love) cyv Huayes products / weaving milk cCtecem6er24. · V. Description of the invention (9 Viscosity; (5) Provide an acceptable degree of flake or wettable low viscosity Γ for improved product touch, such as improving the softness of the product and lowering the point: and another =! 本 = 巾 的Wet p ... ⑺Improving skin care, such as lowering the skin (2 muscle vocal sternness, (8 tactile f, qian (9) promotes good by providing a balance between friction (sliding) on the skin and friction and lubricity) Cleaning. The ion-sensitive polymer formulation and articles of manufacture of the present invention, especially wipes containing a unique wet composition below the hair, can be in contact with many or all of the above principles. Tian ..., not sure is the preferred implementation of the present invention All the advantages of the examples are within the scope of the present invention. The polymer formulation of the present invention can be a single trigger polymer (such as an ion-sensitive polymer) or a combination of two or more different polymers (such as a trigger polymer and a Co-binder) shaped Ideally, at least one polymer of the polymer formulation of the present invention is a micro-ion-sensing polymer. Ion-sensing polymers are known techniques and include any polymer that is water-soluble and that varies according to the type and amount of ions in the water. Ion-sensing polymers beneficial to the present invention include, but are not limited to, Lioxi polymers (such as Lion acrylic terpolymers) that are superior to the above, and joint undecided case transferred to Kimberly-Clark International Corporation 09 / 223,999 sulfonated anion cross-linking propylammonium S51 dimer; jointly undecided US Patent Application Serial No. XXX, which was filed on May 4, 2000, and titled "Ion-Inductive Hard Water Dispersible Polymer and Uses thereof, , (I〇n-Sensitive Hard Water

Dispersible Polymers and Applications Therefor (self-proclaimed KC No. 1585 1; J & a No. 113〇2-〇481; Express Mail Symbol No. EL498682165US), also transferred to Kimberly-Clark International Corporation; this paper The scale is applicable to the Chinese National Standard (CNS) A4 specification stone 0x 297 public love) m〇WS ^ n} files \ i / sefADesktop \ PKO01 ~ 0734.Doc December 24, 2001 A7 1237030 __B7___ 5. Description of the invention (1〇) Other chemosensory polymers, including U.S. Patent No. 6,043,3 17, issued March 28, 2000 by Mumm et al., Are also transferred to Kimberly-Clark International Corporation; which is fully incorporated herein by reference.

Other known trigger polymers include temperature- and heat-sensitive polymers, as well as water-dispersible polymers that become dispersible to help toilet bowls or other water sources, such as those issued by Pomplun et al. Patent No. 5,948,710 was transferred to Kimberly-Clark International. Kimberly-Clark International specifically mentioned that other devices that propose polymers that are degradable in water are temperature changes between uses. A certain polymer represents a cloud point temperature. As a result, these polymers will coagulate into a solution at a particular temperature, which is the cloud point. These polymers can be used to form fibers that do not dissolve in water above a certain temperature, but become soluble and therefore degrade in water at lower temperatures. As a result, it is possible to select or mix a polymer that will not reduce body fluids (such as urine) at or near room temperature (37 ° C), but will decrease when exposed to sub-temperature water, for example in Room temperature (23 ° C). An example of such a polymer is polydivinyl ether, which has a cloud point of 34 ° C. When the polymer is exposed to body fluids (such as urine at 37 ° C), it will not decrease when the temperature is greater than the cloud point (34 ° C). In any case, if the polymer is placed in water at room temperature (23 ^ C), the polymer will return to the solution exposed to water below the cloud point temperature over time. As a result, the polymer will begin to decrease. Mixtures of poly (divinyl methyl ether) and copolymers are also contemplated. Other cold-water-soluble polymers include polyvinyl alcohol branched copolymers, which are supplied by Nippon Synthetic Chemicals Co., Ltd. in Osaka, Japan. Their symbols are Ecomaty AX2000, AX10000, and AX300 £ S. This paper is sized for China National Standard (CNS) A4 specifications ( 210 X 297 mm) lw3 \ WIND0WS \ Pmfiles \ UsefADesktop \ Pfmm34.DOC December 24, 2001 (Please read the notes on the back before filling out this page)-Binding ·-丨 Line · 1237030 A7 V. Description of the Invention (Π) Ion-sensing polymer common undecided above and U.S. patent of Kimberly-Clark International Corporation <Ion-sensing Lion polymer and ionic-sensing polymer are used in the present invention # and to Kimberly-Clark International's joint undecided patent case No. 0 9/223 = Sulfonated anion-changing acrylic terpolymer is ideal because it is different from L.K. Co., Ltd. polymers and other polymers cited in the technical literature. Total = Unsettled polymer No. 09 / 223,999 Soluble in water with less than about Q and / or Mg2 + up to fine ppm to + and / or. The jointly undecided polymer composition minimizes the potential strong cross-interactions between anionic polymers and poplar ions in water. This strong interaction can be explained by the hard-Sy-Si base theory 1¾, which was proposed by R.G. Pearsoon in Yan House Vol. 85, p. 3533, U963) or by N. Isaacs in the Department of Polygonum It was suggested that this book was published by John Manley Scientific and Technical, John Wiley &amp; Sons of New York. Hard anions and hard cations interact strongly with one another. Soft anions and soft cations also interact strongly with one another. In any case, the opposite is also true, soft anions and hard cations interact weakly with one another. In Lion Polymer X, the carboxylate anion of sodium acrylate strongly interacts with the hard cations Ca2 + and / or + which are moderately present in hard water and hard water. By replacing the carboxylated anion with a softer anion, the interaction between Ca2 + and / or Mg2 + ions in hard and hard water that triggers polymer anions and hard cations is reduced. The term "soft water" as used herein means water having a divalent ion content of less than about 10 ppm. As used herein, "moderately hard water"-the word is intended to have a bivalent value of about 10 to 50 ppm.

---------- ^ · (Please read the notes on the back before filling in this page) • ^ 1 n 1 n--···· If —. Order-1237030 A7 V. Description of the invention (β Ion-containing water. As used herein, "hard water" — water meaning 50 ppm to 200 ppm monovalent ion content. By controlling the hydrophobicity / hydrophilicity balance and polymer composition and forming the formula Polymer combination to produce an ion-sensing polymer formulation with ideal adhesive strength and water dispersibility in water. The ion-sensing polymer may be a copolymer, such as trimerization. The ion-sensing acrylic copolymer of the present invention may contain a polymer capable of polymerizing into Any propionic acid monomer and acrylate (alkyl-propionate) monomer that are radically polymerized to copolymers (especially terpolymers). Suitable acrylic monomers include (but are not limited to) acrylic acid and methyl Propionic acid. Suitable acrylic monomers include (but are not limited to) propionic acid esters and methacrylic acid esters having alkyl groups of 1 to 18 carbon atoms and cyclic alkyl groups of 3 to 18 carbon atoms, preferably For alkyl groups with 丨 to 12 carbon atoms and 3 to 12 Atomic cyclic alkyl propionates and / or methacrylates can be used singly or in combination. Other suitable monomers include (but are not limited to) acrylamide and methacrylamide monomers (such as propidium Amine, NN, dimethyl acrylamide, n-ethyl acrylamine, n-isopropyl acrylamide and hydroxymethyl acrylamine), n- ▲ vinyl such as alkylone, n-ethylene formamide, hydroxyl Alkyl acrylates and light alkyl methacrylates (such as hydroxyalkyl ethyl methacrylate and hydroxyethyl acrylate). Other suitable acrylic monomers and acrylic monomers are disclosed in US Patent No. It is here for reference. A particularly preferred tertiary acid trimer is the L term SSB-3b 'which is obtained from Li On Co., Ltd. (In another embodiment, the ion-sensing polymer is from other acrylic acid or its derivative, Or less acrylic acid, methacrylic acid and its salts). The hyaluronic acid paper size of the present invention can be changed according to the desired characteristics in the final polymer _ t @ 0 house standard ^ A / OOIVS \ P / Dfi / es \ (ysert \ OesWop \ PK ^ 〇f ^ 734.Doc December 24, 2001 12370 30

5. Description of the invention (1 3) The relative amount of monomers in the copolymer. In A, the mole percentage of acrylic early bodies in 1 and 1 rose to about 70 mole%. Then again, _ Dan said in other words, the mole percentage of acrylic monomers in the copolymer is about 15 to 50% of Caoer ® μa, and Kamikawa Wuer. In other words, the mole percentage of the propionic acid monomer in the copolymer is about 25 to 40 mole%. In other words, examples of acrylic copolymers used in the present invention include 10 wt% to 90 wt% copolymers, ideally 20 wt% to 70 wt% acrylic acid and / or methacrylic acid, and 90 wt% to 10 wt%, preferably 80% to 30 wt% acrylic acid and / or methacrylic acid having i to 18 carbon atom alkyl groups or 3 to 18 carbon atom cycloalkyl groups, wherein idO mo Ear%, ideally 5 to 50 mole% of acrylic acid and / or methacrylic acid neutralize to form salts, or 30 wt% to 75 wt% copolymer, ideally 40 wt% to 65 wt % Propionate, 5 wt% to 30 wt%, ideally having 8 to 12 carbon atoms and 20 wt% to 40 wt% 10 wt% to 25 wt% acrylate and / or methacrylate "Ideally 25 to 35 wt% of propionate with 2 to 4 carbon atoms" and / or methyl propionate, of which 1 to 50 mole%, ideally 2 to 4 〇Mor acrylic is neutralized to form salts. The acrylic copolymer of the present invention may have an average molecular weight, which varies depending on the last use of the polymer. The acrylic copolymer of the present invention has a weight-average molecular weight ranging from about 10,000 to 5,000,000. In other words, the propionic acid copolymer of the present invention has a weight average molecular weight ranging from about 25,000 to 2,000,000, or more specifically, from about 200,000 to 1,000,000. The acrylic copolymer of the present invention can be prepared according to various polymerization methods, and a solution polymerization method is desirable. Suitable solvents for the polymerization process include (but are not limited to) reducing alcohol (such as methanol, ethanol, and propanol); water and one or more of the above

This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) CW ^^ D〇WS \ Pr〇files \ UsefADesKtop \ HK-〇〇m34.U〇c December 24,200T 1237030 V. Description of the invention ( : «&ΗΪΪ; ΗΪΪΚ.Γ Sr.pm Table I. Alcohol-reducing and mixed solvents; and water and one or more ketones (such as acetone or methyl ethyl ketone) mixed solvents. Polymerization in the present invention In the method, any polymerization initiator can be used. The choice of the special initiator can be determined according to many factors, including (but not limited to) the polymerization temperature, the solvent, and the monomer used. Suitable monomers used in the present invention include (but Not limited) 2,2, azobisisobutoxime, 2,2'-azobis (2-methylbutoxime), 2,2_azobis (2, t dimethylpentoxime), 2,2'_Azobis (1 眛 propane) dihydroacid, 2,2'-Azobis (N, N, dimethylisobutylamidine), persulfate, persulfate, and peroxidation Hydrogen. The ideal amount of the polymerization initiator is about 0 to 5 wt%, which is based on the total weight of the monomers stored. The polymerization temperature can be based on the polymerization solvent, monomers, and primers used. Agents, but generally ranged from about 20 ° C to 90 ° C. The polymerization time generally ranged from about 2 to 8 hours. The sulfonated anion-varying acrylic copolymer of the present invention includes a hydrophilic monomer such as acrylic acid or Methacrylic acid) which incorporates the acrylic copolymer of the present invention and one or more sulfonate-containing monomers. The sulfonate of these monomers is softer than the carboxylate anion because the negative charge of the sulfonate anion leaves Three oxygen atoms and a larger sulfur atom, as opposed to only the dioxy atom and a smaller carbon atom in the carboxylate anion. These monomers containing softer sulfonate anions and polyvalent ions in the shadow water (Especially Ca2 + ions and Mg2 + ions) interact. Suitable sulfonates containing monomers include, but are not limited to, 2-propanamidin-2-methyl-1-propanesulfonic acid (AMPS) and 2- Organic or inorganic salts of propionamine-2-methyl-1-propanesulfonic acid, such as alkaline soil metals and organic ammonia salts of 2-propenylamino-2-methyl-1-propanesulfonic acid, especially 2_ Sodium salt of propylene argon-2-methyl-1-propanesulfonic acid (Please read the precautions on the back before filling Page). -Ϋ 1 · n · Order · -ϋ ni I _ This paper rule &amp; Applies to China National Standard (CNS) A4 (210 χ 297 Public Love> C) i &gt; C ^ INDOWS ^ rofibs \ UserWesktopm ^ 01 ^ 734Doc December 24, 2001 1237030

(NaAMPS). Additional suitable sulfonate-containing monomers include, but are not limited to, 2-methyl-2-propenium bismuth, ethylene sulfonic acid, styrene sulfonic acid, thiopropylmethylpropionate, and 3-¾propionate Acrylic acid and organic or inorganic salts (such as alkaline soil metals and organic helium salts, such as alkyl ammonium hydroxide), where the alkyl group is Ci ~ Ci8. To maintain the hydrophobic / hydrophilic balance of the ion-sensing polymer, one or more hydrophobic monomers can be added to the polymer. The ionic sulfonated anion-varying acrylic copolymer of the present invention can be manufactured from monomers, including monomers: acrylic acid, methacrylic acid, or a combination thereof; 2 propane helium-2-methyl-1-propanesulfonic acid (AMPS) and Organic and inorganic salts, such as its sodium salt (NaAMPS); butyl acrylate and 2-ethylhexyl acrylate. Desirably, the ion-induced sulfonated anion-varying propionic acid copolymer of the present invention is produced from malonic acid, AMPS, NaAiyiPS or a combination thereof, butyl malonate and 2-ethylhexyl malonate. Desirably, the monomer is a thioanion-changing acrylic copolymer, and the mole percentage is: about 35 to less than 80 mole% acrylic acid, greater than 0 to about 20 mole% AMPS or Na AMP S, greater than 0 to about 65 mol% of butyl propionate and greater than 0 to about 45 mol% of 2-ethylhexyl acrylate. In other words, the percentage of moles of monomers present in the sulfonated anion-modified propionic acid copolymer is: about 50 to 67 mole% of propionic acid, greater than 0 to about 10 mole% of AMPS or NaAMPS About 15 to 28 mol% of butyl acrylate and about 7 to 15 mol% of 2-ethylhexyl acrylate. In other words, the percentage of moles of monomers present in the anion-modified acrylic copolymer is about 57 to 66 mole% acrylic acid, about 1 to 6 mole% AMPS or NaAMPS, and about 15 to 28 moles. % Butyl propionate and about 7 to 13 mole% of acrylic acid-2-

(Please read the precautions on the back before filling this page) -f-cloth. • Thread · This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) c + f OWS \ Proffles \ UsertWes_P reading rights 〇〇〇0_ 绀 24,20 (»1237030 A7 _______ Π7_ V. Description of the invention (16) Ethylhexidine, especially about 6 〇 Stem ΈΓ 〇 / tL · -r- μχ, —ρ

Wudou% propionate, about 5 mole% of AMPS or NaAMPS, about 24.5 hydrazine and glutamate Wudou% butyl acrylate, and about 0.5 mole (Please read the notes on the back before filling (This page)% 2-Ethylhexanoic acid. If AMPS is used as its monomer, it is desirable to neutralize at least part of the acidic components. Any inorganic or organic base can be used as a neutralizing agent to neutralize acidic ingredients. Examples of neutralizing agents include, but are not limited to, inorganic bases (such as sodium hydroxide, caustic potassium, lithium hydroxide, and sodium carbonate) and ammonium (such as monoethanolamine, monoethanolamine, helyl monoethanol, ammonia, trimethylamine, Triethylamine, tripropylamine, 1,4-oxazepine). Preferred neutralizing agents include sodium hydroxide, caustic potassium, or combinations thereof. Alternatively, the polymer can be acidified to produce sulfonated copolymers that are sensitive to salts, such as copolymers or acrylic acid-derived terpolymers. The method of sulfonating polymers is a well-known technique. A method for manufacturing sulfonated or vulcanized polymers is U.S. Patent No. 3,624,069 issued by Schwelger in January 1991; U.S. Patent No. 4,419,403 issued by Varona on December 6, 1983; issued by Shet in 1996 U.S. Patent No. 5,522,967 dated June 4, 2014; U.S. Patent No. 4,22,739 issued by Walles on September 2, 1980; U.S. issued by Motley et al. On July 21, 1998 Disclosed under Patent No. 5,783,200, and the following patents: U.S. Patent Nos. 2,400,720, 2,937,066, 2,786,780, 2,832,696, 3,613,957, 3,740,258 All incorporated here for reference. Sulfonation or sulfonation (such as sulfamic acid treatment by reaction with thionyl chloride or gasified sulfonic acid, or exposure to sulfur trioxide) revealed by Samuel Shore and D.R. Berger Warner This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 厕 toilet 1237030 A7

'Alcohol and Ether Alcohol Sulfates' in Anionic Surfactants, the first edition of M. Linfield: Marcel Dekker Ltd., pages i35 to i49, 1976 ·' And "The Mechanisms of Sulfonation an (1 Sulfation)" by Ben E, Edwards in the first edition of anionic surfactants at Warner M. Linfield, New York: 1976, 1 1 1 to 134 Marcel Dekker Co., Ltd., both of which are incorporated herein by reference. In a further embodiment of the present invention, the ion-sensing polymer formulations described above are used as flushable and / or non-washable products. To be effective as the United States As a binder material in medium flush products, the ion-sensitive polymer formula of the present invention retains durability and remains intact while being dry or lower in single-compensation viscosity, but becomes soluble in the product containing up to 200 ppm. Valence ions in water, especially calcium ions and magnesium ions. Ideally, the ion-sensitive polymer formulation of the present invention including acrylic copolymers is soluble A salt solution containing at least about 0.3 wt% of one or more inorganic and / or organic salts with monovalent ions. More desirably, the ion-sensitive polymer formulation of the present invention is dissolved in a solution containing at least about 0.3 wt% to 5 0% by weight of one or more inorganic and / or organic salts with a monovalent ion in a salt solution. Even more desirably, the ion-sensitive polymer formulation of the present invention including an acrylic acid copolymer is dissolved in a solution containing at least about t corrected% ~ 3 ”in the heart-or more salt solutions of inorganic and / or organic salts with monovalent ions. Suitable monovalent ions include (but not limited to) Na + ions, κ + ions," ions, Li 4 + ion, low molecular weight tetraammonium compounds (for example, with less than 5 carbons on any side groups) and their compounds. ', III · 11 w (Please read the precautions on the back before filling this page). • Line -In another embodiment, the present invention includes a modified sulfonated anion

Size of this paper Gu Zhongguan * a (cns) a vague X 297 mm) C-mNDOWS ^ rnHlemefADeskii ^ K-001 ^) 734.d〇c December 24, 2001 1237030 A7

: ws: r ^ .r 美 1 才 1, the acid-copolymer sensing polymer formula is a solvent containing at least about iwt% I or more in a salt solution of an inorganic and / or organic salt with a single ammonium ion I. More desirably, the ion-sensing polymer formulation of the present invention including a sulfonated anion-modified propionate terpolymer is dissolved in a solution containing at least about 5 () or more with a monopyrene ion II and / or Organic salt in salt solution. Even more desirable: The present invention's ion-sensing polymer formulation including an acrylic terpolymer modified by anion is dissolved in inorganic and / or organic materials containing at least about 1 to 3 Salt in salt solution. Appropriate monovalent ions include, but are not limited to, Na + ions, κ + ions, ions, Li 4+ materials, low molecular weight tetraammonium compounds (for example, having less than 5 carbons on any side groups), and their compounds. According to the latest research management of the American Chemical Society, for hard water, the United States has greatly changed the concentration of CaC03 to approximately 500CaC03 (approximately 2 (H) ppm Ca2 + ions) in soft water at a concentration near zero in hard water. American water hardness. To ensure the dispersibility of polymer formulations across countries (and throughout the world), the ion-sensitive polymer formulations of the present invention are ideally soluble in water containing up to about 50 PPmCa2 + and / or ions. More desirably, the ion-sensitive polymer formulation of the present invention is ideally soluble in water containing Ca and / or Mg ions rising to about 1 ⑻ Ppm. Even more desirably, the ion-sensing polymer formulation of the present invention is ideally soluble in water containing up to about 150% of melons or ions. Even more desirably, the ionomer composition of the present invention is ideally soluble in water containing Ca2 + and / or Mg2 + ions rising to about 2000 ppm. A wide range of polymer / surfactant systems can be used to provide and remove (please read the notes on the back before filling out this page); install I I I

Specifications of this paper rule (Ca ^ 〇WS ^ rofiles \ UserM) esktop \ PK-001-0734.Doc December 24, 2001 1237030

Ion-sensing Lion polymers and common pending patent application No. ο · 3,9 &quot; Ion-sensing sulfonated anions change the same function of the propionic acid trimer, and there is no need to limit half the sulfonic acid or carboxylic acid. Other systems are described below. Phosphorylated polymers containing phosphorus groups, thiophsulphonic groups, or other organic trivalent phosphorus groups as "soft" ions which may be mismatched with Ca + + can be used as the ion-sensitive polymer in the present invention. This may include changing cellulose or cellulose derivatives and related gums, which cannot be dissolved by monovalent salts or other electrolytes. In the example, a soluble cellulose derivative (such as cmc) is phosphorylated and becomes insoluble, and is effective as an ion-sensitive polymer formulation in a high ionic strength or appropriate pH solution, but dispersible In tap water. In another embodiment, a squamate bond group, which can be negative or amphoteric, is added to a polymer. The ammonium phosphate group can be added by coagulation of a hypophosphite having a first amine. The reaction of gaseous methyl hypophosphorous acid with amines can also trigger useful anionic groups. This is described by Guenther W. Wasow in "Phosphorous-Containing Anionics Surafactants", anionic surfactant: Helmut W. Stache's Organic Chemistry, New York: Marcei Dekker, 1996, pp. 589-590. The entire section, including Wasow mentioned above on pages 551 to 629, provides additional instructions related to the production of polymers with a trivalent phosphorus group and is incorporated herein by reference. Other methods of preparing phosphorylated cellulose fibers are well known. These methods can be adapted to CMC and then used as a binder. An exemplary method is US Patent No. 3,739,782 issued by Bernardin on June 19, 1993. Cellulose and synthetic or natural I compounds that have other "soft" anionic groups can be used as the ion-sensitive polymer of the present invention. (Please read the notes on the back before filling this page) -I I — — · -line-

This paper size applies to national standards (CNSM4 specifications (2) 0 X 297 mm C.) WINDOWS [Pr〇aes \ Usermesktop \ PK-001-0734.Doc December 24, 2001 -III · 1237030 A7 a- ^ Γ T- ° _fTT ^ (1 Talent uJ h ^ t II. Inn J fi 5. Description of the invention (2 () Natural polymers which have provided useful anionic groups can also be used in the present invention. Such polymers include agar, antlers Carageenan, which has a variety of sulfate groups. If necessary, these can be further changed to have additional anionic groups (such as horizontal acidification, gallic acidification, etc.). The polymer has two or more different soft anionic groups, such as sulfonate Acids and phosphoric acids, in which a considerable number of different anions can be adjusted to make full use of strength, ion stem sensitivity, and polymer dispersibility, can also be used in the present invention. This also includes zwitterions and amphoteric compounds. Especially polyampholyte can be Dissolves quickly above or below the point of isoelectric charge, but cannot dissolve at the point of isoelectric charge, which presents a potential triggering mechanism according to the electrolyte concentration and pH. Examples of polyampholyte include (but are not limited to) methacrylic acid Copolymers of enamines, copolymers of methacrylic acid and 2 vinyl nitriles, polyoxygenated ionomers with protruding amphoteric groups, and polymers formed directly from zwitterionic monomer salts, such as Salamone Ion pair co-monomers (Ipc), et al., All revealed by ⑺ &amp; New York's polymeric surfactants: Marcel Go ~ Co., Ltd. ^ State Years, pp. 251 ~ 254, which is incorporated herein by reference. Proteins have salts The possibility of pickling can be arbitrarily changed to have an additional soft ionic group, which can be used as the ion-sensing polymer of the present invention. For example, those systems containing thin glue derivatives or natural continuation polymers, at the south concentration (greater than in hard water) 250 ppm or less) of ma ion can not tolerate the binder 'but even allows hard water to sufficiently dilute the ions to provide a dispersible binder for the purpose of making a fortune. Therefore, what is thought of is the ion-sensing binder of the present invention Can't be dissolved in the solution containing the critical tritium library ^ 3 critical, more than monovalent metal solution, in some examples of detached tin ~ should not be dissolved in the paper containing Zhang scales towels Guan Jiaxian (CNS) A4 regulations; 297 mm) (Please read the precautions on the back before filling out this page) -I pack. -Line- • emDesWoplPK-00i-0734.DOC Decei mb ^ 24, 2001 1237030

: t &lt; ^ r ^ r &amp; 'tl In a solution of divalent metal ions above the scale concentration, but becomes soluble when the divalent ions and agricultural products fall to about 200 ppm or more to 100 ppm, making As a binder, the fiber matrix with ion-sensitive polymer maintains a good wet strength in a solution containing a rising concentration of divalent metal ions, and becomes water that can be dispersed in hard or medium hard water. Therefore, as a result, the monovalent or divalent metal ions (especially alkaline metal ions having monovalent ions, such as nano ions) are diluted to lose the wet strength and become the trigger mechanism of wet wipes that are flushable even in hard water. Natural polymers and gums suitable for use as ion-sensing adhesives are described by R.L. Whistler and J.N. BeMiller in Industrial Gels (IndustHal Gums), contract: Academic Press Co., Ltd., 1973, which is hereby incorporated by reference. Natural polymers that become firm or form gels in calcium ions are described below. Thin glue (adhesives that use medicinal tablets according to the nature of the report, sodium alginate and calcium alginate have good dispersibility, depending on Whistler and BeMiUer, page 62) cannot be dissolved in alginic acid, calcium alginate or general As salts of most polyvalent metals, but soluble in sodium glutamate or as salts with low molecular weight amines or tetraammonium compounds (page 67), they can be used in the present invention. This material can be used especially when the zinc element is a metal ion that does not dissolve. Other useful polymers include Carageenan and Iridophycan, both of which are sulfate-containing seaweed derivatives. A natural polymer (including cellulose and synthetic polymers) can provide anionic groups, such as acidic sulfate, phosphate, and carboxylic acid groups, which can form other molecules that bridge to the appropriate type and concentration of ions. When the ion concentration changes substantially, such as in the toilet article of the present invention, the article becomes weak and decomposed. (Please read the notes on the back before filling this page)

