TW536812B - Dynamic random access memory and manufacturing method thereof - Google Patents
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- TW536812B TW536812B TW91112448A TW91112448A TW536812B TW 536812 B TW536812 B TW 536812B TW 91112448 A TW91112448 A TW 91112448A TW 91112448 A TW91112448 A TW 91112448A TW 536812 B TW536812 B TW 536812B
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Abstract
Description
536812 A7 B7 優[L γ年%/灼匕无 五、·發明説明( 發明領域: 本發明係有關於一種動態隨機存取記憶體(Dynamic Random Access Memory ; Embedded DRAM)之結構及其製 造方法,特別是有關於利用金屬-絕緣層-金屬 (Metal-Insulator-Metal; MIM)之方法來製作動態隨機存取 記憶體之電容結構,但其應用不限於本領域。 發明背景: 互補式金氧半導體(Complementary Metal-Oxide Semiconductor ; CMOS)在技術上不斷地縮小尺寸,不論在 工業或消費性領域,提供了系統整合單晶片 (System-On-A-Chip ; SOC)的機會,也就是可以整合更多功 能在同一個晶片上。近來中央處理器(Central Processing Unit ; CPU)的面積不斷縮小,於一個晶片上其餘的空間將 填入記憶體及週邊線路。過去這幾年中,内崁式DRAM成 為非常受人重視的領域。這種内崁式技術的特性係結合邏 輯電路(Logic Circuit)與DRAM於同一個積體電路上,但仍 保持兩者正f的性能。在很多情形下,内崁式DRAM可由 兩個獨立的晶片(邏輯晶片加上DRAM晶片)組成,或者以 多晶片模組(Multi-Chip Module ; MCM)來取代,但這必須 由成本和功能的取捨來決定。不過,内崁式DRAM的獨特 優點所創造出的新商機非常具有潛力,這些優點包括高頻 寬、較有彈性的結構、低耗能量、小尺寸等等。 本紙張尺度適用中國國.家;^準(CNS)A4規格(210χ 297公袭) Γ L---.---1裝........‘訂.........線 <請先閲讀背面之注意事項再填寫本頁) 536812 1X年 h) 五發明説明( (請先閲讀背面之注意事項再填寫本頁) 由於邏輯電路和dram的製程各有其需求與特性,要 將這兩種製程整合是一個極大的挑戰。近來,製程發展的 努力放在如何將邏輯電路及dram的製程共通起來,如共 通的元件,電容的電極板與元件線等以減少光罩數目及節 省成本。最近,一種以金屬_絕緣層-金屬(MIM)之方法來製 作DRAM的電容,在内崁式DRAM的發展上得到極大重 視。因為此種電容製作方法可減化製程,又與邏輯電路的 後段製程相似,這使内崁式DRAM的接受度大為增加。 請參考第1圖,係繪示利用習知技術之内崁式Dram 的剖面結構圖。首先提供基材10,其材質為矽。此基材1〇 已疋義邏輯區1與DRAM區2,並於基材1〇中已設有複數 個淺溝渠隔離(Shallow Trench Isolation ; STI)結構 1 1、複 數個輕摻雜没極(Light Doped Drain)15與複數個源/汲極 (Source/Drain)17。在基材1〇上依序設有已定義之複數個 閘極氧化層12與複數個閘極多晶矽層1 3,並暴露出部份 之淺溝渠隔離結構1 1、部份之輕摻雜汲極1 5、與部份之源 /沒極17的表面,且於閘極氧化層12與閘極多晶矽層13 之兩側設有間隙壁16。然後,形成光阻保護氧化層(Resist〇r Protective Oxide Layer ; RP0 Layer)18 於閘極多晶矽層 13、間隙壁16、以及暴露之淺溝渠隔離結構u、輕摻雜汲 極1 5、與源/没極1 7的表面上,藉以在後續於邏輯區1進 行邏輯元件之製作時,光阻保護氧化層18可保護DRAM區 2。之後,以厚光阻層(圖未繪示)覆蓋DRAM區2,利用濕 本纸張尺度適用中國國.家標準(CNS)A4規格(210X 297公袭) 536812536812 A7 B7 Excellent [L γ% / Burning Dagger No. 5 · Description of the invention (Field of the invention: The present invention relates to a structure of a Dynamic Random Access Memory (Dynamic Random Access Memory; Embedded DRAM) and a method for manufacturing the same, In particular, it is related to the use of a metal-insulator-metal (MIM) method to fabricate a capacitor structure of a dynamic random access memory, but its application is not limited to this field. BACKGROUND OF THE INVENTION: Complementary metal-oxide-semiconductor (Complementary Metal-Oxide Semiconductor; CMOS) technology continues to shrink in size, whether in industrial or consumer fields, provides the opportunity of System-On-A-Chip (SOC), that is, can be integrated more Multifunctional on the same chip. Recently, the area of the Central Processing Unit (CPU) has been shrinking. The remaining space on a chip will be filled with memory and peripheral circuits. In the past few years, internal DRAM It has become a very important field. The characteristics of this intrinsic technology is to combine logic circuits and DRAM on the same integrated circuit. The performance of the two is still maintained. In many cases, the internal DRAM can be composed of two independent chips (logic chip plus DRAM chip), or replaced by a multi-chip module (MCM). However, this must be determined by the choice of cost and function. However, the unique advantages created by intrinsic DRAM have great potential. These advantages include high frequency, more flexible structure, low energy consumption, small size, etc. This paper size is applicable to Chinese homes; ^ quasi (CNS) A4 size (210χ 297 public attack) Γ L ---.--- 1 pack ......... 'Order ..... .... line < Please read the precautions on the back before filling this page) 536812 1X h) Five invention descriptions ((Please read the precautions on the back before filling this page) Because logic circuits and dram have their own processes Its requirements and characteristics are a great challenge to integrate these two processes. Recently, efforts in process development have focused on how to integrate logic circuits and dram processes, such as common components, capacitor electrode plates and component lines. To reduce the number of masks and save costs. Recently, one _ Insulating layer-metal (MIM) method for making DRAM capacitors has received great attention in the development of internal DRAM. Because this method of capacitor production can reduce the manufacturing process and is similar to the latter stage of logic circuits, this This greatly increases the acceptance of internal DRAM. Please refer to FIG. 1, which is a cross-sectional structure diagram of an internal-type ram using a conventional technique. First, a substrate 10 is provided, and the material is silicon. The substrate 10 has a logic region 1 and a DRAM region 2, and a plurality of Shallow Trench Isolation (STI) structures 1 have been provided in the substrate 10. A plurality of lightly doped anodes ( Light Doped Drain) 15 and a plurality of Source / Drain17. A plurality of gate oxide layers 12 and a plurality of gate polycrystalline silicon layers 13 are sequentially arranged on the substrate 10, and a part of the shallow trench isolation structure 1 is exposed. The electrodes 15 and the surface of the source / induction electrode 17 are provided with a spacer 16 on both sides of the gate oxide layer 12 and the gate polycrystalline silicon layer 13. Then, a Resistor Protective Oxide Layer (RP0 Layer) 18 is formed on the gate polycrystalline silicon layer 13, the spacer wall 16, and the exposed shallow trench isolation structure u, the lightly doped drain electrode 15, and the source. On the surface of / Waiji 17, the photoresist protective oxide layer 18 can protect the DRAM area 2 during the subsequent fabrication of logic elements in the logic area 1. After that, cover the DRAM area 2 with a thick photoresist layer (not shown), and use the wet paper standard to apply China National Standard (CNS) A4 specification (210X 297 public attack) 536812
五:、·發明説明( (請先閲讀j面之注意事項再場窝本頁) 式餘刻法去除邏輯區1之光阻保護氧化層18,並在邏輯區 1中’藉由自行對準金屬矽化物(Self-Aligned Silicide ; Salicide)之製程,於閘極多晶矽層13與源/汲極I?上形成 金屬矽化物層20,而金屬矽化物層20之材質則例如石夕化 始(Cobalt Silicide ; CoSix)。接著,去除 DRAM 區 2 上之 厚光阻層,先共形地形成蝕刻終止層21於邏輯區1與 DRAM區2上,再覆蓋氧化層22與蝕刻終止層23在邏輯 區1與DRAM區2上。然後,進行DRAM之電容之點接觸 之製作,係定義出複數個開口 24,以暴露出部份之輕摻雜 汲極15,其中開口 24係例如作為電容之點接觸窗(N〇de Contact)。之後,於點接觸窗中沉積阻障層(圖未繪示),其 中阻障層之材質係例如鈦/氮化鈦,並藉由化學氣相沉積 (Chemical Vapor Deposition ; CVD)法與化學機械研磨 (Chemical Mechanical Polishing; CMP)平坦化,將鎢插塞 (Tungsten Plug ; W Plug)25填滿於開口 24中,而形成如第 1圖所示之部份結構。在第1圖中鎢插塞25係作為電容之 點接觸。 然後’進行金屬-絕緣層-金屬型電容之製程,先覆蓋 氧化層26於邏輯區1與DRAM區2上,再定義氧化層26, 並暴露出部份之蝕刻終止層23與鎢插塞25 ,以在DRAM 區2中形成儲存點接觸窗(storage Node Contact)(圖未繪 示)。