TW350863B - Liquid, radiation-curable composition, especially for stereolithography - Google Patents
Liquid, radiation-curable composition, especially for stereolithographyInfo
- Publication number
- TW350863B TW350863B TW086110701A TW86110701A TW350863B TW 350863 B TW350863 B TW 350863B TW 086110701 A TW086110701 A TW 086110701A TW 86110701 A TW86110701 A TW 86110701A TW 350863 B TW350863 B TW 350863B
- Authority
- TW
- Taiwan
- Prior art keywords
- weight
- methyl
- formula
- liquid
- hydrogen atom
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 239000007788 liquid Substances 0.000 title abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- -1 aryl acrylate Chemical compound 0.000 abstract 2
- 239000012952 cationic photoinitiator Substances 0.000 abstract 2
- 239000003085 diluting agent Substances 0.000 abstract 2
- 239000003822 epoxy resin Substances 0.000 abstract 2
- 239000000945 filler Substances 0.000 abstract 2
- 239000012949 free radical photoinitiator Substances 0.000 abstract 2
- 229920000647 polyepoxide Polymers 0.000 abstract 2
- 125000006755 (C2-C20) alkyl group Chemical group 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 102220467487 Drebrin_R10G_mutation Human genes 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000002440 hydroxy compounds Chemical class 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920000193 polymethacrylate Polymers 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/022—Polycondensates containing more than one epoxy group per molecule characterised by the preparation process or apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/62—Alcohols or phenols
- C08G59/621—Phenols
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0037—Production of three-dimensional images
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Resins (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Materials For Photolithography (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH188596 | 1996-07-29 | ||
| CH220196 | 1996-09-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW350863B true TW350863B (en) | 1999-01-21 |
Family
ID=25688916
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW086110701A TW350863B (en) | 1996-07-29 | 1997-07-28 | Liquid, radiation-curable composition, especially for stereolithography |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5972563A (zh) |
| EP (1) | EP0822445B2 (zh) |
| JP (1) | JP3564650B2 (zh) |
| KR (1) | KR100491736B1 (zh) |
| AT (1) | ATE191090T1 (zh) |
| AU (1) | AU716984B2 (zh) |
| CA (1) | CA2211628C (zh) |
| DE (1) | DE59701299D1 (zh) |
| ES (1) | ES2144836T3 (zh) |
| TW (1) | TW350863B (zh) |
Families Citing this family (71)
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| US6287745B1 (en) | 1998-02-18 | 2001-09-11 | Dsm N.V. | Photocurable liquid resin composition comprising an epoxy-branched alicyclic compound |
| US6136497A (en) * | 1998-03-30 | 2000-10-24 | Vantico, Inc. | Liquid, radiation-curable composition, especially for producing flexible cured articles by stereolithography |
| US6100007A (en) * | 1998-04-06 | 2000-08-08 | Ciba Specialty Chemicals Corp. | Liquid radiation-curable composition especially for producing cured articles by stereolithography having high heat deflection temperatures |
