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TWI262140B - Decorative plate and its preparation - Google Patents

Decorative plate and its preparation Download PDF

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Publication number
TWI262140B
TWI262140B TW94111403A TW94111403A TWI262140B TW I262140 B TWI262140 B TW I262140B TW 94111403 A TW94111403 A TW 94111403A TW 94111403 A TW94111403 A TW 94111403A TW I262140 B TWI262140 B TW I262140B
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TW
Taiwan
Prior art keywords
decorative
decorative pattern
adhesive
pattern
layer
Prior art date
Application number
TW94111403A
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Chinese (zh)
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TW200635804A (en
Inventor
Hiroo Nakayama
Original Assignee
Tefco Aomori Co Ltd
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Priority to TW94111403A priority Critical patent/TWI262140B/en
Application granted granted Critical
Publication of TWI262140B publication Critical patent/TWI262140B/en
Publication of TW200635804A publication Critical patent/TW200635804A/en

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Abstract

This invention provides a decorative plate, where even small decorative patterns can also be adhered to an object to be adhered, where the patterns would not detach upon collision. Sharp edges of the patterns can also prevent abrasion and prevent injuries upon contact while fully utilizing the original metal gloss of the decorative patterns. Since the decorative plate of this invention is made of an object to be adhered, that has an indent portion and a decorative pattern configured to substantially the same indent portion, it is characterized in that, the decorative pattern is adhered to the indent portion via an adhesive agent layer containing a mixture of a hot-melt adhesive and an ultraviolet curing adhesive, an adhesive agent layer or an adhesive layer.

Description

1262140 九、發明說明: 【發明所屬之技術領域】 又銳利圖像邊緣 本發轉缺錄$綠,,#削、 亦能讓康嶋紅,;__姆,⑴賴& 亦能防止磨耗及防止因接觸引起受傷。 【先前技術】1262140 IX. Description of the invention: [Technical field to which the invention belongs] Sharp image edges are turned to the default of $green, #切, can also make Kang Yuhong,;__姆, (1) Lai & can also prevent wear and prevent Injury due to contact. [Prior Art]

有物用之令散文子或裝飾零件等在微細複轉狀的物品,由 於2屬板之表面在該賴像形成部以外之部分形成祕_,於金屬板 之表面上_麟等圖像職的導_,在此導電部上藉電絲出金屬 形成作^時字等裝侧案的電像,將此裝飾圖案介由接著劑層一旦 複製於薄膜等支持基材上保持之後’於裝飾圖案之露出面上形成固定用 接著劑層,從支持基材剝離此裝飾圖案,同時藉由固定用接著劑層黏貼 在計時用顯示板等之待接著體上已廣泛實行,.日本專利文獻i及2 等揭示種種上述電鍍圖像法以及其改良。 如此的裝飾圖案,係為了表示製造公司名、商品名作為顯示構件 (裝飾板)所使用。於字母的H·』等之點極微小,藉由固定用接 著層貼著於待接著紅,亦因接著力不充分而械落的狀況。 又依電鍍B像法,在字母之『V』'『w』之於銳角部分形成銳利的邊 緣。此銳角部容易磨耗,勾住衣服纖維或亦有造成受傷的原因。 為了解決此等問題,本案申請人於專利文獻3提案有將電鍍圖像密 封於熱熔融性樹脂層内作成裝飾板。依此裝飾板,樹脂内密封有電鍍圖 像’所以微小的電鍍圖像不會有圖像脫落之虞,又為邊緣銳利的圖像亦 能防止磨耗及防止因接觸造成受傷。然而,由於用樹脂覆蓋電鍍圖像表 面,故使電鍍圖像本來具有的金屬光澤消失。 為了防止微小裝飾圖案的圖像脫落,及防止於邊緣銳利的圖案磨耗 及因接觸造成受傷,且為了有效利用裝飾圖案本來具有的金屬光澤,本 案申請人於日本專利文獻4提案有由具有凹部的待接著體及與該凹部大 致同形狀的裝飾板所成且裝飾圖案於該凹部内介由紫外線硬化型接著劑 OP050130/SF-1176F 5 1262140 層所固定之裝飾板。 此裝飾板製造如下。將裝飾圖案整列暫時黏著而形成於支持構件 上,於具有第1紫外線硬化型接著劑層的應用帶複製該裝飾圖案,照射 紫外線於該紫外線硬化型接著劑層使降低接著力,再於裝飾圖案接著的 面上,形成第2紫外線硬化型接著劑層,將裝飾圖案介由第2紫外線硬 化型接著劑層,喪合於具有大致同形狀之凹部的待接著體之該凹部,從 應用帶側照射紫外線,自裝飾圖案剝離應用帶。 然而,介由如上述的第2紫外線硬化型接著劑層固定裝飾圖案之 際’特別是未在適當條件下照射紫外線時,不使接著劑硬化,不能得到In the case of a whispering piece or a decorative part, the surface of the two-piece plate is formed in a part other than the image forming portion, and the surface of the metal plate is formed on the surface of the metal plate. In the conductive portion, the metal is formed by the wire on the conductive portion to form an electric image for the side case, and the decorative pattern is retained by the adhesive layer once it is reproduced on a supporting substrate such as a film. A fixing adhesive layer is formed on the exposed surface of the pattern, and the decorative pattern is peeled off from the support substrate, and the adhesive layer for fixing is adhered to the to-be-attached body such as the timing display panel, etc., Japanese Patent Publication No. And 2, etc. disclose the above-described plating image method and its improvement. Such a decorative pattern is used to indicate a manufacturing company name and a product name as display members (decorative panels). The point of the letter H·′′ etc. is extremely small, and it is attached to the red layer by the fixing layer, and the state is dropped due to insufficient adhesion. According to the electroplating B image method, a sharp edge is formed in the sharp corner portion of the letter "V"'"w". This sharp corner is easy to wear, hooking up the fibers of the clothes or causing injuries. In order to solve such problems, the applicant of the present application proposed in Patent Document 3 that a plating image is sealed in a layer of a heat-meltable resin to form a decorative sheet. According to this decorative plate, the resin is sealed with a plated image. Therefore, the minute plated image does not have an image peeling off, and the sharp-edged image can also prevent abrasion and prevent injury due to contact. However, since the plated image surface is covered with a resin, the metallic gloss originally possessed by the plated image disappears. In order to prevent the image of the micro decorative pattern from falling off, and to prevent sharp edge pattern wear and damage due to contact, and to effectively utilize the metallic luster originally possessed by the decorative pattern, the applicant of the present application proposed a concave portion in Japanese Patent Document 4. A decorative sheet formed of a layer of a UV-curable adhesive OP050130/SF-1176F 5 1262140 to be formed by a decorative sheet having a shape substantially the same as the recess and having a decorative pattern in the recess. This decorative panel is manufactured as follows. The decorative pattern is temporarily adhered to the support member, and the decorative pattern is reproduced on the application tape having the first ultraviolet curable adhesive layer, and the ultraviolet ray is applied to the ultraviolet curable adhesive layer to lower the adhesion force and then the decorative pattern. On the subsequent surface, a second ultraviolet curable adhesive layer is formed, and the decorative pattern is immersed in the concave portion of the object to be bonded having the substantially identical concave portion via the second ultraviolet curable adhesive layer, from the application side Irradiated with ultraviolet light, the strip is applied from the decorative pattern. However, when the decorative pattern is fixed by the second ultraviolet curable adhesive layer as described above, in particular, when the ultraviolet ray is not irradiated under appropriate conditions, the adhesive is not cured and cannot be obtained.