The dimensions of this paper are in accordance with China National Standard (CNS) A4 (210 X 297 mm) mm. ^ ^^ NDOWSiProliles \ Useft [Desktop \ PK-001-0734.Doc December 24, 2001 I — —-1237030 A7 r- I-_ ___ V. Description of the invention (22) Ion-sensing polymers include those that can be dispersed in an aqueous environment under specified conditions. Examples include alkali-dispersible or salt-insoluble materials. For example, ’Eastman AQ Copolymer (Eastman Chemical Company, Kingsport, Tennessee) is dispersible in deionized water and cannot be dissolved in saline. Articles such as diapers have been proposed for attempts to absorb body fluids. Further information on polymers is proposed by European Patent No. 77 ^ 5-A1, entitled "Nonwoven Web Comprising Water Soluble Polyamides and Compositions Containing Water-Soluble Polyamide" Articles Constructed Therefrom), published by SUAhmed on May 14, 1997. Beneficial amphoteric electrolytes include acrylamide copolymers that are highly sensitive to sodium vaporization concentrations. U.S. Patent No. 3,939,836 describes alkaline sulfate cellulose ester resins that give fabrics good dry tensile strength when such fabrics come in contact with saline fluids such as blood, menstrual fluid, or urine At this time, this strength retains a significant portion and can be quickly dispersed in water, which is incorporated herein by reference. The resin has a sulfate substitution effect of 0.10 to 0.45. In U.S. Patent No. 4,419,403, the colloidal sulfate of cellulose is effectively used in the binder f, whose t binder has many higher sulfate substitutions than the '836 patent, which is incorporated herein. Reference. 403. The patented adhesive forms a gel of gentle ion ten f. Other patents on dispersible polymers and wipes include U.S. Patent No. 7,117,187; 5,417,977; 4,309,469; 5,3 17,063; 5,3 12,883; 5,384 No. 189, No. 5,543,448; No. 5,571,876; No. 5,709,940; No. 5,718,790, stand I_ _1 This paper size is applicable to China National Standard (CNS) A4 specifications (210 X 297 male H ~ coffee surface w〇 p coffee 〇〇〇 detailed discussion

• Line · (Please read the precautions on the back before filling out this page) -I 1 n-Order · 1237030 A7 V. Inventive Note. (2 3) Merge here for reference. Co-Adhesive Copolymers. The polymer formulation of the present invention is formed from a single ion-sensing polymer or a combination of different polymers one or more days, wherein at least one polymer is an ion-sensing polymer. The second polymer is a co-binder polymer. The co-adhesive polymer is a kind and when combined with the ion-sensing polymer, it becomes a quantity. The co-adhesive polymer is ideally mainly dispersed in the ion-sensing polymer. That is, the ion-sensing polymer is ideally a continuous phase, and the common The binder polymer is ideally a discontinuous phase. Ideally, co-binder polymers may also encounter several additional criteria. For example, the glass transition temperature, i.e., &amp;, is lower than the glass transition temperature of an ion-sensitive polymer. In addition, the thread compound cannot be expected in the water towel, and the shearing degree of the ionophore is reduced. The solid mass of the co-binder in the initiating polymer is about 45% or less, specifically about 30% or less, more specifically about 20% or less, more specifically about 15% or less, and The most explicit is about 10% or less, the range of demonstration is about 1% to 45% or about 25% to 35%, and about 1% to 20% or about 5% to 25%. The amount of co-adhesive is small enough to form a co-adhesive of water-insoluble binder or film. The co-adhesive leaves a discontinuous phase that does not cause sufficient cross-bonds, or does not dissolve the binder so that the processing matrix is indispersible Danger. In one embodiment, the ion-sensitive polymer formulation of the present invention may include 75 wt% acrylic terpolymer and about 25 wt% poly (ethylene-ethyl acetate) co-binder. Ideally (but not necessarily), when combined with ion-sensitive polymers, the paper size of the paper applies to the Chinese National Standard (CNS) A4 &quot; i grid (210 X 297 mm 1237030) V. Description of the invention (24) 2 Adhesive The polymer will reduce the ion-induced shear viscosity until the second ion-sensitive polymer and the co-adhesive polymer can be sprayed. Spraying means that the polymer can be applied to the nonwoven fiber matrix with two sprays, and the polymer distribution It crosses the matrix and the polymer penetrates into the matrix, so that the polymer formulation is uniformly applied to the matrix. The co-binder polymer can be an emulsion. The surfactant system used in the emulsion generally harms the ion-sensitive polymer. Dispersibility. In some embodiments, the combination of an ion-sensing polymer and a co-binder polymer reduces the stiffness of the article, which is only compared to an article of an ion-sensing polymer. It has been found that in order to form a wipe, When polymers (such as sulfonated anion-modified propionic acid terpolymers) are applied to nonwoven substrates (such as air-laid, pulverized mussel pulp layers), nonwovens The sheet may have a number of undesired stiffness, when s loses the brittleness of the drying matrix, this is not good for the touch of the dried product or the feel of the dry fabric during the action. By the combination of ion sensing and common binder polymer, it can be reduced The stiffness of such articles. The co-adhesive polymer of the present invention may have an average molecular weight that varies according to the end use of the polymer. Ideally, the range of weight average molecular weight of the co-adhesive polymer is approximately 500,000 ~ 200,000,000. Ideally, the range of weight average molecular weight of the co-adhesive polymer is about 50,000, 100,000 to 100,000, 100,000, 100,000. You can experience the commonality of all the aforementioned standards. Adhesive polymers include (but are not limited to) poly (acetamidine-vinyl acetate), poly (styrene-butadiene), poly (phenylacetamidine-propionic acid), acetamidine trimer, neo Prien, polyester emulsion, propionate emulsion, polygasified olefins, ethoxylated-gasified olefin copolymers, chlorinated vinyl acetate emulsions, etc. are all non-crosslinkable (eg lack of N-methylolpropane Women and children Or other cross 1237030 A7 ----------- B7 _ V. Description of the invention (25) Bonding agent), cross-linking or potential cross-linking (ie prepared with cross-linking agent), but generally in the final product No cross-linking. A particularly preferred non-cross-linking poly (ethylene-vinyl acetate) is Dur-O-Set® RB 'from Natural Starch and Chemical Company of Bridgewater, New Jersey. A particularly preferred non-cross-linking poly (ethylene Styrene-butadiene) is Rovene⑧4817 'which is a Mallard Creek polymer obtained from Charlotte, North Carolina. A particularly preferred non-crosslinked poly (styrene-propanoic acid) is

Rhoplex® NM 1715K, obtained from Rohnl and I Hass of Philadelphia, Pennsylvania. When using an emulsion co-binder or any potentially cross-linkable co-binder, the 'emulsion prevents the formation of a binder that is inherently water-insoluble, The cement binds the fibrous matrix together and hinders the dispersibility of the article. Therefore, the emulsion can be cross-linker-free, such as NMA, or a cross-linker-free catalyst, or both. Alternatively, an inhibitor may be added, which harms the cross-linking agent or catalyst, so that the cross-linking is damaged even when the article is heated to the standard cross-linking temperature. Inhibitors may include free radical scavengers, methylhydroquinone, t-butylphenylphosphonodiol, pH control agents (ratio I such as potassium hydroxide), and the like. For example, for some emulsion cross-linking agents (such as N-methyl methacrylamide (NMA)), such as high pH like _ or higher can harm the standard cross-linking temperature (such as # 13 (rc Or higher). And or 'the object containing the emulsion co-binder can be maintained at a temperature lower than the cross-bonding temperature range ®, so that cross-linking does not lead to cross-linking, and the amount of money left is low enough. To place the object in a dispersible danger. And, alternatively, the number of cross-linkable emulsions is maintained at the beginning, so that even after the cross-linking, the object remains dispersible. For example, the W 1 fork-bondable emulsion dispersion is used as dispersive ion induction adhesion. Paper in the agent—National Standard ^ _____ 〇Wg £; A ^ DOWS ^ mfiles \ UserWes ^ mm34.Doc December 24, 2001

# ·-LINE · (Please read the notes on the back before filling this page) P Ψ momProfiles \ UsefADesktofm ~ 0m734.DOC December 24, 2001 1237030 V. Description of the invention (2 tablets, this allows even when the bonds are completely cross-linked Dispersible. For subsequent examples, the amount of the emulsion may be less than about 20 wt%, and more specifically, less than about 15 wt% of an ion-sensitive adhesive. The emulsion compound (whether or not cross-linked) need not be Co-adhesive. SEM photomicrographs of popular ion-sensitive adhesive films with non-crosslinked emulsions can be left as individual in the ion-sensitive adhesive, perhaps partly as a filler. Believe other materials A similar role may be provided, including dispersing minerals or particulate aggregates in ion-sensitive adhesives, which may optionally include added surfactants / dispersants. For example, in a proposed embodiment, the presperse limited Z Division ( Freeflowing Ganzpearl PS-8F particles from Piscataway, New Jersey), styrene / diphenylene copolymers with 0.4 micron particles can be dispersed in an ion-sensing adhesive to approximately 2 to 10 wt% To change the mechanical, tactile, and visual characteristics of ion-sensitive adhesives. Other filler-like materials include metal, glass, carbon, mineral, quartz, and / or plastic (such as acrylic or phenol) microparticles, particles, or beads, and have seals Hollow particles in a blunt atmosphere inside the inside. These examples include EXPENCEL phenol particles from Expancel, Sweden, which generally swells when heated, or the famous PM 6545 acrylic particles obtained from pQ Co., Ltd. of Pennsylvania. Foams (including CO2 decomposed in ion-sensing adhesives) can also provide discontinuous bubbles useful in ion-sensing adhesive binding, which allows the gas phase in the ion-sensing adhesive to be dispersed as a co-adhesive In general, if the covalent bond state of the connecting fiber is not provided in the water-dispersible mode of the product, any consistent material that is easily mixed with the adhesive (especially it has viscosity or bonding properties) can be used as a common material. Adhesive. In any case, it also provides additional benefits (such as reducing the size of the sprayed paper to the Chinese national standard (CN S) A4 specification (210 X 297 mm) I --- 1 · Installation ---- I &gt; (Please read the notes on the back before filling this page) Order .. i-line-1237030 A7 B7 V. Description of the invention (2 7. Viscosity) materials are exceptionally good. Viscous co-adhesives (such as emulsions) that do not contain cross-linking agents or that reduce the amount of cross-linking agents have been found to be particularly helpful in providing good results over a wide range of conditions, including Dry at high temperature. As mentioned above, the Tg of the co-adhesive polymer can be lower than the Tg of the ion-sensing polymer. This is thought to improve the flexibility of the treated substrate, especially in the dry state. Comparison of glass transition temperatures of some of the preferred polymers in the invention.

-——__ ^ 1. Critical evaluation of the glass of claw lean milk polymer: 鸪 transition temperature glass transition temperature -Ts sulfonated anion changed acrylic terpolymer (dry) ^-sulfonated anion changed acrylic terpolymer (wet)- 22 ° C Rhoplex NW 1715K (dry) -6 ° C Rovene 4817 (dry)-4 ° C Elite 33 (dry) 10 ° C Elite 22 (dry) -15. C (Please read the notes on the back before filling this page) f · -I ϋ 1 ϋ-. In another embodiment, the ion-sensitive polymer formulation of the present invention contains about 55 ~ 95 wt% sulfonated anion change Acrylic terpolymer and about 5 to 45 wt% poly (ethylene-vinyl acetate). More desirably, the ionic polymer formulation of the present invention comprises about 75 wt% of a sulfonated anion-varying propionic acid trimer and about 25 wt% of poly (ethylene-vinyl acetate). As stated above, useful co-binder polymers can include a variety of industrial emulsions, including those selected from the Rovene® series (styrene butadiene latex, Mai lard Creek polymer from Charlotte, North Carolina), Rohm and Haas' Rhoplex® latex and Elite⑧ latex from natural starch. --Line · -1111- This paper size applies to China National Standard (CNS) A4 (210x 297 mm) '\ WlNDOWS ^ ProHles \ UserWesktop \ PK-001-0734.Doc December24 2001 A7 B7 1237030 V. Description of the invention (2) Polymer emulsions or dispersions generally include small polymer particles such as cross-linkable ethylene-vinyl acetate copolymers, which are generally spherical, dispersed in water, and formulated with active ingredients such as low molecular weight emulsions or High molecular weight protective colloid) is stable. Some liquid adhesives can be applied to air-laid fabrics or other substrates through well-known non-woven fabric adhesive treatment techniques, including spraying or foaming applications, immersion infusion, curtain covering, etc. Wait for subsequent drying. In general, a wide range of latex compounds and other resins or emulsions can be considered, including latex acetate copolymers (such as Resyn® 2 5-1 103 of the United Petrochemical Division and Natural Dianfen Co., Ltd.) , Resyn⑧ 25-1 109, Resyn® 25-1 1 19, and Resyn® 25-1189), Ethyl-vinyl acetate copolymer emulsions (such as Air Flex by Air Products and Chemical Co., Ltd. -Ethyl Acetate Acetate), Propyl Acetate-Vinyl Acetate Emulsion Copolymer Emulsion (such as Rohm and Haas' Rhoplex® AR-74, Synthemul® 97-726 from Reichhold Chemical Co., Ltd., Resyn® 25 from Natural Powder & Chemical Co., Ltd. -1140, 25-1141, 25-1142, and Resyn-6820), ethylene-propylene terpolymer latex (such as 76RES 3 103 of the United Petrochemical Division and Resyn® 25 1 1 1 〇 of Natural Starch & Chemical Co., Ltd.), propylene emulsion Latex (e.g. Rhoplex® B-15J, Rhoplex® P-376, Rhoplex® TR-407, Rhoplex® E-940, Rhoplex® TR934, Rhoplex® TR-520, Rhoplex® HA-24, and Rhoplex® NW1825 from Rohm and Hass 'And Hycar® 2600 X 322, Hycar® 2671, Hycar® 2679, Hycar® 26120, and Hycar® 2600 X 347 from the Goodrich Chemical Group), styrene-butadiene latex (such as those obtained from the United Petrochemical Division) 76 RES 4100 and 76 RES 8100, Tylac® resin emulsion 68-412, Tylac⑧ obtained from Reichhold Chemical Co., Ltd. (Please read the precautions on the back before filling out this page)

P This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm J ^ CC.WNDOWS \ Profifes \ UserWeskt〇fAPK-001-0734.Doc December 24, 2001 A7 1237030 __B7___ V. Description of the invention (29) Resin Emulsions 68-067, 68-319, 38-413, 68-500, 68-50 1 and DL6672A, DL6663A, DL663 8A, DL6626A, DL6620A, DL615A, DL617A, DL620A, DL640A, DL6 obtained from Dow Chemical Company 50A) and rubber latex (such as Neoparin from Serva Biochemical), polyester latex (such as Eastman AQ 29D from Eastman Chemical Company), chlorinated olefin latex (such as B, F. Goodrich Chemical Group) Geon⑧352), ethylene-rhenium chloride copolymer emulsions (such as Air Products and chemical Air flex® ethylene-rhenium chloride), polyvinyl acetate equivalent polymer emulsions (such as Air Products and chemical Vinac®), Acetyl acetate emulsion resins (such as Synthemul® synthetic resin emulsions 40-502, 40-503, and 97-664 from Reichhold Chemical Co., Ltd., and Polyco® 2149, 2150, and 2 1 7 1 from Rohm and Haas). Also consider silicone emulsions and adhesives. The co-binder polymer may contain a surface-active compound that improves the wettability of the matrix after the binder is mixed applied. The wettability of a dry matrix that has been treated with an ion-sensing polymer formulation is a problem in some embodiments because the hydrophobic portion of the ion-sensing polymer formulation can become selectively advanced toward the gas phase during drying. When a wet composition is used After that (unless a surfactant), the hydrophobic surface that is trapped in the humidification is added to the wet composition. Surfactants or other surface-active ingredients in the co-binder polymer can be treated with an ion-sensitive polymer formulation to improve the wettability of the dry matrix. Surfactants in co-binder polymers do not significantly impede ion-sensitive polymer formulations. Therefore, the adhesive will maintain good integrity and the tactile properties of a wet wipe with the presence of a surfactant. In an embodiment, an effective co-adhesive polymer replaces the ionic sense (please read the precautions on the back before filling this page) _pack-· line. This paper size applies the Chinese National Standard (CNS) AUC grid (210x 297 CWC-C \ WINDOWS ^ roHles \ UserWesktop \ PK-001-0734.Doc December 24, 2001 A7 1237030 of the public 3 V. Description of the invention (30) The polymer formulation part should be allowed to achieve specific strength and the wipes should have at least Low stiffness, better tactile properties (such as lubricity or smoothness), or reduced costs' This is related to the lack of a binder polymer and the same wipes containing an ionic polymer formulation to achieve sufficient tensile strength. Co-Binders

Dry emulsion powder (DEP) binders (such as those of the VINNEK (R) system) of the Wacker t compound system (BurghaUsen, Germany) can be used in some embodiments of the present invention. Dispersible, non-flowing adhesive powder is formed from a liquid emulsion. Some dispersed polymer particles are provided in a protective matrix of water-soluble protective particles. The surface of the powder particles is protected from solidification of the mineral crystal plate. . As a result, once the polymer particles dispersed in the liquid are currently free flowing, the dry powder form can be re-disposed in water or turned into swollen, sticky particles with moisture. These particles can be applied to a bulky non-woven fabric by precipitating these fibers during airlaying, and then 10% to 30% moisture is added to cause the particles to swell and stick to the fibers. This can be called the "chewing gum effect", which means that the dry, non-tacky fibers in the fabric become sticky like chewing gum once they become wet. Obtain good adhesion to polar surfaces or other surfaces. These binders are preferably used as free-flowing granules formed from an emulsion that has been dried and treated with a medicament to prevent cohesion in a dry state. It can enter the air and settle in the fiber during air-laid action, or it can be applied to the substrate by electrostatic devices, direct contact, self-weight feeding devices and other devices. Either before or after drying the adhesive, it can be separated from the adhesive. Contact with moisture (liquid or gaseous), re-late the latex particles into hydrates and cause 〃 〃 This paper ruler (CJNS) A ⑵ 格 ⑵G X 297 ^ -------- ^ CW ^ CmNDOW ^ m ^^ erf ^ esktop \ PK-001 ^) 734.Doc December24 2001

-nf I. (Please read the precautions on the back before filling this page) Scale: Order · -Thread. 1237030 A7 B7 V. Description of the invention (Swell or stick to the fiber. Dry and heat to high temperature (for example, greater than 16 ° .c ), Causing the adhesive branch to become cross-linked and waterproof, but drying at lower temperatures (for example, at ιο ° C. or lower) can cause film formation, and the degree of fiber adhesion does not seriously impair the moisture dispersibility of the wipes. Therefore, it is believed that industrial products can be used by controlling the correction of the co-adhesive polymer without reducing the amount of cross-linking agent, such as limiting the time and drying temperature to provide a degree of adhesion without significant cross-linking.

Dr. Klaus Kohlhammer's "New Aidaid Binders" (on pages 20 to 22), published in Non-woven Reports International in September 1999, points out that emulsion binder powders have the advantage of being on fabrics. It can be easily incorporated into non-woven or airlaid fabrics during formation, whereas materials can be applied to the existing matrix, which allows for increased control over the configuration of all common binder polymers. Therefore, when using an inductive ion polymer formulation solution, a non-woven or air-laid fabric with a slightly wet dry emulsion binder can be prepared, and then the dry emulsion powder becomes sticky and promotes matrix cohesion. Alternatively, when the matrix has been treated with an ion-sensitive adhesive and dried, the dry emulsion powder &apos; in the matrix may be filtered and the dry emulsion powder may then become sticky for wet composition applications. In another embodiment, after the mixture is applied to the fabric by spraying, foaming application methods, or other known techniques, the dry emulsion powder is either sprayed onto the fabric with the powder of the ion-sensitive polymer formula solution or added and dispersed to dryness. The emulsion powder particles are dispersed into the ion-sensitive polymer formulation solution and dispersed into the ion-sensitive polymer formulation solution. ¥ Thread Adhesive Formulation and Fabrics The polymer formula of the present invention can be used as an adhesive. The paper size of the present invention is applicable to China National Standard (CNS) A4 specifications (210x 297 mm C articles mws \ Pmms \ use her sk (〇! M side micro Doc December24 2〇0011237030 A7 __ B7 _ V. Invention The (3 2) compound formulation can be applied to any fiber matrix. Adhesives are particularly suitable for use in water-dispersible products. Suitable fiber matrices include (but are not limited to) nonwoven and woven fabrics. In many embodiments, Especially for personal care products, preferably the substrate is a non-woven fabric. As used herein, "non-woven fabric" (non-woven fabric)-a word meaning to have individual fibers arbitrarily listed in a thick pad-like manner (including paper) Fabrics with a single fiber structure. Nonwoven fabrics can be manufactured by a variety of functions, including (but not limited to) airlaid, wetlaid, water entanglement, main fiber combing and bonding, and solution spinning. Binder composition It can be applied to fiber-based materials by any known application. Suitable uses of adhesive materials include (but are not limited to) printing, spraying, electrostatic spraying, gluing, overflow clips, Pressure roller, soaking or any other technique. The quantity of adhesive composition can be measured and uniformly distributed in the fiber matrix, or it can be distributed unevenly in the fiber matrix. The adhesive composition can be distributed to the entire fiber matrix, or can be distributed Within a variety of micro-tightly spaced regions. In most embodiments, the same distribution of adhesive composition is desirable. · For applications that are simply used in fiber matrices, the adhesive can be dissolved in water or has water. Good solvent in non-aqueous solvents (such as methanol, ethanol, propane, etc.). The amount of binder dissolved in the solvent can vary depending on the polymer used and the application of the fabric. Ideally, the binder solution contains about as high as 25 wt% (weight percent) of the binder constitutes a solid. More desirably, the binder solution contains about 10 ~ 20 wt% of the binder constitutes a solid, especially about 12 of the binder constitutes a solid. If ideal, the plasticity is enhanced Agents, perfumes, dyes, antifoams, fungicides, preservatives, surfactants, thickeners, fillers, transparent agents, adhesives, detackifiers And similar additives may be incorporated into the binder I___ - _ present paper offering fine rotation (⑽A tank ⑵

I ----- (Please read the precautions on the back before filling this page) Order .. • Line-1237030 A7 I ----- §Z_ ____ V. Description of the invention (3¾ I solution. Once the adhesive The composition is applied to the matrix, and the matrix is dried in any conventional manner. Once dried, the adhesive fiber matrix shows improved tensile strength when compared to an untreated wet-laid or dry-laid matrix, and when placed with a higher multivalency Ion-concentrated soft or hard water has the ability to "fall apan" or disintegrate quickly and agitate. For example, compared to the dry tensile strength of untreated substrates without binders, The dry tensile strength can be increased by at least 25%. More specifically, the dry tensile strength of the fiber matrix can be increased by 100% compared to the dry tensile strength of the untreated matrix without the binder. Even more special Yes, the dry tensile strength of the fiber matrix can be increased by 500% compared to the dry tensile strength of the untreated matrix without the binder. The ideal characteristic of the present invention is to effectively improve the tensile strength. Saved in An increase in the amount of binder composition represents only a small portion of the total matrix weight. The amount that can be increased for a particular application; however, the optimum amount of increase is the result. The result is an intact fibrous matrix in use and agitated in water. It also disperses quickly. For example, the binder composition is generally about 5 ~ 65 wt% of the total organic weight. More specifically, the binder composition can be about 10 ~ 35 wt% of the total organic weight. Even more special Yes, the binder component may be about 17 to 22 wt% of the total organic weight. The nonwoven fabric of the present invention has good tensile strength and ion triggering ability in use. The nonwoven fabric of the present invention is resistant to abrasion, For the formulation of oxalic acid dimer, it maintains significant tensile strength in an aqueous solution containing more than about 0% by weight of NaC1 or a mixture of monovalent ions, and for sulfonate anion. Cross-linked propylene fe dimer, Contains more than i wt% Nacl or the unit price is off the scale of this paper Applicable Chinese National Standard (CNS) A4 specifications (210 X 297 Kg £ 7 (Please read the notice on the back before filling out this page) Order ·- -Line · '^ WlNDOWSJ3ιΌliles \ UserfJ) esMopΨK ^ 001-0734.Doc December 24, 2001 1237030 V. Description of the Invention (3f submixture in the aqueous solution retains significant ^^ tensile strength. And, nonwoven fabrics can be very mild Appropriately dispersed in spines, 7. Because of the later characteristics, the nonwoven fabric of the present invention is also suitable for use in Aqueous A # disposables, such as sanitary napkins, diapers, adult disposable products, and dry and wet wipes.任何 Wipe wipes can be thrown into the flush toilet after use anywhere in the world. The fibers forming the upper fabric can be made from a variety of materials, including natural fibers, synthetic fibers, and their compositions. For example, the choice of fiber is based on the flushable fabric and fiber to be used last. For example, a suitable fiber-based Beco G includes (but is not limited to) natural fibers (such as cotton, linen, jute, hemp, wool, wood pulp, etc.). Similarly, regenerated cellulose fibers (such as viscose fibers and copper ammonium hafnium), modified cellulose fibers (such as cellulose acetate), or synthetic fibers (such as derived from polypropylene, polyethylene, polyolefin, polyester, Polyamide, polypropylene, etc.) can be used singly or in combination with another. If so desired ', one or more of the above fibers may also be used. Among the wood pulp fibers, any known papermaking fibers can be used, including softwood and hardwood fibers. For example, fibers can be chemically or mechanically pulped, bleached or unbleached, virgin or regenerated, high or low throughput, and so on. Can also be used for lye treatment, chemical coagulation or cross-linked fibers. Synthetic cellulose fiber types include tritium in all species and other fibers derived from fiber slime or chemically modified cellulose, including regenerated cellulose and lyocell (such as Lyocell). Chemically treated natural cellulose fibers can be used, such as lye-treated pulp, chemically coagulated or cross-linked fibers, or sulfonated fibers. Regenerated fibers can be used as well as virgin fibers. Cellulose made from microorganisms and other cellulose derivatives can be used. "Cellulose" as used here «1 ^ ------------ Packing --- (Please read the precautions on the back before filling out this page) Orders ----- Lines and paper sizes apply to China National Standard (CNS) A4 specification (210 X 297 mm i3 ^ WC ~ C. \ WIND〇W ^ Profiles \ UserfJ) esktop \ PK-001 ~ 0734.Doc December 24, 2001 1237030 --- V. Description of the invention ( 3 歹 (Cellu1〇S1C) —The word is intended to include any material that has cellulose as the main composition and explicitly contains at least 50 wt% cellulose or cellulose derivatives. Therefore, this item includes cotton, typical wood pulp, non- Lignocellulose fiber, cellulose acetate, cellulose triacetate, concrete, thermomechanical wood pulp, chemical raw wood pulp, debonded chemical wood pulp, maleix or bacterial cellulose Fiber length is important in fabrics of the invention. In some embodiments, such as punchable products, fiber length is more important. The minimum fiber length is determined according to the method selected to form the fiber matrix. For example Here, the fiber matrix can be formed by combing. The fiber is usually at least about 42 millimeters in length. The fiber matrix here is formed by air-laid or wet-laid process, and the fiber length is ideally about 0.2 to 6 millimeters. According to the present invention, the garden has a length greater than 50 mm fiber, it has been determined that when actually having a number of fibers longer than pen meters placed in the punchable fabric, even if the fiber will be dispersed in the water and cut away, its length may be sufficient to form a fiber "bundle" (ropes) ), This is not ideal for flushing in a domestic toilet. Therefore, for these products, it is desirable that the fiber length be about 15 mm or less, so when flushing through the toilet, the fiber does not "(Rope). Although various fibers of different lengths are suitable for use in the present invention, it is desirable that these fibers have a length of less than about 15 mm, so when rain contacts, these fibers easily disperse each other. These fibers can also be crimped, especially synthetic Fibers. The fabric of the present invention may be formed of a single layer or multiple layers. In a multilayer state, the layers are generally arranged side by side or in a face-to-face relationship, and the entire layer or part may be connected to an adjacent layer. The non-woven fabric of the present invention can also be made from most separated non-woven fabrics, — — — — — — — I «^-I! (Please read the notes on the back before filling this page) nn-