| US6287748B1 (en) | 1998-07-10 | 2001-09-11 | Dsm N.V. | Solid imaging compositions for preparing polyethylene-like articles |
| US6762002B2 (en) | 1998-07-10 | 2004-07-13 | Dsm Desotech, Inc. | Solid imaging compositions for preparing polypropylene-like articles |
| US6379866B2 (en) * | 2000-03-31 | 2002-04-30 | Dsm Desotech Inc | Solid imaging compositions for preparing polypropylene-like articles |
| US20060154175A9 (en) * | 1998-07-10 | 2006-07-13 | Lawton John A | Solid imaging compositions for preparing polypropylene-like articles |
| ES2345031T3 (es) * | 2000-02-08 | 2010-09-14 | Huntsman Advanced Materials (Switzerland) Gmbh | Composicion liquida curable por radiacion, especialmente para estereolitografia. |
| JP4837187B2 (ja) * | 2001-06-06 | 2011-12-14 | 株式会社クラレ | 活性エネルギー線硬化性樹脂組成物 |
| US6811937B2 (en) * | 2001-06-21 | 2004-11-02 | Dsm Desotech, Inc. | Radiation-curable resin composition and rapid prototyping process using the same |
| US20030149124A1 (en) * | 2001-11-27 | 2003-08-07 | Thommes Glen A. | Radiation curable resin composition for making colored three dimensional objects |
| US20030198824A1 (en) * | 2002-04-19 | 2003-10-23 | Fong John W. | Photocurable compositions containing reactive polysiloxane particles |
| CN100576069C (zh) * | 2002-05-03 | 2009-12-30 | Dsm;Ip财产有限公司 | 可辐射固化树脂组合物及利用该组合物的快速成型方法 |
| GB0212977D0 (en) * | 2002-06-06 | 2002-07-17 | Vantico Ag | Actinic radiation curable compositions and their use |
| US20040054025A1 (en) * | 2002-06-20 | 2004-03-18 | Lawton John A. | Compositions comprising a benzophenone photoinitiator |
| US6989225B2 (en) * | 2002-07-18 | 2006-01-24 | 3D Systems, Inc. | Stereolithographic resins with high temperature and high impact resistance |
| US6833231B2 (en) * | 2002-07-31 | 2004-12-21 | 3D Systems, Inc. | Toughened stereolithographic resin compositions |
| US20040077745A1 (en) * | 2002-10-18 | 2004-04-22 | Jigeng Xu | Curable compositions and rapid prototyping process using the same |
| US20040087687A1 (en) * | 2002-10-30 | 2004-05-06 | Vantico A&T Us Inc. | Photocurable compositions with phosphite viscosity stabilizers |
| US20040137368A1 (en) * | 2003-01-13 | 2004-07-15 | 3D Systems, Inc. | Stereolithographic resins containing selected oxetane compounds |
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| US6856283B2 (en) * | 2003-02-28 | 2005-02-15 | Raytheon Company | Method and apparatus for a power system for phased-array radar |
| DE10328302A1 (de) * | 2003-06-23 | 2005-01-27 | Dreve Otoplastik Gmbh | Niedrigviskose, strahlungshärtbare Formulierung, insbesondere für die Stereolithographie, zum Einsatz in der Medizintechnik, insbesondere zur Herstellung von Ohrstücken |
| US20050040562A1 (en) * | 2003-08-19 | 2005-02-24 | 3D Systems Inc. | Nanoparticle-filled stereolithographic resins |
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| US20070149667A1 (en) * | 2003-10-16 | 2007-06-28 | Dsm Ip Assets B.V. | Curable compositions and rapid prototyping process using the same |
| US20050101684A1 (en) * | 2003-11-06 | 2005-05-12 | Xiaorong You | Curable compositions and rapid prototyping process using the same |
| US20050165127A1 (en) * | 2003-12-31 | 2005-07-28 | Dsm Desotech, Inc. | Solid imaging compositions for preparing polyethylene-like articles |
