_麟錢纖I纖寒響驅I擊發· 戀議8^1||麵績議_||議^1|_|議 1297369 玖、發明說明 【發明所屬之技術領域】 本發明是有關於一種紡纖製品之表面處理法，且特 是有關於一種製造具有單一或複合機能之紡纖製品的 法0 【先前技術】 隨著人們對於紡織製品有不同功能性的要求，紡織 品單純提供保暖的功能已無法滿足消費者的需求。紡織 業不斷開發出一些功能性的紡織品，例如可以提供撥水 抑菌或親水（吸濕）等單一或複合機能之紡纖製品。 具有撥水功能的纺織品係將具有撥水功能的材料塗 於織品的外表面，而具有親水（吸濕）功能的紡織品係將 有親水（吸濕）功能的材料塗佈於織品的内表面，至於具 抑菌功能的紡織品則是將具有抑菌功能的材料塗佈於織 的表面。 將這些不同的材料分別塗佈於相同或不同的表面上 會有塗佈不均和塗佈層不夠牢固因而抗水洗不佳的問題 習知揭露了解決塗佈層不夠牢固因而抗水洗不佳的問題 方法，例如中華民國專利公告號第429280號揭露，使 微波電漿將纖維製品之表面活化，於產生自由基後，再 單體接枝聚合形成官能基，以賦予纖維製品特定的親水 功能；又如日本公開專利特開平11-256476號揭露採用 溫電漿處理方式，進行針梭織物或不織布的單面改質， 別 方 製 工 佈 具 有 品 常 〇 的 用 與 性 低 以 1297369 獲得具有表裡 13-159074 號 連續處理進行 裡異機能性之 有下述的缺點 以改質，進而 應必須在真空 氣壓電漿方式 導入含氦氣或 加工，大約需 里產處理。 異機能性之製品；再如曰 揭露採用大氣壓電漿處理 針梭織物或不織布的單面 製品。利用能源照射方法 •第一、利用低溫電漿將 賦予纖維製品特定機能性 狀態下進行，設備成本昂 進行處理的話，在接枝加 氬氣的混合氣體、氮氣及 要24〜36小時，故難以 本公開 方式， 改質， 進行單 纖維製 功能的 貴；第 工時需 丙烯酸 進行快 專利特開平 經8小時的 以獲得具表 面改質，具 品之表面予 方法，其反 二、採用大 分數次分另lj 等方可完成 速的連續式 另外又如世界專利公告號w〇02〇75〇38則揭露應用 提高藥劑黏度的方法抑制藥劑滲透而達成單面塗佈之功 月b ’但此傳統塗佈或網版轉印加工製程缺點如下：第一、 右採用一般傳統的塗佈加工流程，為了讓機能性藥劑單面 塗佈於織物的單面上，將必須提高該藥劑的黏度，容易造 成作業的不穩定性；第二、一般傳統的塗佈加工製程，藥 劑的塗佈量必須在30-200g/m2之範圍，難以進行超薄塗佈® 處理’加工基布易受限，而在在30-2 〇〇g/m2的塗佈量下， 、纺織品的柔軟性會受到影響；第三、為了提高藥劑粘度加 入如增稠劑或隔離劑等中間體，易使紡纖製品產生水潰 痕；第四、因為不易雙面塗佈，所以難以有複合化功能性。、· 因此，如何將具有不同功效的塗佈材料有效的分別塗 · 佈於紡織品的上下兩面而使紡織品具有複合化功能性，而 1297369 且還可維持紡織品的柔軟度與舒適性並且可耐水洗，是— 個亟待解決的問題。 【發明内容】 據上所述，本發明係提供一種紡纖製品之表面處理 法’可以有效的形成至少一極薄的功能性塗佈層於織品的 表面，而得到一牢靠耐水洗且具有單一或複合機能之 製品。 規 本發明之目的係提供一種紡纖製品之表面處理法，選 擇使用具有架橋基之聚合物形成具有不同功能，例如撥 水、抑菌或親水（吸濕），的塗佈液，分別利用凹版塗佈表 面處理技術，適度選擇凹槽形狀和雕刻輪的網目數，分別 將不同功能和劑量（粘度，濃度，厚度）之藥劑利用連二塗 佈的加工技術，塗佈於紡纖製品的表面，經過加熱乾燥等 架橋方式，分別使功能性藥劑產生架橋反應固著於紡纖 °口進而分別產生具有單面撥水，另一面抑菌％ 等單面功能化纺纖製品。 親水（吸濕） 、本發明之另一目的係提供一種紡纖製品之表面户 法’採用凹版塗佈方式，可利用、網目數任意調整：处 性化學藥劑的枯度，濃度和薄塗厚度等變冑，在加 : 等架橋方式，使功能性化學藥劑在紡纖製品:：： 生架橋，不僅乾燥加工快速’而且大大提昇纺纖製 機能的耐水洗堅牢度。 複a 本發明之又-目的係提供一種紡纖製品之表面處理 1297369 法，利用凹版塗佈處理 數，功能性藥劑的粘度 佈的厚度。 技術選擇凹槽形狀和雕刻輪的網目 ’濃度（固含量）等任意調整藥劑塗 目的係提供一種紡纖製品之表面處理 法=凹版塗佈處理方式，可直接調整掌控各種功能性 化二柰塗佈在紡纖製品表面的劑量和厚度，使功能性化 學藥劑能均勻塗佈到紡纖製品的表面，在不同表面之功能 獨立而不相互影響。 、本發明之再又一目的係提供一種紡纖製品之表面處理 法無肩事先進行任何表面活化或改質等前置作業，也無 須處理的程序’即能在纺織品表面形成具有撥水，抑菌和 親水（吸濕）等單一或複合機能的塗佈層，節省設備投資， 減少此源和人力的耗費。 本發明所揭露之紡纖製品之表面處理法，可以對紡織 品的表面進行改質，係將具有功能性之化合物組成形成塗 ^液’其中包括具有架橋基之聚合物，例如環氧基，雙鍵（如 壓克力基’烯基等），異氰酸酯，矽氧烷基（sHane)，次乙 亞胺基（aziridine或ethyleneimlne)，醇基，有機酸等架 橋基聚合物之功能性添加物。針對在紡織品上欲形成之塗 佈層所需求的功效所添加之功能性添加物，包括撥水劑、 有機兩分子含四級胺鹽官能基之抑菌劑或含多醇基或醚基 戈有機I鹽類之親水劑等多種的功能性藥劑，其中撥水劑 可以為石蠟、聚矽烷系或氟化物等等。塗佈液的黏度視所 而开> 成塗佈層的厚度而定。特別的是，本發明所揭露的紡 1297369 纖製品之表面處理法不受塗佈液的黏度的限制 黏度的塗佈液（粘度在1000 )， ^ ^ ^ ^ ^ 丨J…、肩使用增稠劑調 m:版網目(選擇凹槽形狀和雕刻輪)，即 此達成均勻薄層塗佈的目的。紡織品可以為針 不織布等纖維結構之化織物。 因此，本發明提供一種超薄凹版塗佈方式， 所形成具有撥水，菌和親水(吸濕)等 力月,的塗佈液塗佈於紡纖製品的表面，經由加献 Φ n二:r力能性成分固著於紡纖製品的單面或局部上木 製品。本發明…η函及吸濕等複合機能紡纖 <摩用μ: 般習知衣料領域產製品外，亦 此控料/要表面撥水之鞋材、皮包等基材用布。且在 此技術平σ下預期將可應用於包 =產:r處理法將可大幅提升產製品==ΐ 一產成本、進而提升產業價值與競爭力。 降 【實施方式】 ^了讓本發明所提供之纺纖製品之表面處理 方：文特舉實施例，來詳細說明如何運用本發明 優:。…並進-步由測試結果之揭露來瞭解本發明之 :參，第！圖，第’圖係緣示本發明所揭露之 佈式表面處理母供士立m 四版塗 1Ω. 叹備不忍圖。凹版印刷設備100至少包括— 槽體102、一凹版印刷滾輪（Q_「e ρm — 10 1297369 106及導輪108、110。選擇使用具有架橋基之聚合物形成 、 具有不同功能，例如撥水、抑菌或親水（吸濕），的塗佈液 112，放置於一具有開口的槽體1〇2中，其中塗佈液ία 所使用的溶劑可以為醇類或水。凹版印刷滾輪1 〇4設置於 、 槽體1 02的上方，而壓輪1 06設置於凹版印刷滾輪1 04的 側邊。需要進行表面處理的紡織品11 4經由導輪1 〇8的導 引進而穿過凹版印刷滾輪1 04與壓輪1 06之間，紡織品彳巧4 再經由導輪110的導引而進入一烘乾設備（未繪示於圖上） 進行烘乾膠聯的製程。紡織品11 4的厚度約介於〇·5毫米 至2毫米之間，其重量則介於約每公尺1 50〜300公克 (g/m )之間。紡織品11 4在設備上移動的速度在每分鐘2 〜1 〇公尺（m/miη )之間。烘乾設備一般係採用加熱烘乾 的方式，而加熱烘乾的溫度一般約介於攝氏80度至200 度之間。