接著’於健存點接觸窗中依序共形地堆積阻障層27、 介電層28與阻障層29,並藉由化學氣相沉積法與化學機 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公愛) 536812 A7 B7Five :, · Description of the invention ((Please read the precautions on the j side first, and then use this page)) to remove the photoresist protective oxide layer 18 in the logic region 1 and align it in the logic region 1 by itself The process of metal-silicide (Self-Aligned Silicide; Salicide) forms a metal silicide layer 20 on the gate polysilicon layer 13 and the source / drain I ?, and the material of the metal silicide layer 20 is, for example, Shi Xihua ( Cobalt Silicide; CoSix). Next, the thick photoresist layer on the DRAM area 2 is removed, and an etch stop layer 21 is formed conformally on the logic area 1 and the DRAM area 2 and then covered with the oxide layer 22 and the etch stop layer 23 in the logic. Area 1 and DRAM area 2. Then, the point contact of the DRAM capacitor is made by defining a plurality of openings 24 to expose a part of the lightly doped drain electrode 15, where the opening 24 is, for example, the point of a capacitor. Node Contact. After that, a barrier layer (not shown) is deposited in the point contact window, wherein the material of the barrier layer is, for example, titanium / titanium nitride, and chemical vapor deposition (Chemical Vapor Deposition) is used. Vapor Deposition; CVD) and Chemical Mechanical Poli (shing; CMP) flattening, and a tungsten plug (Tungsten Plug; W Plug) 25 is filled in the opening 24 to form a partial structure as shown in FIG. 1. In the first figure, the tungsten plug 25 is used as The capacitor is in point contact. Then, the process of metal-insulating layer-metal capacitor is performed, and the oxide layer 26 is first covered on the logic region 1 and the DRAM region 2, and then the oxide layer 26 is defined, and a part of the etching stop layer 23 is exposed. And a tungsten plug 25 to form a storage node contact (not shown) in the DRAM area 2. Then, a barrier layer 27 and a dielectric layer are sequentially conformally deposited in the contact window of the healthy point. Electrical layer 28 and barrier layer 29, and chemical vapor deposition method and chemical machine paper size apply Chinese National Standard (CNS) A4 specification (210 x 297 public love) 536812 A7 B7
修正I濡J 五·、發明説明( 械研磨平坦化,將鎢插塞3 〇填入儲存點接觸窗中,而形成Correction I 濡 J V. Description of the invention (Mechanical grinding and flattening, filling tungsten contact plug 30 into the storage point contact window to form
請 先 閲 讀 Γ背 面 之 注 意 事 項 再 填 寫 本 頁 金屬-絕緣層-金屬型電容結構,其中阻障層2 7係作為下電 極板(Bottom Electrode Plate)。之後,進行上電極板之製 程,係利用微影與蝕刻之製程,定義鴒插塞30、阻障層29 與介電層28,而形成由鎢插塞3〇與阻障層29所組成之上 電極板(Top Electr〇4e Plate)3 1,其中上電極板3 1之寬度大 於電容之寬度,而形成如第1.圖所示之部份結構。 接著,位元線接觸之製程,係覆蓋氧化層32於邏輯區 1與DRAM區2上,並利用微影與蝕刻之製程,定義出複 數個開口 33,以暴露出邏輯區1中部份之金屬矽化物層20 與DRAM區2中部份之輕摻雜汲極15 ,其中開口 33係例 如作為位元線接觸窗(Bit Line Contact)。然後,沉積阻障 層(圖未繪示)於開口 3 3中,其中阻障層之材質係例如鈦/ 氮化欽’並藉由化學氣相沉積法與化學機械研磨製作鎢插 塞34於開口 33中,而形成如第1圖所示之部份結構。在 第1圖中之鶴插塞3 4係作為位元線接觸。 之後’依序覆蓋碳化矽(Silicon Carbide ; SiC)層35與 介電層36於氧化層32與鶴插塞34上,其中介電層36之 材質為低介電係數介電質。接著,進行邏輯區1與dram 區2之單金屬鑲嵌結構之製程’係先定義介電層36與碳化 矽層35,以形成開口 49,並暴露出邏輯區1與dRAM區2 之鎢插塞34,其中開口 49係為金屬導線開口,。然後,沉 積阻障層50於開口 49中,其中阻障層5〇之材質係例如氮 本紙張尺度適用中國國.家標準(CNS)A4規格(210 X 297公釐) 536812 A7 B7 五、.發明説明(Please read the notes on the back of Γ before filling in this page Metal-Insulation-Metal Capacitor Structure, where the barrier layer 2 7 is used as the bottom electrode plate (Bottom Electrode Plate). After that, the process of the upper electrode plate is performed. The process of lithography and etching is used to define the 鸰 plug 30, the barrier layer 29, and the dielectric layer 28, and a tungsten plug 30 and a barrier layer 29 are formed. Top electrode plate 31, wherein the width of the top electrode plate 31 is larger than the width of the capacitor, and a part of the structure shown in FIG. 1 is formed. Next, the process of bit line contact is to cover the oxide layer 32 on the logic region 1 and the DRAM region 2 and use the lithography and etching process to define a plurality of openings 33 to expose a part of the logic region 1 The metal silicide layer 20 and a portion of the lightly doped drain 15 in the DRAM region 2, wherein the opening 33 is, for example, a bit line contact window. Then, a barrier layer (not shown) is deposited in the opening 33. The material of the barrier layer is, for example, titanium / nitride, and a tungsten plug 34 is formed by chemical vapor deposition and chemical mechanical polishing. A part of the structure shown in FIG. 1 is formed in the opening 33. In the first figure, the crane plugs 3 and 4 are connected as bit lines. After that, the silicon carbide (Silicon Carbide; SiC) layer 35 and the dielectric layer 36 are sequentially covered on the oxide layer 32 and the crane plug 34, and the material of the dielectric layer 36 is a low-dielectric constant dielectric. Next, the process of the single metal damascene structure of logic region 1 and dram region 2 is to first define a dielectric layer 36 and a silicon carbide layer 35 to form an opening 49 and expose the tungsten plugs of logic region 1 and dRAM region 2 34, wherein the opening 49 is a metal wire opening. Then, a barrier layer 50 is deposited in the opening 49, in which the material of the barrier layer 50 is, for example, a nitrogen paper standard applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 536812 A7 B7 5. Description of the invention
請 先 閲 讀 .背 Φ 之 注 意 事 項 再 寫 本 頁 化组’並藉由化學氣相沉積法,將金屬層5 1填入開口 49 中並覆蓋於阻障層50上,其中金屬層51為金屬導線。之 後’再藉由化學機械研磨平坦化金屬層51與阻障層50, 而形成如第1圖所示之結構。 如上述習知技術之内崁式DRAM之剖面結構圖,係於 形成電容之點接觸後,先製作DRAM區2之電容及其上電 極板31,再進行位元線接觸窗(即開口 33)之製程。然而當 製程的線寬隨著元件積集度的上昇而逐漸縮短之後, DRAM區之電容受限於結構,已無法提供足夠之電容。首 先’在有限的單位元件面積内,需要有相當的高度以確保 有足夠的電容來儲存電荷。這額外增加的高度會使得隨後 的位元線接觸窗更難蝕刻。如欲藉由提高電容之高度來增 加表面積,以獲得dram區更多的電容,勢必會使得作為 位元線接觸窗之金屬導線開口變得更深,對於將金屬填入 位元線接觸窗是相當南的挑戰。其次,習知之dram區之 電容中尚具有上電極板31’這在定義上電極板31及位元 線接觸窗時·,兩者曝光的光罩容易產生重疊的區域,而使 得上電極板3 1及位元線接觸窗的大小均受到限制。 發明目的及概述: 鑒於上述之發明背景中,在製作dram區之電容不僅 需要有相當的高度以確保有足夠的電容來儲存電荷,同時 額外增加的高度會影響位元線接觸窗的蝕刻,相對也提高 將金屬填入位元線接觸窗之挑戰。其次,dram區之電容 本紙張尺度適用中國國.家標準(CNS)A4規格(210 X 297公釐)Please read the “Notes on Back Φ” before writing the page group and fill in the opening 49 and cover the barrier layer 50 by the chemical vapor deposition method, where the metal layer 51 is a metal wire. After that, the metal layer 51 and the barrier layer 50 are planarized by chemical mechanical polishing to form a structure as shown in FIG. As shown in the cross-sectional structure diagram of the internal DRAM of the conventional technology, after the point contact of the capacitor is formed, the capacitor of the DRAM area 2 and its upper electrode plate 31 are first made, and then the bit line contact window (ie, the opening 33) is made. The process. However, when the line width of the process is gradually shortened with the increase of the component accumulation degree, the capacitance of the DRAM area is limited by the structure, and it cannot provide sufficient capacitance. First, within a limited unit element area, a considerable height is required to ensure sufficient capacitance to store charge. This extra height makes subsequent bit line contact windows more difficult to etch. If you want to increase the surface area by increasing the height of the capacitor to obtain more capacitance in the dram region, the opening of the metal wire as the bit line contact window is bound to be deeper. It is equivalent to filling metal into the bit line contact window. South challenge. Secondly, the capacitor in the conventional dram area still has an upper electrode plate 31 ′. When defining the upper electrode plate 31 and the bit line contact window, the exposed masks of the two are likely to overlap, which makes the upper electrode plate 3 The size of the 1 and bit line contact windows is limited. Object and summary of the invention: In view of the above-mentioned background of the invention, not only does the capacitor in the dram region need to have a considerable height to ensure sufficient capacitance to store the charge, but the additional height will affect the etching of the bit line contact window. It also raises the challenge of filling metal into the bit line contact windows. Secondly, the capacitance of the dram area is suitable for the Chinese standard (CNS) A4 (210 X 297 mm).