本來的接著力。藉此,裝飾圖案之接著力變得不充分,有因落下衝擊而 使圖案脫落的狀況。 『專利文獻1』日本國特開平7-331479號公報 『專利文獻2』日本國特開平8-27597號公報 『專利文獻3』日本國特開平2002-205496號公報 『專利文獻4』日本國特開平2003-12420號公報 【發明内容】 (發明欲解決的課題) 本發明’係為了固定裝觸案㈣2料線硬倾接著劑層, ^由於介賴熔化接著軸料線硬化齡接著劑層、教 飾板及其製造方法為目心 獲仔防止因衝擊使圖像脫落之裝 (解決課題的手段) (^決-如^目=轉衡取_為要旨。 形狀的裝_案所成徵部的待接著體及與該凹部大致同 紫外線硬化型^著劑的混 ^=2内介由熱熔化接著劑與 定者。 °接著浙成之裝飾圖案用固黏層予以固 倚困案所成,且裝爛案係於該凹部内介由熱炫化接著割The original force. As a result, the adhesion force of the decorative pattern is insufficient, and the pattern is detached due to the falling impact. [Patent Document 1] Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. Kaiping 2003-12420 SUMMARY OF INVENTION [Problem to be Solved by the Invention] The present invention is for fixing a touch-contact (four) 2-line hard-dipping agent layer, ^ due to melting and subsequent axial line hardening of the adhesive layer, The teaching board and its manufacturing method are designed to prevent the image from falling off due to impact (the means to solve the problem) (^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^ The body to be bonded and the recessed portion are substantially the same as the ultraviolet curing type agent, and the heat-melting adhesive is used to determine the composition. ° Then the decorative pattern of Zhecheng is fixed with a solid layer. And the rotten case is placed in the recess by heat slashing and then cutting

OP050130/SF-1176F 1262140 所成之裝飾圖案用固勒層予以固定者。 (3)、,-種裝触,其槪為係由具凹觸待接著财與該凹部大致同 形狀的裝飾圖案所成,且裝飾圖案於該凹部内介由黏著劑所成之裝 飾圖案用固黏層予以固定者。 ⑷、如上述⑴〜⑶任—項之賴版,其巾在裝飾_表面及侧面設有 樹脂被覆層。 (5) 、如上述⑴〜⑷任一項之裝飾版,其中裝飾圖案與裝飾圖案用固黏 層之合計厚度為相對於該凹部之深度,在—2〇〇以瓜〜+如“瓜之範 圍。OP050130/SF-1176F 1262140 The decorative pattern is fixed by a Guler layer. (3), - - type of touch, which is formed by a decorative pattern having a concave shape and a substantially identical shape of the concave portion, and the decorative pattern is formed by the adhesive in the recess The anchor layer is fixed. (4) The stencil of the above (1) to (3), wherein the towel is provided with a resin coating layer on the decorative surface and the side surface. (5) The decorative plate according to any one of (1) to (4) above, wherein the total thickness of the decorative layer and the decorative pattern is a thickness relative to the depth of the concave portion, and the melon is at -2 range.

(6) _如上述(1)〜(5)任一項之裝飾版,其中該裝飾圖案係電鍍圖像。 (7) 、如上述(1)〜(5)任一項之裝飾版,其中該裝飾圖案係蝕刻圖像。 (8) 、一種裝飾板之製造方法,其特徵為:在支持構件上形成整列暫時 黏著的裝飾圖案,將該裝飾圖案複製於具接著劑層的應用帶上,再 於裝飾圖案的接著面上,形成選自由下列組成組群之裝飾圖形用固 黏層: (i) 熱熔化接著劑與紫外線硬化型接著劑的混合接著劑, (ii) 熱熔化接著劑,以及 (iii) 黏著劑 於具有與裝飾圖案大致同形狀凹部的待接著體之該凹部内,介由 裝飾圖案用固黏層嵌合該裝飾圖案, 自裝飾圖案剝離應用帶。 (9) 、如上述(8)之裝飾板之製造方法,更包含其中應用帶之接著劑層係 含紫外線硬化型接著劑且複製該裝飾圖案於應用帶之後,照射紫外 線於接著劑層使降低接著力之步驟。 (10) 、如上述(8)或(9)之裝飾板之製造方法,更包含其中裝飾圖案用固 黏層包含紫外線硬化型接著劑及熱熔接著劑且嵌合裝飾圖案於待接 著體凹部之後,從應用帶側照射紫外線,且從應用帶側施予加熱或 加熱與加壓之步驟。 (11) 、如上述(8)或(9)之裝飾板之製造方法,更包含其中裝飾圖案用固 OP050130/SF-1176F 7 1262140 黏層含熱熔化接著劑且嵌合裝飾圖案於待接著體凹部後,從應用 帶側施予加熱或加熱與加壓之步驟。 (12) 、如上述(8)〜(11)任一項之裝飾板之製造方法,更包含將裝飾圖案 以整列暫雜辆支持構件上之狀態,對裝制絲祕以剝離處 - 理之步驟。 (13) 、如上述(8)〜(11)任一項之裝飾板之製造方法,更包含將裝飾圖案 以整列暫時黏著於支持構件上之狀態,對裝飾圖案表面及側面被覆 樹脂之步驟。 (14) 、如上述(8)〜(11)任一項之裝飾板之製造方法,更包含將裝飾圖案 φ 以整列暫時黏著於支持構件上之狀態,對裝飾圖案表面及側面被覆 樹脂,且於樹脂被覆表面施以剝離之步驟。 (發明之效果) 依本發明係提供一種其中微小的裝飾圖案不因衝擊使圖像脫落之強固 接著的裝飾板。又提供其中邊緣銳利的圖像可防止磨耗及防止因接觸而 受傷,且裝_案能有效糊本來具有的金屬綺的裝條及其製造方 法。再者依本發明,提供其中用以固定裝飾圖案的接著劑不至於從裝飾 圖案滲出、不殘留於待接著體上且外觀優越的裝飾板。 【實施方式】 (實施發明的最佳形態) 鲁以下,麵赋更紐綱本發明之賴減其製造方法。 如第1圖所示,裝飾板1〇係由具有凹部2的待接著體i,及與該凹 部2大致_狀的裝飾圖案3所成,裝飾圖案3介由後述特定的固黏層4 固定於該凹部内。 /待,著體1係由金屬或各種合成樹脂所成,其材質並無特別限定。 又待接著體1之厚度亦無特別限定,依據裝飾板1〇之用途可為各式各 樣’又藉後述裝飾圖案3與固黏層4的合計厚度適宜選擇者,但一般為 500 〜5000# m 程度。 待接著體1之表面,形成有收容後述裝飾圖案3的凹部2。凹部2之 形成方法係依據待接著體i之材質而為各式各樣,因應於材質適宜選擇(6) The decorative plate according to any one of (1) to (5) above, wherein the decorative pattern is a plated image. (7) A decorative plate according to any one of (1) to (5) above, wherein the decorative pattern is an etched image. (8) A method of manufacturing a decorative panel, characterized in that: a decorative pattern temporarily attached to the support member is formed on the support member, and the decorative pattern is reproduced on the application tape having the adhesive layer, and then on the adhesive surface of the decorative pattern. Forming a cured layer for a decorative pattern selected from the group consisting of: (i) a mixed adhesive of a hot melt adhesive and an ultraviolet curable adhesive, (ii) a hot melt adhesive, and (iii) an adhesive having The decorative portion is fitted into the concave portion of the concave portion having the substantially the same shape as the decorative pattern, and the decorative pattern is fitted through the decorative layer with a decorative layer, and the application tape is peeled off from the decorative pattern. (9) The method for producing a decorative sheet according to the above (8), further comprising wherein the adhesive layer of the application tape contains an ultraviolet curable adhesive and the decorative pattern is copied after the application tape, and the ultraviolet ray is applied to the adhesive layer to lower Then follow the steps of strength. (10) The method for producing a decorative sheet according to the above (8) or (9), further comprising wherein the decorative pattern fixing layer comprises an ultraviolet curing adhesive and a hot-melt adhesive, and the decorative decorative pattern is in the concave portion to be attached Thereafter, ultraviolet rays are irradiated from the application tape side, and heating or heating and pressurization are applied from the application tape side. (11) The method for manufacturing a decorative panel according to the above (8) or (9), further comprising a decorative layer for fixing OP050130/SF-1176F 7 1262140, the adhesive layer containing a hot melt adhesive and a fitting decorative pattern to be attached to the body After the recess, the step of heating or heating and pressurizing is applied from the side of the application belt. (12) The method for producing a decorative panel according to any one of the above (8) to (11), further comprising: arranging the decorative pattern on the support member in a row; step. (13) The method for producing a decorative panel according to any one of the above (8) to (11), further comprising the step of temporarily coating the decorative pattern on the support member in a state in which the decorative pattern is temporarily adhered to the support member. (14) The method for producing a decorative sheet according to any one of the above (8) to (11), further comprising the step of temporarily adhering the decorative pattern φ to the support member in a row, and coating the surface and the side surface of the decorative pattern with a resin, and The step of peeling off the surface of the resin coating is applied. (Effect of the Invention) According to the present invention, there is provided a decorative panel in which a minute decorative pattern is not strongened by an impact. Further, an image in which an image with sharp edges is prevented from being worn and which is prevented from being injured by contact, and a metal crucible having a paste can be effectively used and a manufacturing method thereof can be provided. Further, according to the present invention, there is provided a decorative sheet in which an adhesive for fixing a decorative pattern does not ooze out from the decorative pattern, does not remain on the object to be bonded, and has an excellent appearance. [Embodiment] (Best Mode for Carrying Out the Invention) The following is a method for manufacturing the invention. As shown in Fig. 1, the decorative panel 1 is formed of a to-be-attached body i having a recessed portion 2, and a decorative pattern 3 substantially constituting the recessed portion 2, and the decorative pattern 3 is fixed by a specific adhesive layer 4 to be described later. In the recess. The body 1 is made of metal or various synthetic resins, and the material thereof is not particularly limited. The thickness of the body 1 is not particularly limited, and may be selected according to the use of the decorative sheet 1 ', and the total thickness of the decorative pattern 3 and the adhesive layer 4 to be described later is appropriately selected, but generally 500 to 5000. # m degree. On the surface of the adherend 1, a recess 2 for accommodating the decorative pattern 3 to be described later is formed. The method of forming the concave portion 2 is various according to the material of the body to be bonded i, and is suitable for the material selection.

