TWI267382B - Cleaning agent composition - Google Patents

Abstract

The present invention provides a cleaning composition comprising (a) 0.01 to 1% by weight of special amino-modified silicone, (b) 0.05 to 2% by weight of special fatty acid soap, (c) 0.05 to 2% by weight of polyethylene oxide sorbitan ester type non-ionic interfacial agent, and (d) 1 to 20% by weight of soluble polyol. The composition can be used in skin-suitable dilution type of cleaning agent.

Description

1267382 发明Invention Description: [Technical Field] The present invention relates to a dermatological wiper composition which is diluted with water or warm water. In more detail, the composition of the sputum for the purpose of rubbing the dirt such as the buttocks and the genitals has a sufficient rinsing property, and the skin is not slippery after use, and the skin is sufficiently moistened and the skin is prevented from being rough and difficult. A decontaminant composition that is recontaminated and has excellent stability over time. [Prior Art] In life, we must regularly remove dirt from the outside world and body dirt from secretions such as sebum and sweat. Usually, a detergent such as solid or liquid soap is used to wash away the dirt during bathing. However, it is not easy for infants and physically handicapped persons to use a wet towel or other caregiver to keep the body clean. At this time, the medicine used to make the body more clean is called a "scrubbing agent". Generally, the wiper can be classified into a type that is used without being diluted or a type that is diluted with warm water or the like. Among them, the type of deodorant used after dilution is usually diluted with 10 to 1 000 times of warm water, the amount of the active ingredient in the prescription is reduced, and the dilution is not required in terms of the hydratility after use and after use. The type used is not ideal. However, this diluted type of deodorant is not only advantageous in terms of safety because of its low concentration at the time of use, and it is possible to use water of a preferred temperature for dilution, which is comfortable for the care recipient. In addition, because the amount of pharmaceutical use is small at one time, it has a high cost benefit to the consumer, and is often used for care of the elderly and wiping of the baby. In particular, in recent years, with the formation of an aging society, the demand for deodorants has increased by 1,267,382, and it is expected to develop a more excellent deodorant. Among them, the part of the buttocks and the genitals which are exposed to the mucous membrane is very sensitive, and the specific contamination is attached to the site where the number of wiping is frequent. Therefore, it is desirable to develop safer, highly functional deodorants. Up to now, JP-A-64-3 80 1 8 and JP-A-6, No. 79 1 08 have developed a wipe containing t-polymethyl oxa oxide and polyether modified polyglycol as a main component. Agent, but the purity of either one is insufficient, and the skin after use is deeply hampered, and it is impossible to prevent rough skin. Especially when other parts are wiped, dirt such as dirt will be removed from the towel and re-contamination may occur. Therefore, it is required to have a type of deodorant after dilution, especially when used in the buttocks and genitals, and the skin is not slippery after use. In addition to maintaining the elasticity and moisturization of the skin, it can prevent rough skin. When it is wiped again, it is not easy to re-contaminate, and the composition of the deodorant is excellent in stability and safety over time. SUMMARY OF THE INVENTION The inventors of the present invention have studied the above-mentioned problems, and specific polyoxynitrides, specific fatty acid soaps, specific nonionic surfactants, and water-soluble polyols are combined at a specific ratio. A target wiper composition can be prepared. The wiper composition of the present invention contains the following components, and (a) formula (;[)