_ 麟 纤 纤 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I The surface treatment method of spun fiber products, and especially a method for manufacturing a spun fiber product having a single or composite function. [Prior Art] As people have different functional requirements for textile products, textiles simply provide warmth function. It has been unable to meet the needs of consumers. The textile industry has continued to develop functional textiles such as single or composite functional textiles that provide water bacteriostatic or hydrophilic (hygroscopic). A textile having a water-repellent function applies a water-repellent material to the outer surface of the fabric, and a textile having a hydrophilic (hygroscopic) function coats the inner surface of the fabric with a hydrophilic (hygroscopic) function. As for the textile with antibacterial function, a material having a bacteriostatic function is applied to the surface of the woven fabric. Applying these different materials to the same or different surfaces separately may cause uneven coating and insufficient coating layer and thus poor water washing resistance. It is disclosed that the coating layer is not strong enough to be resistant to water washing. The problem method, for example, the Republic of China Patent No. 429280 discloses that the microwave plasma activates the surface of the fiber product, and after generating a radical, the monomer is graft polymerized to form a functional group to impart a specific hydrophilic function to the fiber product; For example, Japanese Patent Laid-Open No. Hei 11-256476 discloses the use of a warm plasma processing method for single-sided modification of a needle shuttle fabric or a non-woven fabric, and the other fabrics have a low degree of use and low availability to obtain a table with 1297369. The continuous treatment of No. 13-159074 for the continuation of the functional properties has the following disadvantages to be modified, and it is necessary to introduce helium-containing gas or processing in the vacuum gas plasma mode, which requires approximately processing. A product with a different function; and a single-sided product that treats a needle shuttle fabric or a non-woven fabric using an atmospheric piezoelectric slurry. The use of energy irradiation method: First, the use of low-temperature plasma will be given to the specific functional state of the fiber product, and the cost of the equipment is high. It is difficult to mix argon gas and nitrogen gas for 24 to 36 hours. The disclosed method is modified, and the function of the single fiber system is expensive; the first working time requires acrylic acid to be patented for 8 hours to obtain surface modification, and the surface is applied to the method, and the second is adopted. The second time, another lj, etc. can complete the speed of the continuous type. In addition, as the world patent announcement number w〇02〇75〇38, the method of increasing the viscosity of the drug is applied to inhibit the penetration of the agent to achieve the single-sided coating power b'. The disadvantages of the conventional coating or screen printing process are as follows: First, the right is a conventional conventional coating process. In order to apply the functional agent to one side of the fabric, it is necessary to increase the viscosity of the agent. It is easy to cause instability of the work; second, the