TWI226374B - High strength multi-component alloy - Google Patents
High strength multi-component alloy Download PDFInfo
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- TWI226374B TWI226374B TW092116847A TW92116847A TWI226374B TW I226374 B TWI226374 B TW I226374B TW 092116847 A TW092116847 A TW 092116847A TW 92116847 A TW92116847 A TW 92116847A TW I226374 B TWI226374 B TW I226374B
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 77
- 239000000956 alloy Substances 0.000 title claims abstract description 77
- 229910052802 copper Inorganic materials 0.000 claims abstract description 30
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 66
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 32
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 29
- 239000010949 copper Substances 0.000 claims description 29
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 21
- 239000010941 cobalt Substances 0.000 claims description 15
- 229910017052 cobalt Inorganic materials 0.000 claims description 15
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims 1
- 229910052776 Thorium Inorganic materials 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 abstract description 32
- 229910052804 chromium Inorganic materials 0.000 abstract description 21
- 229910052782 aluminium Inorganic materials 0.000 abstract description 14
- 238000013461 design Methods 0.000 abstract description 9
- 239000011651 chromium Substances 0.000 description 20
- 238000012360 testing method Methods 0.000 description 11
- 239000000470 constituent Substances 0.000 description 8
- 229910000601 superalloy Inorganic materials 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 229910000531 Co alloy Inorganic materials 0.000 description 2
- -1 Iron cobalt nickel chromium copper aluminum Chemical compound 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910017767 Cu—Al Inorganic materials 0.000 description 1
- 229910000997 High-speed steel Inorganic materials 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 229910001315 Tool steel Inorganic materials 0.000 description 1
- ZATYNPNTYABVCY-UHFFFAOYSA-N [Co].[Cu].[Fe].[Cr].[Ni] Chemical compound [Co].[Cu].[Fe].[Cr].[Ni] ZATYNPNTYABVCY-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000012669 compression test Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000007542 hardness measurement Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/02—Alloys containing less than 50% by weight of each constituent containing copper
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Adornments (AREA)
- Laminated Bodies (AREA)
Abstract
Description
1226374 五、發明說明（1) 【發明所屬之技術領域】 本發明是關於一種多元合金，特別是關於一種可在高 溫使用之高強度多元合金。 【先前技術】 所謂的合金是指「一種金屬和另一種或者一種以上的 金屬或非金屬互相融合，而具有金屬的各種性質之物 質」。由兩種成分混合製成的合金稱為兩元合金，同理， 由多種成分混合的合金成之為多元合金。傳統上實用合金 系統的開發，皆以一至兩種元素為主要組成元素，以鐵元 素為主，即為一般的鋼鐵材料，如合金鋼、工具鋼和高速 鋼等。或以銘元素為主，則為發展相當成熟之铭合金。廣 泛使用於各領域之超合金材料，則有鐵基合金、鈷基合 金、錄基合金之分。上述之合金成份，主成分的元素皆佔 合金組成原子百分比的4 0 %以上，再依不同的特性需求， 加入其他的輔助元素。 上述之合金設計理念顯然限制了合金成分的自由度， 勢必也會限制合金性能的發展。目前使用於高溫環境的合 金，其種類常依使用溫度高低來選擇，例如碳鋼或低合金 鋼適合使用於攝氏3 7 0度以下、耐熱不銹鋼則通常使用於 攝氏4 2 5度以下。原因為此類合金的強度會隨著溫度升高 而快速劣化，尤其溫度超過攝氏5 0 0度時，其降伏強度大 多低於2 0 0 MPa，而造成使用上的諸多限制。另一種常使用 於高溫者為超合金，超合金可使用於攝氏540度以上，在 一定溫度範圍内，超合金的強度可隨溫度升高不會劣化，1226374 V. Description of the invention (1) [Technical field to which the invention belongs] The present invention relates to a multicomponent alloy, and particularly to a high-strength multicomponent alloy that can be used at high temperatures. [Prior art] The so-called alloy refers to "a metal and another or more than one metal or non-metal are fused with each other and have the various properties of the metal". An alloy made of a mixture of two components is called a binary alloy. In the same way, an alloy made of a mixture of multiple components is a multicomponent alloy. Traditionally, the development of practical alloy systems has one or two elements as the main constituent elements, and iron elements as the main components, which are general steel materials, such as alloy steel, tool steel, and high-speed steel. Or the main element is Ming, which is a fairly mature Ming alloy. Superalloy materials widely used in various fields include iron-based alloys, cobalt-based alloys, and base-based alloys. In the above alloy composition, the main component elements all account for more than 40% of the alloy composition atomic percentage, and other auxiliary elements are added according to different characteristics. The above-mentioned alloy design concept obviously limits the degree of freedom of the alloy composition, and will certainly limit the development of alloy properties. At present, the types of alloys used in high temperature environments are often selected according to the use temperature. For example, carbon steel or low alloy steel is suitable for use below 370 ° C, and heat-resistant stainless steel is usually used below 425 ° C. The reason is that the strength of such alloys will deteriorate rapidly with increasing temperature, especially when the temperature exceeds 500 degrees Celsius, its drop strength is much lower than 200 MPa, which causes many restrictions on use. Another type often used at high temperatures is superalloys. Superalloys can be used above 540 degrees Celsius. In a certain temperature range, the strength of superalloys will not deteriorate with temperature.
