TWI295935B - - Google Patents
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- TWI295935B TWI295935B TW94143582A TW94143582A TWI295935B TW I295935 B TWI295935 B TW I295935B TW 94143582 A TW94143582 A TW 94143582A TW 94143582 A TW94143582 A TW 94143582A TW I295935 B TWI295935 B TW I295935B
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- TW
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- Prior art keywords
- grinding
- powder
- hardness
- particles
- particle size
- Prior art date
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- 238000000227 grinding Methods 0.000 claims description 25
- 239000002245 particle Substances 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 15
- 230000000694 effects Effects 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- -1 fatty acid amine Chemical class 0.000 claims description 2
- 238000001238 wet grinding Methods 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 229910052761 rare earth metal Inorganic materials 0.000 description 9
- 150000002910 rare earth metals Chemical class 0.000 description 8
- 229910052613 tourmaline Inorganic materials 0.000 description 7
- 229940070527 tourmaline Drugs 0.000 description 7
- 239000011032 tourmaline Substances 0.000 description 7
- 239000000835 fiber Substances 0.000 description 5
- 238000005054 agglomeration Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- KZNMRPQBBZBTSW-UHFFFAOYSA-N [Au]=O Chemical compound [Au]=O KZNMRPQBBZBTSW-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007688 edging Methods 0.000 description 1
- 239000012636 effector Substances 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910001922 gold oxide Inorganic materials 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- PFXYOQASYIHLDX-UHFFFAOYSA-M lithium oxygen(2-) titanium(4+) hydroxide Chemical compound [OH-].[Li+].[O-2].[O-2].[Ti+4] PFXYOQASYIHLDX-UHFFFAOYSA-M 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000007709 nanocrystallization Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000005619 thermoelectricity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Disintegrating Or Milling (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
Description
1295935 九、發明說明: 【發明所屬之技術領域】 本發明係相關於一種硬質素材的加工研磨方 、匕 一種關於硬度大於莫氏6度以上的 /尤私 法。 更貝物貝之加工研磨方 【先前技術】 電氣石 於該類礦石 生負離子。 礦石結晶體 化,產生遠 人體產生熱 循環,對人 礦石粒子應 特性,而賦 子的功能。 係為一種含石夕的複雜 硬度高,具有良好的 在溫度及壓力變化的 兩端能產生電壓,其 紅外線波長的電磁輻 效應和共振吸收效應 體具有保健保暖作用 用於纖維内時,可藉 予该纖維具有提供遠1295935 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a processing and polishing method for a hard material, and a method for a hardness of more than 6 degrees Celsius or more. More processing and grinding of shellfish [Prior Art] Tourmaline produces negative ions in this type of ore. The ore crystallizes, producing a thermal cycle that is far away from the human body, and should be characterized by the characteristics of the ore particles. It is a kind of high hardness with high temperature and good temperature. It has good voltage at both ends of temperature and pressure change. The electromagnetic radiation effect and resonance absorption effector of infrared wavelength have health care and warmth effect. Give the fiber a farther
來狀結構組成,其特性在 電壓性與熱電性,且可產 情況下’ t氣石與稀土族 電子震動而引起偶極距變 射。遠紅外線輻射可以使 ,使微血管擴張促進血液 。因此將電氣石與稀土族 由電氣石與稀土族礦石的 紅外線、保暖及產生負離 當電氣石與稀土族礦石粒子粒徑較小時,其表面積大 ’且其電n電熱性的效果更佳。當於纖維中加入電氣 石與稀土知礦石粉末時’該粒子需小於5〇⑽至。然 口電乱石與稀土族礦石之硬度高,造成研磨加工不易。 -般硬質物質其加工研磨方法,係利用濕式研磨機提 供長時間研磨以獲取粉末產品。當欲使常見的硬質物質, 例:電氣石或包含鋰、㉟、鈽等稀土族礦石,其研磨粒徑 達奈米私度時’所f之時間長且其所獲取的產品因長時間 5 :1295935 較佳的是’低濃度醇類係為1〇%至3〇%(w/幻的甲醇或 一 乙醇。 更佳的是’低浪度醇類係為20%至30%(w/w)的甲醇或 乙醇。 較佳的是,轉速為約每分鐘13〇〇轉至16〇〇轉。 ^ 較佳的是’其中局硬度素材與研磨介子的比例約為1 _ : 2 〇 較佳的是’研磨時間為2〇至35分鐘。 § 較佳的是,將粒子粉體進行研磨以獲取奈米粒徑大小 之粉體之步驟中所使用的濕式研磨機,其内設有硬度8 5 且粒從大小為p 0 · 2至〇 · 5毫米之錯珠。 較佳的是,研磨時間為4〇至5〇分鐘,且於研磨後加 入1 %的脂肪酸胺類界面活性劑。 本發明另相關於一種由前述加工研磨方法所獲製的產 品° 藉由本發明所提供之二段式加工研磨方法,以第一階 •段降低粒子間的表面能以避免凝結現象產生,再以第二階 段進行研磨使粒子可達粒徑更小的奈米 小產生粉體間的凝集現象,且加工時間不會延長,: 品分散性良好的優點。 【實施方式】 本發明係相關於一種硬質素材奈米化之加工研磨方法 、’其係藉由提供二段式加卫研磨方法,使高硬度的素材可 以被研磨至奈米顆粒大小,且減小並延緩粉體間產生凝集 1295935 現冢。 本發明以首先係以具有高衝擊 高硬度素材,使苴A w的J切力先仃破碎該 未具有表面能二ΐ 狀態,且該粒子之表面尚 磨方法使粒子“字經破碎的粒子放入研磨機中,以研 粒碎至粉,。