TWI237062B - Method for modulating converter reducing slag of converter smelted stainless steel - Google Patents
Method for modulating converter reducing slag of converter smelted stainless steel Download PDFInfo
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- TWI237062B TWI237062B TW91124771A TW91124771A TWI237062B TW I237062 B TWI237062 B TW I237062B TW 91124771 A TW91124771 A TW 91124771A TW 91124771 A TW91124771 A TW 91124771A TW I237062 B TWI237062 B TW I237062B
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- 239000010935 stainless steel Substances 0.000 title claims abstract description 108
- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 108
- 239000002893 slag Substances 0.000 title claims abstract description 106
- 238000000034 method Methods 0.000 title claims abstract description 97
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 70
- 239000010959 steel Substances 0.000 claims abstract description 70
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 66
- 239000000463 material Substances 0.000 claims abstract description 42
- 229910052742 iron Inorganic materials 0.000 claims abstract description 33
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 28
- 238000007664 blowing Methods 0.000 claims abstract description 26
- 230000008569 process Effects 0.000 claims abstract description 25
- 238000010079 rubber tapping Methods 0.000 claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract 7
- 239000002184 metal Substances 0.000 claims abstract 7
- 239000004615 ingredient Substances 0.000 claims abstract 2
- 230000009467 reduction Effects 0.000 claims description 48
- 238000002844 melting Methods 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 28
- 238000007670 refining Methods 0.000 claims description 28
- 230000008018 melting Effects 0.000 claims description 27
- 238000003801 milling Methods 0.000 claims description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000004575 stone Substances 0.000 claims description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 12
- 238000003723 Smelting Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- 229910052804 chromium Inorganic materials 0.000 claims description 8
- 239000011651 chromium Substances 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 239000000395 magnesium oxide Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 238000009628 steelmaking Methods 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims 8
- 235000012239 silicon dioxide Nutrition 0.000 claims 8
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims 4
- 239000000292 calcium oxide Substances 0.000 claims 4
- 229940087373 calcium oxide Drugs 0.000 claims 4
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 241000219112 Cucumis Species 0.000 claims 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- 241001674048 Phthiraptera Species 0.000 claims 1
- KZNMRPQBBZBTSW-UHFFFAOYSA-N [Au]=O Chemical compound [Au]=O KZNMRPQBBZBTSW-UHFFFAOYSA-N 0.000 claims 1
- 229910052785 arsenic Inorganic materials 0.000 claims 1
- 235000019402 calcium peroxide Nutrition 0.000 claims 1
- 229910001882 dioxygen Inorganic materials 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910001922 gold oxide Inorganic materials 0.000 claims 1
- 238000007689 inspection Methods 0.000 claims 1
- 150000004767 nitrides Chemical class 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 238000011084 recovery Methods 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 239000012530 fluid Substances 0.000 abstract 1
- 239000011449 brick Substances 0.000 description 19
- 239000000956 alloy Substances 0.000 description 8
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000010436 fluorite Substances 0.000 description 7
- 230000006872 improvement Effects 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 239000000571 coke Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- -1 dolomitic Substances 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- KEIFWROAQVVDBN-UHFFFAOYSA-N 1,2-dihydronaphthalene Chemical compound C1=CC=C2C=CCCC2=C1 KEIFWROAQVVDBN-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910000604 Ferrochrome Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- IYNWNKYVHCVUCJ-UHFFFAOYSA-N bismuth Chemical compound [Bi].[Bi] IYNWNKYVHCVUCJ-UHFFFAOYSA-N 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Carbon Steel Or Casting Steel Manufacturing (AREA)
Abstract
Description
