TWI250996B

TWI250996B - Curable composition and color filter protective film

Info

Publication number: TWI250996B
Application number: TW089115739A
Authority: TW
Inventors: Masashige Takatori; Masayuki Endo
Original assignee: Jsr Corp
Priority date: 1999-09-01
Filing date: 2000-08-04
Publication date: 2006-03-11
Also published as: KR20010070042A; KR100631001B1

Abstract

The objective of the invention is to obtain a curable composition capable of providing a cured product excellent in heat resistance, flatness and transparency, especially a film for protecting a color filter, excellent in heat resistance. This curable composition comprises [A] a copolymer of (a1) a monomer containing an epoxy group, (a2) a maleimide-based monomer and (a3) other monomers, [B] at least one compound selected from a group of a polybasic carboxylic acid anhydride and a polybasic carboxylic acid, and [C] an epoxy resin different from the component [A]. The film for protecting the color filter is formed therefrom. The mixing ratio of [B] is 10 to 200 pts. wt. per 100 pts. wt. of [A], and the mixing ratio of [C] is 0.01-40 pts. wt. per 100 pts. wt. of [B].

Description

1250996 A7 —— B7 五、發明說明（1 ) 【發明的技術分野】本發明係關於硬化性組成物及濾色保護膜。更詳細而言’關於可賦於優良耐熱性以及透明性之硬化物，故適用於形成濾色保護膜之硬化性組成物以及濾色保護膜。【過去的技術】超扭轉絲狀液晶（S T N )方式的彩色液晶顯示元件經由，濾色保護膜上形成透明電極膜，且於其上面形成液晶定向膜之步驟而製得。此時欲加熱形成透明電極膜的步驟以及形成液晶定向膜的步驟，保護膜的溫度上昇至 2 5 0 °C以上，若保護膜的耐熱性不充分時透明電極膜中蒸散物會由保護膜侵入，使得透明電極膜的電阻增加而降低導電力，或保護膜本身會被著色而降低透明性。 .過去，作爲保護膜的材料，已知如特開平 6 - 1 5 7 7 1 6號公報所記載的共聚物等，相關的共聚物其依舊具有上述之問題。【發明欲解決的課題】. 本發明的目的爲提供一種硬化性組:成物，其含有具有優良耐熱性、平坦性以及透明性的硬化物。本發明的另一目的爲提供一種濾色保護膜，其由本發明的硬化性組成物所形成，具有優良的耐熱性以及透明性本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再菜： · _ 經濟部智慧財產局貝工消费合作社印製 -4- 1250996 Α7 _ Β7 五、發明說明（2 ) 【欲解決課題之方法】本發明中，上述的本發明的目的係由一種硬化性組成物’其含有第1〔A〕（al)不飽和羧酸以及/或不飽和羧酸無水物、（a2)含環氧基單體、（a3)馬來酸酐縮亞胺系單體以及（a 4 )其他單體之共聚物、〔B〕多官能性單體、〔C〕自由基引發劑者所達成。上述的硬化性組成物因應情況，可再含有〔D〕與上述〔A〕成份相異之環氧基樹脂以及〔E〕酸引發劑。本發明的上述目的係一種的硬化性組成物，其含有第 2〔A’〕（a2)含環氧基單體、（a3)馬來酸酐縮亞胺系單體以及（a 4 )其他單體之共聚物、〔F〕至少一種選自於多電子價羧酸無水物以及多電子價羧酸所成的群化合物，以及〔D ’〕與上述〔A ’〕成份相異之環氧基樹脂〇 . 上述的硬化性組成物，因應狀況，可再含有〔E ’〕酸引發劑。本發明的另一目的以及優點爲一種保護膜，由第3本發明的硬化組成物所形成之濾色保護膜。以下係對本發明的硬化性組成物的各成份作詳述。本發明的第1型態爲一種硬化性組成物’其含有〔A 〕（a 1)不飽和羧酸以及/或不飽和羧酸無水物、（ a 2)含有環氧基單體、（a 3)馬來酸酐縮亞胺系單體以及（a 4)其他單體的共聚物' 〔B〕多官能性單體、〔C〕自由基引發劑。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公f 一~ -5- ·!11!!裝·！ (請先閱讀背面之注意事項再頁：訂- 經濟部智慧財產局貝工消费合作社印製 1250996 A7 B7 五、發明說明（3 ) 上述的硬化性組成物，因應狀況，可再含有〔D〕與上述〔A〕成份相異之環氧基樹脂以及〔E〕酸引發劑。共聚物〔A ] 共聚物〔A〕可由化合物（al)、化合物（a2) 、化合物（a 3)以及化合物（a 4)於溶媒中，於聚合起始劑存在下，使其自由基聚合而製得。本發明所使用的共聚物〔A〕係由化合物（a 1 )衍生而得之構造單體，較佳爲含有5至5 0重量％、特佳爲 10至40重量％。此構造單位若未滿5重量％則此共聚物的耐熱性、耐藥物性、表面硬度會有下降的傾向。若超過4 0重量％之共聚物其保存安定性會下降。經濟部智慧財產局貝工消费合作社印製 §m& ϋ n si ml ϋ ϋ ϋ mm— n ϋ MMMm I · 1 el (請先閱讀背面之注意事項再頁) 作爲化合物（a 1)，例如有丙烯酸、甲基丙烯酸、巴豆酸等的單羧酸；如馬來酸、富馬酸、檸康酸、中康酸、衣康酸等的二羧酸；以及可舉出這些二羧酸無水物。其中，因由丙烯酸、甲基丙烯酸、無水馬來酸對於共聚物反應性、以及較易得到之優點而適合使用。這些化合物可單獨或組合使用。本發明所使用的共聚物〔A〕係由化合物（a 2 )衍生而得之構造單體，較佳爲含有1 0至，了〇重量％、特佳爲2 0至6 0重量％。此構造單位若未滿1 〇重量％則此共聚物的耐熱性、表面硬度會有下降的傾向。另一方面，若超過7 0重量％之共聚物其保存安定性會下降。作爲含有環氧基的單體（a2)如下述式（1)。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -6 - 1250996 A7 B7 五、發明說明（4 ch2=cr1250996 A7 - B7 V. INSTRUCTION DESCRIPTION (1) [Technical Fields of the Invention] The present invention relates to a curable composition and a color filter protective film. More specifically, the present invention relates to a cured product which can impart excellent heat resistance and transparency, and is therefore suitable for forming a curable composition for a color filter protective film and a color filter protective film. [Preliminary technique] A super-twisted filament liquid crystal (S T N ) type color liquid crystal display element is obtained by forming a transparent electrode film on a color filter protective film and forming a liquid crystal alignment film thereon. At this time, in order to heat the step of forming the transparent electrode film and the step of forming the liquid crystal alignment film, the temperature of the protective film rises to 250 ° C or higher, and if the heat resistance of the protective film is insufficient, the vaporized material in the transparent electrode film is protected by the protective film. The intrusion causes the resistance of the transparent electrode film to increase to lower the electric conductivity, or the protective film itself is colored to lower the transparency. In the past, as a material of the protective film, a copolymer such as that described in JP-A-6-1577-1166 is known, and the related copolymer still has the above problems. [Problem to be Solved by the Invention] An object of the present invention is to provide a curable group: a cured product comprising a cured product having excellent heat resistance, flatness, and transparency. Another object of the present invention is to provide a color filter protective film which is formed of the curable composition of the present invention and which has excellent heat resistance and transparency. The paper scale is applicable to the China National Standard (CNS) A4 specification (210 X 297 gong). PCT) (Please read the following notes on the back: · _ Ministry of Economic Affairs Intellectual Property Bureau Bayer Consumer Cooperative Print -4- 1250996 Α7 _ Β7 V. Invention Description (2) [Method to solve the problem] In the present invention The above object of the present invention is to provide a curable composition which contains a first [A] (al) unsaturated carboxylic acid and/or an unsaturated carboxylic acid anhydride, (a2) an epoxy group-containing monomer, ( A3) The maleic anhydride imide monomer and the (a 4) copolymer of another monomer, the [B] polyfunctional monomer, and the [C] radical initiator are achieved. The above-mentioned hardenable composition is required In other cases, it may further contain [D] an epoxy resin different from the above component [A] and an [E] acid initiator. The above object of the present invention is a curable composition containing the second [A']. (a2) an epoxy group-containing monomer, (a3) maleic anhydride a copolymer of an amine-based monomer and (a4) another monomer, [F] at least one selected from the group consisting of a polyelectrovalent carboxylic acid anhydride and a polyelectron valent carboxylic acid, and [D'] and the above [A '] an epoxy resin having a different composition. The above-mentioned curable composition may further contain an [E '] acid initiator depending on the condition. Another object and advantage of the present invention is a protective film. 3. A color filter protective film formed by the hardened composition of the present invention. Hereinafter, each component of the curable composition of the present invention will be described in detail. The first form of the present invention is a curable composition which contains [A]. (a1) an unsaturated carboxylic acid and/or an unsaturated carboxylic acid anhydride, (a2) an epoxy group-containing monomer, (a3) a maleic anhydride imide monomer, and (a4) another monomer Copolymer '[B] polyfunctional monomer, [C] free radical initiator. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 public f one ~ -5- ·! 11!! ·! (Please read the notes on the back page again: Order - Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Bayer Consumer Cooperative 1250996 A7 B7 V. INSTRUCTION DESCRIPTION OF THE INVENTION (3) The above-mentioned curable composition may further contain [D] an epoxy resin different from the above component [A] and an [E] acid initiator. A] The copolymer [A] can be obtained by radically polymerizing a compound (al), a compound (a2), a compound (a3) and a compound (a4) in a solvent in the presence of a polymerization initiator. The copolymer [A] used in the present invention is a structural monomer derived from the compound (a 1 ), preferably containing 5 to 50% by weight, particularly preferably 10 to 40% by weight. If the structural unit is less than 5% by weight, the heat resistance, chemical resistance, and surface hardness of the copolymer tend to decrease. If the copolymer exceeds 40% by weight, the preservation stability will decrease. Ministry of Economic Affairs, Intellectual Property Bureau, Bayer Consumer Cooperative, §m& ϋ n si ml ϋ ϋ ϋ mm— n ϋ MMMm I · 1 el (please read the note on the back page again) as compound (a 1), for example a monocarboxylic acid such as acrylic acid, methacrylic acid or crotonic acid; a dicarboxylic acid such as maleic acid, fumaric acid, citraconic acid, mesaconic acid or itaconic acid; and exemplified by these dicarboxylic acid anhydrides . Among them, acrylic acid, methacrylic acid, anhydrous maleic acid are suitable for use because of their copolymer reactivity and the advantages that are easily obtained. These compounds can be used singly or in combination. The copolymer [A] used in the present invention is a structural monomer derived from the compound (a 2 ), and preferably contains 10% by weight, 〇% by weight, particularly preferably 20% to 60% by weight. If the structural unit is less than 1% by weight, the heat resistance and surface hardness of the copolymer tend to decrease. On the other hand, if the copolymer exceeds 70% by weight, the storage stability may be lowered. The monomer (a2) containing an epoxy group is represented by the following formula (1). This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -6 - 1250996 A7 B7 V. Description of invention (4 ch2=cr