general coating processing process, the coating amount of the agent must be in the range of 30-200g/m2, it is difficult to carry out ultra-thin coating® Processing 'processed base fabric is easy to be limited, and at a coating weight of 30-2 〇〇g/m2, the softness of the textile will be affected; third, in order to increase the viscosity of the agent, such as thickener or isolation Intermediates such as agents are easy to cause water scars in the spun fiber products; and fourth, because it is not easy to apply on both sides, it is difficult to have a composite function. Therefore, how to effectively apply the coating materials with different functions to the upper and lower sides of the textile to make the textile have a composite function, while 1297369 can also maintain the softness and comfort of the textile and can be washed with water. , is a problem that needs to be solved urgently. SUMMARY OF THE INVENTION According to the above, the present invention provides a surface treatment method for a spun fiber product, which can effectively form at least one extremely thin functional coating layer on the surface of the fabric, thereby obtaining a reliable washable and single Or a composite function product. The object of the present invention is to provide a surface treatment method for a spun fiber product, which comprises selecting a polymer having a bridging group to form a coating liquid having different functions, such as water repellent, bacteriostatic or hydrophilic (hygroscopic), respectively, using a gravure Coating surface treatment technology, moderately selecting the shape of the groove and the mesh number of the engraving wheel, respectively applying the different functions and dosages (viscosity, concentration, thickness) of the agent to the surface of the spun fiber product by the processing technique of the second coating By means of heating and drying, the bridging reaction of the functional agent is fixed to the spun fiber port to produce a single-sided functionalized spun fiber product having one-side water repellent and the other side antibacterial %. Hydrophilic (hygroscopic), another object of the present invention is to provide a surface method for a spun fiber product, which adopts a gravure coating method, and can be adjusted by any number of meshes: the dryness, concentration and thin coating thickness of the chemical agent. Equivalent enthalpy, in addition: Build bridging, so that functional chemical agents in the textile products::: raw bridge, not only dry processing fast 'and greatly improve the washing fastness of the spinning machine function. Further, a further object of the present invention is to provide a surface treatment of a spun product 1297369, which utilizes a gravure coating process, a viscosity of a functional agent, and a thickness of the cloth. The technique selects the shape of the groove and the mesh of the engraving wheel 'concentration (solid content), etc., and provides a surface treatment method for the spun fiber product = gravure coating treatment method, which can directly adjust and control various functionalized dip coatings. The dose and thickness of the cloth on the surface of the spun fiber product enables the functional chemical agent to be uniformly applied to the surface of the spun fiber product, and the