(I) 1267382 (wherein 'R1 is represented by a respective methyl or phenyl group, and at least one of the plurality of Ri is a methyl group; R2 is represented by a respective methyl group, a hydroxyl group, or a r3z; _ R3 is represented by each Independent alkyl groups having a carbon number of 3 to 6; Z is represented by -N(R4) 2 or an N R4 (Ch2) a N (R4) 2 amine group, and R 4 is represented as a respective independent hydrogen atom or carbon number 1 ～4 alkyl, a is an integer of 2 to 6; m and η are independent 〇~20000 integers, respectively, and m+n=30~20000) amine-based modified polyoxalate·〇1~1 weight % , (b) Formula (Π ) is expressed as R5C〇〇M ( π ) φ (wherein R5COO is expressed as a linear or branched fatty acid residue having a carbon number of 8 to 24; Μ is expressed as an alkali metal atom) Soap 〇.〇5~2% by weight, (c) polyethylene oxide sorbitan ester type nonionic surfactant 〇·〇 5~2% by weight, and (d) water-soluble polyol ^20 weight %. Preferably, the deodorant composition of the present invention further comprises (e) at least one extract derived from the leaves of the tea (c sinensis L.) of the genus Polygonum, from the three white grasses. An extract of a plant of the genus Heliconia (H〇uttuynia Thunb), an extract from a plant of the genus Asteraceae (Artemisia l.), and a plant of the genus Astragalus (Pheii〇dendron Rupr.) The extract was present in an amount of 0.00005% by weight of the dry residue. BEST MODE FOR CARRYING OUT THE INVENTION The wiper composition of the present invention comprises the following components (a), (b), (c) and (d) which may contain (e) component and (f) additive as required. , (g) solvent, etc. The content of each component of the wiper composition of the present invention means the total amount of the composition relative to the solvent-containing (usually water). 1267382 (a) Amine-based modified polyoxylamine-based modified polyoxo system (I) R 1 I R 2 - S i 0

The compound represented. In the formula (I), R1 represents a methyl group or a phenyl group which is independent of each other, and at least one of the plurality of R1 is a methyl group. The R2 table is not a unique methyl group, a trans group, or a r3Z. R3 is represented by an independent alkyl group having 3 to 6 carbon atoms, and is preferably -(CH2) 3 -. Z represents an N(R4)2 or an NR4(cH2)aN(R4)^ amine group, and R4 represents an independently hydrogen atom or an alkyl group having a carbon number of 丨4, and a is an integer of 2 to 6. Preferred such amine groups are, for example, -NH2, _NHCH3, -N(CH3)2, -NH(CH2)2NH2, -NH(CH2)2NHCH3, or -NH(CH2)2N(CH3)2 . m and η are independent integers of 200~20000, respectively, and m+n = 30 to 20000. m + η is preferably 100 to 20000, more preferably 1000 to 20000. In the total amount of the deodorant composition of the present invention, the content of the amine-modified polyfluorene oxide is 0.01 to 1% by weight, more preferably 0.03 to 0.7% by weight, still more preferably 0.05 to 1% by weight. If the content is less than 0.01% by weight, a slippery feeling is obtained after use, and the effect of preventing recontamination is not good. If it exceeds 1% by weight, it is difficult to uniformly disperse in the solvent-containing composition, which is disadvantageous for cost consideration. (b) fatty acid soap 1267382 fatty acid soap formula (II) . · R5COOM ( II ) (wherein R5C〇〇 is represented by a linear or branched fatty acid residue having a carbon number of 8 to 24; Μ is represented by an alkali metal atom ) an alkali metal salt of a fatty acid represented. Fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, palmitic acid, oleic acid, linoleic acid, linolenic acid and other linear fatty acids; branched fatty acids such as iso-fatty acids; and coconut oil fatty acid, palm kernel oil Mixed fatty acids such as fatty acids, palm oil fatty acids, olive oil fatty acids, sunflower oil fatty acids, tallow fatty acids, and hardened tallow fatty acids. Among them, from the stability, the touch of φ during wiping, and the effect of preventing skin roughness, cis-Δ 9-octadecenoic acid (generally referred to as oleic acid) containing 75 wt% or more and containing the oil The acid cis-Δ 9-unsaturated fatty acid accounts for more than 85% by weight of the total fatty acid, and further contains 80% by weight or more of cis-Δ 9-octadecenoic acid (oleic acid) and contains the oil. The acid cis-?9-unsaturated fatty acid accounts for more than 85% by