1226374 五、發明說明（2) 常使用之超合金有鎳基和钻基兩類，其中鎳基超合金被廣 泛應用於需要高強度的高溫元件合金，鈷基合金在攝氏 73 0度至11 00度的條件下，仍具有一定的高溫強度。這類 合金經鍛造處理其降伏強度在攝氏8 0 0度可維持在40 0Mpa 以上。超合金的合金設計理念還是「以單一元素為主要組 成元素」，其主要組成元素，如錄或始，含量約為4 5 %至 7 5 % ，並且再添加絡、始、鎳、鉬、鎢、銳、銘、鈦、 鐵、錳、矽、碳、硼、鍅和釩等6至1 0種次元素來進行改 質’使其能夠增進各種性能以達到南溫使用的目的。這種 以單一元素為主的合金設計思考方式，所可能產生的組合 及發展已到了相當成熟的階段，如欲再提昇其高溫性質亦 很難再有所突破。 【發明内容】 為了製造具有優良高溫使用性質的合金，本發明提供 一種由多種元素所組合而成的高強度多元合金，其跳脫了 傳統合金設計架構，多元合金所包含的每一種主要元素分 別佔總組成的5 %至3 5 %原子百分比，同時高強度多元合 金在高溫下具有高強度的特性。 為達上述目的，本發明之高強度多元合金係以鐵、 I古、錄、鉻、銅和銘作為主要元素，其中，每一種元素分 別佔合金總組成的5 %至3 5 %原子百分比。並且，經過實 際的測試證明，高強度多元合金在高溫下具有優異的高強 度性質。多元合金提供了合金設計上更大的自由度，同時 其成分比例可以針對所需之各種不同性質來加以調整和改1226374 V. Description of the invention (2) Nickel-based and diamond-based superalloys are commonly used. Nickel-based superalloys are widely used in high-temperature component alloys that require high strength. Cobalt-based alloys range from 7300 to 1100 ° C. Under the conditions of temperature, it still has a certain high temperature strength. After forging, this type of alloy can maintain a drop strength of more than 400 MPa at 800 degrees Celsius. The alloy design concept of superalloys is still "with a single element as the main constituent element". Its main constituent elements, such as recording or starting, contain about 45% to 75%, and further add complexes, starting, nickel, molybdenum, tungsten , Sharp, Ming, Titanium, Iron, Manganese, Silicon, Carbon, Boron, Samarium and Vanadium, etc., to be modified by 6 to 10 kinds of sub-elements. This kind of single-element-based design thinking of alloys, the possible combination and development has reached a fairly mature stage, and it is difficult to make further breakthroughs if you want to further improve its high temperature properties. [Summary of the Invention] In order to manufacture an alloy with excellent high-temperature use properties, the present invention provides a high-strength multi-component alloy composed of a variety of elements, which breaks away from the traditional alloy design framework. It accounts for 5 to 35 atomic percent of the total composition. At the same time, high strength multicomponent alloys have high strength characteristics at high temperatures. In order to achieve the above object, the high-strength multi-component alloy of the present invention uses iron, iron, copper, chromium, copper, and metal as the main elements. Among them, each element accounts for 5 to 35 atomic percent of the total composition of the alloy. Moreover, after actual tests, the high-strength multicomponent alloy has excellent high-strength properties at high temperatures. Multiple alloys provide greater freedom in alloy design, and their composition ratios can be adjusted and modified for various different properties required