Rz COOCmH2ni — ^CH2 其中’可舉出R1表示氫原子或碳數爲1至5的烷基、 R2表示氫原子、甲基或乙基，而m爲1至8的整數，所表示的化合物。上述式（1 )中，m爲1至8，較佳爲1至4的整數。又’ R1表示氫原子或碳數爲1至5的低級烷基。此低級烷基可直鏈或支鏈任一皆可，作爲具體例爲甲基、乙基、 η -丙基、異丙基.、η - 丁基、異丁基、s e c — 丁基、 t e !· t - 丁基以及η -戊基可舉出。且R2表示氫原子、 -------------裝— * 0 (請先閱讀背面之注意事項再頁： ^ 經濟部智慧財產局員工消费合作社印製甲基或乙基上述式酸環氧丙基酸環氧丙基 1 )所表示的單體，例如有如（甲基）丙烯 α乙基丙烯酸環氧丙基、α — η —丙基丙烯 α - η -丁基丙烯酸環氧丙基、（甲基）丙烯酸—3，4 —環氧丁基、（甲基）丙烯酸一 4，5 —環氧戊基、（甲基）丙烯酸一 6，7 —環氧戊基、α —乙基丙烯酸一 6，7 —環氧戊基、（甲基）丙烯酸甲基環氧丙基等可舉出。其中特別以（甲基）丙烯酸環氧丙基較佳。這些單體可單獨或2種以上組合使用。本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公釐）經濟部智慧財產局員工消费合作社印製 1250996 A7 _ B7 五、發明說明（5 ) 本發明所使用的共聚物〔A〕係由化合物（a 3 )衍生而得之構造單體，較佳爲含有2至50重量％、特佳爲 5至40重量％。此構造單位若未滿2重量％則此共聚物的耐熱性、耐藥物性、表面硬度會有下降的傾向。另一方面，若超過5 0重量％時塗膜的成膜性會有下降的傾向。作爲馬來酸酐縮亞胺系單體（a3)，可舉出N-苯基馬來酸酐縮亞胺、N -苄基馬來酸酐縮亞胺、N -環己基馬來酸酐縮亞胺、N -琥珀銑酵亞胺基- 3 -馬來酸酐縮亞胺苯甲酸酯、N -琥珀銑酵亞胺基- 4 -馬來酸酐縮亞胺丁酸酯、N -琥珀銑酵亞胺基一 6 -馬來酸酐縮亞胺己酸酯、N -琥珀銑酵亞胺基- 3 -馬來酸酐縮亞胺丙酸酯、N-（9一吖啶基）馬來酸酐縮亞胺。這些化合物可單獨或2種以上組合使用。本發明所使用的共聚物〔A〕係由其他單體（a 4 ) 衍生而得之構造單體，較佳爲含有5至6 0重量％、特佳爲1 0至5 0重量％。此構造單位若未滿5重量％時，會有塗膜的成膜性不充分的狀況，又，或若超過6 0重量％時會有耐熱性或耐藥性不充分的狀況。作爲相關的其他單體成份（a 4 )，，例如可舉出，甲基甲基丙烯酸酯、乙基甲基丙烯酸酯、、h — 丁基甲基丙烯酸酯、s e c — 丁基甲基丙烯酸酯、t 一丁基甲基丙烯酸酯等甲基丙烯酸烷基酯；甲基丙烯酸酯、異丙基丙烯酸酯等丙烯酸烷基酯；環己基甲基丙烯酸酯、2 -甲基環己基甲基丙烯酸酯、三環〔5·2·1·02,6〕癸烷一8— 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -·1 ϋ ϋ n I n 1 ·1 1 I ϋ 1 I · ϋ ·1 ** (請先閱讀背面之注意事項再頁) 訂：綉· -8- 1250996 A7 _____________ B7 五、發明說明（6 ) 基甲基丙烯酸酯（該技術領域中以二環戊基甲基丙烯酸作爲慣用名詞）、二環戊基氧基乙基甲基丙烯酸酯、異冰片基甲基丙烯酸酯等甲基丙烯酸環狀烷基酯；環己基丙烯酸酯、2 -甲基環己基丙儲酸酯、三環〔 .5 · 2 · 1 · 02’ 6〕癸烷一 8 -基丙烯酸酯（該技術領域中以二環戊基丙烯酸作爲慣用名詞）、二環戊基氧基乙基丙烯酸酯、異冰片基丙烯酸酯等丙烯酸環狀烷基酯；苯基甲基丙烯酸酯、苄基丙烯酸酯等丙烯酸芳基酯；馬來酸二乙基、福馬酸二乙基、衣康酸二乙基等二羧酸二酯；2 -羥基乙基甲基丙烯酸酯、2 —羥基丙基甲基丙烯酸酯等羥基烷基酯；以及苯乙烯、α —甲基苯乙烯、m —甲基苯乙烯、P —甲基苯乙烯、乙烯甲苯、P —甲氧基苯乙烯、丙烯腈、甲基丙烯腈、氯化乙烯、氯化乙烯叉、丙烯醯胺基、甲基丙嫌醯胺基、醋酸乙烯基、1，3 - 丁二烯、異戊二烯、2，3 —二甲基一 1 ，3 — 丁二烯等。‘ 其中，以苯乙烯、t一丁基甲基丙烯酸酯、二環戊基甲基丙烯酸酯、P -甲氧基苯二烯、2 —甲基環己基丙烯酸酯、三環〔5 · 2 · 1 · 02’ 6〕癸烷一 8 —基甲基丙烯酸酯、三環〔5 · 2 · 1 · 02,6〕癸烷一 8 -基丙烯酸酯、1，3 — 丁二烯等由共聚物反應性的點上較爲佳’ 這些可單獨或組合使用。共聚物〔A〕的較佳具體例子爲’可舉出（甲基）丙烯酸/(甲基）丙烯酸環氧丙基/N 一苯基馬來酸酐縮亞胺/苯乙烯共聚物、（甲基）丙烯酸/(甲基）丙嫌酸環本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） !!·裝·1 * « (請先閱讀背面之注意事項再1^4頁) 訂- 線經濟部智慧財產局員工消费合作社印製 -9- 1250996 A7 B7 五、發明說明（7 ) (請先閱讀背面之注意事項再頁：氧丙基/N-環己基馬來酸酐縮亞胺/苯乙烯共聚物、（甲基）丙烯酸/(甲基）丙烯酸環氧丙基/N 一苯基馬來酸酐縮亞胺/苯乙烯/三環〔5·2·1·02’6〕癸烷一8-基（甲基）丙烯酸酯共聚物、（甲基）丙烯酸/ (甲基）丙嫌酸環氧丙基/N —環己基馬來酸酐縮亞女/ 苯乙烯/三環〔5·2·1·02’6〕癸烷一8—基（甲基）丙烯酸酯共聚物。經濟部智慧財產局員工消费合作社印製製造共聚物〔A〕時所使用的溶劑，具體而言可舉出，例如甲醇、乙醇等醇類；四氫呋喃等醚類；乙二醇單甲基醚、乙二醇單乙基醚等乙二醇醚類；甲基溶纖劑乙酸酯、乙基溶纖劑乙酸酯等乙二醇烷基醚乙酸酯類；二乙二醇單甲基醚、二乙二醇單乙基醚、二乙二醇二甲基醚、二乙二醇二乙基醚、二乙二醇乙基甲基醚等二乙二醇類；丙二醇甲基醚、丙二醇乙基醚、丙二醇丙基醚、丙二醇丁基醚等丙二醇單烷基醚類；丙二醇甲基醚乙酸酯、丙二醇乙基醚乙酸酯、丙二醇丙基醚乙酸酯、丙二醇丁基醚乙酸酯等丙二醇烷基醚乙酸酯類；丙二醇甲基醚丙酸酯、丙二醇乙基醚丙酸酯、丙二醇丙基醚丙酸酯、丙二醇丁基醚丙酸酯等丙二醇烷基醚乙酸酯類；甲苯、二甲，苯等芳香族碳水化合物；甲基乙基酮、環己酮、4 一羥基^4 一甲基一 2 — 戊酮等酮類；以及乙酸甲基、乙酸乙基、乙酸丙基、乙酸丁基、2 -羥基丙酮酸乙基、2 -羥基一 2 -甲基丙酮酸甲基、2 —羥基一 2 —甲基丙酮酸乙基、羥基乙酸甲基、羥基乙酸乙基、羥基乙酸丁基、乳酸甲基、乳酸乙基、乳本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -10- 經濟部智慧財產局員工消费合作社印製 1250996 A7 _ B7 五、發明說明（8 ) 酸丙基、乳酸丁基、3 -羥基丙酸甲基、3 -羥基丙酸乙基、3 -羥基丙酸丙基、3 —羥基丙酸丁基、2 -羥基一 3 —甲基丁酸甲基、甲氧基乙酸甲基、甲氧基乙酸乙基、甲氧基乙酸丙基、甲氧基乙酸丁基、乙氧基乙酸甲基、乙氧基乙酸乙基、甲氧基乙酸丙基、甲氧基乙酸丁基、丙氧基乙酸甲基、丙氧基乙酸乙基、丙氧基乙酸丙基、丙氧基乙酸丁基、丁氧基乙酸甲基、丁氧基乙酸乙基、丁氧基乙酸丙基、丁氧基乙酸丁基、2 —甲氧基丙酸甲基、2 —甲氧基丙酸乙基、2 —甲氧基丙酸丙基、2 —甲氧基丙酸丁基、2 —乙氧基丙酸甲基、2 —乙氧基丙酸乙基、2 —乙氧基丙酸丙基、2 -乙氧基丙酸丁基、2 —丁氧基丙酸甲基、2 -丁氧基丙酸乙基、2 —丁氧基丙酸丙基、2 -丁氧基丙酸丁基、3 —甲氧基丙酸甲基、3 —甲氧基丙酸乙基、3 —甲氧基丙酸丙基、3 —甲氧基丙酸丁基、3 —乙氧基丙酸甲基、3 -乙氧基丙酸乙基、3 —乙氧基丙酸丙基、3 -乙氧基丙酸丁基、3 —丙氧基丙酸甲基、3 -丙氧基丙酸乙基、3 -丙氧基丙酸丙基、3 -丙氧基丙酸丁基、3 -丁氧基丙酸曱基、3 —丁氧基丙酸乙基、3 —丁氧基丙酸丙基、3 - 丁氧基丙酸丁基等酯類。作爲使用於製造共聚物〔A〕的聚合起始劑’ 一般已知使用自由基聚合起始劑，例如2 ’ 2 ’ —偶氮二異丁腈、 2，2’一偶氮二一（2，4 一二甲基戊腈）、2，2’一偶氮二一（4 一甲氧基一 2，4 一二甲基戊腈）等偶氮化合物；過氧化苯甲酿、過氧化月桂酿、t -丁基過氧化三甲本紙張尺度適用中國國家標準（CNS〉A4規格（210 X 297公爱） ----I--— II--- -裝 i I * « <請先閱讀背面之注意事項再頁) 方：線· 11 - 1250996 A7 __ B7 五、發明說明（9 ) 基乙酸酯、1，1’一雙一（t 一過氧化丁基）環己烷等有機過氧化物；以及過氧化氫可舉出。作爲自由基聚合起始劑使用過氧化物時，過氧化物可與還原劑同時使用而作爲氧化還原型起始劑使用。使用於本發明的共聚物〔A〕，其聚苯乙烯換算重量平均分子量（以下，稱爲「Mw」）爲，一般以2X103 至5xl〇5，較佳爲5X103至1X105。若Mw不足2 X 1 0 3時，所得之包膜有耐熱性、表面硬度下降傾向。另一方面，若超過5 X 1 0 5時，有平坦性下降的傾向。多官能件單體ί B 1 作爲本發明所使用的多官能性單體〔Β〕，使用2官能或3官能以上的（甲基）丙烯酸酯爲佳。作爲上述2官能（甲基）丙烯酸酯，例如可舉出乙二醇（甲基）丙烯酸酯、1，6 —己二醇二（甲基）丙烯酸酯、1，9 一壬二醇二（甲基）丙烯酸酯、聚丙二醇二（甲基）丙烯酸酯、四乙二醇二（甲基）丙烯酸酯、雙苯氧基乙醇芴二丙烯酸酯等。作爲其商品例如有阿羅尼克斯Μ —210、同 Μ-240、同 M-62t〇0 (以上，東亞合成股份有限公司製）、K A Y A R A、.D H D D A、同 HX - 220、同R— 604 (以上，曰本化藥股份有限公司製）、比氏克特260、同312、同335HP( 以上，大阪有機化學工業股份有限公司製）等。作爲上述3官能以上的（甲基）丙烯酸酯’例如可舉本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） • ·1 ϋ 1 ϋ mm— β§Β ·1 ·ϋ a— 1 ϋ I · ·ϋ ι 麵 % <請先閱讀背面之注意事項再頁： I®]· 經濟部智慧財產局員工消費合作社印製 -12· 1250996 A7 -------^ B7 五、發明說明（1〇 ) 出三殘甲基丙院（甲基）丙烯酸酯、季戊四醇三（甲基）丙稀酸酯、三（（甲基）丙烯醯基氧基乙基）磷酸鹽、季戊四醇四（甲基）丙烯酸酯、二季戊四醇六（甲基）丙烯酸酯、二季戊四醇七（甲基）丙烯酸酯等。作爲商品例如有阿羅尼克斯M— 3 19、同M— 400、同Μ — 402 、同 Μ— 405 、同 μ-450、同 Μ — 7100、同 Μ 一 8083、同 Μ 〜8060、同 Μ — 1310、同 Μ — 1600、同 M —ig6〇、同 Μ 一 81〇〇、同 μ — 8530、同Μ— 8560、同Μ — 9050 (以上，東Rz COOCmH2ni - ^CH2 wherein '1' represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, R2 represents a hydrogen atom, a methyl group or an ethyl group, and m is an integer of 1 to 8, and the compound is represented. In the above formula (1), m is an integer of 1 to 8, preferably 1 to 4. Further, R1 represents a hydrogen atom or a lower alkyl group having 1 to 5 carbon atoms. The lower alkyl group may be either linear or branched, and specific examples thereof are methyl, ethyl, η-propyl, isopropyl, η-butyl, isobutyl, sec-butyl, te !· t-butyl and η-pentyl groups are mentioned. And R2 represents a hydrogen atom, ------------- loaded - * 0 (please read the notes on the back page again: ^ Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed methyl or ethyl The monomer represented by the above-mentioned acid epoxidized propyl propyl acrylate 1) is, for example, (meth) propylene α-ethyl acrylate epoxy propyl, α η propyl propylene α - η - butyl acrylate Epoxypropyl, (meth)acrylic acid-3,4-epoxybutyl, (meth)acrylic acid-4,5-epoxypentyl, (meth)acrylic acid-6,7-epoxypentyl, α-Ethyl acrylate-6,7-epoxypentyl group, methyl (meth)acrylate methyl epoxy group and the like can be mentioned. Among them, epoxypropyl (meth)acrylate is particularly preferred. These monomers may be used alone or in combination of two or more. This paper scale applies to China National Standard (CNS) A4 specification (210 297 297 mm) Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 1250996 A7 _ B7 V. Invention Description (5) Copolymer used in the present invention [A] The structural monomer derived from the compound (a 3 ) preferably contains 2 to 50% by weight, particularly preferably 5 to 40% by weight. If the structural unit is less than 2% by weight, the heat resistance, chemical resistance, and surface hardness of the copolymer tend to decrease. On the other hand, when it exceeds 50% by weight, the film formability of the coating film tends to decrease. Examples of the maleic anhydride imide monomer (a3) include N-phenylmaleic anhydride imide, N-benzyl maleic anhydride imide, and N-cyclohexyl maleic anhydride imide. N-Amber Milling Imino-3 - Maleic Anhydride benzoate, N-Amber Milling Imino-4 - Maleic Anhydride, N-Amber Milled Imine 1-6-maleic anhydride imide hexanoate, N-amber milling imido-3-maleic anhydride imide propionate, N-(9-acridinyl) maleic anhydride imide . These compounds may be used alone or in combination of two or more. The copolymer [A] used in the present invention is a structural monomer derived from the other monomer (a 4 ), preferably containing 5 to 60% by weight, particularly preferably 10 to 50% by weight. When the amount is less than 5% by weight, the film forming property of the coating film may be insufficient, or if it exceeds 60% by weight, heat resistance or chemical resistance may be insufficient. Examples of the other monomer component (a 4 ) which are related include methyl methacrylate, ethyl methacrylate, h-butyl methacrylate, sec-butyl methacrylate, and t-butyl group. Alkyl methacrylate such as acrylate; alkyl acrylate such as methacrylate or isopropyl acrylate; cyclohexyl methacrylate, 2-methylcyclohexyl methacrylate, tricyclic [5· 2·1·02,6] decane-8—This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -·1 ϋ ϋ n I n 1 ·1 1 I ϋ 1 I · ϋ ·1 ** (Please read the notes on the back page again) Order: Embroidery · -8- 1250996 A7 _____________ B7 V. Description of invention (6) Group methacrylate (dicyclopentylmethyl in the technical field) Acrylic acid as a conventional term), dicyclopentyloxyethyl methacrylate, isobornyl methacrylate, etc., methacrylic acid cyclic alkyl ester; cyclohexyl acrylate, 2-methylcyclohexyl propylene storage acid Ester, tricyclo [ .5 · 2 · 1 · 02' 6] decane 8-octyl acrylate ( In the technical field, dicyclopentylacrylic acid is used as a conventional term), dicyclopentyloxyethyl acrylate, isobornyl acrylate such as cyclic alkyl ester; phenyl methacrylate, benzyl acrylate, etc. Aryl acrylate; dicarboxylic acid diethyl ester, diethyl fumarate diethyl ester, diethyl itaconate dicarboxylate; 2-hydroxyethyl methacrylate, 2-hydroxypropyl methacrylate Isohydroxyalkyl ester; and styrene, α-methylstyrene, m-methylstyrene, P-methylstyrene, vinyl toluene, P-methoxystyrene, acrylonitrile, methacrylonitrile, Ethylene chloride, vinyl chloride fork, acrylamide, methyl propyl amide, vinyl acetate, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3 — Butadiene, etc. ' Among them, styrene, t-butyl methacrylate, dicyclopentyl methacrylate, P-methoxy benzenediene, 2-methylcyclohexyl acrylate, tricyclo [5 · 2 · 1 · 02' 6] decane 8-octyl methacrylate, tricyclo [5 · 2 · 1 · 02, 6] decane 8- acrylate, 1,3-butadiene, etc. Better on the spot' These can be used individually or in combination. A preferred specific example of the copolymer [A] is 'methacrylic acid/(meth)acrylic acid epoxypropyl/N-phenylmaleic anhydride imide/styrene copolymer, (methyl) Acrylic / (meth) propylene acid ring This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) !!·装·1 * « (Please read the back note first 1^4 Page) Order - Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumer Cooperatives Printed - 9- 1250996 A7 B7 V. Inventions (7) (Please read the notes on the back page again: Oxypropyl/N-cyclohexylmaleic anhydride Imine/styrene copolymer, (meth)acrylic acid/(meth)acrylic acid epoxypropyl/N-phenyl maleic anhydride imide/styrene/tricyclic [5·2·1·02' 6] decane-8-yl (meth) acrylate copolymer, (meth) acrylate / (meth) propylene succinic acid epoxy propyl / N - cyclohexyl maleic anhydride acetylene / styrene / three Cyclo [5·2·1·02'6] decane-8-yl (meth) acrylate copolymer. The Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, printed and manufactured copolymer [A] Specific examples of the solvent include alcohols such as methanol and ethanol; ethers such as tetrahydrofuran; glycol ethers such as ethylene glycol monomethyl ether and ethylene glycol monoethyl ether; and methyl cellosolve. Ethylene glycol alkyl ether acetate such as acetate or ethyl cellosolve acetate; diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol dimethyl ether, Diethylene glycol such as diethylene glycol diethyl ether or diethylene glycol ethyl methyl ether; propylene glycol monoalkyl ether such as propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol propyl ether or propylene glycol butyl ether Propylene glycol alkyl ether acetate such as propylene glycol methyl ether acetate, propylene glycol ethyl ether acetate, propylene glycol propyl ether acetate, propylene glycol butyl ether acetate; propylene glycol methyl ether propionate, Propylene glycol ethyl ether propionate, propylene glycol propyl ether propionate, propylene glycol butyl ether propionate, etc.; propylene glycol alkyl ether acetate; toluene, dimethyl, benzene and other aromatic carbohydrates; methyl ethyl ketone, a ketone such as cyclohexanone or 4-hydroxy-2-methyl-1-pentanone; and methyl acetate and ethyl acetate Acetate propyl, butyl acetate, ethyl 2-hydroxyacetonate, 2-hydroxy-2-methylpyruvate methyl, 2-hydroxy-2-ethylpyruvate ethyl, hydroxyacetic acid methyl, glycolic acid Base, hydroxyacetic acid butyl, lactic acid methyl, lactate ethyl, milk paper scale applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -10- Ministry of Economic Intelligence Intellectual Property Bureau employee consumption cooperative printed 1250996 A7 _ B7 V. INSTRUCTIONS (8) Acid propyl, butyl lactate, 3-hydroxypropionic acid methyl, 3-hydroxypropionic acid ethyl, 3-hydroxypropionic acid propyl, 3-hydroxypropionic acid butyl, 2 -hydroxy-3-methylbutyric acid methyl, methoxyacetic acid methyl, methoxyacetic acid ethyl, methoxyacetoxypropyl, methoxyacetic acid butyl, ethoxyacetic acid methyl, ethoxy Ethyl acetate, methoxyacetic acid propyl, methoxyacetic acid butyl, propoxyacetic acid methyl, propoxyacetic acid ethyl, propoxyacetic acid propyl, propoxy butyl acetate, butoxyacetic acid Methyl, butoxyacetic acid ethyl, butoxyacetic acid propyl, butoxyacetic acid butyl, 2-methoxypropionic acid methyl, 2 - methoxypropionic acid ethyl, 2-methoxypropionic acid propyl, 2-methoxypropionic acid butyl, 2-ethoxypropionic acid methyl, 2-ethoxypropionic acid ethyl, 2 —ethoxypropionic acid propyl, 2-ethoxypropionic acid butyl, 2-butoxypropionic acid methyl, 2-butoxypropionic acid ethyl, 2-butoxypropionic acid propyl, 2 - butyl butoxypropionate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, 3-methoxypropionic acid propyl, 3-methoxypropionic acid butyl, 3 - ethoxypropionic acid methyl, 3-ethoxypropionic acid ethyl, 3-ethoxypropionic acid propyl, 3-ethoxypropionic acid butyl, 3-propoxypropionic acid methyl, 3 - propoxypropionic acid ethyl, 3-propoxypropionic acid propyl, 3-propoxypropionic acid butyl, 3-butoxypropionic acid decyl, 3-butoxypropionic acid ethyl, 3 An ester such as butyloxypropionic acid propyl or 3-butoxypropionic acid butyl. As a polymerization initiator used for the production of the copolymer [A], it is generally known to use a radical polymerization initiator such as 2 ' 2 '-azobisisobutyronitrile, 2,2'-azobis(2) , 1,4-dimethylvaleronitrile, 2,2'-azobis(4-methoxy-2,4-dimethylpentanenitrile) and other azo compounds; benzoic peroxide, oxidized laurel Stuffed, t-butyl peroxylated paper standard for Chinese national standards (CNS>A4 specifications (210 X 297 public) ----I--- II----install i I * « <Please Read the precautions on the back page) Party: Line · 11 - 1250996 A7 __ B7 V. Description of invention (9) Organic acetate, 1,1'-double (t-butyl peroxide) cyclohexane, etc. Peroxide; and hydrogen peroxide can be mentioned. When a peroxide is used as a radical polymerization initiator, a peroxide can be used together with a reducing agent to be used as a redox type initiator. The copolymer [A] used in the present invention has a polystyrene-equivalent weight average molecular weight (hereinafter referred to as "Mw"), and is usually 2X103 to 5x10, preferably 5X103 to 1X105. When Mw is less than 2 X 1 0 3 , the obtained coating film has heat resistance and a tendency to lower the surface hardness. On the other hand, when it exceeds 5 X 1 0 5, flatness tends to decrease. Polyfunctional monomer ί B 1 As the polyfunctional monomer (Β) used in the present invention, it is preferred to use a 2 or more functional (meth) acrylate. Examples of the bifunctional (meth) acrylate include ethylene glycol (meth) acrylate, 1,6-hexane diol di(meth) acrylate, and 1,9 fluorene diol di(a). Acrylate, polypropylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, bisphenoxyethanoloxime diacrylate, and the like. As its products, for example, Aronix Μ-210, Μ-240, M-62t 〇0 (above, manufactured by Toagosei Co., Ltd.), KAYARA, .DHDDA, HX-220, and R-604 ( The above is made by Sakamoto Chemical Co., Ltd., bis, 260, 312, and 335HP (above, Osaka Organic Chemical Industry Co., Ltd.). As the above-mentioned trifunctional or higher (meth) acrylate, for example, the Chinese National Standard (CNS) A4 specification (210 X 297 mm) is applicable to the paper scale. • · 1 ϋ 1 ϋ mm—β§Β ·1 ·ϋ A-1 ϋ I · ·ϋ ι面% <Please read the notes on the back page: I®]· Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Print -12· 1250996 A7 -------^ B7 V. INSTRUCTIONS (1〇) Out of Sanwei Methyl Propylene (meth) acrylate, pentaerythritol tris(meth) acrylate, tris((meth) propylene decyl oxyethyl) phosphate Pentaerythritol tetra (meth) acrylate, dipentaerythritol hexa (meth) acrylate, dipentaerythritol hepta (meth) acrylate, and the like. As commodities, for example, there are Aronix M-3 19, the same M-400, the same - 402, the same - 405, the same μ-450, the same - 7100, the same as an 8083, the same ~ 8060, the same — 1310, the same Μ — 1600, with M — ig6 〇, the same Μ 81 〇〇, with μ — 8530, the same Μ — 8560, the same Μ — 9050 (above, East

亞合成股份有限公司製）、KAYARAD TMPTA 、同 DPHA、同 DPCA — 20、同 DPCA— 30、同DPCA—60、同DPCA—120(以上，曰本化藥股份有限公司製）、比氏克特295、同300、同 3 6 0、同G P T、同3 P A、同4 0 0 (以上，大阪有機化學工業股份有限公司製）等。這些2官能或3官能以上的（甲基）丙烯酸酯，可單獨或組合使用。多官能性單體〔B〕的使用量，每1 〇〇重量份的〔 A〕成份’通常爲1 〇至2 0 0重量份，較佳爲2 0至 1 5 0重量份。對於此使用範圍，可得到優良的高平坦性、密著性、耐藥物性、耐熱性之濾色保護膜。自由基起始劑〔C〕作爲本發明所使用的自由基起始劑〔C〕，係由熱以本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） --------------裝--- * · (請先閲讀背面之注意Ϋ項再6本頁) 訂·- --線· 經濟部智慧財產局員工消费合作社印製 -13- 經濟部智慧財產局員工消费合作社印製 1250996Synthetic Co., Ltd.), KAYARAD TMPTA, DPHA, DPCA-20, DPCA-30, DPCA-60, DPCA-120 (above, Sakamoto Chemical Co., Ltd.), Bishop 295, the same 300, the same 3 60, the same GPT, the same 3 PA, the same 400 (above, Osaka Organic Chemical Industry Co., Ltd.) and so on. These difunctional or trifunctional or higher (meth) acrylates may be used singly or in combination. The polyfunctional monomer [B] is used in an amount of usually from 1 Torr to 200 parts by weight, preferably from 20 to 1,500 parts by weight, per 1 part by weight of the [A] component. For this range of use, a color filter film excellent in high flatness, adhesion, chemical resistance, and heat resistance can be obtained. The radical initiator [C] is used as the radical initiator (C) used in the present invention, and is applied to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) by heat on the paper scale ---- ----------Install--- * · (Please read the note on the back and then on page 6) Order ·- -- Line · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing-13- Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, Printed 1250996

五、發明說明（11 ) 及/或先而產生自由基之化合物。作爲如此的化合物，可舉出聯二咪唑系化合物、苯偶因系化合物、三嗪系化合物、乙醯本系化合物、一苯甲嗣系化合物、α —二嗣系化合物、多核苯酮系化合物、咕噸酮系化合物、偶氮系化合物等。其中聯二咪唑系化合物、三嗪系化合物、乙醯苯系化合物、偶氮系化合物爲佳。上述聯二咪唑系化合物，例如爲 2 ’ 2 —雙（2 - 氯苯基）一4，4^，5，5 一一四（4 一乙氧基羰基苯基）一 1，2 — —聯二咪唑、 2，2/-雙（2—溴苯基）一4，4^，5，5一 —四（4 一乙氧基鑛基苯基）一 1，2 ' —聯二味β坐、 2 ’ 2 —雙（2 —氯苯基）一 4，4^，5，5' —四苯基一 1，2 / —聯二咪唑、 2，2 —雙（2 , 4 —二氯苯基）一 4 , 4 / ，5 ，5 / —四苯基一 1 ，2 / —聯二咪唑、 2，2 / —雙（2，4 · 6 -三氯苯基）一 4，4 一，5，5，一四苯基一 1，2，—聯二咪唑、 2，2/-雙（2-溴苯基）一4，4/，5，5一一四苯基一1，2^ -聯二咪唑、 2，2 / -雙（2，4 —二溴苯基)一 4，4 一，5 ，5 — -四苯基—1，2 / —聯二咪唑、 2，2 / —雙（2，4，6 -三溴苯基）一 4，4 一，5，-四苯基一 1，-聯二咪唑可舉出、這些聯二咪唑系化合物中較佳的化合物爲本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）5. Description of the invention (11) and/or compounds which generate free radicals first. Examples of such a compound include a biimidazole-based compound, a benzoin-based compound, a triazine-based compound, an acetamidine-based compound, a benzamidine-based compound, an α-diterpenoid compound, and a polynuclear benzophenone compound. , xanthone compound, azo compound, and the like. Among them, a diimidazole-based compound, a triazine-based compound, an acetophenone-based compound, and an azo-based compound are preferred. The above-mentioned biimidazole-based compound is, for example, 2'2-bis(2-chlorophenyl)-4,4^,5,5-tetra(4-ethoxycarbonylphenyl)-1,2- Diimidazole, 2,2/-bis(2-bromophenyl)-4,4^,5,5-tetra(4-ethoxyphenyl phenyl)-1,2'-linked di-flavor β , 2 ' 2 —bis(2-chlorophenyl)-4,4^,5,5'-tetraphenyl- 1,2 /-biimidazole, 2,2-bis(2,4-dichlorobenzene Base) a 4, 4 / , 5 , 5 / - tetraphenyl - 1 , 2 / - biimidazole, 2, 2 / - bis (2,4 · 6 - trichlorophenyl) - 4, 4 one, 5,5,tetraphenyl-1,2,-diimidazole, 2,2/-bis(2-bromophenyl)-4,4/,5,5-tetraphenyl-1,2^ -biimidazole, 2,2 / -bis(2,4-dibromophenyl)-4,4,5,5-tetraphenyl- 1,2 /-biimidazole, 2,2 / Bis(2,4,6-tribromophenyl)- 4,4-,5,-tetraphenyl-1,-biimidazole, the preferred compound among these bi-diimidazole-based compounds is a paper Scale applies to Chinese national standards CNS) A4 size (210 X 297 mm)