536812 A7 -----— B7 五、.發明説明() 中尚具有上電極板,這在定義上電極板及位元線接觸窗 時兩者曝光的光罩容易產生重疊的區域,結果使得上電 極板及位70線接觸窗的大小均受到限制。 因此,本發明的主要目的之一為提供一種動態隨機存 取記憶體ί製造方法,其特徵在於形成電容之點接觸後, 先製作電容之位元線接觸,再製作電容及上電極板,因此 可降低動態隨機存取記憶體之高度,同時亦減少位元線接 觸窗之蝕刻深度。因此本發明避免習知技術需要有相當的 高度以確保有足夠的電容來儲存電荷的缺點。 本發明之另一目的為提供一種動態隨機存取記憶體之 製造方法,其另一特徵在於控制第一氧化層之厚度,藉以 降低位元線接觸窗的钱刻深度。因此本發明避免習知技術 在製作位元線接觸窗時,蝕刻高深寬比(High八邛⑽ Ratio’ HAR)開口及將金屬填入高深寬比開口之困難。 本發明之又一目的為提供一種動態隨機存取記憶體 之結構’其特徵在於所使用之電容之上電極板係為自行對 準式(Self-Aligned),即上電極板與電容等寬度,因此可以 獲得較多的電容。本發明避免習知技術定義上電極板及位 元線接觸窗時’兩者曝光的光罩容易產生重叠的區域,而 使得兩者的大小均受到限制。536812 A7 -----— B7 V. Description of the invention () There is still an upper electrode plate, which defines the areas where the exposed masks of the upper electrode plate and the bit line contact window easily overlap when the upper electrode plate and the bit line contact window are defined. As a result, The size of the upper electrode plate and the bit 70 line contact window are limited. Therefore, one of the main objects of the present invention is to provide a method for manufacturing a dynamic random access memory, which is characterized in that after the point contact of the capacitor is formed, the bit line contact of the capacitor is first made, and then the capacitor and the upper electrode plate are manufactured. It can reduce the height of the dynamic random access memory, and also reduce the etch depth of the bit line contact window. Therefore, the present invention avoids the disadvantage that the conventional technique requires a considerable height to ensure that there is sufficient capacitance to store the charge. Another object of the present invention is to provide a method for manufacturing a dynamic random access memory, which is further characterized by controlling the thickness of the first oxide layer, thereby reducing the depth of the engraving of the bit line contact window. Therefore, the present invention avoids the difficulty in etching the high aspect ratio (High 邛 ⑽ Ratio) HAR opening and filling the metal into the high aspect ratio opening when the bit line contact window is manufactured by the conventional technology. Another object of the present invention is to provide a structure of a dynamic random access memory, which is characterized in that the upper electrode plate of the capacitor used is self-aligned, that is, the width of the upper electrode plate and the capacitor, etc. Therefore, more capacitance can be obtained. The present invention avoids that conventionally, when the upper electrode plate and the bit line are in contact with the window, the photomasks exposed by both are prone to overlap, and the size of both is restricted.
II
[ 根據以上所述之目的,本發明提供了一種動態隨機存 f . 取記憶體之製造方法,至少包括:首先提供基材,其中基 ^ . 材上至少已設有第一蝕刻終止層並暴露出複數個點接觸; r 本紙張尺度適用中眺家標準(CNS) A4規格(2^297^^ ............,-¾........It.........$ <請先閲讀背面之注意事項再場寫本頁) 536812[According to the above-mentioned purpose, the present invention provides a method for dynamically and randomly storing f. Memory fetching, at least including: firstly providing a substrate, wherein the substrate has at least a first etch stop layer and is exposed. Plural points of contact; r This paper size is applicable to the CNS A4 specification (2 ^ 297 ^^ ............, -¾ ........ It ......... $ < Please read the notes on the back before writing this page) 536812
五:、·發明説明( (請先閲讀背面之注意事項再填窝本Ϊ 然後,形成第-氧化層於第_蚀刻終止層舆此也點接觸 上;然後進行位元線接觸之製程;之後,依序覆蓋碳化 石夕層 '第-介電層與第三#刻終止層於第二氧化層與第二 鎢插塞上;接著,進行金屬經祕思人 疋叮鱼屬·絕緣層-金屬型電容之製程, 係形成複數個電容於第一介雷涵、斤几〜θ ^ 示)丨電層、奴化矽層與第一氧化層 中,其中電容之上電極板係為自行對準式,即上電極板與 電容等寬度;以及,進行第一層金屬導線之製帛,係利用 單金屬鑲嵌(Single Damascene)之技術,於位元線接觸上形 成第一層金屬導線。 根據以上所述之目的,本發明更提供了 一種動態隨機 存取記憶體之結構,至少包括··基材,其中基材上至少已 設有第一蝕刻終止層,並暴露出複數個點接觸;第一氧化 層設於第一餘刻終止層與此些點接觸上;複數個位元線接 觸;碳化矽層與第一介電層依序設於第一氧化層與位元線 接觸上;複數個金屬·絕緣層-金屬型畲容設於第一介電 層、碳化矽層與第一氧化層中,其中電容之上電極板係為 自行對準式·,即上電極板與電容等寬度;以及複數個第〜 層金屬導線設於第一介電層與碳化石夕層中。 圖式簡單說明: 本發明的較佳實施例將於往後之說明文字中輔以下 列圖形做更詳細的闡述,其中: 第1圖係繪示利用習知技術之内崁式DRAM的剖面、蛛 構圖;以及 本紙張尺度適用中國國.家標準(CNS)A4規格(210 X 297公爱) 536812 A7 B7 五:、‘發明説明( -P 士 (請先閲讀背面之注意事項再填窝本頁} 第2圖至第1 9b圖係繪示依據本發明之一較佳實施例 進行内崁式DRAM製程的剖面圖,其中第13a圖係繪示第 13b圖與第13c圖之上視圖、第14a圖係繪示第14b圖與第 14c圖之上視圖、第15a圖係繪示第15b圖與第15c圖之上 視圖、第16a圖係繪示第l6b圖與第16c圖之上視圖、第 17a圖係繪示第17b圖與第17c圖與第17d圖之上視圖及第 1 9 a圖係緣示第1 9 b圖之上視圖。 圓號對照說明: 1 邏輯區 2 DRAM 區 10 基材 11 淺溝渠隔離結 12 閘極氧化層 13 閘極多晶發層 14 硬罩幕層 15 輕摻雜汲極 16 間隙壁 17 源/没極 18 光阻保護氧化層 19 光阻層 20 金屬矽化物層 21 敍刻終止層 22 氧化層 23 餘刻終止層 24 開口 25 鎢插塞 26 氧化層 27 阻障層 28 介電層 29 阻障層 30 鎢插塞 31 上電極板 32 氧化層 33 開口 34 嫣插塞 35 碳化石夕層 36 介電層 37 钱刻終止層 10 本紙張尺度適用中國國.家榼準(CNS)A4規格(210 X 297公袭) ,3.、536812 A7 B7 ^\\ (ψ 五、·發明説明(V :, · Description of the invention ((Please read the precautions on the back before filling in the text.) Then, the-oxide layer is formed on the _ etch stop layer and the point contact is made; then the bit line contact process is performed; , Sequentially covering the first dielectric layer and the third #etched stop layer of the carbide fossil layer on the second oxide layer and the second tungsten plug; and then, the metal is treated by the mysterious genus 疋 · insulation layer- The manufacturing process of metal capacitors is to form a plurality of capacitors in the first dielectric culvert, a few kilograms ~ θ ^) 丨 the electrical layer, the silicon layer and the first oxide layer, where the electrode plate above the capacitor is self-aligned According to the above, the width of the upper electrode plate and the capacitor, etc .; and the first layer of metal wires are made using a single metal damascene technique to form the first layer of metal wires on the bit line contacts. For the stated purpose, the present invention further provides a structure of a dynamic random access memory, including at least a base material, wherein at least a first etch stop layer is provided on the base material, and a plurality of point contacts are exposed; An oxide layer is set to terminate at the first moment The layer is in contact with these points; a plurality of bit line contacts; the silicon carbide layer and the first dielectric layer are sequentially disposed on the first oxide layer and the bit line contact; a plurality of metal · insulating layers-metal type capacitors It is located in the first dielectric layer, the silicon carbide layer and the first oxide layer, wherein the electrode plate above the capacitor is