TWI288978B - Manufacturing method of electronic light emitting device - Google Patents
Manufacturing method of electronic light emitting device Download PDFInfo
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- TWI288978B TWI288978B TW92100268A TW92100268A TWI288978B TW I288978 B TWI288978 B TW I288978B TW 92100268 A TW92100268 A TW 92100268A TW 92100268 A TW92100268 A TW 92100268A TW I288978 B TWI288978 B TW I288978B
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 239000000758 substrate Substances 0.000 claims abstract description 45
- 239000002184 metal Substances 0.000 claims abstract description 29
- 229910052751 metal Inorganic materials 0.000 claims abstract description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052802 copper Inorganic materials 0.000 claims abstract description 17
- 239000010949 copper Substances 0.000 claims abstract description 17
- 229910052709 silver Inorganic materials 0.000 claims abstract description 11
- 239000004332 silver Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims description 13
- 239000013078 crystal Substances 0.000 claims description 6
- 230000005012 migration Effects 0.000 claims description 4
- 238000013508 migration Methods 0.000 claims description 4
- 239000004020 conductor Substances 0.000 claims 6
- 238000012876 topography Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 11
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 9
- 239000010410 layer Substances 0.000 description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 230000007613 environmental effect Effects 0.000 description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
- 229910052737 gold Inorganic materials 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 239000011247 coating layer Substances 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910001316 Ag alloy Inorganic materials 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- XTKDAFGWCDAMPY-UHFFFAOYSA-N azaperone Chemical compound C1=CC(F)=CC=C1C(=O)CCCN1CCN(C=2N=CC=CC=2)CC1 XTKDAFGWCDAMPY-UHFFFAOYSA-N 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013500 data storage Methods 0.000 description 1
- 239000002305 electric material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
1288978 五、發明說明(i) 發明所屬之技術領域 方 造 製 之 \^y ο 6 C法 • 1—I V方 6 d 造 (製 件之 器件 光器 ,月 子極 電二 種光 _ 發 於種 關一 係於 月 aw rrr'-v 發其 本尤 法 先前技術 發光二極體器件之應用頗為廣泛,例如,可應用於光 學顯示裝置、交通號誌、資料儲存裝置、通訊裝置、照明 裝置、以及醫療裝置。如何以經濟有效且符合現代環保要 求之方式提升發光二極體之亮度,是研發人員所關心之一 重要課題。 目前最常見的一種發光二極體器件之製造方法包含下 列各步驟:.1 .準備一片由玻璃環氧樹脂(G 1 a s s Ε ρ ο X y) 或類似材質製成的基板、2 .依預定圖案(p a. 11 e r η),在 該基板中形成複數個貫穿孔、3 .在該基板之表面(含該等 複數個貫穿孔之内表面)上形成銅覆蓋層、4.將該基板之 — 〜 表面形成鎳覆蓋層、5.將該基板之表面形成盒_覆蓋層、6 . 一'''''一 以曝光顯影技術,除去該基板表面預定區域上之各金屬覆 蓋層,因而在基板表面形成具有預定圖案之一導電金屬疊 層、7.將複數個發光二極體晶粒於相應之複數個預定位 置,分別依附於該導電金屬疊層之鑛金表面上、8.在每一 發光二極體晶粒與該導電金屬疊層間,以一金屬線建立適 當之電連接、9.以適當之封裝材料(例如環氧樹脂)將每 一發光二極體晶粒與相關之金屬線封裝於基板上、1 1.切 割該基板,以形成複數個發光二極體器件。1288978 V. INSTRUCTIONS (i) The technical field of the invention belongs to the \^y ο 6 C method • 1 - IV side 6 d (the device optoelectronics of the workpiece, the two kinds of light of the moon) The application of the ancestors in the month aw rrr'-v has been widely used in the prior art luminescent diode devices, for example, it can be applied to optical display devices, traffic signs, data storage devices, communication devices, lighting. Devices and medical devices. How to improve the brightness of light-emitting diodes in a cost-effective and modern environmental protection manner is an important issue for researchers. The most common method for manufacturing light-emitting diode devices includes the following. Each step: 1. Preparing a substrate made of glass epoxy resin (G 1 ass Ε ρ ο X y) or the like, 2. Forming a predetermined pattern (p a. 11 er η) in the substrate a plurality of through holes, 3. a copper coating layer is formed on the surface of the substrate (including the inner surface of the plurality of through holes), 4. a nickel coating layer is formed on the surface of the substrate, and the substrate is formed. Surface forming box_covered a cover layer, a '''''''''''''''''''''''''''''' The light-emitting diode crystal grains are respectively attached to the surface of the gold-plated metal of the conductive metal layer at a plurality of predetermined positions, and a metal wire is disposed between each of the light-emitting diode grains and the conductive metal layer. Establishing appropriate electrical connections, 9. encapsulating each of the light-emitting diode dies and associated metal lines on the substrate with a suitable encapsulating material (eg, epoxy), 1 1. cutting the substrate to form a plurality of luminescent layers Diode device.