-14- 1250996 A7 __ B7 五、發明說明（12 ) 2，2^ -雙（2 -氯苯基）一 4，4^，5，5 一一四苯基一1，—聯二咪唑、 --------------裝--- * > (請先閱讀背面之注意事項再頁) 2，2 雙（2，4 一二氯苯基）一 4，4 —，5 ，5 / —四苯基一 1，2，一聯二咪唑、 2，2 > —雙（2，4 · 6 —三氯苯基）一 4，4丫 ’ 5，5 / -四苯基一 1，2 / -聯二咪唑，特佳的化合物爲 2，2 / —雙（2，4 一二氯苯基）一 4，4，，5 ，5 / —四苯基一 1，2 > -聯二咪唑。又，作爲上述三吖嗪系化合物的具體例子， 2，4，6 —三（三氯化甲基）一 s —三吖嗪、 2 —甲基一 4，6 —雙（三氯化甲基）一 s—三吖嗪 2 -〔 2 -（5 -甲基呋喃一 2 —基）乙烯基〕一 4 ，6 —雙（三氯化甲基）一 s —三吖嗪、 2 —〔 2 —（4 —二乙基胺一 2 —甲基苯基）乙烯基〕一4，6 —雙（三氯化甲基）一 s —三π丫嗪、經濟部智慧財產局員工消费合作社印製 2 —〔2 — (3，4 —二甲氧基苯基）乙烯基〕一 4 ，6 —雙（三氯化甲基）一 s —三吖嗪、 2 —（4 一甲氧基苯基）一 4，6:—雙（三氯化甲基 )一 s —三吖嗪、、， 2 —（ 4 一乙氧基苯乙嫌基）一 4，6 —雙（三氯化甲基）一s —三吖嗪、 2 -（4 一 η -丁氧基苯基）一4，6 —雙（三氯化甲基）一 S -二Ρ 丫嗪等具有齒素甲基的三πγ嗪系化合物。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐〉 -15· A7 B7 Ϊ250996 五、發明說明（13 ) 這些三吖嗪系化合物中，以2 一〔2 一（3，4 —二甲氧基苯基）乙烯基〕一 4，6 —雙（三氯化甲基）一 s i — — —— — — — — — — — — ^ i — (請先閱讀背面之注意事項再ιΛ本頁) s二吖嗪爲佳。這些三吖嗪系化合物可單獨或2種以上混合使用。作爲上述苯乙酮系化合物的具體例，有 2 -羥基一 2 -甲基一 1 一苯基丙烷一 1 一酮、 2 —甲基一1 一〔4 一（甲基硫基）苯基〕一2 -嗎啉丙酮一 1、 2 —苄基一 2 —二甲基胺基一 1 一（4 一嗎啉苯基）丁酮一 1、 1 一羥基一環己基一苯基一酮、 2，2 —二甲氧基一 1，2 —二苯基乙焼一 1 一酮可舉出。 --線· 這些苯.乙酮系化合物之中，特別以2 -苄基一 2 -二甲基胺基一 1 一（4 一嗎啉苯基）丁酮一 1爲佳。前述苯乙酮系化合物可單獨或2種以上混合使用。經濟部智慧財產局員工消费合作社印製作爲前述偶氮基系化合物的具體例子，有2，2 / -偶氮雙（4一甲氧基一2，4一二甲基戊腈）、2，2> —偶氮雙（4 一二甲基戊腈）、2，2/ —偶氮雙（2 — 甲基丙腈）、2，—偶氮雙（2—甲基丁腈）、1， 1>一偶氮雙（環己基—1 一腈）、4，4< 一偶氮雙（ 4 一氰基戊酸鹽）、1，1 / 一偶氮雙（1 一乙酸基一 1 -苯基乙烷）可舉出。這些偶氮系化合物中，特別以2，2 / —偶氮雙（4 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -16- 1250996-14- 1250996 A7 __ B7 V. INSTRUCTION DESCRIPTION (12) 2,2^-bis(2-chlorophenyl)-4,4^,5,5-tetraphenyl- 1 ,-biimidazole, - -------------装--- * > (Please read the notes on the back page again) 2,2 Double (2,4 di-dichlorophenyl)-4,4 — , 5 , 5 / - tetraphenyl - 1,2, a diimidazole, 2, 2 > - bis (2,4 · 6 - trichlorophenyl) - 4, 4 丫 ' 5, 5 / - four Phenyl-1,2-di-biimidazole, a particularly preferred compound is 2,2/-bis(2,4-dichlorophenyl)-4,4,5,5/-tetraphenyl-1, 2 > - biimidazole. Further, as a specific example of the above triazine compound, 2,4,6-tris(methyl chloride)-s-triazine, 2-methyl-4,6-bis(methyl chloride) a s-triazine 2-[2-(5-methylfuran-2-yl)vinyl]- 4,6-bis(trimethyl chloride)-s-triazine, 2 —[ 2 —(4-diethylamine-2-methylphenyl)vinyl]- 4,6-bis(trimethylmethyl)-s-tris-pyridazine, printed by the Intellectual Property Office of the Ministry of Economic Affairs 2-(2-(3,4-dimethoxyphenyl)vinyl]- 4,6-bis(methyl chloride)-s-triazine, 2-(4-methoxyphenyl) ) 4,6:-bis(methyl chloride)-s-triazine, , 2 -( 4 -ethoxyphenethyl)- 4,6-bis(trimethyl chloride) a s-triazine, 2-(4-n-butoxyphenyl)- 4,6-bis(trimethyl chloride)-S-dioxazine, etc. a compound. This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm 〉 -15· A7 B7 Ϊ250996 5. Inventive Note (13) Among these triazine-based compounds, 2 one [2 one (3, 4) -dimethoxyphenyl)vinyl]- 4,6-bis(methyl chloride)-si — — — — — — — — — — — ^ i — (Please read the notes on the back first) Λ Λ ) Λ 吖吖这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些这些. Propane-1-one, 2-methyl-l-[4-(methylthio)phenyl]-2-oxamorphone-1-1, 2-benzyl-2-dimethylamino- 1 (4 monomorpholine phenyl) Butanone-1, 1 monohydroxy-cyclohexyl-phenyl-one, 2,2-dimethoxy-1,2-diphenylacetone-1-one may be mentioned. - line · Among these benzene ethyl ketone compounds, 2-benzyl-2-dimethylamino-1-yl 4-tetramorphophenyl phenyl ketone is particularly preferred. The aforementioned acetophenone The compounds may be used singly or in combination of two or more. The Ministry of Economic Affairs, Intellectual Property Office, and the Consumer Cooperatives are printed as a specific example of the above azo-based compound, which has 2,2 / - azobis (4-methoxy- 2, 4) Monomethylvaleronitrile), 2,2>-azobis(4-dimethylvaleronitrile), 2,2/-azobis(2-methylpropionitrile), 2,-azobis ( 2-methylbutyronitrile), 1, 1>-azobis(cyclohexyl-1 -carbonitrile), 4,4<-azobis(4-cyanovalerate), 1,1/monoazo The bis(1-monoacetoxy-1-phenylethane) can be exemplified. Among these azo compounds, 2, 2 / - azo double is used (4 paper grades are applicable to the Chinese National Standard (CNS) A4 specification ( 210 X 297 mm) -16- 1250996

五、發明說明（μ) 甲氧基—2 ’ 4 一一甲基戊腈）、2，2 / —偶氮雙（ 4〜二甲基戊腈）、2，2 / —偶氮雙（2 —甲基丙腈） * ·.1 ϋ ϋ ϋ ϋ a— ·ϋ mmmmm β— ·1 1 I I · tmmw I * # (請先閱讀背面之注意事項再頁) 、2，2 / -偶氮雙（2 —甲基丙腈）、1，1 - 一偶氮又（環己院一1一臆）較佳。自由基的起始劑〔C〕的使用量，對1 〇〇重量份的多官能性單體〔B〕而言，爲〇·〇1至40重量份，較佳爲0 · 5至3 0重量份，且更佳爲1至2 0重量份。〔D〕成份作爲與〔A〕成份相異的環氧基樹脂，例如有雙酚a 型環氧基樹脂、雙酚F系環氧樹脂、酚漆用酚醛樹脂環氧樹脂、甲酚漆用酚醛環氧樹脂等可使用。作爲這些環氧樹脂的販賣品，例如作爲雙酚A型環氧樹脂的埃皮科特 1001 、同 1 0 02、同 1003、同 1004、同 1007、同 1009、同 1010、同 828 (以上爲油化蜆殼環氧股份有限公司製）等，經濟部智慧財產局員工消费合作社印製作爲雙酚F型環氧樹脂埃皮科特8 0 7、同8 3 4 ( 以上爲油化視殻環氧股份有限公司製）；作爲酹漆用酹酵型環氧基樹脂有埃皮科特1 5 2、同15 4、同 1 5 7H6 5 (以上爲油化蜆殻環氧股份有限公司製）、 EPPN201、同202 (以上爲日本化藥股份有限公司製）等、作爲甲酚漆用酚醛型環氧基樹脂，有E〇CN -102、E〇CN—1〇3S、EOCN—1〇4S、 E〇CN — 1 020 、 E〇CN — 1025 、 E〇CN — 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公漦） -17- 1250996 A7 B7 五、發明說明（15 ) 1 0 2 7 (以上爲曰 1 8 0 S 7 5 (油化作爲環式脂肪族環氧基樹脂有CY 1 7 5、CY 1 7 7 CY179 (以上爲本化藥股份有限公司製）、埃皮科特蜆殼環氧股份有限公司製）等；其他、ERL-4234 4221 、ERL —V. Description of the invention (μ) methoxy-2'-4 monomethylvaleronitrile), 2,2/-azobis(4~dimethylvaleronitrile), 2,2/-azobis (2) -Methylpropionitrile) * ·.1 ϋ ϋ ϋ ϋ a- ·ϋ mmmmm β— ·1 1 II · tmmw I * # (Please read the notes on the back page again), 2,2 / - azo double (2-methylpropionitrile), 1,1 - azo and (cyclohexyl-1) are preferred. The amount of the radical initiator [C] used is 1 to 40 parts by weight, preferably 0 to 5 to 3 0, per 1 part by weight of the polyfunctional monomer [B]. Part by weight, and more preferably 1 to 20 parts by weight. [D] Component As the epoxy resin different from the component [A], for example, bisphenol a type epoxy resin, bisphenol F type epoxy resin, phenolic resin phenol resin epoxy resin, cresol paint A phenolic epoxy resin or the like can be used. As a commercial product of these epoxy resins, for example, Epicot 1001, 1200, 1003, 1004, 1007, 1009, 1010, 828 (for the bisphenol A epoxy resin) Oiled clamshell epoxy Co., Ltd.), etc., Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperatives, printed as bisphenol F-type epoxy resin Epicote 80 7, same as 8 3 4 (above is oily shell ring) Oxygen Co., Ltd.); as a enamel paint, the epoxy resin is Epicote 1 5 2, the same 15 4, the same 1 5 7H6 5 (above is the oily clamshell epoxy Co., Ltd.) , EPPN201, and 202 (the above are manufactured by Nippon Kayaku Co., Ltd.), etc., as a phenolic epoxy resin for cresol paint, there are E〇CN-102, E〇CN-1〇3S, EOCN-1〇4S , E〇CN — 1 020 , E〇CN — 1025 , E〇CN — This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) -17- 1250996 A7 B7 V. Description of invention (15) 1 0 2 7 (The above is 曰1 8 0 S 7 5 (oilification as a cyclic aliphatic epoxy resin has CY 1 7 5, CY 1 7 7 CY179 (above Bento Chemical Co., Ltd.), Epicote Shell Epoxy Co., Ltd., etc.; Others, ERL-4234 4221, ERL —

CIBA — GEIGY A. 、ERL — 4299、ERL 4206 (以上，U.C.C 修達因5 0 9 (昭和電工股份有限公司製）、CIBA — GEIGY A., ERL — 4299, ERL 4206 (above, U.C.C Xi Dain 509 (made by Showa Denko Co., Ltd.),

達德CY-182、同CY 以上爲C I BA - G 經濟部智慧財產局員工消费合作社印製Dade CY-182, the same as CY or above, C I BA - G Ministry of Economics, Intellectual Property Bureau, Staff and Workers, Consumer Co., Ltd.

2 0 0、同 4 0 0 ( )、埃皮科特8 7 1 以上爲油化蜆殼環氧、E D - 5 6 6 2 ( )等，作爲脂肪族聚同1 9 1 P (以上爲波拉得1 0 0 M F ( 歐路ΤΜΡ (日本油其中，較佳爲雙氧樹脂以及甲酚漆用環氧基樹脂〔D 份〔A〕，較佳爲1 重量份。且，成份〔A〕氧基樹脂與成份〔A E I G Y 以上爲大、同8 7 股份有限以上爲賽環氧丙基油化蜆殼共榮社化脂股份有酚A型環酚醛型環〕的使用至2 0 0 192、同 CY - 1 A · G製）、埃皮曰本墨水工業股份有 2、ΕΡ1〇32Η 公司製）、E D — 5 拉泥斯塗料股份有限醚，有埃皮科特19 環氧股份有限公司製學股份有限公司製）限公司製）等。氧基樹脂、酚漆用酚氧樹脂。比例，每1 0 0重量重量份，較佳爲3至 G製）公司製阿拉魯 8 4 ( 科龍限公司 6 0 ( 6 6 1 公司製 0 P、 )、耶、埃皮醛型環份的成 10 0 亦爲環氧基樹脂，但成份〔D〕的環〕比較其爲低分子量體，對於平坦化本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） — — — — — — — — — — — III · I I * ί {請先閲讀背面之注意事項再本頁) 上0· 線. -18- A7 B7 1250996 五、發明說明（16 ) 性的提升效果上相異 ·1 — — — — — — — — — — — — · .1 I - * (請先閱讀背面之注意事項再104頁) 〔E〕成份〔E〕成份的酸引發劑’包含由熱產生酸的化合物以及由放射線產生的酸的化合物。作爲由熱產生酸的化合物，有鎏鹽、苯并噻唑鹽、銨鹽、錢鹽等的_鹽。其中鎏鹽以及苯并噻唑鹽較佳。上述鎏鹽（除前述三芳基鎏鹽之外）的具體例子’ 4 -乙醯苯基二甲基鎏鹽六氟氧銻鹽、4 一乙醒苯基二甲基鎏鹽六氟氧砷鹽、二甲基一 4 一（苄基氧基鑛基氧基）苯基鎏鹽六氟氧銻鹽、二甲基一 4 一（苯酿基氧基）苯基璧鹽六氟氧銻鹽、二甲基- 4-(苯醯基氧基）苯基璧鹽六氟氧砷鹽、二甲基一 3 —氯一 4 一乙酸基苯基鎏鹽六氟氧銻鹽等烷基鎏鹽；. 線- 經濟部智慧財產局員工消费合作社印製苄基- 4 -羥基苯基甲基鎏鹽六氟氧鍊鹽、爷基一 4 -羥基苯基甲基鎏鹽六氟磷酸鹽、4 一乙酸基苯基爷基甲基鎏鹽六氟氧銻鹽、苄基- 4 一甲氧基苯基甲基璧鹽六氣氧銻鹽、苄基—2 —甲基一 4 -羥基苯基甲基璧鹽六氣氧銻鹽、苄基- 3 -氯- 4 -羥基苯基甲基鎏鹽六氟氧砷鹽、4 -甲氧基苯基- 4 -羥基苯基甲基鎏鹽六氟磷酸鹽等苄基鎏鹽；二苄基—4 一羥基苯基鎏鹽六氟氧鍊鹽、二爷基一 4 -羥基苯基鎏鹽六氟磷酸鹽、4 一乙酸基苯基二苄基鎏鹽六氟氧銻鹽、二苄基- 4 -甲氧基苯基變鹽六氯氧鍊鹽、本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） .19- 1250996 A7 B7 五、發明說明（17 ) 二苄基一 3 —氯一 4 一羥基苯基鎏鹽六氟氧砷鹽、二苄基一 3〜甲基一 4 一羥基一 5 — t 一丁基苯基鎏鹽六氟氧銻鹽、苄基一 4 一甲氧基苄基一 4 -羥基苯基鎏鹽六氟磷酸鹽等二苄基鎏鹽； P —氯化苄基一 4 -羥基苯基甲基鎏鹽六氟氧銻鹽、 P -硝基苄基一 4 一羥基苯基甲基鎏鹽六氟氧銻鹽、P 一氯化苄基- 4 -羥基苯基甲基鎏鹽六氟磷酸鹽、P -硝基苄基一 3 —甲基一 4 一羥基苯基甲基鎏鹽六氟氧銻鹽、3 ’ 5 -二氯苄基一 4 一羥基苯基甲基鎏鹽六氟氧銻鹽、0 -氯化苄基一 3 —氯化- 4 -羥基苯基甲基鎏鹽六氟氧銻鹽等取代苄基鎏鹽可舉出下述式（2)至（8)所表示的鎏鹽作爲上述苯并噻唑鹽類的具體例子，例如可舉出3 -苄基苯并噻唑鹽六氟氧銻鹽、3 -苄基苯并噻唑鹽六氟磷酸鹽、3 —苄基苯并噻唑鹽四氟硼酸鹽、3 —（P —甲氧基苄基）苯并噻唑鹽六氟氧銻鹽、3 —苄基一 2 —甲基硫基苯并噻唑鹽六氟氧銻鹽、3 -苄基一 5 —氯化苯并噻哩鹽六氟氧銻鹽等苄基苯并噻唑鹽。 · chHQkso3' …〇) • _ CH3COO-/QV-g^ . CF3C03* --- 〇 ) ' / CH^ 。 ch3cc>--^〇^s^^2 · CF3S〇3* ... 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -------------裝--- * · (請先閱讀背面之注意i項再%本頁) .tr. •線· 經濟部智慧財產局員工消费合作社印製 -20- !25〇996 A7 B7 五、發明說明（18 )2 0 0, same as 4 0 0 ( ), Epicot 8 7 1 or more is oily clam shell epoxy, ED - 5 6 6 2 ( ), etc., as an aliphatic group with 1 9 1 P (above is Pola 1 0 0 MF (Ouchi ΤΜΡ (Japanese oil, preferably epoxy resin and epoxy resin for cresol paint [D part [A], preferably 1 part by weight. Moreover, the component [A] oxygen Base resin and ingredients [AEIGY above is large, same as 8 7 shares limited or more for the production of epoxy propylated eucalyptus oyster shell Kyungwon Chemical Co., Ltd. phenol A type phenolic phenolic ring] to use to 2 0 0 192, same CY - 1 A · G system), Epiruthen ink industry shares 2, ΕΡ 1 〇 32 Η company system), ED — 5 Lagas paint shares limited ether, there is Epicote 19 Epoxy Co., Ltd. Limited company system) company limited). Oxygen resin, phenolic resin for phenol paint. Proportion, per 100 parts by weight, preferably 3 to G) Company-made Alaru 8 4 (Kelong limited company 6 0 (6 6 1 company 0 P, ), yeah, epoxiphenone type ring The formation of 10 0 is also an epoxy resin, but the ring of the component [D] is a low molecular weight body. For the flattening of the paper scale, the Chinese National Standard (CNS) A4 specification (210 X 297 mm) is applied. — — — — — — — — — III · II * ί {Please read the notes on the back and then on this page.) 0. Line. -18- A7 B7 1250996 V. Description of invention (16) Sexual improvement effect ·1 — — — — — — — — — — — — . . . I - * (Please read the notes on the back and then on page 104) [E] The acid initiator of the component [E] contains heat generated A compound of an acid and a compound of an acid generated by radiation. As the compound which generates an acid by heat, there are a salt of a phosphonium salt, a benzothiazole salt, an ammonium salt, a money salt or the like. Among them, sulfonium salts and benzothiazole salts are preferred. Specific examples of the above sulfonium salt (other than the above-mentioned triarylsulfonium salt) '4-ethyl phenyl dimethyl sulfonium salt hexafluorooxonium salt, 4- hexyl phenyl dimethyl sulfonium salt hexafluoro oxy arsenate , dimethyl-tetra-(benzyloxy-ortyloxy)phenylphosphonium salt hexafluorooxonium salt, dimethyl-tetra-(phenylphenyloxy)phenylphosphonium salt hexafluorooxonium salt, An alkyl sulfonium salt such as dimethyl 4-(phenylhydrazinyloxy)phenyl sulfonium salt hexafluoroox arsenate or dimethyl-3-chloro-tetracarboxylic acid phenyl sulfonium salt; Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Benzyl-4-hydroxyphenylmethyl sulfonium hexafluorooxyl salt, aryl 4-hydroxyphenylmethyl sulfonium hexafluorophosphate, 4 Acetylphenyl aryl methyl sulfonium salt hexafluorooxonium salt, benzyl-4 monomethoxyphenyl methyl sulfonium salt hexahydrooxonium salt, benzyl-2-methyl-4-hydroxyphenyl group Base salt hexahydrooxonium salt, benzyl-3-chloro-4-hydroxyphenylmethylsulfonium salt hexafluorooxoarsenate, 4-methoxyphenyl-4-hydroxyphenylmethylsulfonium salt hexafluoro Benzyl sulfonium salt such as phosphate; dibenzyl-4 hydroxyphenyl sulfonium salt Oxygen chain salt, di-aryl 4-hydroxyphenyl phosphonium salt hexafluorophosphate, 4-monoacetoxyphenyl dibenzyl phosphonium salt hexafluorooxonium salt, dibenzyl-4-methoxyphenyl salt Hexachlorooxychloride salt, this paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm). 19- 1250996 A7 B7 V. Description of invention (17) Dibenzyl-3-chloro-4-hydroxybenzene Base salt hexafluoroox arsenate salt, dibenzyl-3~methyl-4-hydroxy-5-t-butylphenyl sulfonium salt hexafluorooxonium salt, benzyl-4-methoxybenzyl- 4 Dibenzyl sulfonium salt such as hydroxyphenyl sulfonium salt hexafluorophosphate; P - benzyl chloro 4-methyl hydroxymethyl sulfonium salt hexafluoro oxonium salt, P - nitrobenzyl 4- hydroxy benzene Methyl hydrazine salt hexafluorooxonium salt, P benzyl-4-hydroxyphenylmethyl sulfonium salt hexafluorophosphate, P-nitrobenzyl 3-methoxy- 4-hydroxyphenyl group Base salt hexafluorooxonium salt, 3'5-dichlorobenzyl-4-hydroxyphenylmethyl phosphonium salt hexafluorooxonium salt, 0-benzyl chloride-3-hydroxy-4-phenylol a substituted benzyl sulfonium salt such as a methyl sulfonium salt hexafluorooxonium salt The onium salt represented by the following formulas (2) to (8), as specific examples of the above-mentioned benzothiazole salt, may, for example, be a 3-benzylbenzothiazole salt hexafluorooxonium salt or a 3-benzylbenzene. Thiazole salt hexafluorophosphate, 3-benzylbenzothiazole salt tetrafluoroborate, 3-(P-methoxybenzyl)benzothiazole salt hexafluorooxonium salt, 3-benzyl-2-methyl group a benzyl benzothiazole salt such as a thiobenzothiazole salt hexafluorooxonium salt or a 3-benzyl-5-chlorobenzothiazepine salt hexafluorooxonium salt. · chHQkso3' ...〇) • _ CH3COO-/QV-g^ . CF3C03* --- 〇 ) ' / CH^ . Ch3cc>--^〇^s^^2 · CF3S〇3* ... This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------------ - Packing--- * · (Please read the back of the note i item and then the % page) .tr. • Line · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing -20- !25〇996 A7 B7 V. Description of invention (18)