weight of the total fatty acid. The alkali metal atom of ruthenium, such as sodium or potassium, is preferably potassium from the viewpoint of stability and solubility. φ In the total amount of the deodorant composition of the present invention, the content of the fatty acid soap is 0·0 5 to 2% by weight, preferably 〇·07 to 1.5% by weight, more preferably 0.1 to 1% by weight. If the content is less than 0.05% by weight, not only the cleanliness is not good, but also the effect of preventing skin roughness is insufficient. When it exceeds 2% by weight, it is sticky after use, and the stability of the composition is deteriorated. (c) Polyethylene oxide sorbitan ester type nonionic surfactants Generally, the production of 'polyethylene oxide sorbitan ester type nonionic surfactants is based on sorbitan and fatty acids. 1 : 1 to 1 : 4 molar ratio anti-1267382 After the ester (sorbitan fatty acid ester) is added with ethylene oxide. :- The above fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, brown decenoic acid, oleic acid, linoleic acid, linolenic acid and other linear fatty acids; branched fatty acids such as iso-fatty acids; and coconut oil Mixed fatty acids such as fatty acids, palm kernel oil fatty acids, palm oil fatty acids, olive oil fatty acids, sunflower oil fatty acids, tallow fatty acids, and hardened tallow fatty acids. More preferably, it is lauric acid or oleic acid. Further, the average molar amount of ethylene oxide added is 5 to 100, preferably 10 to 60. 〇 In the total amount of the deodorant composition of the present invention, the polyethylene oxide sorbitan φ ester type is not The content of the ionic surfactant is 0.05 to 2% by weight, preferably 0.07 to 1.5% by weight, more preferably 0.1 to 1% by weight. If the content is less than 〇·〇5 wt%, not only is the cleanliness poor, but the stability is also poor. If it exceeds 2% by weight, the touch is not good after use. (d) Water-soluble polyol A water-soluble compound containing two or more hydroxyl groups in one molecule of a water-soluble polybasic product, and is usually used as a moisturizer for cosmetics. Specifically, for example, propylene glycol, dipropylene glycol, isoprene diol, 1,3-butanediol, glycerin, di- glycerol, sorbitol, mannitol or the like. Among them, preferred alcohols are dipropylene glycol, isoprene diol, 1,3-butylene glycol, glycerin, diglycerin, and polyethylene glycol, and more preferably a polymer having a molecular weight of 6 〇〇 to 4,000. Ethylene glycol. The total amount of the water-repellent polyol in the total amount of the deodorant composition of the present invention is 1 to 20% by weight, more preferably 3 to 18% by weight, still more preferably 5 to 15% by weight. If the content is less than 1% by weight, the touch and stability after use are not good, and if it exceeds 20% by weight, the dispersibility at the time of dilution is not good. (e) Plant extract -10- 1267382 The plant extract contained in the wiper composition of the present invention is at least one plant extract selected from the following (i) to (i v ). (i) Leaf extract of tea of Camellia (C. sinensis L.). This extract uses at least one selected from the group consisting of water or lower alcohol (ethanol, isopropanol, propylene glycol, 1,3-butanediol, etc.) The solvent extracts the extract of the leaves of the tea of Camellia (C. sinensis L.). Usually, tea can be divided into two types, one type is v a r · s i n e n s i s of green tea, and the other type is var. assamica (Mast·) Kitam· which is black tea. Any of these two types can be used in the present invention. When extracting the extract of these tea leaves, it is usually preferred to dry, ferment (by enzymes in tea), steaming, frying, and the like. For example, raw tea leaves are directly heat treated as non-fermented tea, such as green tea, yellow tea, and the like. Specifically, there are steamed teas such as jade, sencha, matcha, scented tea, and roasted tea; and tea made from jade green tea and Chinese green tea. A fermented tea produced by fermentation (oxidation reaction of a tea component using an enzyme in tea leaves), such as black tea, black tea, white tea, etc., and a semi-fermented tea such as oolong tea in the middle. (ii) an extract