第4頁 1288978 五、發明說明(2) 該先前技藝發光二極體器件之製造方法所製成的發光 二極體器件,有多項缺點:1.鍍金表面對於短波長光線 (如藍光)之反射率偏低,例如對藍光之反射率僅約 4 0%,因而無法有效反射短波長發光二極體晶粒所發射之 光線、2.在一般印刷電路板所使用之銅箔基版上鍍金之 前,為避免金與銅之、間產生遷移(m i g r a t i ο η)現象,須 先在銅箔表面鍍上一層鎳,作為阻隔層,導致偏高之製造 成本、3.鎳係一種有害健康物質(請參閱中華民國九十 一年八月三十曰行政院環境保護署環署水字第0九一 0 0 五九九0 —號公告)、4.以及金之材料成本偏高。 · 本案發明人長期構思如何能夠兼顧環保且經濟有效地 提升發光二極體器件之亮度,熟習本技藝者皆以為··於製 造發光二極體之程序中,在銅扳一表面-鍍-銀,其.所鍍^ ,故不可行。但本案發明人,以逆向思考方 法,在大家皆曰不可行之概念上思考,並經實u登實二於 一—......... …’ 製造發光二極體之程序中’在印刷電路板預定表面區域鑛 對於短波長光線有較高反射率之銀(其例如對於藍光之反 射率約為9 7 %),以取代該先前技藝之鍍金,竟然电 料之為地,能夠避免先前技藝之前述各項缺點’而達致_能 夠兼顧環保且經濟有效地提升發光二極體器件亮度之進步遽, 功效。 發明内容 本發明之一目的在於提供一種電子發光器件之製造方Page 4 1288978 V. DESCRIPTION OF THE INVENTION (2) The light-emitting diode device fabricated by the prior art method for fabricating a light-emitting diode device has several disadvantages: 1. Reflection of a gold-plated surface for short-wavelength light (such as blue light) The rate is low, for example, the reflectance of blue light is only about 40%, so that the light emitted by the short-wavelength light-emitting diode crystal grains cannot be effectively reflected, 2. Before the gold-plated copper plate used in general printed circuit boards is plated with gold In order to avoid the phenomenon of migration between gold and copper, it is necessary to first coat a layer of nickel on the surface of the copper foil as a barrier layer, resulting in a high manufacturing cost and 3. Nickel is a harmful health substance (please Refer to the Announcement of the Water Quality Department of the Environmental Protection Department of the Executive Yuan, August 30, 2011, and the material cost of gold. · The inventor of the present invention has long conceived how to balance the environmental protection and cost-effectively improve the brightness of the light-emitting diode device. Those skilled in the art believe that in the process of manufacturing the light-emitting diode, in the copper plate-surface-plating-silver , it is plated ^, it is not feasible. However, the inventor of this case, in the way of reverse thinking, thinks on the concept that everyone is not feasible, and through the real thing, it is in the process of manufacturing a light-emitting diode. 'In the predetermined surface area of the printed circuit board, the silver has a higher reflectivity for short-wavelength light (for example, the reflectance of blue light is about 97%), instead of the gold plating of the prior art, even the electric material is ground, It is possible to avoid the aforementioned shortcomings of the prior art and achieve the advantages and advantages of environmentally friendly and cost-effectively improving the brightness of the light-emitting diode device. SUMMARY OF THE INVENTION An object of the present invention is to provide a manufacturer of an electronic light emitting device
第5頁 1288978 五、發明說明(3) 法,以此方法所製造之發光二極體器件,能夠產生較高之 亮度。 本發明之另一目的在於提供一種電子發光器件之製造 方法,其製造程序較簡單,因而能夠降低製造成本。 本發明之又一目的在於提供一種電子發光器件之製造 方法,其中使用價格較低廉之電鍍反射金屬材料,因而能 夠降低材料成本。 本發明之又另一目的在於提供一種電子發光器件之製 造方法,其中免用先前技藝所使用之一種有害健康物質-鎳,因而能夠符合現代之環保要求。 # 為達成上述各目的,依本發明一較佳實施例之一種電 子發光器件之製造方法,.包含下列各步驟:依一預定圖 案,在一基板中形成複數個貫穿孔;在該基板之表面(含 該等複數個貫穿孔之内表面)形成一銅覆蓋層;在該銅覆 蓋層上形成一銀覆蓋層;以曝光顯影技術,除去該基板表 面預定區域上之該銅覆蓋層與該銀覆蓋層,因而在該基板 表面形成具有預定圖案之一導電金屬疊層;將複數個發光 二極體晶粒於相應之複數個預定位置,分別依附於該導電 金屬疊層之表面上;在該等複數個發光二極體晶粒中之每 一發光二極體晶粒與該導電金屬疊層間,以一金屬線建立 適當之電連接;以一封裝材料,將該發光二極體晶粒與該 金屬線封裝於該基板上;以及切割該基板,以形成複數個 發光二極體器件。