self-aligning type, that is, the width of the upper electrode plate and the capacitor is equal; In the first dielectric layer and the carbide layer. Brief description of the drawings: The preferred embodiment of the present invention will be described in more detail in the following explanatory text with the following figures, where: Figure 1 is a drawing Shows the cross-section and spider composition of the internal DRAM using the conventional technology; and this paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 public love) 536812 A7 B7 5: 'Explanation of invention (-P (Please read the precautions on the back before filling in this page} Figures 2 to 19b are cross-sectional views of an internal DRAM process in accordance with a preferred embodiment of the present invention, of which Figure 13a is The top views of Figures 13b and 13c are shown, and the Figure 14a shows the 14b and 14 Top view of Figure c, Figure 15a shows top views of Figures 15b and 15c, Figure 16a shows top views of Figures 16b and 16c, and Figure 17a shows Figure 17b and The top views of Figures 17c and 17d and the edge of Figure 19a show the top view of Figure 19b. The comparison of French horns: 1 Logic area 2 DRAM area 10 Substrate 11 Shallow trench isolation junction 12 Gate oxidation Layer 13 Gate polycrystalline layer 14 Hard cover curtain layer 15 Lightly doped drain 16 Spacer 17 Source / inverted 18 Photoresistive protective oxide layer 19 Photoresistive layer 20 Metal silicide layer 21 Termination stop layer 22 Oxide layer 23 End stop layer 24 Opening 25 Tungsten plug 26 Oxide layer 27 Barrier layer 28 Dielectric layer 29 Barrier layer 30 Tungsten plug 31 Upper electrode plate 32 Oxide layer 33 Opening 34 Bright plug 35 Carbide layer 36 Electric layer 37 Money engraved termination layer 10 This paper size is applicable to China. Furniture standard (CNS) A4 (210 X 297 public attack), 3., 536812 A7 B7 ^ \\ (ψ V. Description of the invention (
(請先閲讀背面之注意事項再埽寫本頁} 38 阻障層 40 光阻層 42 溝渠 44 阻障層 46 上電極板 48 光阻層 50 阻障層 t 預定厚度 e 區域 Η 高度 發明詳細說明: 本發明揭露-種動態隨機存取記憶體的製造方法,係 利用金屬'絕緣層-金屬之方法來製作内崁式動態隨機存取 記憶體之電容結構,其特徵在於形成電容之點接觸,先製 作電谷之位兀線接_ ’再製作電容及上電極板。為了使本 發明之敘述更加詳盡與完備,可參照下列描述並配合第2 圖至第19b圖,係綠示依據本發明之一較佳實施例進行内 炭式dram製程的剖面圖,其中第13a圖、第14&圖、第 15a圖、第16a圖、第17a圖及第19a圖係繪示依據本發明 之一較佳實施例進行内崁式DRAM製程之上視圖。本發明 係適用於内崁式動態隨機存取記憶體之製造,但不限於 此,亦可應用於其他型式之動態隨機存取記憶體之製造。 請參照第2圖’首先提供基材10,其材質為石夕。1基 11 本紙張尺度適用中國國.家_準(匸〜3)六4規格(210X297公逢) 536812 五:、·發明説明( A7 B7(Please read the precautions on the back before writing this page} 38 Barrier layer 40 Photoresist layer 42 Trench 44 Barrier layer 46 Upper electrode plate 48 Photoresist layer 50 Barrier layer t Predetermined thickness e Area Η Detailed description of the invention : The present invention discloses a method for manufacturing a dynamic random access memory, which uses a metal 'insulating layer-metal method to make a capacitive structure of an internal dynamic random access memory, which is characterized by forming a point contact of a capacitor, First make the cable connection of the electric valley _ 'and then make the capacitor and the upper electrode plate. In order to make the description of the present invention more detailed and complete, you can refer to the following description and cooperate with Figures 2 to 19b, which are shown in green according to the present invention. A preferred embodiment is a cross-sectional view of an internal carbon-type dram process, wherein FIG. 13a, FIG. 14 & FIG. 15a, FIG. 16a, FIG. 17a, and FIG. Top view of the preferred embodiment of the internal DRAM process. The present invention is suitable for the manufacture of internal dynamic random access memory, but is not limited to this. It can also be applied to the manufacture of other types of dynamic random access memory. . please According to Fig. 2 ', the base material 10 is provided first, and its material is Shi Xi. 1 base 11 This paper size is applicable to the Chinese country. Home_Jun (3 ~ 3) 6 4 specifications (210X297 public meeting) 536812 5 :, · Description of the invention (A7 B7
if 先 間 讀 .背 之 意 事 項 再 填 窝 本 頁 材10已定義邏輯區1與DRAM區2,並於基材10中已設 有複數個淺·溝渠隔離結構1 1。然後,在基材1 0上依序設 有已定義之複數個閘極氧化層12、複數個閘極多晶矽層13 與複數個硬罩幕層1 4,並暴露出部份之淺溝渠隔離結構 11,如第2圖所示之結構,其中硬罩幕層14之材質係例如 氮氧化石夕(Silicon Oxynitride ; SiOxNy)。接著,去除硬罩幕 層14’利用離子植入(i〇n impiantati〇n)法在基材1〇中形成 複數個輕摻雜汲極15,如第3圖所示之結構。然後,在閘 極氧化層12與閘極多晶矽層1 3之兩側形成間隙壁1 6,並 利用離子植入法在基材1 〇中形成源/汲極1 7,如第4圖所 示之結構。之後,共形地覆蓋光阻保護氧化層1 8於閘極多 晶矽層1 3、間隙壁1 6、以及暴露之淺溝渠隔離結構1 1、 輕摻雜汲極15、與源/汲極17的表面上,而形成如第5圖 所示之結構,藉以在後續於邏輯區1進行邏輯元件之製作 時’光阻保護氧化層1 8可保護DRAM區· 2。隨後,以厚光 阻層1 9覆蓋DRAM區2,利用濕式蝕刻法去除邏輯區1之 光阻保護氧化層18,並在邏輯區1中,藉由自行對準金屬 石夕化物之製程,於閘極多晶矽層1 3與源/汲極丨7上形成金 屬石夕化物層20,如第6圖所示之結構,其中金屬矽化物層 2〇之材質則例如矽化鈷(CoSix)。 接著,去除DRAM區2上之厚光阻層19,並共形地覆 蓋飯刻終止層2 1於邏輯區1之間隙壁1 6、金屬矽化物層 2〇、暴露之輕摻雜汲極15以及暴露之淺溝渠隔離結構n、 12 本紙張尺度適用中國國家;^準(CNS)A4規格(210 X 297公釐> 536812If you read it first. The meaning of the memorandum and then fill in this page. The material 10 has defined the logic area 1 and the DRAM area 2 and has a plurality of shallow trench isolation structures 11 in the base material 10. Then, a plurality of gate oxide layers 12, a plurality of gate polycrystalline silicon layers 13 and a plurality of hard mask layers 14 are sequentially arranged on the substrate 10 in sequence, and a part of the shallow trench isolation structure is exposed. 11. The structure shown in FIG. 2, wherein the material of the hard cover curtain layer 14 is, for example, Silicon Oxynitride (SiOxNy). Next, the hard mask layer 14 'is removed, and a plurality of lightly doped drain electrodes 15 are formed in the substrate 10 by an ion implantation (ion implantation) method, as shown in FIG. 3. Then, a spacer 16 is formed on both sides of the gate oxide layer 12 and the gate polycrystalline silicon layer 13, and a source / drain 17 is formed in the substrate 10 by an ion implantation method, as shown in FIG. 4. The structure. Thereafter, conformally covering the photoresist protective oxide layer 1 8 on the gate polycrystalline silicon layer 1 3, the spacer 16 and the exposed shallow trench isolation structure 1 1, the lightly doped drain 15 and the source / drain 17 On the surface, a structure as shown in FIG. 5 is formed, so that when a subsequent logic element is manufactured in the logic region 1, the photoresist protection oxide layer 18 can protect the DRAM region · 2. Subsequently, the DRAM area 2 is covered with a thick photoresist layer 19, and the photoresist protection oxide layer 18 of the logic area 1 is removed by a wet etching method, and in the logic area 1, by a process of self-aligning the metal oxide compound, A metal oxide layer 20 is formed on the gate polycrystalline silicon layer 13 and the source / drain electrode 7 as shown in FIG. 6, and the material of the metal silicide layer 20 is, for example, cobalt silicide (CoSix). Next, remove the thick photoresist layer 19 on the DRAM area 2 and conformally cover the etch stop layer 2 1 on the spacer 16 of the logic area 1, the metal silicide layer 20, and the exposed lightly doped drain electrode 15 And exposed shallow trench isolation structure n, 12 This paper size is applicable to China; ^ Standard (CNS) A4 size (210 X 297 mm > 536812