functions on different surfaces are independent and do not affect each other. Still another object of the present invention is to provide a surface treatment method for a spun fiber product without any pre-operations such as surface activation or modification, and a process that does not require treatment, that is, a water-repellent water can be formed on the surface of the textile. Single or composite functional coatings such as bacteriostatic and hydrophilic (hygroscopic) save equipment investment and reduce the cost of this source and manpower. The surface treatment method of the spun fiber product disclosed in the present invention can modify the surface of the textile by forming a functional compound to form a coating liquid, which comprises a polymer having a bridging group, such as an epoxy group, double Functional additives for bridging polymers such as bonds (such as acryl base 'alkenyl, etc.), isocyanates, sulfonyl (sHane), aziridine or ethyleneimlne, alcohol groups, organic acids, and the like. Functional additives added to the desired efficacy of the coating layer to be formed on the textile, including water repellents, organic two-molecule bacteriostatic agents containing quaternary amine salt functional groups or polyol-containing or etheric groups A plurality of functional agents such as a hydrophilic agent of an organic I salt, wherein the water repellent may be paraffin, polydecane or fluoride or the like. The viscosity of the coating liquid depends on the thickness of the coating layer. In particular, the surface treatment method of the spun 1297369 fiber product disclosed in the present invention is not limited by the viscosity of the coating liquid (the viscosity is 1000), ^ ^ ^ ^ ^ 丨 J..., shoulder thickening The agent is adjusted to m: the mesh (selecting the shape of the groove and the engraving wheel), that is, the purpose of uniform thin coating is achieved. The textile may be a fabric of a fiber structure such as a needle non-woven fabric. Therefore, the present invention provides an ultra-thin gravure coating method in which a coating liquid having water-repellent, bacteria, and hydrophilic (hygroscopic) is applied to the surface of a spun fiber product by adding Φ n two: The r-force component is fixed to the single-sided or partially-coated wood product of the spun fiber product. The invention is a composite machine capable of spun fiber such as η letter and moisture absorption, and the use of a material such as a shoe material or a leather bag which is required to be water-repellent. And it is expected that this technology will be applied to the package = production: r processing method will greatly increase the production cost == ΐ production cost, and thus enhance industrial value and competitiveness. [Embodiment] The surface treatment of the spun fiber product provided by the present invention is described in detail by way of an example to explain how to use the present invention. ...and progress-by-exposure of the test results to understand the invention: 参,第! The figure is shown in the figure. The cloth surface treatment method disclosed in the present invention is applied to the mother's clothing m four-plate coating. 