1237062 五、發明說明(i) "~—- 【發明領域】 本發明係關於一種轉爐煉製不銹鋼之轉爐還原渣調整 方法,特別係關於一種改變轉爐煉製不銹鋼之轉爐還原渣 特性,以增加其液化比率、改善轉爐上錐部(Upper 及出鋼口(Tapping Hole)下方爐磚爐渣結石現象、降低g 爐殘鋼量,使生產作業順暢的方法。 \ 【發明背景】1237062 V. Description of the invention (i) " ~ —- [Field of invention] The present invention relates to a converter reducing slag adjustment method for converter-refined stainless steel, and particularly relates to changing the characteristics of converter reducing slag for converter-refined stainless steel to increase The liquefaction ratio, a method for improving the slag stone formation phenomenon of the bricks under the upper cone of the converter (Upper and the tapping hole), reducing the amount of steel remaining in the g furnace, and making the production process smooth. [Background of the Invention]
請參考第1A〜1C圖,係顯示以轉爐煉製不銹鋼時的出 鋼過程;而以轉爐煉製不銹鋼時,須將含鉻、鎳、或其他 合金成份的氧化物的氧化渣作還原,以回收氧化渣中的合 金成分’而使第1 A圖所示轉爐1 〇 〇中之轉爐還原渣12〇具有 較高的熔點溫度而具有部份的固體成分;請參考第丨B圖, 隨著煉製的爐次增加,在出鋼的過程中,轉爐還原渣丨2 〇 的固體成分就逐漸沉積並累積在轉爐1 〇 〇的上錐部1 〇 5及出 鋼口 106下方而出現爐渣結石丨22,其所造成的負面影響如 第1C圖所示:(1)出鋼後,轉爐1〇〇内有大量的殘鋼112 (約1公"頓);(2 )出鋼時部份轉爐還原渣1 2 0隨著不銹鋼鋼 液11 0流出(未繪示於圖面),造成後製程精煉前扒渣量亦 隨之增加;上述兩者都會增加作業時間,增加轉爐煉鋼時 的成本。 而本發明之特徵之一,係提供種轉爐煉製不銹鋼之轉 爐還原渣調整方法,因此而改變轉爐煉製不銹鋼之轉爐還 原 >查特性’以增加其液化比率、改善轉爐上錐部(U ρ p e r Cone)及出鋼口(Tapping Hole)下方爐磚爐渣結石現象、Please refer to Figures 1A to 1C, which shows the tapping process when stainless steel is converted into a converter. When stainless steel is converted into a converter, the oxide slag containing oxides of chromium, nickel, or other alloys must be reduced to Recover the alloy components in the oxidized slag to make the converter reduction slag 12 in the converter 1000 shown in Figure 1A have a higher melting temperature and part of the solid content; please refer to Figure 丨 B, as The number of refining furnaces has increased. During the tapping process, the solid content of the converter reduction slag 丨 2 0 gradually deposits and accumulates under the upper cone 105 of the converter 1000 and under the tapping port 106, resulting in slag stone formation.丨 22, its negative impact is shown in Figure 1C: (1) After tapping, there is a large amount of residual steel 112 in the converter (about 1 kilometer "ton); (2) when tapping 1 2 0 of converter reduction slag flows with stainless steel molten steel 1 1 0 (not shown in the figure), resulting in an increase in the amount of slag pick-up before post-process refining; both of these will increase the operating time and increase the converter steelmaking time. the cost of. One of the features of the present invention is to provide a converter reducing slag adjustment method for converter-refined stainless steel. Therefore, the converter reduction of converter-refined stainless steel is changed > check characteristics to increase its liquefaction ratio and improve the converter upper cone (U ρ per Cone) and slag stone formation of the bricks under the tapping hole,
0109-8621TWF(N);dwwang.ptd 第5頁 1237062 五、發明說明(2) 降低轉爐殘鋼量,使生產作業順暢。 【先前技藝】 ^ hi參考第2圖,顯示一般轉爐煉製不銹鋼之流程。在 ::步驟20",係提供一轉爐,内有一含鐵熔銑,而轉 =種類可以是頂吹式轉爐、頂底同吹式轉爐、或複合型 =,在廢鋼投入2〗〇的步驟中,係於含鐵熔銑中加入回 、廢鋼。轉爐吹煉220之步驟,可再細分為升溫222、合 土入:224、與氧化渣還原226之步驟;在轉爐吹煉22〇之 =,1鐵熔銑的溫度為^⑽^〜125(rc,而轉爐吹煉12〇 ^ ’ 3鐵熔銑的溫度一般為168〇t〜17〇(pc,因此在升溫 ,係在含鐵熔銑中加入焦炭,並將氧氣吹入轉爐 中’發生下列反應: 2C + 〇2 ~>2C0+ 氧化熱 將含鐵熔銑的溫度提高至168〇t〜17〇〇χ:,同時也加 :石灰、氧化鎂、自雲石、及其他材料來作為造渣劑來造 而在合金入料224中,係加入高碳鉻鐵、及/或鎳鐵、 及/或其他合金材料來提供不銹鋼中鉻、鎳等合金成分, 使含鐵熔銑轉變為不銹鋼鋼液,而轉爐並持續吹氧,刀以 不銹=鋼液的溫度維持在168〇。〇〜17〇〇它;此時並在轉爐 中大里吹入一惰性氣體,以增加不銹鋼鋼液的攪拌功俨, 並且在下式 此’ 3C + Cr203 — 3C0 + 2Cr 中,因降低C0的分壓,促使反應向右移動而抑制鉻 化。接著在氧化渣還原226時,加入矽鐵或鋁粒來°作為還0109-8621TWF (N); dwwang.ptd Page 5 1237062 V. Description of the invention (2) Reduce the amount of converter residual steel and make production operations smooth. [Previous technique] ^ hi, refer to Figure 2, showing the general stainless steel refining process. In: Step 20 ", a converter is provided with an iron-containing melting and milling, and the type of the converter can be a top-blown converter, a top-bottom co-blow converter, or a composite type. Medium, is added in the iron-containing melt milling to add back, scrap steel. The steps of converter smelting 220 can be further subdivided into the steps of heating up 222, combining soil into: 224, and reducing slag by 226; in the converter smelting 22 ° =, the temperature of 1 iron melting and milling is ^ ⑽ ^ ~ 125 ( rc, while the temperature of converter melting 12〇 ^ '3 iron melting and milling is generally 1680t ~ 17〇 (pc, so in increasing temperature, coke