Page 5 1288978 V. Description of Invention (3) The light-emitting diode device manufactured by this method can produce higher brightness. Another object of the present invention is to provide a method of manufacturing an electron-emitting device which is simple in manufacturing process and thus can reduce manufacturing costs. It is still another object of the present invention to provide a method of manufacturing an electroluminescent device in which a relatively inexpensive electroplated reflective metal material is used, thereby reducing material cost. Still another object of the present invention is to provide a method of manufacturing an electroluminescent device in which a harmful health substance, nickel, which is used in the prior art, is dispensed with, thereby being able to meet modern environmental requirements. In order to achieve the above objects, a method for fabricating an electronic light-emitting device according to a preferred embodiment of the present invention comprises the steps of: forming a plurality of through holes in a substrate according to a predetermined pattern; on the surface of the substrate Forming a copper cap layer on the copper cap layer; forming a silver cap layer on the copper cap layer; removing the copper cap layer on the predetermined surface of the substrate surface and the silver by exposure and development techniques a cover layer, thereby forming a conductive metal stack having a predetermined pattern on the surface of the substrate; and dicing the plurality of light-emitting diodes on the surface of the conductive metal laminate respectively at a plurality of predetermined positions; A suitable electrical connection is established between each of the plurality of light-emitting diode crystal grains and the conductive metal layer by a metal wire; and the light-emitting diode die is formed by a packaging material The metal line is packaged on the substrate; and the substrate is diced to form a plurality of light emitting diode devices.
第6頁 1288978 五、發明說明(4) 實施方式 茲參照附圖,詳細說明本發明如後。Page 6 1288978 V. DESCRIPTION OF THE INVENTION (4) Embodiments The present invention will be described in detail with reference to the accompanying drawings.
依本發明一較佳實施例之一電子發光器件之製造方法 包含下列各步驟:1 .準備一片基板、2.依預定圖案 (p a 11 e r η),在該基板中形成複數個貫穿孔、3 .將該基 板之表面上形成一銅覆蓋層,使該等複數個貫穿孔之内表 面皆覆蓋一層銅材料、4 .將該基板之表面I度銀、5 .以曝光 顯影技術,除去基板表面預定區域上之金屬,因而在該基 板表面形成具有預定圖案之一導電金屬疊層、6.將複數個 發光二極體晶粒於相應之複數個預定位置,分別依附於該 導電金屬疊層之鍍銀表面上、7 .在每一發光二極體晶粒與 該導電金屬疊層間,以一金屬線建立適當之電連接、8 ·以 適當之封裝材料(例如環氧樹脂)將每一發光二極體晶粒 與相關之金屬線封裝於該基板上、9 .切割該基板,以形成 複數個發光二極體器件。 熟習本技藝者應可瞭解,在以上任何相鄰之二步驟 間,可加入適當之其他一步驟或多步驟。依本發明一較佳 實施例之製造方法,於完成前述步驟6後之基板11,顯示 於圖1 ,包含複數個貫穿孔2 0、複數個導電區3 0,其中每A method of manufacturing an electronic light-emitting device according to a preferred embodiment of the present invention comprises the following steps: 1. preparing a substrate, 2. forming a plurality of through holes in the substrate according to a predetermined pattern (pa 11 er η), Forming a copper coating on the surface of the substrate, so that the inner surfaces of the plurality of through holes are covered with a layer of copper material, 4. The surface of the substrate is silvered at a degree of 1. 5, by exposure and development techniques, the surface of the substrate is removed. a metal on the predetermined area, thereby forming a conductive metal stack having a predetermined pattern on the surface of the substrate, 6. Having a plurality of light-emitting diode dies in a corresponding plurality of predetermined positions, respectively attached to the conductive metal stack On the silver-plated surface, between each of the light-emitting diode dies and the conductive metal stack, a suitable electrical connection is established by a metal wire, and each illuminating is performed with a suitable encapsulating material (such as an epoxy resin). A diode die and associated metal lines are packaged on the substrate, and the substrate is diced to form a plurality of light emitting diode devices. Those skilled in the art will appreciate that any other step or steps may be added between any two adjacent steps above. According to a manufacturing method of a preferred embodiment of the present invention, the substrate 11 after the completion of the foregoing step 6 is shown in FIG. 1 and includes a plurality of through holes 20 and a plurality of conductive regions 30, each of which