1 Ω. The gravure printing apparatus 100 includes at least a tank body 102, a gravure printing roller (Q_"e ρm - 10 1297369 106 and guide wheels 108, 110. It is selected to be formed using a polymer having a bridging base, having different functions, such as watering, suppressing The coating solution 112 of the bacteria or hydrophilic (hygroscopic) is placed in a tank body 1〇2 having an opening, wherein the solvent used for the coating liquid ία may be an alcohol or water. The gravure printing wheel 1 〇 4 is set. Above the tank body 102, the pressure roller 106 is disposed on the side of the gravure printing roller 104. The textile material 11 that needs to be surface-treated is guided through the guide wheel 1 〇8 and then passes through the gravure printing wheel 104. Between the pressure roller and the pressure roller 106, the textile fabric 4 is guided by the guide wheel 110 into a drying device (not shown) for drying the glue. The thickness of the textile 11 4 is approximately Between 5 mm and 2 mm, the weight is between about 150 and 300 gram (m/m) per meter. The speed of the textile 11 4 moving on the device is 2 to 1 metre per minute. Between (m/miη). Drying equipment is generally heated and dried, and The drying temperature is generally between about 80 degrees Celsius to 200 degrees.
當凹版印刷滾輪1 04轉動時，凹版印刷滾輪1 〇4表面 的凸塊（Bump)會將槽體102中的塗佈液112帶起，並 在凹版印刷滾輪1 04及壓輪1 06間的壓合點將塗佈液11 2 塗佈在紡織品11 4的一表面上。一般而言，凹版印刷滾輪 104表面的凸塊的大小約介於每平方英吋40〜200網目 (Mesh/in2)之間，較佳的凸塊的大小約介於每平方英叶 40〜1 80網目之間。凹版印刷滚輪1 〇4及壓輪1 〇6間的壓 力每平方公分小於等於2公斤重（Kgw/cm2 )。塗佈液11 2 的黏度並不需加以限制，但較佳的黏度係介於1 〇〜 10000cps之間，最佳的黏度係介於200〜i〇〇〇〇cps之間。 11 1297369 經，，佈液帶到紡織品表面的具有架橋基之聚合物組成的 重！每平方公尺小於1 〇〇公克（g/m2)，事實上，運用本發 明所2 ^的凹版塗佈可輕易達成具有架橋基之聚合物組成 的重里母平方公尺小於50公克（g/m2)的要求。 凹版印刷滾輪1 04表面的凸塊的大小可以控制凹版印 刷，輪104輸送塗佈液的量，較大網目數的凸塊可以攜帶 :多的,佈液而較小的網目數的凸塊所能攜帶的塗佈液較 ’若再配a使用黏度較低的塗佈液，例如黏度小於 1〇〇〇CP2S的塗佈液，可以得到每平方公分0.5〜5公克重 (gw/cm2)具有架橋基之聚合物組成塗佈的紡織品，而塗佈 層的厚度可以薄到僅有一微米U m)而已。 田％、紡織品When the gravure printing wheel 104 rotates, a bump on the surface of the gravure printing roller 1 〇 4 will bring up the coating liquid 112 in the groove body 102, and between the gravure printing wheel 104 and the pressing wheel 106. The coating liquid 11 2 is applied to a surface of the textile 11 4 at a press-fit point. In general, the size of the bumps on the surface of the gravure printing roller 104 is between 40 and 200 mesh per square inch (Mesh/in2), and the preferred size of the bump is about 40 to 1 per square inch. Between 80 mesh. The pressure between the gravure printing roller 1 〇 4 and the pressure roller 1 〇 6 is less than or equal to 2 kg weight (Kgw/cm 2 ) per square centimeter. The viscosity of the coating liquid 11 2 is not limited, but the preferred viscosity is between 1 〇 and 10000 cps, and the optimum viscosity is between 200 〜 i 〇〇〇〇 cps. 11 1297369 The weight of the polymer with bridging base brought to the surface of the textile by the cloth liquid! Less than 1 gram per gram (g/m2) per square meter. In fact, it is easy to achieve a polymer with a bridge base of less than 50 grams (g/) using the gravure coating of the present invention. M2) requirements. The size of the bump on the surface of the gravure printing roller 104 can control the gravure printing, and the amount of the coating liquid is conveyed by the wheel 104. The bump of the larger mesh number can carry: a plurality of bumps with a smaller number of meshes and a smaller number of meshes. The coating liquid that can be carried can be obtained by using a coating liquid having a lower viscosity, for example, a coating liquid having a viscosity of less than 1 〇〇〇 CP 2 S, and can have a weight of 0.5 to 5 gram per square centimeter (gw/cm 2 ). The polymer of the bridging base constitutes the coated textile, and the thickness of the coating layer can be as thin as only one micron U m). Tian%, textiles