is added in iron containing melting and milling, and oxygen is blown into the converter. The following reactions: 2C + 〇2 ~> 2C0 + heat of oxidation will increase the temperature of iron-containing fusion milling to 1680t ~ 1700x: and also add: lime, magnesia, dolomitic, and other materials as manufacturing materials Slag is used to make alloy feed 224. High-carbon ferrochrome and / or nickel iron and / or other alloy materials are added to provide alloy components such as chromium and nickel in stainless steel, so that iron-containing melt milling is transformed into stainless steel. The molten steel, while the converter continues to blow oxygen, the knife maintains the temperature of stainless steel = 1680. 00 ~ 1700; at this time and inert gas is blown into the converter to increase the stainless steel molten steel. Stir work, and in the following formula '3C + Cr203 — 3C0 + 2Cr, because the partial pressure of C0 is reduced, the reaction is promoted. Mobile suppressed chromium Next 226 upon oxidation reduction slag, or silicon iron aluminum shot was added to a further °
1237062 --------- 五、發明說明(3) 原劑’發生下列反應: 2Cr203 + 3Si ->4Cr + 3Si02 Cr203 + 2A1 ~>2Cr + Al2〇3 以回收氧化渣中之合金成分而轉變為轉爐還原渣。在轉爐 吹煉吹止230時,停止將氣體吹入轉爐中,此時在轉爐内· 的為不銹鋼鋼液與轉爐還原渣。出鋼2 4 〇時,將轉爐傾倒 ]R 〇 〜11 0 ° ,使不銹鋼鋼液流出,將轉爐還原渣留於轉爐 内。1237062 --------- V. Description of the invention (3) The following reaction occurred in the original agent: 2Cr203 + 3Si-> 4Cr + 3Si02 Cr203 + 2A1 ~> 2Cr + Al2〇3 to recover the oxide slag The alloy composition is converted into converter reducing slag. When the converter blowing and blowing stop 230, the gas blowing into the converter was stopped. At this time, the stainless steel molten steel and the converter reducing slag were in the converter. When the steel is tapped at 240, the converter is dumped] R0 ~ 110 ° to allow the stainless steel molten steel to flow out, and the converter reduction slag is left in the converter.
傳統上解決上述轉爐的上錐部及出鋼口下方出現爐 石現象為(1)以物理方法將轉爐吹煉溫度由原來的1 6 8 ( c 1 7 0 0 C提南為1 7 1 〇 °c〜1 7 3 0 °C以使轉爐還原渣液化; 2)以化學手段添加低熔點之螢石(Cah)作為助熔劑,來 降低轉爐還原渣之熔點與黏度(visc〇sity)。 =而’提高轉爐吹煉溫度會使轉爐内所使用之 例如爐襯耐火磚與底呤口啟榮m丄、土一, 人α a 士 低人〇口件專因加速溶損而減少其使用_Traditionally, to solve the furnace stone phenomenon under the upper cone part and the tapping hole of the above-mentioned converter is (1) physical conversion of the converter blowing temperature from the original 1 6 8 (c 1 7 0 0 C to 1 7 1 〇 ° c ~ 730 ° C to liquefy the converter reducing slag; 2) chemically add low melting point fluorite (Cah) as a flux to reduce the melting point and viscosity of the converter reducing slag. = 'Increasing the blowing temperature of the converter will make it used in the converter. For example, the furnace lining refractory bricks and Diolin mouth Qirong m 丄, Tu Yi, person α a person low person 0 mouth parts are reduced due to accelerated dissolution loss_
口ρ ’且會使不銹鋼鋼液中的哉I 輕旺成,而/备几: 與其他合金成份的氧化作 季乂旺盛,而在乳化渣還原226時, 紹粒等還原劑,更是加重了 太貝加入車父多的石夕鐵或 時間的增加,·而以添加低熔 :土擔與作業、保.Mouth ρ 'will make 哉 I in stainless steel liquid light and strong, and / prepare a few: Oxidation with other alloy components is strong for season 乂, and when the emulsified slag reduces 226, the reducing agent such as slag is aggravated. The increase in time for Taibei to join the driver ’s Shi Xitie or the increase in time, and to add low melting: soil burden and operation, security.
段’榮石會與上述爐襯耐火碑發炼,化學 降低上述爐襯耐火磚之你用軎=化學反應而將其溶損’ 擔與作業、保養時間的增加了〒,亦加重了生產成本的 而本發明之特徵之二,係 轉爐還原渣調整方法’在不增加;;ί二爐煉製不錄鋼: 卜菜,皿度,且不犧牲轉The section "Rong Shi will be refined with the above furnace lining refractory monument, and chemically reduce the above furnace lining refractory brick. You use 軎 = chemical reaction to dissolve it", which increases the operation and maintenance time, and also increases the production cost. The second feature of the present invention is that the reduction slag adjustment method of the converter is 'not increasing;' The second furnace does not record steel: vegetable, dish, and without sacrificing conversion