OP050130/SF-1176F 8 1262140 具成型。凹o f旁兄時 ’亦可使用模 寬、長度辑圖案3大致相同。亦即,凹部2之 時,與褒飾_ 相同或比蘭微大。設心部務微大 300 為相 且對裝飾圖案之寬、長度設定為大100〜 产而、il又。凹部2之深度如後述,考慮裝飾圖案3與固著層4之厚OP050130/SF-1176F 8 1262140 with molding. When the concave o f is next to the brother', the mold width and the length pattern 3 can be used to be substantially the same. That is, the recess 2 is the same as the _ _ or slightly larger than the 兰. The center of the department is 300, and the width and length of the decorative pattern are set to be larger than 100 to il. The depth of the recess 2 is as described later, considering the thickness of the decorative pattern 3 and the fixing layer 4.

飾圖* 3係如記載於特開平7—331479號公報、·平8—27597號 么報等,藉公知之電朗像法錄造驗圖餅可,又藉_法、壓製 ^雷射光_法製造的微小_也可以。在該等之中,本發明係特別 是耩電鍍圖像絲聽所得之微小醜(以下,有時稱為_圖像)為 理想。本=_為上述裝侧案3,大部分都具有製造公司名、商品 名、商標等文字,圖形圖案的裝飾圖案,但不限定於此,亦可為各種之 裝飾圖案。 又裝飾圖案3之厚度理想為50〜200μιη,更理想為30〜150#111,特 別理想為30〜100#m。在裝飾圖案3之表面賦予花樣亦可,又施予著色 精電鍍亦可。 裝飾圖案3係介由固黏層4固定於待接著體1之凹部内。固黏層4 係選自由(i)熱熔化接著劑與紫外線硬化型接著劑的混合接著劑、 (ii)熱熔化接著劑及(iii)黏著劑所成之群。 作為紫外線硬化型之感壓接著劑之代表例,無任何限定,但可列舉 具有2個以上不飽和鍵之加成聚合性化合物或如具有環氧基的烷氧基矽 烷光聚合性化合物,與配合有例如羰基化合物或有機硫化合物、過氧化 物、胺、鑌鹽系化合物的光聚合引發劑之橡膠系感壓接著劑,或丙烯酸 系感壓接著劑等(參照曰本特開昭60-196956號公報)。光聚合性化合 物、光聚合引發劑之配合量,相對每100重量份聚合物,一般分別為10 〜500重量份、〇· 1〜20重量份。 熱熔化接著劑係以溶融狀態密黏於待接著體,冷卻時就固化而具有 接著性質者,各種熱溶化接著劑為眾所週知。較好係使用聚酯系之熱熔 化接著劑’通常係作為聚醋與芳香族碳氫化合物、環己_、二氧化梦等Decorations * 3 series are described in Unexamined No. 7-331479, No. 8-27597, etc., by the well-known electric lang image method to create a picture cake, and by _ method, suppression ^ laser light _ The tiny _ made by law can also be. Among these, the present invention is particularly preferable to a micro-clown (hereinafter sometimes referred to as an image) obtained by electroplating an image. This is the case of the above-mentioned case 3, and most of them have a decorative pattern such as a company name, a product name, a trademark, and the like, but are not limited thereto, and may be various decorative patterns. Further, the thickness of the decorative pattern 3 is preferably 50 to 200 μm, more preferably 30 to 150 #111, and particularly preferably 30 to 100 #m. A pattern may be applied to the surface of the decorative pattern 3, and a coloring plating may be applied. The decorative pattern 3 is fixed in the recess of the body to be bonded 1 by the adhesive layer 4. The anchor layer 4 is selected from the group consisting of (i) a hot-melt adhesive and a UV-curable adhesive, (ii) a hot-melt adhesive, and (iii) an adhesive. The representative example of the UV-curable pressure-sensitive adhesive is not particularly limited, and examples thereof include an addition polymerizable compound having two or more unsaturated bonds or an alkoxydecane photopolymerizable compound having an epoxy group, and A rubber-based pressure-sensitive adhesive containing a photopolymerization initiator such as a carbonyl compound or an organic sulfur compound, a peroxide, an amine or a phosphonium salt compound, or an acrylic pressure-sensitive adhesive or the like (refer to 曰本特开昭60- Bulletin No. 196956). The compounding amount of the photopolymerizable compound and the photopolymerization initiator is usually 10 to 500 parts by weight, and 1 to 20 parts by weight per 100 parts by weight of the polymer. The heat-melting adhesive is adhered to the body to be bonded in a molten state, and is solidified upon cooling to have a subsequent property. Various heat-melting adhesives are known. It is preferred to use a polyester-based hot melt adhesive agent 'usually as a polyester and an aromatic hydrocarbon, a cyclohexane, a dioxide dream, etc.