五、.發明説明(V. Description of the invention (
I !F P 與DRAM區2之光阻保護氧化層18上,其中蝕刻終止層 2 1之材質係例如氮氧化矽。然後,例如利用化學氣相沉積 (Chemical Vapor Deposition ; CVD)法來形成氧化層 22 於 蝕刻終止層21上,其中氧化層22之材質係例如内複晶矽 氧化物(Inter Poly Oxide ; IPO)或硼磷矽玻璃 (Boro-Phospho-Silicate Glass ; BPSG),如第 7 圖所示之結 構。之後’利用乾式餘刻法進行氧化層2 2之回姓刻,並控 制殘留在DRAM區2之閘極多晶石夕層13上的氧化層22至 預定厚度t,其中預定厚度t介於約1〇〇〇入± 400人之間。隨 後,在氧化層22上形成蝕刻終止層23 ,其中蝕刻終止層 23之材質係例如氮氧化矽或氮化矽(silic〇I1 Nitride ; SiNx)。接著,進行DRAM之電容之點接觸之製作,係定義 蝕刻終止層23、氧化層22、蝕刻終止層21與光阻保護氧 化層1 8,以形成複數個開口 24,並暴露出部份之輕摻雜汲 極15,其中開口 24係例如作為點接觸窗。之後,共形地 沉積阻障層(圖未繪示)於開口 24中,其中阻障層之材質係 例如鈦/氮化鈦,並藉由化學氣相沉積法與化學機械研磨平 坦化’將鎢插塞2 5覆蓋於阻障層上並填滿開口 2 4中,而 形成如第8圖所示之部份結構。在第8圖中之鎢插塞2 5係 作為電容之點接觸’並與DRAM區2之部份之輕摻雜没極 15連接。 然後,進行位元線接觸之製程,先覆蓋氧化層26於邏 輯區1與DRAM區2上,藉由微影與蝕刻之製程,定義邏 13 本纸張尺度適用中國國.家標準(CNS)A4規格(210X 297公爱) ............Γ---, (請先閲讀背面之注意事項再場寫本頁) 訂. 線 ^36812I! F P and the photoresist protective oxide layer 18 of the DRAM region 2, wherein the material of the etch stop layer 21 is, for example, silicon oxynitride. Then, for example, a chemical vapor deposition (Chemical Vapor Deposition; CVD) method is used to form an oxide layer 22 on the etch stop layer 21, wherein the material of the oxide layer 22 is, for example, Inter Poly Oxide (IPO) or Boro-Phospho-Silicate Glass (BPSG), as shown in Figure 7. Afterwards, the dry etching method is used to carry out the last name engraving of the oxide layer 22 and control the oxide layer 22 remaining on the gate polycrystalline stone layer 13 of the DRAM region 2 to a predetermined thickness t, wherein the predetermined thickness t is between about Between 100,000 and ± 400 people. Subsequently, an etch stop layer 23 is formed on the oxide layer 22, and the material of the etch stop layer 23 is, for example, silicon oxynitride or silicon nitride (SiN1Nitride; SiNx). Next, the point contact production of the DRAM capacitor is defined by defining the etch stop layer 23, the oxide layer 22, the etch stop layer 21, and the photoresist protection oxide layer 18 to form a plurality of openings 24, and expose a portion of the light. The doped drain 15 is formed, wherein the opening 24 serves as a point contact window, for example. Afterwards, a barrier layer (not shown) is deposited conformally in the opening 24. The material of the barrier layer is, for example, titanium / titanium nitride, and is planarized by chemical vapor deposition and chemical mechanical polishing. The tungsten plug 25 covers the barrier layer and fills the opening 24, thereby forming a partial structure as shown in FIG. The tungsten plug 25 in Fig. 8 serves as a point contact of the capacitor 'and is connected to the lightly doped electrode 15 of the part of the DRAM region 2. Then, the process of bit line contact is performed, and the oxide layer 26 is first covered on the logic area 1 and the DRAM area 2. The lithography and etching processes are used to define the logic 13. The paper size is applicable to the China National Standard (CNS) A4 specifications (210X 297 public love) ............ Γ ---, (Please read the precautions on the back before writing this page) Order. Line ^ 36812
'、·發明說明( 輯區1之氧化㉟26、钱刻終止層23、氧化層22、敍刻级 止層21與金屬梦化㈣2G,並定義DRAM區2之氧❹ %、餘刻終止層23、氧化層22、㈣終止層21與光阻: 遵氧化層18,以形成複數個開口 33,並暴露出邏輯區i中 部份之金屬梦化物層20與_區2中部份之輕摻雜及 極H,其巾33係、例如作為位元線接觸窗。然後,共 形地沉積阻障層(圖未繪示)於開口 33中,其中阻障層之材 質係例如鈦/氮化鈦,並藉由化學氣相沉積法與化學機械研 磨平坦化,將鎢插塞34覆蓋於此阻障層上並填滿於開口 33中,而形成如第9圖所示之部份結構。在第9圖中之鎢 插塞34係作為位元線接觸,並與DRAM區2之另一部份 之輕摻雜汲極15以及邏輯區丨之金屬矽化物層2〇連接。 之後,依序覆蓋碳化矽層3 5、介電層3 ό與蝕刻終止 層37於氧化層26與鎢插塞34上,其中介電層36之材質 係為低介電係數介電質(L〇w k Dielectrics),而形成如第j 〇 圖所不之結構。接著,進行金屬_絕緣層_金屬型電容之製 作’此電容為例如位元線下電容型動態隨機存取記憶體 (Capacitor Under Bit Line-DRAM; CUB-DRAM)之金屬-絕', · Description of the invention (Edition region 1 ㉟26, money etch stop layer 23, oxide layer 22, narration stop layer 21 and metal dream ㈣2G, and define the oxygen ❹% of DRAM area 2 and the etch stop layer 23 , Oxide layer 22, hafnium termination layer 21 and photoresist: follow the oxide layer 18 to form a plurality of openings 33 and expose a portion of the metal dream layer 20 in the logic region i and a light doping in the region _ The electrode 33 is, for example, a bit line contact window. Then, a barrier layer (not shown) is conformally deposited in the opening 33, and the material of the barrier layer is, for example, titanium / nitride. Titanium is planarized by chemical vapor deposition and chemical mechanical polishing. The tungsten plug 34 is covered on the barrier layer and filled in the opening 33 to form a partial structure as shown in FIG. 9. The tungsten plug 34 in FIG. 9 serves as a bit line contact, and is connected to the lightly doped drain 15 of the other part of the DRAM region 2 and the metal silicide layer 20 of the logic region 丨. Cover silicon carbide layer 3, dielectric layer 3, and etch stop layer 37 on oxide layer 26 and tungsten plug 34 in sequence. The material of dielectric layer 36 is low dielectric. Dielectrics (L0wk Dielectrics) to form a structure not shown in Figure j. Next, the metal_insulation layer_metal capacitor is made. This capacitor is, for example, a capacitor type dynamic random access under the bit line. Metal (Capacitor Under Bit Line-DRAM; CUB-DRAM)