| GB0413366D0 (en) | 2004-06-15 | 2004-07-21 | Heeschen Andreas | Binder-free photopolymerizable compositions |
| DE102004030019A1 (de) * | 2004-06-22 | 2006-01-19 | Xetos Ag | Photopolymerisierbare Zusammensetzung |
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| JP4753601B2 (ja) * | 2005-03-23 | 2011-08-24 | 旭化成イーマテリアルズ株式会社 | 感光性組成物 |
| JP5306814B2 (ja) * | 2005-09-13 | 2013-10-02 | スリーディー システムズ インコーポレーテッド | Abs類似物品製造を目的とした光硬化性組成物 |
| US20070075461A1 (en) * | 2005-09-30 | 2007-04-05 | 3D Systems, Inc. | Rapid prototyping and manufacturing system and method |
| US7690909B2 (en) * | 2005-09-30 | 2010-04-06 | 3D Systems, Inc. | Rapid prototyping and manufacturing system and method |
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| US20070092733A1 (en) * | 2005-10-26 | 2007-04-26 | 3M Innovative Properties Company | Concurrently curable hybrid adhesive composition |
| JP5084461B2 (ja) * | 2007-11-16 | 2012-11-28 | 東邦化学工業株式会社 | 光重合性不飽和化合物 |
| EP2215525B1 (en) * | 2007-11-27 | 2018-01-10 | 3D Systems Incorporated | Photocurable resin composition for producing three dimensional articles having high clarity |
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| CN102665402B (zh) * | 2009-12-22 | 2014-09-10 | 亨斯迈石油化学有限责任公司 | 含有柔性片段和刚性片段的醚胺及其作为用于聚合物合成的中间体的用途 |
| JP5680108B2 (ja) | 2009-12-22 | 2015-03-04 | ハンツマン ペトロケミカル エルエルシーHuntsman Petrochemical LLC | エーテルアミンおよびそれらを重合体合成時に中間体として用いる使用 |
| KR20170091788A (ko) | 2009-12-23 | 2017-08-09 | 메르크 파텐트 게엠베하 | 중합체성 결합제를 포함하는 조성물 |
| EP2468789A1 (de) | 2010-12-24 | 2012-06-27 | Sika Technology AG | Klebstoff für Rotorblätter für Windkraftanlagen |
| EP2814802B1 (en) | 2012-02-17 | 2020-12-16 | Huntsman Advanced Materials Americas LLC | Mixture of benzoxazine, epoxy and anhydride |
| AR098050A1 (es) | 2013-10-18 | 2016-04-27 | Huntsman Petrochemical Llc | Eteraminas con mayor estabilidad térmica y su uso como curativos o intermediarios para la síntesis de polímeros |
| JP6056032B2 (ja) | 2013-11-05 | 2017-01-11 | ディーエスエム アイピー アセッツ ビー.ブイ. | 付加造形用の安定化マトリックス充填液状放射線硬化性樹脂組成物 |
| US10513578B2 (en) | 2013-11-05 | 2019-12-24 | Huntsman Petrochemical Llc | Etheramines and their use as curatives or intermediates for polymer synthesis |
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| CN114734628A (zh) | 2014-06-23 | 2022-07-12 | 卡本有限公司 | 由具有多重硬化机制的材料制备三维物体的方法 |
| MX2017015276A (es) | 2016-01-12 | 2018-02-19 | Huntsman Petrochemical Llc | Preparacion simultanea de polieteraminas y alquilenaminas. |
| US20190153226A1 (en) | 2016-04-08 | 2019-05-23 | Solvay Specialty Polymers Usa, Llc | Photocurable polymers, photocurable polymer compositions and lithographic processes including the same |
| US11198756B2 (en) | 2016-06-16 | 2021-12-14 | Huntsman Petrochemical Llc | Blend for curing epoxy resin composistions |
| US11650498B2 (en) | 2016-06-30 | 2023-05-16 | 3M Innovative Properties Company | Printable compositions including highly viscous components and methods of creating 3D articles therefrom |
| AU2017312122A1 (en) | 2016-08-19 | 2019-02-28 | Huntsman Advanced Materials Americas Llc | Adducts and uses thereof |
| US11542364B2 (en) | 2017-02-06 | 2023-01-03 | Huntsman Petrochemical Llc | Curing agent for epoxy resins |
| ES2945162T3 (es) | 2017-02-06 | 2023-06-28 | Huntsman Petrochemical Llc | Agente de curado para resinas epoxi |