OP050130/SF-1176F 9 1262140 的混合接著劑所市販。本發明特別是使用JELCON AD-ΗΜΙ (十条化學 (股)公司製)、JELCON AD-HM6 (十条化學(股)公司製)等為理想, 可依需要併用遲乾劑、稀釋劑等。使用遲乾劑、稀釋劑時,其配合比率 係對主劑的聚酯100重量份,遲乾劑、稀釋劑之合計為20重量份之程度 為理想。 於固黏層4使用熱熔化接著劑與紫外線硬化型接著劑的混合接著劑 (i) 時,熱熔化接著劑與紫外線硬化型接著劑的混合比率(熱熔化接著 劑/紫外線硬化接著劑)(固形份重量比),理想係1· 5/1〜0· 5/1,更理想 為1· 2/1〜0· 8/1,特別理想為1.1/1〜〇. 9/1。 固黏層亦可由混合接著劑(i)所形成,又亦可從熱炼化接著劑 (ii) 形成。再者,混合接著劑(i)及熱熔化接著劑(ii),亦可用通 常接著劑中配合的充填劑、硬化助劑、黏著賦予劑之各種成分以任意比 率配合。 固黏層4亦可自黏著劑(iii)形成。在本發明特別是丙烯酸系接著 劑為理想,亦可依需要配合環氧樹脂等之硬化劑、醋酸溶纖素等之稀釋 劑。在此狀況,對作為主劑的丙烯酸系接著劑1〇〇重量份,硬化劑係以5 〜30重量份程度,稀釋劑係以5〜30重量份程度之比率使用。 本發明之裝飾板10,介由固黏層4固定裝飾圖案於凹部2内。固黏 層4之厚度理想上為10〜60,更理想為15〜50/zm,特別理想為15〜 30 gm 〇 又於本發明之裝飾板10,該裝飾圖案3與固黏層4的合計厚度,對 該凹部2之深度為_200"111〜+50/zm,更好為-150/zm〜+20/zm,特別好 在-100/zm〜±0#m之窥圍。 如此關於本發明的裝飾板10,裝飾圖案3介由固黏層4固定在待接 著體1之凹部2内,所以微小的裝飾圖案亦不引起圖像脫落。例如將此 固黏層4係由熱熔化接著劑與紫外線硬化型接著劑的混合接著劑(i)形 成時,由於紫外線照射條件為不適當的使紫外線硬化型接著劑之接著性 未充分展現時,藉熱熔化接著劑予以補完接著力,故能確實固定裝飾圖 案。又於使用熱熔化接著劑或粘著劑,不予實行紫外線照射,變成能固 OP050130/SF-1176F 10 1262140 定裝飾圖案。 又將裝飾圖案3與固勘声4 66人古ώ: & 述,裝飾圖_部之銳角部“ 2之深度設定為如上 1小攸捋接著體表面突出,所以邊緣銳利的圖 像圖案亦能防止磨耗及防止因接觸 ,帛細‘=== 裝飾了於裝飾圖案表面著色等當然容許形成樹脂層。 ^抛;’側钮刻之結果有時圖像側面會變成粗糙。此OP050130/SF-1176F 9 1262140 mixed adhesive is commercially available. In particular, it is preferable to use JELCON AD-ΗΜΙ (manufactured by Shijo Chemical Co., Ltd.), JELCON AD-HM6 (manufactured by Shijo Chemical Co., Ltd.), and the like, and a dry-drying agent, a diluent, or the like may be used in combination. When a dry adhesive or a diluent is used, the blending ratio is preferably 100 parts by weight of the polyester of the main component, and the total amount of the dry adhesive and the diluent is 20 parts by weight. When the adhesive (i) is mixed with the hot-melt adhesive and the ultraviolet curable adhesive in the adhesive layer 4, the mixing ratio of the hot-melt adhesive to the ultraviolet-curable adhesive (hot melt adhesive/ultraviolet hardening adhesive) The solid content ratio is preferably 1·5/1 to 0·5/1, more preferably 1·2/1 to 0·8/1, and particularly preferably 1.1/1 to 〇. 9/1. The solid layer may also be formed by mixing the adhesive (i) or from the heat refining adhesive (ii). Further, the mixed adhesive (i) and the hot-melt adhesive (ii) may be blended at any ratio with various components of a filler, a hardening aid, and an adhesion-imparting agent which are usually blended in the adhesive. The adhesive layer 4 can also be formed from the adhesive (iii). In the present invention, in particular, an acrylic adhesive is preferable, and a curing agent such as an epoxy resin or a diluent such as cellulose acetate may be blended as needed. In this case, the acrylic adhesive as a main component is used in an amount of from 5 to 30 parts by weight, and the diluent is used in an amount of from 5 to 30 parts by weight, based on 1 part by weight of the curing agent. The decorative panel 10 of the present invention fixes the decorative pattern in the recess 2 via the adhesive layer 4. The thickness of the adhesive layer 4 is desirably 10 to 60, more desirably 15 to 50/zm, particularly preferably 15 to 30 gm. Further, in the decorative panel 10 of the present invention, the total of the decorative pattern 3 and the adhesive layer 4 The thickness, the depth of the recess 2 is _200 "111~+50/zm, more preferably -150/zm~+20/zm, particularly preferably -100/zm~±0#m. Thus, with respect to the decorative panel 10 of the present invention, the decorative pattern 3 is fixed in the concave portion 2 of the body 1 to be attached via the adhesive layer 4, so that the minute decorative pattern does not cause the image to fall off. For example, when the adhesive layer 4 is formed of a mixed adhesive (i) of a hot-melt adhesive and an ultraviolet curable adhesive, when the ultraviolet irradiation condition is inappropriate, the adhesion of the ultraviolet curable adhesive is not sufficiently exhibited. The heat-melting adhesive is used to complete the bonding force, so that the decorative pattern can be surely fixed. Further, by using a hot-melt adhesive or an adhesive, ultraviolet irradiation is not performed, and it becomes a decorative pattern of OP050130/SF-1176F 10 1262140. Moreover, the decorative pattern 3 and the solid survey sound 4 66 people: "The sharp corner of the decorative figure _ part" is set to the above 1 small 攸捋 and then the surface of the body is prominent, so the sharp edge image pattern is also It can prevent wear and prevent contact, and the thickness of the decorative pattern is allowed to form a resin layer. ^Throwing; 'The result of the side button is sometimes roughened on the side of the image.

-之像側面。為了防止此不良情況,亦可於裝飾圖 i胸Γϋ讀龄覆。藉樹雜敷侧面會平滑化,所以能減低 =雜。如此_____之斜線硬化型聚合物,丙 产並混合系及聚胺他旨系之熱魏錢合辨形成,其厚 度^無特別限度,但理想為5〜25仰’更理想為5〜2〇仰,特別理想為 5〜15/zm。 其次說明本發明裝飾板1〇之製造方法。 首先,在支持構件11上整列暫時黏著形成裝飾圖案3。如錄關 木3之製造,例如亦可應用日本特開平Μ·號公號,特開平卜 27597號公報等記載之電鍍圖像法實行,又作為支持構件u,使_著 片等’由於在該黏著片上貼附金屬笛,將該金屬絲蝴法、壓製法、 雷射光線截切絲形成_,在黏著片上形成整列暫時黏著的裝飾圖案3 亦可。 又本發明,與形成裝飾圖案3之同時,亦可在圍繞裝飾圖案3之周 圍形成製程管理用圖案9。如此的製程管理用圖案9,最終予以去除,但 於後述固黏層4之形成B^r ’能作為掩蔽使用。又製程管理用圖宰亦可 形成有用以對位等的孔。 又,在此所謂的整列暫時黏著的裝飾圖案3,表示裝飾圖案以全體表 示製造公司名、商品名、商標等文字·圖形圖案狀態,且能夠剝離的固 定於支持構件11上之狀態。 作為如此的裝飾圖案3,從製造容易度等之觀點,特別是電鍍圖像或 OP050130/SF-1176F 11 1262140 钱刻圖像為理想。 μΪΪΓΓΓ,例如作為支持構件11 __,貼附金屬落 mi屬紅形成抗驗,祕光、顯像之後予以 蚀刻’取、,、去除抗鋪膜來實行。藉如此的方法, 裝飾圖案的_雜為整㈣_著陳態 ^離 钱刻圖像,作為黏著錄好使用紫外線硬化型黏著片。衣程為了今易剝離 時較侧案3之表面及麻設置上述脑魏層。設樹脂 示織,辦在支觸件11上,_胸黏著 w 2.恶’塗敷或嘴霧用以形成樹月旨被覆層的原料樹脂,使樹脂- The image side. In order to prevent this unfavorable situation, you can also read the age of the figure in the decorative figure. The side of the tree will be smoothed, so it can be reduced = miscellaneous. Such a _____ slant-hardening polymer, a C-produced and mixed system and a polyamine he is intended to form a heat, the thickness of the ^ is not particularly limited, but ideally 5 to 25 Yang' is more ideally 5~ 2 〇, especially ideal 5~15/zm. Next, a method of manufacturing the decorative panel of the present invention will be described. First, the decoration pattern 3 is temporarily adhered to the support member 11 in a row. For example, it is also possible to apply the electroplating image method described in the Japanese Patent Publication No. 27597, and the support member u, such as the support member u. A metal flute is attached to the adhesive sheet, and the wire-cutting method, the pressing method, and the laser cutting of the laser light are formed, and a decorative pattern 3 which is temporarily adhered to the entire surface is formed on the adhesive sheet. Further, in the present invention, the process management pattern 9 can be formed around the decorative pattern 3 at the same time as the decorative pattern 3. Such a process management pattern 9 is finally removed, but the formation of the adhesive layer 4, which will be described later, can be used as a mask. In addition, the process management can also be used to form holes for alignment and the like. In addition, the decorative pattern 3 which is temporarily adhered to the entire column is a state in which the decorative pattern is in a state of a character or graphic pattern such as a company name, a product name, or a trademark, and is detachably fixed to the support member 11. As such a decorative pattern 3, it is preferable from the viewpoint of ease of manufacture and the like, in particular, a plated image or an OP050130/SF-1176F 11 1262140 money-etched image. For example, as the supporting member 11 __, the metal is attached to the genus red to form an anti-test, and the secret light and the image are etched and removed, and the anti-film is removed. By such a method, the decorative pattern of the _ miscellaneous is the whole (four) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ In order to facilitate the peeling of the garment, the above-mentioned brain Wei layer is set on the surface and the hemp of the side case 3. Resin weaving, on the contact member 11, _ chest adhesion w 2. ’ 'coating or mouth mist used to form the raw material resin of the tree month coating, so that the resin