I SF P f請先閲讀背面之>±意事項再嘴窝本ί 緣層-金屬型電容,係在DRAM區2中定義蝕刻終止層37、 介電層30、碳化矽層35與氧化層26,以形成儲存點接觸 窗39,並暴露出部份之蝕刻終止層23與鎢插塞25。然後, 於儲存點接觸窗3 9中共形地形成阻障層3 8,如第1 1圖所 示之結構,其中阻障層38之材質為氮化鈦(Titanium 14 本紙張尺度適用中國國家標準(CNS)A4規袼(210X297公爱) 536812I SF P f Please read the back side > ± Matters first, then the rim of the edge-metal capacitor, which defines the etch stop layer 37, the dielectric layer 30, the silicon carbide layer 35 and the oxide layer in the DRAM area 2. 26 to form a storage point contact window 39 and expose a part of the etch stop layer 23 and the tungsten plug 25. Then, a barrier layer 38 is conformally formed in the storage point contact window 39, as shown in the structure shown in FIG. 11, wherein the material of the barrier layer 38 is titanium nitride (Titanium 14) (CNS) A4 Regulations (210X297 Public Love) 536812
五:、·發明説明(Five :, · Description of invention (
Nitride ; TiN)或氮化组(Tantalum Nitride ; TaN),以氮化组Nitride; TiN) or nitrided group (Tantalum Nitride; TaN)
請 先 閲 讀 背 £ 之 注 意 事 項 再 埸 :裝 I 為較佳。隨後,利用光阻層4 0填滿儲存點接觸窗3 9並以 乾式ϋ刻法回餘刻儲存點接觸窗3 9内之光阻層4 0與阻障 層38凹陷至預定深度d,其中預定深度d約為1〇〇 〇Α,如 第12圖所示之結構,其中阻障層38係作為下電極板。 訂 隨後,請參考第1 3 a圖,係緣示本發明之一較佳實施 例在去除光阻層40與蝕刻終止層37後之内崁式DRAM製 程之上視圖,其中在DRAM區2中為介電層36、儲存點接 觸窗39及阻障層38,而剖面線A-A之製程剖面圖為第i3b 圖,且剖面線B-B之製程剖面圖為第13c圖。接著,請參 考第1 3b圖,係繪示沿著剖面線A-A所得之剖面圖,其中 阻障層3 8已凹陷至預定深度。然後,請參考第1 3 c圖,係 繪示沿著剖面線B - B所得之剖面圖,其中阻障層3 8亦已凹 陷至預定深度。 線 接者’請參考第1 4 a圖’係繪示本發明之一較佳實施 例在微影製程後利用扭線(Twist Line)型的光阻圖案覆蓋 在邏輯區1及DRAM區2之内炭式DRAM製程之上視圖, 其中扭線型的光阻圖案係用以形成上電極板之圖案,而區 域u為未曝光的區域,且區域e為已曝光並已姓刻出扭、線 之溝渠的區域,而剖面線A-A之製程剖面圖為第14b圖, 且剖面線B-B之製程剖面圖為第1 4c圖。然後,請參考第 14b圖,係繪示沿著剖面線A-A所得之剖面圖·,其中形成 扭線型圖案之光阻層4 1已定義出扭線型之溝渠42。之後, 15 本纸張尺度適用中國國.家標準(CNS)A4規格(210X 297公釐) 536812 A7 B7 /</ 五、·發明説明( 請參考第1 4C圖’係繪示沿著剖面線b-B所得之剖面圖, 其中區域e·中形成溝渠42之介電層36已去除,且區域6 中之阻障層3 8已蝕刻至與碳化矽層3 5約等高。根據本發 明之另一較佳實施例,亦可將區域e中之碳化矽層3 5與氧 化層26去除,藉以在後續製程中增加電容之面積,此另一 較佳實施例之製程於後詳述於第丨7d圖。 然後,請參考第15a圖,.係繪示本發明之一較佳實施 例在去除光阻層41後之内崁式DRAM製程之上視圖,其 中區域e為將形成扭線型之溝渠的區域,而剖面線a_a之 製程剖面圖為第1 5b圖,且剖面線B-B之製程剖面圖為第 15c圖。之後,請參考第15b圖,係繪示沿著剖面線a_a 所得之剖面圖,在去除光阻層41後,係暴露出儲存點接觸 囪3 9。再者’請參考第1 5 c圖,係緣示沿者剖面線b - b所 得之剖面圖,在去除光阻層4 1後,亦暴露出儲存點接觸窗 39。 * 之後,請參考第1 6 a圖’係繪不本發明之一較佳實施 例在形成銅層45後之内崁式DRAM製程之上視圖,其中 剖面線A-A之製程剖面圖為第16b圖,且剖面線B-B之製 程剖面圖為第16c圖。接著,請參考第16b圖,係繪示沿 著A-A所得之剖面圖,先依序共形地形成介電層43、阻障 層44在儲存點接觸窗39之阻障層38上,再覆蓋鋼層45 在阻障層44上並填滿儲存點接觸窗39中,其中介電層43 之材質為高介電係數介電質,而高介電係數介電質則例如 16 本紙張尺度適用中國國.家;^準(CNS)A4規格(210X297公爱) ----裝: (請先閲讀背面之注意事項再埃寫本頁) 丨訂· 線 536812 五、·發明説明()Please read the note of memorandum before reading: 装 I is better. Subsequently, the photoresist layer 40 is used to fill the storage point contact window 39, and the photoresist layer 40 and the barrier layer 38 in the storage point contact window 39 are recessed to a predetermined depth d by dry etching. The predetermined depth d is about 1000 A, as shown in FIG. 12, wherein the barrier layer 38 is used as the lower electrode plate. After ordering, please refer to FIG. 13a, which shows a top view of an internal DRAM process after removing the photoresist layer 40 and the etch stop layer 37 according to a preferred embodiment of the present invention. In the DRAM area 2, For the dielectric layer 36, the storage point contact window 39, and the barrier layer 38, the process cross-sectional view of the section line AA is the i3b figure, and the process cross-section view of the section line BB is the 13c figure. Next, please refer to FIG. 13b, which is a cross-sectional view taken along the section line A-A, in which the barrier layer 38 has been recessed to a predetermined depth. Then, please refer to FIG. 1 c, which is a cross-sectional view taken along the section line B-B, in which the barrier layer 38 has also been recessed to a predetermined depth. The line connector 'please refer to Figure 14a' shows a preferred embodiment of the present invention to cover the logic area 1 and DRAM area 2 with a Twist Line type photoresist pattern after the lithography process. Top view of the internal carbon DRAM process, where the twisted photoresist pattern is used to form the pattern of the upper electrode plate, and the area u is the unexposed area, and the area e is the exposed and surnamed engraved twist and line. In the area of the trench, the cross-sectional view of the process of section line AA is FIG. 14b, and the cross-sectional view of the process of section line BB is FIG. 14c. Then, please refer to FIG. 14b, which is a cross-sectional view taken along the section line A-A, in which the twist-type groove 42 is defined in the photoresist layer 41 that forms the twist-type pattern. After that, 15 paper sizes are applicable to China National Standard (CNS) A4 specification (210X 297 mm) 536812 A7 B7 / < / V. Description of the invention (please refer to Figure 14C) The cross-sectional view of line bB, in which the dielectric layer 36 forming the trench 42 in the region e · has been removed, and the barrier layer 38 in the region 6 has been etched to approximately the same height as the silicon carbide layer 35. According to the present invention, In another preferred embodiment, the silicon carbide layer 35 and the oxide layer 26 in the area e can also be removed, so as to increase the area of the capacitor in the subsequent process. The process of this another preferred embodiment is described in detail in the following section.丨 7d. Then, please refer to FIG. 15a, which shows a top view of the internal DRAM process after removing the photoresist layer 41 in a preferred embodiment of the present invention, where the area e is a twisted line In the trench area, the process cross-section view of section line a_a is Figure 15b, and the process cross-section view of section line BB is Figure 15c. After that, please refer to Figure 15b, which shows the section obtained along section line a_a. Figure, after the photoresist layer 41 is removed, the storage point is exposed to the contact point 39. Furthermore, 'please refer to section 1 5c The system edge shows the cross-sectional view along the section line b-b. After the photoresist layer 41 is removed, the storage point contact window 39 is also exposed. * After that, please refer to FIG. 16 a. A preferred embodiment is a top view of an internal DRAM process after the copper layer 45 is formed, wherein the process cross-sectional view of the section line AA is FIG. 16b, and the process cross-sectional view of the section line BB is FIG. 16c. Next, Please refer to Figure 16b, which is a cross-sectional view taken along AA. A dielectric layer 43 and a barrier layer 44 are sequentially conformally formed on the barrier layer 38 of the storage point contact window 39, and then covered with a steel layer. 45 on the barrier layer 44 and filled in the storage point contact window 39, wherein the material of the dielectric layer 43 is a high dielectric constant dielectric, and the high dielectric constant dielectric is, for example, 16 .Home; ^ quasi (CNS) A4 specification (210X297 public love) ---- install: (Please read the precautions on the back before writing this page) 丨 order · line 536812 V. · description of the invention ()