AWIND (MS {Proliles \ UserWesktop \ PK ~ 001 ~ 0734.Doc December24, 2001 1237030 A7 B7 36. V. Description of the invention (where the separated nonwoven fabric can be formed from a single layer or multiple layers. The nonwoven fabric includes multiple layers In the embodiment, the entire thickness of the nonwoven fabric can be added to the adhesive use, or each individual layer can be added to the adhesive use separately, and then combined with other layers in a side-by-side relationship to form a completed nonwoven fabric. For example, the fabric substrate of the present invention may be incorporated into purification and body fluid absorbent articles, such as sanitary napkins, diapers, adult incontinence products, surgical bandages, tissue paper, wipes, etc. These articles may include an absorbent core, the absorbent core Contains one or more layers of absorbent fiber material. This absorbent core may also include one or more layers of fluid permeable members, such as fiber tissue, tissue, plastic mesh, etc. It is generally useful as a wrapping material to hold the core components in place Together. In addition, the core may contain fluid-impermeable members or barriers to prevent fluid from passing through the core and the outer surface of the article. Ideally, the barriers are also water-resistant Dispersion. Films with substantially the same composition as the water-dispersible adhesives described above are particularly well-suited for this purpose. According to the present invention, the polymer composition is beneficial for the formation of each of the product ingredients mentioned above, which includes an absorbent core layer, a permeable Fluid components, wrapping materials, and fluid-tight or barrier devices. The adhesive formulations of the present invention are particularly beneficial for the bonded fibers of airlaid nonwoven fabrics. These airlaid materials can be used for bodyside liners, fluid distribution materials, and fluid inhalation Materials (such as surge materials), absorbent wraps, and cover stocks for various water-dispersible personal care products. Airlaid materials are especially useful as wet wipes. Basis weight of airlaid nonwovens The range is about 20 to 200 grams per square meter ("gsm"), and its main fibers have a length of about 0-5 to 10 denier and about 6 to 15 mm. Surge or inhalation materials require better elasticity and higher Bulky, so it has 6 denier or larger (please read the notes on the back before filling this page), order-line_ K paper size applies to China Home Standard (CNS) A4 Specification (210 X 297 mm) rniNDOWS ^ mfiles \ UsefN) esktQp \ PK-Q01-Q734.DQC December 24, 2001 1237030 A7 B7 37 V. INTRODUCTION (Fiber is used to make these products. The final ideal density of a thirsty or inhaled material is approximately 0.025 grams per cubic centimeter (g / cc) to 〇10 g / cc. The fluid distribution material may have a higher density, and the ideal range is approximately 0.1 to 0.2 Og / cc, which uses lower denier fibers, and more desirable fibers have about less than 5 denier. Wet wipes can generally have a fiber density of about 0.025 g / cc to 0_2 g / cc, and a basis weight of about 20 to 150 gsm; specifically about 3 () to 90 gSm, more specifically It is about 60 to 65 gsm. The nonwoven fabric of the present invention can also be incorporated into this body fluid absorbent article, such as sanitary napkins, diapers, surgical bandages, tissue paper, and the like. In one embodiment, the 'adhesive will not decompose when it encounters body fluid, because the concentration of monovalent ions in the body fluid exceeds the degree of decomposition required', that is, greater than 0.3 wt% and / or greater than 1%. Nonwoven fabrics have their own structure, softness, and hardness suitable for practical use. In any case, when contacted with water having a concentration of polyvalent ions (such as + and Mg ^ ions) rising to 200 ppm, for example, a binder containing a sulfonated anion-changing acrylic terpolymer is dispersed. Similarly, when contacted with water having a concentration of polyvalent ions (e.g., Ca &gt; Mg2 + ions) less than PPm, a binder containing a trimeric acid trimer is dispersed. The nonwoven structure is then easily broken and dispersed in water. In one embodiment of the present invention, the tensile strength of the non-woven fabric is improved by forming a non-woven fabric having a binder material containing the ion-sensitive polymer formulation of the present invention, and thereafter using-or more unit price and / Or more · Valence salts to nonwovens. This salt can be applied to nonwoven fabrics by methods generally known in the art, and the amount of salt can vary depending on the particular application. To put it in perspective, the amount of salt applied to the fabric is about 0 ″ ^ ~ ΐ〇W⑽ block :,. ^ I I (please read the note on the back? Matters before filling out this page) J ^ T ·. Line · &lt; 4 -Q / indo \ WS \ Pmfiles \ UserAD (^ sktopmoi ^ Doc December 24 2 A7 1237030 V. Description of the invention (3 This depends on the total weight of the fabric. The salty fabric of the present invention can be used for various purposes. (But not limited to) female padding, surgical bandages and diapers. Those skilled in the art will readily understand that the fibrous matrix adhesive formulation of the present invention can be beneficially applied to a wide variety of product preparations, including (but not limited to) designs designed to interact with body fluids Contacted absorbent personal care products. Such articles may only contain single-layer fibers, fluorene, or may include a combination of the components described above. Although the adhesive formulation and fiber matrix of the present invention are particularly suitable for personal care products, bonding Agent formulations and fiber matrices can be beneficially applied to a wide variety of consumer products. The combination of a propionate dimer or a sulfonated anion-varying acrylic terpolymer with a non-crosslinked poly (acetamidine-vinyl acetate) improves the results. Trimers are used alone. For example, when the ion-sensitive polymer formulation of the present invention is used in the adhesive composition of wet wipes, the wet wipes have improved wettability for the first soiling without losing the speed of the wiper sheet at normal speed. It is easily wetted by the wipe solution. The ion-sensitive polymer of the present invention can also reduce the stiffness of the dry sheet, improve the exudation ability during further product conversion and different brittle sheets, reduce the stickiness and / or of the wipe Improve the spraying ability of the ion-sensing adhesive to improve the distribution and penetration of the adhesive in the substrate. Among other different adhesive systems known in the art, the ion-sensing polymer formulation of the present invention can promote the adhesive without the need for high temperature. Reaction. Although drying or water removal is necessary to complete a good distribution of the binder in the fiber fabric at high temperatures, because the binder does not need to cross-link or other chemical reactions with high activation energy to act as a binder. Conversely, Interaction with a soluble activating compound (usually a salt) sufficiently causes the adhesive to become active (insoluble) or "salted out". So, if ideal, can prevent the drying step, or at low temperature--Ί — — — — — — — — — — — ^ i — (Please read the precautions on the back before filling this page) Order II ί , This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm 4wh C \ WIND〇WS \ Pmfibs \ Use (Wesktop \ PK-001-0734.Doc December 24, 2001 1237030) V. Description of the invention (39 (Water removal, such as room-temperature drying or freeze-drying. High temperatures are generally helpful for drying, but drying can be done at a temperature below the generally required cross-linking reaction. Therefore, the substrate is exposed to the highest temperature or below any of the following temperatures: temperature: 180. c, i600e C, C, 120. C, 110. c, 100. c, 90. c, 75. c and c, the maximum maximum fabric temperature range is about 50. c ~ 11〇. C, or about 70. C 1 40 C. Of course, higher temperatures can be used, but this is not necessary in most embodiments. Polymer systems (e.g., industrial emulsions) that incorporate co-binders may also contain polymers that are suitable at 160 ° C. C or a cross-linking agent that reacts at a higher temperature, and maintaining a lower maximum temperature can be beneficial to prevent excessive development in the common adhesive polymer of water-dispersible wipes with different adhesives. Wet wipe composition and its wet wipes A particularly interesting embodiment of the present invention is the manufacture of the wet wipes from the above-mentioned composition of ionic adhesive and fibrous materials. For wiping, the fibrous material can be in the form of woven or non-woven fabrics; however, non-woven fabrics are preferred. Nonwoven fabrics are ideally formed from shorter fibers, such as wood pulp fibers. The minimum fiber length depends on the method chosen to form the nonwoven fabric. Here, the nonwoven fabric is formed by a wet or dry method, and the fiber length is desirably 0.1 mm to 15 mm. Ideally, the nonwoven fabric of the present invention has a low wet adhesion strength when not bonded together with a bonding agent or an adhesive material. When such non-woven fabrics are bonded together with an adhesive composition (this loses the bonding strength in tap water and sewer water), the fabric will be washed and stirred to quickly disintegrate and move to the sewer pipe. Ideally, the finished wipes can be used in a folded state, a moisture-proof envelope, or any paper size applicable to the Chinese country ii (CNS) A4m210 X 297

-Line · (Please read the notes on the back before filling this page) Φ 丨 Install. CMMWOWS \ Pmff / es \ User / \ D &gt; esktop \ PK-001-0734.Doc December 24, 2001 1237030 A7 B7 Description of the invention (49 why many ideal sheets are fixed individually in a water-resistant package with a wet composition for wipes. When many sheets are ideally fixed on a roller (having a wet composition applied to wipes) in a moisture-proof container The detachable sheet roller can also be packaged with finished wipes. The roller can be coreless and either hollow or solid. The coreless core, including the central center or the central center, can be made with a known coreless roll winder ' Including SRP Industries, Inc. (San Jose, California), Shimizu

Manufacturing (Japan) and the device disclosed by Gietman in U.S. Patent No. 4,667,890, issued May 26, 1987. For a given volume T, solid wound coreless rolls produce more products and are suitable for a wide range of dispensers. Regarding the weight of the dry fabric, the wipe may ideally include a wet composition of about 丨 0% to 400%, a more ideal wet composition of about 500,000 to 300%, and even more preferably about 180. % ~ 240% wet composition. Wipes maintain ideal characteristics throughout storage, shipping, retail display, and storage by consumers. Therefore, the shelf life is two months to two years. Covers and storage devices in various impervious forms containing wet packaging materials such as wipes and hand towels are known in the art. Any of these can be used in the wipes package of the present invention. Ideally, the wet wipes of the present invention are wetted with a water-containing wet place, which has one or more of the following characteristics: (1) consistent with the composition of the ion-sensitive adhesive described above in the present invention; (2) during conversion, storage and During the processing (including dispensing), the wipes can maintain its own wet strength and dispersibility in the toilet; (3) Does not cause skin inflammation; i Paper size 剌 China (21Q x 297 public love) (please first Read the notes on the back and fill in this page again) Binding-• Thread. CMINDOWS ^ Proiiles \ ilserf [Desktop \ PKO01 ~ 0734.Doc December 24, 2001 A7 1237030 ______B7__ 5. Description of the invention (4 $ (4) Reduce the glue of the wipes Tackiness and provide tactile properties such as smooth skin and a "lotion-like feel"; and (5) act as a vehicle to deliver slightly wet cleansing and other skin health benefits. A moisturizing fragrance and Depending on the salt concentration, the wet composition is not a solvent that acts as a binder, and generally does not involve solvents other than water, especially organic solvents, although a small amount (&lt; 1%) of aroma solubilizers (such as polysorbate 20). Ideally, based on the total weight of the wet composition, the wet composition contains less than 10 wt% of organic solvents, such as propylene glycol or other ethylene glycol, polyalcohol, etc. More desirably, the wet composition contains About less than 4 wt% of organic solvents. Even more desirably, the wet composition contains less than about 1 wt% of organic solvents. The wet composition may be substantially free of organic solvents. One aspect of the present invention is a wet composition containing an activated compound. The compound maintains the strength of the water-dispersible adhesive until the activated compound is diluted with water, and then the strength of the water-dispersible adhesive begins to decline. The water-dispersible adhesive can be any of the ion-sensitive adhesive compositions of the present invention. Activation in a wet composition The compound can be a salt, such as sodium gaseous or any other compound, which provides a binder composition that is in use and storage strength to water dispersible, and can be diluted in water to allow the binder polymer to cause a weak state when the matrix Dispersion. Ideally, based on the total weight of the wet composition, the wet composition contains about less than 1Q% of the active compound. In other words, the wet composition may contain about 0.3 to 5 wt% of the activated compound. Even more specifically, the wet composition may contain about 2 to 4 wt% of the activated compound. I · ------- ----- Install—— (Please read the precautions on the back before filling in this page) Order-Wood paper size is applicable to China National Standard (CNS) A4 (210 X 297 public love) 0 \ λ4 ^ 〇〇 \ m \ Pmfiles \ USeiADesktop \ Pimim4.Doc Decent 24 2001 1237030 A7 B7 V. Description of the invention ((Please read the phonetic notes on the back before filling out this page) The wet composition of the present invention can further include various active compounds and water-dispersible Consistent additions of adhesives make the strength and dispersibility of the wipes not at risk. Appropriate additives in the wet composition include (but are not limited to) the following types of additives: skin care additives, odor control agents, detackifiers that reduce the adhesion of adhesives, particulate matter, antibacterial agents, antiseptics Agents, wetting agents and dust storage agents (such as detergents, surfactants and some silicones), softeners, surface touch modifiers that improve the feel on the skin (such as lubricating properties), aromas, aroma dissolving agents, sunscreens, Fluorescent brighteners, UV absorbers, drugs and pH control agents (such as malic acid or caustic potassium). Skin Care Additives As used herein, the term "skin-care additives" refers to additives that provide one or more benefits to the consumer, such as diaper reduction. Hair treatments and / or other skin caused by fecal enzymes The possibility of damage. These enzymes (especially trypsin, chymotrytin and elastin enzymes) are proteolytic enzymes' which are passed through the gastrointestinal tract to digest food. For example, in infants, diarrhea tends to be watery and contains bacteria and other non-degrading amounts of digestive enzymes in other materials. At any noticeable period, these enzymes, if left in contact with the skin, have been found to cause an uncomfortable inflammation and can make the skin prone to microbial infection. As a countermeasure, skin care additives include (but are not limited to) enzyme inhibitors and chelating agents that have been published since. Based on the total weight of the wet composition, the wet composition may contain less than about 5 wt% of skin care additives. More specifically, the 'wet composition may contain about 0.01 to 2 wt% of skin care products. Even more specifically, the wet composition can contain about 0.001 wt% ~ 〇 G5 wt. This paper size applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) j at 1237030

5. Description of the invention (4% of skin care additives. 0 kinds of skin care additives can be added to the moisturizing composition and wipes of the present invention. In one embodiment of the present invention, the skin care additives in the form of particles are added to As a stool enzyme inhibitor, this provides benefits that reduce the possibility of diaper hair treatment and skin damage caused by stool enzymes. U.S. Patent No. 6,05 issued April 18, 2000 by Schulz et al. No. 1,749, which is incorporated herein by reference in its entirety for reference to 'this organophilic clay disclosed in woven or non-woven fabrics' which is beneficial for inhibiting fecal enzymes. Such materials used in the present invention include clays having one or more of the following Long-chain organic tetraammonium compound products: kaolinite, bentonite, beidellite, hectorite, soapstone, stevensite. Other known enzyme inhibitors and chelating agents can be used as skin care additives in the moisturizing composition of the present invention. Including those Inhibitors of trypsin and other digestive enzymes and urea-marinated inhibitors. For example, enzyme inhibitors and antibacterial agents can be used to prevent odors It is formed in liquid. For example, the urea pickled inhibitor that can also play the role of odor absorption is Ding Trinh in the world patent please No. 98/26808 "Absorbent Article with odor control system (Absorbent Article with Odor Control System), which was published on June 25, 1998, which is fully incorporated herein by reference. Such inhibitors can be incorporated into the wet composition and wipes of the present invention, and include the transfer of metal ions and their soluble salts , Such as silver, copper, zinc, iron, and aluminum salts. This anion can also provide urea evaporation inhibition, such as borate, phytate, etc. Possible compounds include (but are not limited to) silver gasification, silver nitrate, mercury acetate, gasification Mercury, mercury nitrate, copper metaborate, copper bromate, copper bromide, gasified copper, dichromate steel, copper nitrate, copper salicylate, copper sulfate, zinc acetate, zinc borate, zinc bromate, zinc bromide 、 The size of this paper is applicable to the Chinese National Standard (CNS) A4 specification (2W X 297 mm), • installed --- (Please read the precautions on the back before filling this page) Order · J ·. Line · -ϋ n H ϋ-• Introduction to Doc December 24,200, 1237030 A7 B7 V. Description of the Invention (41 Zinc, Zinc Gasification, Zinc Sulfate, Cadmium Acetate, Cadmium Borate, Cadmium Bromide, Cadmium Gas Acid, Chloride Surface, Formic Acid, Cadmium Iodate, Cadmium Iodide, Cadmium Perrhenate , Cadmium nitrate, tin sulfate, and gold chloride. Other salts that have been reported to have urea-suppressing properties include iron and aluminum salts, especially nitrates and bismuth salts. Other urea-suppressant inhibitors have been disclosed by Trinh, including oxygen 4 acids And its derivatives; sulfur; hydroxylamine; phytate; extracts from various plants (including various tannins, such as rice bean tannin and other derivatives, such as chlorogenic acid derivatives); naturally occurring acids (such as ascorbic acid) , Citric acid and other salts); phenylphosphine diamine / diaminophosphate phenyl vinegar; metal aromatic amino phosphate complex (including substituted amino phosphate compounds); nitrogen-free substituted helium phosphate; boric acid And / or its salts (especially including borax and / or organoboric acid compounds); compounds disclosed in European Patent Application No. 408,199; dithiocarbamates, copper, bells and / or zinc ;.酴; thiurams; substituted rhodanine acetic acid; alkylated benzene; formamidine disulfide; 1,3-dione maleimide; succinimide; benzyl liver; pehenic acid; Ν , N- 二 # 代 -2- 咪 ①alkanone; N_painted 2-oxa①alkanone; thio and / or phosphonophosphonium ammonium and / or its substituted derivative, thionitrile bite- N-oxides, thionitrile, and sulfanyl sulfide; diarninophosphinyl compounds with sulfur oxide by-products; cyclotriphosphazatriene derivatives; n-diaminophosphonium derivatives of bromide; brominated-nitrate compounds; 8-aromatic groups and / Alkyl diaminophosphothiolates; diaminophosphoryl derivatives; mono- and / or polyphosphonium diammonium; 5-substituted-benzoxazinylthiol_2_one; N (diaminophosphoryl) aromatics Ammonium acylate; oxyl-l, 2-benzothaizin compounds, etc. Many other skin care additives can be incorporated into the moisturizing composition and J-pack of the present invention-(Please read the precautions on the back before filling out this page) Order --- Line-Private paper size applies Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) 4 Tm-o: ^ N ^ WS ^ rnms \ UserWes ^ K ^ im4.Doc December 24, 200 ^ A7 1237030 5. Description of the Invention (Wet wipes, including (but not limited to) sun protection Agents and UV absorbers, sores treatment methods, music, carbon dihydrochloride (including capsule shape), vitamins and their derivatives (such as vitamin A or E), plants (such as witch hazel peel analgesic extracts and Aloe vera gel), allantoin, softener, fungicide, alkyd with crease control or anti-aging effect, light shielding, tanning promoter, skin brightener, deodorant and antiperspirant, skin benefits and other used Ceram ides, tinctures, wetting agents, nail polishes, insect repellents, antioxidants, preservatives, anti-inflammatory agents, etc., which provide additives consistent with the composition of ion-sensitive adhesives, especially the ions of the present invention Inductive adhesive composition (that is, the same as before dilution in water Permit can be dispersed in water, does not cause loss of strength of wet wipes). Useful extensive skin care and other benefits is the material listed in 1999

McCutcheon s Book 2: Practical Materials from MC Publishing, Glen Rock, New Jersey. Many useful botanical skin care are provided by Activated Organics, Lewisville, Texas. Odor control additives Appropriate odor control additives used in the wet composition and wipes of the present invention include (but are not limited to) zinc salts; talc; capsule flavors (including small capsules, large capsules, and perfumes filled with micro particles, vessels, or Small emulsions); cheiants (such as ethylene diamine 4-acetic acid); zeolites; activated carbon particles or fibers; activated silica particulate materials; carboxylic acids (such as citric acid); cyclodextrin and cyclodextrin derivatives; Chitin or chitin of acetamidine and its derivatives; oxidants; antibacterial agents (including silver-coated zeolites, such as those sold under the trademark HEALTHSHIELDtm, which is located in BF Technology, Beverly, Mass.); Its mixture. Except this paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm 公 0)

Obi (Please read the precautions on the back before filling this page) Order · --line-'WC ^. \ WINDOWS ^ rofites \ UserWesktop \ PK-001-0734.Doc December 24 2001 1237030

V. Description of the Invention (4 In addition to controlling the odor of the body or body excretion, the odor control method can also be applied to mask or control any odor of the treatment substrate. Ideally, the wet composition contains less than 5 wt. % Odor control additive, which is based on the total weight of the wet composition. More desirably, the wet composition contains about 0.01 Wt% ~ 2 wt% of the odor control additive. Even more desirably, the wet composition Contains about 0.003 wt% to 1 wt% of odor control additives. In one embodiment of the present invention, the wet composition and / or the wipes include a derivatized cyclodextrin, such as hydroxypropyl 5 in solution ten. _Cyclodextrin, which remains on the skin after wiping and provides an odor-absorbing layer. In other embodiments, odor-controlling additives are used to remove or neutralize the odor source, such as cheUnt acts to bind metal bases, This requires many proteases and other enzyme functions that generally produce odors. Combining metal-based compounds prevents enzymes and reduces the risk of odors in products. Deacetylated chitin or chitin derivatives are non-woven. Fabrics and cellulose fibers The application principle is described by S. Lee et al. In "Antimicr〇bial and B100d Repellent Finishes for Cotton and Nonwoven Fabrics Based on Chitosan and Flu〇ro〇lymers), which is a textile exploration hybrid 69 (2), February 1999, pages 104 ~ 112. (Please read the precautions on the back before filling out this page). Equipment • I -I ϋ One ti-order · • Line de-adhesive agent South salt concentration can reduce the viscosity of ion-sensitive adhesives. Other devices with reduced viscosity are often not ideal. Therefore, de-adhesive agents can be used to wet the composition to reduce Adhesive, even if there is an ion-sensitive adhesive. Appropriate de-adhesive This paper size applies to China National Standard (CNS) A4 (210 X 297)> 4 9ivc-ci ^ WINDOWS ^ mfiles \ UserWesktop \ PK-001-0734 .Doc December 24 2 1237030 A7 ^ ___ B7 V. Description of the Invention 1-"Based on Known Techniques" to use adhesive-like polymers or to reduce skin: glue like adhesive-like polymers Sticky feel possible with any substrate treatment to reduce fiber flakes Adhesiveness. Detackifier can be used as solid particles in a dry form, this can be used as a suspension or granular slurry. It can be sprayed, covered, electrostatic = sedimentation, collision, filtration (that is, different pressures drive full particle gas) The phase passes through the matrix and is precipitated by a filtering mechanism), etc., and can be uniformly used on one or more substrate surfaces, or it can be used for a pattern on the surface of the substrate (such as ^ or Rensi, pattern). Detackifiers can be spread across the thickness of the substrate, but can be concentrated on either or both surfaces, and can generally be present on only one or two substrate surfaces. Special detackifiers include (but are not limited to) powder (such as talc, calcium carbonate, mica); starch (such as corn starch); stone pine powder; mineral aggregates (such as titanium dioxide); silica powder; alumina; general metal oxidation Materials; baking powder; diatomaceous earth; Polymers and other additives with low surface energy can also be used, including a wide range of fluorinated polymers, dream additives, polyfluorene and thermoplastics, bad, well known in the paper industry. A chain compound, such as having 16 or more carbons. The use of compounds as release agents for casting and making candlesticks, as well as dry lubricants and fluorinated release agents can also be considered. In one embodiment, the detackifier comprises poly4-fluorinated acetamidine (ptfE), Bigemouth PTFE telomer (KRYTOX® DF; H dagger compound, which is used as a PTFE release agent drying lubricant MS-122DF It is sold by Miller-Stephenson (Danbury, Connecticut) as a spray product. For example, pTFE particles can be sprayed onto one side of the substrate before the wipes are rolled. In one embodiment, the Before being wound into a roll, the de-adhesive is applied to only one surface of the substrate. The ideal wet composition contains less than 25 wt% de-adhesive. This applies to the Chinese National Standard (CNS) A4 specifications for each wet paper size. (210 X 297 mm) (Please read the precautions on the back before filling out this page}-Installation: Order · • Line · '^ NDOWS \ Profiles \ User1 \ Desktop \ PK-001-0734.Doc December 24,2001 ! 237〇3〇Α7 5. Description of the invention (The total weight of the / 闰 composition is based. More desirably, the wet composition contains about 〇〇 丨 ~ i 〇wt% of the detackifier, more specifically about 5% Or less. Even more specifically, the wet composition contains about 0.05 to 2 wt% of a tackifier. In addition to acting as a tackifier, starchy It can also improve the strength characteristics of wet wipes. For example, it has been found that 'non-gelatinous starch particles (such as hydrophilic tapioca starch) can be tolerated at a wet composition weight of about 1 wt% or higher. At lower salt concentrations than without starch, the wipes maintain the same strength. So, for example, compared to 4% salt without starch, the given strength can reach 2% salt of the wet composition. Starch Can be used to add starch to laponhe suspensions to improve starch dispersion in the wet composition.