| ES2685280B2 (es) | 2017-03-31 | 2019-06-21 | Centro Tecnologico De Nanomateriales Avanzados S L | Composición de resina curable por radiación y procedimiento para su obtención |
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| KR102780988B1 (ko) | 2020-02-04 | 2025-03-17 | 캐보트 코포레이션 | 액체-기반 적층 제조를 위한 조성물 |
| EP3909747A1 (en) | 2020-05-12 | 2021-11-17 | TIGER Coatings GmbH & Co. KG | Thermosetting material for use in a 3d printing process |
| BR112023017181A2 (pt) | 2021-02-25 | 2023-09-26 | Huntsman Adv Mat Licensing Switzerland Gmbh | Composição polimerizável monocomponente para impregnação por gotejamento |
| EP4094942A1 (en) | 2021-05-26 | 2022-11-30 | TIGER Coatings GmbH & Co. KG | Radiation curable composition for additive manufacturing suitable for electronic applications |
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| JP3197907B2 (ja) * | 1991-02-15 | 2001-08-13 | 旭電化工業株式会社 | エネルギー線を用いた注型成型方法 |
| JP2873126B2 (ja) * | 1991-04-17 | 1999-03-24 | 日本ペイント株式会社 | 体積ホログラム記録用感光性組成物 |
| TW269017B (zh) * | 1992-12-21 | 1996-01-21 | Ciba Geigy Ag | |
| TW259797B (zh) * | 1992-12-23 | 1995-10-11 | Ciba Geigy | |
| JPH07128856A (ja) * | 1993-04-30 | 1995-05-19 | Japan Synthetic Rubber Co Ltd | 感光性樹脂組成物および感光性樹脂レジスト |
| EP0646580B1 (de) * | 1993-09-16 | 2000-05-31 | Ciba SC Holding AG | Vinyletherverbindungen mit zusätzlichen von Vinylethergruppen verschiedenen funktionellen Gruppen und deren Verwendung zur Formulierung härtbarer Zusammensetzungen |
| US5707780A (en) * | 1995-06-07 | 1998-01-13 | E. I. Du Pont De Nemours And Company | Photohardenable epoxy composition |
| US5665792A (en) * | 1995-06-07 | 1997-09-09 | E. I. Du Pont De Nemours And Company | Stabilizers for use with photoacid precursor formulations |
| JPH09268205A (ja) * | 1996-03-29 | 1997-10-14 | Asahi Denka Kogyo Kk | 光学的立体造形用樹脂組成物および光学的立体造形法 |
-
1997
- 1997-07-21 EP EP97810510A patent/EP0822445B2/de not_active Expired - Lifetime
- 1997-07-21 AT AT97810510T patent/ATE191090T1/de not_active IP Right Cessation
- 1997-07-21 ES ES97810510T patent/ES2144836T3/es not_active Expired - Lifetime
- 1997-07-21 KR KR1019970033932A patent/KR100491736B1/ko not_active Expired - Lifetime
- 1997-07-21 DE DE59701299T patent/DE59701299D1/de not_active Expired - Lifetime
- 1997-07-25 CA CA002211628A patent/CA2211628C/en not_active Expired - Lifetime
- 1997-07-28 US US08/901,303 patent/US5972563A/en not_active Expired - Lifetime
- 1997-07-28 AU AU31579/97A patent/AU716984B2/en not_active Ceased
- 1997-07-28 TW TW086110701A patent/TW350863B/zh not_active IP Right Cessation
- 1997-07-29 JP JP21822197A patent/JP3564650B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU716984B2 (en) | 2000-03-16 |
| AU3157997A (en) | 1998-02-05 |
| CA2211628A1 (en) | 1998-01-29 |
| ATE191090T1 (de) | 2000-04-15 |
| EP0822445A1 (de) | 1998-02-04 |
| KR980009381A (ko) | 1998-04-30 |
| US5972563A (en) | 1999-10-26 |
| JPH1087791A (ja) | 1998-04-07 |
| JP3564650B2 (ja) | 2004-09-15 |
| EP0822445B1 (de) | 2000-03-22 |
| DE59701299D1 (de) | 2000-04-27 |
| KR100491736B1 (ko) | 2005-09-09 |
| EP0822445B2 (de) | 2005-02-09 |
| CA2211628C (en) | 2007-03-13 |
| ES2144836T3 (es) | 2000-06-16 |
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| MK4A | Expiration of patent term of an invention patent |