1237062 五、發明說明(4) 内所使用之耗材之使用壽命下,來改變轉爐煉製不銹鋼之 轉爐還原渣特性,以增加其液化比率。 【發明概述】 本發明之主要目的為提供一種轉爐煉製不銹鋼之轉姨 還原渣調整方法,因此而改變轉爐煉製不銹鋼之轉爐還^ 渣特性,以增加其液化比率,因而改善轉爐上錐部及出鋼 口下方爐磚爐渣結石現象、降低轉爐殘鋼量,進而使生 作業順暢。 本發明之另一目的為提供一種轉爐煉製不銹鋼之轉濟 ί:渣Γ ί方*,在不增加作業溫度’且不犧牲轉爐内; :用:耗材之使用壽命下,,文善轉爐上錐 斤 暢。 降低轉爐殘鋼量,進而使生產作業順 為了達成本發明之卜w θ 煉製不銹鋼之轉爐還原潰調整;法本供-種轉爐 鋼之製程中添加一含叙姑祖 法’係於一轉爐煉製不銹 鋼之製程中所產生的轉爐;原上述轉爐煉製不錢 不銹鋼之製程係包括··( 一、成刀,而上述轉爐煉製 銑;(b)於上述含鐵熔銑内加又二轉爐,内有一含鐵熔 對上述含鐵熔銑進行轉濟;^造潰劑與其他材料;(c) 二含鐵炼銑已成為—包含轉爐吹煉吹止’此時 及(e)出鋼。 壚遇原渣之不銹鋼鋼液丨以 【發明詳細說明】1237062 V. Description of the invention (4) In the service life of the consumables used in (4), the characteristics of the converter reduction slag of stainless steel made by the converter are changed to increase its liquefaction ratio. [Summary of the invention] The main purpose of the present invention is to provide a method for adjusting the reduction slag of converter-refined stainless steel. Therefore, the converter slag characteristics of converter-refined stainless steel are changed to increase its liquefaction ratio, thereby improving the upper cone of the converter. And the phenomenon of slag stone formation in the furnace bricks below the tap hole, reducing the amount of converter residual steel, thereby making the raw operation smooth. Another object of the present invention is to provide a conversion of stainless steel for converters: slag Γ ί square *, without increasing the operating temperature 'and without sacrificing the inside of the converter; use: the life of the consumables, Wenshan converter Cong Jinchang. Reduce the amount of converter residual steel, so that the production operation is in order to achieve the cost of the invention. W θ Reduction adjustment of converters for refining stainless steel; method for adding a type of converter steel to a converter process The converter produced in the process of refining stainless steel; the original process of refining stainless steel by the above converter includes: (1. a knife, and the above converter refining and milling; (b) adding the above-mentioned iron-containing fusion milling The second converter contains an iron-containing melt to convert the above iron-containing melt milling; ^ blasting agent and other materials; (c) the second iron-containing smelting and milling has become-including converter blowing and blowing stop 'at this time and (e) The stainless steel molten steel encountering the original slag 丨 [Detailed description of the invention]
本發明係於M w A 、轉爐練製不錢鋼時, --、不銹鋼鋼液添加 Μ 〇l〇9-862_(N);d_g 撕 第 頁The present invention relates to M w A and converter for making stainless steel, --- adding stainless steel molten steel 〇〇09-862_ (N); d_g
發明說明(5) =鋁材料(其化學成分如表工所示)1 2 原乂查二成分較好為:Al2〇3含量為5 w Kg,使轉爐還 =量比為 i.442、Mg0 含量 ❶:5 wu、Ca〇/ ί轉爐還原潰的性質例如溶點,使轉^二i5 Wt% ’以降 所佔的比率增加。咸少爐渣結石的2還中液態成分 襯耐火磚,請參考第3圖所示,以本 並斯•保護轉爐爐 鋼之轉爐還原渣調整方法之轉爐還原之轉爐煉製不銹 之轉爐煉製不錄鋼之轉爐還圍;而本 、煉製:鉻含量12 wt%以上的不銹鋼、式曰/:1^用於以轉 以上的含錄不錢鋼;其中上述含紹匕^量 Kg,而傳統上加入螢石以降低轉爐還原渣之.1 = 去’每噸不銹鋼鋼液需添加約4Kg的螢石,: 元/Kg。 八或本為約2· 3 表一本發,所使用之含鋁材料之,學成分(wt%)Description of the invention (5) = Aluminum material (its chemical composition is shown in tablework) 1 2 The original composition of the two components is preferably: Al2O3 content is 5 w Kg, so that the converter = volume ratio is i.442, Mg0 Content ❶: 5 wu, Ca〇 / ί The nature of converter reduction such as melting point makes the conversion ratio i5 Wt% increase with decreasing ratio. Refractory bricks lined with 2 liquid components of salty slag slag stones, please refer to Figure 3, and the stainless steel converter is smelted by the converter reduction method of the converter reduction method of the converter reduction slag that protects the converter steel. The converter that does not record steel is also surrounded; and the refining: stainless steel with a chromium content of 12 wt% or more, the formula /: 1 ^ is used for the above-mentioned non-reportable steel; where the above-mentioned content is Kg, Traditionally, fluorite is added to reduce the reduction slag in the converter. 1 = to remove about 4Kg of fluorite per ton of stainless steel molten steel: RMB / Kg. 8 or this is about 2 · 3 Table 1 this hair, the aluminum-containing material used, the chemical composition (wt%)
Ah〇3 A1+A1N Si〇2 MgO CaO 60 〜70 15 〜20 4〜5 2〜4 0〜2 請參考第4圖,係顯示與未添加含銘材料時比較,轉 爐還原渣初熔溫度變化與轉爐還原渣中A 12 03含量的關係。 在A1203含量5 wt %〜15 wt%,可以有效地降低轉爐還原渣 之溶點,使轉爐還原渣中液態成分所佔的比率增加,減少 爐渣結石的發生。Ah〇3 A1 + A1N Si〇2 MgO CaO 60 ~ 70 15 ~ 20 4 ~ 5 2 ~ 4 0 ~ 2 Please refer to Figure 4, which shows the change of the initial melting temperature of converter reducing slag compared with the case without adding material with inscription. Relationship with A 12 03 content in converter slag. The A1203 content of 5 wt% to 15 wt% can effectively reduce the melting point of converter reducing slag, increase the proportion of liquid components in converter reducing slag, and reduce the occurrence of slag stone formation.