π W孟神队王外Μ里q M衩制到非常 低’所以不會有塗佈液擴散到紡織品另一側表面的問題 :此’本發明可以同時在紡織品的上下表面分別塗佈撥 親水（吸濕）的塗佈層，而可以形成具有外表面撥水且 表面親水之複合機能塗佈層的紡織品。π W Meng Shen team Wang Wai Μ q q M衩 is very low 'so there is no problem of the coating liquid spreading to the other side of the textile: this invention can simultaneously apply the hydrophilicity on the upper and lower surfaces of the textile The (water-absorbent) coating layer can form a textile having a composite functional coating layer having an outer surface water-repellent and a hydrophilic surface.
第2圖及第3圖係為一由本發明所揭露的處理方法 處理之不同材質紡織布料均為聚酉旨材質 分別為0.35毫来、〇 24离本 士 a ’、 , 2 卡〇.24笑未，布重則分別為155g/m2 136g/m的影像圖。請參照第2圖及第 200、300為經顇皮w、、蟲、泠猛各 在左側表 202 a/ 層處理的表面而右侧表 、302為經撥水塗層處理的表面。由兩影像圖中 看出在親水表面2〇〇、3〇〇滴 月· X表面202、302滴下的水則聚集於表面。一般而言、 12 1297369 毫==揭=的紡織品表面處理方法，可讓厚度介於約ο.5 。2毫米，布重約介於12〇 g/m2至3〇〇g/m2的紡纖製 :^到撥水度_以上。至於親水（吸濕）的方面，纺纖 欠表面的擴散面積在20秒時大於1500平方毫米， 彻在ί不水在纺織品表面的擴散面積與時間的關係，比較 卢理二未經表面親水處理的紡織品而實驗例為經表面親水 :、紡、織。口口。明冑可以纟出水在經表面親水處理的紡 擴散速度快了3倍以上。紡纖製品親水面的吸水性 ^，2秒’乾燥的速率在4G分鐘至6G分鐘的乾 間可以排除大於93%的吸水量。 ' ---------- 表一 擴散時間 纺織物； 睛散面積 （mm2) 5秒 20秒 3分鐘 4分鐘 比較例 實驗例 0 96 6 __69 1670 jM〇 3780 518 3931 八有杀橋基的聚合物本身即可採用具有親水性 :! 生的聚合物’而聚合物本身係做為一個載體以固著於 織品之上，撥水劑、親水劑或抗菌劑則可附著於聚合物 上以增加聚合物的親、撥水功能’而抗菌劑的添加 紡織品能產生抗菌的功㉟’ 一般而言抑菌率大於99 另外，聚合物上的架橋基會錯釘在纺織品的纖維之中，0 以耐水洗，不易脫落’一般耐水洗平均，8次以上。 據上所述，本發明係提供一種纺纖製品之表面處 13 1297369 法，利用凹版塗 學藥劑的塗佈液 量，使塗佈液不 單一或複合機能 架橋基’在經加 織品的纖維中使 表面或局部產生 紡纖製品複合機 本發明以車交 解本發明之實施 域技藝者於領悟 範圍内，當可作 保護範圍當視後 佈方式 的黏度 會滲透 塗佈層 熱乾燥 具有功 架橋， 能的耐 佳之實 ，非用 本發明 些許更 附之申 ，藉由調整網 來調整塗佈液 的紡織品的另 的紡織品。塗 等固著處理後 能性化學藥劑 不僅乾燥加工 水洗堅牢度。 施例說明如上 以限定本發明 之精神後，在 動潤飾及等同 °用專利範圍及 目數及具有功能性化 在紡織品表面塗:佈的 一表面以能形成具有 佈液中的聚合物具有 ’架橋基會錨釘在紡 的聚合物在紡纖製品 快速，而且大大提昇 僅用於藉以幫助了 之精神，而熟悉此領 不脫離本發明之精神 之變化替換，其專利 其等同領域而定。 【圖式簡單說明】 弟1圖係綠示本發明 傷示意圖；^ ^所揭狀凹版塗佈式表面處理言 弟2圖及第3圖裤兔 處理之不同材質访二由本發明所揭露的處理方法齊 J材質紡織布料的影像圖。 【元件代表符號簡單說明 102 :槽體 I 06 :壓輪 II 2 :塗佈液 1〇〇 ··凹版印刷設備 104 ··凹版印刷滾輪 108、11〇 :導輪 14 1297369 300 ··左側表面 114 ··紡織品 200 202、302 :右侧表面 152 and 3 are a different material of the textile fabrics processed by the processing method disclosed in the present invention, which are 0.35 milligrams of material, 〇24, respectively, and a card. No, the cloth weight is 155g/m2 136g/m image map. Please refer to Fig. 2 and Fig. 200 and 300 for the surface treated by the suede w, insect, and sputum on the left side of the table 202 a/layer, and the right side and 302 are the water-repellent coated surfaces. It is seen from the two image views that the water dropped on the hydrophilic surface 2〇〇, 3〇〇月·X surface 202, 302 is concentrated on the surface. In general, 12 1297369 毫 == 揭 = textile surface treatment method, the thickness can be made to be about ο.5. 