1226374 五、發明說明（3) 變。而本發明即根據多元合金的設計理念，找出適於應用 在高溫環境下的高強度多元合金的成分組合。 本發明更包含一種高強度多元合金，其包含原子百分 比各為1 3 %至1 9 %的鐵、鈷、鎳、鉻、銅元素，以及5 % 至3 5 %的鋁元素。此外，高強度多元合金的製造可藉由習 知的合金製造和冶鍊技術來加以完成，例如電子溶解法、 感應熔解法、電弧熔解法、電漿熔解法、電子束熔解法、 粉末冶金法和機械合金法或組合上述方法以進行金屬炫鍊 和合金合成，並且可在大氣氣氛、保護氣氛或真空等環境 下完成。 為使對本發明的目的、構造特徵及其功能有進一步的 了解，茲配合圖示詳細說明如下： 【實施方式】 本發明係應用多元合金設計理念，以鐵、鈷、鎳、 鉻、銅和鋁作為主要元素，並使每一種元素分別佔合金總 組成的5 %至3 5 %原子百分比，以組成具有優良高溫性質 的高強度多元合金： 請參考表1，其為本發明第一實施例至第三實施例的 成分比例表。 表11226374 V. Description of the invention (3) Changes. According to the design concept of the multicomponent alloy, the present invention finds a combination of components of a high-strength multicomponent alloy suitable for application in a high temperature environment. The invention further comprises a high-strength multicomponent alloy, which contains iron, cobalt, nickel, chromium, copper, and aluminum in an atomic percentage of 13% to 19%, and aluminum in an amount of 5% to 35%. In addition, the manufacture of high-strength multi-component alloys can be completed by conventional alloy manufacturing and chain smelting techniques, such as electron dissolution, induction melting, arc melting, plasma melting, electron beam melting, and powder metallurgy. And mechanical alloy method or combination of the above methods for metal chain and alloy synthesis, and can be completed in the atmosphere, protective atmosphere or vacuum and other environments. In order to further understand the purpose, structural features and functions of the present invention, detailed descriptions are given in conjunction with the drawings as follows: [Embodiment] The present invention applies a multi-alloy design concept to iron, cobalt, nickel, chromium, copper and aluminum As the main elements, make each element 5% to 35% atomic percentage of the total composition of the alloy to form a high-strength multicomponent alloy with excellent high-temperature properties: Please refer to Table 1, which is the first embodiment to Table of component ratios of the third embodiment. Table 1
1226374 五、發明說明（4) 合金編號 組成元素含量比例（原子百分比％) ' η 鐵 鈷 鎳 鉻 銅 ~——^ 鋁 第一實施例 18.2 18.2 18.2 18.2 18.2 ---^, 9 第二實施例 16.7 16.7 16.7 16.7 16.7 16.1^ 第二實施例 14.3 14.3 14.3 14.3 14.3— 本發明之第一實施例係取鐵、鈷、鎳、鉻、銅、銘+ 種元素，其組成元素含量比例為鐵、鈷、鎳、鉻、銅佔' 1 8 · 2 % (原子百分比），鋁佔9 °/〇(原子百分比）。 本發明之第二實施例係取鐵、鈷、鎳、鉻、銅、銘& 種元素，其組成元素含量比例為鐵、鈷、鎳、鉻、銅佔 1 6 . 7 % (原子百分比），鋁佔1 6 . 5 % (原子百分比）。 本發明之第三實施例係取鐵、鈷、鎳、鉻、銅、銘& 種元素，其組成元素含量比例為鐵、鈷、鎳、鉻、鋼佔、 1 4 · 3 % (原子百分比），鋁佔2 8 · 5 % (原子百分比）。 刀別依第一實施例至第三實施例的元素含量比例，將六牙重 凡素配成總重約2 0 0 0公克之原料，利用真空感應熔解爐將 原料溶解之後，澆鑄於銅模中固化成鑄錠，再利用機械加 工的方式把鑄錠製成直徑1 〇毫米、高丨5毫米的圓柱形試° 棒。1226374 V. Description of the invention (4) Alloy number composition element content ratio (atomic percentage%) 'η Iron cobalt nickel chromium copper ~ —— ^ Aluminum First Embodiment 18.2 18.2 18.2 18.2 18.2 --- ^, 9 Second Embodiment 16.7 16.7 16.7 16.7 16.7 16.1 ^ Second Embodiment 14.3 14.3 14.3 14.3 14.3 — The first embodiment of the present invention takes iron, cobalt, nickel, chromium, copper, and + elements, and the composition element content ratio is iron, cobalt , Nickel, chromium, and copper account for '18 · 2% (atomic percentage), and aluminum accounts for 9 ° / 〇 (atomic percentage). The second embodiment of the present invention takes iron, cobalt, nickel, chromium, copper, Ming & elements, and the composition element content ratio is iron, cobalt, nickel, chromium, copper accounts for 16.7% (atomic percentage) Aluminium accounts for 16.5% (atomic percentage). The third embodiment of the present invention takes