of the plant of the genus H. sylvestris (Houttuynia Thunb). The extract is at least one selected from the group consisting of water or lower alcohol (ethanol, isopropanol, propylene glycol, 1,3-butanediol, etc.) Solvent extraction of the aboveground or whole grass extract of the plant of the genus H. sylvestris (Houttuynia Thunb.). It is more desirable to extract from the aerial part of the flowering stage of H. cordata Thuiib (the herb called "Scented Grass"). (iii) an extract of a plant of the genus Asteraceae (A rtemisia L ·). The extract is at least one selected from the group consisting of water or a lower alcohol (ethanol, isopropyl 1267382 alcohol, propylene glycol, 1,3-butanediol, etc.) Solvent extraction of plants of the genus Asteraceae. (Artemisia L.) leaves or whole grass extracts. For example, A. absinthium L., A. capillaries Thunb., A. japonica Thunb., A. princeps Pamp., A. maritime L. A. mongoria Fisch., the extract of the temple of A. montana Pamp. It is preferred to extract the leaves of a. japonica Thunb., A. princeps Pamp., A. mongoria Fisch, or A. montana Pamp. (iv) an extract of a plant belonging to the genus Phylloendron Rupr. The extract is at least one selected from the group consisting of water or a lower alcohol (ethanol, isopropanol, propylene glycol, 1,3-butanediol, etc.) The solvent extracts the extract of the genus Astragalus (Phellodendron Rupi: ·). It is preferable to extract the extract of the bark of the pericarp of the scutellaria (ρ· amurense Rupr*·) (the name of the herb is "yellow" or "yellow"). In order to enhance the moisturization after use, the effect of preventing skin roughness, and the effect of making the skin elastic, these (i) to (i v ) plant extracts may be added to the wiper composition of the present invention as needed. The deodorant composition of the present invention is preferably 0.00005% by weight based on the dry residue extract, more preferably 0. 0 0 0 1 to 0. 5 % by weight. If it is less than 〇 · 〇 〇 〇 〇 5 〇 〇 / 〇, the addition effect is not easy to be exerted, and if it exceeds 1% by weight, the stability of the composition is poor, and it is disadvantageous for cost consideration. The dry residue of the present invention means a residue obtained by drying the extract at 105 ° C or drying under reduced pressure to remove the solvent, i.e., a solute. Further, when the extraction solvent is not volatile, the amount of the solvent can be determined by a quantitative amount of the solvent such as gas chromatography or high-speed liquid chromatography, and the amount of the residue is -12-1267382. (f) Additives Generally, additives commonly used in cosmetics can be used, and can be added to the composition within a range not affecting the properties of the composition of the present invention. For example, the following $additives: lower alcohols such as ethanol and isopropanol; liquid stone, liquid isomers, tridecane, petrolatum, solid paraffin and other hydroxyl oils; tallow, pig fat, fish oil and other natural oils a triglyceride such as triethyl 2-ethylhexanoate; isopropyl myristate, isopropyl palmitate, cetyl palmitate, ethyl oleate, oleic acid ester, nutmeg An ester oil such as octyl lauryl acetate; a wax such as bee mites and bran wax; a polyoxyl derivative such as a linear or cyclic dimeric methyl siloxane or a polyether modified dimeric methyl oxane; Oily bases such as neuropterin, cholesterol, protein derivatives, lanolin, lanolin derivatives, lecithin; polyethylene oxide alkyl ether, polyethylene glycol fatty acid ester, polypropylene oxide alkyl ether, Polypropylene glycol fatty acid ester, sorbitan fatty acid ester, poly epoxy compound hardened castor oil, polyglycerin fatty acid ester, glycerol monobasic fatty acid ester, alkyl polyglucoside, polyethylene oxide polyepoxy Nonionic surfactants such as propane block copolymers and alkanolamines; soaps, alkyl sulfates , alkyl ether sulfate, α-ene sulfonate, decyl taurate, thiol glutamate, thioglycolate, thioglycolate, decyl isethionate Anionic surfactants such as alkyl ether carboxylates, guanamine ether sulfates, alkyl phosphate esters; alkyl dimethyl amino acetate betaine, guanamine propyl dimethyl ammonium acetate betaine , amphoteric amine acid salt, alkyl