由於經衝擊剪切力破碎的 得瓦力,形成有因長期研磨所產生的靜電及凡 後將該延而團聚,因此不具有凝集現象;而 至奈米大小的=現象的粒子加以研磨’而可以良好研磨 意二的最佳實施狀態,並非 實例The composition of the incoming structure is characterized by voltage and thermoelectricity, and can be produced under the condition that the t-stone and the rare earth electrons vibrate to cause dipole moment variation. Far-infrared radiation can cause microvascular expansion to promote blood. Therefore, the tourmaline and rare earth elements from the tourmaline and rare earth ore infra-red, warm and negatively generated when the tourmaline and rare earth ore particles have a small particle size, the surface area is large 'and its electric n electric heating effect is better . When the tourmaline and rare earth ore powders are added to the fiber, the particles need to be less than 5 〇 (10). However, the hardness of the electric stone and the rare earth ore is high, which makes the grinding process difficult. The method of processing and grinding a hard material is to provide a powder product by using a wet grinder for a long time grinding. When it is desired to make common hard substances, such as tourmaline or rare earth ores containing lithium, 35, lanthanum, etc., the grinding particle size is up to the nanometer private degree, and the time of the product is long and the product obtained is long. : 1295935 It is preferred that the 'low concentration alcohol system is from 1% to 3% by weight (w/magic methanol or monoethanol. More preferably, the low-altitude alcohol system is from 20% to 30% (w/ W) Methanol or ethanol. Preferably, the rotation speed is from about 13 rpm to about 16 rpm. ^ It is preferred that the ratio of the local hardness material to the grinding meson is about 1 _ : 2 〇 Preferably, the grinding time is from 2 to 35 minutes. § Preferably, the wet grinding machine used in the step of grinding the particle powder to obtain a powder having a nanometer particle size is provided therein. The hardness is 8 5 and the particles are from the wrong size of p 0 · 2 to 〇 · 5 mm. Preferably, the grinding time is 4 〇 to 5 〇 minutes, and 1% of the fatty acid amine surfactant is added after grinding. The invention further relates to a product obtained by the aforementioned processing and grinding method, by the two-stage processing and grinding method provided by the invention, The first-order segment reduces the surface energy between the particles to avoid the formation of condensation, and then grinds in the second stage to make the particles reach a smaller particle size and produce agglomeration between the powders, and the processing time is not prolonged. The present invention relates to a processing and polishing method for hard material nanocrystallization, which is capable of being ground by high-hardness materials by providing a two-stage edging method. To the size of the nanoparticle, and to reduce and delay the formation of agglomeration between the powders. 1295935 The present invention firstly has a high impact and high hardness material, so that the J shear force of the 苴A w is first broken and the surface energy is not ΐ state, and the surface of the particle is still ground to make the particle "broken particles into the grinder, to grind the granules to the powder. Due to the impact of the impact shear force, the formation of the long-term grinding The generated static electricity and the subsequent agglomeration will not have agglomeration; and the particles of the nanometer size = phenomenon will be polished, and the best implementation state of the second can be well polished, and Examples
研磨材料:硬唐P 上的電氧石或稀土族礦石 研磨機·日本二井礦業公司所生產之研磨機 首先錢待處理的高硬度素材,置人設置有以硬产 .5之鍅珠作為研磨介子的研磨機内,研磨介子粒徑大小 為0.6 i 2.2毫米。待處理的高硬度素材與研磨介 比例約為1 : 2。 、 於該研磨機中加入流動载體,流動載體的種類,視恭 要地’可為醇類或水’其中醇類可為甲醇或乙醇。流動载 體的濃度可設為較低濃度的前述醇類流體,例如較 10%至30%(w/w)的賴,最佳為m至順w/w)的曱醇或 乙醇溶液。使研磨機的轉動速率調至高轉速,較佳係為每 8 1295935 免研磨後的粉體粒子旋結,並使其快速乾燥而可獲得所欲 之奈米大小的粉體。將所獲取之粉體於電子顯微鏡下觀察 ’其粒徑大小約在50至800奈米之間。 實施例三:以本發明所揭示之二段式研磨加工方法所 素材種類 既有研磨 既有方法 本發明研 本發明方 方法所獲 獲取之粉 磨方法所 法獲取之 取的粉體 體之應用 獲取的粉 粉體之應 粒徑大小 體粒徑大 用 、----___ 小 礦 電氣石 D100/3. 5 β 僅能應用 D100/500nm 均可直接 石 稀土族 m 於纖維的 v ^ J〇L 加入紡絲 礦石 表面處理 利用,且 植 竹碳 D100/0. 