2 mm, the weight of the cloth is about 12〇 g/m2 to 3〇〇g/m2 of the spun fiber: ^ to the water level _ or more. As for the hydrophilic (hygroscopic) aspect, the diffusion area of the surface of the spun fiber is greater than 1500 mm 2 at 20 seconds, and the relationship between the diffusion area of the surface of the textile and the time is relatively low. The treated textiles were experimentally hydrophilic on the surface: spinning and weaving. Mouth. Alum can pump out water at a rate of more than three times faster than the hydrophilic treatment of the surface. The water absorption of the hydrophilic side of the spun fiber product ^, the 2 second' drying rate can exclude more than 93% of the water absorption between 4G minutes and 6G minutes. ' ---------- Table 1 diffusion time textiles; eye area (mm2) 5 seconds 20 seconds 3 minutes 4 minutes Comparative example Experimental example 0 96 6 __69 1670 jM〇3780 518 3931 Eight have a bridge The polymer of the base itself can be made of a hydrophilic polymer: the polymer itself is used as a carrier to be fixed on the fabric, and the water repellent, hydrophilic agent or antibacterial agent can be attached to the polymer. In order to increase the pro- and water-repellent function of the polymer' while the addition of the antibacterial agent can produce antibacterial work 35' In general, the inhibition rate is greater than 99. In addition, the bridging group on the polymer is staggered in the fiber of the textile. Medium, 0 is washable, not easy to fall off 'Generally washable average, more than 8 times. According to the above, the present invention provides a method of 13 1297369 at the surface of a spun fiber product, which utilizes the amount of coating liquid of the gravure coating agent to make the coating liquid not singular or composite functional bridging base 'in the fiber of the fabric. The invention relates to a surface or partial production of a spun fiber composite machine. The invention is within the scope of comprehension of the embodiments of the invention. When the protection range is available, the viscosity of the post-distribution mode will penetrate the coating layer to thermally dry the bridge. The ability to be good, not to use the invention, to adjust the net, to adjust the textile of the coating liquid to another textile. After the coating and other fixing treatments, the chemical agent not only drys and processes the washing fastness. DESCRIPTION OF THE PREFERRED EMBODIMENT As described above, in order to define the spirit of the present invention, in the context of the dynamic retouching and equivalent range and the number of meshes and functionalized on the surface of the textile: a surface of the cloth to form a polymer having a liquid in the cloth has ' The bridging base anchors the spun polymer in the spun fiber product quickly and greatly enhances the spirit of the invention, and the familiarity of the present invention is replaced by a change in the spirit of the invention, the patent of which is equivalent to the field. [Simple diagram of the drawing] The brother 1 shows the green injury diagram of the invention; ^ ^ The gravure coating type surface treatment method 2 and the 3rd figure rabbit processing different materials are treated by the present invention. Method image of the J material textile fabric. [Component Representation Symbol Simple Description 102: Tank I 06 : Pressure Roller II 2 : Coating Liquid 1 〇〇 · Gravure Printing Apparatus 104 · Gravure Printing Rollers 108, 11 〇: Guide Wheel 14 1297369 300 · Left Side Surface 114 · Textiles 200 202, 302: right side surface 15