I Microparticulate matter Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs • (Please read the precautions on the back before filling this page) The wet composition of the present invention can be further changed by adding solid particulate matter or particulate matter. Suitable particulate materials include, but are not limited to, mica, silica, alumina, calcium carbonate, kaolin, talc, and zeolite. If desired, the particulate matter may be treated with stearic acid or other additives to increase the attraction or connection of the particulate matter to the adhesive system. In addition, a two-component particulate material system that is generally used as a help in the paper industry can also be used. This two-component particulate matter system typically contains a colloidal particulate state (such as silica particles) and a cationic polymer that dissolves water to form the particles that connect the fabric fibers. The particulate matter in the wet composition can serve as one or more useful functions, such as (1) increasing the opacity of the wipes; (2) changing the rheology or reducing the adhesion of the wipes; (3) improving the wipes' Tactile properties; or (4) the ideal agent is delivered to the skin via a particulate substance transporter (such as a porous transmitter or microcapsule). Ideally, the paper size is in accordance with China National Standard (CNS) A4 (21〇X 297 public love) g | O CWC-C \ WINDOW ^ Pr〇aies \ Usermesktop \ PK-001-0734.Doc December 24 2001 1237030 Ministry of Economic Affairs Printed by the Intellectual Property Bureau employee consumer cooperative A7 B7 V. Description of the invention (The wet composition contains less than 25 wt% of particulate matter, which is based on the total weight of the wet composition. More specifically, the wet composition contains About 0.05 to 10% of particulate matter, and even more specifically, the wet composition contains about $ wt% of particulate matter. Microcapsules and other delivery vehicles Microcapsules and other delivery vehicles can also be used in the present invention Invented moisturizing composition 'to provide skin care agents; contrabands; comfort enhancers (such as tree oil); fragrances; skin care agents; odor control additives; vitamins, powders; and other additives to the user's skin. More specific The wet composition may contain about 0.05 wt% to 10 wt% of microcapsules or other delivery vehicles. Even more specifically, the wet composition may contain about 0.2 wt% to 50 wt% of microcapsules or other Delivery media Mediators. Microcapsules and other delivery vehicles are a well-known technique. For example, POLY-PORE⑧E200 (Chemical Co., Ltd., Arlington Heights, Ill.) Is a delivery agent that contains soft, hollow spheres that contain more than Additives that deliver 10 times the weight of the vehicle. Known additives using POLγ_poRE⑧E200 include (but are not limited to) benzene peroxide, salicylic acid, rosin oil, retinyl hexadecanoate, octylmethoxycinnamate, Vitamin E, silicone compound 435) and mineral oil. Other useful delivery vehicles are sponge-like materials, which are sold by POLY-PORE⑧L200. This green is silicone (Dc 435) and mineral oil. Other delivery vehicle systems, including cyclodextrin and its derivatives, a crypto-polymer sponge, and spray-dried starch. Addition of microcapsules from other agents in the environment and wet composition I ^ ----------------- (Please read the note on the back? Matters before filling out this page) · /

cmNDOWSiProfHes \ User ^ Desktop \ PK-001.〇734.Doc December 24. 2001 1237030 A7 B7 V. Description of the invention (sp he = on the skin 'and then the microcapsules are broken and passed to the skin or its preservatives and antibacterial agents 2. The wet composition of the present invention may also contain preservatives and / or antibacterial agents. Number = preservatives and / or antibacterial agents (such as 仏 also ⑻Η 6, obtained from the 6th episode of the egg 卵 in Chicago, Illinois) have been found to prevent Bacteria and casting growth give excellent results. Other suitable preservatives and antibacterials include (but are not limited to) DMDM betaine (eg, G] yant piusTM, a New Jersey shirt company, L0), Iodopropynyl carbamate, Kathon (Rohn ^ 、 —, —,] bromo_2_nitropropane difluorene, benzoic acid, etc. in Philadelphia, Pennsylvania. Ideally, the wet composition contains about Less than 2 wt% of preservatives and / or antibacterials, based on the total weight of the wet composition. More specifically, the wet composition contains about 0.001 preservatives and / or antibacterials. Even more specifically, , Wet composition contains about 0.001 wt% ~ 0.5 wt% Preservatives and / or antibacterials. Wetting agents and detergents Various types of wetting / eliminating agents and / or detergents printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy can be used in the wetting composition of the present invention. Appropriate wetting agents and / or Detergents include (but are not limited to) detergents and nonionic, amphoteric, and anionic surfactants, especially acidic surfactants. Amino acid surfactant systems (such as derived from amino acids, L-aminoglutaric acid, and other natural fatty acids ） Provide pH compatibility with human skin and good cleansing powder 'It is also safer when compared with anionic surfactants, and provides paper size modified to apply Chinese National Standard (CNS) A4 specification (210 X 297 mm) υ Λ &quot; 〇 ^ -〇 ^ NDOWS \ Profile $ \ UserWesktop \ PK-001-0734.DocDecember24 2001 1237030 Printed by the Consumer Cooperative of the Intellectual Property Bureau, Ministry of Economic Affairs, A7. 5. Description of the invention (Good tactile and moisture characteristics. The function is to improve the wetting of a dry substrate with a thirsty composition. When the wipes contact the pimple area, the other function of the surfactant is a dispersible bath Stain and enhance the absorption of the substrate. Surfactants can further help to remove, general personal cleaning, difficult surface cleaning, odor control, etc. Examples of industrial amino acid surfactants are fluorenylamino Glutamate is sold by Amisoft of Ajinomoto Co., Ltd., Tokyo. Ideally, the wet composition contains less than 3 wt% of a wetting agent and / or a cleaning agent, depending on the total weight of the wet composition. More desirably, the wetting composition contains about 0.01 wt% to 2 wt% of a wetting agent and / or a cleaning agent. An even more desirable 疋 'wetting composition contains about 0.1 wt% to 0.5 wt% of a wetting agent and / or a cleaning agent. / Although amino acid surfactants are particularly used in the wet composition of the present invention, a wide variety of surfactants can be used in the present invention. Suitable nonionic surfactants include, but are not limited to, concentrated products of ethylene oxide and hydrophobic (lipophilic) polyoxyethylene, which are formed by the concentration of propylene oxide and propylene glycol. The hydrophobic portion of these compounds desirably has a sufficiently high molecular weight so as to become water-insoluble. All in all, adding half of the polyoxyethylene to this hydrophobic part increases the water solubility of the molecule, and the liquid properties of the product are kept up to the total weight of the concentrated product with a polyoxyethylene content of about 50%. Examples of compounds of this type include commercially available pluronic surfactants (BASF Wyandotte Co., Ltd.), especially polyoxypropylene ethers having a molecular weight of about 1500 to 3,000, and polyoxyethylammonium content of about 35 to 55. The molecular weight in%, that is, 1 &gt; 11 ^ 〇1 ^ 1_62. Other useful non-ionic surfactants include (but are not limited to) per mole

# · 装 ----- 丨 ^ —if --------- C Please read the legal notice on the back and fill in this tribute), V The paper size applies to China National Standard (CNS) A4 (21 × 297 mm, 54 ° C: \ WIND0WS \ Pmfiles \ UserADesktop \ PK-001 ~ 0734.DOC December 24 2001 1237030 A7 B7 V. Description of the invention Concentrated products of kb alkyl alcohol. Examples of compounds of this type include concentrated products of Cn ~ Ci5 second alkyl alcohols with 3 to 50 moles of ethylene oxide per mole of alcohol, which are industrially derived from 〇Ηη chemical The product's POY-Tergent SLF series or the TERGITOLL series from UniOn, namely TERGITOLL 25 l-7, is formed of about 7 moles of ethylene oxide with a Cu-Cb chain alcohol. Others used in the wet composition of the present invention Non-ionic surfactants include ethylene oxide esters of C6 ~ c12 alkyl phenols, such as (nonphenoxy) polyoxyethylene ethers. Particularly useful are ethylene oxides with a reduction of about 8 to 12 moles. Prepared esters, namely IGEPAL® C0 series (GAF Co., Ltd.)-Furthermore, non-ionic surfactants include (but are not limited to) Polyglycoside (APG) 'which is a concentrated product derived from glucose (D_glucose) and linear or branched chain alcohols. The glycoside portion of the surfactant provides confidentiality, which improves the solubility of water-soluble H-glycosides. _The inherent stability of the connection provides chemical stability in the test system. Furthermore, some different non-ionic surfactants, alkyl polyglycosides do not have cloud points. This allows it to become anhydrous and very mild And non-ionic surfactants that are rapidly microbially decomposable. Such surfactants are obtained from Horizon Chemicals under the trade names ApG 300, ApG 3500, and APG-500. Silicone is another wetting agent that can be used In purebred form or microemulsion, macroemulsion, etc. An example of a group of nonionic surfactants is a silicone ^ ethylene glycol copolymer. These surfactants are made by adding a poly (lower) alkoxy chain to two Free Hydroxyl Preparation of Methylxoxeol, which is obtained from Dow Corning Co., Ltd., is Dow Corning 190 and 193 surfactant (CTFA name: This paper size applies to Chinese National Standard (CNS) A4 Specification 7_2i 〇x 297 public release-'C-CMINDOWS \ Pm files \ lJserfiDesktop \ PK-001-0734.DOC December 24, 2001 1237030

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (dimethiccme cop〇ly〇1). These surfactants, with or without the use of any volatile lithosterone as a solvent, function to control foam generated by other surfactants and also add gloss to the surfaces of metals, ceramics and glass. Anionic surfactants can also be used in the wetting composition of the present invention. Because of the high detergency 'anionic surfactant is beneficial to include anionic degreasing salt having 8 to 22 carbon atoms, such as higher water-soluble fatty acid alkaline metals such as sodium myristate and sodium palmitate. A better type of anionic surfactant contains water-soluble sulfurized and sulfonated anionic alkali metal and alkaline soil metal washing salt, which contains a more hydrophobic half alkyl group (usually contains about 8 to 22 carbon atoms) For example, the salts of higher mono- or polynuclear aromatic hydroxysulfonates having about 1 to 16 carbon atoms in the alkyl group can be exemplified by the Bio-Soft series, namely Bi-Soft D-40 (Stepan Chemistry the company). Other useful types of anionic surfactants include, but are not limited to, alkali metal salts of alkyl camphorsulfonic acid (sodium methyl camphorsulfonate, petr0 AA, Petrochemical Co., Ltd.); sulfurized higher fatty acid monoglycerides, such as cocoa butter Sodium salts of sulfurized monoglycerides of fatty acids and potassium salts of sulfurized monoglycerides of tallow fatty acids; alkali salts of sulfurized fatty alcohols containing about 10 to 18 carbon atoms (such as sodium lauryl sulfate and sodium stearate) ); CM-C16-a-ene _ sodium sulfonic acid, such as Bio-Terge series (Stepan Chemical Company); alkali metal salts of sulfurized ethylene oxide fatty alcohols (about 3 moles with ethylene oxidation of C12-C15 n-alkanol) Sodium or ammonium sulfate of concentrated products of products such as Neodol ethoxysulfates (Shell Chemical Company); alkali metal salts of higher fatty esters of low molecular weight alcohol sulfonic acids, such as fatty acid esters of sodium isosulfuric acid; Fatty acid ammonium, such as ammonium laurate, and many other anionic organic surfactants,

丨 丨 --- Order ---------- ^ 1 ^ &quot;. (Please read the notes on the back before filling this page)

Call for MB I This paper size applies the Chinese national standard (CNSM4 specification ⑽297 issued) 5 "___ 论 卿 __. 崎 _ 1237030 A7 ______B7 _ V. Description of the invention (such as one * month benzoic acid steel, selective brain acid Sodium, toulene sodium dibasic acid extreme mixture. |, Further useful anionic surfactant types include 8- (4-n-alkyl-2-cyclohexyl) -octanoic acid, in which the cyclohexyl ring is substituted with an additional carboxylic acid group. Some Chemical compounds or potassium salts are commercially available from Westvaco Co., Ltd. as Diacid 1550 or H-240. These anionic surfactants can be used to test metal salts, ammonium, or magnesium salts.

Alkali soil metal salts. S Italian Silicone particles of macroemulsions and microemulsions The wet composition may further comprise silicone particles of an aqueous microemulsion. For example, U.S. Patent No. 6,037,407, "Preparation Process for Silicone Oil and / or Gum and / or Resin of Aqueous Emulsions" (Prcess for the

Preparation of Aqueous Emulsions of Silicone Oils and / or Gums and / or Resins), which was promulgated in March 2000, discloses that organopolysiloxanes are contained in aqueous emulsions. Desirably, the wet composition contains less than 5 wt% of the silicone particles of the microemulsion, depending on the total weight of the wet composition. More desirably, the wet composition contains about 0.02 wt% to 3 wt% of the silicone particles of the microemulsion. Even more desirably, the wet composition contains about 0.22 wt% to 0.5 wt% of the silicone particles of the microemulsion. In general, the lithone emulsion can be applied to wet wipes using known covering methods. For example, wet wipes can be wetted with an aqueous composition containing a water-dispersible, water-miscible, silicone component. This silicone The ingredients are consistent with the active compounds in the wet composition. Furthermore, the wipe may comprise a fibrous nonwoven fabric with a water-dispersible adhesive, wherein the fabric is comprised of a silicone thiosuccinate. Silicone stone provides butylated phthalide salt with good and effective washing without the need of 活化 grade surfactants. Paper size is compliant with China Standards (CNS) A4 specification (x 297 ~ Please fill in this page for details) Γ 装 • nnn — ， — Order, --------- # C ^ WINDOWS \ Profiles \ UserM) esktop \ PK-001-0734.Doc December 24, 2001 1237030 Printed by A7, B7, Employee Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs 5. Description of the invention (5? Net force. In addition, stone ketone thiosuccinate provides a dissolving function, which prevents the precipitation of oil-soluble components, such as flavor components, vitamin extracts, plant extracts and refined oils. In According to an embodiment of the present invention, the 'wet composition contains co-polyol thiosuccinate, such as dimethicone polyol thiosuccinate and diammonium dimethicone polyol thiosuccinate. Ideally, The wet composition contains about less than 2 wt% of the silicone thiosuccinate, and about greater than 0.05 wt% to 0.30 wt% of the cetyl thiosuccinate. In the silicone emulsion containing In other examples of products, the wet composition may also have Dow Corning 9506 powder. Dow Cornitfg 9506 powder contains dimethicone / vinyl dimethicone cross-linked polymer, and is a spherical powder, which is used to control skin oil (see "New Chemical Perspectives" fat pen and cosmetics, volume 76, number 3, page 12, vids (March 2000) c; Therefore, water-dispersible wipes that effectively control skin oils and fats are also within the scope of the present invention. The principle for preparing syringone emulsion is described in WO 97/10100, which was published in 1997 3 May 20. Softener The wet composition of the present invention may also contain one or more softeners. Suitable softeners include (but are not limited to) PEG 75 refined lanolin fat, methyl gluceth 20 phenyl potassium fe salt, Cu- C〗 5 Benzylbenzene potassium salt, ethoxylated cetyl stearyl alcohol (products sold as WS-L, Lambent WD-F, Cetiol HE (Henkel Co., Ltd.)), Glucam P20 ( AmerchoI), P〇iyox WSR Nl〇 (Union Carbide) ^ Polyox · -install --------- order --------- ^ wi (Please read the precautions on the back before filling in this Page) &lt; This paper size applies to China National Standard (CNS) A4 (210 x 297 mm S〇3-c : MIND (MS \ Pmfiles \ UserfiDesktop \ PK ~ 001-0734.Doc December 24,2001 1237030 A7

Order 1237030 A7 ----- B7 — ____ 5. Description of the invention (Combination of dimethicone and other alkyl-substituted polysiloxane polymers. In some embodiments of the present invention, a liquid hydrocarbon softener and / or Alkyl-substituted polysiloxane polymers can be blended with one or more fatty acid gg softeners derived from fatty acids or fatty alcohols. Also consider HE (Henkel Co., Hoboken, NJ) of PE (3.7 glycerol Water-soluble self-emulsifying and softening oils for wet composition include polyoxyalkoxylated refined lanolin and polyoxyalkoxylated fatty alcohols. This oil is described by Smith et al. In US Patent No. 4,690,821, which issued On September 1, 1987, the polyoxyalkoxy chain will ideally contain a mixture of propoxy and ethaneoxy. The refined lanolin derivative will generally contain about 20 to 70 lower alkoxy groups, while Fatty acids will be derivatized with about 8-15 lower alkyl groups. A useful refined lanolin derivative is Lanexol AWS (PPG-12_PEG_50 from Croda Corporation of New York). A useful poly (15_2〇) (VCV alkoxylated to PPG- 5-Ceteth-20, already Known as procetyl AWS (CrOda Co., Ltd.

Division) P According to an embodiment of the present invention, even with a wet composition, the softener material reduces bad tactile characteristics. For example, a softener material that includes dimethicone can reduce the stickiness caused by ion-sensitive adhesives or other ingredients in the wetting composition. Desirably, the wet composition contains less than about 25 wt% of a softener, depending on the total weight of the wet composition. More specifically, the wet composition may contain less than about 5 wt% of a softener, and more specifically, less than about 2 wt% of a softener. More desirably, the wet composition may contain about 0.01 to 8 wt% of a softener. Even more ideally, the wet composition may contain about 0.2 wt% ~ 2 wt of this paper rule ^ Applicable to China National Standard (CNS) A4 specifications (21 × x 297 mm ^ cw〇-C.mND〇WS \ Pmfiles \ Usermesktop \ PK-001-0734.Doc December 24, 2001 ------------ Pan-install i — (Please read the notes on the back before filling this page) Order .. Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperatives 1237030 V. Description of the invention (5 dream% softener. ----------- ^ --- (Please read the note on the back? Matters before filling out this page ) In one embodiment, the wet composition and / or wipes of the present invention comprise an oil-water emulsion of an oil phase, the oil phase contains at least one softening oil and at least one softening female foot agent, and the stabilizer is dispersed in an aqueous solution. Phase, which contains at least one polyhydric alcohol softener and at least one organic water-soluble detergent, which was disclosed by Smith et al. In U.S. Patent No. 4,559 1 57, which was issued on January 17, i985, and is fully incorporated This is for reference. Surface Touch Improver Surface Touch Improver printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs is used to improve the surface touch Tactile daring during the use of this product, such as lubricity. Suitable surface touch modifiers include (but are not limited to) industrial detackifiers and softeners, such as softeners used in tissue manufacturing techniques, including fatty acid side groups, Tetravalent ammonium compounds of silicones, waxes, etc. Exemplary tetravalent ammonium compounds used as softeners were disclosed by Hervey et al. In US Patent No. 3,554,862, issued January 12, 1971; Emanuelsson et al. U.S. Patent No. 4,144,122, issued March 13, 1979; U.S. Patent No. 5,573,637, Ampulski et al., Issued November 12, 1996; and U.S. Patent No. Hellsten, et al. No. 4,476,323, which was issued on October 9, 1984, which is fully incorporated herein by reference. Ideally, the wet composition contains less than 2 wt% of a surface touch modifier, which is based on the total weight of the wet composition It is more desirable that the wet composition contains about 0.01 wt% to 1 wt% of the surface touch improver. Even more desirably, the wet composition contains about 0.01 wt% to 0.05 wt% of the surface Sensitivity improver. This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm 61! CWOC: \ WINDOWS \ Protiles \ UserADesktop \ PK-001-〇734.Doc December 24, 2001 1237030 A7 B7 V. DESCRIPTION OF THE INVENTION (Aroma) Various aromas can be used in the moisturizing composition of the present invention. Desirably, the wet composition contains less than about 2% by weight of aroma, depending on the total weight of the wet composition. More desirably, the wet composition contains about 0.1 to 1 wt% of the aroma. Even more desirably, the wet composition contains about 0.011 wt% to 0.05 wt% of the aroma. Aroma Dissolving Agent Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Furthermore, various aroma dissolving agents can be used in the moisturizing composition of the present invention. Suitable aroma solubilizers include, but are not limited to, polysorbate 20, propylene glycol, ethanol, isopropanol, diethylene glycol monoethyl ether, dipropylene glycol, dipropylene glycol Enzyme ethyl acetate, ethyl citrate, Ameroxol 〇E-2 (Amerchol Co., Ltd.), Brij 78 and Brij 98 (ICI surfactant), Arias〇ive 200 (ICI surfactant), Calfax 16L -35 () Pilot Chemical Company, Capmul POE-S (Abitec Co., Ltd.), Finsolv SUBSTANTIAL (Finetex), etc. Desirably, the wet composition contains less than about 2 wt% of the aroma solubilizer, depending on the total weight of the wet composition. More desirably, the wet composition contains about 0.01 wt% to 1 wt% of an aroma dissolving agent. Even more desirably, the wet composition contains about 0.01 wt% to 0.05 wt% of an aroma dissolving agent. Suitable, including but not limited to titanium dioxide or other minerals or pigments, and synthetic sunscreens, such as REACTOPAQUE® particles (obtained from South Carolina's A-sheet scale applicable to Chinese National Standard (CNS) A4 specifications (210 X 297 Public Love WC-CAWINDOWS ^ rofiles \ UserM) esktqi ^ K-001-0734.Doc December 24 2001 — — — — — — — I --- (Please read the precautions on the back before filling this page) 1237030 A7 V. Description of the invention (Sequa Chemical Co., Ltd., Chester, LA). Ideally, the wet composition contains less than 2 wt% of the sunscreen, which is determined by the longitudinal weight of the wet composition. More ideally, The wetting composition contains about 0.001% of the sunscreen. Even more desirably, the wetting composition contains about 0.001% to 0% by weight of the opacifier. The pH control agent is used at an appropriate pH of the wetting composition of the present invention. Control agents include, but are not limited to, malic acid, citric acid, hydrochloric acid, acetic acid, sodium hydroxide, caustic potassium, etc. A suitable pH range is to minimize skin inflammation caused by moist composition on the skin. Ideally, , The pH range of the wet composition is about 35 to 65. More desirably, the pH range of the wet composition is about 4 to 6. Ideally, the wet composition contains about less than 2 wt% of a pH adjuster, which is based on the wet composition The total weight is sufficient. It is more desirable that the 'wet composition contains about 0.001 Wt% ~ 1 wt% of the pH adjuster. Even more desirably, the wet composition contains about 0.001 to 0.0 5 wt% of pH adjustment Although various wet compositions formed from one or more of the ingredients described above can be used in the wipes of the present invention, in one embodiment, the wet composition contains the following ingredients, and the weight percentages of the wet compositions given are as shown in Table 2 below Note: ----------- ^ --- (Please read the notes on the back before filling out this page) Order ·· Printed by the consumer intellectual property agency of the Ministry of Economic Affairs, Intellectual Property Co., Ltd. Wet composition weight percentage deionization Water about 86 to 98 Active compounds about 1 to 6 Preservatives up to about 2 ^ Paper size applies Chinese National Standard (CNS) A4 specifications (21〇X 297 public love) ό 3ivc ·, -C: \ WINDOWS] Pmfiles \ Usei1 \ Desktop \ PK ~ 001-0734.Doc December24, 2001 1237030

V. Description of the invention (6J Surfactant ------ about 1 to 2 silicone emulsion-&gt; ----- ^ about 1 to 1 softener ~~~~~~-about to 1 fragrance-- ------ about up to 0_3 solubilizing agent about up to 0.05 pH adjuster --- about up to (K2 In another embodiment of the present invention, the wet composition contains the following ingredients to the weight of the wet composition The percentage is expressed as shown in Table 3 below: ----------- click-install (please read the note on the back? Matters before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 3 Wet Composition Types of Wet Composition: Specific Wet Composition; Ingredient Name: Weight Percent: Vehicle Deionized Water-about 8 6 $ 〇〇 Active Compound Gasification Sodium (Millport, Milwaukee, Wisconsin Ent.) Approx. 1 to 6 Preservatives Glycerin, IPBC, and DMDM Hyaluronic acid Mackstat H-66 (McIntyre Group, Chicago, Illinois) Approx. 2 Surfactant Argonyl glutaric acid CS22 (Said Tokyo Aj inomoto) --- ~ -——-- up to 2 paper sizes applicable to China National Standard (CNS) A4 regulations Grid (210 X 297 mm & 4 CWC-aWNDOWS \ Pmfiles \ iJserADesktop \ PK-001-0734.DOC December 24, 2001 Printed by the Consumer Consumption Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1237030 A7 _B7 V. Description of the invention (6? Silicon Ketone Emulsion (Tack Remover / Skin Tactile) Dimethiconol and TEA Dodecyl Sulfonate DC 1785 (Dow Corning, Mid Michigan) Up to 1 Softener PEG-75 Lanolin Solulan L-575 (Mid Jersey Amerchol, Sexx) Approx. 1 Aroma Aroma Dragoco 0/708768 (Dragoco, Rhodesville, Minnesota) Approx. 0.3 Aroma Solvent Polysorbate 20 Glennsurf L20 (Glenn Inc., Paul Street, Minnesota) Approx. To 0.5 pH adjuster malic acid to pH 5 (Haarman &amp; Reimer of Tetrboro, New Jersey) about as high as 0.2 In another embodiment of the present invention, the wet composition contains the following ingredients, expressed as a weight percentage of the wet composition, as shown in Table 4 below Shown: Table 4 Demonstration of wet composition-pack ------.- tr --------- # (Please read the precautions on the back before filling this page), _ This paper size applies to China National standard CNS) A4 specification (210 X 297 public% £ CWC-C. \ WINDOWS ^ rofiles \ UserM) esktop \ PK-001-0734.Doc December 24, 2001 1237030 A7 B7 V. Description of the Invention (Types of Wet Composition: Specific Wet composition of ingredients; Ingredient name: Weight percent: Vehicle deionized water about 93 Active compound sodium vaporized about 4 Preservatives glycerin, IPBC and DMDM Hydrazone Mackstat H-66 about 1 Surfactant aminoglutaric acid CS22 / ECS 22P About 1 Silicone emulsion Dimethiconol and TEA dodecylsulfonated benzene DC 1784 / DC 1785 About 0.5 Softener PEG-75 Lanolin Solulan L-575 About 0.25 Aroma Aroma Dragoco Aroma 0/708768 About 0.05 Aroma Soluble Polysorbate 20 Glennsurf L20 about 0.25 pH adjuster malic acid to pH5 about 0.07 (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs It should be noted that the moist composition described above in the present invention uses the above description Any one of the ion-sensitive adhesives of the present invention. Furthermore, the wetting composition described above in the present invention can be made using any other adhesive composition, including conventional adhesive compositions or any known fibrous or dispersible absorbent matrix. Characteristic strength This paper size applies to China National Standard (CNS) A4 (210 X 297 mm I WC-CmNDOWS ^ rofiles \ UserM) esktop \ PK-001-0734.Doc December 24, 2001 1237030 A7 ------ -V. Description of the invention (except for the detailed description, the tension test is performed according to the following method. The drying test is performed in accordance with the seventh paragraph ASTM_!! 1 7_8M head order -------- --- Pan-fitting --- (Please read the precautions on the back before filling out this page) Under α (50% relative calendar, 73〇ρ) hypothesis. Strong man ~ subscriber m &amp; 3 reasons. Tension $ 测 以 -Determining the link speed tension tester (such as a D-h _ ^ 256_100 tension tester with a load of 21 kilograms). Cut the sample into 3 inches and 6 inches' and install The length is 4 inches between the jaws. The speed of this coupling is ^ 12 inches per blade. Measure the highest load (tensile strength) and the extension at the highest load, (tensile). For the cross direction (CD For the tensile test of). Cut the sample in the cross direction. For the tensile test of mechanical direction _), cut the sample in the cross. Before the wet composition is applied, the tension test of the fabric in the dry state is recorded. The dry tensile strength in the mechanical direction is abbreviated as "Mdd Ding", and the dry tensile strength in the cross direction is reduced to "⑽". The result can be recorded as kilograms, inches, or grams / foot or grams / 2.54 cm. Once the sample is cut into the appropriate size based on the dry weight of the sample, the remaining wet composition amount (with 4% test solution without other additives, unless different details are included) is applied to a solution that increases by 250 to 400%. The wet sample was then immediately printed by a consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