0109-8621TWF(N);dwwang.ptd 第9頁 !237〇620109-8621TWF (N); dwwang.ptd Page 9! 237〇62
、發明說明(6) 添加廢^添2鋁材2的時機可以是:(1)轉爐吹煉前 轉游^煻1,5 、添加S鋁材料;(2)轉爐添加廢鋼後, 材含紹材料;(3)轉爐吹煉過程中添加含叙 【=例f批加入,視製程需要而定。 . 本發心1 f 所不一 一般轉爐煉製不銹鋼之流程,提出 法來作::二施例與三組傳統轉爐煉製不銹鋼之流程與方 =二增加作業溫度,且不犧牲轉爐内所使 原潰特性,以增加其液化不錄f 2爐還 :方爐磚爐渣結石現象、降低轉爐;ΐ上 暢的功效;而其他形式的轉Μ里’、使生產作業順 轉爐亦可適用。 如頂吹式轉爐或複合型 统轉爐煉製不鱗鋼之流程與方法。 (2) 對照組2 .傳統轉爐煉製不 以物理方法將轉爐吹煉溫度提高,,洲·私,、方法中, (3) 對照組3:傳統轉爐煉K1錄,〜1航。 以化學手段添加低炫點之螢石=鋼之流程與方法中’ 原渣之熔點與黏度,其中每噸不銹=,來降低轉爐還 ⑷第一實施例:以本發明之韓榦鋼::加入爾。 還原渣調整方法,於轉爐吹煉前添風煉製不錄鋼之轉爐 含鋁材料,來改變轉爐煉製不銹鋼1 一並加入一 • 褥爐還原潰特性,以2. Description of the invention (6) The timing of adding waste ^ Tim 2 aluminum material 2 can be: (1) conversion tour before converter blowing ^ 5 1,5, adding S aluminum material; (2) after adding scrap steel in the converter, the material contains Materials; (3) Adding narrative [= case f batch addition during converter blowing process, depending on process needs. The process of refining stainless steel in the general converter is not the same as that in Benfaxin 1f, and the following methods are proposed: Two examples and three groups of traditional converters for refining stainless steel. The second method is to increase the operating temperature without sacrificing the converter's interior. Make the original collapse characteristics to increase its liquefaction and not record the f 2 furnace also: the square furnace brick slag stone phenomenon, reduce the converter; shangchangchang the effect; and other forms of transfer M ', so that the production operation can be applied to the converter. Such as the top-blown converter or composite system converter to make non-scale steel processes and methods. (2) Control group 2. Traditional converter refining does not increase the temperature of the converter by physical methods. (3) Control group 3: Traditional converter refining K1, ~ 1 flight. In the process and method of adding low-dazzle fluorite = steel by chemical means, the melting point and viscosity of the original slag, of which each ton of stainless steel =, to reduce the converter also. First embodiment: The Korean dry steel of the present invention :: Add Seoul. Adjusting method of reducing slag, adding converter to make steel without recording steel before blowing in converter. Containing aluminum materials to change converter to make stainless steel. 1 Add one together.
1237062 五、發明說明(7) 增加其液化比率;其φ > lUKg。 母領不銹鋼鋼液加入含銘材料約 (5)第一實施例: 還原渣調整方法,於轉姨:二爐煉製不錄鋼之轉爐 來改變轉爐煉製不錄^轉 ^ ’加人一含銘材料, 請參考第5A~5CH鋼鋼入含紹材料約i”Kg。 二實施例調整轉爐還V、,二 轉爐500内有不銹铜鋼1 出鋼過程;請參考第5A圖, 鋼液510之上;接下來往’轉爐還原渣52〇浮於不銹鋼 調整後的轉爐還原;查52°月〇二,5B圖’在出鋼過程中,經 沒有爐渣結石的沉積;再么化△例增加,轉爐5〇〇内幾乎 少量的殘鋼512(約"噸)疼多♦第5C圖’出鋼後,僅有 上述五組實驗所d:;爐_内。 1 π <々細結果,如下列表2所示:1237062 V. Description of the invention (7) Increase its liquefaction ratio; its φ > lUKg. Add stainless steel liquid with female collar about (5) First embodiment: Adjusting method of reducing slag, Yu Zhuan: The second furnace does not record steel converter to change the converter does not record ^ transfer ^ '加 人 一For materials with inscriptions, please refer to the 5A ~ 5CH steel and steel into the material with about 1 ”Kg. The second embodiment adjusts the converter and V, the second converter 500 has stainless copper steel 1 tapping process; please refer to Figure 5A, Above the molten steel 510; next, go to the converter reduction slag 52o floated on the stainless steel adjusted converter; check 52 ° on February 5, 5B. During the tapping process, no slag stone deposition; △ Increase in cases, almost a small amount of residual steel 512 (about " ton) in the converter 500 is more painful ♦ Figure 5C 'After steelmaking, there are only the above five groups of laboratories d :; furnace_in. 1 π < Refine the results, as shown in Listing 2:
1237062 五、發明說明(8)1237062 V. Description of the invention (8)