五乳化二鈕(Ta2〇5),至於阻障層44之材質為例如氮化起 ⑽)。再者,請參考第l6e圖,騎示沿著剖面線B-B所 得之剖面圖,在去除光阻層41後,亦依序共形地形成介電 層43 |a障層44在儲存點接觸窗中,並將銅層覆 蓋在阻障層44上且填滿儲存點接觸窗39中。 隨後,請參考第17a _,係緣示纟發明之一較佳實施 例在經過化學機械研磨平坦化.後之内炭式DRAM製程之上 視圖中銅層4 5經過化學機械研磨平坦化後轉變為扭線 型之銅層45a,而剖面線A-A之製程剖面圖為第17b圖, 且剖面線B-B之製程剖面圖為第17〇圖。接著,請參考第 1 7b圖,係繪示沿著剖面線A-A所得之剖面圖,銅層45經 過化學機械研磨平坦化後轉變為銅層45a,使内崁式Dram 整體兩度轉變為高度Η。同時,部份之阻障層44與部份之 銅層45a垂直組成上電極板46,其中上電極板46係為自行 對準式’即上電極板46與儲存點接觸窗39等寬度,而銅 層45a即構成扭線型之上電極板46。然後,請參考第i7c 圖,係繪示沿著剖面線B-B所得之剖面圖,銅層45經過化 學機械研磨後轉變為銅層45a,使内崁式DRAM整體高度 轉變為高度Η’,其中高度Η ’與高度Η為約相等。之後, 請參考第1 7d圖,係繪示根據本發明之另一較佳實施例沿 著剖面線B-B所得之剖面圖,係將碳化矽層3 5與氧化層 26去除,以暴露出部份之蝕刻終止層23。隨後·,依序共形 地形成介電層43與阻障層44在阻障層38與蝕刻終止層 17 本纸張尺度適用中國國家瘭準(CNS)A4規格(210 X 297公爱)Five-emulsion two buttons (Ta205), and the material of the barrier layer 44 is, for example, nitride nitride. Furthermore, please refer to FIG. 16e, and show the cross-sectional view taken along the section line BB. After the photoresist layer 41 is removed, the dielectric layer 43 | a and the barrier layer 44 are sequentially conformally formed at the storage point contact window. The copper layer is covered on the barrier layer 44 and fills the storage point contact window 39. Subsequently, please refer to Section 17a_, which is a preferred embodiment of the invention, which is planarized by chemical mechanical polishing. In the top view of the internal carbon DRAM process, the copper layer 45 is transformed by chemical mechanical polishing and planarization. It is a twisted copper layer 45a, the cross-sectional view of the process of section line AA is FIG. 17b, and the cross-sectional view of the process of section line BB is FIG. 170. Next, please refer to FIG. 17b, which is a cross-sectional view taken along the cross-section line AA. The copper layer 45 is transformed into a copper layer 45a after being planarized by chemical mechanical polishing, so that the entire internal-type ram is transformed to a height of Η twice. . At the same time, part of the barrier layer 44 and part of the copper layer 45a form the upper electrode plate 46 perpendicularly, wherein the upper electrode plate 46 is self-aligned, that is, the upper electrode plate 46 and the storage point contact window 39 are as wide as The copper layer 45a constitutes a twisted upper electrode plate 46. Then, please refer to FIG. I7c, which is a cross-sectional view taken along the section line BB. The copper layer 45 is converted into a copper layer 45a after chemical mechanical polishing, so that the overall height of the internal DRAM is changed to a height Η ', where the height Η 'is approximately equal to height Η. After that, please refer to FIG. 17d, which is a cross-sectional view taken along section line BB according to another preferred embodiment of the present invention. The silicon carbide layer 35 and the oxide layer 26 are removed to expose a part. The etch stop layer 23. Subsequently, a dielectric layer 43 and a barrier layer 44 are formed conformally in order. The barrier layer 38 and the etch stop layer 17 are formed on this paper. The paper size is applicable to China National Standard (CNS) A4 (210 X 297).
536812 五、. 發明説明()536812 V. Explanation of the invention ()
23上,並將鋼層45覆蓋在阻障 ^ φ $ Λ 上且填滿於儲存點接 觸向39中,,再經過化學機械研 /由允山4 ^ ^後將鋼層45轉變為鋼層 45a,使内坎式dRam整體高度 得變為兩度Η’,其中高声 Η,與高度Η為約相等,而形成如 ,、史〇度 第17d圖之結構,苴中第 i7d圖之電容結構之表面積比 筹八中第 積來得大。 帛…圖之電容結構之表面 接著,依序形成蝕刻終止層 • w 47與光阻層48於介雷層 36、介電層43、阻障層44與鋼 s宣—装紅w 增45a上,以光阻層48為 罩幕,疋義蝕刻終止層47、介雷 €層36與碳化矽層35,藉 以形成複數個開口 49,並暴露出鎮 鴣插塞34,而形成如第 1 8圖所不之結構。在第1 8圖中之M ^ <開口 49,係於後續進行 單金屬鑲嵌製程之用。 τ 之後’請參考第19a圖,传給一 係繪不本發明之一較佳實施 例在依序填入阻障層50與金屬層s^ 30增51後的内崁式DRAM製 程之上視圖,其中作為電容之上雷 · 極板之鋼層45a為扭線 型,而剖面線A-A之製程剖面圖Λ馇 Μ馬第19b圖。接著,請參 考第19b圖;係繪示沿著剖面線a Λ 所得之剖面圖,首先 共形地形成阻障層50在開口 49 Φ ^ τ ’其中阻障層50之材質 係例如為氮化组。然後,藉由化擧名 G予軋相沉積法,將金屬層23, and the steel layer 45 is covered on the barrier ^ φ $ Λ and filled in the contact point 39 of the storage point. After chemical mechanical research / Yunshan 4 ^ ^, the steel layer 45 is transformed into a steel layer 45a, the overall height of the internal dRam becomes two degrees Η ', in which the high-pitched Η is approximately equal to the height ,, and forms a structure such as the history of FIG. 17d, and the capacitance of i7d in FIG. The surface area of the structure is larger than that of the eighth high school.帛 ... The surface of the capacitor structure is followed by the formation of an etch stop layer in sequence • w 47 and photoresist layer 48 on the dielectric layer 36, the dielectric layer 43, the barrier layer 44 and the steel s—install red w by 45a The photoresist layer 48 is used as a mask, the etching stop layer 47, the dielectric layer 36, and the silicon carbide layer 35 are formed, thereby forming a plurality of openings 49, and exposing the ballast plug 34, as shown in FIG. The structure not shown in the figure. M ^ < opening 49 in Fig. 18 is used for subsequent single metal damascene process. After τ ', please refer to FIG. 19a, which is a top view of an internal DRAM process after a barrier layer 50 and a metal layer s ^ 30 are sequentially added to a preferred embodiment of the present invention. Among them, the steel layer 45a serving as the thunder plate on the capacitor is twisted, and the cross-sectional view of the process line AA is shown in FIG. 19b. Next, please refer to FIG. 19b; it is a cross-sectional view taken along the section line a Λ. First, a barrier layer 50 is conformally formed at the opening 49 Φ ^ τ 'wherein the material of the barrier layer 50 is, for example, nitride. group. Then, the metal layer was deposited by the pseudo-G pre-rolled phase deposition method.