iron, cobalt, nickel, chromium, copper, Ming & elements, and the composition element content ratio is iron, cobalt, nickel, chromium, steel, 14 · 3% (atomic percentage ), Aluminum accounts for 28.5% (atomic percentage). According to the element content ratio of the first embodiment to the third embodiment, the knife is made of raw materials with a total weight of about 2,000 grams. The raw materials are dissolved in a vacuum induction melting furnace and then cast into a copper mold. It is solidified into an ingot in the middle, and then the ingot is made into a cylindrical test bar with a diameter of 10 mm and a height of 5 mm by mechanical processing.
使用維氏硬度機M a t s u z a w a S e i k i Μ V - 1量測試棒的η v 硬度值’量測前試棒表面先經碳化矽砂紙依序以丨8 〇 #、 g4〇 #、4 0 0 #、6 0 0 #、8 0 0 #、12〇〇 # 磨平，施加荷重為 士斤，下針速度為70微米/秒，負荷時間為2〇秒，每一合Use Vickers hardness tester Matsuzawa S eiki Μ V-1 to measure the η v hardness value of the test rod. Before the measurement, the surface of the test rod was first passed through silicon carbide sandpaper in order with 8 〇 #, g4〇 #, 4 0 0 #, 6 0 0 #, 8 0 0 #, 12〇〇 # Grind, apply a load of jin, lower needle speed is 70 microns / second, load time is 20 seconds, each combination
12263741226374
金皆量測七點並取其平均值，第一實施例至第三每 硬度值分別為HV2 0 8、HV4 0 6及HV5 6 6。 貝、⑦列之Jin Jie measured seven points and took the average value. Each of the first to third hardness values was HV208, HV406, and HV56. Shelley
使用Gleeble 2〇〇〇a金屬熱加工模擬機對於一奋> 例至第三實施例的試棒進行高溫壓縮測試，以得貝， dfset降伏強度數據。其測試方式係以每秒攝氏“度0 (°C /sec)的升溫速率將試棒加溫至測試溫度後，維持^ 兩分鐘使其均溫。再以應變速率丨0^、測試溫度介於皿攝^ 氏3 0 0度至1 2 0 0度的條件進行測試。其結果如第】圖所示， 其為本發明第一實施例至第三實施例之降伏強度對溫度的 關係圖。本發明實施例之高強度多元合金係設定相同的 鐵、鈷、鎳、鉻、铜元素含量，僅調整鋁含量。比較第一 實施例至第三實施例的結果可發現降伏強度隨著鋁含量的 增加而上升，其’則4溫度在攝氏8 〇 〇度之内的降伏強度均 大於400MPa。因此，本發明更包含一種高強度多元合金， 其包含原子百分比各為1 3 %至1 9 %的鐵、鈷、鎳、鉻、銅 元素，以及5 %至3 5 %的銘元素。A Gleeble 2000a metal thermal processing simulator was used to perform high-temperature compression tests on the test rods of the Fen > example to the third example to obtain the dfset drop strength data. The test method is to heat the test rod to the test temperature at a temperature increase rate of "degree 0 (° C / sec) per second" and maintain it for ^ two minutes to make it uniform. Then use the strain rate 丨 0 ^, the test temperature The test was performed at a temperature of 300 degrees to 120 degrees in a dish. The results are shown in the figure. It is a graph of the relationship between the drop intensity and the temperature of the first to third embodiments of the present invention. The high-strength multi-component alloy of the embodiment of the present invention sets the same content of iron, cobalt, nickel, chromium, and copper elements, and only adjusts the aluminum content. Comparing the results of the first to third examples, it can be found that the drop strength with the aluminum As the content increases, its dropout strength is greater than 400 MPa at a temperature of 800 degrees Celsius. Therefore, the present invention further includes a high-strength multi-component alloy, which contains 13% to 19% of each atomic percentage. % Iron, cobalt, nickel, chromium, copper, and 5% to 35% of the elements.