表二實驗結果 對照組1 對照組2 對照組3 第一實施例 第二實施例 轉爐煉製茗度(ec) 1680〜1700 1710-1730 1680^1700 1680-1700 1680^1700 増加的焦炭成本(元/爐次) (相對於對照組1) 1500-25D0 0 0 0 投人螢石成本(元/爐次) 700-1200 投入含钻材科成本 (元/爐次) 1650 2500 煃襯耐火磚#命(爐次) 3000 2500 2600 3000 2900 平均耐火磚粍用成本 (元/爐次) 6700 8000 7700 6700 6900 増加的粍材成本(元/煃次) (相對於對眹鉍1) 2800-3800 1700-2200 1650 2700 煃渣結石清除迥期(爐次) 5 8 8 15 18 平均作業時間(分矮/爐次) (含因更換爐襯耐火磚、清除 爐渣結石之停機時間) 110 115 112 100 105 殘鋇董(嘴/爐次) 1 0.3 0.4 0.1 0.1 其中每爐約1 2 0噸不銹鋼鋼液;每更換一次轉爐的爐 襯耐火磚,耗材成本為約20000000元。 相對於對照組2、3,可使每爐次的殘鋼量由1公σ頓降Table 2 Experimental results Control group 1 Control group 2 Control group 3 First example Second example Converter refining degree (ec) 1680 ~ 1700 1710-1730 1680 ^ 1700 1680-1700 1680 ^ 1700 Increased coke cost (yuan / Furnace) (compared to the control group 1) 1500-25D0 0 0 0 Cost of fluorite investment (yuan / furnace) 700-1200 Cost of investment including drilling materials (yuan / furnace) 1650 2500 煃 lining refractory brick # Life (furnace) 3000 2500 2600 3000 2900 Average cost of refractory bricks (yuan / furnace) 6700 8000 7700 6700 6900 Increased cost of aerobium (yuan / furnace) (relative to bismuth bismuth 1) 2800-3800 1700 -2200 1650 2700 Slag stone removal period (furnace times) 5 8 8 15 18 Average operation time (short / furnace) (including downtime due to replacement of furnace lining refractory bricks and removal of slag stones) 110 115 112 100 105 Residual Barium Dong (mouth / furnace) 1 0.3 0.4 0.1 0.1 Of which about 120 tons of stainless steel molten steel per furnace; each time the furnace lining refractory brick of the converter is replaced, the cost of consumables is about 20 million yuan. Compared with the control group 2 and 3, the amount of residual steel per heat can be reduced from 1cm sigma
0109-8621TWF(N);dwwang.ptd 第 12 頁 1237062 五、發明說明(9) 至0 · 3〜0 · 4公噸’爐渣結石清除週期由5爐次延長為8爐 次’但本發明之第一與第二實施例更可以將每爐次的殘鋼 量降為約0 · 1公噸,爐渣結石清除週期更延長為丨5〜丨8爐 次’係達成了本發明之改善轉爐上錐部(Upper c〇ne)及出 鋼口(Tapping Hole)下方爐磚爐渣結石現象、降低轉爐殘 鋼量’進而使生產作業順暢之主要目的。 再者,如前所述,對照組2以物理方法將轉爐吹煉溫 度由原來的1 680 °C〜1 700 °c提高為171〇。〇173〇 〇c以使轉燐 還原渣液化,因爐襯耐火磚與底吹品件等因加速溶損而^ 少其使用壽命,使得爐襯耐火磚的壽命由對照組1的3〇〇〇 爐次,降低到2500爐次;而對照組3以化學手段添加低熔 點之螢石作為助熔劑,來降低轉爐還原渣之熔點與黏度, 亦使爐襯耐火碑的壽命降低到26〇〇爐次;而在本發明 一與第一 例中,爐襯耐火磚的壽命為29〇〇〜3〇〇〇燐 次’並未有明顯的負面影響,係達成本發明之改-錐部(Upper Cone)及出鋼口(Tapping H〇ie)下方爐磚& 結石現象、降低轉爐殘鋼量’進而使生 目的。 、切心为一 <1 法,=。:115达:广二^組係傳統的轉爐煉製不銹鋼之方 ' 刀里才能產出一爐約1 2 0噸的不銹鋼· 發,之轉爐煉製不錢銅之轉爐還原潰調整方法的實施 如在:述第一與第二實施例中,因達成了上述本發:之例 u:以將每爐次平均作業時間降低為1〇〇1〇5;目 達成了增加轉爐的作業效率、增加單位時間的產出量V附0109-8621TWF (N); dwwang.ptd Page 121232705 V. Description of the invention (9) to 0 · 3 ~ 0 · 4 metric tons 'The slag stone removal cycle is extended from 5 to 8 times', but the first of the present invention According to the first and second embodiments, the residual steel amount per heat can be reduced to about 0.1 metric tons, and the slag stone removal period is further extended to 5 to 8 heats, which achieves the improvement of the upper cone of the converter of the present invention. The main purpose is to reduce the amount of residual steel in the converter, and to reduce the amount of residual steel in the converter. In addition, as described above, the control group 2 physically increased the converter blowing temperature from 1 680 ° C to 1 700 ° C to 171 °. 〇173〇c to liquefy the transition reduction slag, because the furnace lining refractory bricks and bottom-blown products due to accelerated dissolution loss and reduce their service life, so that the life of the furnace lining refractory bricks from the 3,000 furnaces of the control group 1. The control group 3 added low-melting fluorite as a flux by chemical means to reduce the melting point and viscosity of the reducing slag of the converter, and also reduced the life of the furnace lining refractory monument to 2600 times. However, in the first and first examples of the present invention, the life of the furnace lining refractory bricks is 2900 to 300,000 times. There is no obvious negative impact, which is a modification of the invention-Upper Cone and Upper Cone. The furnace brick & stone formation phenomenon under the tapping hole, reduces the amount of steel in the converter, and further achieves the purpose. , Tangent is one < 1 method, =. : 115 Da: Guang Er ^ is a traditional converter for refining stainless steel. Only about 120 tons of stainless steel can be produced in the knife, and the converter's reduction method for refining copper can be implemented. For example, in the first and second embodiments described above, because the above-mentioned present invention is achieved: Example u: To reduce the average operating time per furnace to 1005; the objective is to increase the operating efficiency of the converter, Increasing output per unit time