硬化。樹脂被覆層’經由後述2次的複製製程,配置在裝飾板1〇之露出 面側。設置如此的樹脂被覆層’則形成固定層的接著劑,或於複製製程 中使用t翻帶的接著劑’齡止_於裝_案3之表面及侧面。因 此衣衣程或固黏製程並不至於接著劑引起拉絲,故能製造無污染 的裝飾板10。 同本κ之目的,於裝飾圖案3之表面施予剝離處理也可以。在此作為 剝離劑’較好使用石夕氧系剝離劑。再者亦可在設樹脂被覆層後,在樹脂 被覆層表面辭_處理n不但能防止接__,如後述的最 後從裝飾圖案3 _朗帶12之際,裝飾圖案3附著於應用帶12側而 能防止剝離。 又,特別是本發明,按照日本特開平7—331479號公報記載之方法, 如第2圖所示於金屬板6表面上形成導電性被膜5,將此作為支持構件 11使用’於該導電性被膜5表面,藉電鍍圖像法,形成裝飾圖案3為理 想。 接著,將形成在支持構件11表面的裝飾圖案3,複製於具有接著劑 層7的應用帶12上。具體上係由基材8與接著劑層7所成的應用帶12, 貼附在裝飾圖案形成面,由於將應用帶12從支持構件u剝離,使裝飾 圖案3劇々於接賴層7之狀關離,麟裝侧案3複製在應用帶 12上。在形成蝕刻圖像之際,作為支持構件u使用黏著片之情況下,作 為應用帶12乃選擇其接著力大於該黏著片者。又,特別是作為支持餅 OP050130/SF-1176F 12 !262l4〇 係在敍刻圖像形成後實行紫外 則容易將裝飾圖案3複製在應 11,使用紫外線硬化型黏著片之情況下, 線硬化,予以降低支持構件側的接著力, 用帶12上。 又如第2圖所示,於金屬板6表面上形成導電性被膜5,於該導電性 裝侧案3時’如第3騎示,將裝觸案3夾持於導 ^性被膜5與_帶12辭_離,接著如第4圖示,料電性被膜5 ° _^°此的製程’從支持構件11將裝倚 ^木3複叔顧帶12之際’能防止過度之變形應力施加於裝飾圖案3 ’或防止裝飾圖案3飛散。hardening. The resin coating layer ′ is disposed on the exposed surface side of the decorative sheet 1 through a secondary copying process described later. The resin coating layer is provided to form an adhesive for the fixing layer, or the surface of the adhesive layer of the t-turning tape is used in the reproduction process. Therefore, the coating process or the solid-adhesive process does not cause the drawing to cause drawing, so that the non-contaminating decorative panel 10 can be manufactured. For the purpose of the κ, the surface of the decorative pattern 3 may be subjected to a release treatment. Here, as the release agent, it is preferred to use an anthracycline-based release agent. Further, after the resin coating layer is provided, the surface of the resin coating layer can be prevented from being processed, and the decorative pattern 3 can be attached to the application tape 12 at the end of the decorative pattern 3_lang tape 12, which will be described later. Side to prevent peeling. Further, in the present invention, the conductive film 5 is formed on the surface of the metal plate 6 as shown in Fig. 2, and the conductive member 5 is used as the support member 11 in accordance with the method described in Japanese Laid-Open Patent Publication No. Hei 7-331479. It is preferable to form the decorative pattern 3 by the plating image method on the surface of the film 5. Next, the decorative pattern 3 formed on the surface of the supporting member 11 is copied onto the application tape 12 having the adhesive layer 7. Specifically, the application tape 12 formed of the substrate 8 and the adhesive layer 7 is attached to the decorative pattern forming surface. Since the application tape 12 is peeled off from the supporting member u, the decorative pattern 3 is played on the adjacent layer 7. The shape is off, and the side case 3 is copied on the application belt 12. When an etched image is formed, in the case where an adhesive sheet is used as the supporting member u, the application tape 12 is selected such that its adhesive force is larger than that of the adhesive sheet. Further, in particular, as the support sheet OP050130/SF-1176F 12!262l4, after the formation of the image is carried out, it is easy to copy the decorative pattern 3 to the coating 11, and in the case of using the ultraviolet-curable adhesive sheet, the wire is hardened. The adhesion force on the side of the support member is lowered, and the belt 12 is used. Further, as shown in Fig. 2, the conductive film 5 is formed on the surface of the metal plate 6, and when the conductive case 3 is used, the tape contact 3 is sandwiched between the conductive film 5 and the third lens. _With 12 words _ away, and then as shown in the fourth figure, the process of the electrical film 5 ° _ ^ ° this 'from the support member 11 will be installed on the back of the wood 3 叔 顾 顾 belt 12 can prevent excessive deformation Stress is applied to the decorative pattern 3' or the decorative pattern 3 is prevented from scattering.

,用黏著劑於接著劑層7時,較好触將離模齡霧於裝飾圖案3 ^此如後述在最後從待接著體剝離應用帶12之際,能防止裝飾圖案 3附著在應用帶12側而剝離。 複製於應崎12的裝3,於秘餘再複製在雜著體上。 ,而’作為應用帶12的接著劑層7,係可使肖具有再剝離性的弱黏著性 劑或於紫外線·下降低接著力㈣外線硬化獅著劑等。 然而’於裝飾圖案3表面形成樹脂被覆層時,或施予剝離處理時, ,裝飾圖絲面無時12的接著力不會敎,所料限定闕接著劑 ’紫外線硬化型接’種種接著舰作為_帶12之接著麵7來使 用。特別是用以將裝飾圖案3最終狀於待接著體的固黏層4,使用同樣 或類似的接著劑’將自裝_案3露出的接賴,與接著綱7 一體化 能從裝飾圖案周邊部去除。 、形成固黏層4的接著劑如上所述,所謂與此類似的接著劑,係組 f物I*生與形成固黏層4的接者劑不同時,成為在形成上述固黏層的接 著劑相關說明之綱者。例如,職_ 4由鮮化接著雜紫外線硬 化型接著綱混合劑⑴形鱗,所謂與賴似的接著劑,絲示熱溶 化接著劑與紫精硬倾接著細合比率,魏實__黏層4不 同,但其配合比率仍在本說明書記載之範圍者。 朴應用帶上2之基材8較好經預先電暈放電處理後再形成接著劑層7。 藉此,能提絲材8與縣_ 7的㈣力,最倾待接著體剝離應用When the adhesive layer is applied to the adhesive layer 7, it is preferable to contact the mold age in the decorative pattern 3. Thus, when the application tape 12 is peeled off from the object to be bonded later, the decorative pattern 3 can be prevented from adhering to the application tape 12. Stripped on the side. Copy the 3 in the Acais 12 and copy it on the hybrid in the secret. Further, as the adhesive layer 7 of the application tape 12, it is possible to impart a re-adhesive weak adhesion agent or to reduce the adhesion force under the ultraviolet rays (4) an external hardening lion agent or the like. However, when a resin coating layer is formed on the surface of the decorative pattern 3, or when the peeling treatment is applied, the decorative force of the decorative silk surface is not smashed, and the adhesive is limited to the 'ultraviolet hardening type'. It is used as the back surface 7 of the tape 12 . In particular, the decorative layer 3 is finally formed in the adhesive layer 4 to be bonded to the body, and the same or similar adhesive is used to expose the attachment of the self-installation method 3 to the periphery of the decorative pattern. Part removed. The adhesive forming the adhesive layer 4 is as described above, and the like is a similar adhesive, and when the group I* is different from the carrier forming the solid layer 4, it becomes the formation of the above-mentioned solid layer. The relevant instructions of the agent. For example, the job _ 4 is made of fresh and then UV-curable type of sizing agent (1) scale, the so-called with the like, the wire shows the hot melt adhesive and the purple fine hard to pour the fine ratio, Wei Shi __ sticky The layer 4 is different, but the compounding ratio is still within the scope of the description. The substrate 8 with the upper layer 2 is preferably subjected to a pre-corona discharge treatment to form the adhesive layer 7. In this way, it is possible to raise the wire 8 and the (four) force of the county _ 7, which is the most suitable for the peeling application of the body.