Wnnge took advantage of the Atlas Electrical Equipment Company of Chicago, No. 0404 LW-1 ‘Where to load’, to distribute the sample uniformly and gradually move the remaining solution to reach a final solution that increased to 200%. Depending on the sample, individual repetitions or approvals may be required to achieve additional goals. The wipe tissue samples were then all packed in plastic bags' to prevent drying before the test. The cross direction wet tension test (CDWT) or mechanical direction wet tensile strength (MDWT) is described after being placed in a sealed plastic bag and equilibrated overnight. The above paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 Gong Wu Gong 7 '· \\ MND〇WS \ Profiles \ UseiWesktop \ PK-0〇1-〇734.Doc December 24 2001 1237030 A7 B7

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Use of wet samples. For Test Two I regarding the loss of strength after the wipes were exposed to the new solution, it had a size of 200 mm x 120 mm and was large enough to hold a pen and a pinch of picking solution. Seven books of no more than 1G8 square inches are immersed in 700 liters of immersion solution. This depends on the sample size. ^ The wipes samples that have been balanced overnight are immersed in the immersion solution, and then allowed to dip calmly. For! Hours). During the soaking period, the sample was carefully removed from the ditch solution, allowed to flow out 'and then tested as described above (i.e., the sample was immediately installed with a tensile tester and tested, which did not require a twisting machine). In the case of an ancient dispersible material, the sample is often unable to be retrieved from the non-disintegrating immersion solution =. The immersion tension of the sample was recorded as green to zero, which corresponds to the solution. For the deionized immersion cross-direction wet tension test and s_Cdwt, when this sample is immersed in U ion water H, the money test 1 for hard water immersion and cross-directional wet tension test 'S_CDWT-M (M represents divalent metal ion) The samples were immersed in water containing 200 ppm of Ca 2 / Mg + 2 μ Ca 2+ / Mg ++ prepared from vaporized calcium and magnesium vapor for an hour and then tested. For the medium-hard water immersion birch cross-directional wet tension test, Ms_CDWT_M, the sample was immersed in water containing ㈣ 2: 1 ratio of Ca ++ / Mg ++ for 1 hour and then tested. The test was completed by adding or immersing the solution in one additional time, which means that the test was prevented with 8-tin, S-CDWT-M. In an embodiment of the present invention, the wet wipes are manufactured using the wet composition described in Table 3 above. An airlaid fiber material contains about 80% bleached cowhide fibers and 20 wt% of any of the present invention described above-the ion-sensing composition: The weight percentage is based on the total weight of the dry nonwoven fabric. In this post

This paper size applies to China National Standard (CNS) A4 (2

• — II ----- ^ ----- (Please read the notes on the back before filling out this page) IIII ·; Pretend play · ⑽ · D〇c〇 &lt; Member 24, 2001 1237030 A7 B7 V. Description of the invention (66) I 丨 丨 — I installed i I (please read the precautions on the back before filling this page) In a further embodiment, the wipes are manufactured using the wet composition described in Table 3 above, an air-laid web The fibrous material comprises about 90 wt% of softwood fibers and 10 wt% of an ion-sensitive adhesive containing an acrylic terpolymer or a copolymer substantially free of acrylic monomers, wherein the weight percentage is based on the total weight of the dry nonwoven fabric . The amount of wet composition added to the non-woven fabric in proportion to the weight of the dry non-woven fabric in these examples is desirably about 180 to 2400% by weight. After having an Ca2 ++ and / or Mg2 ++ ion concentration of about 50 ppm for 1 hour (MS-CDWT-M), the wipes of the present invention have a wet tensile strength (CD WT) of at least 100 g / inch in use, And a tensile strength of less than about 30 grams per inch. More desirably, the wipes have a wet resistance of at least 300 g / inch (CDWT) in use after being immersed in a Ca2 ++ and / or Mg2 + ion concentration of about 50 ppm for 1 hour (MS-CDWT-M). Tensile strength, and tensile strength of less than about 30 grams per inch. In a further embodiment, after being immersed in a Ca2 + and / or Mg2 + ion concentration of about 200 ppm for 1 hour (MS-CDWT-M), the wipes have a wetness of at least 200 grams per inch (CDWT) during use. Tensile strength, and a tensile strength of less than about 20 grams per inch. Even more desirably, after soaking in a Ca2 + and / or Mg2 + ion concentration of about 200 ppm for 1 hour (MS-CDWT-M), the wipes have a wet resistance using at least 300 grams per inch (CDWT) Tensile strength, and tensile strength of less than about 20 grams per inch. Desirably, the wipes treated with the adhesive material of the present invention include an acrylic terpolymer having at least 100 grams per inch in the cross-machine direction when soaked in a 10 Wt% to 400 wt% wet wipe solution. Inch wet tensile strength of 1 inch This paper is sized for China National Standard (CNS) A4 (21 × 297 mm) 62 fC-CmiNDOWS \ Pmfiles \ UserADesktop \ PK-001-0734.Doc December 24, 2001 1237030 A7 B7 V. Description of the invention (6f -pack --- (please read the precautions on the back before filling this page) width sample, this wipe solution contains more than 0.3 Wt% unit ions (NaC1) after soaking in deionized water for 1 hour ) And a tensile strength of less than about 30 g / in pairs. More desirably, a wet wipe treated with the adhesive material of the present invention includes an acrylic terpolymer having a name of 10 to 400. When the wt% wipes solution is soaked, use an i-inch width sample with a wet tensile strength of at least 200 g / inch in the cross-machine direction. This wipe solution contains more than 0.3 wt% unit after soaking in deionized water for 1 hour. Samarium ion (Naa) concentration and tensile strength less than about 30 g / inch Printed by a Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs in a further embodiment, the wipes treated with the adhesive material of the present invention include a sulfonated anion-modified acrylic terpolymer, which has a range of 10% to 400% by weight. When wet wipe solution is immersed, use a wet tensile strength of at least 200 g / inch across the mechanical direction! Inch width sample, this wet wipe solution has about 50 ppm of Ca2 + and / or Mgh ion. Deionized water! After hours, it contains a monovalent ion (NaCi) concentration of greater than 1 wt% and a tensile strength of less than about 30 grams per square inch. Even more desirably, the wipes treated with the adhesive material of the present invention include sulfonate Anion-modified acrylic terpolymer having a wet tensile strength of 200 inches per inch when soaked in a wet wipe solution of 10 to 400 wt%! Width sample, this wet tissue solution, after soaking in deionized water with Ca 200 + and / or Mg2 + ions for about 200 ppm} hours, contains a concentration of monovalent ion (NaC1) greater than 1 wt% and less than about 3 (g / inch) Tensile strength. Articles with a basis weight or wet strength may have higher wet tensile strength. For example, articles such as wet hand towels or hard surface cleaning towels may have a basis weight greater than 70 gsm, such as 80 gsm to 150 gsrn. This The paper size is applicable to China National Standard (CNS) A4 (2i0 x 297 mm297Λ /ClWc.W/NDOWS\Profites\UserftDes«op\PK-001*0734.Doc December 24, 2001 1237030 Ministry of Economic Affairs Intellectual Property Printed by the Bureau's Consumer Cooperative: i \ WINDOWS ^ rOfiles \ UserM &gt; esktop \ PK-001-0734.Doc December 24, 2001 A7 V. Description of the invention (6 wheat products can have 500 grams. Φ, brothers inch or Larger CDWT 値, about 150 m3 / 芷 4 times smaller S-CDWT # see / central inch, Φ m 値, more specifically about 100g / inch or #f and more specifically about 50 charge / 芷 $, Ding-Fei is smaller, maybe Fan Yuan. Κ 付 or less' has dispersibility similar to s-CDWT- ^ Before trying to measure the dispersibility of this pre-wet fabric from σ β τ _ 疋, stirrers; two t Shearing systems, for example, measure the time for a mechanical stirrer to disintegrate. In order to design the article to be continuously exposed in the toilet to shear to provide impractical and overly optimistic tests, the degree of shear becomes weaker and very simple here. -Once the product passes through the narrow part of the toilet, the shear rate can be ignored. Furthermore, when flushing the toilet, the product is not: Wang: The water in the toilet is wet, to be more precise, when using a flushed spectator, there is not enough time for the wet composition of the product to be replaced by the water in the toilet. Therefore, previous dispersibility measurements have suggested dispersible products when there is virtually no suitable system for corruption. For practical estimates of dispersibility, it is believed that relatively static measurements need to better simulate low shear, and this actual product will experience once it becomes completely wet with toilet water. As a result, dispersibility testing methods have been developed that do not rely on shear and provide improved ways to evaluate products suitable for a corrupt system. In this method, the tensile strength of the guest product is measured in the initial wet state (as described by the CDWT measurement above) and after the product is immersed in the first bath for 1 hour (either S_CDWT or s_cdWT_m test). The second solution was either "Deioonized Dispersibility" (deioonized dispersibility), or "hard water. This paper is sized to the Chinese National Standard (CNS) A4 (210 X 297 g)) y / Clfc-c: ^ i · ^ --------- Order · --------- «_ (Please read the precautions on the back before filling out this page) ·, 1237030 A7 Staff Consumption of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the cooperative V. Description of the invention (6? Hard Water DisDersih.i., P blllty) 値 Hard water (according to -CDWT-M test) 〇 Anyway, can be divided into Ke * Hugh, San 14 The meaning is (1-Trans-Universal Wet Tensile Strength Ratio in the Second Solution + Initial Trans-Universal Wet Tensile Strength) X 100 ^ Therefore, if the wipes lose MCD after 1 hour in hard water impregnated; .. Tensile strength, hard water dispersibility is depressing tenderness: heart. The object of the present invention can have a large ionic dispersibility of 80% or more, and more specifically 90% or more, more specific It is 95% or larger, and may have an ion dispersibility of about 100%. The article of the present invention may have a hardness of Tj /, 70% or more. The dispersibility is more specifically 80% or more, more specifically 90% or more, and may have a deionization dispersibility of about 100%. A method of manufacturing a wet wipe of the present invention Wet wipes can be made in several ways. In one embodiment, the ion-sensing polymer composition is used in the fiber matrix as a partial aqueous solution or suspension I 'where subsequent drying is required to remove water' and promote fiber adhesion. Especially during drying During this time, the adhesive moves to the U point of the fiber and becomes an adhesive that activates this area ', thus providing acceptable strength to the matrix. For example, the following steps can be used: 1. For an absorption matrix without high adhesion, That is, non-stick airlaid, thin fabrics, comb fiber webs, woolen pulp, etc. 2. Apply the ion-sensing polymer composition to the substrate, usually liquid, suspension or foam. 3. Co-bond The polymer is applied to the substrate. 4. Dry the substrate to promote the adhesion of the substrate. This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) IIIIII ^-IIIIJII · 11111 --- (Please Read the notes on the back and fill out this page). * On _〇_ 聪 〇She_Please) 1237030 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy Exceeding ⑽.C or 120.C, 110.c and 140 ^ 100 C. In one embodiment, the matrix degree does not exceed 80. c or 60. C. Dish 5. Apply the wet composition to the substrate. 6. Place the wet substrate in a roll or stack and pack the product. The use of the co-adhesive t compound can be performed simultaneously with the use of the adhesive composition. This can be done by mixing the two in advance, or the co-adhesive polymer can be added before or after the adhesive is used. Ideally, the other steps are pointed out in order above. The use of the ion-sensitive polymer composition for the substrate can be sprayed, foamed, immersed in a bathtub, curtain coating, coated with a steel wire wound rod, and the substrate is contacted with a wet roll pre-metered with an adhesive solution through a immersion clamp Compress the substrate on a deformable transporter containing an ion-sensitive polymer, such as a sponge or felt that facilitates transfer to the substrate, printing (such as gravure, inkjet or rubber roll printing), and any other well-known device. In the application of foam to an adhesive or co-adhesive polymer, this mixture is typically foamed with a foaming agent and uniformly spread on the substrate, and then used for foam-filled passage through the substrate. Any well-known foam application method can be used, including U.S. Patent No. 4,018,647, "The Saturation Process of Wet Fiber Fabrics with Thermal Foam Latex Adhesives" (Prcess⑹the Impregnation of a Wet Fiber Web with a Heat Sensitized Foamed Latex Binder) , Which was promulgated by Wietsma on April 19, 1977, which is fully incorporated herein by reference. Wietsma has disclosed a method in which foamed latex is a thermally induced foamed latex with a heat sensitive agent (such as a practical silicone compound including a silicone oxyalkane block copolymer and an organopolysiloxane). Suitable-(Please read the notes on the back before filling this page) Γ The size of this paper is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 703〇: .W / WDOlVS \ Proff / es \ l; serftOesWop \ PK-OOi-0734.Doc December 24, 2001 1237030 A7 V. Description of the invention (Specific examples of heat sensitive agents and the use of latex heat sensing are described in US Patent Nos. 3,255,140, 3,255,141 No. 3,483 No. 240 and No. 3,484,394, which are combined and subtracted as a reference. Compared with the previous method of using latex adhesives, the use of heat sensitive agents results in products that are very soft and feel like fabrics. The amount of heat sensitive agents added It is determined according to the type of latex used, the expected solidification temperature, the mechanical speed, and the temperature of the mechanical drying zone, and the general range is about 0.05 wt% to 3 wt%, which is calculated as the dry weight of the latex; however, a larger amount of latex can also be used. Or a smaller amount. The heat-sensing agent added to the latex will solidify far below the water point, for example, at a temperature of 35 ° C to 95 ° C, or about 35.c to 65 ° C. Nexus theory, believed in binders After the solution is applied and before the wet composition is applied, the drying step improves the adhesion of the fiber matrix by driving the adhesive to the fiber intersections, removing water, and thus promoting the efficient use of the adhesive. However, in another method, skip the above The drying steps are listed and the ion-sensitive polymer composition is applied to the substrate as a wet composition without significant intermediate drying. In the interpretation of this method, the ion-sensitive polymer composition can be selectively attached to the fiber 'this allows too much The water is removed in any extrusion step, and this step does not significantly lose the binder of the matrix. In the other explanation, no significant amount of water removal occurs before the wet composition is applied. 纟 In other methods, the same method is used to use ion induction polymerization. Composition and wet composition, and then arbitrarily add salts or other active compounds to promote or further advance the reaction of the adhesive. The present invention is further-further illustrated by the following example, which does not use any addition of 297 mm) tr This paper scales Zhongguanxian (CNS) A4 regulations ^^ &gt; CmNDOWS ^ rofiles \ UserWesktop \ PK-0〇m34.Do c December 24, 2001 1237030 A7 V. Explanation of the invention (73 Restricted scope to explain. On the contrary, after reading this description, it became clear that various other embodiments, variations and equivalents can be used to make a mastery of itself This technique does not exceed the spirit of the invention and / or additional patent application scope. As used herein, the term "thickness" is intended to be measured with a 3-inch acrylic plastic disc, which is connected to Mitut 〇y〇 ring and mail, pressure indicator (Shiba 5-chomme 31 ~ 19 of Tokyo, Japan (108) Minat〇-kii, Mitutoyo Co., Ltd.), and transmitted to the net load of 0.05 psi ^ Instead measure. When the plate is placed on a horizontal surface, Mitut〇y〇 = the pressure indicator is reset to zero. When a sample of at least the same size as an acrylic disk is placed in the disk, the thickness reading can be read from the number of the pressure indicator. The invention = The water-dispersible substrate may have any suitable thickness, such as about 0.01 mm to 5 mm. For wet wipes, the thickness ranges from 0.2 mm to 1 mm, more specifically = about 0.3 mm to 0.7 mm. For example, a compaction roller can be used to control the thickness during or after fabric formation, compaction after an adhesive or wet composition has been used, or control of the winding tension when a roller is formed. The platen method was used to measure the average thickness to the naked eye. Local thickness can be varied, especially if the article has surfaced or has a three-dimensional texture. Example 1 Preparation of sulfonated anion-modified acrylic trimer acrylic acid (43.3 g, 0.60 mole), AMPS (107 g, 0.0052 mole), butyl acrylate (35.2 g, 0.27 mole) And 2-ethylhexyl acrylate (20 g, 0.11 mole) was dissolved in 55 g of an acetone / water (70/30) mixture. This paper size applies to China National Standard (CNS) A4 specifications_ (21〇X 297 male f CWC ~ C.WIND〇mP_es \ UserWesktop \ PK-0〇1-〇734.Doc December 24, 2 1237030 A7 ----- -— __B7______ 5. Explanation of the invention (pressure indicator, 2,2-nitrogen-containing diisobutyl neck (AIBN) (0 51 g, 3 ″ χ 1 · 0.3 mol) dissolved in 20 moles of acetone. The monomer solution was reduced by foaming through the solution for 20 minutes. A 1000-millimeter round-bottom flask was fitted with a condenser, two additional funnels, and a magnetic stirrer, and 120 grams of acetone / water (70/3) was added. The mixture is heated to a steady countercurrent under nitrogen. The monomer and initiator are added simultaneously from the additional funnel for more than 2 hours. The polymerization is carried out for 2 hours. Finally, the distillation head and mechanical stirring rod are used to replace the additional funnel and condenser. Remove propane. During the distillation, maintain a steady flow of nitrogen while gradually increasing the temperature from about 65 ° C to 90 ° c. When the distillation is complete, add 400 grams of deionized water to reduce the viscosity of the polymer solution. A misty but identical solution was obtained. All were synthesized using the procedure described above Seven polymers (samples 丨 ~ 9). NaOH (2.1 g, 0.052 mol) was added to 20 liters of water at room temperature to neutralize the AMPS components of the sample. Table 5 below illustrates examples 1 ~ Composition of 9. All percentages are expressed in mole percentages. (Please read the note W on the back before filling out this page)

Table 5. Samples of sulfonated anion-modified acrylic terpolymers% AMPS ^ NaAMPS% AA% BA% EHA 1 0.0 3.0 64.0 22.5 10.5 2 0.0 3.5 63.5 22.5 10.5 3 0.0 3.9 62.1 24.6 9.4 4 0.0 4.0 57.0 26.5 12.5 5 0.0 4.2 64.7 19.7 11.4 6 0.0 5.0 58.0 26.5 10.5 7 0.0 4.0 63.0 21.5 11.5 8 0.0 5.0 59.0 25.5 10.5 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) 1237030 A7 B7

T 10 0.0 75.0

Example 4 Solubility of Ion-Sensitive Polymer Formulations Measure the solubility of the polymer formula of Example 3 to divalent cations stored in hard water. Samples 1-10 of Example 3 existed in some CaCh solutions with Ca2 + concentrations (ranging from less than 10 to 200 ppm). With soaking for i hours, note the solubility of each polymer. The solubility results are shown in Table 7 below. Table 7 (Please read the note on the back -161m: fill in this page first) Solubility results printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy Sample solubility in Ca2 + &lt; 10 ppm 50 ppm 100 ppm 2 0 〇pp it »Sample 1 100 94 78 12 Sample 2 100 100 98 91 Sample 3 100 60 36 ------- 2 Sample 4 99 100 97 90 Sample 5 100 97 88 19 Sample 6 100 100 99 90 Sample 7 89 42 31 0 Sample 8 100 96 96 90 Sample 9 100 73 1 ----- 78 7 Sample 10 100 100 100 90 In each case, the film was cast from a film containing a mixture of NaAMPS-Ill —mi &gt; 1 · ιιι— ·-this paper size Applicable to China's National Standards (CNS) A4 specifications (21 0X 2 97 publicly referred to as DOl ^ S \ P side sWse⑽ please f_.Doc December 24, fine 1237030 Employees' Cooperatives of Intellectual Property Bureau of the Ministry of Economic Affairs printed A7 ----- -_____ B7 V. Invention!-Can be dissolved in films containing acrylic acid terpolymers, especially when the calcium ion concentration increases. 0 Example 5 Test the adhesive strength of polymer formulations with and without cross-linking. For the performance adjustment test, we use a pulp-based airlaid substrate % Bico fibers are bonded together. Bico fibers are either Type-255 (KoSa fibers from Salisbury, North Carolina) with a reactive polyethylene covering and a polyester core or a polyethylene core with a polypropylene covering and a polypropylene core. Danaklon fiber (FiberVisions from Varde, Denmark). The two bico fibers are 2-3 denier and cut into 6 mm lengths. The adhesive formulation can be used to spray 12-15 wt% solution adhesive formulation onto the substrate above. Two sides. Under various conditions, due to bico fibers, the strength of the green substrate is recorded after deducting the basic strength of the fabric. Table 8 is proposed in 0.4 wt% NaCl (CDWT) and immersed in ionized water (SCDWT). After hours, the strength of the substrate with different formulations.

Table 8. Tensile strength samples% trimer% EVA EVA cross-linked or not BW (gsm) Binder (%) added Oven temperature (° C) CDWT (g / inch) S-CDWT (g / inch ) 1 85 15 70 22 400 413 112 2 65 35 Yes 70 22 400 467 375 3 85 15 Yes 71 23 400 444 116 4 85 15 Yes 76 28 400 518 143 This paper size applies to China) ------ Ding, 〇 / CWC-C: \ WINDOWS [Profiles \ UserWesktop \ PK-001-0734.DocDecember24, 2001

1237030 --- rr- A7 B7, description of the invention () Γ τ · ~ —__ / 5 85 ——π 15 No 70 22 400 430 21 6 85 Yes 73 25 350 336 60 7 65 35 Yes '' 7 18 350 332 237 8 65 35-&quot; ------- _ yes 69 21 350 268 165 9 85 15 yes 68 20 350 219 '' one------- 35 10 65 35 yes 67 19 350 199 74 11 85 15 no 69 21 350 226 20 12 65 35 No 67 19 350 196 29 BW: Basis weight CDWT · Wet tensile strength across machine direction

S-CDWT: All numbers on cdwT after 1 hour immersion in ionized water are best and contained in the first stain! The binder formulation of the 0.00% propionic acid dimer was dried in a proportional manner. In addition, adhesive formulations containing EVA are better sprayed than 100% acrylic terpolymers, resulting in substantial improvements in adhesive distribution and penetration into the substrate. Significantly, those formulations are not parentable &apos; i.e. samples 5, 11 and 12 have S-CDWTs less than 30 g / inch. Example 6 An adhesive formulation having the composition shown in Table 9 below was prepared. A 12 wt% solids adhesive formulation was sprayed on both sides of the airlaid fabric. Airlaid fabrics are based on pulp (CF 4 05 from Weyerhaeuser). Table 9 shows the strength of the substrate after 1 hour in 0.9% NaCl solution (CDWT) and immersion in deionized water (s_CDWT). It also shows the effect of strength after 16 weeks of aging of the samples in saline. Add a preservative (such as Mackstat H66) to the sample to prevent

Ψ ® Si (~ CNS (^^ X ^^^^ C-hw) NDOWS ^ mfiles \ UserM) es ^ K-001-0734.DocDecember24, 2001 1237030 A7-: --η ---- V. Description of the invention ( ) Shape and grow on the substrate when the salt solution matures.

(Please read the note on the back to fill in this page first) &lt; 7 Results Table 9 shows that even when Dur_〇_SetRB is used as eva, it is fully cured after using salt solution, the fabric has not lost its initial characteristics. Assuming crosslinkables are stored in EVA, there are lower dispersibility results after aging these samples for several weeks. Example 7 In the first figure, the strength characteristics of the modified terpolymer of NaAMPS are shown, which can also be dispersed in hard water (up to 200 ppm Ca ++ / Mg ++ solution). Substrates based on 75 wt% NaAMPS modified acrylic terpolymer (SSB) and 25 wt% EVA (Dur-0-Set® RB) show very high performance during use (in 15% or 4.0% NaCl solution) Good strength and dispersed in hard water. SSB-4 was dispersed in hard water within 10 minutes. ssB-5 dispersed within 3 hours