0109-8621TWF(N);dwwang.ptd 第13頁 1237062 五、發明說明(10) 加利益。 另外,在製程改善成本方面,對照組2以物理方法將 ,爐吹煉溫度由原來的1 680 °c〜1 70 0 °c提高為1710 t〜1730 °C以使轉爐還原渣液化,不但因爐襯耐火磚壽命的減少, 使母爐平均耐火磚成本由約6700元提高至約8qqq元,再輪 爐吹煉過程中更必須投入更多的焦炭來作升溫,使得每姨 次的焦炭投入成本增加了 1 5 0 0〜250 0元,在耗材方面,必μ 須多付出每爐次28 00〜3800元的改善成本;而對照組3 學手段添加低熔點之螢石作為助熔劑,來降低轉爐還原渣 之熔點與黏度,亦因爐襯耐火磚壽命的減少,使^芈= 耐火磚成本由約6700元提高至約77〇〇元,而所二二 成本為每爐次700〜1200元,在杯好方而 、、的營石 υ ^ 隹耗材方面,必須吝朴山益咏 次1700〜2200元的改盖成太•品士、 、 母爐 tμ@ 成本,本發明之轉爐煉製不銹鋼 ,轉爐遝原產調整方法的實施,例如在上述第 錄又 ,例中隨所投入的含銘材料成本每爐次為16 5〇第一貝 付出每爐次1 650〜2700元的改盖成太,愈义才方面,必須多 兩種傳統的改善方法比如," 一刖述對照組2、3 爐還原渣調整方法的者=毛明之轉爐煉製不銹鋼之轉 2,而與對照組3相當具::力:的改善的成本低於對照組 爐還原潰調整方;“實::=:;爐煉製不錢鋼之轉 ’遠遠勝於對照組2、3兩4 述與上 帶來的改善成果,係读士 哥、元的改善方法所 更優異改善成果的另 ^程改善成本的付出,換取 ^ 附加利益。0109-8621TWF (N); dwwang.ptd Page 13 1237062 V. Description of the invention (10) Plus benefits. In addition, in terms of process improvement costs, the control group 2 physically increased the furnace blowing temperature from 1 680 ° c to 1 70 0 ° c to 1710 t to 1730 ° C to liquefy the converter reduction slag. The reduction in the life of the refractory bricks of the furnace lining has increased the average refractory brick cost of the mother furnace from about 6,700 yuan to about 8 qqq yuan. In the round furnace blowing process, more coke must be invested to raise the temperature, making the cost of each coke investment Increased 1550 ~ 2500 yuan. In terms of consumables, μ must pay an additional improvement cost of 2800 ~ 3800 yuan per heat; while the control group added 3 low-melting fluorite as a flux to reduce the cost. The melting point and viscosity of the converter reducing slag also reduces the life of the refractory bricks of the furnace lining, so that the cost of refractory bricks is increased from about 6700 yuan to about 77000 yuan, and the cost of the second and second furnaces is 700 ~ 1200 yuan per furnace. In terms of consumables, good and easy to use, it is necessary to change the price of Pu Shan Yi Yongci from 1700 to 2200 yuan to cover the cost of the goods. • The master furnace, tμ @ cost. , The implementation of converter 遝 origin adjustment method, such as in the above According to the example, with the cost of the materials with the inscriptions in the example, the cost is 1650 per furnace. The first shellfish costs 1,650 ~ 2700 yuan per furnace, and it is rebuilt into the Taiyuan. In terms of righteousness, two more traditional improvements are required. For example, "quote who describes the adjustment method of the reduction slag in the control group 2 and 3 = Mao Mingzhi's converter 2 for stainless steel refining, which is quite equivalent to the control group 3: the cost of improvement is lower than that of the control group Furnace reduction and adjustment method; "Real :: = :; The transformation of the furnace to make money without steel" is far better than the control group 2, 3, 2 and the improvement results brought by the above, which is the improvement of Shige and Yuan The method is more cost-effective in terms of improving the results and paying for additional benefits.
1237062 五、發明說明(11) 雖然本發明已以較佳實施例揭露如上,然其並非用以 限定本發明,任何熟習此技藝者,在不脫離本發明之精神 和範圍内,當可作些許之更動與潤飾,因此本發明之保護 範圍當視後附之申請專利範圍所界定者為準。1237062 V. Description of the invention (11) Although the present invention has been disclosed in the preferred embodiment as above, it is not intended to limit the present invention. Anyone skilled in the art can make some changes without departing from the spirit and scope of the present invention. Changes and retouching, therefore, the protection scope of the present invention shall be determined by the scope of the appended patent application.