其中’第一實施例在測試溫度在攝氏3〇〇度至8〇〇度之 間時’其降伏強度並無明顯變化，並不隨著溫度上升而大 幅下降。第二實施例以攝氏9 〇〇度進行測試時，其降伏強 度仍大於40 0MPa。第三實施例甚至以攝氏丨丨〇〇度進行測試 時，其降伏強度仍維持4〇〇MPa以上。由上述結果顯示本發 明之高強度多凡合金具有優異的高溫機械性能，並且超越 傳統的耐熱不銹鋼和多種超合金，另再固定五種主要元素 成分，逐一改、炎鐵、姑、錄、鉻和銅的元素成分比，以作Among them, when the test temperature is between 300 ° C and 800 ° C in the first embodiment, the drop intensity does not change significantly, and does not decrease significantly with the temperature rise. When the second embodiment is tested at 900 degrees Celsius, the drop-down strength is still greater than 400 MPa. In the third embodiment, even when the test was performed at a temperature of 1100 ° C, its drop strength was maintained above 400 MPa. The above results show that the high-strength Dover alloy of the present invention has excellent high-temperature mechanical properties, and surpasses traditional heat-resistant stainless steel and a variety of superalloys. In addition, five main element components are fixed, and the iron, iron, iron, chromium, chromium And copper's elemental composition for
1226374 五、發明說明（6) 表2為本發明第四實施例至 為第四實施例至第八實施例 第八實施例的成分比例表： 表2 合金編號 組成元素含量比例（原子百分比％ ) 鐵 鈷 鎳 鉻 銅 鋁 第四實施例 9 18.2 18.2 18.2 18.2 18.2 第五實施例 18.2 9 18.2 18.2 18.2 18.2 第六實施例 18.2 18.2 9 18.2 18.2 18.2 第七實施例 18.2 18. 2 18.2 9 18.2 18.2 第八實施例 18.2 18.2 18.2 18.2 9 18.2 本發明之第四實施例 種元素，其組成元素含量 1 8. 2 % (原子百分比），鐵 本發明之第五實施例 種元素，其組成元素含量 1 8. 2 % (原子百分比），鈷 本發明之第六實施例 種元素，其組成元素含量 1 8 · 2 % (原子百分比），鎳 本發明之第七實施例 種元素，其組成元素含量 1 8. 2 % (原子百分比），鉻 本發明之第八實施例 係取鐵、録、錄、鉻、銅、紹六 比例為始、鎳、絡、銅、铭佔 佔9 % (原子百分比）◦ 係取鐵、銘、錄、絡、銅、ί呂六 比例為鐵、錄、絡、銅、ί呂佔 佔9 % (原子百分比）。1226374 V. Description of the invention (6) Table 2 is the composition ratio table of the fourth embodiment to the eighth embodiment of the fourth embodiment to the eighth embodiment of the invention: Table 2 Alloy element composition ratio (atomic percentage%) Iron cobalt nickel chromium copper aluminum fourth embodiment 9 18.2 18.2 18.2 18.2 18.2 fifth embodiment 18.2 9 18.2 18.2 18.2 18.2 sixth embodiment 18.2 18.2 9 18.2 18.2 18.2 seventh embodiment 18.2 18.2 18.2 9 18.2 18.2 eighth Example 18.2 18.2 18.2 18.2 9 18.2 The element of the fourth embodiment of the present invention has a constituent element content of 18.2% (atomic percentage), and the element of the fifth embodiment of the present invention has a constituent element content of 18. 2% (atomic percentage), cobalt is an element of the sixth embodiment of the present invention, and its constituent element content is 18 · 2% (atomic percentage), nickel is the seventh embodiment of the present invention, and its constituent element content is 18. 2% (atomic percentage), chromium The eighth embodiment of the present invention is based on the ratio of iron, iron, copper, chromium, copper, and copper, and nickel, iron, copper, and copper account for 9% (atomic percentage). Take iron, Ming , Lu, Luo, Copper, and Lu Lu The proportion is iron, Lu, Luo, Copper, and Lu Lu accounting for 9% (atomic percentage).