CHnC ch3 .cf3so3· CH, HO- CH, cf3so3· aCHnC ch3 .cf3so3· CH, HO- CH, cf3so3· a

HOHO

• CF3S〇3* CF3S03- CH, — — — — —— — — — — — I· I I I (請先閱讀背面之注意事項再本頁) 經濟部智慧財產局員工消費合作社印製其卡基-基苄基六氟氧其一 L 1 S I - 這合物之這又基碘鐵作二苯基中以使用4 一乙 4 一羥基苯基甲甲基鎏銻鹽、中作爲 10、 L 1 6 些由熱功能。些化合，作爲鹽類、爲二芳碘鑰鹽酸基苯基二甲基鎏鹽六氟氧砷鹽、基鎏鹽六氟氧銻鹽、4 -乙酸基苯鹽六氟氧銻鹽、二苄基- 4 -羥基苯基鎏鹽 4 一乙酸基苯基苄基鎏鹽六氟氧銻鹽爲佳。商品，可舉出三元多S I — L85、同S I 同 SI— L145、同 SI—L150、同〇 (三新化學工業股份有限公司）等。產生酸的化合物亦具有由放射線產生酸的化物可單獨或2種以上組合使用。由放射線產生酸的化合物，例如可使用二芳三芳基鎏鹽類。基碘鎗鹽類，有二芳基碘鑰鹽三氟乙酸酯、三氟甲基硫酸鹽、4 -甲氧基苯基苯基碘鑰本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）訂 -21 - 1250996 Α7 _ Β7 五、發明說明（19 ) 鹽三氟甲基硫酸鹽或4 一甲氧基苯基苯基碘鑰鹽三氟乙酸鹽；作爲三芳基鎏鹽類，較佳可舉出三苯基鎏鹽三氟甲基硫酸鹽、三苯基鎏鹽三氟乙酸鹽、4 -甲氧基苯基聯苯基鎏鹽三氟甲基硫酸鹽、4 一甲氧基苯基聯苯基鎏鹽三氟乙酸鹽、4 -苯基硫代苯基聯苯基三氟甲基硫酸鹽或4 -甲基硫代甲基聯苯三氟乙酸鹽。由熱或放射線產生酸的化合物〔E〕之使用比例，對 100重量份的成份〔A〕而言，爲0·01至20重量份爲佳，較佳爲0 · 2至1 0重量份。成份〔E〕的使用比例爲，對1 0 0重量份的成份〔 A〕而言，不足0.01重量份時，因加熱或受放射線的而產生的酸量較少，故成份〔A〕以及成份〔D〕的交聯十分難進行.，所得之硬化膜的耐熱性、平坦化性、耐藥性、與基板的密著性等皆會降低。另一方面，成份〔E〕的使用比例對1 0 0重量份的成份〔A〕而言若超過2 0重量份時，塗膜較易產生乾裂。且，自由基起始劑i C〕中三嗪系化合物具有感應放射線酸引發劑之功能。 ν ( 其他添加劑本發明的硬化性組成物之第1型態，於不破壞本發明的目的之範圍內，因應必要可含有上述以外的其他添加物本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） !||層 — — · t i I *·*> (請先閱讀背面之注意事項再ιφ本頁) 訂： --鎳- 經濟部智慧財產局員工消费合作社印製 •22- 1250996 A7 _ B7 五、發明說明（2〇 ) 做爲其他添加劑，例如可舉出有機矽烷偶合劑、界面活性劑等。〈有機矽烷偶合劑〉有機矽烷偶合劑係欲提升硬化膜與基體間的密著性而使用者，其中使用含有具羧基、甲基丙烯醯基、異氰酸酯、環氧基等反應性取代基（官能基）的官能基之烷氧基矽烷化合物爲佳。具體而言，可舉出三甲氧基甲矽烷基安息香酸、7 -甲基丙烯醯氧基丙基三甲氧基矽烷、乙烯三乙醯氧基、乙烯三甲氧基矽烷、r 一異氰酸根丙基三乙氧基石夕院、7 -環氧丙氧基丙基三甲氧基砂院、β —（3，4 -環氧基環己基）乙基三甲氧基矽烷等。如此接著劑對 1 0 0重量份的成分（Α)而言，較佳爲2 0重量份以下、特佳爲1 5重量份以下的量。若接著劑的量超過2 0重量份時耐熱性較易降低。〔界面活性劑〕界面活性劑係欲提、升塗佈性而使用’可適當使用氟素系界面活性劑以及聚矽氧烷系界面活性劑。作爲氟素系界面活性劑，可使用於末端、主鏈以及支鏈上至少一處具有氟化烷基或氟化烷撐基之化合物爲佳。作爲其具體例子可舉出1，2，2，2 -四氟辛（1，1 ，2，2 —四氟丙基）醚、1，2，2，2 —四氟己醚、八乙二醇二（1 ，1 ，2，2 —四氟丁基）醚、六乙二醇本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） --------------裝--- * _ ί (請先閱讀背面之注意事項再m本頁： *tr: --線· 經濟部智慧財產局員工消费合作社印製 -23- 1250996 A7 B7 五、發明說明（21 ) 二（1，1 ’ 2，2，3，3 —六氟戊基）醚、八丙二醇二（1，1 ，2，2 —四氟丁基）醚、六丙二醇二（1 ， 1 ’ 2 ’ 2 ’ 3 ’ 3 -六氟戊基）酸、全氟十二擴酸鈉、 1，1，2，2，8，8，9，9，10，10 —十氟十二碳烷、1，1，2，2，3，3 —六氟十二碳烷、氟化烷基苯磺酸鈉、氟化烷基苯硫酸鈉、氟化烷基苯羧酸鈉、氟化烷基聚氧基伸乙基醚、二甘油四（氟烷基聚氧伸乙基醚）、氟化烷基銨碘化物、氟化烷基田菜鹼、氟化烷基聚氧基伸乙基醚、全氟烷基聚氧乙醇、全氟烷基烷氧鹽等氟系烷基酯類。又，作爲這些商品，例如有BM — 1〇〇〇、BM — 1100 (以上爲BM化學公司製）、面加氟克 F142D、同 172、同 173、同 F183、同F17 8、同F191、同F471 (以上爲大日本墨水股份有限公司製）、氟拉多FC170C、FC-171、FC — 430、FC — 431 (以上爲住友 3M 股份有限公司製）、沙氟隆S — 1 1 2、同S — 1 1 3、同 S — 131 、同 S — 103 、同 S — 10 4、同 S — 105、同S - 106 (以上爲旭硝子股份有限公司製）、Ftop EP301、同 303、，同 352 (以上爲新秋田化成股份有限公司所製）、福德全得F T - 1 0 0 、同 FT— 1 10 、同 FT — 140A、同 FT — 150 、同 FT— 250、同 FT— 251 、同 FTX — 251 、同？了乂一218、同？丁一300、同？丁一310 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -------------裝--- * V 請先閲讀背面之注意事項再1¾本頁) 有· -線- 經濟部智慧財產局員工消费合作社印製 -24- 1250996 A7 ______B7 五、發明說明（22 ) * ·1 ϋ ϋ ϋ ·1 ·1 ϋ n I ·1 ϋ «ϋ I · I ·1 * f (請先閱讀背面之注意事項再本頁) 、同FT — 4 0 0 S (以上由泥爾司股份有限公司所製）等可舉出。作爲聚矽氧烷系界面活性劑，例如有東雷矽氧烷 DC3PA、同 DC7PA、同 SH11PA、同 SH21PA、同 SH28PA、同 SH29PA、同 SH30PA、同SH—190、同SH—193、同 SZ — 6 0 32、同 SF — 8428、同 DC — 57、同D C - 1 9 0 (以上爲東雷島矽氧烷股份有限公司製）、TSF — 4440、TSF — 4300、TSF-4445、TSF - 4446、TSF - 446 0、 TSF - 4 4 5 2 (以上爲東芝聚矽氧烷股份有限公司製 )的販賣品可舉出。線- 又，其他亦可舉出聚氧伸乙基月桂醚、聚氧伸乙基硬脂醯醚、聚氧伸乙基油醚等聚氧伸乙基烷醚類、聚氧伸乙基辛基苯醚、聚氧伸乙基壬基苯醚等的聚氧伸乙基芳基醚類、聚氧伸乙基二月桂酸鹽、聚氧伸乙基二硬脂酸酯等聚氧伸乙基二烷基酯等非離子系界面活性劑；可舉出有機矽氧烷聚合物K P 3 4 1 (信越化學工業股份有限公司製）經濟部智慧財產局員工消費合作社印製、（甲基）丙烯酸系共聚物聚福羅No · 57、95 (共榮社化學股份有限公司製）等。這些界面活性劑對1 0 0重量份的、共聚物〔A〕而言，較佳爲5重量份以下，更佳爲2重量份以下。界面活性劑的量若超過5重量份時塗佈時膜較容易乾裂。本發明的第2型態之硬化性組成物，其特徵爲〔A ’〕 (a2)含有環氧基的單體、（a3)馬來酐酸縮亞胺系本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -25- 1250996 A7 B7 五、發明說明（23 ) -------------裝— ** 請先閲讀背面之注意事項再H本頁) 單體以及（a4)其他單體的共聚物、〔F〕至少一種化合物選自於多電子價羧酸無水物以及多電子價羧酸所成群，以及〔D’〕含有與上述〔A ’〕成份相異的環氧基樹脂。上述的硬化性組成物，依情況可再含有〔E ’〕酸引發劑。• CF3S〇3* CF3S03- CH, — — — — —— — — — — — I· III (Please read the notes on the back and then on this page) The Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs prints its Kaki-Ki Benzyl hexafluorooxyl-L 1 SI - the thiol iron of this compound is used as a diphenyl group to use 4 - ethyl 4-hydroxyphenyl methyl sulfonium salt, as 10, L 1 6 By the heat function. Some compounds, as a salt, are diaryl iodide hydrochloride phenyl dimethyl sulfonium salt hexafluoro oxy arsenate, sulfonium salt hexafluorooxonium salt, 4-acetic acid benzene salt hexafluorooxonium salt, dibenzyl The 4-tetrahydroxyphenyl phosphonium salt 4-monoacetoxyphenylbenzyl phosphonium salt hexafluorooxonium salt is preferred. Commodities include ternary multiple S I — L85, the same S I with SI-L145, the same SI-L150, and the same (Sanxin Chemical Industry Co., Ltd.). The acid generating compound may also have a chemical which generates an acid by radiation, and may be used singly or in combination of two or more kinds. As the compound which generates an acid by radiation, for example, a diaryltriarylsulfonium salt can be used. Base iodine salt, with diaryl iodine salt trifluoroacetate, trifluoromethyl sulfate, 4-methoxyphenyl phenyl iodide paper scale applicable to China National Standard (CNS) A4 specification ( 210 X 297 mm) Order -21 - 1250996 Α7 _ Β7 V. Description of invention (19) Salt trifluoromethyl sulfate or 4-methoxyphenyl phenyl iodine salt trifluoroacetate; as triaryl sulfonium Preferred examples of the salt include triphenylsulfonium salt trifluoromethyl sulfate, triphenylsulfonium salt trifluoroacetate, 4-methoxyphenylbiphenyl phosphonium salt trifluoromethyl sulfate, and 4 Monomethoxyphenylbiphenyl phosphonium salt trifluoroacetate, 4-phenylthiophenyl biphenyl trifluoromethyl sulfate or 4-methylthiomethylbiphenyl trifluoroacetate. The ratio of the compound [E] which generates an acid by heat or radiation is preferably from 0. 01 to 20 parts by weight, preferably from 0. 2 to 10 parts by weight, per 100 parts by weight of the component [A]. The component [E] is used in a proportion of less than 0.01 part by weight to the component [A] of 100 parts by weight, and the amount of acid generated by heating or radiation is small, so the component [A] and the component are contained. The crosslinking of [D] is extremely difficult. The heat resistance, flatness, chemical resistance, and adhesion to the substrate of the obtained cured film are all lowered. On the other hand, when the proportion of the component [E] is more than 20 parts by weight based on 100 parts by weight of the component [A], the coating film is liable to cause dry cracking. Further, the triazine-based compound in the radical initiator i C] functions as an inducing radiation acid initiator. ν (Other Additives The first type of the curable composition of the present invention may contain other additives other than the above, as long as the object of the present invention is not impaired. The paper size applies to the Chinese National Standard (CNS) A4 specification. (210 X 297 mm) !||层——— · ti I *·*> (Please read the note on the back and then ιφ this page) Order: -- Nickel - Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing • 22- 1250996 A7 _ B7 V. INSTRUCTIONS (2〇) As other additives, for example, an organic decane coupling agent, a surfactant, etc. may be mentioned. <Organic decane coupling agent> The organic decane coupling agent is intended to enhance the cured film and It is preferable that the user uses an alkoxydecane compound having a functional group having a reactive substituent (functional group) such as a carboxyl group, a methacryl group, an isocyanate or an epoxy group. In other words, trimethoxymethyl decyl benzoic acid, 7 - methacryloxypropyl trimethoxy decane, ethylene triethoxy methoxy, ethylene trimethoxy decane, r - isocyanatopropyl three Ethoxy Shi Xiyuan, 7-glycidoxypropyltrimethoxy sand, β-(3,4-epoxycyclohexyl)ethyltrimethoxydecane, etc. such an adhesive to 100 parts by weight The component (Α) is preferably 20 parts by weight or less, particularly preferably 15 parts by weight or less. When the amount of the adhesive exceeds 20 parts by weight, the heat resistance is easily lowered. [Interfacial Agent] Interface The active agent is used for the purpose of improving the coating property, and a fluorine-based surfactant and a polyoxyalkylene surfactant can be suitably used. As a fluorine-based surfactant, it can be used for the terminal, the main chain, and the branch. Preferably, at least one compound having a fluorinated alkyl group or a fluorinated alkyl group is used. Specific examples thereof include 1,2,2,2-tetrafluorooctyl (1,1,2,2-tetrafluoropropene). Ether, 1,2,2,2-tetrafluorohexyl ether, octaethylene glycol di(1,1,2,2-tetrafluorobutyl)ether, hexaethylene glycol, paper scale applicable to Chinese national standards ( CNS) A4 specification (210 X 297 public) -------------- Pack --- * _ ί (Please read the notes on the back and then m page: *tr: -- Line · Ministry of Economics Intellectual Property Employee Consumption Cooperative Printed -23- 1250996 A7 B7 V. Description of Invention (21) Two (1,1 '2,2,3,3-hexafluoropentyl)ether, octapropylene glycol II (1,1,2,2 -tetrafluorobutyl)ether, hexapropanediol di(1 , 1 ' 2 ' 2 ' 3 ' 3 -hexafluoropentyl) acid, sodium perfluorododecanlate, 1,1,2,2,8,8 , 9, 9, 10, 10 - decafluorododecane, 1,1,2,2,3,3 - hexafluorododecane, sodium fluorinated alkylbenzene sulfonate, fluorinated alkylbenzene sulphate Sodium, sodium fluorinated alkyl benzenecarboxylate, fluorinated alkyl polyoxyethylene ether, diglycerol tetra(fluoroalkyl polyoxyethyl ether), fluorinated alkyl ammonium iodide, fluorinated alkyl field Fluorine alkyl esters such as alkaloids, fluorinated alkyl polyoxyethylene ethers, perfluoroalkyl polyoxyethylenes, perfluoroalkyl alkoxylates. Further, as these products, for example, BM-1 〇〇〇, BM-1100 (above, BM Chemical Co., Ltd.), surface fluorocarbon F142D, 172, 173, F183, F17 8, F191, and the like F471 (above is made by Dainippon Ink Co., Ltd.), Fradado FC170C, FC-171, FC-430, FC-431 (above Sumitomo 3M Co., Ltd.), Shaflon S-1 1 2 S - 1 1 3, same as S - 131, same as S - 103, same as S - 10 4, same as S - 105, same as S - 106 (above is Asahi Glass Co., Ltd.), Ftop EP301, same 303, and 352 (The above is made by New Akita Chemical Co., Ltd.), Ford Full FT - 1 0 0, FT-1 10, FT-140A, FT-150, FT-250, FT-251, same FTX — 251, the same?乂一218, the same? Ding Yi 300, the same? Ding Yi 310 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) -------------Installation --- * V Please read the notes on the back and then 13⁄4 This page) Yes - Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed -24 - 1250996 A7 ______B7 V. Invention Description (22 ) * ·1 ϋ ϋ ϋ ·1 ·1 ϋ n I ·1 ϋ «ϋ I · I ·1 * f (please read the precautions on the back side of this page), the same FT — 4 0 0 S (above, manufactured by Muir Division, Inc.), etc. As the polyoxyalkylene-based surfactant, for example, Dongleioxane DC3PA, the same DC7PA, the same SH11PA, the same SH21PA, the same SH28PA, the same SH29PA, the same SH30PA, the same SH-190, the same SH-193, the same SZ- 6 0 32, with SF - 8428, with DC - 57, with DC - 1 9 0 (above is made by Donglei Island Aerobic Co., Ltd.), TSF-4440, TSF-4300, TSF-4445, TSF-4446 TSF-446 0, TSF-4 4 5 2 (The above is manufactured by Toshiba Polyoxane Co., Ltd.) can be mentioned. Line - In addition, polyoxyethylene ethyl laurate, polyoxyethylene ethyl stearyl ether, polyoxyethyl ether ether, polyoxyethylene ethyl ether, polyoxyethylene ethyl octyl ether Polyoxyethylene ethyl aryl ethers such as polyphenylene ether and polyoxyethylidene phenyl ether, polyoxyethylene ethyl dilaurate, polyoxyethylene ethyl distearate, etc. A nonionic surfactant such as a dialkyl acrylate; an organic siloxane polymer KP 3 4 1 (manufactured by Shin-Etsu Chemical Co., Ltd.) printed by the Intellectual Property Office of the Ministry of Economic Affairs, employee consumption cooperative, (methyl) Acrylic copolymer polyforo No. 57, 95 (manufactured by Kyoeisha Chemical Co., Ltd.). These surfactants are preferably 5 parts by weight or less, more preferably 2 parts by weight or less, based on 100 parts by weight of the copolymer [A]. When the amount of the surfactant exceeds 5 parts by weight, the film is more likely to be cracked when applied. The curable composition of the second aspect of the present invention is characterized in that [A '] (a2) an epoxy group-containing monomer and (a3) maleic anhydride acid imide type paper are applicable to the Chinese national standard ( CNS)A4 specification (210 X 297 mm) -25- 1250996 A7 B7 V. Invention description (23) -------------Installation - ** Please read the notes on the back and then H a monomer and (a4) a copolymer of another monomer, [F] at least one compound selected from the group consisting of polyelectron carboxylic acid anhydrides and polyelectrovalent carboxylic acids, and [D'] [A '] An epoxy resin having a different composition. The above curable composition may further contain an [E'] acid initiator as the case may be.