8// 可加入紡 D100/200nm 所加入的 物 備長碳 m 至 600nm 絲或短纖 粒子呈完 全分散狀 金 氧化錘 可直接加 D100/100nm 屬 三氧化 入紡絲 、 類 二鋁 長短纖 二氧化 D100/300nm 矽 二氧化 鈦 氧化鋰 10 ,1295935 氧化鋅 【圖式簡單說明】 無 【主要元件符號說明】 無Abrasive material: Electro-oxidic stone or rare earth ore grinding machine on the hard Tang P. The grinding machine produced by Japan's Erjing Mining Co., Ltd. firstly has high-hardness materials to be processed, and the bead is set to be hardened. In the meson mill, the particle size of the grinding meson is 0.6 i 2.2 mm. The ratio of the high hardness material to the abrasive to be treated is about 1:2. The flow carrier is added to the mill, and the type of the flow carrier may be, by way of course, an alcohol or water, wherein the alcohol may be methanol or ethanol. The concentration of the flowing carrier can be set to a lower concentration of the aforementioned alcoholic fluid, for example, a 10% to 30% (w/w) lye, most preferably m to cis w/w) sterol or ethanol solution. The rotation rate of the grinder is adjusted to a high rotation speed, preferably, the spin-off powder particles are entangled per 8 1295935, and are quickly dried to obtain a desired nanometer-sized powder. The obtained powder was observed under an electron microscope to have a particle size of about 50 to 800 nm. Embodiment 3: The material of the two-stage grinding processing method disclosed by the present invention has both the method of grinding and the method of the powder obtained by the grinding method obtained by the method of the present invention. The particle size and particle size of the obtained powder powder are large, -----___ small ore tourmaline D100/3. 5 β can only be applied to D100/500nm, direct stone rare earth m to fiber v ^ J 〇L is added to the surface treatment of the spinning ore, and the bamboo carbon D100/0. 8// can be added to the spinning D100/200nm. The material added is long carbon m to 600nm. The silk or short fiber particles are completely dispersed. The gold oxide hammer can be directly added. D100/100nm is a trioxide into spinning, aluminous-like short-length fiber dioxide D100/300nm 矽 titanium dioxide lithium oxide 10, 1295935 zinc oxide [simple description] No [main component symbol description]
1111
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Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW094143582A TW200722178A (en) | 2005-12-09 | 2005-12-09 | Grinding method for the nanonization of hard material and product made thereby |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW094143582A TW200722178A (en) | 2005-12-09 | 2005-12-09 | Grinding method for the nanonization of hard material and product made thereby |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200722178A TW200722178A (en) | 2007-06-16 |
| TWI295935B true TWI295935B (en) | 2008-04-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW094143582A TW200722178A (en) | 2005-12-09 | 2005-12-09 | Grinding method for the nanonization of hard material and product made thereby |
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| Country | Link |
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| TW (1) | TW200722178A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI728158B (en) * | 2015-02-24 | 2021-05-21 | 小林光 | Hydrogen-containing liquid, method for manufacturing hydrogen-containing liquid, apparatus for manufacturing hydrogen-containing liquid, and biological hydrogen generating material |
| US11311572B2 (en) | 2016-01-29 | 2022-04-26 | Bosquet Silicon Corp. | Preparation, method for producing preparation, and method for generating hydrogen |
| US11583483B2 (en) | 2016-08-23 | 2023-02-21 | Bosquet Silicon Corp. | Hydrogen supply material and production therefor, and hydrogen supply method |
| US11707063B2 (en) | 2016-08-23 | 2023-07-25 | Bosquet Silicon Corp. | Compound, production method therefor, and hydrogen supply method |
-
2005
- 2005-12-09 TW TW094143582A patent/TW200722178A/en not_active IP Right Cessation
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI728158B (en) * | 2015-02-24 | 2021-05-21 | 小林光 | Hydrogen-containing liquid, method for manufacturing hydrogen-containing liquid, apparatus for manufacturing hydrogen-containing liquid, and biological hydrogen generating material |
| US11311572B2 (en) | 2016-01-29 | 2022-04-26 | Bosquet Silicon Corp. | Preparation, method for producing preparation, and method for generating hydrogen |
| US11752170B2 (en) | 2016-01-29 | 2023-09-12 | Bosquet Silicon Corp. | Solid preparation, method for producing solid preparation, and method for generating hydrogen |
| US11583483B2 (en) | 2016-08-23 | 2023-02-21 | Bosquet Silicon Corp. | Hydrogen supply material and production therefor, and hydrogen supply method |
| US11707063B2 (en) | 2016-08-23 | 2023-07-25 | Bosquet Silicon Corp. | Compound, production method therefor, and hydrogen supply method |
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| Publication number | Publication date |
|---|---|
| TW200722178A (en) | 2007-06-16 |
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