0109-8621TWF(N);dwwang.ptd 第15頁 1237062 圖式簡單說明 為讓本發明之上述和其他目的、特徵、和優點能更明 顯易懂,下文特舉出較佳實施例,並配合所附圖式,作詳 細說明如下: 【圖式之簡單說明】 第1 A〜1 C圖為一系列剖面圖,.用以說明習知以轉爐煉 製不銹鋼時的出鋼過程。 第2圖為一流程圖,用以說明一般轉爐煉製不銹鋼之 流程。 第3圖為一CaO-Si〇2-Al2〇3- 15wt%Mg0多元相圖,用以 說明本發明之轉爐還原渣的組成範圍。 第4圖為一線性座標圖,用以說明與未添加含鋁材料 時比較,本發明之轉爐還原渣初熔溫度變化與轉爐還原渣 中A 12 03含量的關係。 第5A〜5C圖為一系列剖面圖,用以說明本發明一較佳 實施例實施後的不銹鋼出鋼過程。 【符號說明】 1 0 0〜轉爐; 1 0 1〜底吹口; 1 0 2〜爐底; 1 0 3〜下錐部; 1 0 4〜爐腹; 1 0 5〜上錐部; 1 06〜出鋼口; 1 0 7〜爐口;0109-8621TWF (N); dwwang.ptd Page 15 1237062 Brief description of the drawings In order to make the above and other objects, features, and advantages of the present invention more comprehensible, the following exemplifies preferred embodiments and cooperates with all The drawings are described in detail as follows: [Brief description of the drawings] Figures 1A to 1C are a series of cross-sectional views, which are used to explain the tapping process when the stainless steel is conventionally made by a converter. Fig. 2 is a flow chart for explaining the general stainless steel refining process. Fig. 3 is a CaO-Si〇2-Al2O3- 15wt% Mg0 multiphase diagram, which is used to illustrate the composition range of the converter reduction slag of the present invention. Fig. 4 is a linear coordinate diagram for illustrating the relationship between the change in the initial melting temperature of the converter reducing slag and the content of A 12 03 in the converter reducing slag compared with the case where no aluminum-containing material is added. Figures 5A to 5C are a series of cross-sectional views for explaining the stainless steel tapping process after the implementation of a preferred embodiment of the present invention. [Symbol description] 100 ~ converter; 10 ~ 1 ~ bottom mouth; 10 ~ 2 ~ bottom; 10 ~ 3 ~ lower cone part; 104 ~~ hearth; 10 ~ 5 ~ upper cone part; 1 ~ 06 ~ Tapping port; 107 ~ furnace port;
0109-8621TWF(N);dwwang.ptd 第16頁 1237062 圖式簡單說明 11 0〜不銹鋼鋼液; 11 2〜殘鋼; 1 2 0〜轉爐還原渣; 1 2 2〜爐渣結石; 2 0 0〜開始步驟; 2 1 0〜廢鋼投入; 2 2 0〜轉爐吹煉; 2 2 2〜升溫; 224〜合金入料; 2 2 6〜氧化渣還原; 2 3 0〜轉爐吹煉吹止; 240〜出鋼; 30 0 〜CaO-Si02-Al2 03 -15wt%Mg0 多元相圖; 3 5 0〜本發明之轉爐還原渣的組成範圍; 50 0〜轉爐; 5 0 1〜底吹口; 5 0 2〜爐底; 5 0 3〜下錐部; 5 0 4〜爐腹; 5 0 5〜上錐部; 506〜出鋼口; 507〜爐口; 5 1 0〜不銹鋼鋼液; 5 1 2〜殘鋼;0109-8621TWF (N); dwwang.ptd Page 16 1237062 Brief description of the drawing 11 0 ~ Stainless steel steel; 11 2 ~ Residual steel; 1 2 0 ~ Converter reduction slag; 1 2 2 ~ Slag calculus; 2 0 0 ~ Start steps; 2 1 0 ~ Scrap steel input; 2 2 0 ~ converter blowing; 2 2 2 ~ temperature rise; 224 ~ alloy feed; 2 2 6 ~ oxide slag reduction; 2 3 0 ~ converter blowing stop; 240 ~ Tapping; 30 0 ~ CaO-Si02-Al2 03 -15wt% Mg0 multivariate phase diagram; 3 5 0 ~ composition range of converter reducing slag of the present invention; 50 0 ~ converter; 5 0 1 ~ bottom mouth; 5 0 2 ~ Furnace bottom; 5 0 3 ~ lower cone; 5 0 4 ~ furnace belly; 5 5 5 ~ upper cone; 506 ~ steel outlet; 507 ~ furnace mouth; 5 1 0 ~ stainless steel liquid; 5 1 2 ~ residual steel;
0109-8621TWF(N);dwwang.ptd 第17頁 1237062 圖式簡單說明 520〜轉爐還原渣 5 2 2〜爐渣結石。0109-8621TWF (N); dwwang.ptd Page 17 1237062 Brief description of the drawing 520 ~ converter reduction slag 5 2 2 ~ slag calculus.
IBI 0109-8621TWF(N);dwwang.ptd 第18頁IBI 0109-8621TWF (N); dwwang.ptd Page 18
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