共聚物〔A 共聚物〔A ’〕係化合物（a 1 )、化合物（a 3 )以及化合物（a 4)於溶媒中，於聚合起始劑的存在下進行自由基聚合而製造者。其中，化合物（a2)、化合物（a3)以及化合物 (a 4 )可使用如共聚物〔A〕中所舉例者。本發明所使用的共聚物〔A ’〕係較佳爲含有1 〇至 7 0重量％、.特佳爲2 0至6 0重量％的化合物（a 2 ) --線* 經濟部智慧財產局員工消費合作社印製中衍生出的構造單位。此構造單位若不足1 0重量％的共聚物，其所得之保護膜則有耐熱性、表面硬度下降的傾向。另一方面，若超過7 0重量％時則有硬化性組成物的保存安定性會有下降的傾向。本發明所使用的共聚物〔A ’〕係較佳爲含有2至5 0 重量％、特佳爲5至4 0重量％的化合、物（a 3 )中衍生出的構造單位。此構造單位若不足2重量％時則有耐熱性、耐藥性、表面硬度下降的傾向。若此構造單位若超過 5 0重量％時則有塗膜的成膜性有下降的傾向。本發明所使用的共聚物〔A ’〕係較佳爲含有5至8 0 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -26- 經濟部智慧財產局員工消费合作社印製 1250996 Α7 —_____ Β7 五、發明說明（24 ) 重量％、特佳爲1 0至7 0重量％的化合物（a 4 )中衍生出的構造單位。此構造單位若不足5重量％時則有塗膜的成膜性有下降的傾向。若此構造單位若超過8 0重量％時則有耐熱性或耐藥性不足的狀況。共聚物〔A ’〕的較佳具體例子爲，可舉出（甲基）丙烯酸環氧丙基/N -苯基馬來酸酐縮亞胺/苯乙烯共聚物、（甲基）丙烯酸環氧丙基/N-環己基馬來酸酐縮亞胺 /苯乙烯共聚物、（甲基）丙烯酸環氧丙基/N-苯基馬來酸酐縮亞胺/苯乙烯//三環〔5 · 2 · 1 · 02’6〕癸烷一8-基（甲基）丙烯酸酯共聚物、（甲基）丙烯酸環氧丙基/N -環己基馬來酸酐縮亞胺/苯乙烯//三環〔5·2·1·02’6〕癸烷一8—基（甲基）丙烯酸酯共聚物。作爲製:造共聚物〔A ’〕所使用的溶媒，可使用於共聚物〔A〕所舉例者。又，作爲製造共聚物〔A ’〕所使用的聚合起始劑，可使用於共聚物〔A〕所舉例者。本發明所使用的共聚物〔A ’〕係以聚苯乙烯換算重量平均分子量（以下稱〔Mw〕），通常爲2xl〇3至5X 105，較佳爲5X103至1\1〇5“若1^1不足2>< 1 Ο3時，所得之包膜其具有耐熱性、表面硬度下降的傾向。另一方面，若超過5 X 1 0 5則有平坦性下降的傾向。〔F〕成份本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） I H ·ϋ ϋ I 1_· ·1- I 1 I _1 ·1 I · 1 mtm •-I <請先閱讀背面之注意事項再ιφ本頁) 訂· ;綉· -27· 1250996 A7 _ _ B7 五、發明說明（25 ) 作爲〔F〕成份所使用的多電子價羧酸無水物或多電子價羧酸係作爲〔A ’〕成份的硬化劑作用者。作爲多電子價羧酸無水物的具體例子，可舉出無水衣康酸、無水琥珀酸、無水檸康酸、無水十二碳烯酸、無水三苯胺基甲酸、無水馬來酸、無水六氫苯二酸、無水甲基四氫苯二酸、無水安眠酸的脂肪族二翔酸無水物；1，2 ，3，4 一丁基四羧酸二無水物；無水苯二酸、無水均苯四甲酸、無水三苯六甲酸、無水二苯甲酮四羧酸的芳香族多電子價羧酸三苯六甲酸酯的含酯基酸無水物。其中芳香族多電子價羧酸無水物、特別爲無水三苯六甲酸可得到耐熱性較高的硬化膜。又，作爲多電子價羧酸之具體例子，琥珀酸、戊二酸、己二酸、丁烷四羧酸、馬來酸、衣康酸等的脂肪族多電子價羧酸；六氫苯二酸、1，2 -環己烷羧酸、1，2， 4 -環己烷三羧酸、環戊烷四羧酸等的脂肪族多電子價羧酸、苯二酸、異苯二酸、對苯二甲酸、三苯四甲酸、均苯四甲酸、1，2，5，8 -萘基四羧酸等的芳香族多電子價羧酸。其中由硬化組成物的反應性、形成硬化膜的耐熱性等觀點，芳香族多電子價羧酸爲較適當。這些多電子價羧酸無水物或多電子價羧酸可單獨或2 種以上組合使用。〔F〕成份的使用比例，一般對100重量份的〔A’ 〕而言，較佳爲1至1 00重量份，較佳爲1 〇至7 0重量份。〔F〕成份的比例若不足1重量份時，難以得到具本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -ft— 1· ϋ ϋ ϋ ϋ ϋ ϋ ϋ I a— ϋ I · ·ϋ · J < i (請先閱讀背面之注意事項再本頁：訂· 線- 經濟部智慧財產局員工消费合作社印製 -28- 1250996 A7 _ B7 五、發明說明（26 ) 有十分高交聯密度的硬化膜，且該硬化膜的各種耐性可能會下降。另一方面，〔F〕成份的比例若超過1〇〇重量份時，所得之硬化佛中未反應的成份〔F〕較易大量殘留下來，其結果造成該硬化膜性質的不安定，且對基體的硬化膜之密著性亦會下降。 iD ’〕成份作爲與〔A ’〕成份相異的環氧基樹脂，可使用於〔D 〕成份舉例者。環氧基樹脂〔D’〕的使用比例爲每1 〇 0重量份的成份〔A’〕，較佳爲1至200重量份、更佳爲3至100 重量份。且，成份〔A ’〕亦爲環氧基樹脂，但成份〔D’〕的環氧基樹脂與成份〔.A ’〕作比較爲低分子量體，且對平坦化性的提升效果上則相異。請先閲讀背，面之注項再本頁裝 •訂 ▲ 經濟部智慧財產局員工消费合作社印製〔E ’〕成份作爲〔E ’〕酸引發劑，於〔E〕成份所舉例出中，可使用由熱產生酸的化合物。酸引發劑〔E ’〕的使用比例，對每1 0 0重量份的〔 A ’〕成份而言，0 · 01至20重量份爲佳，較佳爲 0 . 2至1 0重量份。〔E’〕成份的使用比例對1 〇〇重量份的〔A’〕成份而言，若不足0·01重量份時，因加熱產生的酸量會減本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -29- 1250996 Λ7 -------- B7 五、發明說明（27 ) 少’故十分難進行〔A，〕成份以及〔D，〕成份的交聯，所得之硬化膜之耐熱性、平坦化性、耐藥性、與基板的密著性等會有下降之狀況。另一方面，〔E ’〕成份的使用比例對1 0 0重量份的〔A ’〕成份而言，若超過2 〇重量份時 ’塗膜的膜會產生龜裂現象。墓他的添加劑本發明的硬化性組成物之第2型態係於，不損害本發明的目的之範圍內，因應必要可含有上述以外的其他添加劑。做爲其他添加劑，例如有有機矽烷偶合劑、硬化促進劑、界面活性劑、紫外線吸收劑等可舉出。〔有機矽烷偶合劑〕有機矽烷偶合劑係欲提升形成硬化膜時與基體之密著性而使用，可使用本發明的第1型態所舉例出之有機矽烷偶合劑。有機矽烷偶合劑之使用比例較佳爲對成份1 0 0重量份的〔A ’〕成份而言，爲100重量以下，較佳爲0 · 1 至1 0 0重量份，特佳爲1至4 0重量份。若有機矽烷偶合劑的使用比例不滿0 · 1時，無法得到欲形成硬化膜時與基體之間的密著性效果。另一方面，有機矽烷偶合劑的使用比例超過1 0 0重量份時，所得之硬化膜的耐鹼性、耐溶劑性等則會降低。本紙張尺度適用中國國家標準（CNS〉A4規格（210 X 297公釐） I I 1« ϋ «1 ϋ 1 ϋ ϋ 1 ·1 ϋ I · _ I I 請先閱讀背面之注意事項再訂· --線- 經濟部智慧財產局員工消费合作社印製 -30- 1250996 A7 ____ B7 五、發明說明（28 ) 〔硬化促進劑〕硬化促進劑係可促進〔A ’〕成份以及〔F〕成份’即與硬化劑的反應而使用者。一般使用含有2級氮原子或3 級氮原子之雜環構造的化合物。作爲此化合物的具體例子，可舉出吡咯、咪唑、吡啶、吡嗪、嘧啶、吲哚、吲唑、苯并咪唑或三聚異氰酸或這些的衍生物。其中以2 —甲基咪唑、2 —乙基一 4 一甲基咪唑、2 -十七烷基咪唑、4 一甲基一 2 -苯基咪唑、1 一苄基一 2 —甲基咪唑、2 —乙基一 4 一甲基一1 一（2’ 一氰基乙基）咪唑、2 —乙基一 4 一甲基一 1 一〔2’一（ 3”，5”一二胺基三嗪基）乙基〕咪唑、苯并咪唑等的咪嗤衍生物爲佳，最佳爲2 —乙基一 4 一甲基咪唑、4 一甲基一 2 -苯基咪唑、.1 —苄基—2 —甲基咪唑。這些化合物可單獨或2種以上組合作爲硬化促進劑使用。經濟部智慧財產局員工消費合作社印製 i — — — — — — — — — — — — ^ * I I W ^ f (請先閱讀背面之注意事項再本頁) 線- 硬化促進劑的使用比例對1 0 0重量份的成分〔A ’〕而言，以0.01至10重量份爲佳，較佳爲0.05至 5重量份。、· 〔界面活性劑〕界面活性劑使用於提升塗佈性，可使用本發明的第1 型態所舉出者。界面活性劑的使用比例其依種類或構成硬化性組成物本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -31 - 1250996 Λ7 ---B7 五、發明說明（29 ) 之各成份種類或比例等皆相異，使用對成分1 〇 0重量份的〔A’〕而言，以〇至1 〇重量份難，較佳爲 0.000 1至5重量份之範圍。硬化性組成物的調製本發明的硬化性組成物較有利爲溶解於適當的溶媒中成溶液狀態使用。例如本發明的第1型態，將共聚物〔A 〕、多官能性單體〔B〕、自由基引發劑〔C〕、與可任一添加的環氧基樹脂〔D〕、以及其他添加劑，於溶媒中以所定的比例混合，調製出溶液狀態的硬化性組成物。又，本發明的第2型態時，將共聚物〔A ’〕、成份〔 F〕、環氧基樹脂〔D’〕、與可任一添加的成份〔E〕、以及其他添加劑，於溶媒中以所定的比例混合，調製出溶液狀態的硬化性組成物。製造本發明的硬化性組成物所使用的溶劑，具體而言可舉出，例如甲醇、乙醇等醇類；四氫呋喃等醚類；乙二醇單甲基醚、乙二醇單乙基醚等乙二醇醚類；甲基溶纖劑乙酸酯、乙基溶纖劑乙酸酯等乙二醇烷基醚乙酸酯類；二乙二醇單甲基醚、二乙二醇單乙基醚、二乙二醇二甲基醚、二乙二醇二乙基醚、二乙二醇乙基甲基醚等二乙二醇類 ;丙二醇甲基醚、丙二醇乙基醚、丙二醇丙基醚、丙二醇丁基醚等丙二醇單烷基醚類；丙二醇甲基醚乙酸酯、丙二醇乙基醚乙酸酯、丙二醇丙基醚乙酸酯、丙二醇丁基醚乙酸酯等丙二醇烷基醚乙酸酯類·，丙二醇甲基醚丙酸酯、丙本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） --------I-----裝： (請先閱讀背面之注意事項再 * -綉· 經濟部智慧財產局員工消费合作社印製 -32· 1250996 A7 B7 五、發明說明（3〇 ) 二醇乙基醚丙酸酯、丙二醇丙基醚丙酸酯、丙二醇丁基醚丙酸酯等丙二醇烷基醚乙酸酯類；甲苯、二甲苯等芳香族碳水化合物；甲基乙基酮、環己酮、4 一羥基一 4 一甲基 -2-戊酮等酮類；以及乙酸甲基、乙酸乙基、乙酸丙基、乙酸丁基、2—羥基丙酮酸乙基、2—羥基一2-甲基丙酮酸甲基、2 —羥基一 2 —甲基丙酮酸乙基、羥基乙酸甲基、羥基乙酸乙基、羥基乙酸丁基、乳酸甲基、乳酸乙基、乳酸丙基、乳酸丁基、3 -羥基丙酸甲基、3 -羥基丙酸乙基、3 —羥基丙酸丙基、3 —丁氧基丙酸甲基、3 -丁氧基丙酸乙基、3 -丁氧基丙酸丙基、3 —丁氧基丙酸丁基等酯類。這些溶劑中，由溶解性、與各成份的反應性以及塗膜之較易形成觀點看來，以使用乙二醇醚類、乙二醇烷基醚乙酸酯類、酯類以及二乙二醇類較佳。且可與上述溶媒同時倂用高沸點溶媒。作爲可倂用的高沸點溶媒，例如可舉出，N —甲基甲醯胺、N，N —二甲基甲醯胺、N —甲基甲醯苯胺、N —甲基乙醯胺、N， N -二甲基乙醯胺、N —甲基吡咯烷酮、二甲基亞碼、苄基乙基醚、二己基醚、丙酮基丙酮、異佛爾酮、卡普輪酸、辛酸、1 一辛醇、1 一壬醇、苯甲醇 < 苯甲基乙酸、乙基安息香酸、硝酸二乙基、馬來酸二乙基、7 —丁內酯、碳酸乙烯酯、碳酸丙烯酯、苯基溶纖劑乙酸酯等可舉出。又，如上述所調製出之組成物溶液使用孔徑爲0 · 5 # m程度之米利波阿過濾器濾過後提供於使用者。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐1 一 -33 - — — — — — — — — — — — — · · I I < 鬢請先閱讀背面之注意事項再頁) 訂： -·錄· 經濟部智慧財產局員工消费合作社印製 1250996 A7 ___ B7 五、發明說明（31 ) I--— — — — — — — — — — ^ . (請先閲讀背面之注意事項再對於組成物溶液的硬化性組成物之濃度而言，雖無特別限制，可因應使用目的適宜地選擇。固體成份之濃度以 1至6 0重量％爲佳，較佳爲5至40重量份。霞·色保護膜的形成方法因使用本發明的硬化性組成物，可形成例如下述之硬化膜。本發明的硬化性組成物可適用於濾色保護膜的形成，此爲過去完全未知的事。使用本發明的第1型態的硬化性組成物時，可形成如以下之濾色保護膜。錄· 首先，於基板上的濾色保護膜表面塗上本發明的硬化性組成物溶液，經加熱除去溶劑而形成塗膜。作爲對濾色保護膜表面的硬化性組成物溶液之塗佈方法，例如可使用噴霧法、滾筒塗佈法、旋轉塗佈法等各方法。再將加熱（預熱）此塗膜。因加熱使得溶劑揮發出，得到無流動性之塗膜。經濟部智慧財產局員工消费合作社印製加熱條件依各成份的種類、組成比例等而相異，但通常可以於6 0至1 2 0°C下，以1 0至6 0 0秒程度之廣範圍下使用。、.‘ 且，過去的保護膜以照片石印法形成時，作爲預熱的條件，一般採用7 0至9 0 °C、3 0至3 0 0秒鐘之條件。因此作爲使用於本發明的硬化性組成物形成本發明的保護膜時之預熱條件，可無變更過去的保護膜形成步驟之條本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -34· 1250996 A7 B7 經濟部智慧財產局員工消费合作社印製五、發明說明（32 ) 而有直接採用之優點。再將加熱後的塗膜介著所定之圖案罩蔽以放射線照射後’以顯像液進行顯像，將不需要的部分除去。作爲顯像液，係由使用例如可使用氫氧化鈉、氫氧化鉀 '碳酸鈉、矽酸鈉、甲基矽酸鈉、氨水等無機鹼類；如乙基胺、η —丙基胺等一級胺類；二乙基胺、二一 η -丙基胺等二級胺類；三乙基胺、甲基二乙基胺、Ν —甲基吡咯烷酮等三級胺類；如二甲基乙醇胺、三乙醇胺等醇胺類 :如四甲基羥基銨鹽、四乙基羥基銨鹽、膽鹼等四級銨鹽 ;如吡咯、哌啶、1，8 —二吖雙環〔5 · 4 . 0〕— 7 一十一碳烯、1，5 -二吖雙環〔4 · 3 · 0〕一 5 —壬烷的環狀胺類之鹼類所成之鹼性水溶液所成。又上述鹼性水溶液中，可使用添加適當量甲醇、乙醇等之水溶性有機溶媒，界面活性劑等之水溶液作爲顯像液〇顯像時間通常爲3 0至1 8 0秒之間。又可使用液盛法、浸漬法等任一種皆可。顯像後，進行3 0至9 0秒間的流水洗淨，經由壓縮、空氣或壓縮氮氣風乾法，將基板上的水分除去，形成圖案狀包膜。繼續，以加熱板、烤箱等加熱裝置，‘所定溫度例如爲 1 5 0至2 5 0 °C下所定時間，例如於加熱板上進行5至 3 0分鐘、烤箱中爲3 0至9 0分鐘進行加熱處理，而得到模型狀的包膜。且於本發明所謂的「放射線」含有可見光、紫外線、X光線、電子線等意思。 $紙張尺度適用中S國家標準（CNS)A4規格（210 X 297公釐） ------— — — — — — — ^ · I I 歡 <請先閱讀背面之注意事項再本頁) 訂： # -線· -35- 1250996 A7 __ B7 五、發明說明（33 ) 其後，對使用本發明第2型態之硬化性組成物，形成濾色保護膜的方法作說明。 (請先閱讀背面之注意事項再本頁) 首先，將調製出的組成物溶液塗佈於必須形成硬化膜之基板表面上，進行預燒烤而將溶劑除去形成硬化性組成物之塗膜後，進行主要燒烤做成硬化膜。如上述，作爲組成物之塗佈方法，雖無特別限制，但可採用例如噴霧法、滾筒塗佈法、轉動塗佈法等適宜的方法。預燒烤的條件，雖依組成物溶液的各成分種類、使用比例等而不同，但較佳爲約6 0至1 2 0 °C中0 . 5至 2 0分鐘程度之間。又，作爲主要燒烤的條件，較佳爲採用1 5 0至 2 5 0 °C中〇 · 2至2小時程度之間。又，預燒烤以及主要燒烤各別可分1階段或2階段以上之步驟組合進行。【實施例】經濟部智慧財產局員工消费合作社印製以下示的合成例、實施例雖對本發明作具體說明’ 但本發明不受以下實施例所限制。合成例1 於具備有冷卻管、攪拌機的錐形瓶中放入1 0重量份的2，2’一偶氮（2，4 一二甲基戊腈）、250重量份的二乙二醇乙基甲基醚。再加入1 8重量份的苯乙烯、本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -36- 1250996 a? B7 五、發明說明（34 ) 2 0重量份的甲基丙烯酸、4 0重量份的甲基丙烯酸環氧丙基以及2 2重量的N -苯基馬來酸酣縮亞胺，氮素取代後開始緩和攪拌。使溶液溫度上昇至7 0 °C，於此溫度下保持3小時，得到含有共聚物〔A - 1〕的聚合物溶液。所得之聚合物溶液之固體部份濃度爲3 0 · 8重量％。合成例2 於具備有冷卻管、攪拌機的錐形瓶中放入1 〇重量份的2，2’ —偶氮（2，4 —二甲基戊腈）、250重量份的二乙二醇乙基甲基醚。再加入1 8重量份的苯乙烯、 2 0重量份的甲基丙烯酸、4 0重量份的甲基丙烯酸環氧丙基以及2 2重量的N -苯基己基馬來酸酣縮亞胺，氮素取代後開始緩和攪拌。使溶液溫度上昇至7 0 °C，於此溫度下保持3小時，得到含有共聚物〔A - 2〕的聚合物溶液。所得之聚合物溶液之固體部份濃度爲3 0 · 1重量％合成例3 於具備有冷卻管、攪拌機的錐形瓶中放入1 〇重量份的2，2’一偶氮（2，4 —二甲基戊腈·）、250重量份的二乙二醇乙基甲基醚。再加入2 0重量份的苯乙烯、 2 0重量份的甲基丙烯酸、4 0重量份的甲基丙烯酸環氧丙基以及20重量的三環〔5·2·1·02·6〕癸烷— 8 一基甲基丙烯酸酯，氮素取代後開始緩和攪拌。使溶液本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） --------------Μ--- - · (請先閱讀背面之注意事項再本頁) 訂： Φ •線· 經濟部智慧財產局員工消費合作社印製 -37- 1250996 A7 -B7 經濟部智慧財產局員工消费合作社印製五、發明說明（35 ) 溫度上昇至7 0 °C，於此溫度下保持3小時，得到含有共聚物〔A - 3〕的聚合物溶液。所得之聚合物溶液之固體部份濃度爲3 0 · 5重量％。實施例1 歷JL性樹脂組成物的調製溶解合成例1所得之聚合物溶液（相當於1 〇〇重量份（固體部份）的共聚物〔A — 1〕）、與80重量份的作爲成份〔B〕的KAYARAD DPHA (日本化藥股份有限公司製，二季戊四醇己基丙烯酸酯）、與1〇重量份的作爲成份〔C〕的IRGACURE-819 (筑波•特別•化學公司製、雙（2，4，6 —三甲基苯醯） -苯基膦化氧）與作爲接著劑的1 0重量份之r -環氧丙氧基丙.基三甲氧棊矽烷以及作爲界面活性劑的〇 . 1重量份之SH-28PA(東雷矽氧烷有限公司製）、並混合，使固體部份濃度爲2 8重量％溶解於二乙二醇二甲基醚後，濾過孔徑0 · 5 // m的米利波阿過濾器調製出硬化性樹脂組成物之溶液（S - 1 )。平坦化膜（I )的形成、、於玻璃基板上，上記的硬化性組成物（S - 1 )，使用旋轉塗佈機塗佈至膜厚爲2 ，使用加熱板進行8 0 °C下3分鐘條件的預先燒烤而形成塗膜。此塗膜中使用所定的圖案光罩，以3 6 5 nm強度1 OmW/cm2的紫外The copolymer [A copolymer [A]]-based compound (a 1 ), the compound (a 3 ) and the compound (a 4) are produced by radical polymerization in the presence of a polymerization initiator in a solvent. Among them, the compound (a2), the compound (a3), and the compound (a 4 ) can be used as exemplified in the copolymer [A]. The copolymer [A '] used in the present invention is preferably a compound (a 2 ) containing from 1 Torr to 70% by weight, particularly preferably from 20 to 60% by weight. A structural unit derived from the printing of employee consumption cooperatives. When the structural unit is less than 10% by weight of the copolymer, the resulting protective film tends to have heat resistance and surface hardness. On the other hand, when it exceeds 70% by weight, the storage stability of the curable composition tends to decrease. The copolymer [A'] used in the present invention is preferably a structural unit derived from a compound (a 3 ) containing 2 to 50% by weight, particularly preferably 5 to 40% by weight. When the structural unit is less than 2% by weight, heat resistance, chemical resistance, and surface hardness tend to be lowered. When the structural unit exceeds 50% by weight, the film formability of the coating film tends to decrease. The copolymer [A '] used in the present invention preferably contains 5 to 80% of the paper size applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -26- Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative Printing 1250996 Α7 —_____ Β7 V. Description of the invention (24) % by weight, particularly preferably from 10 to 70% by weight of the structural unit derived from the compound (a 4 ). When the amount of the structural unit is less than 5% by weight, the film formability of the coating film tends to decrease. If the structural unit exceeds 80% by weight, the heat resistance or the resistance is insufficient. Preferable specific examples of the copolymer [A '] include (meth)acrylic acid epoxypropyl/N-phenylmaleic anhydride imide/styrene copolymer, and (meth)acrylic acid propylene glycol. Base/N-cyclohexylmaleic anhydride imide/styrene copolymer, (meth)acrylic acid epoxypropyl/N-phenylmaleic anhydride imide/styrene//tricyclic [5 · 2 · 1 · 02'6] decane-8-yl (meth) acrylate copolymer, (meth)acrylic acid epoxy propyl / N - cyclohexyl maleic anhydride imide / styrene / / tricyclic [5 · 2·1·02'6] decane-8-(meth) acrylate copolymer. The solvent used in the production of the copolymer [A'] can be used as exemplified for the copolymer [A]. Further, as the polymerization initiator used for the production of the copolymer [A '], those exemplified for the copolymer [A] can be used. The copolymer [A '] used in the present invention is a polystyrene-equivalent weight average molecular weight (hereinafter referred to as [Mw]), and is usually 2 x 10 3 to 5 x 105, preferably 5 X 103 to 1 \ 1 〇 5 "if 1 When the ratio is less than 2, < 1 Ο 3, the obtained coating film tends to have heat resistance and surface hardness. On the other hand, if it exceeds 5 X 1 0 5, the flatness tends to decrease. Paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) IH ·ϋ ϋ I 1_· ·1 - I 1 I _1 ·1 I · 1 mtm •-I <Please read the notes on the back first Further ιφ this page) order · embroidered · -27 · 1250996 A7 _ _ B7 V. Description of invention (25) As the [F] component used in the multi-electron carboxylic acid anhydride or multi-electron carboxylic acid system as [A As a specific example of the polyelectron carboxylic acid anhydrate, anhydrous itaconic acid, anhydrous succinic acid, anhydrous citraconic acid, anhydrous dodecenoic acid, anhydrous triphenylaminecarboxylic acid are mentioned. Aliphatic dihydromanic acid, anhydrous maleic acid, anhydrous hexahydrophthalic acid, anhydrous methyltetrahydrophthalic acid, anhydrous hypnotic acid Anhydrous; 1,2,3,4 monobutyltetracarboxylic acid dihydrate; aromatic polyelectron of anhydrous phthalic acid, anhydrous pyromellitic acid, anhydrous triphenyl hexacarboxylic acid, anhydrous benzophenone tetracarboxylic acid An ester-containing acid anhydride of a carboxylic acid triphenyl hexacarboxylate, wherein an aromatic polyelectrovalent carboxylic acid anhydride, particularly anhydrous triphenyl hexacarboxylic acid, can obtain a cured film having high heat resistance. Specific examples of the carboxylic acid, an aliphatic polyelectron valent carboxylic acid such as succinic acid, glutaric acid, adipic acid, butane tetracarboxylic acid, maleic acid or itaconic acid; hexahydrophthalic acid, 1, 2 - An aliphatic polyelectron valent carboxylic acid such as cyclohexanecarboxylic acid, 1,2,4-cyclohexanetricarboxylic acid or cyclopentanetetracarboxylic acid, phthalic acid, isophthalic acid, terephthalic acid, or the like An aromatic polyelectron valent carboxylic acid such as pyromellitic acid, pyromellitic acid or 1,2,5,8-naphthyltetracarboxylic acid, which has a viewpoint of reactivity of a hardened composition and heat resistance of a cured film. An aromatic polyelectron valent carboxylic acid is suitable. These polyelectrovalent carboxylic acid anhydrides or polyelectrovalent carboxylic acids may be used alone or in combination of two or more. The proportion of the component [F] is generally from 1 to 100 parts by weight, preferably from 1 to 70 parts by weight, per 100 parts by weight of [A']. When less than 1 part by weight, it is difficult to obtain the Chinese National Standard (CNS) A4 specification (210 X 297 mm) - ft - 1 · ϋ ϋ ϋ ϋ ϋ ϋ ϋ I a ϋ I · · ϋ · J < i (Please read the notes on the back and then this page: Order · Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed -28- 1250996 A7 _ B7 V. Invention Description (26) Very high crosslink density The film is cured, and various resistances of the cured film may be lowered. On the other hand, when the ratio of the component [F] exceeds 1 part by weight, the unreacted component [F] in the obtained hardened Buddha is more likely to remain in a large amount, and as a result, the properties of the cured film are unstable, and The adhesion of the cured film of the substrate also decreases. The iD '' component is an epoxy resin different from the [A'] component, and can be used as an example of the [D] component. The epoxy resin [D'] is used in an amount of from 0 parts by weight per part [A'], preferably from 1 to 200 parts by weight, more preferably from 3 to 100 parts by weight. Further, the component [A '] is also an epoxy resin, but the epoxy resin of the component [D'] is compared with the component [.A '] as a low molecular weight body, and the effect of improving the planarization property is different. Please read the back, face notes and then install this page. ▲ The Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, printed the [E'] component as the [E'] acid initiator, as exemplified in the [E] component. A compound which generates an acid by heat can be used. The use ratio of the acid initiator [E '] is preferably from 0.01 to 20 parts by weight, preferably from 0.2 to 10 parts by weight, per 100 parts by weight of the [A'] component. When the [E'] component is used in an amount of less than 0. 01 parts by weight of the [A'] component, the amount of acid generated by heating may be reduced by the paper size. The Chinese National Standard (CNS) is applicable. A4 size (210 X 297 mm) -29- 1250996 Λ7 -------- B7 V. Invention description (27) Less, it is very difficult to carry out cross-linking of [A,] ingredients and [D,] ingredients. The heat resistance, flatness, chemical resistance, adhesion to the substrate, and the like of the obtained cured film may be lowered. On the other hand, when the component [E ‘] is used in an amount of more than 2 parts by weight based on 100 parts by weight of the component [A ‘], the film of the coating film may be cracked. Additive to the tomb of the present invention The second form of the curable composition of the present invention is within the range not impairing the object of the present invention, and may contain other additives other than the above as necessary. As other additives, for example, an organic decane coupling agent, a curing accelerator, a surfactant, an ultraviolet absorber, etc. may be mentioned. [Organic decane coupling agent] The organic decane coupling agent is used in order to improve the adhesion to the substrate when the cured film is formed, and the organic decane coupling agent exemplified in the first aspect of the invention can be used. The use ratio of the organic decane coupling agent is preferably 100% by weight or less, preferably 0. 1 to 100 parts by weight, particularly preferably 1 to 4, for the component [A'] of the component of 100 parts by weight. 0 parts by weight. When the proportion of the organic decane coupling agent used is less than 0.1, the adhesion between the substrate and the substrate when the cured film is to be formed cannot be obtained. On the other hand, when the proportion of the organic decane coupling agent used exceeds 100 parts by weight, the alkali resistance and solvent resistance of the obtained cured film are lowered. This paper scale applies to Chinese national standards (CNS>A4 specifications (210 X 297 mm) II 1« ϋ «1 ϋ 1 ϋ ϋ 1 ·1 ϋ I · _ II Please read the notes on the back and re-order - line - Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumer Cooperatives Printed -30-1250996 A7 ____ B7 V. INSTRUCTIONS (28) [hardening accelerator] The hardening accelerator promotes the [A '] and [F] components and hardeners. For the reaction, a compound having a heterocyclic structure containing a secondary nitrogen atom or a tertiary nitrogen atom is generally used. Specific examples of the compound include pyrrole, imidazole, pyridine, pyrazine, pyrimidine, anthracene, pyrene. An azole, a benzimidazole or a trimeric isocyanate or a derivative of these, wherein 2-methylimidazole, 2-ethyl-4-methylimidazole, 2-heptadecylimidazole, 4-methylidene-2 -phenylimidazole, 1-benzyl-2-methylimidazole, 2-ethyl-4-methyl-1-1(2'-cyanoethyl)imidazole, 2-ethyl-4-methyl-1-yl a [2'-(3",5"-diaminotriazinyl)ethyl]imidazole, benzimidazole, etc. Derivatives are preferred, and are preferably 2-ethyl-4-methylimidazole, 4-methyl-2-phenylimidazole, and 1-benzyl-2-methylimidazole. These compounds may be used alone or in combination of two or more. The combination is used as a hardening accelerator. Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed i — — — — — — — — — — — ^ * IIW ^ f (Please read the back note before this page) Line - Harden The proportion of the accelerator to be used is preferably 0.01 to 10 parts by weight, preferably 0.05 to 5 parts by weight, based on 100 parts by weight of the component [A ']. ···[Interfacial agent] Surfactant is used for The coating property can be improved by using the first type of the present invention. The proportion of the surfactant used depends on the type or composition of the curable composition. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297). -31 - 1250996 Λ7 ---B7 V. Inventive Note (29) The composition or proportion of each component is different. For the case of [A'] of 1 〇 0 parts by weight, 〇 to 1 The weight of the crucible is difficult, preferably in the range of 0.0001 to 5 parts by weight. Preparation of the composition The curable composition of the present invention is advantageously used in a solution in a suitable solvent. For example, in the first embodiment of the present invention, the copolymer [A], the polyfunctional monomer [B], The radical initiator [C], the epoxy group resin [D] which can be added thereto, and other additives are mixed in a predetermined ratio in a solvent to prepare a curable composition in a solution state. In the second form, the copolymer [A '], the component [F], the epoxy resin [D'], the optional component [E], and other additives are present in the solvent at a predetermined ratio. The mixture was mixed to prepare a hardenable composition in a solution state. Specific examples of the solvent used for producing the curable composition of the present invention include alcohols such as methanol and ethanol; ethers such as tetrahydrofuran; and ethylene glycol monomethyl ether and ethylene glycol monoethyl ether. Glycol ethers; ethylene cellosolve acetate, ethyl cellosolve acetate, etc., ethylene glycol alkyl ether acetate; diethylene glycol monomethyl ether, diethylene glycol monoethyl ether Diethylene glycol such as diethylene glycol dimethyl ether, diethylene glycol diethyl ether or diethylene glycol ethyl methyl ether; propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol propyl ether, Propylene glycol monoalkyl ethers such as propylene glycol butyl ether; propylene glycol alkyl ether acetate such as propylene glycol methyl ether acetate, propylene glycol ethyl ether acetate, propylene glycol propyl ether acetate, propylene glycol butyl ether acetate Class, propylene glycol methyl ether propionate, C-paper scale applicable to China National Standard (CNS) A4 specification (210 X 297 mm) --------I----- Packing: (Please first Read the precautions on the back and - * Embroidery · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing -32· 1250996 A7 B7 V. Invention description (3〇) Propylene glycol alkyl ether acetates such as alcohol ethyl ether propionate, propylene glycol propyl ether propionate, propylene glycol butyl ether propionate; aromatic carbohydrates such as toluene and xylene; methyl ethyl ketone, cyclohexyl Ketones, ketones such as 4-hydroxy-4-methyl-2-pentanone; and methyl acetate, ethyl acetate, propyl acetate, butyl acetate, ethyl 2-hydroxyacetonate, 2-hydroxy- 2- Methyl methylpyruvate, ethyl 2-hydroxy-2-methylpyruvate, methyl hydroxyacetate, ethyl hydroxyacetate, butyl hydroxyacetate, methyl lactic acid, ethyl lactate, propyl lactate, butyl lactate , 3-hydroxypropionic acid methyl, 3-hydroxypropionic acid ethyl, 3-hydroxypropionic acid propyl, 3-butoxypropionic acid methyl, 3-butoxypropionic acid ethyl, 3-butoxy An ester such as propyl propionate or butyl 3-butoxypropionate. Among these solvents, glycol ethers are used from the viewpoints of solubility, reactivity with each component, and ease of formation of a coating film. Further, ethylene glycol alkyl ether acetates, esters, and diethylene glycols are preferred, and a high-boiling solvent can be used together with the above solvent. Examples of the high-boiling solvent which can be used include N-methylformamide, N,N-dimethylformamide, N-methylformamide, N-methylacetamide, and N. , N-dimethylacetamide, N-methylpyrrolidone, dimethylamethylene, benzylethyl ether, dihexyl ether, acetone acetone, isophorone, caprolic acid, octanoic acid, 1 Octanol, 1-nonanol, benzyl alcohol < benzylglycolic acid, ethyl benzoic acid, diethyl nitrate, diethyl maleate, 7-butyrolactone, ethylene carbonate, propylene carbonate, phenyl The cellosolve acetate or the like can be exemplified. Further, the composition solution prepared as described above is supplied to the user after filtration using a Millipona filter having a pore diameter of 0 · 5 # m. The paper scale is applicable to the Chinese country. Standard (CNS) A4 specifications (210 X 297 mm 1 -33 - — — — — — — — — — — — · · · · < 鬓 Please read the notes on the back and then page) Order: - Record · Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1250996 A7 ___ B7 V. Invention Description (31) I-------- - - -. ^ (Read Notes on the back for further concentration of the solution of the composition of the curable composition, although not particularly limited, may be suitably selected in response to the purpose of use. The concentration of the solid component is preferably from 1 to 60% by weight, preferably from 5 to 40 parts by weight. Method for Forming Xia Color Protective Film By using the curable composition of the present invention, for example, a hardened film described below can be formed. The curable composition of the present invention can be applied to the formation of a color filter protective film, which is completely unknown in the past. When the curable composition of the first form of the present invention is used, a color filter protective film such as the following can be formed. Recording First, the surface of the color filter protective film on the substrate is coated with the curable composition solution of the present invention, and the solvent is removed by heating to form a coating film. As a method of applying the curable composition solution to the surface of the color filter film, for example, various methods such as a spray method, a roll coating method, and a spin coating method can be used. This coating film is heated (preheated). The solvent is volatilized by heating to obtain a coating film having no fluidity. The heating conditions printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, the consumer cooperatives, vary according to the type and composition ratio of each component, but usually can be as high as 10 to 600 seconds at 60 to 120 °C. Used under the scope. 。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。 Therefore, as the preheating condition for forming the protective film of the present invention as the curable composition of the present invention, the paper size of the past protective film forming step can be applied to the Chinese National Standard (CNS) A4 specification (210 X 297). PCT) -34· 1250996 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description (32) and has the advantage of direct adoption. Further, the heated coating film was masked by a predetermined pattern to be irradiated with radiation, and then developed with a developing liquid to remove unnecessary portions. As the developing solution, for example, an inorganic base such as sodium hydroxide, potassium hydroxide, sodium carbonate, sodium citrate, sodium methyl citrate or ammonia can be used; for example, ethylamine, η-propylamine, etc. Amines; secondary amines such as diethylamine and di-n-propylamine; tertiary amines such as triethylamine, methyldiethylamine and hydrazine-methylpyrrolidone; such as dimethylethanolamine, Alcoholamines such as triethanolamine: such as tetramethylammonium salt, tetraethylhydroxyammonium salt, choline and other quaternary ammonium salts; such as pyrrole, piperidine, 1,8-dioxabicyclo [5 · 4 . 0] — 7 is formed by using an alkaline aqueous solution of a base of a cyclic amine such as an undecene, 1,5-dibicyclo[4·3·0]-5-decane. Further, in the above aqueous alkaline solution, a water-soluble organic solvent such as methanol or ethanol may be added, and an aqueous solution such as a surfactant may be used as the developing liquid. The development time is usually from 30 to 180 seconds. Further, any one of a liquid method and a dipping method can be used. After the development, the running water was washed for 30 to 90 seconds, and the water on the substrate was removed by compression, air or compressed nitrogen air drying to form a pattern-like envelope. Continue to use a heating device such as a heating plate or an oven. The specified temperature is, for example, a time set at 150 to 250 °C, for example, 5 to 30 minutes on a hot plate and 30 to 90 minutes in an oven. Heat treatment was carried out to obtain a mold-like envelope. Further, the term "radiation" as used in the present invention means visible light, ultraviolet light, X-rays, and electron lines. $ paper scale applies to the S National Standard (CNS) A4 specification (210 X 297 mm) ---------------^ ^ II Huan <Please read the back note before this page) 。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。。 (Please read the precautions on the back side and then on this page.) First, apply the prepared composition solution to the surface of the substrate on which the cured film must be formed, pre-bake and remove the solvent to form a coating film of the curable composition. Perform a main barbecue to make a cured film. As described above, the coating method of the composition is not particularly limited, and an appropriate method such as a spray method, a roll coating method, or a spin coating method can be employed. The pre-baking conditions vary depending on the type of the components of the composition solution, the ratio of use, and the like, but are preferably between about 60 and 20 ° C in the range of about 0.5 to 20 minutes. Further, as a condition of the main grilling, it is preferable to use between 1 and 2 to 2 hours in the range of 150 to 250 °C. Further, the pre-baked and the main grills may be combined in a single step or a combination of two or more steps. [Embodiment] Printing by the Ministry of Economic Affairs, Intellectual Property Office, and Employees' Cooperatives The following description of the synthesis examples and examples will be specifically described, but the present invention is not limited by the following examples. Synthesis Example 1 10 parts by weight of 2,2'-azo (2,4-dimethyl pentanenitrile) and 250 parts by weight of diethylene glycol B were placed in an Erlenmeyer flask equipped with a cooling tube and a stirrer. Methyl ether. Add 18 parts by weight of styrene, this paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -36- 1250996 a? B7 V. Description of invention (34) 20 parts by weight of methyl Acrylic acid, 40 parts by weight of glycidyl methacrylate, and 22 parts by weight of N-phenylmaleic acid ruthenium imine, which were gradually agitated after nitrogen substitution. The temperature of the solution was raised to 70 ° C and maintained at this temperature for 3 hours to obtain a polymer solution containing the copolymer [A-1]. The solid portion concentration of the obtained polymer solution was 3 0 · 8 wt%. Synthesis Example 2 1 part by weight of 2,2'-azo (2,4-dimethylvaleronitrile) and 250 parts by weight of diethylene glycol B were placed in an Erlenmeyer flask equipped with a cooling tube and a stirrer. Methyl ether. Further, 18 parts by weight of styrene, 20 parts by weight of methacrylic acid, 40 parts by weight of glycidyl methacrylate, and 22 parts by weight of N-phenylhexyl maleic acid acetimimine, nitrogen After the substitution, the mixture began to ease the agitation. The temperature of the solution was raised to 70 ° C and maintained at this temperature for 3 hours to obtain a polymer solution containing the copolymer [A - 2 ]. The solid portion concentration of the obtained polymer solution was 30% by weight. Synthesis Example 3 In a conical flask equipped with a cooling tube and a stirrer, 1 part by weight of 2,2'-azo (2, 4) was placed. - dimethyl valeronitrile ·), 250 parts by weight of diethylene glycol ethyl methyl ether. Further adding 20 parts by weight of styrene, 20 parts by weight of methacrylic acid, 40 parts by weight of epoxypropyl methacrylate, and 20 parts by weight of tricyclo [5·2·1·02·6] decane — 8-Methyl methacrylate, after the nitrogen substitution, began to ease the agitation. Make the solution paper size applicable to China National Standard (CNS) A4 specification (210 X 297 mm) --------------Μ--- - · (Please read the notes on the back first) This page) Order: Φ • Line · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing -37- 1250996 A7 -B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description (35) Temperature rise to 70 ° C The mixture was kept at this temperature for 3 hours to obtain a polymer solution containing the copolymer [A-3]. The solid portion concentration of the obtained polymer solution was 3 0 · 5 wt%. Example 1 Preparation of JL Resin Composition The polymer solution obtained in Synthesis Example 1 (corresponding to 1 part by weight (solid portion) copolymer [A-1]) and 80 parts by weight as a component [B] KAYARAD DPHA (manufactured by Nippon Kayaku Co., Ltd., dipentaerythritol hexyl acrylate), and 1 part by weight of IRGACURE-819 (made by Tsukuba Special Chemical Co., Ltd.) 4,6-trimethylphenylhydrazine)-phenylphosphine oxide) with 10 parts by weight of r-glycidoxypropyltrimethoxysilane as an adhesive and as a surfactant. Parts by weight of SH-28PA (manufactured by Toray Oxygen Co., Ltd.), and mixed, so that the solid portion concentration of 28% by weight is dissolved in diethylene glycol dimethyl ether, and the filtration pore size is 0 · 5 // m The Miriboa filter modulates a solution (S - 1 ) of the curable resin composition. The formation of the planarizing film (I) and the curable composition (S-1) on the glass substrate were applied to a film thickness of 2 using a spin coater, and 80 ° C was performed using a hot plate. A coating film is formed by pre-baking in a minute condition. The coating mask used in this coating film is UV at a density of 3 6 5 nm and 1 OmW/cm 2 .