imine diacetate and other amphoteric surfactant; alkyl amine oxide, polyethylene oxide alkyl amine oxide and other semi-polar surfactant; alkyl chloride, ammonium chloride, chlorine a cationic surfactant such as dialkyldimethylammonium; a hydrochloride of an alkylamine or amidinoamine; and a 1268732 salt of acetic acid; talc, ceramic clay, sericite, mica, vermiculite, magnesium carbonate, calcium carbonate, Diatomaceous earth, magnesium citrate, calcium citrate, aluminum citrate, barium strontium citrate, total chopped acid, barium sulfate, metal tungstate, cerium oxide, zeolite, hydroxylated apatite, boron nitride, ceramic soil Powders such as inorganic materials, organic powders such as crystalline cellulose, polyethylene powder, and polytetrafluoroethylene powder; oxidation, oxidation , red iron oxide (iron oxide red), loess, carbon black, Ming purple, chrome oxide, ultramarine and other inorganic pigments; titanium oxide coated mica, fish scale foil, colored titanium oxide coated mica and other gray pigment; Ming powder, copper powder and other metals Powder pigment; red 2 〇1, orange 204, yellow 205, blue 404 and other organic pigments; red 3, red 1 〇 6, red 2 2 7 , yellow 4, yellow 6 , blue Chromium compound such as color No. 1; natural pigment such as chlorophyllin and /3-carotene; alginic acid, carboxyvinyl polymer, carboxymethyl cellulose, hydroxypropyl methyl cellulose, ethyl cellulose, hydrazine a water-soluble polymer such as a copolymer of B-ton, hyaluronic acid, 2-(meth)acryloyl-hydroxyl-based phosphonium and propylene (meth)acrylate; magnesium sulfate, sodium chloride, sodium citrate, Inorganic or organic salts such as sodium pyrrolide residue; pH adjusters such as acid or alkali; fungicides; chelating agents; antioxidants; ultraviolet absorbers; anti-inflammatory agents; natural extracts of plants and animals; The above additives are added to the composition insofar as the stability is not impaired. (g) Solvent Water (purified water or the like) is usually used as a solvent. The residual amount of the total amount (% by weight) of the above (a) to (f) is a solvent. Since the deodorant composition of the present invention contains a specific component in a predetermined ratio, it has sufficient cleansing properties, and the skin is not slippery after use, and maintains sufficient elasticity and moisturization to prevent skin roughness. It is not easy to re-contaminate when it is wiped again. It is also excellent in long-term preservation when it is qualitatively and 14- 1267382. Since the composition is designed to be diluted by 5 to 10 Q times, preferably 10 to 80 times, it has the advantage of cost. Therefore, it is suitable for wiping off the skin, especially when rubbing the buttocks and genitals. [Embodiment] [Examples] Next, the present invention will be described in more detail by way of examples. The properties of the wiper composition produced by the present invention were evaluated according to the methods (1) to (5) described below. (1) Hygienicity and prevention of re-contamination The composition of the deodorant was diluted 30 times with purified water, and the "wet artificial contamination cloth" (nS-C9606 specification) manufactured by Washing Chemical Society was used, with a Terg-0-tometer at 40. Rinse for 10 minutes at °C, and wash the water three times with the same amount of water. Thereafter, the water was dehydrated, air-dried, and the whiteness was measured using a "color tester" manufactured by Nippon Denshoku Industries Co., Ltd. The whiteness of the white cloth (white cloth not contaminated) and the whiteness of the contaminated cloth before washing are measured in advance before washing, and the cleaning rate is obtained by the following formula, according to the following criteria. Assess the aptitude. Next, when the above-mentioned contaminated cloth is washed, the test for the simultaneous washing of the contaminated cloth and the white cloth is carried out, and the re-contamination rate of the white cloth is determined by the following formula, and the re-contamination resistance is evaluated based on the following criteria. Chast rate (%) = (C-B)/(A-B) X100