係取鐵、鈷、鎳、鉻、銅、鋁六 比例為鐵、钻、鉻、銅、铭佔 佔9 % (原子百分比）◦ 係取鐵、始、錄、鉻、銅、ί呂六 比例為鐵、钻、錄、銅、銘佔 佔9 % (原子百分比）。 係取鐵、鈷、鎳、鉻、銅、鋁六The ratio of iron, cobalt, nickel, chromium, copper, and aluminum is iron, diamond, chromium, copper, and the proportion of 9% (atomic percentage). ◦ The ratio of iron, iron, chromium, copper, and aluminum is calculated. For iron, drill, record, copper, Ming accounted for 9% (atomic percentage). Based on iron, cobalt, nickel, chromium, copper, and aluminum
第9頁 1226374 五、發明說明（7) 種元素，其組成元素含量比例為鐵、鈷、鎳、鉻、鋁佔 1 8. 2 % (原子百分比），銅佔9 % (原子百分比）。 採用相同於第一實施例至第三實施例之硬度量測法所 的硬度值如表3所列。 表3 合金編號 維氏硬度值 第四實施例 HV418 第五實施例 HV473 第六實施例 HV423 第七實施例 HV367 第八實施例 HV458 由此可看出第四實施例至第五實施例的硬度值皆高於 第一實施例Η V 2 0 8，顯而易見以此合金組成在相當的範圍 内仍具有很高的強硬度。 此外，根據本發明的多元合金設計理念，在六種主要 成分元素之外，更可根據不同性質需求添加4. 5 % (原子百 分比）以下之次元素，如銦、鐵、銳、錯、组、銃、鈦、 鈒、猛、硼、碳、氣、石夕等來進行改質。其第九至第十四 實施例如表4所示。 1226374 五、發明說明（8) 合金編號 組成元素含量比例（原子百分比％ ) 鐵 銘 鎳 鉻 銅 鋁 次元 素 硬度 第九實施例 17.5 17.5 17.5 17.5 17.5 8.8 3. 5硼 HV347 第十實施例 17.5 17.5 17.5 17.5 17.5 8. 8 3. 5矽 HV266 第十一實施例 17.5 17.5 17.5 17.5 17.5 8.8 3· 5!目 HV220 第十二實施例 18.5 18.5 18.5 18.5 18.5 5.6 1.9碳 HV210 第十三實施例 27.8 13.9 13.9 13. 9 13.9 13.9 2. 7碳 HV287 第十四實施例 15.9 15.9 31.8 15.9 8 8 4. 5碳 HV305 雖然本發明之較佳實施例揭露如上所述，然其並非用 以限定本發明，任何熟習相關技藝者，在不脫離本發明之 精神和範圍内，當可作些許之更動與潤飾，因此本發明之 專利保護範圍須視本說明書所附之申請專利範圍所界定者 為準。Page 9 1226374 V. Description of the invention (7) The proportion of its constituent elements is iron, cobalt, nickel, chromium, aluminum accounting for 18.2% (atomic percentage), and copper accounting for 9% (atomic percentage). The hardness values by the same hardness measurement methods as in the first to third embodiments are shown in Table 3. Table 3 Vickers hardness value of the alloy number The fourth embodiment HV418 The fifth embodiment HV473 The sixth embodiment HV423 The seventh embodiment HV367 The eighth embodiment HV458 The hardness values of the fourth to fifth embodiments can be seen Both are higher than the first embodiment (V 2 0 8), and it is obvious that the alloy composition still has a very high hardness in a considerable range. In addition, according to the multi-alloy design concept of the present invention, in addition to the six main component elements, secondary elements below 4.5% (atomic percentage) can be added according to different property requirements, such as indium, iron, sharp, wrong, and group. , Hafnium, titanium, hafnium, fierce, boron, carbon, gas, Shi Xi, etc. to modify. The ninth to fourteenth embodiments are shown in Table 4. 1226374 V. Description of the invention (8) Alloy number composition element content ratio (atomic percentage%) Tie Ming Ni-Cr Cu-Al secondary element hardness Ninth embodiment 17.5 17.5 17.5 17.5 17.5 8.8 3. 5 Boron HV347 Tenth embodiment 17.5 17.5 17.5 17.5 17.5 8. 8 3.5 Silicon HV266 Eleventh embodiment 17.5 17.5 17.5 17.5 17.5 18.8 8.8 3 · 5! Mesh HV220 Twelfth embodiment 18.5 18.5 18.5 18.5 18.5 5.6 1.9 Carbon HV210 Thirteenth embodiment 27.8 13.9 13.9 13 9 13.9 13.9 2. 7 carbon HV287 fourteenth embodiment 15.9 15.9 31.8 15.9 8 8 4. 5 carbon HV305 Although the preferred embodiment of the present invention is disclosed above, it is not intended to limit the present invention, any familiarity related The artist may make some modifications and retouching without departing from the spirit and scope of the present invention. Therefore, the scope of patent protection of the present invention must be determined by the scope of the patent application attached to this specification.