51填入開口 49中並覆蓋於阻障層L 巧50上,其中金屬層51 為金屬導線。之後,再藉由化學機楠讲&丁 ^ 啊餓研磨平坦化金屬層51 與阻障層50,而形成如第19b圖所示之妹構。 根據本發明所提供之動態隨機存取\己憶體之製造方 18 本紙張尺度適用中國國.家稔準(CNS)A4規格(210X297公釐) Α751 is filled in the opening 49 and covers the barrier layer L5050, wherein the metal layer 51 is a metal wire. After that, the planarization metal layer 51 and the barrier layer 50 are polished by a chemical machine and ammonium oxide to form a sister structure as shown in FIG. 19b. The manufacturer of dynamic random access / memory body provided by the present invention 18 This paper size is applicable to China. Furniture Standard (CNS) A4 (210X297 mm) Α7
=觸在於形成電容之點接觸後,先製作位元線 觸(Ρ鶴插塞34),再製作雷& (即金屬居⑴。 電極板46與金屬導線 ^ ^ )’、藉由控制氧化層22之厚度,以降低動態 1己憶體之高度。請比較第1圖,習知技術係先製 電谷再製作位元線接觸,因此需形成氧化層⑴臭,才能 、:金屬導線之製作’戶斤以不僅增加動態隨機存取記憶體 =回度’更增加蝕刻高深寬比開口及將金屬填入高深寬比 :口之困難。反之’請參考帛m圖,本發明先製作位元 、·、,觸再製作電谷、上電極板46與金屬導線,並藉由控 】氧化層22之厚度’在不需形成氧化層32的條件下,即 可製作金屬導線,當然降低動態隨機存取記憶體之高度。 根據本發明所提供之動態隨機存取記憶體之製造方 法其另一特徵在於所使用之電容的上電極板46,其圖案 係為扭線型而非整面式,且本發明之上電極板粍與電容結 構、金屬層51以及介電層36均等高,如第19b圖所示之 結構。相較於習知技術之上電極板31,不僅突出於電容結 構,而且金屬層51更高過上電極板31,如第!圖所示之 結構。= The touch is to form a point contact of the capacitor, first make a bit line contact (Phe plug 34), and then make a thunder & (ie, metal dwelling. The electrode plate 46 and the metal wire ^ ^), by controlling the oxidation The thickness of the layer 22 is to reduce the height of the dynamic memory. Please compare Figure 1. The conventional technology is to make the electric valley first and then to make the bit line contact. Therefore, it is necessary to form an oxide layer to deodorize. In order to: The production of metal wires not only increases dynamic random access memory = back The degree 'increases the difficulty of etching high aspect ratio openings and filling metal into high aspect ratio: mouth. On the contrary, please refer to the 帛 m diagram. In the present invention, first, the bit, ·, and the electrode are made, and then the valley, the upper electrode plate 46, and the metal wire are produced, and the thickness of the oxide layer 22 is controlled. Under the conditions, metal wires can be made, of course, the height of the dynamic random access memory is reduced. The method for manufacturing a dynamic random access memory provided by the present invention is further characterized in that the upper electrode plate 46 of the capacitor used has a twisted line pattern instead of a full surface type, and the upper electrode plate of the present invention 粍It has the same height as the capacitor structure, metal layer 51 and dielectric layer 36, as shown in the structure shown in FIG. 19b. Compared to the conventional electrode plate 31, not only does it protrude from the capacitor structure, but the metal layer 51 is higher than the upper electrode plate 31, as described above! The structure shown in the figure.
I P 根據本發明所提供之動態隨機存取記憶體之结構,立 又一特徵在於所使用之電容之上電極板46係為自行對準 式,即上電極板46與電容等寬度,且部份之阻障層44與 部份之銅層45a垂直組成上電極板46,如第i9b圖所示之 結構’當定義上電極板46及金屬導線開口(即開口 49)時, 19 本纸張尺度適用中國國家標準(CNS)A4規格(21〇X297公誉) 536812 A7 B7IP According to the structure of the dynamic random access memory provided by the present invention, another feature is that the upper electrode plate 46 of the capacitor used is self-aligning, that is, the width of the upper electrode plate 46 and the capacitor is equal, and part The barrier layer 44 and a portion of the copper layer 45a form the upper electrode plate 46 perpendicularly. The structure shown in FIG. I9b 'When defining the upper electrode plate 46 and the opening of the metal wire (ie, the opening 49), 19 paper sizes Applicable to China National Standard (CNS) A4 specification (21 × 297 reputation) 536812 A7 B7
XT 五、·發明説明() 兩者曝光的光罩不易產生重疊的區域,因此可以獲得較多 的電容。 請 先 閲 讀 .背 ΰ 之 注 意 事· 項 再 堤 寫 本 頁 因此’本發明之一優點就是提供一種動態隨機存取記 憶體之製造方法,其特徵在於形成電容之點接觸,先製作 電容之位元線接觸’再製作電容及上電極板,因此可降低 動態隨機存取έ己憶體之兩度’同時亦減少位元線接觸窗之 姓刻深度。因此本發明避免習知技術需要有相當的高度以 確保有足夠的電容來儲存電荷的缺點。 本發明之另一優點為提供一種動態隨機存取記憶體之 製造方法,其另一特徵在於控制第一氧化層之厚度,藉以 降低位元線接觸窗的儀刻深度。因此本發明避免習知技術 在製作位元線接觸®時’钱刻高深寬比開口及將金屬填入 高深寬比開口之困難。 本發明之又一優點為提供一種動態隨機存取記憶體之 結構,其特徵在於所使用之電容之上電極板係為自行對準 式’即上電極板與電容等寬度,因此可以獲得較多的電容。 本發明避免習知技術定義上電極板及位元線接觸窗時,兩 者曝光的光罩容易產生重疊的區域,而使得兩者的大小均 受到限制。 經濟部智慧財產局員工消费合作社印製 如熟悉此技術之人員所瞭解的,以上所述僅為本發明 之較佳實施例而已,並非用以限定本發明之申請專利範 圍;凡其它未脫離本發明所揭示之精神下所完成之等效改 變或修飾,均應包括在下述之申請專利範圍内。 本紙張尺度適用中國國家標準(CNS)A4規格(210X297公釐)XT V. Description of the invention () The exposed masks of the two are not likely to produce overlapping areas, so more capacitance can be obtained. Please read it first. Note on the back · Items and then write this page So 'One of the advantages of the present invention is to provide a method for manufacturing a dynamic random access memory, which is characterized by the formation of a point contact of a capacitor, and the capacitor is first made. The element line contact 're-produces the capacitor and the upper electrode plate, so that the dynamic random access can be reduced to two degrees, and at the same time, the depth of the bit line contact window is reduced. The present invention therefore avoids the disadvantages of conventional techniques that require considerable height to ensure sufficient capacitance to store charge. Another advantage of the present invention is to provide a method for manufacturing a dynamic random access memory, which is further characterized by controlling the thickness of the first oxide layer, thereby reducing the engraving depth of the bit line contact window. Therefore, the present invention avoids the difficulty of the conventional technique when making the bit line contact ® to make a high aspect ratio opening and fill a metal with a high aspect ratio opening. Another advantage of the present invention is to provide a structure of a dynamic random access memory, which is characterized in that the upper electrode plate of the capacitor used is self-aligned, that is, the width of the upper electrode plate and the capacitor, so that more can be obtained. Capacitor. The present invention avoids that when the upper electrode plate and the bit line contact window are defined by the conventional technique, the exposed masks of the two are likely to produce overlapping areas, so that the sizes of both are limited. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. As understood by those familiar with this technology, the above is only a preferred embodiment of the present invention, and is not intended to limit the scope of patent application for the present invention. Equivalent changes or modifications made under the spirit disclosed by the invention should be included in the scope of patent application described below. This paper size applies to China National Standard (CNS) A4 (210X297 mm)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101990710B (en) * | 2008-04-08 | 2013-01-30 | 美光科技公司 | High aspect ratio openings |
| TWI419265B (en) * | 2007-03-06 | 2013-12-11 | 南亞科技股份有限公司 | Semiconductor structure and forming method |
-
2002
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI419265B (en) * | 2007-03-06 | 2013-12-11 | 南亞科技股份有限公司 | Semiconductor structure and forming method |
| CN101990710B (en) * | 2008-04-08 | 2013-01-30 | 美光科技公司 | High aspect ratio openings |
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