OP050130/SF«1176F 13 1262140 帶12之際,能防止裝飾圖案3殘黏接著劑層7的接著劑。 又於接著劑層7中含有紫外線硬化型接著劑時,作為基材8係使用 各種透明或半透明的樹脂薄膜。所謂接著劑層7中含有紫外線硬化型接 著劑之情況,包含應用帶12為通用之UV帶(紫外線硬化型黏著帶)之 情況以及接著劑層7為熱熔化接著劑與紫外線硬化型接著劑的混合接著 劑(i)之情況兩者。 作成如上述,於具有接著劑層7的應用帶12上複製該裝飾圖案3之 後,接者劑層7中含紫外線硬化型接著劑時,如第5圖所示,照射紫外 線降低接者力。此時,從基材8面側照射紫外線使含紫外線硬化型接著 劑的接著 7全體充分硬化,亦棚定裝侧# 3的部分降低接著 力。 接著如第6圖所示,在固定裝飾圖案的面再形成固黏層4。固黏層4 之厚度理想為1G〜60卿更理想為15〜5G/zm,特別理想為15〜3〇// m 〇 使用於固黏層4的接著劑組成,係如上述,與應用帶12之接著劑層 7之組成同樣或不同均可,但理想為具有同樣或_的組成。 固黏層4之形成,例如將上述接著劑因應必要用溶劑稀釋後,藉絲 網印刷法、噴霧法等實行,理想為藉絲網印刷法來實行。 立形成固黏層4之際,亦可使用與裝飾圖案3具有大致同形狀之開口 ,的遮,。亦即,將遮罩之開口部與裝飾圖案3位置對準後,由於塗 敷、吹氣接著劑能將_層4形成於裝飾_ 3的露出面上。又如上所 述’开>成製程管理用圖案9亦能作為遮罩使用。 又’形成作為遮罩之製程管理用圖案9之情況下,塗敷吹氣接著劑 後,去除圖案9。 經由如此的製程,如第6圖所示,可僅在裝讎案3之露出面與僅 在,、週j部形成_層4,能減低雜於待接著體丨後的接鶴露出。 另方面’與上述不同,準備具有與裝飾圖案3大致同形狀凹部2 1 (第7 ® )。待接著體1由金域各種合麟賴成,並不 、別限疋其材質。又待接著體1之厚度特別並無特別限定,依據裝飾板OP050130/SF«1176F 13 1262140 When the belt 12 is worn, the adhesive of the decorative pattern 3 to the adhesive layer 7 can be prevented. Further, when the adhesive layer 7 contains an ultraviolet curable adhesive, various transparent or translucent resin films are used as the substrate 8. The case where the adhesive layer 7 contains an ultraviolet curable adhesive includes a case where the application tape 12 is a general-purpose UV tape (ultraviolet curing adhesive tape), and the adhesive layer 7 is a thermal fusion adhesive and an ultraviolet curing adhesive. Both of the cases of the adhesive (i) are mixed. As described above, when the decorative pattern 3 is reproduced on the application tape 12 having the adhesive layer 7, and the ultraviolet ray-curable adhesive is contained in the carrier layer 7, as shown in Fig. 5, ultraviolet rays are irradiated to lower the contact force. At this time, ultraviolet rays are irradiated from the surface side of the substrate 8 to sufficiently cure all of the entire ultraviolet ray-curable adhesive, and the portion of the venting side #3 is lowered in adhesion. Next, as shown in Fig. 6, the anchor layer 4 is further formed on the surface on which the decorative pattern is fixed. The thickness of the adhesive layer 4 is desirably 1 G to 60 cm, more preferably 15 to 5 G/zm, and particularly preferably 15 to 3 Å / m m. The adhesive composition used for the adhesive layer 4 is as described above, and the application tape The composition of the adhesive layer 7 of 12 may be the same or different, but desirably has the same or a composition. The formation of the anchor layer 4 is carried out, for example, by diluting the above-mentioned adhesive with a solvent, by a screen printing method, a spraying method, or the like, and is preferably carried out by a screen printing method. When the solidified layer 4 is formed, it is also possible to use a cover having an opening of substantially the same shape as the decorative pattern 3. That is, after the opening of the mask is aligned with the decorative pattern 3, the _ layer 4 can be formed on the exposed surface of the decorative _ 3 by the application and the blowing adhesive. Further, the "opening" pattern management pattern 9 can also be used as a mask. Further, in the case where the pattern management pattern 9 as a mask is formed, the pattern 9 is removed after the blowing of the blowing agent is applied. Through such a process, as shown in Fig. 6, it is possible to form the layer 4 only on the exposed surface of the mounting case 3 and only in the portion j of the circumference, and it is possible to reduce the exposure of the crane which is mixed with the body to be attached. On the other hand, unlike the above, the concave portion 2 1 (the seventh ® ) having substantially the same shape as the decorative pattern 3 is prepared. After the body 1 is made up of various kinds of Jinlin, it is not limited to its material. Further, the thickness of the body 1 is not particularly limited, depending on the decorative board.

OP050130/SF-H76F 14 1262140 10之用途有各種變化,但一般係500〜1〇〇〇_程度。凹部2之形成方法 依待接著體1之材質而異,因應材質而適當選擇方法。例如,壓製成形 或蝕刻法也可以,又合成樹脂之情況下,亦可使用模具成形。凹部2之 輪廓形狀係與裝飾圖案3大致同樣。亦即凹部2之寬、長度係設定為與 裝飾圖案3同樣或比此稍微大。將凹部設定為稍微大時,與裝飾圖案3 為相似形’且對裝飾圖案之寬、長度設定為大100〜300/zm的程度。凹 邠2之珠度係如上述,考慮裝飾圖案3與固黏層$之厚度而適宜設定。 接著,介由固黏層4固定裝飾圖案3於凹部内,實行待接著體1之There are various variations in the use of OP050130/SF-H76F 14 1262140 10, but generally it is 500~1〇〇〇. The method of forming the concave portion 2 varies depending on the material of the adherend 1, and the method is appropriately selected depending on the material. For example, a press forming or etching method may be used, and in the case of a synthetic resin, a mold may be used. The outline of the recess 2 is substantially the same as that of the decorative pattern 3. That is, the width and length of the recessed portion 2 are set to be the same as or slightly larger than the decorative pattern 3. When the concave portion is set to be slightly larger, it is similar to the decorative pattern 3, and the width and length of the decorative pattern are set to be about 100 to 300/zm. The bead of the concave ridge 2 is suitably set as described above in consideration of the thickness of the decorative pattern 3 and the adhesive layer $. Next, the decorative pattern 3 is fixed in the concave portion via the adhesive layer 4, and the body 1 to be adhered is implemented.

凹部2與裝飾圖案3的位置對準,將裝飾圖案3介由固黏層4嵌合於凹 部内(第8圖)。 接著,固黏層4由熱熔化接著劑與紫外線硬化型接著劑的混合接著 劑所成時,從應用帶側照射紫外、線(第9圖),且從應用帶側施予加熱或 加熱與加壓(第1〇圖)。於加熱或加熱與加壓處理,較好使用與裝飾圖 本3同大小的耐熱橡膠刻印13。其條件係因應於所使用熱溶化接著劑之 性質適宜的選擇,但較好橡膠表面溫度係9〇〜15〇〇c,更好為9〇〜13〇 C,理想的壓力係3〜5 kg/cm2,壓接時間較好為5〜15秒。紫外線照射 之際、,位於裝飾圖案3下面的固黏層4,藉裝飾圖案3所隱蔽,所以紫外 ,無法到達,維持未硬化之狀態,因此能將裝侧案3以充分接著力固 疋於凹部Θ。X假設鱗紫外絲辆冑,财硬蹄外線硬化型接著 劑時,藉鱗接著_完接著力,故能將裝飾_ 3確實目定在凹部 内m露出於裝飾圖案3週邊部的接著劑,瞧射紫外線而聚 合硬化,形成與應用帶12之接著劑層7 一體化的硬化物。特別是,將應 用帶12之接著劑層7與_層4 _同或類_接賴形成時,兩者堅 固的一體化。 又固黏層4用熱溶化接著劑形成時,如第1〇圖所示,從應用帶12 側,亦即應用帶12之基材8側施予加熱或加熱與加壓。此結果,介由固 黏層4能將裝飾圖案3峻在凹部内。—方面,露出於裝飾圖案3周邊 部的接著劑,形成與接著劑層7 一體化的硬化物。 最後,從待接著體1剝離應用帶12,在基材8上,從接著劑層7及The concave portion 2 is aligned with the position of the decorative pattern 3, and the decorative pattern 3 is fitted into the concave portion via the adhesive layer 4 (Fig. 8). Next, when the adhesive layer 4 is formed of a mixed adhesive of a hot-melt adhesive and an ultraviolet curable adhesive, the ultraviolet rays and the wires are irradiated from the application tape side (Fig. 9), and heating or heating is applied from the application tape side. Pressurize (Figure 1). For heat treatment or heating and pressure treatment, it is preferred to use heat-resistant rubber engraving 13 of the same size as the decorative figure 3. The conditions are suitably selected depending on the nature of the hot melt adhesive to be used, but the surface temperature of the rubber is preferably 9 〇 15 15 ° C, more preferably 9 〇 13 〇 C, and the ideal pressure system is 3 〜 5 kg. /cm2, the crimping time is preferably 5 to 15 seconds. When the ultraviolet ray is irradiated, the adhesive layer 4 located under the decorative pattern 3 is concealed by the decorative pattern 3, so that the ultraviolet ray cannot be reached and remains unhardened, so that the side case 3 can be fixed with sufficient adhesion. Concave Θ. X assumes that the scale is UV-cured, and when the hard-hardened outer-line hardening type of adhesive is used, the squaring is followed by the force, so that the decoration _3 can be surely exposed to the adhesive in the peripheral portion of the decorative pattern 3 in the concave portion. The ultraviolet rays are irradiated and polymerized and hardened to form a cured product integrated with the adhesive layer 7 of the application tape 12. In particular, when the adhesive layer 7 of the application tape 12 is formed in the same manner as the _ layer 4 _ or the same type, the two are firmly integrated. Further, when the anchor layer 4 is formed of a hot melt adhesive, as shown in Fig. 1, the heating or heating and pressurization are applied from the side of the application belt 12, that is, the side of the substrate 8 to which the belt 12 is applied. As a result, the decorative pattern 3 can be made to protrude in the concave portion via the adhesive layer 4. On the other hand, the adhesive exposed to the peripheral portion of the decorative pattern 3 forms a cured product integrated with the adhesive layer 7. Finally, the application tape 12 is peeled off from the body 1 to be bonded, on the substrate 8, from the adhesive layer 7 and