一導電區3 0於完成前述步驟9後,.形成複數個導電區1 2與 複數個導電區1 3,如圖2中所示。 請參閱圖2,依本發明之前述製造方法所製成之一發 光二極體器件1例如包含一基板1 1、二導電區1 2與1 3、一 發光二極體晶粒1 4、一金屬線1 5 (例如由金製成)、及一After completing the foregoing step 9, a conductive region 30 forms a plurality of conductive regions 12 and a plurality of conductive regions 13 as shown in FIG. Referring to FIG. 2, a light-emitting diode device 1 manufactured by the above manufacturing method of the present invention includes, for example, a substrate 1 1 , two conductive regions 12 and 13 , and a light-emitting diode die 14 . Metal wire 15 (for example made of gold), and one
1288978 五、發明說明(5) ’ 封裝材料1 6,其中基板1 1例如為用以製造印刷電路板之一 般玻璃環氧樹脂基板,導電區1 2與1 3_為在基板1 1之二預定 —一 _______________________-一________—一一1288978 V. INSTRUCTION DESCRIPTION (5) 'Packaging material 1 6, wherein the substrate 1 1 is, for example, a general glass epoxy substrate for manufacturing a printed circuit board, and the conductive regions 12 and 1 3 are predetermined on the substrate 1 1 - one _______________________ - one ________ - one by one
CH 表面區域上依前述方法形成一銅覆蓋層及一銀覆..蓋..層所構 、成’發光二極體晶粒1 4之陰極以電連接方式依附於導電區 1 2上,金屬線1 5使導電區1 3電連接於發光二極體晶粒1. 4之 陽極。封裝材料1 6,例如由耐高溫之矽膠或環氧樹脂形 成,將發光二極體晶粒1 4與金屬線1 5封裝於導電區1 2與1 3 以及基板1 1上。被封裝材料1 6封住之導電區1 2與1 3的鍍銀 表面,因一與空氣“隔一暴」—故—無氧.化-變·黑之…時-1§一。 經實驗證實,依本發明之發光二極體器件1所產生之 亮度約為前述先前技藝藍色發光二極體器件所產生亮度之 1 4 0%,亦即能夠達成亮度提升約4 0%之增進功效。 此夕卜,由於基板1 1之銅材料與其上所鍍之銀牲王j生 ,一-----------------------------------...............一〜一 遷移現象,故可直接在基板1 1之銅材料上鑛銀,而無須如 前述先前技藝發光二極體器件要求先鍍一層鎳作為防止該 遷移現象之阻隔層,因而依本發明之發光二極體器件1能 夠達致簡化生產程序及兼顧現代環保要求之優點。 0 以上所述者,僅為用以方便說明本發明之一較佳實施 例,本發明之範圍不限於該較佳實施例,凡依本發明所做 的任何變更,皆屬本發明申請專利之範圍。例如,以銀合 金取代銀,做為導電區1 2與1 3表面之反射材料,顯然不脫 離本發明之精神與範圍。On the surface of the CH, a copper coating layer and a silver coating are formed according to the above method. The cathode is formed, and the cathode of the LED diode 14 is electrically connected to the conductive region 12, metal. The anode of the light-emitting diode die 1.4 is electrically connected to the anode of the light-emitting diode. The encapsulating material 166 is formed, for example, of a high temperature resistant silicone or epoxy resin, and the luminescent diode die 14 and the metal line 15 are encapsulated on the conductive regions 12 and 13 and the substrate 11. The silver-plated surface of the conductive regions 1 2 and 1 3 sealed by the encapsulating material 16 is "one violent" from the air - therefore - anaerobic, chemical-transformed, black, and the like -1. It has been experimentally confirmed that the brightness of the light-emitting diode device 1 according to the present invention is about 140% of the brightness produced by the prior art blue light-emitting diode device, that is, the brightness can be increased by about 40%. Improve efficacy. In addition, since the copper material of the substrate 1 1 and the silver plated on it are born, one --------------------------- --------............... One to one migration phenomenon, so it can be directly on the copper material of the substrate 1 1 without silver, without the prior art The diode device requires a layer of nickel to be used as a barrier layer to prevent the migration phenomenon, so that the light-emitting diode device 1 according to the present invention can achieve the advantages of simplifying the production process and taking into consideration modern environmental protection requirements. The above is only a preferred embodiment for facilitating the description of the present invention, and the scope of the present invention is not limited to the preferred embodiment, and any changes made in accordance with the present invention are claimed in the present invention. range. For example, the replacement of silver with a silver alloy as a reflective material for the surfaces of the conductive regions 12 and 13 does not clearly depart from the spirit and scope of the present invention.
12889781288978
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