(請先閱讀背面之注意事項再I本V •裝 l^J· •絲· 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -38 - 1250996 Α7 ___________________ Β7 五、發明說明（36 ) 光照射3 0秒。此紫外線照射於空氣中實施。於無塵烤箱中實施2 5 0 °C的1小時的主燒烤形成平坦化膜。 --------------裝--- (請先閱讀背面之注意事項再I本頁) 平坦化膜（II)的形成於玻璃基板上，形成以J S R系光阻劑（R · g · B )具有條狀的紅、藍、綠三色的濾色（條福爲1 〇〇 V m )之基板。具有此濾色的玻璃基板表面之凹凸以表面凹凸計α - step (天克路公司製）測定，結果爲1 · 0//m。此形成濾色的玻璃基板上，與上述平坦化膜（I )的形成相同，進行硬化性組成物的塗佈、預先燒烤、以及主燒烤，形成平坦化膜（I I )。平坦化膜的評價密著性 •線- 經濟部智慧財產局貝工消费合作社印製 JIS K— 5400(1900)8.5 的附著性試驗中以8 . 5 · 2的方格帶子法，於上述平坦化膜（I )以及平坦化膜（Π )的以切刀形成1 0 0方格子而進行附著性試驗。此時，未剝離殘留的格子數如表1所示。平坦化膜（I )的密著性爲密著性（I )、平坦化膜 (n )的密著性爲密著性（π )。 ’ ‘ 表面硬度 J IS K - 5400 (1900) 8·4 的鉛筆刮擦試驗中，8 · 5 · 1的試驗法爲準’對上述所形成的平本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公* ) -39- 1250996 A7 _ B7 經濟部智慧財產局貝工消费合作社印製五、發明說明（37 ) 坦化膜（I )進行鉛筆刮擦試驗，實施平坦化膜的表面硬度之評估。結果如表1所示。耐酸性如上述所形成的平坦化膜（I )所形成的剝離基板，於 HC 1/F e C 1 2 · H2O/水=2/1/1 重量比水溶液中於4 5 °C浸漬1 5分鐘後，由觀察平坦化膜的外觀變化進行保護膜的耐酸性之評估。此時，外觀無變化者爲耐酸性良好，而外觀已剝落且白化者爲耐酸性不良。耐鹼性上述平坦化膜（I )所形成的玻璃基板，浸漬於5重量％氫氧化鈉水溶液中於3 0 °C下浸漬3 0分鐘後，藉由觀察平坦化膜的外觀變化對保護膜的耐酸性進行評估。此時，外觀無變化者爲耐鹼性良好，而外觀已剝落且白化者爲耐酸性不良。耐熱性 . 對於上述形成的保護膜，以接觸式膜厚測定裝置α -step (天可爾日本股份有限公司製）測、膜厚後，於無塵烤箱中進行2 5 0 °C以及2 7 0 °C、6 0分鐘的追加燒烤。經追加燒烤後，再度測定膜厚，計算出經追加燒烤前後之膜減少率。結果如表1所示。 (請先閱讀背面之注意事項再頁：訂· — 線. 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -40- 1250996 A7 B7 經濟部智慧財產局員工消费合作社印製五、發明說明（38 ) 耐熱變色性對上述平坦化膜（I )所形成的玻璃基板，測定對波長4 0 0至7 0 0 nm的透過光譜。再將此玻璃基板於無塵烤箱中以2 5 0 °C下加熱6 0分鐘後，再測定對波長 400至700nm的透過光譜。調查加熱前後的400 nm透過光譜之變化，評估耐熱變色性。加熱前後的 4 0 0 nm透過光譜之變化率如表1所示。平坦化性上述平坦化膜（Π )的表面凹凸，以表面凹凸計α -step測定。以下式爲準計算出之平坦化率如表1所示。平坦化率=平坦化膜（Π)的表面凹凸/保護膜塗佈前的彩色濾器之表面凹凸X 1 0 0 (% )。實施例2 對於實施例1，取代作爲成份（B ) K A Y A R A D DPHA使用阿羅倪克斯TO - 1 4 5 0，其他與實施例 1相同調製出組成物溶、液（S - 2 )作評價。其結果如表 1所示。 v 實施例3 對於實施例1，取代含有共聚物〔A - 1〕的溶液使用含有合成例2所得之共聚物〔A - 2〕的溶液，其他與實施例1相同調製出組成物溶液（S — 3 )作評價。其結本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公' •41 - ------------裝 — 丨_丨\ (請先閱讀背面之注意事項再頁) _ 訂· •絲· 1250996 五、發明說明（39 ) 果如表1所示。比較例1 對於實施例1 ’取代含有共聚物〔A - 1〕的溶液使用含有合成例3所得之共聚物〔A — 3〕的溶液，其他與實施例1相同調製出組成物溶液（S — 4 )作評價。其結果如表1所示。表密著性表面硬度耐酸性耐鹼性耐熱性（％) 耐熱變色平坦化率 (%) (I) (II) 250 °C 270 °C 250 °C 270 °C 實施例1 0/100 0/100 5H 良良 98 93 3 7 18 好好實施例2 0/100 0/100 4H 良良 98 92 3 7 20 好好實施例3 0/100 0/100 5H 良良 97 92 3 7 23 好好比較例1 0/100 0/100 5H 良良 94 85 5 13 32 好好合成例4 於具備有冷卻管、攪拌機的錐形瓶中放入6重量份的 2，2’一偶氮（異丁腈）、200重量份的丙二醇單甲基醚乙酸酯。再加入2 0重量份的苯乙烯6 5重量份的甲基本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------I ^ i — (請先閱讀背面之注意事項再%本頁) 訂· -線· 經濟部智慧財產局員工消费合作社印製 -42 - 1250996 A7 _ B7 經濟部智慧財產局員工消費合作社印製五、發明說明（4〇 ) 丙烯酸環氧丙基以及15重量份的N-苯基馬來酸酣縮亞胺，氮素取代後開始緩和攪拌。使溶液溫度上昇至9 5 °C ，於此溫度下保持4小時，得到含有共聚物〔A - 4〕的聚合物溶液。所得之聚合物溶液之固體部份濃度爲 3 2 · 8重量％。合成例5 於具備有冷卻管、攪拌機的錐形瓶中放入6重量份的 2，2’一偶氮（異丁腈）、200重量份的丙二醇單甲基醚乙酸酯。再加1 8重量份的苯乙烯6 2重量份的甲基丙烯酸環氧丙基以及2 0重量份的N -環己基馬來酸酣縮亞胺，氮素取代後開始緩和攪拌。使溶液溫度上昇至9 5 °C ，於此溫度下保持4小時，得到含有共聚物〔A - 5〕的聚合物溶液。所得之聚合物溶液之固體部份濃度爲 3 3 . 0重量％。合成例6 於具備有冷卻管、攪拌機的錐形瓶中放入6重量份的 2，2’一偶氮（異丁腈）、200重量份的丙二醇單甲基醚乙酸酯。再加入4 0重量的三環〔5, : 2 · 1 . 0 2 · 6 〕癸烷- 8 -基甲基丙烯酸酯、6 0重量份的甲基丙烯酸環氧丙基，氮素取代後開始緩和攪拌。使溶液溫度上昇至 9 ，於此溫度下保持4小時，得到含有共聚物〔A - 6〕的聚合物溶液。所得之聚合物溶液之固體部份濃度爲 (請先閲讀背面之注意事項再.¾本頁) -裝訂- ;線- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -43- 1250996 A7 B7 經濟部智慧財產局員工消費合作社印製五、發明說明（41 ) 3 2 . 8重量％。合成例7 於具備有冷卻管、攪拌機的錐形瓶中放入6重量份的 2，2’一偶氮（異丁腈）、200重量份的丙二醇單甲基醚乙酸酯。再加2 0重量份的苯乙烯8 0重量份的甲基丙烯酸環氧丙基，氮素取代後開始緩和攪拌。使溶液溫度上昇至9 5 °C，於此溫度下保持4小時，得到含有共聚物〔 A - 7〕的聚合物溶液。所得之聚合物溶液之固體部份濃度爲3 2 · 4重量％。實施例4 硬化性樹脂組成物的調製含有上述合成例4所合成的聚合物〔A — 4〕聚合物溶液（相當於1 0 0重量份（固體部份）的聚合物〔A -4〕）以100重量份的丙二醇單甲基乙酸酯稀釋後，添加作爲成份〔D’〕使用2 0重量份的埃皮科特 1032H60 (環式脂肪族環氧基樹脂、油化貝殼環氧股份有限公司製）、作爲有機矽烷偶合劑使用0 . 0 2重量份美格福克1 7 2 (氟素界面活性劑、大日本墨水化學股份有限公司製）爲主劑，作爲成份「F」的硬化劑，添加以二乙二醇甲基乙基醚的2 5%溶液固體部份換算値爲 2 0重量份的無水偏苯三酸，經充分攪拌後而得到硬化性組成物（S — 5 )。 (請先閱讀背面之注意事項再裝訂· ;錦· 0 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -44- 1250996 A7 B7 經濟部智慧財產局員工消费合作社印製五、發明說明（42 ) 保護膜（I I I )的形成於玻璃基板上，上記的硬化性組成物（S - 5)，使用旋轉塗佈機塗佈至膜厚爲2 //m，使用加熱板進行8 Ot下 3分鐘條件的預先燒烤而形成塗膜。再於無塵烤箱中實施 2 5 0 °C的1小時的主燒烤形成保護膜。濾色保護膜（I V )的形成於玻璃基板上，形成以J SR系光阻劑（R · G · B )具有條狀的紅、藍、綠三色的濾色（條福爲1 〇〇 )之基板。具有此濾色的玻璃基板表面之凹凸以表面凹凸計α — step (天克路公司製）測定，結果爲1 · 0//m。此形成濾色的玻璃基板上，與上述平坦化膜（I I I )的形成相同，進行硬化性組成物的塗佈、預先燒烤、以及主燒烤，形成保護膜（I V )。保護膜的評價密著性 J IS K— 5400 (1900) 8. 5 的附著性試驗中以8 · 5 · 2的方格帶子法，於上述保護膜（ III)以及保護膜（IV)的以切刀形成100方格子而進行附著性試驗。此時，未剝離殘留的格子數如表2所示。保護膜（I I I )的密著性爲密著性（I I I )、保(Please read the notes on the back and then I. V • Install l^J· • Silk • This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -38 - 1250996 Α7 ___________________ Β7 V. Invention Description (36) Light irradiation for 30 seconds. This ultraviolet light is applied to the air. The main grill is dried at 250 ° C for 1 hour in a dust-free oven to form a flattening film. ----装--- (Please read the precautions on the back and then I page) The flattening film (II) is formed on the glass substrate to form a strip of JSR photoresist (R · g · B) A substrate of a red, blue, and green color filter (1 〇〇V m ). The unevenness of the surface of the glass substrate having the color filter is measured by a surface unevenness meter α - step (manufactured by Tiankelu) The result is 1 · 0 / / m. The glass substrate forming the color filter is coated with the curable composition, pre-baked, and main grilled to form a flattening as in the formation of the planarizing film (I). Membrane (II). Adhesiveness of flattened film • Line - Ministry of Economic Affairs, Intellectual Property Bureau, Bayer Consumer Cooperative, JIS K-5400 In the adhesion test of (1900) 8.5, adhesion was performed by forming a 100-square lattice on the flattening film (I) and the planarizing film (Π) by the square tape method of 8.5 · 2 At this time, the number of lattices which were not peeled off was as shown in Table 1. The adhesion of the planarizing film (I) was adhesion (I), and the adhesion of the planarizing film (n) was adhesion ( π ). ' ' Surface hardness J IS K - 5400 (1900) 8·4 pencil scratch test, 8 · 5 · 1 test method shall prevail 'Applicable to the Chinese national standard for the above-mentioned flat paper scale ( CNS)A4 specification (210 X 297 public*) -39- 1250996 A7 _ B7 Ministry of Economic Affairs Intellectual Property Bureau Bayer Consumer Cooperative Printed 5, Invention Description (37) Tanned film (I) pencil scratch test, flat The surface hardness of the film was evaluated. The results are shown in Table 1. The peeling substrate formed of the flattening film (I) formed by the above-mentioned acid resistance was HC 1/F e C 1 2 · H 2 O / water = 2 / After immersing for 1 5 minutes at 45 ° C in a 1/1 by weight aqueous solution, the acid resistance of the protective film was evaluated by observing the change in appearance of the planarized film. The appearance is unchanged, the acid resistance is good, and the appearance is exfoliated and the whitening is acid-resistant. The alkali-resistant glass substrate formed by the flattening film (I) is immersed in a 5 wt% sodium hydroxide aqueous solution at 30. After immersion for 30 minutes at ° C, the acid resistance of the protective film was evaluated by observing the change in appearance of the planarizing film. At this time, the appearance is unchanged, the alkali resistance is good, and the appearance is peeled off and the whitening is poor in acid resistance. Heat resistance. The protective film formed as described above was measured by a contact-type film thickness measuring device α-step (manufactured by Tenkel Japan Co., Ltd.), and then subjected to a film thickness of 2,500 ° C and 2 7 in a dust-free oven. Additional barbecue at 0 °C, 60 minutes. After the additional grilling, the film thickness was measured again, and the film reduction rate before and after the additional grilling was calculated. The results are shown in Table 1. (Please read the notes on the back page again: Book · Line. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -40- 1250996 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative 5. Description of the invention (38) Heat-resistant discoloration The glass substrate formed by the planarizing film (I) is measured for a transmission spectrum of a wavelength of from 400 to 700 nm. The glass substrate is placed in a dust-free oven. After heating at 205 ° C for 60 minutes, the transmission spectrum at a wavelength of 400 to 700 nm was measured. The change in the transmission spectrum at 400 nm before and after heating was investigated to evaluate the heat discoloration resistance. The transmission spectrum of 400 nm before and after heating The rate of change is shown in Table 1. Flatness The surface unevenness of the flattening film (Π) was measured by surface unevenness α-step. The flattening ratio calculated by the following formula is shown in Table 1. = surface unevenness of the flattening film (Π) / surface unevenness of the color filter before application of the protective film X 1 0 0 (%). Example 2 For Example 1, substitution as a component (B) KAYARAD DPHA use Aro Ni克斯TO - 1 4 5 0, other and implementation The composition solution and the liquid (S - 2 ) were prepared in the same manner as in Example 1. The results are shown in Table 1. v Example 3 For the example 1, the solution containing the copolymer [A-1] was used instead of the synthesis example. 2 The solution of the obtained copolymer [A-2] was evaluated in the same manner as in Example 1 for the composition solution (S-3). The paper size of the paper was applied to the Chinese National Standard (CNS) A4 specification (210 X 297).公' •41 - ------------装— 丨_丨\ (Please read the notes on the back page again) _ 订· •丝·1250996 V. Inventions (39) Table 1 is shown in Comparative Example 1. For the solution of Example 1 'substituted with the copolymer [A-1], a solution containing the copolymer [A-3] obtained in Synthesis Example 3 was used, and other compositions were prepared in the same manner as in Example 1. The solution (S-4) was evaluated. The results are shown in Table 1. Surface adhesion hardness, acid resistance, alkali resistance, heat resistance (%), heat dissipation, flatness (%) (I) (II) 250 ° C 270 °C 250 °C 270 °C Example 1 0/100 0/100 5H Liangliang 98 93 3 7 18 Good example 2 0/100 0/100 4H Liangliang 98 92 3 7 20 Good example 3 0/100 0/100 5H Liangliang 97 92 3 7 23 Good comparison example 1 0/100 0/100 5H Liangliang 94 85 5 13 32 Good synthesis example 4 In an Erlenmeyer flask having a cooling tube and a stirrer, 6 parts by weight of 2,2'-azo (isobutyronitrile) and 200 parts by weight of propylene glycol monomethyl ether acetate were placed. Add 20 parts by weight of styrene, 6 5 parts by weight of methyl paper. The scale of the paper applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ------------I ^ i — (Please read the note on the back and then the % page) Order · Line · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing -42 - 1250996 A7 _ B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description ( 4〇) Epoxypropyl acrylate and 15 parts by weight of N-phenylmaleic acid hydrazide, which were gradually agitated after nitrogen substitution. The temperature of the solution was raised to 95 ° C and maintained at this temperature for 4 hours to obtain a polymer solution containing the copolymer [A - 4]. The solid portion concentration of the obtained polymer solution was 3 2 · 8 wt%. Synthesis Example 5 6 parts by weight of 2,2'-azo (isobutyronitrile) and 200 parts by weight of propylene glycol monomethyl ether acetate were placed in an Erlenmeyer flask equipped with a cooling tube and a stirrer. Further, 18 parts by weight of styrene, 62 parts by weight of methacrylic acid epoxypropyl group and 20 parts by weight of N-cyclohexylmaleic acid condensed imide were added, and the stirring was started after the nitrogen substitution. The temperature of the solution was raised to 95 ° C and maintained at this temperature for 4 hours to obtain a polymer solution containing the copolymer [A - 5 ]. The solid portion concentration of the obtained polymer solution was 33.0% by weight. Synthesis Example 6 6 parts by weight of 2,2'-azo (isobutyronitrile) and 200 parts by weight of propylene glycol monomethyl ether acetate were placed in an Erlenmeyer flask equipped with a cooling tube and a stirrer. 40 parts of tricyclo [5, : 2 · 1 . 0 2 · 6 ] decane-8-yl methacrylate and 60 parts by weight of epoxy methacrylate were added, and the nitrogen substitution was started. Alleviate the agitation. The temperature of the solution was raised to 9 and maintained at this temperature for 4 hours to obtain a polymer solution containing the copolymer [A-6]. The solids concentration of the obtained polymer solution is (please read the precautions on the back page again. 3⁄4) - Binding - ; Line - This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -43- 1250996 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printing V. Inventions (41) 3 2 . 8 wt%. Synthesis Example 7 6 parts by weight of 2,2'-azo (isobutyronitrile) and 200 parts by weight of propylene glycol monomethyl ether acetate were placed in an Erlenmeyer flask equipped with a cooling tube and a stirrer. Further, 20 parts by weight of styrene 80 parts by weight of methacrylic acid epoxypropyl group was added, and after the substitution by nitrogen, the stirring was started. The temperature of the solution was raised to 95 ° C and maintained at this temperature for 4 hours to obtain a polymer solution containing the copolymer [A-7]. The solid portion of the obtained polymer solution had a concentration of 3 2 · 4 wt%. Example 4 Preparation of Curable Resin Composition The polymer [A-4] polymer solution synthesized in the above Synthesis Example 4 (corresponding to 100 parts by weight (solid portion) of polymer [A-4]) After diluting with 100 parts by weight of propylene glycol monomethyl acetate, 20 parts by weight of Epicot 1032H60 (cycloaliphatic epoxy resin, oiled shell epoxy) was added as a component [D']. The company's system), as an organic decane coupling agent, used 0.02 part by weight of Megford 1 7 2 (fluorine surfactant, manufactured by Dainippon Ink Chemical Co., Ltd.) as the main agent, and hardened as the ingredient "F". The agent is added with 20 parts by weight of anhydrous trimellitic acid in a 25% solution solid portion of diethylene glycol methyl ethyl ether, and is sufficiently stirred to obtain a hardenable composition (S-5). . (Please read the precautions on the back and then bind. · Jin· 0 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -44- 1250996 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative print V. INSTRUCTION OF THE INVENTION (42) The protective film (III) is formed on a glass substrate, and the above-mentioned curable composition (S-5) is applied to a film thickness of 2 //m using a spin coater, and a heating plate is used. A coating film was formed by pre-baking under a condition of 8 Ot for 3 minutes, and a protective film was formed by performing a main grill at 250 ° C for 1 hour in a dust-free oven. The color filter film (IV) was formed on the glass substrate. Forming a substrate having a strip of red, blue, and green color (striped as 1 以) in a J SR-based photoresist (R · G · B ). The surface of the glass substrate having the color filter The unevenness was measured by a surface unevenness meter α - step (manufactured by Tektronix Co., Ltd.), and it was 1 · 0 / / m. The glass substrate on which the color filter was formed was cured in the same manner as the formation of the planarizing film (III ). Coating of the composition, pre-baking, and main grilling to form a protective film (IV Evaluation of adhesion of protective film J IS K-5400 (1900) 8. The adhesion test of 8.5 in the adhesion test of the protective film (III) and the protective film (IV) The adhesion test was carried out by forming a 100-square lattice with a cutter. At this time, the number of lattices which were not peeled off was as shown in Table 2. The adhesion of the protective film (III) was adhesion (III), and the protection was maintained.