Recontamination rate (%) = (A-D)/AX 100 Whiteness of white cloth: A Whiteness of the contaminated cloth before washing: B Whiteness of the contaminated cloth after washing: C and the cloth being washed at the same time Whiteness of white cloth: D 1267382 Chastity: 〇: good chamferability (happiness rate is more than 25%) X: poor cleanliness (chaise rate less than 25%) Prevention of recontamination: 〇: prevention of re-contamination Good sex (recontamination rate less than 5%) X: Prevention of poor recontamination (recontamination rate greater than 5%) (2) Skininess after use is 13 women (32 to 45 years old) and 7 men ( 33 to 44 years old) as a tester. The 35 mL of the wiper composition was diluted to 1 L (about 30 times) with a pot of warm water at about 40 ° C, and a 135 mm X 190 mm dry non-woven fabric was immersed in the solution and then gently wrung out. The buttocks and the genitals were wiped with a non-woven fabric immersed in the composition of the wiper, and then the skin was evaluated for the smoothness according to the following criteria. 2 points: The skin is not slippery after use. 1 point ·· The skin is slightly slippery after use. 〇: After use, the skin feels slippery and feels bad. The average 値 of 20 people was determined, and the slippery feeling after use was evaluated based on the following criteria. Φ 〇: no slipperiness is good (average 値 is greater than 1 · 5 points) X : bad greasy feeling (average 値 less than 1 · 5 points) (3) skin elasticity and moisturization after use to 13 women (32 years old ~ 45 years old) and 7 males (33 to 44 years old) as testers. In the same manner as in the above (2), the whole body was wiped with a non-woven fabric immersed in the composition of the wiper, and after 15 minutes, the moist feeling of the skin was evaluated according to the following criteria. 2 points: The skin is elastic and moist, and it feels healthy. -16 - 1267382 1 point: The skin is slightly dry, not too moist or less elastic. :· 〇: The skin feels dry ‘no moist or elastic. — Find the average 値 of 20 people and evaluate the elasticity and wetness after use according to the following criteria. 〇: Good elasticity and moist feeling (average 値 is greater than 1.5 points) X: Inelastic and moist feeling is not good (average 値 is less than 1 · 5 points) (4 ) 7 women who are sensitive to skin with sensitive skin (32 3 males (aged to 40 years old) and sensitive skin (33 to 37 years old) as testers. In the same manner as in the above (2), the non-woven fabric impregnated with the composition of the wiper was gradually added to the inside of the arm for several times, and the dirt on the inside of the arm was gently wiped. After 2 weeks of continuous use, the skin was evaluated according to the following criteria. status. 2 points: The skin has no rough feeling. 1 point: The skin is slightly rough. 0: The skin is obviously rough. The average 値 of 10 was determined. The effect of preventing rough skin was evaluated according to the following criteria. · 〇: It is good for preventing rough skin (average 値 is greater than 1.5 points) X : It is not good for preventing rough skin (average 値 less than 1.5 points) (5) Sealing the composition of the sputum in clear glass containers with stability It was stored at 5 ° C, 2 5 t:, and 40 ° C for 3 months, and its appearance was observed and evaluated in the following three grades. 〇: good stability (no change in appearance at any temperature) △: slightly poor stability (micro-deposition at any temperature or precipitation of -17-1267382, or slight coloration) x·female sex Good (deposition or precipitation at any temperature, or separation, or significant coloration) (Examples 1 to 7) The wiper compositions containing the respective components in the proportions shown in Table 1 were separately prepared and evaluated according to the above method. The details of the ingredients in Table 1 are shown in Table 2. The results are shown in Table 4. In Table 4, the number of brackets in the brackets for the "wash rate" and "re-pollution rate" are expressed as the wash rate and the re-pollution rate. The number of lines in the brackets of the "smoothness of the skin after use", "elasticity and moistness after use", and "the effect of preventing skin roughness" are indicated as the number of points in the test.