OP050130/SF - 1176F 15 1262140 裝飾圖案露出之固黏層用接著劑硬化物伴隨應甩帶12剝離。露出於裝飾 圖案3周邊部之接著劑,因與接著劑層7 —體化,所以在待接著體1表 面或裝飾圖案3之周邊部,不殘留固黏層用接著劑之硬化物。此結果, 於待接著體1之凹部内,裝飾圖案3介由固黏層4固定,獲得第1圖所 示之本發明裝飾板1〇。 特別是在裝飾圖案3之表面及側面設置樹脂被覆層,則形成固黏層$ 的接著劑或於複製製程使用的應用帶12之接著劑層7,能防止殘黏在裝 飾圖案3之表面及側面。因此於複製製程或固定製程中,接著劑不會引 起拉絲,能製造無污染的裝飾板10。 曰 又在裝飾圖案3表面施予剝離處理,不但能防止於裝飾圖案3表面 的接著劑殘黏,欲從裝飾圖案3剝離應用帶12之際,為了使應用帶與裝 飾圖案表面之間確實地剝離,能防止裝飾圖案3附著在應用帶12侧而剝 離者,變成能將裝飾圖案3確實固定於待接著體1之凹部内。 又,固黏層4含紫外線硬化型接著劑時,因應必要實行蝕刻,使紫 外線硬化型接著劑之未硬化物(接著劑)的接著力更提高,能堅固的將 裝飾圖案3接著於待接著體1的凹部内。 又,構成固黏層4的接著劑含熱熔化接著劑時,耐熱橡膠刻印後, 較好接者劑之溫度在50°C以上狀態,很快的剝離應用帶為理想。溫度過 於降低則熱熔化接著劑之接著力變強,剝離成困離,又有時裝飾圖案3 之周邊部會殘留露出的接著劑。 # (產業上之利用可能性) #依本發明,提供微小的裝飾圖案亦不會因衝擊使圖像脫落而可堅固 接著之裝飾板。又,提供能防止邊緣銳利的圖像磨耗及防止因接觸而受 傷且裝飾@案能有效顧本來具有的金屬光澤的裝飾板及其製造方法。 再者’依本發明,用以gj定裝飾圖案的接著劑,不至於從裝飾圖案露 出,殘黏在待接著體上,提供外觀優越的裝飾板。 八OP050130/SF - 1176F 15 1262140 The adhesive layer exposed by the decorative pattern is peeled off by the adhesive tape 12 with the adhesive. The adhesive exposed to the peripheral portion of the decorative pattern 3 is integrated with the adhesive layer 7, so that the cured portion of the adhesive for the adhesive layer does not remain on the surface of the surface to be bonded 1 or the peripheral portion of the decorative pattern 3. As a result, in the concave portion of the body 1 to be bonded, the decorative pattern 3 is fixed by the fixing layer 4, and the decorative sheet 1 of the present invention shown in Fig. 1 is obtained. In particular, when a resin coating layer is provided on the surface and the side surface of the decorative pattern 3, an adhesive for forming the adhesive layer $ or an adhesive layer 7 for the application tape 12 used in the replication process can be prevented from sticking to the surface of the decorative pattern 3 and side. Therefore, in the copying process or the fixed process, the adhesive does not cause drawing, and the non-contaminating decorative panel 10 can be manufactured. Further, the enamel is applied to the surface of the decorative pattern 3 to prevent the adhesive on the surface of the decorative pattern 3 from sticking. When the application tape 12 is to be peeled off from the decorative pattern 3, in order to surely apply the surface between the application tape and the decorative pattern. The peeling prevents the decorative pattern 3 from adhering to the side of the application tape 12 and peels off, so that the decorative pattern 3 can be surely fixed in the concave portion of the body 1 to be bonded. Further, when the adhesive layer 4 contains an ultraviolet curable adhesive, etching is required to improve the adhesion of the uncured material (adhesive) of the ultraviolet curable adhesive, and the decorative pattern 3 can be firmly adhered to Inside the recess of the body 1. Further, when the adhesive constituting the solidified layer 4 contains a hot-melt adhesive, after the heat-resistant rubber is imprinted, the temperature of the good carrier is preferably 50 ° C or higher, and it is preferable to apply the tape quickly. When the temperature is too low, the adhesive force of the hot-melt adhesive becomes strong, and the adhesive is peeled off, and the exposed adhesive remains in the peripheral portion of the decorative pattern 3. # (Industrial Applicability) # According to the present invention, a minute decorative pattern is provided, and the image is not detached by the impact, and the decorative sheet can be sturdy. Further, it is possible to provide a decorative panel which can prevent sharp edges from being worn by an image and which can be prevented from being damaged by contact, and which can effectively take care of the metallic luster which the original has. Further, according to the present invention, the adhesive for decorating the decorative pattern is not exposed from the decorative pattern, and remains adhered to the body to be attached, thereby providing a decorative sheet having an excellent appearance. Eight

OP050130/SF-1176F 16 1262140 【圖式簡單說明】 第1圖係顯示關於本發明之裝飾板之一形態剖面圖。 第2圖係顯示本發明製造方法之一製程概略圖。 第3圖係顯示本發明製造方法之一製程概略圖。 第4圖係關於本發明製造方法之一製程概略圖。 第5圖係關於本發明製造方法之一製程概略圖。 第6圖係關於本發明製造方法之一製程概略圖。 第7圖係關於本發明製造方法之一製程概略圖。 第8圖係關於本發明製造方法之一製程概略圖。OP050130/SF-1176F 16 1262140 [Simplified description of the drawings] Fig. 1 is a cross-sectional view showing a state of a decorative panel according to the present invention. Fig. 2 is a schematic view showing a process of a manufacturing method of the present invention. Fig. 3 is a schematic view showing a process of a manufacturing method of the present invention. Fig. 4 is a schematic view showing a process of a manufacturing method of the present invention. Fig. 5 is a schematic view showing a process of a manufacturing method of the present invention. Fig. 6 is a schematic view showing a process of a manufacturing method of the present invention. Fig. 7 is a schematic view showing a process of a manufacturing method of the present invention. Fig. 8 is a schematic view showing a process of a manufacturing method of the present invention.