(請先閱讀背面之注意事項再A •裝訂：線. 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -45- 經濟部智慧財產局員工消费合作社印製 1250996 A7 _ B7 五、發明說明（43 ) 護膜（I V )的密著性爲密著性（；[V )。表面硬度 J I S K — 5 4 0 0 ( 1 9 0 〇 ) 8 · 4 的鉛筆刮擦試驗中，8 · 5 · 1的試驗法爲準，對上述所形成的保護膜（I I I )進行鉛筆刮擦試驗，實施保護膜的表面硬度之評估。結果如表2所示。耐酸性如上述所形成的保護膜（I I I )所形成的玻璃基板，於 HC Ι/FeC 12·Η2〇/水=2/1/1 重量比水溶液中於4 5 °C浸漬1 5分鐘後，由觀察平坦化膜的外觀變化進行保護膜的耐酸性之評估。此時，外觀無變化者爲耐酸性良好，而外觀已剝落且白化者爲耐酸性不良。耐鹼性上述保護膜（I I I )所形成的玻璃基板，浸漬於5 重量％氫氧化鈉水溶液中於3 0 °C下浸漬3 0分鐘後，藉由觀察保護膜的外觀變化對保護膜的耐酸性進行評估。此時，外觀無變化者爲耐鹼性良好，而外觀已剝落且白化者爲耐酸性不良。耐熱性對於上述所形成的保護膜（I I I )，以接觸式膜厚本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） •I ft— ϋ ϋ ft— ft— I ϋ ft— ϋ ft— ft— I · ·_1 ·1 -X (請先閲讀背面之注意事項再ίφ本頁) 0 .線- -46- 1250996 A7 B7 五、發明說明（44 ) 測定裝置α - step (天可爾日本股份有限公司製）測膜厚後，於無塵烤箱中進行250 °C以及270 °C、60分鐘的追加燒烤。經追加燒烤後，再度測定膜厚，計算出經追加燒烤前後之膜減少率。結果如表2所示。耐熱變色性對上述平坦化膜（I I I )所形成的玻璃基板，測定對波長4 0 0至7 0 0 nm的透過光譜。再將此玻璃基板於無塵烤箱中以2 5 0 °C下加熱6 0分鐘以及2 7 0。(：下加熱6 0分鐘後，再測定對波長4 0 0至7 0 0 nm的透過光譜。調查加熱前後的4 0 0 nm透過光譜之變化，評估耐熱變色性。以加熱前的4 0 0 nm的透過光譜値爲 1 0 0，加熱後的4 0 0 nm透過光譜之値如表2所示。平坦化性上述保護膜（I V)的表面凹凸，以表面凹凸計α -step測定。以下式爲準計算出之平坦化率如表2所示。平坦化率=保護膜（I V )的表面凹凸/保護膜塗佈前的彩色濾器之表面凹凸X100(%)。實施例6 作爲成份〔A ’〕使用合成例5的聚合物，其他與實施例4相同。結果如表2。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公藿） —— — — — — — — — — — —II · I I <請先閱讀背面之注意事項再i本頁) --線· 參經濟部智慧財產局員工消费合作社印製 -47- 1250996 A7 ------B7 經濟部智慧財產局貝工消费合作社印製五、發明說明（45 ) 實施例7 作爲成份〔A ’〕使用合成例5的聚合物，其他與實施例5相同。結果如表2。實施例8 含有上述合成例4所合成的聚合物〔A - 4〕聚合物溶、液（相當於1 0 0重量份（固體部份）的聚合物〔A -4〕），混合作爲成份〔D’〕使用2 0重量份的埃皮科特 1032H60 (環式脂肪族環氧基樹脂、油化貝殼環氧股份有限公司製）、作爲有機矽烷偶合劑使用5重量份的 ^ -環氧丙氧基丙基三甲氧基矽烷以及作爲界面活性劑使用〇 · 0 2重量份的美格福克1 7 2 (氟素界面活性劑、大曰本墨水化學股份有限公司製），欲使固體濃度成26 重量％添加丙二醇單甲基醚乙酸酯者作爲主劑，作爲成份 ^ F」的硬化劑，添加以二乙二醇甲基乙基醚的2 5%溶液以固體部份換算値爲2 0重量份的無水偏苯三酸，經充分攪拌後而得到硬化性組成物。使用此硬化性組成物，與實施例4相同形成保護膜（ III)、以及保護膜（I V )，進行評價。結果如表2 所示。 < . 比較例2 作爲〔A ’〕使用合成例6的聚合物其他與實施例4相同。結果如表2。 (請先閱讀背面之注意事項再4本頁) -裝 II· # •綠· 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -48- 1250996 A7 B7____五、發明說明（46 ) 比較例3 作爲〔A ’〕使用合成例7的聚合物其他與實施例4相同。結果如表2。表密著1: £ 表面硬度耐酸性 7Π1 AA 耐鹼性耐熱性耐熱變色性（％) 平坦化率 (%) (III) (IV) 250 °C 270 °C 250 °C 270 °c 貫施例4 0/100 0/100 4〜5H 良好良好 98.8 95.0 98.2 95.5 5.5 實施例5 0/100 0/100 4〜5H 良好良好 99.0 97.2 98.1 95,1 4.0 實施例6 0/100 0/100 4〜5H 良好良好 99.1 97.0 98.5 95,8 5.8 實施例7 0/100 0/100 4〜5H 良好良好 99.4 98.0 98.3 95.0 5.0 實施例8 0/100 0/100 4〜5H 良好良好 98.8 95.2 98.1 95.6 5.6 比較例2 0/100 0/100 4H 良好良好 96.0 73.2 94.9 83.3 4.2 比較例3 0/100 0/100 4〜5H 良好良好 97.8 87.5 98.3 94.7 4.9 請先閱讀背面之注意事項再t本頁：裝 •線· 經濟部智慧財產局員工消费合作社印製【發明的效果】本發明的硬化性組成物，係具有優良的耐熱性、平坦化性以及透明性之硬化物，此可製造出具有優良耐熱性的濾色保護膜。本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -49·(Please read the precautions on the back and then A • Binding: Line. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -45- Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 1250996 A7 _ B7 V. Inventive Note (43) The adhesion of the film (IV) is adhesion (; [V]. Surface hardness JISK — 5 4 0 0 (1 9 0 〇) 8 · 4 pencil scratch test The test method of 8 · 5 · 1 shall be carried out, and the protective film (III) formed above shall be subjected to a pencil scratch test to evaluate the surface hardness of the protective film. The results are shown in Table 2. The acid resistance is formed as described above. The glass substrate formed by the protective film (III) was immersed in an aqueous solution of HC Ι/FeC 12·Η2〇/water=2/1/1 by weight at 45 ° C for 15 minutes, and then observed by the planarizing film. The change in appearance is used to evaluate the acid resistance of the protective film. At this time, the appearance is unchanged, the acid resistance is good, and the appearance is exfoliated and the whitening is acid-resistant. The alkali-resistant glass substrate formed by the protective film (III), Immersed in a 5 wt% aqueous sodium hydroxide solution at 30 ° C After 30 minutes, the acid resistance of the protective film was evaluated by observing the change in the appearance of the protective film. At this time, the appearance was unchanged, the alkali resistance was good, and the appearance was peeled off and the whitening was poor in acid resistance. The protective film (III) formed above is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) in the contact film thickness. • I ft— ϋ ϋ ft— ft— I ϋ ft— ϋ ft — ft— I · ·_1 ·1 -X (Please read the notes on the back and then ίφ) 0. Line - -46- 1250996 A7 B7 V. Description of invention (44) Measuring device α - step (Tian Kerr After measuring the film thickness, the oven was heated at 250 ° C and 270 ° C for 60 minutes in a clean oven. After additional grilling, the film thickness was measured again, and the film reduction before and after additional grilling was calculated. The results are shown in Table 2. Heat Discoloration Resistance The glass substrate formed by the planarizing film (III) was measured for a transmission spectrum at a wavelength of from 400 to 700 nm. The glass substrate was placed in a dust-free oven. Heat at 60 ° C for 60 minutes and 2 70. (: After heating for 60 minutes, the transmission spectrum of the wavelength of 400 to 700 nm was measured. The change of the transmission spectrum of 400 nm before and after heating was investigated to evaluate the heat discoloration resistance. The transmission of 400 nm before heating was performed. The spectral enthalpy is 1 0 0, and the transmitted spectrum of the 400 nm after heating is shown in Table 2. Flatness The surface unevenness of the protective film (I V) was measured by a surface unevenness meter α -step. The flattening rate calculated by the following formula is shown in Table 2. Flattening ratio = surface unevenness of the protective film (I V ) / surface unevenness X100 (%) of the color filter before application of the protective film. Example 6 The polymer of Synthesis Example 5 was used as the component [A], and the same procedure as in Example 4 was carried out. The results are shown in Table 2. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 藿) —— — — — — — — — — — — II · II < Please read the notes on the back and then i) Line · Participating in the Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumer Cooperatives -47- 1250996 A7 ------B7 Ministry of Economic Affairs, Intellectual Property Bureau, Beigong Consumer Cooperatives Printing 5, Inventions (45) Example 7 as a component [A The polymer of Synthesis Example 5 was used, and the others were the same as in Example 5. The results are shown in Table 2. Example 8 The polymer [A-4] polymer solution (the polymer [A-4] equivalent to 100 parts by weight (solid portion)) synthesized in the above Synthesis Example 4 was mixed as a component [ D'] using 20 parts by weight of Epicot 1032H60 (cycloaliphatic epoxy resin, manufactured by Oiled Shell Epoxy Co., Ltd.), and using 5 parts by weight of ethyl epoxide as an organic decane coupling agent Oxypropyltrimethoxydecane and y·0 2 parts by weight of Meghfolk 172 (fluorine surfactant, manufactured by Otsuka Ink Chemical Co., Ltd.) as a surfactant 26% by weight of propylene glycol monomethyl ether acetate was added as a main component, and as a curing agent of the component F", a 25% solution of diethylene glycol methyl ethyl ether was added as a solid portion. 20 parts by weight of anhydrous trimellitic acid was sufficiently stirred to obtain a curable composition. Using this curable composition, a protective film (III) and a protective film (I V ) were formed in the same manner as in Example 4, and evaluated. The results are shown in Table 2. < . Comparative Example 2 The polymer of Synthesis Example 6 was used as the same as [A]. The results are shown in Table 2. (Please read the notes on the back and then on page 4) - Install II· # • Green · This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) -48- 1250996 A7 B7____ V. Invention Explanation (46) Comparative Example 3 The polymer of Synthesis Example 7 was used as [A'], and the same as Example 4 was used. The results are shown in Table 2. Table adhesion 1: £ Surface hardness Acid resistance 7Π1 AA Alkali resistance Heat resistance Color discoloration (%) Flatness (%) (III) (IV) 250 °C 270 °C 250 °C 270 °C Example 4 0/100 0/100 4~5H Good and good 98.8 95.0 98.2 95.5 5.5 Example 5 0/100 0/100 4~5H Good and good 99.0 97.2 98.1 95,1 4.0 Example 6 0/100 0/100 4~5H Good good 99.1 97.0 98.5 95,8 5.8 Example 7 0/100 0/100 4~5H Good good 99.4 98.0 98.3 95.0 5.0 Example 8 0/100 0/100 4~5H Good good 98.8 95.2 98.1 95.6 5.6 Comparative example 2 0/100 0/100 4H Good and good 96.0 73.2 94.9 83.3 4.2 Comparative example 3 0/100 0/100 4~5H Good and good 97.8 87.5 98.3 94.7 4.9 Please read the notes on the back and then t page: Installation • Line · Economy Printed by the Ministry of Intellectual Property and Employees' Consumer Cooperatives [Effects of the Invention] The curable composition of the present invention is a cured product having excellent heat resistance, flatness, and transparency, and can produce a color filter having excellent heat resistance. Protective film. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -49·