This paper size applies to Chinese National Standards (CNS) M specifications (210, 乂 297 / ^^ Arm surface · Read Se 敝 Chat Gu. DocD_ber2U Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Consumption Cooperative 1237030 Α7 Β7 V. Description of the invention () Hard water. NaAMPS-SSB is more viscous than Uon_SSB. The tension results of Examples 5 to 7 can be obtained from MTs tension test equipment. MTS 500 / S devices (MTS system, MTS system of North Carolina Park) use Windows software. TestworksTM31〇. Instead of a general 3-inch strip test, using a 丨 inch wide strip, cut into 6 inches long. The length of the gap between the jaw of the test equipment wrapped rubber is 3 inches The test is operated at a detailed link speed of 12 inches / minute. The MTS equipment with modified test procedures generally gives results that can be described in advance with a 3 inch wide sample and a Thwing-Albert tester. Comparing. Example 8 Compared with the shear of a single ionic polymer, adding a co-adhesive polymer to the ion-sensitive polymer reduces the shear viscosity of the polymer. According to the present invention, Table 10 illustrates various differences. The effect of adding the same adhesive polymer to the acrylic terpolymer (SSB-2) (Please read the note on the back before filling this page) Order Table 10 · Effect of adding different common adhesive polymers to the SSB-2 Polymer blend viscosity printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs @ 100 seconds 18 wt% SSB-2 Solid too high Measurement: &gt; 1 〇〇〇〇〇〇cps 15 wt% Sodium polyacrylate solid 10,000 cps 12 wt% Pure SbBB-2 80 cps 12 wt% 80 wt% SSB-2 and 20 25 cps wt% Rhoplex NW 1715K mixture 12 wt% 80 wt% SSB-2 and 20 28 cps wt% China National Standard (CNS) Person 4 Specification (1237030 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs --- r0- V. Invention Description () A7 B7 12 wt% 80 wt% SSB-2 and 20 20 cps wt% Dur-O-Set RB Mixture Table 10 shows that the addition of Rhoplex® NW 1715K, Rovene® 4817 and Dui * -0-Set⑧RB significantly reduced the shear viscosity of a single SSB-2 acrylic terpolymer. The decrease in viscosity was not due to only SSB-2 dilution, as the addition of sodium polyacrylate results in a significant reduction SSB-2 shear viscosity. Example 9 Prepare dry solid rods with Rhoplex® NW 1715K, Rovene® 4817, and Dur_0_Set® RB. These rods are cast into a rectangular silicone mold 1 cm wide, 4 cm long, and 3 mm deep by injecting polymer into rectangular silicone. Then the polymer in the mold was 60. C is heated all night. The dry polymer in the mold was then placed in a container with 30 cm of deionized water at about 23 ° C and allowed to stand for 1 hour. None of the rods were dispersed in deionized water. The acrylic acid terpolymer (NaAMPS + SSB) was then changed from the silicone anion and mixed with Rhoplex® NW 1715K, Rovene® 4817, and Dur-0-Set® RB to prepare rod samples. The polymer blend can be made from 75 wt% sulfonated anion-modified acrylic terpolymer and 25 wt% co-binder polymer. The stick samples were prepared in the same way as described above. The stick sample was then added to deionized water. Samples for each rod were made from a mixture of polymers; NaAMPS + SSB / Rhoplex Nw 1715K, NaAMPS + SSB / Rovene 4817, and NaAMPS + SSB / Dur-O-Set RB, which were dispersed in deionized water within 1 hour. (Please read the notes on the back to fill in this page first) 11 The size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (21 0X 297 male and female) ^ Pre-release sto CanesWop \ PK-i) Gi &quot; 0734_DocDecemi) erH 2001 1237030 A7 B7-: -8i --- 5. Description of the invention () Example 10 In the industry, a 66.5-inch wide air-laid machine is used to prepare an air-laid, fabric-like substrate. The Dan Web airlaid model with two forming stations was used to make a substrate with a basis weight of about 60 gsm. The softwood kraft fibers were bleached using Weyerhaeuser CF405 in a pulp sheet and fibrillated in a hammer mill, and then a creamy web was formed at a speed of 2000 to 300 feet per minute on a moving wire. The re-formed fabric is compacted with a heat-compacting roller and transferred to the first wire, where the fabric is sprayed with water powder. It is estimated that 5% moisture is added to the second heat-compacting roller to further compact the fabric. . The fabric was then transferred to an oven wire and sprinkled on the side with the ion-sensitive polymer formulation mixture on the exposed surface of the fabric, using 10% of the ion-sensitive polymer formulation solids related to the amount of dry fibers in the fabric. The ion-sensing polymer formulation mixture contains water (when there is 2% binder solids), where the binder contains 75% SSB_4 (as an ion-sensing polymer formulation) and 25% RhopeX® NW_1715K emulsion emulsion (R0hm and Haas Co., Ltd.) (as a co-binder polymer). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economics. Sprayed using a set of Quick Veejet (R) nozzles, numbered γ〇77, manufactured by Spraying Systems, Wheaton, Illinois, and operated at 95psi. The spray boom is spread across the fabric, with the nozzle at the center of 55 inches, and the distance between the tip and the metal thread is 8 inches. This arrangement caused a 100% overlap in the spray cone of the test ion-sensitive polymer formulation solution. After spraying the fabric, it enters and flows through about 225. C. The air is used to dry the binder solution. Then the fabric is transferred to the inside of another oven wire, which passes through another spray boom. Here are more ion-sensitive polymer formula solutions used in this paper. Appropriate Chinese standard U1 〇 乂 __s \ p_sU; s ^ Bsktop \ PK-001-Q734.Doc December 24,2001 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1237030 V. Description of the invention (bottom side of the fabric to be added) Λ Two continuous cleaners The dry fiber amount of the fabric is filled with solid fabric. Then the air-drying air dryer of the weaving machine passes through the dryer at about 22rc. The pressure difference from the first to the second is about 〖0 忖 忖 water. It is divided into n pieces to dry. The device area is about 91 () and 6 sighs. -2: Thickness base =: other / quality characteristics record =: = mechanical ... ===, 8.98〆 VD tensile measurement of the fabric's cross-direction dry resistance Tensile strength (MDDT). Then, the dried and treated fabric is trimmed to a width of 60 inches, wound and then torn into a 4-centimeter-wide reel, and then treated with a wet composition to form a fabric suitable for use as a wet towel Coreless reel. 4 inches when the fabric is wound to a suitable size Inch-wide fabric sprays this wet composition on the side-on-law. / ,,,,,,, and becomes 4M% NaC1 in deionized water. 4 wt% measured at 0.76 kg / 3 inches Wet tension across the salt water (CDWT). The anti-foaming CDWT strength is effectively 0, as immersion [ο stretch 'means that the flakes can be completely dispersed. Example 11 Same as Example 10 except for the fibers in the airlaid fabric. The flakes in the form are 75% cork leather and 25% PEEΓ fiber. The thickness of the fabric after drying is 1.35 mm. The mechanical tensile dry (mddt) strength is measured at 3 87 kg. 11.31% at 2.84 kg / 3 inches The CD stretch measures the cross-section dry tensile (CDDT) strength of the fabric. The cross-directional wet tension (CDWT) of 4 wt% saline is measured at 0 · 82 kg / 3 inches. The soaked CDWT strength has a tensile dimension Applicable to China National Standard (CNS) (21〇2974: 1 ^ S_dows㈣MtoAOe surface 2000)

1237030 7 Β -------------------- 5. Description of the invention () The effect is 0, and it is stretched as immersed CD. Example 12 (Please read the note on the back before filling this page) According to Example 10, in addition to the Rovene emulsion used as a co-binder polymer, additional examples are cited, and the fiber composition changes are shown in Table 1 丨. # The CDWT results of the foam are all 0, where the pulp / PET indicates the ratio of cork to synthetic fiber in the matrix, BW is the basis weight (gsm), TH is the thickness (mm), and S-CDWT-M is the sample immersed in containing 200 ppm 2: 1 ratio of Ca ++ / Mg ++ in water for 1 hour in CD wet tension test. Table 11 · Measurement types of Examples 3A-3F Pulp basis weight thickness MDDT CDDT CDWT S-CDWT-M 3A 100/0 60.3 1.18 5.44 4.12 0.69 0 3B 85/15 62.9 1.25 4.68 4.23 0.66 0 3C 75/25 55.6 1.04 5.48 4.06 0.66 0 3D 75/25 59.3 1.19 4.87 3.96 0.81 0.17 3E 75/25 60.7 1.48 4.41 3.51 0.79 0.12 3F 85/15 62.7 1.46 4.6 3.82 0.76 0 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Online Economy

For one attempt with 25% PET fibers, the non-zero S CDWT M 値 (sub-bubble wet tension in hard water) is non-zero. This suggests that larger amounts of synthetic fibers can begin to compromise water dispersibility. Example 13 The manufacture of the wipes was similar to Example 10, except that the co-binder polymer was a modified EHte (R) emulsion provided by Nationa Starch that was substantially free of crosslinkers. The basis weight of the fabric is 61.35, the thickness is .21 mm, and the feet are 5.09 WOWS \ Profiles \ UserWesktop \ PK-001 ~ 0n4.DOC December24 · 2001 This paper size applies to the Chinese National Standard (CNS) Μ specifications ( 210X297 points 1237030 A7 V. Description of the invention () '~-L catty two British two, MD stretch is 7.89%, _Τ is 3.90 kg / 3 British leaves, above is 9.50%, CDWT in 4% saline is ο . "The kilogram extension is 32. After one hour, the strength after deionized water (82 and hard water (S-CDWT_M) is 0 kg / 3 inches.) Example 14 Adding particulate matter to contain the wetness of mud particles The composition prepares a wipe containing Example 10 substrate. These particles are selected from the products sold below & Presperse, Inc. (Piscataway, NJ). Please read the back note first and fill out this page. System name composition— "&quot; 1 Mica and polymethyl methacrylate ___ Fine powder 'small plate coated with small spheres, 1 3 -1 7 micron circle · ---- MCP-45 Silk mica SL-012 98% mica , 2% methicone silicon white powder, hydrophobic surface, 2-10 micron rose Color talc talc white powder, 1 (M2 micron Permethyl 104A iso-octahexacontane (polyisopropylene) Cashmir K «H mica (97%), silica beads (3%), 0.3 micron fine white powder, small spheres coated with small spheres , 10-14 micron synthetic FNK-100 fine powder synthesized, 10-15 micron line L paper size applicable to Chinese National Standard (CNS) A4 specifications (_〇_6: 24. WC 1237030, printed by employee consumer cooperative of Intellectual Property Bureau, Ministry of Economic Affairs Preparation of the invention (A7 B7 fluorphogopite Ganzpearl GMX-0610 white powder of styrene / divinylbenzene copolymer, 4.5-8.5 microns Ganzpearl GS-0605 white powder of styrene / divinylbenzene copolymer, 4.5-8.5 microns Ganzpearl PS- 8F styrene / divinylbenzene copolymer 0.4 micron Spheron N-2000 non-crystalline silica white powder, 2-15 micron, low oil absorption Spheron L-1500 sowing crystalline dream stone white powder, 3-15 micron, low oil absorption Effect For each particle type in Table 12, five wet roll compositions were prepared at a particle concentration of 0.05 wt%, i wt%, 2 wt%, 5 wt%, and 10 wt%. Each roll is prepared with an appropriate amount of deionized filtered water in a 1.5-liter beaker (for the five rolls, the amount of water is 926.3 g, 921.3 g, 911 g, 881 g, and 831 g). When the Thermolyne Cimarec 2 blender is set to the highest agitation speed, the 2.5 inch magnet stirrer stirrer bottle content provides a strong central vortex in every 5 bottles. Each roll contains 4 wt% sodium gasified, and water is added to make 40 g of common salt; 1 wt% (10 g) of AmisOft ECS22-P aminoglutaric acid surfactant (Ajinomto of Tokyo); 〇 5 wt% (5 grams) of DC Dream G with emulsion (d0w Corning) to saline and surfactant; 1 wt% (10 grams) of Mackstat (R) 66 preservative (Chicago, Illinois McIntyre Group); and 0.05 wt% (0.5 g) of aroma first mixed cost paper size Applicable to Chinese National Standard (CNS) A4 specifications (210X297 male W ^ NDOW ^ Pmfiles \ UsβrWesk ^ opΨK-001-0734.Doc December 24,2001 (Please read the notes on the back to fill in this page first) • Binding · Thread 1237030 A7

TO Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention description (0 · 25 Wt% (2.5 g) of p〇isorbate 2〇, and then mixed into a solution containing the previous raw materials; 10wt% or 5 ~ 100g). Force the powder to / prepare liquid, stir and allow to wet, and become suspended for more than 30 minutes after adding the powder. Some additional stirring by hand requires some powder to Promote the dispersion of mixed denier powder in liquid, the pH is adjusted to 50 by malic acid, and the concentration in water is 50 wt%. It is based on parmer model 59002-00 pH / mv /. C meter and model 59 〇〇2-72KK8 electrode volume. According to Example 13, then each particle suspension was added to a dry air-laid substrate that had been treated with NaAMps binder and co-binder polymer. 2GG was added to the fabric-side by spray irrigation. %. Then the wet fabric is sealed in plastic # for one night. The inspection of the wet wipes uses the particle suspension as a wet composition treatment to show that the particles generally remain on the wet wipes. This does not require additional thickeners or polymerization retention. Help. For example, with In contrast to the milky white suspension of wet towels, squeezing the wipes caused a general lack of particulate matter, most of which seemed fresh. After using the towel, no residue appeared in the left hand. The particulate matter also improved Opacity, and appears to provide slightly improved tactile properties (reduced tack and better soft feel). Example 15 The role of non-gel powder particles in the wet composition of the present invention is to investigate as a means of reducing stickiness and improving wet wipes The way the surface feels. Five wet compositions containing wood powder powder are prepared according to Table 13. The cork airlaid fabric according to Example 10 is wetted with a wet composition of 300% (QS means "sufficient amount" to complete the ideal PH). I --------- Meal I — (Please read the note on the back before filling in this purchase), v-line

It —-1-1 gsi1 · · 1! Volume 1_ · This paper size applies to China National Standard (CNS) A4 specification (210X25 &quot; Cm ^ 〇WS ^ &gt; rofiles \ UserM) esktop \ PK-001-0734.Doc December 24, 2001 1237030 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

---- 87- V. Description of the invention (Table 13) Five moist composition formulas containing starch AB c DE water (Tap) 76.9 71.9 68.9 66.9 96.45 Laponite XLS 2 2 2 2 Scale 7 0.5 Malic acid (50% Solution) to pH 4 7 7 7 7 Cassava flour 28-1810 10 15 18 20 DC 1784 1 1 1 1 Dragoco Aroma 0/708768 0.1 0.1 0.1 0.1 0.05 Mackstate Η 66 0.5 0.5 0.5 0.5 0.5 Vapor Sodium 1.5 1.5 1.5 1.5 1.5 Mackam 2C 1 1 1 1 1 Malic acid (50% solution) to pH 4 QS QS QS QS QS (please read the notes on the back and fill in this page) .Doc December 24, 2001

^ -Applicable paper size-Chinese national standard) A4 specification (21〇X 1237030 A7 ____ ^ ____________ 5. V. Description of the invention () When touched by human hands, compared with similar starch-free wipes, starch-containing wipes Shown to reduce stickiness. Example 16 Prepare additional wipes using the wet composition shown in Table 14, one of which contains starch (as an additive), and the other contains a plant. The wet composition is added to a gas-laid fibrous matrix containing an ion-sensitive adhesive. Add 300 wt% and 200 wt% to the wet composition individually. __Table 14 · Two kinds of wet composition formulas Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Employees' Cooperatives, No. Starch plant formula 1 2 Water phase of raw materials ~ Water (Tap) 61.4 95.45 Laponite XLS 2 嶙 0.5 malic acid (50% solution) to pH 4 7 tapioca flour 28-1810 25 DC 1784 1 0.5 Dragoco aroma 0/708768 0.1 0.05 Mackstate Η 66 1 0.5 sodium vaporized 1.5 1.5 Mackam 2C 1 malic acid (50% solution) to pH4 QS QS This paper wave scale is applicable to Chinese National Standard (CNS) A4 specifications (210X 297 at public expense c is meaningless (please read the back first) Note to fill out this page) -¾ Ben - port line 1237030 Ministry of Economic Affairs Intellectual Property Office employees consumer cooperatives printed

Sir-V. Description of the invention () A7 B7 CS-22 0.5 Emulgin G 0.5 Witch Hazel 0.5 100 100 pH- 300% 200% added to the final solution ), 2-ethyl • hexyl-acrylic acid, and various ion-sensitive adhesives of AMPS, the mole percentages and molecular weights of which are shown in Table 15 Table 15. Moore percent number of ion-sensitive adhesive SSB monomer containing AMPS MWx10 · 6 AA BA 2-EHA AMPS A 1.54 60 24.5 10.5 5 B 1.32 60 24.5 10.5 5 C 0.604 60 24.5 10.5 5 D 0.548 60 24.5 10.5 5 E 0.609 60 24.5 10.5 5 F 0.545 60 24.5 10.5 5 G 1.21 62 24.5 8.5 5 Η 0.79 60 24.5 10.5 5 I 0.916 60 24.5 10.5 5 J 0.71 60 24.5 10.5 5 This paper size applies to the Chinese National Standard (INS) A4 specifications ( 21〇X 297 &amp; | j2c._DOWS \ Profi / es \ i7se_s_P_i -_. DocDecember24 ^^^ -Snap 丨 — (Please read the note on the back to fill in this page first)

1237030 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (A7 B7 K 0.786 60 24.5 10.5 5 L 0.845 60 24.5 10.5 5 Μ 0.640 60 24.5 10.5 5 Ν 0.800 60 24.5 10.5 5 0 0.635 60 24.5 10.5 5 Ρ 0.610 60 24.5 10.5 5 Q 0.575 60 24.5 10.5 5 R 0.638 60 24.5 10.5 5 S 0.912 62 26.5 7.5 4 T 0.609 60 25.5 10.5 4 U 0.835 58 27 10 5 V 0.675 58 27 10 5 W 0.734 58 27 10 5 X 0.716 58 27 10 5 Υ 0.650 58 27 10 5 Z 0.718 58 27 10 5 ΑΑ 0.518 58 27 10 5 ΑΒ 0.544 58 27 10 5 Prepare these adhesives according to the method of Example 1, but increase the possibility of making hundreds of rolls per roll. Example 18 A representative wetting solution is prepared according to a specific weight percentage by combining the following raw materials. The paper size is in accordance with Chinese National Standard (CNS) A4 specifications (210 公 297 Gong Li 0 3 ^ age 0 ordered) _Visit the Office . 释. 朋 4 俏 __ 「2〇 ^ (Please read the note on the back before filling this page) 1237030

&quot; 9T Α7 Β7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention Agent (McIntyre, Chicago, Ill.), %% CS22 aminoglutaric acid surfactant (Amis 0ft Co., Ltd., Tokyo, Japan), 0.5 wt% DC 1785 silicone emulsion (D0w Corning), 0.25 wt% Solulan L-575 (PEG-75 refined wool, obtained from Amerchol, a division of Union Carbide), 0.05 wt% Dragoco aroma 0/708768 (Izca from DF Mexico) Dragoco SA), 0.25 wt% poiysorbate 20, and about 0.07 wt% 50 wt% malic acid solution to obtain pH 5.0. Example 19 The treated substrate was fabricated using the equipment described in Example 10. An airlaid matrix. Weyerhaeusef cf405 bleached softwood kraft pulp with a basis weight of 65 gsm and fibers of 100%. The binder solution has 128 wt% binder solids, 75 SSB number H from Table 15 , And 25 "% Dur 〇SetRB latex co-binder (natural starch). Binder solution Sprinkled on the fabric described in Example 丨 for all oven areas, the temperature of the dryer was 215 ° C. Example 20 The treated base milk machine-laid fabric was manufactured in accordance with Example 10, except that the basis weight was 0%. And the oven temperature is 227. The reel speed is i97fpm. The thickness of the dry branch is 1.30 mm. The MDDT is 5.55 kg / 3 British pairs, the Ccdt is 4.83 kg ^ British leaves, (in 4% NaC1 solution) is 1 kg door inch, applicable to China National Standard (CNS) A4 specification (210X2974 tAWINDOWS \ ProHles \ UserM) esktop \ PK-00l ^) at this paper standard 734.Doc 〇 &lt; Note on the back: fill in this page} ^ 1 line * 1: 1 ml nnA7

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Ϊ237030

S-CDWT ^ S-CDWTO Cut some dry fabrics into 4 25 苒 inches wide. Composition treatment, which consists of going on a surfaceless surface. Into: "... The moistened fabric is punched with teeth with perforated blades = there are _ deep operations in water and ## is added every 4.5 inches. The perforation is approximately 37.5 with a resistance of 0 · 070. 卷 / fabric roll Into each reel (each in a white plastic core, each with a coreless reel of: follower tooth: sheet) and place it for use in a wipes dispenser. Example 21 The dry part of the treated fabric was changed into a wet set of ㈣18 The perforation reel form is used to dispense a wipe that can be dispensed from a bathroom. Comparative Example 22 〃 Traditional adhesive airlaid matrix with 6 (UgsmA weight) was produced using the method described in Example 10. Dur_〇_ Set Ε · 646 (natural palace powder) is made of wood pulp (CF4G5). This substrate is wetted with Naci solution and tested using the method described. The binder is a completely self-crosslinking Dur_〇_Set E 646 compound, using A salt-free induction adhesive. The solid mass of the adhesive is 7% of the base mass. The dry thickness of the fabric is 14 mm, and the cD wt 値 is 1.3 β kg / 3 ying 同时, while the SCDWT is i 2 kg, and scDWTM is 1.15 kg 'which means that the fabric stays nearly the whole after soaking Degrees, and recommended parent key latex provided the majority of the tensile strength of the fabric, and the adhesive is not recommended that the latex becomes weak in a large body of water. Example 23 Preparation variety of binder / co-binder composition, as described below,

This paper size applies to Chinese National Standard (CNS) A4 specification (t) MNDOWSiPro and es \ UserADesktop \ PK-001-0734.DOC December 24, 2001 1237030 A7 B7 V. Description of the invention () Use the salt induction adhesives in Table 15 and Table 16 shows co-adhesives that are not cross-linkable per se. 16 · Latex Co-Binders Co-Binders Co-Binder ID Co-Binder Manufacturer 1 Dur-O-Set RB National Starch 2 Rhoplex NW-1715K Rohm and Haas 3 Rovene 4817 Mallard Creek Use the method described in Example 10 The airlaid substrate is made from bleached cowhide fibers. The matrix was wet with 4% NaCl and tested using the method described. All substrates include wood pulp (CF405) and a binder. The results are shown in Table n, where the consistent adhesive mixture contains 75% of the salt-sensing adhesive (selected from Table 15) and 25% of the co-adhesive (selected from Table 16). The adhesive / co-adhesive column lists the adhesives and co-adhesives listed in Tables 15 and 16. For example, "A / Γ refers to the SSB number A in Table 15 and the common adhesive 1 in Table 16. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Table 17. Number of tensions of different adhesive systems.% Adhesion SSB Basis Weight Thickness CDWT S- S- S- Adhesive / Total MWx (gsm) (milligrams (kg CDWT (CDWT-M CDWT-M: contract stick 10'6 m) / 3 British kg / 3 British (kg / 3 3 hours (mixture in inches) inches) pounds / 3 inches 16.7 A / 1 1.54 71.3 1.46 0.990 0 0.330 f 7, 4 0.180 20 B / 1 1.32 63.3 1.25 1.242 0.163 0.470 0.3 10 20 B / 1 1.32 66.6 1.46 1.040 0 0.230 0.550 This paper size applies to China National Standard (6ns) A4 specification (^ NDOWS [Pmfiles \ UsefM} esktop \ PK-() 01-0734.Doc December 24, 2 (Please read the note on the back first , Fill in this page). · Ϋ In ml ml nn emeu ——- II U3, 1 line --- 1237030 A7 B7 Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs

1237030 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (5ΓΕΓ A7 B7 Adhesive / Co-adhesive basis weight (gsm) Thickness (mm) CDWT (kg / 3 inches) S- CDWT (Kg / 3 inches) S- CDWT-M (kg / 3 inches) F / 1 Dur-O-Set RB 59.77 1.06 0.735 0 0 F / 2 Rhoplex 60.83 1.14 0.758 0 0 F / 3 of the duplex 60.28 1.18 0.687 0 __ / Under similar operating conditions, all three co-adhesives can be ordered at the same time. All matrices have their own tensile strength (S.CDWT-M) lost in a 200 ppm dication solution that does not depend on the co-adhesive type. Example The peel strength of the outer layer of the coreless wet wipes suitable for use as a wet: toilet paper product is measured. This product is manufactured according to Example 10 with a moisturizing composition. The dry fabric is cut into 4.25 inches and wide Treated with the addition of 200% wet composition, which contains 4% NaCM in deionized human child K with surfactants, ketones, and refined wool, which are listed in Table j I: Q, R, and S The wet fabric is centered on the perforated edge 2 Perforated. The perforated fabric is rolled into a coreless reel with 100 perforated sheets per reel (each | = Γ) and placed inside the square &quot; &quot; for subsequent use in a wipes dispenser. I19. In three solution silicone paper size (210X2975 (please read the note on the back and fill in this page first) Order-line ---

In in ......... c ^ NDOWS \ Profiles \ Usermesktop \ PK-001-0734.Doc December 24 2001 V. Description of Invention () Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 1237030 A7 B7- --- Q 0.50% ------- 0.25% CS22 _3 1.00% 0.25% ECS 22P ------ ECS 22P S 1.00% 0% When the reel pulls the end of the reel vertically to unwind the fabric, The reel is placed in a round plastic bucket by itself, and the bottom of the ridge line will hold the reel in one place with minimal friction. Adjacent layers stick to each other, making it necessary to use some force to separate this: layer. The required peeling force is less than the weight of the reel, and when the reel is rotated, it is significantly larger than the frictional resistance provided by the bucket, confirming that the angle between the fabric and the reel is divided into points of separation. When there is no peeling force, the angle between the fabrics rises, and the midline of the separation point is perpendicular to the reel. The angle at which the salt-inducing adhesive releases the wet reel ’is generally less than 9G. And therefore increase the strength to separate the fabric. Peel force was measured with MTS Sintech = ㈣ Mechanical with TestWorks 3.10 software. The test is performed under the standard conditions under the actual conditions ^ to 实; 4 · 5 inches of leaves with a rubber surface of the central clamp clamping the tail of the reel [the position of the reel is under the clip, so that if there is no cause for fabric to wind the reel Partial and peeling forces that deviate from the vertical plane, the tail is still vertical when released from the reel. The clip is attached to the link, which pulls the sheet of fabric up at a rate of 1 minute / minute.剥离 50 N filled battery to measure peeling force #. The average load of 18 sheets was pulled from each of the individual recording reels by averaging 2 kinds of 4 pieces and averaging 2 kinds of 5 pieces. Only the first 18 tablets in the reel were used for the measurement. In each case, record the average peel force of the two green reels, as shown in Table 20 below. Table 20 · Peeling force (g) removed from winding wet reel A4 size d〇 :; T297 § sorry factory ^ &quot; ~~ --- ^ W ^ mD〇WS ^ mfileS \ UserWesktop \ PK.〇01-0734 .Doc December 24 2001

ΎΤ A7 B7 Basis Weight Thickness (with the addition of the adhesive solution MDWT (gram affinity 4 separation strength (gsm) meters) agent / inch) (g) __ 65 1.1 22% Q 500 167 _ 65 1.1 2 2% R 476 --- ----- 170 65 1.1 22% S 533 162 60 0.76 20% Q 438 131 —55 0.76 20% Q 353 106 55 0.76 20% R 341 120 55 0.84 20% R 385 115 1237030 V. Description of the invention (- ------ (Please read the note on the back to fill in this page first) The peeling force of a reel with a width between 7 and 15 cm (the reel width tested in Table 20 is ^ 8 cm) is ideally less than 500 grams, more specifically less than 300 grams, more specifically about less than 200 grams, the most specific is, the spoon is less than 160 grams, very clear is about less than 120 grams, the model Fan Yuan about It is 50 grams to 350 grams or about 80 grams to 200 grams. In general, the peel force per 4 centimeters of width in a wet scroll can be any of the above ranges. Ϊ-— I --- 1 · The extra samples were prepared according to Example 24 above, except that 15 ~% of 6 meters of crimped PET fiber (K〇Sa) mixed The different co-adhesives in Table 16 were mixed with the salt-sensing adhesive number F of Table VII. The adhesive mixture was then applied using the Wan method described in Example 10 to form an air-laid matrix, the characteristics of which are listed in Table 21. In each case, the binder solids are mixed and applied to the substrate as a 75% SSB / 25 agent. The properties of the tritium, ..., are measured after wetting with a solution. All three common binders can be performed equally. Standard applicable to China

CmiND〇V ^ rofiles \ UserWesktop \ PK-001-〇734.Doc December 24, 2001 1237030 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 --------- V. Description of the invention () ppm Independent common adhesive type In a divalent cationic solution, all substrates lose their own tensile strength. Consistent with the results of Example 24, the combination of synthetic fibers added a little proper strength improvement (CDWT) and a moderate increase in dry fluff. Table 2 1 · Very fair weight adhesives / co-adhesives with PET fibers and various co-adhesives. Co-adhesive basis weight (gsm) thickness (mm) CDWT (kg / 3 inches) S-CDWT (kg / 3 inches) S- CDWT-M (kg / 3 inches) F / 1 Dur-O-Set RB 63.32 1.31 0.782 0 0 F / 2 Rhople X 62.07 1.35 0.820 0 0 F / 3 Rhople X 62.90 1.25 0.660 0 0 Example 27 Additional examples are cited in Example 26, and the increased number of synthetic fibers is added to the fiber mixture. Either a 6mm crimped PET fiber (KoSa) or a 6 tm crimped 2.4 dtex, the Lyocell fiber usage is recorded in Table 22 below. The binder mixture is a certain mixture of 75% SSB and 25% co-binder. ---- Po ------, 玎 (please read this page first to write this page) '. Table 22 · Basic Fibers of PET Fiber and Various Common Adhesives 垆 Pulp / Synthetic Adhesive CDWT S-S-Synthetic Type Mixture / Total (gsm) (milligrams (kg) -001-0734.C &gt; oc December 24, 2001 1237030 V. Description of the invention (ΎΨ A7 B7 agent% with adhesive meter) / 3 inch) 100/0 20% F / 3 60.28 kg / 3 inch)