第9圖係關於本發明製造方法之一製程概略圖。 第10圖係關於本發明製造方法之一製程概略圖。 【符號之說明】 1 待接著體 2 凹部 3 裝飾圖案 4 固黏層 5 導電性被膜 6 金屬板 7 接著劑層 8 基材 9 製程管理用圖案 10 裝飾板 11 支持構件 12 應用帶 13 对熱橡膠刻印 17Fig. 9 is a schematic view showing a process of a manufacturing method of the present invention. Fig. 10 is a schematic view showing a process of a manufacturing method of the present invention. [Description of symbols] 1 to the body 2 recess 3 decorative pattern 4 solid layer 5 conductive film 6 metal plate 7 adhesive layer 8 substrate 9 process management pattern 10 decorative plate 11 support member 12 application tape 13 pairs of hot rubber Mark 17

OP050130/SF-1176FOP050130/SF-1176F

Claims (1)

1262140 、 第094111403號專利申請案申請專利範圍未劃線修正本 94年1〇月7日 十、申請專利範圍: •種装飾板’其特徵為由具有凹部的待接著體及與該凹部大致同形狀之 ^飾圖案所成,裝飾圖案係介由熱熔化接著劑與紫外線硬化型接著劑的 處合接著劑所成之裝飾圖案用之固黏層固定於該凹部内者。 •種褒飾板’其特徵為由具有凹部的待接著體及與該凹部大致同形狀的 裝飾圖案所成’裝飾圖案係介由熱熔化接著劑所成之裝飾圖案用固黏層 固定於該凹部者。 3 種装飾板’其特徵為由具有凹部的待接著體及與該凹部大致同形狀之 裝飾圖案所成’裝飾圖案係介由黏著劑所成之裝飾圖案用固黏層固定於 Φ 該凹部者。 4·如申請專利範圍第1至3項中任一項之裝飾板,其中於裝飾板圖案表面 及侧面設有樹脂被覆層。 5·如申請專利範圍第1至3項中任一項之裝飾板,其中裝飾圖案與裝飾圖 案用固黏層合計厚度係相對該凹部之深度,在-200〜+50//m之範 圍。 6·如申請專利範圍第1至3項中任一項之裝飾板,其中裝飾圖案為電鍍圖 像者。 7·如申請專利範圍第1至3項中任一項之裝飾板,其中裝飾圖案為蝕刻圖 像者。 _ 8. 一種裝飾板之製造方法,其特徵於支持構件上,形成裝飾圖案為整列暫 時黏著,複製該裝飾圖案於具有接著劑層的應用帶上, 接著使裝飾圖案接著的面形成選自由下列所組成組群之裝飾板用固黏 層: (i) 熱熔化接著劑與紫外線硬化型接著劑的混合接著劑, (ii) 熱熔化接著劑,以及 (iii) 黏著劑 . 將裝飾圖案介由裝飾圖案用固黏層,嵌合該裝飾圖案於具有大致同 形狀之凹部的待接著體之該凹部, 從裝飾圖案剝離應用帶。 OP050130/SF-1176F 18 1262140 第094m403號專利申請案申請專利範圍未劃線修正本 94年10月7日 ,9·如申請專利範圍第8項之裝飾板之製造方法,其中更包含其中應用帶之 接著層含紫外線硬化型接著劑,且複製該裝飾圖案於應用帶後,照射紫 外線於該接著劑層使接著力降低的步驟。 10. 如申請專利範圍第8或9項之裝飾板之製造方法,其中更包含其中裝 飾圖案用固黏層含紫外線硬化型接著劑及熱熔化接著劑且嵌合裝飾圖案 於待接著體凹部後,從應用帶侧照射紫外線且從應用帶側施予加熱或加 熱與加壓之步驟。 11. 如申請專利範圍第8或9項之裝飾板之製造方法,其中更包含其中裝 飾圖案用固黏層含熱炼化接著劑且搬合裝飾圖案於待接著體凹部後,從 g 應用帶側施予加熱或加熱與加壓之步驟。 12·如申請專利範圍第8或9項之裝飾板之製造方法,其中更包含在支持 構件上,以整列暫時黏著裝飾圖案之狀態,於裝飾圖案表面施予剝離處 理之步驟。 13·如申請專利範圍第8或9項之裝飾板之製造方法,其中更包含在支持 構件上以整列暫時黏著裝飾圖案之狀態,以樹脂被覆裝飾圖案表面及侧 面之步驟。 14·如申請專利範圍第8或9項之裝飾板之製造方法,其中更包含在支持 構件上以整列暫時黏著裝飾圖案之狀態,以樹脂被覆裝飾圖案表面及侧 面,且樹脂被覆表面施予剝離處理之步驟。 OP050130/SF-1176F 19Patent Application No. 1262140, No. 094,111, 403, the patent application scope is not underlined, and the patent application scope is as follows: • The decorative panel is characterized in that it is characterized by a concave body having a concave portion and substantially the same as the concave portion. The shape is formed by a decorative pattern in which the decorative layer is fixed to the recess by a fixing layer for a decorative pattern formed by a heat-fusible adhesive and an ultraviolet-curable adhesive. a seed plaque 'characterized by a decorative body having a concave portion and a decorative pattern having a shape substantially the same as the concave portion. The decorative pattern is fixed to the decorative pattern by a heat-melting adhesive. Concave. The three decorative panels are characterized in that they are formed by a decorative body having a concave portion and a decorative pattern having a shape substantially the same as the concave portion. The decorative pattern is fixed to the concave portion by a fixing layer formed by an adhesive. . The decorative sheet according to any one of claims 1 to 3, wherein a resin coating layer is provided on the surface and the side surface of the decorative sheet pattern. The decorative panel according to any one of claims 1 to 3, wherein the decorative pattern and the decorative pattern have a total thickness of the fixing layer relative to the depth of the recess, in the range of -200 to +50//m. 6. A decorative panel according to any one of claims 1 to 3, wherein the decorative pattern is a plated image. 7. A decorative panel according to any one of claims 1 to 3, wherein the decorative pattern is an etched image. _ 8. A method of manufacturing a decorative panel, characterized in that a decorative pattern is formed on the supporting member for temporary adhesion, and the decorative pattern is reproduced on an application tape having an adhesive layer, and then the surface of the decorative pattern is formed to be selected from the following The cured layer of the decorative panel of the group consisting of: (i) a mixed adhesive of a hot melt adhesive and an ultraviolet curable adhesive, (ii) a hot melt adhesive, and (iii) an adhesive. The decorative pattern has a fixing layer, and the decorative pattern is fitted to the concave portion of the body to be joined having a substantially identical concave portion, and the application tape is peeled off from the decorative pattern. OP050130/SF-1176F 18 1262140 Patent application No. 094m403 Patent application area is not underlined. The method of manufacturing the decorative board according to item 8 of the patent application, which is included in the patent application, is included in the application method. The adhesive layer contains an ultraviolet curable adhesive, and the step of applying the decorative pattern to the application tape and irradiating the ultraviolet light to the adhesive layer to lower the adhesive force is reproduced. 10. The method of manufacturing a decorative panel according to claim 8 or 9, further comprising wherein the decorative pattern fixing layer comprises an ultraviolet curing adhesive and a hot melt adhesive and the decorative decorative pattern is after the recess of the body to be attached The step of irradiating ultraviolet rays from the application tape side and applying heat or heating and pressurization from the application tape side. 11. The method of manufacturing a decorative panel according to claim 8 or 9, further comprising wherein the decorative pattern fixing layer comprises a heat refining adhesive and the decorative pattern is moved after the recess of the body to be attached, The steps of heating or heating and pressurizing are applied sideways. 12. The method of manufacturing a decorative panel according to claim 8 or 9, further comprising the step of applying a peeling treatment to the surface of the decorative pattern in a state in which the decorative member is temporarily adhered to the supporting member. The method of manufacturing a decorative panel according to claim 8 or claim 9, further comprising the step of coating the surface and the side surface of the decorative pattern with a resin in a state in which the decorative member is temporarily adhered to the decorative member in a row. 14. The method of manufacturing a decorative panel according to the eighth or ninth aspect of the invention, further comprising the step of temporarily adhering the decorative pattern to the support member in a row, coating the surface and the side surface of the decorative pattern with a resin, and applying the peeling of the resin coated surface The steps of processing. OP050130/SF-1176F 19
TW94111403A 2005-04-11 2005-04-11 Decorative plate and its preparation TWI262140B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112770886A (en) * 2018-10-04 2021-05-07 凸版印刷株式会社 Craft paper for concrete decoration and press molding material for concrete decoration

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112770886A (en) * 2018-10-04 2021-05-07 凸版印刷株式会社 Craft paper for concrete decoration and press molding material for concrete decoration

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