Claims

1250996 . Chowder 8 D8 ji' r,·* _,^· Apply for Qi Li's milk supplement “Supplementary patent application for patent application No. 9 1 1 5739] Amendment to the Chinese patent application date of July 29, 1993 -phenyl phenyl maleic anhydride condensed acrylic acid / (methyl / styrene propyl / Ν .1.0 (methyl) A curable composition characterized by containing [A] acrylic acid / (meth) acrylic acid epoxy Propylene/styrene copolymer, (methyl) epoxypropyl / N-cyclohexyl maleic anhydride (meth)acrylic acid / (meth) propylene - phenyl maleic anhydride imine / styrene / three Ring [Copolymer 2 '6] decane-8-yl (meth) acrylate co-acrylic acid / at least one base / N acrylamide epoxide 5.2 acrylate, cyclohexyl maleic anhydride imide /癸一 8 — - ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( D] is functionally derived from a base-initiating portion containing 200 parts by weight containing 1 to 4 0 if the application is specifically related to the [A part of the content ( Acrylic propylene acrylate / N styrene / tricyclo [5.2.1. 02'6] yl) propylene acrylate copolymers in the group of components, bodies, and agents, the amount is, every 1 0 0 Parts by weight of [A] parts by weight; in an amount of parts by weight per part by weight of [B] of the component (B). The hardenable composition of the first item of the first aspect, which contains an epoxy having a different composition The base resin and [E] acid star are 'per 10 parts by weight of the [A] component. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (21 297 297 metric tons) (please read the notes on the back first) Fill in this page again)

8 8 8 8 ABCD 1250996 VI. The scope of application for patents is 1 to 200 parts by weight; (Please read the notes on the back and fill out this page) [E] The content of the ingredients is (b) per 1 part by weight. The composition is from 0. 01 to 20 parts by weight. 3 - a curable composition characterized by containing [a,] at least one selected from the group consisting of (meth)acrylic acid epoxypropyl / N -phenylmaleic anhydride imide / styrene copolymer, (a Ethylene acrylate/N-cyclohexylmaleic anhydride imide/styrene copolymer, (meth)acrylic acid epoxy propyl/N-phenylmaleic anhydride imide/styrene/tricyclic [ 5 .2 . 1 . 0 2 ' 6]decane-8-yl (meth) acrylate copolymer, (meth)acrylic acid epoxy propyl / N-cyclohexyl maleic anhydride imide / styrene / a component of a tricyclic [5 · 2 _ 1 . 02'6] decane-8-yl (meth) acrylate copolymer, [F] at least one selected from the group consisting of polyelectrovalent carboxylic acid anhydrides and a compound in which a group of electron valence carboxylic acids is present, and an epoxy resin in which [D '] is different from the above [A '] component, and the content of the component [F] is [A ' per 1 part by weight. 〕Ingredients are from 1 to 100 parts by weight; The content of the ingredients [D5] printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs is, per 1 〇〇 weight [A5] When the ingredient is 1 to 200 parts by weight. 4. A sclerosing composition according to claim 3, which further contains an [E] acid initiator. The curable composition according to any one of claims 1 to 4, which forms a color filter protective film. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) -2-