85/15 PET 6 mm 20% F / 3 18 0.687 0 62.90

75/25 PET 6 mm 20% F / 3 59.32 1.19 0.805 0 0.170 75/25 PET 6 mm 20% F / 3 60.65 48 0.790 0 0.120 85/15 PET 6 mm 20% F / 3 62.67 1.46 0.757 0 85/15

Lyocell-6 mm 19% E / 2 58.3 1.08 0.969 0 75/25

Lyocell-6 mm 19% E / 2 59.2 1.09 1.080 0.127 Printed by those consumer cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs on those who attempted non-zero immersion in 200-divalent cations such as synthetic fibers (or — The CDWT tension is non-zero, and this suggestion can begin to compromise water dispersibility with larger amounts. Example 28

The substrate shown in Table 23 can be manufactured entirely according to the method of Example 10 and prepared according to the method described in Example 23. All substrates in Table M were formed from airlaid pulp (CF405). All adhesive mixtures are 75% SSB ^^ DOWS \ Pmf} les \ Userf ^ esktop \ PK-001-0734.D (X December 24, 2001 i paper size applies ϋ National Standard (CNS) A4 specifications ( 1237030 A7 roxr B7 V. Description of the invention (<The former was controlled by two compacting reels to adjust the degree of fabric compaction. Use SSB numbers 0 and Q from Table 15. Quality data

And 25% co-binder. The dry thickness of the sheet was printed for the first time with the application of the adhesive. It was printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Obviously, before the adhesive was applied, the compaction of the dry fabric did not need to give up dispersibility, but it appeared to increase the wet strength of the final sheet. This unexpected increase in strength allows the same wet strength to achieve various combinations, including reduced basis weight and / or reduced percentage of binder in the sheet. Example 2 9 All matrices were prepared according to the method described in Example 27. All matrices contain the fiber mix recorded in Table 24, which has a 20% bond in the flakes 1237030 A7 B7 Γ〇Ί &quot; ~~ -------. V. Description of the invention f) agent and Dur as a co-binder -O-Set RB. Crimped synthetic fibers, either 6mm PET (KoSa) or 6 or 8mm Lyocell with} 7 or 2 4 dtex (Accordis) 〇Table 24 | · Matrix data numbers with 1-dimensional and _ different agents % Synthetic Fibers Synthetic Fiber Adhesives / Co-Adhesives SSB Molecular Weight Basis Weight (gsm) Thickness (mm) CDWT (kg / 3 inches) S- CDW T (kg / 3 inches) S- CDW TM (kg / 3 inches Inch) 2701 0 without F / 1 545000 59.8 1.06 0.735 0 0 2702 15 PET F / 1 545000 63.3 1.31 0.782 0 0 2713 15 L-2 · 4-6 F / 1 545000 62.0 1.39 0.840 0 0 2714 15 L-1 · 7-6 F / 1 545000 61.8 1.33 0.768 0 0 2715 15 L-1 · 7-8 F / 1 545000 63.7 1.47 0.842 0 0 2716 0 None J / 1 710000 65.5 Ml 1.193 0 0 2717 15 L-1 · 7- 8 J / 1 710000 61.4 1.02 1.512 0 0.200 3010 0 None R / 1 638000 61.10 0.80 1.710 0 0 3015 15 PET R / 1 638000 62.23 0.86 1.769 0 0.070 3016 5 L-1. R / 1 638000 60.63 0.79 2.620 0 0.170 copies The paper size applies the Chinese National Standard (CNS) A4 specification (210X297々J | ([) j ~ ^ ^ C ^ miNDOWS ^ r〇eies \ U $ erWe $ ktop \ PK-001-0734.Doc December 24, 2001) Printed by the Consumer and Consumer Goods Corporation of the Ministry of Economic Affairs and Intellectual Property of Japan 1237030

Clothing printed by employees' cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs The example in Table 24 suggests that the length of synthetic fibers, the molecular weight of the SSB, and the tightness of the bonded fabric can affect the dispersibility of the product, such as S-CDWT-M 値. All matrices containing 6 or 8 mm of synthetic fibers can be dispersed with a lower molecular weight ssb. As the molecular weight of osmium increases, the 8-mm Lyocell matrix begins to retain some of its own strength after soaking for i hours. The compacted dry fabric can also be added with the dispersibility of synthetic fibers containing the matrix (numbers 3015 and 3016) before the application of the binder. Nos. 3015 and 3016 are completely dispersible in DI (deionized) water. The dispersibility of the flakes can be treated with lower molecular weight SSBs chosen to be combined with the compaction of synthetic fibers and dry fabrics. Example 30 The substrates listed in Table 25 were prepared, wet with a 4% NaCl solution, and tested according to the method described in Example 29. Each matrix contains the recorded fiber mixture and a 20% binder with SSB / co-binder mixture (note green in Table 25). Dur-O-Set RB is a common binder used in all the samples listed in Table 25. All numbers except the last (No. 2813) use 100% softwood fibers, which contain 15% PET fibers (6 mm crimped fiber from KoSa). The basis weight is generally fixed at about 00 gsm. The thickness of the air-laid fabric is controlled by adjusting the degree of compaction of the fabric. This compaction is performed by two compaction reels before the first spraying of the adhesive. The dry cD stiffness of the substrates selected in Table 25 was measured using a fabric handle-o-meter and the stiffness was recorded. Table 25 · Data of substrates with various adhesive mixtures. The paper size is applicable to the Chinese National Standard (CNS) A4 (21〇χ 297 mm) J Λ Right-CWC- ^ m ^ WS \ Pmfiles \ UserADesl (top \ PK-001-0734.Doc December 24,2001 Order ----------- • (Please read the precautions on the back before filling out this page),. TO A7 B7 Adhesive number is a total of 'agent / Adhesive Type Basis Weight (gsm) Thickness (mm) CDW T (kg / 3 inches) S- CDWT (kg / 3 inches) S- CDWT-M (kg / 3 inches) Stiffness s (g · Force) 3025 100/0 R 58.42 1.23 1.003 0 0 200 3026 100/0 RI 58.68 0.76 1.953 0 0 214 3007 75/25 R 60.23 1.19 0.942 0 0 189 3008 75/25 R 59.38 1.03 1.161 0 0 3009 75/25 R 59.73 0.92 1.243 0 0 3010 75/25 R 61.10 0.80 1.713 0 0 181 3021 65/35 R 62.24 1.17 0.988 0 0.050 177 3022 65/35 R 62.07 0.81 1.800 0.030 0.200 167 3024 55/45 R 58.95 1.23 0.853 0 0.100 145 3023 55/45 R 59.01 0.78 1.608 0.150 0.230 141 2812 65/35 P 59.0 1.37 0.735 0 0 2813 65/35 P 59.4 1.41 0.723 0 0 1237030 V. Description of the invention ( Po ------ Order (please read the back page first to write this page-the percentage of salt-sensing adhesive printed in the mixture by the consumer cooperative of employees of the Intellectual Property Bureau of the Ministry of Economic Affairs is reduced from 100% to 55%, only in one Moderately reduced cDWT under dry fluff. In the 65% salt-sensing adhesive composition of the adhesive mixture, after soaking in 2000 divalent cation solution for 1 hour, the matrix began to maintain a larger wet strength portion. With the first time The fabric was compacted before the adhesive was applied, and the salt-sensing adhesive &lt; percentage in the mixture was reduced to 65% or less, the same as that of the higher dry fluffy, and in comparison, 'soaked in deionized water Or 200 ppm divalent cationic solution is called DO ermsktop_m34 fine 24 2000. This paper ruler ® ® S? TCNS) A4 ^ (2iOX 297 ^^ M68b: Ϊ237030 5 ------invention · description} 〇4 A7 B7 After 1 hour, it maintains a large strength. These examples are proposed to increase the co-binder content with additional pressure on the fabric, which can make the fabric compromise the matrix dispersibility. The results in Table 25 also show that when the thickness of the dried fabric is compressed when the adhesive is applied, the CDWT is significantly increased. Nos. 3007 to 3010 show the increased CDWT when the dry fluffy function is reduced with no loss of matrix dispersibility in the condition of a stack of adhesives. Based on the results of the fabric feeler (stiffness), it appears to reduce the percentage of salt-sensitive adhesive in the mixture and reduce the CD stiffness of the matrix. Example 3 1 Prepare the kits listed in Table 26 according to the methods described in Examples 10 and 23. Each matrix contained pulp (CF405) &amp; 20% binder. The adhesives have an SSB / co-adhesive mixture and are listed in Table 26. Dur-O-Set RB is a co-binder. The substrate became a roll and was wet with the solution Q of Table 9 (Solution D). The peel force of the product to be spread from the outer layer of the coreless wipes roll was measured according to the method described in Example 25. The results of these tests are shown in Table 26 below. (Please read the notes on the back of the book first). Slow, 17k Printed by the Intellectual Property Bureau Staff Consumer Cooperative of the Ministry of Economy $ 26. Peeling result of coreless scroll No.% Adhesive binder in sheet / co-basic thickness ( Unpeeled adhesive mix with adhesive (gsm) m) (g) 3026 20 ″ 00/0 R / 1 58.68 0.76 VJ 142 3010 20 75/25 R / 1 61.10 0.80 139 3022 20 65/35 R / 1 62.07 0.81 116 3023 20 55/45 R / 1 59.01 0.78 111 This paper is suitable for financial use_ 家 县 腔 'Wc / side M ID0W ^ rofiles \ UserWesktop \ PK-001-0734.Doc December 24, 2001 I237〇305 Instructions / 05 A7 B7 Reduce the peeling force in this case. Example of reducing the percentage of salt-sensing adhesive in the mixture Example 32 According to the report in Table 27 below, a 75/25 mixed SSB adhesive (see Table 15) and a Dur-O-Set RB co-adhesive (co-adhesive of Table 16 〇 Sample of manufacturing example 10. The tension results in Table 27 show good dispersibility beyond the scope of the review. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs% molecular weight basis of a single adhesive / co-adhesive ( gsm) Thickness (mm) TO ΙΜΜ ^ :; CDWT (kg / 3 inches) 7 栝 S-CDWT (kg / 3 inches) S-CDWT -M (kg / 3 inches) '' 0 0/1 632000 52.5 1.19 0728 0 0 20 Q / 1 575000 54.19 0.75 1.372 0 0 25.2 J / 1 710000 55.2 1.47 0.320 0 0 24 L / 1 834000 60.4 『92 1.070 0 0 20 D / 1 548000 62.5 1.32 0.900 0 0 20 H / 1 790000 63.1 1.3 1.070 0 0 22 R / 1 638000 66.47 0.76 2.273 0 0 20 C / 1 604000 74.4 1.47 1.120 0 0 The example shown in Table 27 proves that some of the binder content, basis weight range, and exceeds the dispersible matrix Example 33 β-sheet scale applies Chinese National Standard (CNS) A4 gauge (210 ^ 297¾¾¾ ^

-ml l—j (Please read the cautionary note on the back-order: · side NDOWS \ Pmfiles \ Usermesktop \ PKO01 ~ 0734.DOC December 24 丨 2001 1237030 A7 106 &quot; ----------- V. Description of the invention ('As recorded in Table 28, the sample in General Example 10 was made using a 75/25 SSB adhesive mixture (see Table 15) and a common adhesive (see Table 16). With 丨 5% The fibers are mixed with 85% softwood fibers. All matrices contain 6 mm crimped 2.4 dtex LyoCell (Accordis) e. All matrices contain 19% binder and 81% binder mixture. 28. Tension of the binder air zone Result gas! Tablet characteristic adhesive / co-adhesive SSB molecular weight basis weight (gsm) thickness (mm) CDWT (kg / 3 inch) —π r '1 soil S- CDWT (kg / 3 inch) S- CDWT -M (kg / 3 inches) L / 1 845,000 61.1 1.17 0.960 0 0 W / 1 734,000 60.2 1.17 0.960 0 0.198 AB / 1 544,000 56.2 0.95 1.060 0 0 AB / 2 544,000 58.6 1.06 0.990 0 0.205 E / 2 609,000 58.3 1.08 0.969 0 0 Printed in Table 28 by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, immersed in 200 ppm divalent cations After 1 hour of fluid (S-CDWT-M), all samples lost at least 75% of the wet strength. The main difference in these samples was the SSB composition, as described in Table 15. Compared with the salt-sensing adhesives W and AB (see Table 1 5), salt-sensing adhesives l and E have the same composition and different molecular weights. Salt-sensing adhesives W and AB have the same composition, but different molecular weights. The W / 1- and AB / 2-treated substrates appear to be more individual. L / 1- and E / 2- co-adhesives that treat the substrate have less dispersibility. Reducing the molecular weight of the salt-sensing adhesive can be used to make the substrate more dispersible, such as substrate AB / 1. Alternatively, change the salt-sensing The composition of the adhesive can be used to make the matrix more dispersible. 1237030 Printed by A7 ______B7, Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Invention · Explanation i07), as demonstrated by L / 1 and E / 2. Therefore, by changing The molecular weight composition of the salt-sensing adhesive or its own molecular weight results in a fully dispersible mixture. Or, by selecting different co-binder chemistries to make it more consistent with the salt-sensing adhesive, a fully dispersible adhesive mixture can be obtained from the matrix 2 and αβπ Manufactured by certification. Example 34 An emulsion containing approximately 6% NMA cross-linking agent, AirFlex 105 (Air Products, Yalin, PA) was combined with the SSB number in Table 15 at a ratio of 75% SSB to 25% emulsion solids , And cast into 8 sticks with a size of 1 cm x 4 cm father 3 mm, as described in Example 9. Four sticks were prepared by drying overnight in air at 60 ° C, while the other four sticks were dried at 67 ° C for 3 hours. Then the rods of each group were each placed in 30 cm of 4% NaCl solution and allowed to stand for 1 hour after the solubility was determined by gravimetric analysis. The two groups of rods (the two groups are in a dry state) are completely insoluble in the alkaline solution. The remaining sticks in each group are at 23. C was placed under 30 cm of hard water containing 200 ppm calcium and magnesium ions, the ratio of calcium ions and magnesium ions was 2: 1, and allowed to stand for 1 hour. The two sticks were dried at 1670 ° C and placed in hard water, which by itself could not be completely dissolved (0% dissolved). The two rods were dried at 60 ° C and placed in hard water, which were soluble at 54% and 53%, respectively, which were unexpectedly low at this temperature where the latex was roughly cross-linked for drying. Regardless of how 'some coagulation occurs when the lactating father mixes with the second mixture, this raises the question of possible consistency between the two mixtures and thus impairs solubility, or some coagulated particles cannot pass through the filter paper. Some NMA cross-linking agents in Airflex latex may also have the ability to promote cross-linking or gelation of the mixture. Although I believe some of this paper HiiTi national standard ^ () A4 specifications γϋϋ? Public ~ '^ Cl ^ cMND〇mPmms \ UserADeskt〇iAPK-001-0734.Doc December 24, 2001 (Please read the note on the back first to write this page )-燊 ·, \ 呑 k — 1237030 Printed A7 by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (1Γ ^ Γ ~ ~ -— The results are shown in 1.5% Naa and 4% Hard water dispersibility of No. YdOM) For fabrics treated with I, it has excellent strength loss, good strength for No. Z, and remaining strength of No. χ. Comparing No. X and No. Y, it is recommended to lower Can promote the dispersibility of salt-sensing adhesives. The second picture is a chart, which shows the wet tensile strength of the softwood airlaid fabric containing ion-sensing adhesive when it is immersed in a solution containing calcium ions. CDWT record, the weight per 2.54 cm) how to change after super ㈣. It contains 85% Lion (Said Tokyo) SSB-2b malonic acid trimer and 15% Dn Ο-Set RB ( Nati〇nal Starch) co-binder 20 wt% binder to prepare a wet fabric. After drying, these fabrics were wetted with a solution containing 109% NaCl, 0.5% phospholipid CDM (Mona), and 0.5% Mackstat η 66, and showed about 400 g / inch (or g / 2.54 cm). Wet strength. The solution was added to 250% by dry weight of the fabric. The treated fabric was then immersed in anhydrous Naa containing calcium ions at 0, i 3, 29, and 109 ppm. This resulted in four curves as shown in the second figure, which were wet. Tensile strength vS time. There is no loss of strength of 109 ppm dance ion itself. Over 100 g / inch is maintained at 29 ppm calcium ion. This appears that even a small amount of calcium ion in water will hinder products with LiON SSBJb The dispersibility of the treated fabric. The third figure compares the second data set, which is the u〇n SSB-3b product of the second figure (referred to as the number 33000) and the continuous salt sensing adhesive (this is similar to Dur-〇- Set Rb polymer mixed at a ratio of 75/25). The data set of No. 2102 refers to a 65 gsm fabric containing a sulfonate sensing adhesive, which is equivalent to the SSB number of Table Η. This fabric is shown in Table 4. The solution is soaked. The solution is increased by 225 dry weight, 7270X297 gauge.

1237030 Α7 ---______ B7 V. Description of invention (11Q)% of fabric. This adhesive formulation shows a rapid drop under tension and therefore has good triggering ability when entering hard water (even at a calcium ion concentration of 257 ppm). Therefore, the sulfonated salt-sensitive adhesive of the present invention shows a dramatic improvement in the ability to disperse in hard water compared to the previous trimeric acid trimer. The tension results in the data in the first and third figures are obtained from an MTS tensile testing device, which is a MTS 500 / S device (MTS system in Research Park, North Carolina) using TestworksTM 3.10 of Windows software. Instead of the standard 3 inch strip test, a 1 inch wide strip cut into 6 inches was used. The spacing between the jaw jaws of the test equipment was 3 inches. The test was run at a joint speed of 12 inches / minute. Of course, it will be understood that the foregoing is only about a certain disclosed embodiment of the present invention, and many changes and alternations can be made without reaching the spirit and scope of anti-invention, which is published in the scope of additional patent applications. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the company ^ w3: \ WINDOWS [Profiles \ UserADesktop \ PK-001-0734.DocDecember24 2 Paper Size (CNS) Α4 Regulation (210X297

Claims (1)