-18- 1267382 Table 1 Ingredient Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 (a) Amine modified polyoxynized emulsion (Note 1) (Amine modified polyoxylized oxygen; wt%) 0.3 ( 0.06) 0.5 (0.1) 1 (0.21) 2 (0.42) 0.5 (0.1) 0.3 (0.06) 0.3 (0.06) (b) Myristic acid (Note 2) 0.2 — — — — Monooleic acid (Note 3) A 0.15 0.15 0.15 0.15 0.3 0.15 483⁄4 potassium hydroxide aqueous solution 0.18 0.15 0.15 0.15 0.15 0.28 0.15 (c) Polyethylene oxide (20 mol) monovalent lauric sorbitan (Note 4) 0.2 0.3 — a 0.3 0.3 0.2 Polyethylene oxide (20 mol) monooleic oleic acid sorbitan (Note 5) - 0.2 0.5 - 0.3 (d) Glycerol 5 5 5 2 5 3 2 Dipropylene glycol 2 2 2 2 5 3 2 Polyethylene glycol 1540 2 2 2 2 2 3 2 (e) Tea extract 1 (Note 6) (dry matter conversion 値; wt%) 1 (0.012) 0.1 (0.0012) 0.5 (0.006) 10 (0.12) Tea extract 2 (Note 7) (dry matter conversion 雷; ray amount %) 1 (0.011) Three white grass extract (Note 8) (dry matter conversion 値; wt%) 0.2 (0.003) 10 (0.15) wormwood extract (Note 9 ) (dry matter conversion 値; weight%) a 0 .5 (0.0055) — 0.1 (0.0011) — — 10 (0.11) Astragalus membranaceus extract (Note 10) (dry matter conversion 値; wt%) 1-2 (0.02) — — — — (a,) Polymethyl oxime Alkane emulsion (Note 11) (Polymethyloxane; wt%) - One-to-one - Additive methylparaben 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Perfume (Note 12) 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Refined water remaining portion remaining portion remaining portion remaining portion remaining portion remaining portion remaining portion 100 100 100 100 100 100 100

Units are % by weight -19· 1267382 Table 2 Note No. Product Name Manufacturing Company Name Detailed Note 1 XS65-B6413 GE Toshiba Poly Oxide (Shares) Contains 21% by weight of aminoethyl propyl propyl oxane-dimethyl Emulsion of aerobicane copolymer 2 NAA-142 Sakamoto oil (stock) Fatty acid composition: 99% by weight of tetrakis acid, 1% of other fatty acids Note 3 EXTRA OS-85 Japanese fat (stock) Fatty acid composition: 87% cis -Δ9-octadecenoic acid, 4% cis-Δ9, cis-12-octadecanoic acid, 3% hexanoic acid, 4% octadecanoic acid, 1% behenic acid, 1% other Fatty acid (91% cis-octa-9-unsaturated fatty acid) Note 4 Nani LT-221 曰本油(股) Note 5 NOFABLE ESO-8520 曰本油(股) Note 6 Tea extract Xiangrong Xingye Extraction solvent: 30% aqueous ethanol solution 7 Black tea extract s Xiangrong Xingye (shares) Extraction solvent: 30% aqueous ethanol solution 8 Biopharmaceutical extract Xiangrong Xingye (stock) Extraction solvent: 50% 1,3-butanediol Aqueous solution Note 9 wormwood extract 九法法斯(股) Extraction solvent: 24% ethanol · 20% 1,3-butanediol aqueous solution Note 10 Obacle E IX Kesi (stock) extraction solvent: 50% aqueous ethanol solution 11 XS65-B2907 GE Toshiba polyoxyl (strand) emulsion containing 34.8 wt% high polymerized polymethyl siloxane. Note 12 Fragrance F3-2373 Xiang Rong Xingye (Comparative Examples 1 to 5) Each of the detergent compositions containing the components shown in Table 3 was prepared and evaluated according to the above method. The results are shown in Table 4.