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| TWI298661B (en) * | 2005-12-30 | 2008-07-11 | Ind Tech Res Inst | Multi metal base hardfacing alloy |
| TWI315345B (en) * | 2006-07-28 | 2009-10-01 | Nat Univ Tsing Hua | High-temperature resistant alloys |
| CN101717969A (en) * | 2009-12-18 | 2010-06-02 | 中国铝业股份有限公司 | Alloy material suitable for inert anode of metal fused-salt electrolysis cell |
| CH705750A1 (en) * | 2011-10-31 | 2013-05-15 | Alstom Technology Ltd | A process for the production of components or portions, which consist of a high-temperature superalloy. |
| CN103667943B (en) * | 2013-11-14 | 2016-03-09 | 安徽荣达阀门有限公司 | A kind of pump impeller is with containing scandium wear-resisting low-carbon steel and preparation method thereof |
| CN104152803A (en) * | 2014-07-24 | 2014-11-19 | 苏州通力电气有限公司 | Corrosion-resistant submerged pump impeller |
| CN104372230B (en) * | 2014-10-15 | 2017-01-11 | 华南理工大学 | High-strength high-toughness ultrafine-grained high-entropy alloy and preparation method thereof |
| CN104818418B (en) * | 2015-05-20 | 2017-10-24 | 安徽工业大学 | A kind of many pivot Laves base intermetallic compounds and preparation method thereof |
| CN107739956B (en) * | 2017-09-14 | 2019-10-29 | 北京理工大学 | A kind of Nb microalloying Ni-Co-Fe-Cr-Al high-entropy alloy |
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| CN115537683B (en) * | 2021-06-30 | 2024-03-12 | 叶均蔚 | High-strength corrosion-resistant ferrochrome block and application thereof |
| US11846356B1 (en) | 2021-08-18 | 2023-12-19 | Vulcan Industrial Holdings, LLC | Self-locking plug |
| US12510164B1 (en) | 2021-08-18 | 2025-12-30 | Vulcan Industrial Holdings, LLC | Sleeved fluid end |
| US12140240B1 (en) | 2022-01-19 | 2024-11-12 | Vulcan Industrial Holdings, LLC | Gradient material structures and methods of forming the same |
| US12297922B1 (en) | 2022-03-04 | 2025-05-13 | Vulcan Industrial Holdings, LLC | Valve seat with embedded structure and related methods |
| US11434900B1 (en) | 2022-04-25 | 2022-09-06 | Vulcan Industrial Holdings, LLC | Spring controlling valve |
| US11920684B1 (en) | 2022-05-17 | 2024-03-05 | Vulcan Industrial Holdings, LLC | Mechanically or hybrid mounted valve seat |
| CN115233075B (en) * | 2022-07-29 | 2023-02-14 | 大连理工大学 | A kind of ultra-high-strength toughness high-entropy alloy, its preparation method and application |
| USD1061623S1 (en) | 2022-08-03 | 2025-02-11 | Vulcan Industrial Holdings, LLC | Fluid end for a pumping system |
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| SE516137C2 (en) * | 1999-02-16 | 2001-11-19 | Sandvik Ab | Heat-resistant austenitic steel |
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