1237030 A8 B8 C8 D8 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 6. The scope of patent application is between 200 g / inch and 2,000 g / inch. After 20oPpm- or more polyvalent ionization, its tensile strength is between 0 g / inch and 50 g / inch, 彳 9 彳 4. If the wiper of item 1 of the patent application scope, · The degree is between ⑽gram / English leaf to 2, _gram / English leaf towel. Yes—the internal wet tension is strong, and it passes through a multivalent ion aqueous solution with a concentration between oppm to so-called ppm—or more—hours. After soaking, its tensile strength is between 0 g / inch and 2 () g / inch. 5. If the wet wipes of item i of the patent application range, sacrifice, the wet wipes have an internal wet tensile strength. G / yang 忖 to ⑽g / yingqi and its tensile strength is between 0 g / inch and 2 after immersion in an aqueous solution of one or more polyvalent ions for one hour at a concentration between oppm to 300 ppm. G / inch. 6. If a patent-applicant's wipes, the wipes have-internal thirst tension between 300 grams / Ying Ye to 2,000 grams / Ying Yu, After being soaked for one hour at a concentration of 70 ppm to 2GGPPm or more of a polyvalent ion solution in water, its tensile strength is between 0 g / inch and 20 g / inch. 7. If applying for a patent Wet wipes in the range 帛) have wet internal wipes having an internal wet stiffness ranging from 0 g / ying Ye to 2,000 g / ying Ye, and they pass through a concentration ranging from 0 PPm to 20 Gppm—or Many polyvalent ionic aqueous solutions-after soaking for an hour, its tensile strength is between 0 g / inch and 10 g / inch. This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) • Order ---------- Line- (Please read the notes on the back before filling out this page) 115 C: \ Eunice \ ΡΚ-00Ί-07 \ ΡΚ-〇0Ί.〇734 ^, chi- cln-2- (〇ri-C 1237030 A8 B8 C8 D8 6. Scope of patent application &amp; For example, the scope of patent application 专利 i wipes, under A ”ISO ^ ^” —Inner Shao wet tension strength J is 150 grams / Centimeter to 2,000 grams per inch, 0 Dom $ 200 Eight in! Tensile strength after soaking for one hour in an aqueous solution of one or more polyvalent ions with a concentration between inch and 200 Ppm From 0 g / inch to 10 g / inch. 9. As for the wipes under item i of the patent application, a wet wipe has an internal tension of 200 g / inch to 2.0 g / inch. Ying. ,,,, and /, after a concentration of one or more aqueous solutions of polyvalent ions_hours between 0PPm and 2000Ppm, the tensile strength is between 0g / inch and 10g / Inch. … As the scope of patent application! Item of wet wipes, the wipes have an "inner" tensile strength of 300 g / inches to 2, _g / inches, and it undergoes one or more polyvalents at a concentration of 0 ppm to 200 ppm After one hour of immersion in the ionic aqueous solution, its tensile strength is between 0 g / inch and 10 g / inch. 1 1 · As for the wet wipes of item 1 of the patent application scope, the wet wipes have an internal wet tensile strength between 100 g / inch to 2,000 g / inch, and after being soaked for one hour in an aqueous solution of one or more polyvalent ions having a concentration between 0 ppm and 200 ppm, the tensile strength is between 0 g / inch Inch to 3 () g / inch. 12. For example, the wipes of the first patent application range, the wipes have an internal wet tensile strength of 100 g / inch to 2,000 g / inch, and One or more aqueous solutions of polyvalent ions with a concentration of 0 ppm to 50 ppm after one hour of soaking, its tensile strength is between 0 g / inch and 30 g / inch. National Standard (CNS) A4 Specification (210 X 297 mm) ^ ------— (Please read the notes on the back before filling this page) 116 c: \ Eunice \ ΡΚ-00Ί-07] ΡΚ-00Ί-0734 \ PK-〇〇l-0 734-chi-cla-2 g88 I — # · 11 — 1! $ (Please read the notes on the back before filling out this page) Member of the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives printed 1237030 VI. Scope of patent application 13. · Wet wipes for item 1 of patent scope And thirsty φ ^ I. There is an internal wet tensile strength between 200 g / inch and 2,000 g / inch, and R has one or more polyvalent ions with a concentration between 0 ppm and 50 ppm. After being soaked for one hour, the muddy water Luosi has a tensile strength between 0 g / inch and 30 g / inch. 14. According to the wet wipes under the scope of the patent application, the wet wipes have an internal wet tensile strength of 300 g / inch to 2,000 g / inch, After one or more hours of immersion in an aqueous polyvalent ion solution or more, its tensile strength is between 0 g / inch and 30 g / inch. 15. The wet wipe according to item 1 of the patent application range, wherein the weight percentage concentration of the organic solvent contained in the wet composition is between 0 wt% and 4 wt%. 16. The wet wipe of item 15 in the scope of patent application, the wet composition of which contains the solvent in a weight percentage concentration of 0 wt% to 1 wt%. 17 · The wet wipe of item 1 in the scope of patent application does not substantially contain an organic solvent in its wet composition. 1 8. The wet wipes according to item 1 of the patent application range, wherein the concentration of the activated mixture in the wet composition is 1 to 5 weight percent. 1 9 · If the wet wipe of item 18 in the scope of the patent application, the activation mixture of the paper wiper is composed of the paper rule Ⅰ 冢 ν 圏 National Takazaki Standard (CNS) A4 (210 x 297 117 C: \ Eunice \ PK-001-07 \ PK.〇〇l ^ 〇734 \ PK-001-0734-chi-dn-2- (〇ri-CWC) .d〇c 1237030 Α8 Β8 C8 D8 Printed and patented by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs The concentration in 4 is 20% by weight. 20 · As in the wet wipes of the first scope of the patent application, the activation mixture is sodium chloride. 2 1 · As in the wet wipes of the first scope of the patent application, the ion-sensitive polymer Formation is from one or more monomers, and these monomers are derived from acrylic acid; aminopropionate 2-ethyl-1-propanylsulfite (AMPS), 2-aminoacrylic acid 2-ethylpropionsulfate Butylacrylic acid; 2-ethylhexylacrylic acid. 22 · As in the wet wipes under the scope of patent application No. 1, the cross-linking adhesive is a non-staggered polymerization (acetamidine-vinyl acetate) 23) The wet wipe according to item 1 of the patent application, wherein the wet composition comprises: a weight percent concentration of 86 to 98 deionized water ; Weight percentage concentration of calcium carbonate of similar active composition is 1 to 6; preservative with weight percentage concentration between one or more of 0 to 2; surfactant with weight percentage concentration between one or more of 0 to 2; (Poly) silicone emulsions with a weight percentage concentration between one or more of 0 to 1; photosensitive emulsions with a weight percentage concentration between one or more of 0 to 1; one weight percentage concentration between one and more than 0 to 0.3 A variety of flavors; soluble incense with a weight percentage concentration of one or more than 0 to 0.5. The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -------- ^- ------- (Please read the notes on the back before filling this page) 118 C: \ Eunice \ PK-〇〇l-〇7 \ PK-001-0734 \ PK-00l-0734-chi-cla -2- (ori-CWC) .doc 1237030 g8S '-----—________ 丨 丨. VI. Patent application materials; and p H adjustment with one or more weight percentage concentrations between one and more than 0 to 0.5 24. The wet wipe according to item 23 of the patent application, the wet composition of which comprises: weight percent Deionized water with a concentration of 86 to 98; · The weight percentage concentration of calcium chloride with similar active composition is from 丨 to 6; one or more preservatives from 0 to 2 weight percentage concentration, which include glycerol, methyl iodide Butyl urethane (IPBC), and bismethyl bismethyl = (DMDM) capsules; soil from 0 to 2 weight percent concentration of surfactant, which contains glutamate nitrate; from 0 to 1 weight percent concentration One or more (poly) siloxane preservatives comprising dimethyl alcohol and TEA; ', a photosensitive emulsion having a concentration of 0 to 1 weight percent, which comprises peg_75 Lanolin; one of a concentration of 0 to 0.3 weight percent One or more flavors; a soluble flavor having a concentration of 0 to 0.5 weight percent, which comprises polysorbate 20; and an acid-base regulator having a concentration of 0 to 0.2 weight percent, including malic acid. 25. The wet wipe according to item 24 of the patent application scope, the wet ingredients of which include: 92.88% by weight of deionized water; sodium carbonate similar to the active mixture and 4% by weight; 1 or more by weight of 1.00 A preservative containing glycerol, Ip B c, and DMDM capsules; the paper size applies the Chinese National Standard (CNS) A4 (210 X 297 mm) — —til — —! $ (Please read the first (Please note this item and fill in this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 119 C: \ Eunice \ ΡΚ-00Ί-07 \ ΡΚ-00Ί-0734 \ PK-001-0734-chi-cla-2- (ori -CWC) .d〇c Ϊ237030 A8 B8 C8 D8 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 120 c: ^ Eimice \ PK-〇〇j.07 \ PK ^, the percentage of the main patent application scope is 1 · 〇〇 Surfactant contains fluorenyl glutenate; one or more (poly) silicone photosensitive emulsions with a weight percentage of 5.00 include diethanol and TEA twelve surfactants; photosensitive emulsions with a weight percentage of 0.25 include peg_75 wool Fat; acid-base regulator of percentage 0.07 Containing malic acid. 2 6 · The wet wipe of item 1 of the patent application, wherein the fiber material comprises one or more layers of woven fibers, non-woven fibers, splicing fibers, or a combination thereof. 27. The wet wipe of item 丨 of the patent application, wherein the fibrous material comprises one or more layers of nonwoven fibers. ^ 28. The wet wipes according to item 1 of the scope of patent application, the length of the fibers contained in the fiber material is greater than 0 mm to 15 mm. 29. As for the wet wipes in item 1 of the patent application, the fiber material includes natural fibers, rayon, or a combination thereof. 30. As for the wet wipes in item 1 of the patent application scope, the fiber material includes one or more fibers, including cotton, linen, hemp fiber, wool, wood, pulp, rayon viscose, acetate fiber, poly Vinegar, polyamino compounds, and polyacrylic acid. 3 1. The wet wipes of item 1 of the patent application, the fiber material contains wood pulp and paper ^ 袼 '袼 01-0734 \ PK-001-0734-chi-cla-2- (ori-CWC) ---- ---- ^ --------- (Please read the precautions on the back before filling in this page) A8B8C8D8 Ϊ237030 ～ ^ __— VI. Patent application scope 32 · — Wet wipes, including: a fiber Materials; 勹 Adhesive contains a complete fabric that adheres to the fiber material, the adhesive = an acrylic terpolymer containing a sulfophthalate anion modified and non-interlaced knots, poly mouth (ethylene-vinyl acetate g purpose), where The sulfonate anionically modified acrylic dipolymer is formed from (a) at least one of acrylic acid and methacrylic acid, X and (b) —or more fluorenyl acrylates. The composition of the agent is insoluble in natural salt solution, which contains 1 to 5 weight percent of salt, the salt contains one or more monovalent ion and 4 adhesives in a composition containing 0 ppm to 200 ppm. , The water of a plurality of polyvalent ions is water-dispersible; and the genus composition contains an activity ranging from i to 1G weight percent concentration ingredient. 3 persons 3. If the wiper of the patent application range 32 items, its adhesive composition is water-separate in water containing one or more polyvalent ions of media :: ppm to 200 ppm 34. Such as patent application range 32 According to the item of the wet wipe, its adhesive composition is water-separate in water containing + = 5 to 15 Gppm-or more multivalent ions. 35. For example, the thirsty towel in Item 32 of the patent application, the composition with adhesive is contained in the medium; 15 ppm to! Water with one or more ppm of ions at ⑽ppm is water separable -------- ^ --------- (Please read the precautions on the back before filling this page) Use China National Standard (CNS) A4 ^ (21〇X297 公 f 消 1237030 Α8 Β8 C8 D8 六 、 Applicable patent scope 36 · Wet wipes such as patent application scope item 32, the adhesive composition of which contains between W ppm i 50 Ppm-or more polyvalent ion in water is ^ 37. The wet wipe of item 32 in the patent application scope, its adhesive composition is in water containing 0 or more than 10 ppm of multivalent ion Water-dispersible 0 38. The wipes as in item 32 of the patent application, the adhesive composition is insoluble in natural salt solution, which contains 1 to 3.0% by weight of salt &39; as in the scope of patent application The wipes of item 32, whose polyvalent ions include positive divalent ions, positive monovalent ions, positive valent monovalent ions, or a group of persons above. -------- 14 ---- ---- (Please read the notes on the back before filling out this page) Order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 40. In the wet wipe of item 32, the monovalent ion includes sodium, bell, potassium, ammonia ion, or a combination of the above. 41. The wet wipe of item 32 in the patent application scope, which is a sulfonate anion The modified acrylic terpolymer is composed of acrylic acid; 2-aminoacrylic acid 2-ethyl-1-propanesulfite (AMPS), 2-aminoacrylic acid 2-ethyl-1-propanesulfite sodium salt ( NaAMPS), or a combination of the above; butylacrylic acid; and 2-ethylhexylacrylic acid. This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) 122 C: \ Eunice \ ΡΚ-00Ί -07 \ ΡΚ-00Ί-0734 \ PK-001-0734-chi-cln-2- (on-CWC) .doc Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1237030 VI. Application for patent scope 42 · Wet wipes such as item 32 of the patent application scope, which are modified with sulfonate anions It is formed by 2-ethyl ethyl acetonitrile acrylamide (AMPS); 2-helium acrylic acid ethyl bis sulfite sodium salt (NaAMPS); and 2-ethylhexyl acrylic acid. 43. For example, the wet wipe of item 32 in the patent application, which is modified with a continuous acid salt anion <propionate terpolymer is formed from 35 to 80 mole percent of propionate, from 0 to 20 mol% 2-Arginoacrylic acid 2-ethyltrisulfite propionate (AMPS), 2-aminopropionic acid 4-ethylpropionite propionate sodium salt (NaAMPS), or the above Mixed; formed from 0 to 65 mole percent butylacrylphthalide; and formed from 0 to 45 mole percent ethylhexyl acrylic acid. 4 4 · The wipes according to item 43 of the patent application range, which are modified with a continuous acid salt anion (acrylic acid terpolymer is formed from 50 to 67 mole percent of propionic acid; from 0 to 1 0 mole percentage AMPS, NaAMps, or a combination thereof; consisting of 15 to 28 mole percentage butyl acrylic acid; and 7 to 15 mole percentage 2-ethylhexyl propyl It is composed of acetic acid. 牦 · As the wet wipe of item 44 in the scope of patent application, the propionic acid tripolymer modified with a continuous acid salt anion is formed from acrylic acid with a concentration of 57 to 66 mole%. To 6 mol% AMPS, NaAMPS, or the above-mentioned 'composed of 15 to 28 mol% butyl propionate; this paper size applies Chinese National Standard (CNS) A4 specification (210 ^^ 7 ^^ ------ 123 C'Eumce \ ΡΚ-00Ί-07 \ PK-001-0734 \ PK-OOl-〇734-chi-cla-2- (ori-CV \ I 1 — ·· I should 1 * — — 11111 I — illllllllllllllllllll — · (Please read the notes on the back before filling out this page) 1237030 A8 B8 C8 D8 The scope of the patent application is composed of 2 ethyl ethylhexylpropanoic acid with a concentration of 13 Wu Er. 46 'Wet wipes as described in item 45 of the patent application scope, which are propylene bismuth modified with sulfonate anion The polymer is formed from 60 mole percent acrylic acid; consisting of 5 mole percent AMps, NaAMps, or the above; 24.5 mole percent butyl acrylic acid; and 5 Molar percent concentration of 2-ethylhexyl acrylic acid. 47. The wet wipes of item 32 of the patent application, the composition of the adhesive contains 65 to 75% by weight of the sulfonate anion Modified acrylic terpolymer and 35 to 25 weight percent non-staggered chain polymerization (ethylene_vinyl acetate). &Lt; 48. Wet wipes such as patent application Fanyuan item 4/7, its adhesive The composition contains 75% by weight of a sulfonate anion-modified acrylic terpolymer and 25% by weight of non-interlaced polymerization (ethylene-vinyl acetate). 49. Wet as described in item 32 of the scope of patent application Towel whose fibrous material contains one or more layers of woven Fiber, non-woven fiber, splicing fiber, or a combination of the above. 50. For example, the wet tissue of item 49 in the scope of patent application, the fiber material contains one or more layers of non-woven fiber. This paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -------- ^ --------- ^. ^ 1 (Please read the notes on the back before filling this page) 124 c: \ Eunice \ PK- 〇〇1-〇7 \ PK-〇〇 ^ 〇734 \ PK-〇〇l-〇734-chi-cla-2- (ori-CWC) .doc Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Consumer Cooperatives 1237030 Six, Scope of patent application = · For example, the wet wipes of Item 49 of the patent application fan garden, the fiber material contains fibers' whose length is between more than 0 mm and 15 mm. Λ 52. The wet wipe according to item 32 of the patent application, which has a fiber material dimension, a rayon, or a combination thereof. …, 53. The wet tissue of item 52 of the patent application, the fiber material of which contains a variety of fibers, including cotton, linen, hemp fiber, wool, head, paper, rayon viscose, acetate fiber, Polyester, polyargon, and polyacrylic acid. 54. The wet tissue according to item 32 of the patent application, whose fiber material includes wood pulp. Each, ', 55. The wet wipe according to item 32 of the patent application scope, the wet composition of which comprises: a weight percent concentration of deionized water of 86 to 98; a weight percent concentration of calcium carbonate of a similar active composition is 1 to 6; weight Preservatives with a concentration of one or more than 0 to 2; Surfactants with a concentration of one to more than one to more than two; weight percent (poly) fat with one or more of more than 0 to one Oxygen-burning photosensitive emulsion; Photosensitive emulsion with a concentration of 1% or more in a weight percentage of 1 or more; Fragrances with a concentration of 1 or more in a weight percentage of 0 to 0.3; The paper size applies to Chinese National Standard (CNS) A4 specifications ( 210 X 297 mm) I! II a-^ il — Ι — — — »^ (Please read the notes on the back before filling this page) 125 C: \ Eunice \ ΡΚ-00Ί-07 \ PK-001- 0734 \ PK-001-0734-chi-cln-2- (〇ri-CWC) .d〇c 1237030 Α8 Β8 C8 D8 六 、 Applicable patent scope The main 1% concentration is between one or more than 0 to 0.5 Soluble fragrances; and (Please read the notes on the back first Complete this page) is greater than the weight percent concentrations of the mediator to-one in 050 or more pH adjusting agents. 5 6 · The wet wipe according to item 55 of the patent application scope, whose wet composition comprises: a weight percentage concentration of deionized water of 86 to 98; a weight percentage concentration of calcium carbonate of similar active composition is from 丨 to 6; from 0 to 2 weight percent concentration of one or more preservatives, which includes glycerol, cyanide, methylbutylcarbamate (IPBC), and bismethylbismethyl (DMDM) capsules; from 0 to 2 weight percent concentration Surfactant containing glutamate; one or more (poly) siliconium preservatives from 0 to 1 weight percent concentration, containing dimethyl alcohol and TEA; photosensitive emulsion from 0 to 1 weight percent concentration , Which contains PEG-75 Lanolin; one or more fragrances with a concentration of 0 to 0.3 weight percent; the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints soluble flavors with a concentration of 0 to 0.5 weight percent, which contains polysorbate 20; and Acid-base regulators from 0 to 0.2 weight percent concentration include malic acid. 57. The wet wipe according to item 56 of the patent application scope, the wet composition of which includes: deionized water with a weight percentage concentration of 9 ； 88; calcium chloride with a similar active composition has a weight percentage concentration of 4.00; this paper size applies Chinese national standards (CNS) A4 specification (210 X 297 mm) 126 C: \ Eunice \ ΡΚ-00Ί-Ο7 \ ΡΚ-ΟΟ1-Ο734 \ ΡΚ-ΟΟΊ-0734-ύιί-εΙπ-2- (οή-〇ν〇.ά 〇 € A8 B8 C8 D8 1237030 VI. The scope of application for patents is 1.00 weight percent concentration of ... or more preservatives, which include glycerol, iodized methylbutyl carbamate (IPBC), and bismethylbismethyl (DMDM) capsule; a surface rain active agent with a concentration of LOO in weight percent, which contains donkey acid salt; a concentration of 0.50% by weight with one or more (poly) stone oxo-fired preservatives, which contains dimethyl alcohol and TEA Photosensitivity emulsion from 0.25 weight percent, which contains pEG_75 Lanolin; one or more flavors from 0.05 weight percent; soluble flavors from 0.25 weight percent, which includes p〇iys〇rbate; 20; and respect by 0.0 7 miles percentage The test conditioner contains malic acid. 5 8.-A wet wipe comprising: a fiber comprising: 78 to 83 weight percent wood pulp, the fiber length of which is greater than 0 mm to 15 mm ; And the adhesive composition of 22 to 17 is applied hereto, and its adhesive composition contains 65 to 75% by weight of a sulfonate anion-modified acrylic terpolymer, which contains 60 mol% of Acrylic acid, 5 mole percent NaAMPS, 24.5 mole percent butyl acrylic acid, and 10.5 mole percent 2-ethylhexyl acrylic acid; and 25 to 35 weight percent non-interlaced links Polymerization (ethylene-vinyl acetate); and a wet composition containing: This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm IIIII 1® ^ illlll — ^ illl — ιί ^ (Please read the back Please fill in this page again for attention) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 127 C: \ £ Nn / ce \ PK-00l-07 \ PiC-003-0734 \ PK-002-0734-c / nc / n- 2- (on-CVVg.rf〇c '1237030 A8 B8 C8 D8 Range of weight percent concentration of deionized water of 92.88; Tongue of chlorine agent with similar active composition (please read the precautions on the back before filling out this page) The emulsified approximate concentration of the concentration is 4.00; One or more preservatives, which include glycerol methyl butylcarbamate, bismethylbismethyl (DMDM) capsules; a surface of 1. 00 weight percent An active agent, which contains glutamate; from 0.5 to 50 weight percent, and also has a very high ratio (one or more (poly) siloxane preservatives, which contains dimethyl alcohol and TEA; Photographic emulsion with a concentration of weight percent, which contains PEG-75 Lanolin; one or more flavors with a concentration of 0.05 weight percent; soluble flavors with a concentration of 0.25 weight percent, which contains polysorbatfe 20; and acid with a concentration of 100 kDa The alkali regulator contains malic acid. 59 · —A kind of wet wipes, which includes: a fiber material; an adhesive printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs contains an adhesive containing the fiber material to a complete fibrous substance, and the adhesive 含 contains a phosphonate anion Modified acrylic terpolymer and non-interlaced poly 5 (ethylene-vinyl acetate), wherein the sulfonate anionically modified acrylic dipolymer is at least one of acrylic acid and methacrylic acid, And (b)-formed by more fluorenyl acrylates; the composition of the adhesive is insoluble in natural salt solution, which contains salt to a concentration of tween percent; and the composition of this adhesive is substantially sodium-free From 128 CΛEI &lt; m'c ^^-00 ^ 07 \ PK-00 ^ 0734 \ PK-OO ^ o734.c / l ^ tg @ ii? &Quot; (CNS) A4 ^ (210 X 297 ^ 1237030 deg? G_ __ 6. The scope of patent application is full and all) 0 ppm Yongzhong with a ratio of calcium ions to magnesium ions of 2: i is water-dispersible, and its aqueous solution contains 50 ppm of one or more polyvalent ions; and A wet composition contains the active ingredient in a concentration of 1 to 10 weight percent. 60. A method of manufacturing a wet wipe, comprising: a fibrous material forming a fiber; applying an adhesive composition to the fabric, the adhesive composition comprising a sulfonate anion modified &lt; acrylic tripolymer and a non- Staggered chain polymerization (ethylene-vinyl acetate), wherein the sulfonate anionically modified acrylic terpolymer is composed of (a) at least one of acrylic acid and methacrylic acid, and one or more alkyl acrylates Formed; its adhesive is crudely insoluble in a natural salt solution, which contains a salt with a concentration of 1 to $ by weight, the salt contains one or more monovalent ions; and the composition of the adhesive is between 0 ppm and Water having one or more polyvalent ions of 200 ppm is water-dispersible; and a wet composition is applied to the fabric, wherein the wet composition contains the active ingredient at a concentration of from 10 to 10 weight percent. 61. The method of claim 60, wherein the adhesive composition is water-dispersible in water containing one or more polyvalent ions of 15 ppm to 200 ppm. 62. The method according to item 60 of the scope of patent application, the adhesive composition of which is contained in the paper standard applicable to the Chinese National Standard (CNS) A4 specification (0 × 297 mm 3 ^) · 1 --- 丨! — II in —--- ^ ---— — — — — (Please read the notes on the back before filling out this page) Printed by a member of the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 129 C: \ Eiinke \ PK-〇〇l -〇7 \ PK, 〇〇: &gt; Ί-〇734 \ PK-001-0734 &lt; hi-cla-2- (ori-CWC) .doc 1237030 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, such as one of 15 Ppm to 100 ppm of the patent application scope No. 60, the adhesive composition is contained. Rhenium ions are water-separate. 64. Such as 15 ppm to 50 ppm of the 60th in the scope of patent application-, its adhesive composition is: Water with a multivalent ion can be divided into water. 6 to 52 two patent applications, around the 60th 'its adhesive composition is contained. The water of PPW or multiple polyvalent ions is water-severable ^ 60. Of course, the salt solution contains 1 to 3.0% by weight of the concentrated solution. For the method of the 6th item in the scope of the patent, the polyvalent ion contains positive two仏 Calcium ion, normal divalent magnesium ion, ping ion, or a combination of the above. : 8. The method according to item 60 of the patent application, wherein the -valent ion includes a monovalent &lt; sodium, lithium, potassium, helium ion, or a combination thereof. 69. The method according to item 60 of the scope of patent application, which uses a continuous acid anion to modify the paper size to apply the Chinese National Standard (CNS) A4 specification (21〇 × 297 mm ΙΙΙΙΙΙ — — — — — — ililm ^ i — 1 — ίι — · ^ — ^ wi (Please read the notes on the back before filling out this page) 130 € ΛΕι1ίή ^ ΡΚ-ΟΟΊ-〇7 \ ΡΚ ^ 〇1.〇734 \ ρκ_〇〇Ί_〇734 ^ ^^^^ A8S8D8 ----------- ^ --------- (Please read the precautions on the back before filling out this page) Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1237030 ~ -------- VI. The patented scope of tri-propionic acid trimer is composed of propionic acid; 2 ~ helyl propionic acid 2-ethylammonium sulfite (AMPS), 2- Aminoacrylic acid-2 • Ethyl sodium bisulphite, sodium salt (NaAMPS), or a combination thereof; butyl acrylic acid; and ethyl ethylhexylpropanoic acid / kg are formed. '70. Such as the scope of patent application No. 6〇 Method, the acrylic terpolymer modified with a sulfonate anion is made of acrylic acid; 2-aminoacrylic acid_2_ethyl · pyalic acid propionate (AMPS), 2-helyl acrylic acid · 2_ It is formed by sodium salt of sodium trisulfite propylene (NaAMPS) and 2-ethylhexyl acrylic acid. 71. The method according to item 60 of the patent application, wherein the acrylic terpolymer modified with sulfonate anion is &amp; Formed from 35 纟 8G mole concentration of acrylic acid; from 0 to 20 mole% of 2-aminopropionic acid_2ethyl + sub-bowl · acid propionate (AMPS), 2-aminopropyl Acetic acid_2_ethyl_ 丨 _ sodium salt of propidium sulfite (NaAMPS), or a mixture of the above; formed from butyl acrylic acid at a concentration of 0 to 65 moles; and from 0 to 45 moles Percent concentration of 2-ethylhexyl acrylic acid. 72. The method according to item 71 of the patent application, wherein the triglyceride tripolymer modified with sulfonate anion is from 5G to 67 mole% Formed from 0 to οοmol% AMps, NaAMps, or the above; composed of 15 to 28mol% butyl acrylic acid, and from 7 to Mol Percent Concentration ❸2_Ethylhexylpropanoic acid. Paper-like degree_ Zhongguanjia Standard (CNS) A4 Specification (21Q x 297u ----- 131 C: \ Eumce \ ΡΚ-00Ί- 07 \ ΡΚ-00Ί-0734 \ PK-〇〇l.〇734-clv-cln-2- (ori-CWC) .doc ^ 37030 6. The scope of the patent application is printed by Qilang Wisdom Time Member X-Consumer Cooperation Li -------- ^ --------- (Please read the precautions on the back before filling this page ): 3 ', as described in the scope of patent application No. 72, which is modified with a sulfonate anion: the acrylic terpolymer is composed of 57 to 66 mole percent of propionate and water; 6 mol% concentration of amps, NaAMPS, or above; consisting of 15 to 28 mol% of butylpropionic acid, and 2 to 2% of 7 to 13 mol% Composed of Hexyl Acrylic. 4. The method according to the scope of patent application No. 73, which is modified by the sulfonate anion to &lt; the acrylic terpolymer is made of acrylic acid with a concentration of 60 mole percent; AMPS, NaAMps, or the above, consisting of 24.5 mole percent butyl acrylic acid; and 0.05 mole percent 2-ethylhexyl acrylic acid. 75. The method according to item 60 of the scope of patent application, wherein the composition of the adhesive comprises an acrylic terpolymer modified with a sulfonate anion at a concentration of 65 to 75 weight percent and a non-interlaced chain of 35 to 25 weight percent Polymerization (ethylene-vinyl acetate). 76. The method according to item 75 of the scope of patent application, wherein the composition of the adhesive comprises 75% by weight of an acrylic terpolymer modified with a sulfonate anion and 25% by weight of non-interlaced polymerization (B _ Vinyl acetate). 77. The method of claim 60, wherein the fiber material comprises one or more woven fibers, non-woven fibers, splicing fibers, or a combination thereof. This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 132 〇ΛΕί {ηΐ € 6 \ ΡΚ-〇〇 ^ 〇7 \ ΡΚ ~ 001.〇734 \ ΡΚ-00 ^^ 1237030 B8 C8 DB VI. Application scope of patent 78. As the method in the scope of the patent, the fiber material contains a layer of non-woven fiber. According to the method of the scope of patent application No. 77, the fiber material contains fiber, Cui /, and length ranging from 0 mm to 15 mm. : As the method of the scope of item 6G in the patent, the fiber material includes natural fiber, ′,, rayon, or a combination of the above. 81. The method according to item 80 of the patent application scope, wherein the fiber lining comprises one or more fibers, including cotton, linen, hemp fiber, wool, wood, paper, rayon, acetate, polyg , Polyamino compounds, and polyacrylic acid 82. The method of item 60 of the patent application scope, wherein the fibrous material comprises wood pulp. I —III --- 11-^ illlllli ^^ (Please read the notes on the back before filling out this page) Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 83. If the method of item 60 of the patent application park, Its wet composition contains: deionized water with a weight percent concentration of 86 to 98; a weight percent concentration of calcium chloride with a similar active composition is 1 to 6; weight percent is a preservative with a specific spread between one and more than 0 to 2 ; Surfactant with a concentration of one or more than 0 to 2 in weight percentage; (Poly) stone oxidized oxygen sensation at tensile concentration of one to more than one to more than one to more than tens of millimeters scale applicable to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 133 C: \ Eumce \ PK-00! -07 \ PK-001-0734 \ PK-0〇l-〇734-chi-cla-2- (on-CWC) .doc A8B8C8D8 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs --------------- (Please read the precautions on the back before filling out this page) Type of acid-base adjustment 1237030 6. Scope of patent application Light emulsion; weight percent concentration between 0 and 1 night, & 1 &lt; one or more photosensitive emulsion; weight percent ^ ^ ΛΛ ^ H υ · j &lt; one or more flavors with a concentration of greater than 0 to 〇3; soluble percentages of one or more soluble flavors with a concentration of greater than 0 to 0 s, ^ ^ ^ & v · 5; And weight percentage concentration between greater than 0 to 0 s, ^ ^ v J one or more doses. 84. According to the patent application No. 83, 廿 丄 sel is 86 to 98 wt% of deionized water; 1 to 6 wt% of sodium carbonate is used as an active compound. One or more than 0 to 2 wt% Preservatives for polydextrose, triethyl glycerol, IPBC and DMDM hyaluronic acid; more than 0 to 2 wt% of nitrogen-containing glutaric acid surfactant; greater than 0 to 1 wt% contains one or more dimethic〇n〇1 and dodecylbenzene sulfonate silicone emulsion; greater than 0 to 1 wt% softener containing PEG-75 refined wool, one or more aromas greater than 0 to 0.3 wt%; greater than 0 to 0.5 wt% containing poiysori3ate 20, an aroma solubilizer; and greater than 0 to 0.2% by weight of a pH adjuster containing malic acid. 85. The method according to item 84 of the scope of patent application, wherein the wet composition contains 92.88 wt% of deionized water; 4.00 wt% of sodium chloride as the active compound; This paper size applies the Chinese National Standard (CNS) A4 specification (21 〇 &gt;: 297 mm) 134 C: \ Eunice \ ΡΚ-001-07 \ ΡΚ-001-0734 \ ΡΚ-00Ί -0734-chi-cla-2- (ori-C ^ C) .doc 1237030 A8 B8 C8 D8 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ----------- ^ --------- (Please read the precautions on the back before filling this page) 6. Apply for a patent One or more preservatives containing glycerol, ipBc and DMDM hydantoin in the range of 1.00 vvt%; 1. 00 wt% surfactants containing aminoglutaric acid | 0.50 wt / 〇 one or more dimethiconol And TEA dodecylbenzene sulfonate of Shixi S with emulsion; 0. 25 wt% contains &gt; softener containing PEG-75 refined wool; 0.05 wt% of one or more aromas; 0.25 wt% of polysorbate 20 aroma solubilizer; And 0.07 wt% of a pH adjuster containing malic acid. 86 · A method for manufacturing a wet tissue, comprising: forming a fabric comprising: 78 to 83 wt% of a wood pulp having a fiber length of more than 0 mm to 15 mm; and using 22 to 1 7 wt% of a binder composition onto the fiber and drying it, the binder composition contains 65 to 75 wt% of a sulfur anion modified parent dimer and 25 to 35 wt% of a non-cross-linked poli (ethylene-vinyl acetate), this trimer contains 60 mol% acrylic acid, 5 mol% NaAMPS, 24.5 mol% butyl acrylate; and 10.5 mol% 2-ethylheyl acrylate; and uses a wet composition On the fabric, the wet composition contains: 92.88 wt% of deionized water; 4.00 wt% of sodium chloride as an active compound; 1.00 wt% of one or more glycerin, IPBC, and DMDM betaine urine paper size Applicable to China National Standard (CNS) A4 specification (210 χ 297 mm) 135 C: \ Eunice \ ΡΚ-00Ί-07 \ ΡΚ-00Ί-0734 \ PK-001-0734-chi-cla-2- (〇ri- CWC) .doc 1237030 A8 B8 C8 D8 6. Preservatives in the scope of patent application; 1.00 wt% Surfactant of aminoglutaric acid; 0.50 wt / 〇 的 Shi Xiyu emulsion with one or more dimethiconol and TEA dodecylbenzene sulfonate; 0.25 wt% softener containing PEG-75 guessed wool; 〇 · 〇5 wt% of one or more aromas; 0.25 wt% of an aroma dissolving agent comprising polySOrbate 20; and 0.07 wt% of a pH adjusting agent comprising malic acid. 87. The method according to claim 60 of the patent application, wherein at least one of the step of using an adhesive composition and the step of using a wet composition is a spraying step, a coating step, or a foaming step. — I— *! — 1 β! — · (Please read the notes on the back before filling in this page) The Ministry of Economic Affairs and Industry Cooperation of Employees of Huihui Industry Bureau printed this paper to apply the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 136 C; \ Eunice \ PK-001 -07 \ ΡΚ-00Ί-0734 \ ΡΚ-00Ί -0734-chi-da-2- (ori-CWC) .doc