-20- 1267382 Table 4

Evaluation Project Example Comparative Example 1 2 3 4 5 6 7 1 2 3 4 5 Washing Rate " ) 〇〇〇〇〇〇〇〇 XXX 〇 (30) (35) (37) (33) (34) (35) (40) (36) (23) (20) (16) (37) Recontamination rate 〇〇〇〇〇〇〇X 〇〇〇〇(%) (0) (0) (0) (0) (0 ) (0) (0) (10) (3) (0) (0) (0) Slimness of skin 〇〇〇〇〇〇〇X 使用 after use (1.7) (1.8) (1.9) (1.9 (1.8) (1.8) (1.8) (1.1) (1.6) (1.5) (1.8) (1.9) Elasticity and wetness after use (1.6) (1.8) (1.8) (1.8) (1.6) (1.9) (1.8) (1.6) (1.6) (1.7) (1.5) (Π) Prevents rough skin X roughing effect (1.6 (1.8) (1.9) (1.8) (1.7) (1.9) (1.8) (1.5) (1.7) (1.3) (1.7) (1.5) Stability over time 〇X 〇Δ X

As is apparent from the results of Table 4, the wiper compositions of any of Examples 1 to 7 have sufficient rinsing properties, and the skin is not slippery after use, and can maintain sufficient elasticity and moisture to prevent skin roughness. Further, when the composition is used, it is not easy to be re-contaminated, and the composition is excellent in stability over time. On the other hand, the wiper compositions of Comparative Examples 1 to 5 did not have sufficient performance. In detail, the composition of Comparative Example 1 does not contain the component (a), and it has a slippery feeling after use, and the effect of preventing recontamination is poor. In Comparative Example 2, since the polyoxonium derivative (a)' which is different from the component (a) of the present invention is substituted for the component (a), the washing rate is not good, and the stability over time is poor. In Comparative Example 3, since the component (b) was not contained, in addition to poor cleanliness, the effect of preventing skin roughness was insufficient. In Comparative Example 4, since the content of the component (c) was small, the stability over time was insufficient in addition to the poor cleanability. In Comparative Example 5, since the component (d) was not used, the skin was inelastic and moisturized after use. From this, it can be seen that 'the use of the composition of the (a), (b), (c), and (d) components of the specified proportion of 22-2226382 after the composition of the present invention is excellent in rinsing effect and feeling of use. . [Industrial Applicability] As described above, the wiper composition of the present invention has sufficient latherness, and the skin is not slippery after use and maintains sufficient elasticity and moisture to prevent rough skin. It is not easy to be twice polluted when it is wiped again, and it is excellent in stability over time and can be stored for a long time. This composition is usually used after being diluted 5 to 100 times, so that it has the advantage of cost. Therefore, it is suitable for wiping off the skin, especially when cleaning the dirt such as the buttocks and the genitals. [Simple description of the map]: None -23-

Claims (1)

Patent application scope 1. A sputum composition comprising the following components: Formula I) is represented by R 1 R2 — S i 〇 R1I S i 〇Ί m RS i 〇 (I) (wherein R1 is represented as a separate methyl or phenyl group, and at least one of the plurality of R1 is a methyl group; R2 is represented as a separate methyl group, a hydroxyl group, or R3Z; and R3 is represented as an independent carbon number of 3 to 6 Alkyl; Z represents an amine group of N(R4) 2 or a NR4(CH2) aN(R4) 2 , and R 4 represents an independently hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and a is 2 to 6 The integers; m and η are independent integers of 〇~20000, respectively, and m+n = 30~20000) amine modified polyoxyl oxide 0.01~1% by weight, (b) formula (II) is expressed as R5C00M (II (wherein, R5COO is represented by a linear or branched fatty acid residue having a carbon number of 8 to 24; Μ is represented by an alkali metal atom) fatty acid soap 〇. 〇 5 to 2% by weight, (c) poly epoxide The sorbitan ester type nonionic surfactant is 0.05 to 2% by weight, and (d) the water-soluble polyol ί 2 2% by weight. 2 · The composition of the sputum as claimed in item 1 of the patent application, which further contains (e) at least one species derived from the leaves of the tea of Camellia (c. sinensis L.), two white An extract of the genus Hepatococcus (Houttuynia -24 - 1267382 T hunb ), an extract from the plant of the genus Asteraceae (A rtemisia L.), and a plant from the genus Astragalus (Phellodendron Rupr. The extract is 0.00005~1% by weight of the dry residue. -25-